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Toxicity of inorganic contaminants, individually and in environmental mixtures, to three endangered fishes (Colorado squawfish, bonytail, and razorback sucker)

Two life stages of three federally-listed endangered fishes, Colorado squawfish ( Ptychocheilus lucius ), bonytail ( Gila elegans ), and razorback sucker ( Xyrauchen texanus ) were exposed to copper, selenate, selenite, and zinc individually, and to mixtures of nine inorganics in a reconstituted water that simulated the water quality of the middle Green River, Utah. The mixtures simulated environmental ratios of arsenate, boron, copper, molybdenum, selenate, selenite, uranium, vanadium, and zinc in two tributaries, Ashley Creek and Stewart Lake outlet, of the middle Green River. The rank order of toxicity of the individual inorganics, from most to least toxic, was: copper > zinc > selenite > selenate. Colorado squawfish larvae were more sensitive to all four inorganics and the two mixtures than the juveniles, whereas there was no consistent response between the two life stages for the other two species. There was no consistent difference in sensitivity to the inorganics among the three endangered fishes. Both mixtures exhibited either additive or greater than additive toxicity to these fishes. The primary toxic components in the mixtures, based on toxic units, were copper and zinc. Acute toxicity values were compared to measured environmental concentrations in the two tributaries to derive margins of uncertainty. Margins of uncertainty were low for both mixtures (9–22 for the Stewart Lake outlet mixture, and 12–32 for the Ashley Creek mixture), indicating that mixtures of inorganics derived from irrigation activities may pose a hazard to endangered fishes in the Green River.

Archives of Environmental Contamination and Toxico↗

Lead and strontium isotopes in rocks of the Absaroka volcanic field, Wyoming

The Absaroka volcanic field is comprised of predominant andesitic volcaniclastic rocks and less abundant potassium-rich mafic lavas (shoshonites and absarokites). Strontium and lead isotopic variations preclude a simple derivation from an isotopically uniform source: Sr 87 /Sr 86 , 0.7042 to 0.7090; Pb 206 /Pb 204 , 16.31 to 17.30; Pb 208 /Pb 204 , 36.82 to 37.64. We postulate that these rocks were derived from a lower crust or upper mantle which underwent a preferential loss of uranium relative to lead approximately 2800±200 m.y. ago. Variations in lead and strontium isotopic compositions are thought to reflect small inhomogeneities in U/Pb and Rb/Sr ratios in the source.

Wyoming↗

Tholeiitic basalt magmatism of Kilauea and Mauna Loa volcanoes of Hawaii

The primitive magmas of Kilauca and Mauna Loa are generated by partial melting of mantle peridotite at depths of −60 km or more. Results of high-pressure melting experiments indicate that the primitive melt must contain at least 20% MgO in order to have olivine as a liquidus mineral. The least fractionated lavas of both volcanoes have olivine (Fa 13 ) on the liquidus at 1 atmosphere, suggesting that the only substance lost from the primitive melt, during a rather rapid ascent to the surface, is olivine. This relation allows the primitive composition to be computed by adding olivine to the composition of an erupted lava until total MgO is at least 20 percent. Although roughly similar, historic lavas of the two volcanoes show a consistent difference in composition. The primitive melt of Mauna Loa contains 20% more dissolved orthopyroxene, a high-temperature melting phase in the mantle, and is deficient in elements such as potassium, uranium, and niobium, which presumably occur in minor low-melting phases. Mauna Loa appears to be the older volcano, deriving its magma at higher temperature and greater depth from a more depleted source rock.

Hawaii↗

Relative inactivity during the last 140,000 years of a portion of the La Paz fault, southern Baja California Sur, Mexico

Uranium-series dating of corals overlying the undeformed Punta Coyote gravels indicates that the underlying La Paz fault zone has been relatively inactive in this part of the Baja California peninsula during the last 140,000 years, and possibly for a significantly longer period. However, Holocene seismic activities along extensions of the fault zone north of Cabo San Lucas suggest potential seismic hazards for the city of La Paz (population 200,000), which lies about 6 km from the fault. ?? 1990 Springer-Verlag New York Inc.

Environmental Geology and Water Sciences↗

One-level prediction-A numerical method for estimating undiscovered metal endowment

One-level prediction has been developed as a numerical method for estimating undiscovered metal endowment within large areas. The method is based on a presumed relationship between a numerical measure of geologic favorability and the spatial distribution of metal endowment. Metal endowment within an unexplored area for which the favorability measure is greater than a favorability threshold level is estimated to be proportional to the area of that unexplored portion. The constant of proportionality is the ratio of the discovered endowment found within a suitably chosen control region, which has been explored, to the area of that explored region. In addition to the estimate of undiscovered endowment, a measure of the error of the estimate is also calculated. One-level prediction has been used to estimate the undiscovered uranium endowment in the San Juan basin, New Mexico, U.S.A. A subroutine to perform the necessary calculations is included. ?? 1992 Oxford University Press.

Nonrenewable Resources↗

INAA determination of major and trace elements in loess, paleosol and precipitation layers in a pleistocene Loess Section, China

Instrumental neutron activation analysis was used for the determination of 31 major and trace elements in 32 samples from the Xinji Loess Section, Shaanxi Province, China. Interferences, including those from uranium fission products, were evaluated and corrections applied where necessary. The 39.7-meter deep section comprises of Lishi Loess of the middle Pleistocene (Q2) and Malan Loess of the late Pleistocene (Q3). The section is characterized by the presence of 5 layers of paleosol, and each paleosol is underlain by a precipitation layer. When the elemental abundances are converted to a carbonate-free basis, there is little compositional difference among the carbonate-free fractions of loess, paleosol and precipitation layers. This indicates that dissolution of carbonate minerals by downward-moving surface water was an important process in paleosol formation while other minerals were not severely weathered and elemental fractionation was minimal. The parent materials of the paleosol and precipitation layers closely resemble the loess layers in their elemental abundances, which suggests that all layers in the section have a compositionally similar source. ?? 1987 Akade??miai Kiado??.

Journal of Radioanalytical and Nuclear Chemistry A↗

Summary of the mineral- and energy-resource endowment, BLM roswell resource area, east-central New Mexico

In this summary of two comprehensive resource reports produced by the U.S. Bureau of Mines and the U.S. Geological Survey for the U.S. Bureau of Land Management, we discuss the mineral- and energyresource endowment of the 14-millon-acre Roswell Resource Area, New Mexico, managed by the Bureau of Land Management. The Bureau and Survey reports result from separate studies that are compilations of published and unpublished data and integrate new findings on the geology, geochemistry, geophysics, mineral, industrial, and energy commodities, and resources for the seven-county area. The reports have been used by the Bureau of Land Management in preparation of the Roswell Resource Area Resource Management Plan, and will have future use in nationwide mineral- and energy-resource inventories and assessments, as reference and training documents, and as public-information tools. In the Roswell Resource Area, many metals, industrial mineral commodities, and energy resources are being, or have been, produced or prospected. These include metals and high-technology materials, such as copper, gold, silver, thorium, uranium and/or vanadium, rare-earth element minerals, iron, manganese, tungsten, lead, zinc, and molybdenum; industrial mineral resources, including barite, limestone/dolomite, caliche, clay, fluorspar, gypsum, scoria, aggregate, and sand and gravel; and fuels and associated resources, such as oil, gas, tar sand and heavy oil, coal, and gases associated with hydrocarbons. Other commodities that have yet to be identified in economic concentrations include potash, halite, polyhalite, anhydrite, sulfur, feldspar, building stone and decorative rock, brines, various gases associated with oil and gas exploration, and carbon dioxide. ?? 1993 Oxford University Press.

Nonrenewable Resources↗

Chemical characterization of gas- and oil-bearing shales by instrumental neutron activation analysis

The concentration of As, Ba, Ca, Co, Cr, Cs, Dy, Eu, Fe, Ga, Hf, K, La, Lu, Mn, Mo, Na, Ni, Rb, Sb, Sc, Se, Sm, Sr, Ta, Tb, Th, U, Yb, and Zn were determined by instrumental neutron activation analysis in block shale samples of the New Albany Group (Devonian-Mississippian) in the in the Illinois Basin. Uranium content of the samples was as high as 75 ppm and interfered in the determination of samarium, molybdenum, barium and cerium. In the determination of selenium a correction was made for interference from tantalum. U, As, Co, Mo, Ni and Sb as well as Cu, V and pyritic sulphur which were determined by other methods, were found to correlate positively with the organic carbon content of the samples. ?? 1982 Akade??miai Kiado??.

Journal of Radioanalytical Chemistry↗

Factors influencing the biogeochemistry of sedimentary carbon and phosphorus in the Sacramento-San Joaquin Delta

This study characterizes organic carbon (C organic ) and phosphorus (P) geochemistry in surface sediments of the Sacramento-San Joaquin Delta, California. Sediment cores were collected from five sites on a sample transect from the edge of the San Francisco Bay eastward to the freshwater Consumnes River. The top 8 cm of each core were analyzed (in 1-cm intervals) for C organic , four P fractions, and redox-sensitive trace metals (uranium and manganese). Sedimentary C organic concentrations and C organic : P ratios, decreased, while reactive P concentrations increased moving inland in the Delta. The fraction of total P represented by organic P increased inland, while that of authigenic P was higher bayward than inland reflecting increased diagenetic alteration of organic matter toward the bayward end of the transect. The redox indicator metals are consistent with decreasing sedimentary suboxia inland. The distribution of P fractions and C:P ratios, reflect the presence of relatively labile organic matter in upstream surface sediments. Sediment C and P geochemistry is influenced by site-specific particulate organic matter sources, the sorptive power of the sedimentary material present, physical forcing, and early diagenetic transformations presumably driven by C organic oxidation.

California↗

Insights into the metamorphic history and origin of flake graphite mineralization at the Graphite Creek graphite deposit, Seward Peninsula, Alaska, USA

Graphite Creek is an unusual flake graphite deposit located on the Seward Peninsula, Alaska, USA. We present field observations, uranium-lead (U–Pb) monazite and titanite geochronology, carbon (C) and sulfur (S) stable isotope geochemistry, and graphite Raman spectroscopy data from this deposit that support a new model of flake graphite ore genesis in high-grade metamorphic environments. The Graphite Creek deposit is within the second sillimanite metamorphic zone of the Kigluaik Mountains gneiss dome. Flake graphite, hosted in sillimanite-gneiss and quartz-biotite paragneiss, occurs as disseminations and in sets of very high grade (up to 50 wt.% graphite), semi-massive to massive graphite lenses 0.2 to 1 m wide containing quartz, sillimanite, inclusions of garnet porphyroblasts, K-feldspar, and tourmaline. Restitic garnet, sillimanite, graphite, and biotite accumulations indicate a high degree of anatexis and melt loss. Strong yttrium depletion in monazite, high europium ratios (Eu/Eu*), and excursions of high strontium and thorium concentrations are consistent with biotite dehydration melting. Monazite and titanite U–Pb ages record peak metamorphism from ~ 97 to 92 million years ago (Ma) and a retrograde event at ~ 85 Ma. Raman spectroscopy confirms the presence of carbonaceous material and highly ordered, crystalline graphite. Graphite δ 13 C VPDB values of − 30 to − 12‰ and pyrrhotite δ 34 S VCDT values of − 14 to 10‰ are consistent with derivation from organic carbon and sulfur in sedimentary rocks, respectively. These data collectively suggest that formation of massive graphite lenses occurred approximately synchronously with high-temperature metamorphism and anatexis of a highly carbonaceous pelitic protolith. Melt extraction and fluid release associated with anatexis were likely crucial for concentrating graphite. High-temperature, graphitic migmatite sequences within high-strain shear zones may be favorable for the occurrence of high-grade flake graphite deposits.

Alaska↗

Polyphase stratabound scheelite-ferberite mineralization at Mallnock, Eastern Alps, Austria

A peculiar type of stratabound tungsten mineralization in metacarbonate rocks was discovered and explored at Mallnock (Austria) during the late 1980s. It is the only tungsten occurrence in the Eastern Alps in which scheelite is associated with wolframite (96 mol% ferberite). The tungsten prospect is located in the Austroalpine Drauzug-Gurktal Nappe System recording polyphase low-grade regional metamorphism. Raman spectroscopy of carbonaceous material yield maximum metamorphic temperatures of 296 ± 27 °C and 258 ± 27 °C, which are assigned to Variscan and Eoalpine metamorphism, respectively. Scheelite and ferberite occur as polyphase stockwork-like mineralization in Fe-rich magnesite in the northern ore zone (Mallnock North), whereas in the western ore zone (Mallnock West), scheelite-quartz veinlets are exclusively hosted in dolomitic marbles. LA-ICP-MS analyses of scheelite and ferberite yield low contents of Mo, Nb, Ta, and rare earth elements, but high contents of Na and Sr. Uranium is particularly high in scheelite (up to 200 µg/g) and makes this mineral a suitable target for U–Pb dating. In situ U–Pb dating of scheelite yielded an early Permian age (294 ± 8 Ma) for Mallnock West and a Middle Triassic age (239 ± 3 Ma) for Mallnock North. A monzodioritic dike close to Mallnock yielded a U–Pb apatite date of 282 ± 9 Ma and supports the polyphase formation of this mineralization. The U–Pb scheelite ages indicate that a model for tungsten metallogeny in the Eastern Alps must also consider remobilization of tungsten by metamorphic fluids. In the Alps, the Permian to Triassic period (ca. 290–225 Ma) is characterized by an overall extensional geodynamic setting related to the breakup of Pangea. Lithospheric thinning caused higher heat flow, low-P metamorphism, and anatexis in the lower crust, which led to enhanced crustal fluid flow in the upper crust. These processes were not only responsible for the formation of metasomatic hydrothermal magnesite and siderite deposits in the Eastern Alps but also for this unique magnesite-ferberite-scheelite mineralization at Mallnock.

Mount Mallock↗

Chronic toxicity of un-ionized ammonia to early life-stages of endangered Colorado pikeminnow (Ptychocheilus lucius) and razorback sucker (Xyrauchen texanus) compared to the surrogate fathead minnow (Pimephales promelas)

Ammonia-contaminated groundwater enters the Upper Colorado River from beneath the abandoned Moab Uranium Mill Tailings Pile near Moab, Utah. This reach of the Upper Colorado River was designated as critical habitat for four endangered fish species because it is one of the few existing areas with known spawning and rearing habitats. Un-ionized ammonia (NH3) concentrations frequently exceed 1.00 mg/L in backwaters adjacent to the tailings pile, which exceeds the Utah 30-d average chronic water quality criterion for un-ionized ammonia (0.07 mg/L NH3; temperature 20??C; pH 8.2) by a factor of more than 10. However, there is little published information regarding the sensitivity of endangered fishes to ammonia. We conducted 28-d static renewal studies with post-swim-up larvae to determine the relative sensitivity of Colorado pikeminnow (Ptychocheilus lucius), razorback sucker (Xyrauchen texanus), and the standard surrogate fathead minnow (Pimephales promelas) to NH3. Chronic values (ChVs) for mortality and growth were determined as the geometric mean of the no observed effect concentration and the lowest observed effect concentration based on analysis of variance. The ChVs for growth of fathead minnow, Colorado pikeminnow, and razorback sucker were 0.43, 0.40, and 0.67 mg/L NH3, respectively. The ChVs for mortality of fathead minnow, Colorado pikeminnow, and razorback sucker were 0.43, 0.70, and 0.67 mg/L NH3, respectively. Therefore, the ChVs for mortality and growth were similar for fathead minnow and razorback sucker; however, the ChV for growth was lower than the ChV for mortality for Colorado pikeminnow. Maximum likelihood regression was used to calculate 28-d lethal concentrations (LCx) for each species. The 28-d LC50, LC20, and LC1 values for fathead minnow were 0.69, 0.42, and 0.13 mg/L NH3, respectively. The 28-d LC50, LC20, and LC1 values for Colorado pikeminnow were 0.76, 0.61, and 0.38 mg/L NH3, respectively. The 28-d LC50, LC20, and LC1 values for razorback sucker were 0.54, 0.38, and 0.25 mg/L NH3, respectively. The fathead minnow, Colorado pikeminnow, and razorback sucker are relatively similar in sensitivity and rank at the 35th, 49th, and 31st percentiles, respectively, of the theoretical chronic fish sensitivity distributions for NH3. The existing water quality criteria for NH3, if met by remediation activities at the Moab site, would be protective of these endangered fishes even if fish sensitivity is based on the conservative LC1 value. ?? 2005 Springer Science+Business Media, Inc.

Archives of Environmental Contamination and Toxico↗

Selected trace elements in the Sacramento River, California: Occurrence and distribution

The impact of trace elements from the Iron Mountain Superfund site on the Sacramento River and selected tributaries is examined. The concentration and distribution of many trace elements—including aluminum, arsenic, boron, barium, beryllium, bismuth, cadmium, cerium, cobalt, chromium, cesium, copper, dysprosium, erbium, europium, iron, gadolinium, holmium, potassium, lanthanum, lithium, lutetium, manganese, molybdenum, neodymium, nickel, lead, praseodymium, rubidium, rhenium, antimony, selenium, samarium, strontium, terbium, thallium, thulium, uranium, vanadium, tungsten, yttrium, ytterbium, zinc, and zirconium—were measured using a combination of inductively coupled plasma-mass spectrometry and inductively coupled plasma-atomic emission spectrometry. Samples were collected using ultraclean techniques at selected sites in tributaries and the Sacramento River from below Shasta Dam to Freeport, California, at six separate time periods from mid-1996 to mid-1997. Trace-element concentrations in dissolved (ultrafiltered [0.005-μm pore size]) and colloidal material, isolated at each site from large volume samples, are reported. For example, dissolved Zn ranged from 900 μg/L at Spring Creek (Iron Mountain acid mine drainage into Keswick Reservoir) to 0.65 μg/L at the Freeport site on the Sacramento River. Zn associated with colloidal material ranged from 4.3 μg/L (colloid-equivalent concentration) in Spring Creek to 21.8 μg/L at the Colusa site on the Sacramento River. Virtually all of the trace elements exist in Spring Creek in the dissolved form. On entering Keswick Reservoir, the metals are at least partially converted by precipitation or adsorption to the particulate phase. Despite this observation, few of the elements are removed by settling; instead the majority is transported, associated with colloids, downriver, at least to the Bend Bridge site, which is 67 km from Keswick Dam. Most trace elements are strongly associated with the colloid phase going downriver under both low- and high-flow conditions.

Archives of Environmental Contamination and Toxico↗

Geochemical and C, O, Sr, and U-series isotopic evidence for the meteoric origin of calcrete at Solitario Wash, Crater Flat, Nevada, USA

Calcite-rich soils (calcrete) in alluvium and colluvium at Solitario Wash, Crater Flat, Nevada, USA, contain pedogenic calcite and opaline silica similar to soils present elsewhere in the semi-arid southwestern United States. Nevertheless, a ground-water discharge origin for the Solitario Wash soil deposits was proposed in a series of publications proposing elevation-dependent variations of carbon and oxygen isotopes in calcrete samples. Discharge of ground water in the past would raise the possibility of future flooding in the unsaturated zone at Yucca Mountain, Nevada, site of a proposed high-level nuclear waste repository. New geochemical and carbon, oxygen, strontium, and uranium-series isotopic data disprove the presence of systematic elevation-isotopic composition relations, which are the main justification given for a proposed ground-water discharge origin of the calcrete deposits at Solitario Wash. Values of ??13C (-4.1 to -7.8 per mil [???]), ??18O (23.8-17.2???), 87Sr/ 86Sr (0.71270-0.71146), and initial 234U/238U activity ratios of about 1.6 in the new calcrete samples are within ranges previously observed in pedogenic carbonate deposits at Yucca Mountain and are incompatible with a ground-water origin for the calcrete. Variations in carbon and oxygen isotopes in Solitario Wash calcrete likely are caused by pedogenic deposition from meteoric water under varying Quaternary climatic conditions over hundreds of thousands of years. ?? Springer-Verlag 2005.

Environmental Geology↗

Discovery of a rare pillar coral (Dendrogyra cylindrus) death assemblage off southeast Florida reveals multi-century persistence during the late Holocene

In recent years, coral populations in the western Atlantic have undergone widespread declines from climate change, anthropogenic stressors, and infectious disease outbreaks. The pillar coral, Dendrogyra cylindrus , has been one of the most affected species, prompting its listing as threatened under the United States Endangered Species Act in 2014 and critically endangered under the IUCN Red List in 2022. However, due to its natural rarity, it is particularly difficult to study using conventional long-term monitoring studies or less common paleontological investigations. Here, we document for the first time, the multi-century persistence of D. cylindrus on high-latitude nearshore reefs off southeast Florida during the late Holocene. Using high-precision uranium–thorium (U-Th) dating, we constrain the ages of well-preserved subfossil D. cylindrus colonies recovered from newly described coral death assemblages. We also describe specific morphological characteristics and taphonomic indicators reflecting their unique depositional environment. Our findings demonstrate long-term persistence of D. cylindrus in southeast Florida, despite geographical isolation and historical rarity in the region.

Coral Reefs↗

Rapid runoff via shallow throughflow and deeper preferential flow in a boreal catchment underlain by frozen silt (Alaska, USA)

In high-latitude catchments where permafrost is present, runoff dynamics are complicated by seasonal active-layer thaw, which may cause a change in the dominant flowpaths as water increasingly contacts mineral soils of low hydraulic conductivity. A 2-year study, conducted in an upland catchment in Alaska (USA) underlain by frozen, well-sorted eolian silt, examined changes in infiltration and runoff with thaw. It was hypothesized that rapid runoff would be maintained by flow through shallow soils during the early summer and deeper preferential flow later in the summer. Seasonal changes in soil moisture, infiltration, and runoff magnitude, location, and chemistry suggest that transport is rapid, even when soils are thawed to their maximum extent. Between June and September, a shift occurred in the location of runoff, consistent with subsurface preferential flow in steep and wet areas. Uranium isotopes suggest that late summer runoff erodes permafrost, indicating that substantial rapid flow may occur along the frozen boundary. Together, throughflow and deep preferential flow may limit upland boreal catchment water and solute storage, and subsequently biogeochemical cycling on seasonal to annual timescales. Deep preferential flow may be important for stream incision, network drainage development, and the release of ancient carbon to ecosystems

Alaska↗

Geochemical characterization of groundwater evolution south of Grand Canyon, Arizona (USA)

Better characterization of the geochemical evolution of groundwater south of Grand Canyon, Arizona (USA), is needed to understand natural conditions and assess potential effects from breccia-pipe uranium mining in the region. Geochemical signatures of groundwater at 28 sampling locations were evaluated; baseline concentrations for select trace elements (As, B, Ba, Cr, Li, Mo, Rb, Se, Sr, Th, Tl, U, V) were established, and anomalous chemistry characteristics were identified. Concentrations at some groundwater sites exceeded the USEPA drinking water standard for As of 10 μg/L (Red Canyon, Miners, JT, Havasu, and Warm Springs) and U of 30 μg/L (Salt Creek Spring). Four springs from the study area (Blue, Havasu, Fern, and Warm Springs) had unique chemistry, which may indicate a deep flow path or potential contribution of fluids from lower in the crust. Other springs in the study area were distinguished by major anion water type: sulfate, bicarbonate, and a mixture of the two. Water type distinctions were somewhat spatially segregated, with sulfate type present on the western side of the study area, bicarbonate type on the eastern side, and a mixture of the two interspersed between the endmember sites. Sulfate-type water from this study area had low strontium isotopic ratio (87Sr/86Sr) values. The location of spring discharge within single drainages of the Grand Canyon may influence chemistry, as groundwater discharging from bedrock was altered after flowing through alluvial material. Geochemical analysis of groundwater in Grand Canyon indicates the importance of continued monitoring and better understanding of short-term chemical fluctuations.

Arizona↗

Indoor radon risk potential of Hawaii

A comprehensive evaluation of radon risk potential in the State of Hawaii indicates that the potential for Hawaii is low. Using a combination of factors including geology, soils, source-rock type, soil-gas radon concentrations, and indoor measurements throughout the state, a general model was developed that permits prediction for various regions in Hawaii. For the nearly 3,100 counties in the coterminous U.S., National Uranium Resource Evaluation (NURE) aerorad data was the primary input factor. However, NURE aerorad data was not collected in Hawaii, therefore, this study used geology and soil type as the primary and secondary components of potential prediction. Although the radon potential of some Hawaiian soils suggests moderate risk, most houses are built above ground level and the radon soil potential is effectively decoupled from the house. Only underground facilities or those with closed or recirculating ventilation systems might have elevated radon potential. ?? 2005 Akade??miai Kiado??.

Journal of Radioanalytical and Nuclear Chemistry↗