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Hydromechanical coupling in geologic processes

Earth's porous crust and the fluids within it are intimately linked through their mechanical effects on each other. This paper presents an overview of such "hydromechanical" coupling and examines current understanding of its role in geologic processes. An outline of the theory of hydromechanics and rheological models for geologic deformation is included to place various analytical approaches in proper context and to provide an introduction to this broad topic for nonspecialists. Effects of hydromechanical coupling are ubiquitous in geology, and can be local and short-lived or regional and very long-lived. Phenomena such as deposition and erosion, tectonism, seismicity, earth tides, and barometric loading produce strains that tend to alter fluid pressure. Resulting pressure perturbations can be dramatic, and many so-called "anomalous" pressures appear to have been created in this manner. The effects of fluid pressure on crustal mechanics are also profound. Geologic media deform and fail largely in response to effective stress, or total stress minus fluid pressure. As a result, fluid pressures control compaction, decompaction, and other types of deformation, as well as jointing, shear failure, and shear slippage, including events that generate earthquakes. By controlling deformation and failure, fluid pressures also regulate states of stress in the upper crust. Advances in the last 80 years, including theories of consolidation, transient groundwater flow, and poroelasticity, have been synthesized into a reasonably complete conceptual framework for understanding and describing hydromechanical coupling. Full coupling in two or three dimensions is described using force balance equations for deformation coupled with a mass conservation equation for fluid flow. Fully coupled analyses allow hypothesis testing and conceptual model development. However, rigorous application of full coupling is often difficult because (1) the rheological behavior of geologic media is complex and poorly understood and (2) the architecture, mechanical properties and boundary conditions, and deformation history of most geologic systems are not well known. Much of what is known about hydromechanical processes in geologic systems is derived from simpler analyses that ignore certain aspects of solid-fluid coupling. The simplifications introduce error, but more complete analyses usually are not warranted. Hydromechanical analyses should thus be interpreted judiciously, with an appreciation for their limitations. Innovative approaches to hydromechanical modeling and obtaining critical data may circumvent some current limitations and provide answers to remaining questions about crustal processes and fluid behavior in the crust.

Hydrogeology Journal↗

Electrothermal atomisation atomic absorption conditions and matrix modifications for determining antimony, arsenic, bismuth, cadmium, gallium, gold, indium, lead, molybdenum, palladium, platinum, selenium, silver, tellurium, thallium and tin following back-extraction of organic aminohalide extracts

A multi-element organic-extraction and back-extraction procedure, that had been developed previously to eliminate matrix interferences in the determination of a large number of trace elements in complex materials such as geological samples, produced organic and aqueous solutions that were complex. Electrothermal atomisation atomic absorption conditions and matrix modifications have been developed for 13 of the extracted elements (Ag, As, Au, Bi, Cd, Ga, In, Pb, Sb, Se, Sn, Te and Tl) that enhance sensitivity, alleviate problems resulting from the complex solutions and produce acceptable precision. Platinum, Pd and Mo can be determined without matrix modification directly on the original unstripped extracts.

Journal of Analytical Atomic Spectrometry↗

Predicting baseflow alkalinity as an index to episodic stream acidification and fish presence

Regression models to predict baseflow alkalinity from basin hydrogeology were developed and verified for headwater streams on the Laurel Hill anticline in southwestern Pennsylvania. Predicted baseflow alkalinities were then used to estimate sensitivity to acidification and presence of trout ( Salvelinus fontinalis ) populations for 61 headwater streams. Sensitivity classifications were verified by surveying trout populations. Geologic variables relating to the carbonate rock burial depth, extent of carbonate rock recharge areas, and length of stream channel flowing through effluent carbonate rock outcrops were much more useful in predicting baseflow alkalinity than areal extent of carbonate rocks. Baseflow alkalinity was not well related to status of trout populations on these anticlinal basins, especially on noneffluent basins where bedrock dip exceeded surface slope.

Journal of the American Water Resources Associatio↗

Chemical hydrogeology in natural and contaminated environments

Chemical hydrogeology, including organic and inorganic aspects, has contributed to an increased understanding of groundwater flow systems, geologic processes, and stressed environments. Most of the basic principles of inorganic-chemical hydrogeology were first established by investigations of organic-free, regional-scale systems for which simplifying assumptions could be made. The problems of groundwater contamination are causing a shift of emphasis to microscale systems that are dominated by organic-chemical reactions and that are providing an impetus for the study of naturally occurring and manmade organic material. Along with the decrease in scale, physical and chemical heterogeneity become major controls. Current investigations and those selected from the literature demonstrate that heterogeneity increases in importance as the study site decreases from regional-scale to macroscale to microscale. Increased understanding of regional-scale flow systems is demonstrated by selection of investigations of carbonate and volcanic aquifers to show how applications of present-day concepts and techniques can identify controlling chemical reactions and determine their rates; identify groundwater flow paths and determine flow velocity; and determine aquifer characteristics. The role of chemical hydrogeology in understanding geologic processes of macroscale systems is exemplified by selection of investigations in coastal aquifers. Phenomena associated with the mixing zone generated by encroaching sea water include an increase in heterogeneity of permeability, diagenesis of minerals, and formation of geomorphic features, such as caves, lagoons, and bays. Ore deposits of manganese and uranium, along with a simulation model of ore-forming fluids, demonstrate the influence of heterogeneity and of organic compounds on geochemical reactions associated with genesis of mineral deposits. In microscale environments, importance of heterogeneity and consequences of organic reactions in determining the distribution and concentrations cf. constituents are provided by several studies, including infiltration of sewage effluent and migration of creosote in coastal plain aquifers. These studies show that heterogeneity and the dominance of organically controlled reactions greatly increase the complexity of investigations.Current investigations and those selected from the literature demonstrate that heterogeneity increases in importance as the study site decreases from regional-scale to macroscale to microscale. Increased understanding of regional-scale flow systems is demonstrated by selection of investigations of carbonate and volcanic aquifers to show how application of present-day concepts and techniques can identify controlling chemical reactions and determine their rates; identify groundwater flow paths and determine flow velocity; and determine aquifer characteristics. The role of chemical hydrogeology in understanding geologic processes of macroscale systems is exemplified by selection of investigations in coastal aquifers. Ore deposits of manganese and uranium, along with a simulation model of ore-forming fluids, demonstrate the influence of heterogeneity and of organic compounds on geochemical reactions associated with genesis of mineral deposits. In microscale environments, importance of heterogeneity is illustrated by studies of infiltration of sewage effluent and migration of creosote in coastal plain aquifers.

Journal of Hydrology↗

Digital mapping of the Mars Pathfinder landing site: Design, acquisition, and derivation of cartographic products for science applications

The Imager for Mars Pathfinder (IMP) acquired more than 16,000 images and provided panoramic views of the surface of Mars at the Mars Pathfinder landing site in Ares Vallis. This paper describes the stereoscopic, multispectral IMP imaging sequences and focuses on their use for digital mapping of the landing site and for deriving cartographic products to support science applications of these data. Two‐dimensional cartographic processing of IMP data, as performed via techniques and specialized software developed for ISIS (the U.S. Geological Survey image processing software package), is emphasized. Cartographic processing of IMP data includes ingestion, radiometric correction, establishment of geometric control, coregistration of multiple bands, reprojection, and mosaicking. Photogrammetric processing, an integral part of this cartographic work which utilizes the three‐dimensional character of the IMP data, supplements standard processing with geometric control and topographic information [ Kirk et al. , this issue]. Both cartographic and photogrammetric processing are required for producing seamless image mosaics and for coregistering the multispectral IMP data. Final, controlled IMP cartographic products include spectral cubes, panoramic (360° azimuthal coverage) and planimetric (top view) maps, and topographic data, to be archived on four CD‐ROM volumes. Uncontrolled and semicontrolled versions of these products were used to support geologic characterization of the landing site during the nominal and extended missions. Controlled products have allowed determination of the topography of the landing site and environs out to ∼60 m, and these data have been used to unravel the history of large‐ and small‐scale geologic processes which shaped the observed landing site. We conclude by summarizing several lessons learned from cartographic processing of IMP data.

Journal of Geophysical Research E: Planets↗

Mars reconnaissance orbiter's high resolution imaging science experiment (HiRISE)

The HiRISE camera features a 0.5 m diameter primary mirror, 12 m effective focal length, and a focal plane system that can acquire images containing up to 28 Gb (gigabits) of data in as little as 6 seconds. HiRISE will provide detailed images (0.25 to 1.3 m/pixel) covering ∼1% of the Martian surface during the 2‐year Primary Science Phase (PSP) beginning November 2006. Most images will include color data covering 20% of the potential field of view. A top priority is to acquire ∼1000 stereo pairs and apply precision geometric corrections to enable topographic measurements to better than 25 cm vertical precision. We expect to return more than 12 Tb of HiRISE data during the 2‐year PSP, and use pixel binning, conversion from 14 to 8 bit values, and a lossless compression system to increase coverage. HiRISE images are acquired via 14 CCD detectors, each with 2 output channels, and with multiple choices for pixel binning and number of Time Delay and Integration lines. HiRISE will support Mars exploration by locating and characterizing past, present, and future landing sites, unsuccessful landing sites, and past and potentially future rover traverses. We will investigate cratering, volcanism, tectonism, hydrology, sedimentary processes, stratigraphy, aeolian processes, mass wasting, landscape evolution, seasonal processes, climate change, spectrophotometry, glacial and periglacial processes, polar geology, and regolith properties. An Internet Web site (HiWeb) will enable anyone in the world to suggest HiRISE targets on Mars and to easily locate, view, and download HiRISE data products.

Journal of Geophysical Research E: Planets↗

The geologic history of Margaritifer basin, Mars

In this study, we investigate the fluvial, sedimentary, and volcanic history of Margaritifer basin and the Uzboi-Ladon-Morava (ULM) outflow channel system. This network of valleys and basins spans more than 8000 km in length, linking the fluvially dissected southern highlands and Argyre Basin with the northern lowlands via Ares Vallis. Compositionally, thermophysically, and morphologically distinct geologic units are identified and are used to place critical relative stratigraphic constraints on the timing of geologic processes in Margaritifer basin. Our analyses show that fluvial activity was separated in time by significant episodes of geologic activity, including the widespread volcanic resurfacing of Margaritifer basin and the formation of chaos terrain. The most recent fluvial activity within Margaritifer basin appears to terminate at a region of chaos terrain, suggesting possible communication between surface and subsurface water reservoirs. We conclude with a discussion of the implications of these observations on our current knowledge of Martian hydrologic evolution in this important region.

Journal of Geophysical Research E: Planets↗

Applying U-Th disequilbrium for dating siliceous sinters

Continental hydrothermal systems are critical avenues for the crustal transport of heat and mass captured for geothermal energy and mineral exploration. Thus, understanding their temporal evolution and longevity is important for resource characterization. Deposits of microlaminated siliceous sinter, common surface expressions of high temperature reservoirs (> 170 °C), have the potential to trace hydrothermal histories. Geothermal reservoirs are often located within uranium-bearing silicic volcanic rock where subsurface fluid-rock interactions extract U into hydrothermal fluids. U incorporated in the surface sinter deposit has the potential to provide a U— Th disequilibrium dating option. We focus on samples from El Tatio geyser field in the Altiplano of northern Chile, the largest geothermal system in the Andes. Our resulting 230 Th/U ages, along with the water and deposit elemental compositions, suggest concentrations of U and Th vary predictably along the sinter apron. While distal facies containing the highest U concentrations (> 50 μg/g) are least affected by detrital Th corrections, they can display suspected open-system behavior. In contrast, more medial facies, where bacterial mats and other porous textures are co mmonly concentrated, have only trace amounts of U (< 0.1 μg/g), which leads to unreliable or geologically improbable dates. Proximal facies tend to date most consistently. By comparing existing 14 C ages with 230 Th/U results, 230 Th/U ages tend to be younger than the 14 C ages, supporting the presence of a 14 C-dead carbon influence. New data confirm that the onset of geothermal activity at El Tatio goes back to the late Pleistocene.

Altiplano, El Tatio geyser field↗

Erosional and depositional patterns associated with the 1993 Missouri River floods inferred from SIR-C and TOPSAR radar data

The Missouri River floods of 1993 caused significant and widespread damage to the floodplains between Kansas City and St. Louis. Immediately downstream of levee breaks, flood waters scoured the bottoms. As the floodwaters continued, they spread laterally and deposited massive amounts of sand as crevasse splays on top of agricultural fields. We explore the use of radar interferometry and backscatter data for quantitative estimation of scour and deposition for Jameson Island/Arrow Rock Bottoms and Lisbon Bottoms, two bottoms that were heavily damaged during the floods and subsequently abandoned. Shuttle imaging radar C (SIR-C) L band (24 cm) HH (horizontally transmitted and horizontally received) radar backscatter data acquired in October 1994 were used together with a distorted Born approximation canopy scattering model to determine that the abundance of natural leafy forbs controlled the magnitude of backscatter for former agricultural fields. Forb areal density was found to be inversely correlated with thickness of sand deposited during the floods, presumably because thick sands prevented roots from reaching nutrient rich, moist bottoms soils. Using the inverse relationship, a lower bound for the mass of sand added was found to be 6.3 million metric tons over the 17 km 2 study area. Digital elevation data from topographic synthetic aperture radar (TOPSAR) C band (5.6 cm) interferometric observations acquired in August 1994 were compared to a series of elevation profiles collected on the ground. Vertical errors in TOPSAR were estimated to range from 1 to 2 m, providing enough accuracy to generate an estimate of total mass (4.7 million metric tons) removed during erosion of levees and scour of the bottoms terrains. Net accretion of material to the study areas is consistent with the geologic record of major floods where sediment-laden floodwaters crested over natural levees, initially scoured into the bottoms, and then deposited sands as crevasse splays as the flows spread out and slowed by frictional dissipation. The addition of artificial levees to the Missouri River system has undoubtedly enhanced flood damage, although quantitative estimation of the degree of enhancement will require additional work.

Journal of Geophysical Research E: Planets↗

Precision of geodolite surveys: A reply to Jackson and Cheng

Jackson and Cheng have suggested that the changes in areal dilatation measured in Geodolite surveys by the U.S. Geological Survey may be simply an artifact of the measuring system. Although systematic error could conceivably account for the observed excursions in dilatation, we maintain that the specific criticisms by Jackson and Cheng are incorrect: the excursions in dilatation cannot be attributed to the offset correction nor to proportional error associated with temperature. The absence of both errors is demonstrated by using data that are particularly sensitive to the two effects.

Journal of Geophysical Research B: Solid Earth↗

Applicability of La-Ce systematics to planetary samples

Ce isotopic compositions in several terrestrial and extraterrestrial materials were determined in order to investigate the applicability of using Ce as an isotopic tracer to geological processes. Owing to the low abundances of 138 La and 138 Ce in nature, our measurements of 138 Ce/ 140 Ce ratios of natural samples have relatively large (>0.02%) errors, and the variations in Ce-isotope ratios were barely resolved. A tenuous anticorrelation was observed between ε Ce and ε Nd for terrestrial basalts and granites, indicating that with some improvement in analytical techniques the Ce isotopic composition may prove useful as a tracer for geological processes. A very low ε Ce predicted from the Ce anomaly in the REE pattern of the Khohar L3 chondrite (Nakamura and Masuda, 1973) was not observed in this study, indicating that the Ce anomaly may be caused by terrestrial contamination or alteration. A low ε Ce estimated for the source of Nakhla is consistent with our previous estimate (Nakamura et al., 1982) of a LREE depleted source.

Journal of Geophysical Research Solid Earth↗

An approach to regional wetland digital elevation model development using a differential global positioning system and a custom-built helicopter-based surveying system

Accurate topographic data are critical to restoration science and planning for the Everglades region of South Florida, USA. They are needed to monitor and simulate water level, water depth and hydroperiod and are used in scientific research on hydrologic and biologic processes. Because large wetland environments and data acquisition challenge conventional ground-based and remotely sensed data collection methods, the United States Geological Survey (USGS) adapted a classical data collection instrument to global positioning system (GPS) and geographic information system (GIS) technologies. Data acquired with this instrument were processed using geostatistics to yield sub-water level elevation values with centimetre accuracy (±15 cm). The developed database framework, modelling philosophy and metadata protocol allow for continued, collaborative model revision and expansion, given additional elevation or other ancillary data.

Florida↗

Molecular and morphometric analyses reveal cryptic diversity within freshwater mussels (Bivalvia: Unionidae) of the western Gulf coastal drainages of the USA

Past geological processes and climate change affected current species distributions and the genetic structure of riverine fauna. Western Gulf of Mexico coastal rivers harbour four mussel species within the genus Fusconaia (Bivalvia: Unionida). The distributions of these species are unclear owing to their indistinguishable shell morphologies. Using molecular phylogenetic and Fourier morphometric analyses, we examined phylogenetic relationships and morphological variation among the species and made inferences about the role of past geological and climatic factors in shaping the current genetic structure and distributions of these species in the region. Our results showed the presence of three Fusconaia species within the region: Fusconaia askewi , Fusconaia chunii and Fusconaia flava . We confirmed that Fusconaia lananensis is a junior synonym of F. askewi and that F. chunii is genetically distinct from F. askewi . The Trinity River has syntopic F. flava whose morphologies are indistinguishable from those of F. chunii . Divergence-time estimates matched major geological and climatic events in the region, where climate-driven river formations during the mid-Miocene to Pleistocene caused major diversification of Fusconaia species. Knowledge gained from the present study provides a better understanding of vicariant events that shaped current species distributions and helps to identify conservation priorities that apply to the Fusconaia species.

Biological Journal of the Linnean Society↗

The NatCarb geoportal: Linking distributed data from the Carbon Sequestration Regional Partnerships

The Department of Energy (DOE) Carbon Sequestration Regional Partnerships are generating the data for a "carbon atlas" of key geospatial data (carbon sources, potential sinks, etc.) required for rapid implementation of carbon sequestration on a broad scale. The NATional CARBon Sequestration Database and Geographic Information System (NatCarb) provides Web-based, nation-wide data access. Distributed computing solutions link partnerships and other publicly accessible repositories of geological, geophysical, natural resource, infrastructure, and environmental data. Data are maintained and enhanced locally, but assembled and accessed through a single geoportal. NatCarb, as a first attempt at a national carbon cyberinfrastructure (NCCI), assembles the data required to address technical and policy challenges of carbon capture and storage. We present a path forward to design and implement a comprehensive and successful NCCI. ?? 2007 The Haworth Press, Inc. All rights reserved.

Journal of Map & Geography Libraries↗

Analysis of low levels of rare earths by radiochemical neutron activation analysis

A procedure for the radiochemical neutron-activation analysis for the rare earth elements (REE) involves the separation of the REE as a group by rapid ion-exchange methods and determination of yields by reactivation or by energy dispersive X-ray fluorescence (EDXRF) spectrometry. The U. S. Geological Survey (USGS) standard rocks, BCR-1 and AGV-1, were analyzed to determine the precision and accuracy of the method. We found that the precision was ??5-10% on the basis of replicate analysis and that, in general the accuracy was within ??5% of accepted values for most REE. Data for USGS standard rocks BIR-1 (Icelandic basalt) and DNC-1 (North Carolina diabase) are also presented. ?? 1985 Akade??miai Kiado??.

Journal of Radioanalytical and Nuclear Chemistry A↗

Tungsten skarn potential of the Yukon-Tanana Upland, eastern Alaska, USA—A mineral resource assessment

Tungsten (W) is used in a variety of industrial and technological applications and has been identified as a critical mineral for the United States, India, the European Union, and other countries. These countries rely on W imports mostly from China, which leaves them vulnerable to supply disruption. Consequently, the U.S. government has a current initiative to understand domestic resource potential. The eastern Alaska portion of the Yukon-Tanana Upland (YTU), is prospective for W skarn deposits, the major source of global W supply. The regional geology consists of juxtaposed Paleozoic lithotectonic packages that were reaccreted to North America in the Mesozoic . Multiple subsequent episodes of arc-related magmatism intruded the lithotectonic packages, accompanied by W skarn formation mostly associated with 100–90 Ma intrusions; major W skarn deposits in Canada are part of the same metallogenic event (e.g., Mactung, Cantung). In this paper, we present an assessment for undiscovered W skarn resources for parts of the lesser-explored western (Alaskan) portion of the YTU. We used GIS proximity analysis to map the intersection of pluton and carbonate-bearing rocks to define three permissive tracts for W skarn deposits. The permissive tracts were qualitatively assessed by mineral potential mapping using region-wide sediment geochemistry and mineral concentrate datasets. This analysis showed that much of the western YTU has high potential for undiscovered W skarn deposits, whereas the eastern and southern YTU had only isolated areas of medium to high potential. Historical production and the quality of the geochemistry data of the western YTU tract (ca. 9200 km 2 ) permitted a quantitative assessment of undiscovered W resources. Probabilistic estimates by a panel of 20 experts predicted a 70% chance of one to three undiscovered W skarn deposits in the western YTU tract. The rationale for favorability employed by the expert panel included favorable lithology, previous production, clustering of previously mined deposits, W placers in the area, lack of recent exploration, pan concentrates containing W minerals, and W geochemical anomalies. Estimates were combined with a global grade and tonnage model for W skarns in a Monte Carlo simulation and provided a median estimate of undiscovered resources of 94 kt WO 3 . If the undiscovered W skarn deposits are located close to infrastructure (e.g., near Fairbanks, or close to roads and/or power grid), application of an economic filter indicates that the median total economically recoverable WO 3 is 63 kt with a net present value (NPV) of $330 million USD (2008 dollars). Whereas if deposits are far from infrastructure, median recoverable WO 3 is only 30 kt and the NPV is $44 million. Our models for contained WO 3 resources and NPV estimates for the western YTU tract are considerably lower than the known resources in skarns in adjacent areas in Canada. Estimates for the western YTU are also lower than preliminary estimates for undiscovered W skarn deposits in areas of the western conterminous United States. We speculate that lower permeability and continuity of favorable carbonate rock horizons in the relatively higher-grade metamorphic country rocks in the Alaska portion of the YTU may explain some of the differences in prospectivity. More detailed geologic mapping, modern geochemistry, and geophysical surveys are needed to refine the resource potential of the whole YTU. Regardless, quantitative mineral resource assessment provides a useful tool for making first-order regional estimates of undiscovered resources, identifying target areas for new data acquisition, and guiding research on the fundamental controls of district-scale metallogenic endowments.

Alaska↗

Summary of the U.S. Geological Survey and U.S. Bureau of Land Management national coal-hydrology program, 1974-84

During the decade 1974-84, the U.S. Geological Survey and the U.S. Bureau of Land Management cooperated on investigations to collect information and to study hydrologic processes related to development and mining of federally owned coal. In addition, the U.S. Geological Survey conducted similar investigations related to nonfederally owned coal. As a result of these nationwide investigations, a large quantity of hydrologic information and data has been collected and compiled in more than 500 reports. This report summarizes the major findings and accomplishments that have resulted from data-collection activities, hydrologic studies, and research concerned with the effects of coal mining on water resources. This summary report includes: (1) A description of the Nation's coal and water-resource issues related to coal development, including history, objectives, and design of the coal-hydrology program; (2) a summary of the hydrologic information collected in the major coal provinces and published in more than 500 reports and journal articles; and (3) a summary and application of results obtained from topical studies undertaken throughout the program, including discussions on watershed modeling, salinity modeling, ground-water flow systems, geochemistry of mine spoils, mine drainage, sedimentation, and aquatic biology. A detailed coal-hydrology reference list concludes the report.

continental United States↗

Observations at the Mars Pathfinder site: Do they provide "unequivocal" evidence of catastrophic flooding?

After Mars Pathfinder landed at the mouth of Ares Valus, a large channel that drains into the Chryse Planitia basin, the mission reports unanimously supported the interpretation that the lander site is the locus of catastrophic flooding by noting that all aspects of the scene are consistent with this interpretation. However, alternatives cannot be ruled out by any site observations, as all aspects of the scene are equally consistent with other interpretations of origin, namely, ice and mass-flow processes subsequently modified by wind erosion. The authors discuss alternative explanations for the geologic history of the channel based on a regional view of the circum-Chryse channels from Viking images (our best broad-scale information to date) and the local view from the recent Pathfinder landing site. Mega-indicators of channel origin, the regional geomorphology, geology, and planetary climatic conditions, taken together suggest some combination of flood, mass flow, glacial, and eolian processes. The macro-indicators of channel origin (sedimentologic) are also not indicative of one process of emplacement, either as single criteria or taken cumulatively. Finally, the micro-indicators of channel origin (geochemical and mineralogic composition) do not provide very tight constraints on the deposits' possible origins other than that water was in some way involved.

Journal of Geophysical Research E: Planets↗