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Batholith and associated rocks of Corona, Elsinore, and San Luis Rey quadrangles southern California

The batholith of Southern and Lower California is exposed continuously from near Riverside, California, southward for a distance of about 350 miles. In central Lower California it is covered in part by younger rocks, but discontinuous bodies extend to the southern end of Lower California, and hence the batholith is probably over 1000 miles long. Its width is about 60 miles. A strip across the northern part of the batholith about 70 miles wide has been studied; the western half was mapped in detail, and the eastern half was covered in rapid reconnaissance. In the area studied the batholith intrudes Triassic sediments and Jurassic(?) volcanic rocks along its western border and Paleozoic sediments along its eastern border. Screens and roof pendants are common within the batholith. The Triassic rocks are mildly metamorphosed in the western part of the area but become progressively more coarsely crystalline toward the east. The Paleozoic rocks are rather coarsely crystalline. The metamorphism in large part preceded the intrusion of the batholith, and only locally was there appreciable contact metamorphism. The batholith and older rocks are overlain by Upper Cretaceous and younger sediments. Small bodies of andesite and basalt are associated with the Tertiary sediments, and small bodies of nepheline basalt of Quaternary age are present in the area. The batholith was intruded in early Upper Cretaceous time. The batholith in the area studied was emplaced by over 20 separate injections. Most of the resulting rock types are found in only one or a few small bodies which are confined to a small area. In the area studied in detail (Pl. 1) five types are present in many large, widely separated bodies, making up about 88 per cent of the area underlain by the batholith. In the eastern half of the batholith three more widespread types are present. In the western half of the body the rocks range fro a gabbro to granite, but in the eastern half several tonalites constitute nearly the whole of the mass. The gabbro is composed of many related rocks. Some have hornblende, some pyroxene; in some the plagioclase is anorthite, in others it is as sodic as andesine-Iabradorite. Some of the tonalites contain abundant inclusions that have been almost completely reworked by the magma and have been softened and stretched into thin discs. These inclusions are well oriented and near the contacts with older rocks they parallel the contacts, but elsewhere they strike about N. 30° W. and dip steeply to the east. One tonalite, whose feldspar is andesine, has scattered crystals with cores of bytownite, and has well-crystallized hornblende with cores of pale uralitic hornblende and remnants of augite. Hornblende and biotite are the predominant mafic minerals of the tonalites and granodiorites. The iron content of the mafic minerals of the gabbros is moderate, and it increases as the rocks become richer in silica. The norms and the modes are shown on a variation diagram (Figs. 11, 12). The chemical analyses of the rocks fall near smooth variation curves (Fig. 4). The general strike of the structures of the area have been about N. 30° W. from Paleozoic to the present time. The Paleozoic and Triassic sediments, the orientation of the inclusions and other structures of the batholith, the elongation of the batholith and the mountain ranges, and the strike of the major faults are in about the same direction. In the batholith and the older sediments the dips are steep to the east. The batholith must have been emplaced by stoping and not by forceful injection. Calculations show that the cooling of a large batholith is chiefly through the roof and not through the walls. Crystallization to a depth of 3 kilometers takes place in about half a million years. The different rocks of the batholith were formed from the intermediate gabbro by crystal differentiation and assimilation in depth. In early Upper Cretaceous time diastrophism folded the older rocks and formed, in depth, a strip of gabbroic magma about 1000 miles long. A small amount of this magma was intruded nearly to the surface. The deep magma differentiated quietly until its upper part attained the composition of a tonalite. Earth movements then occurred at least five times in rapid succession and caused the injection of the different tonalites. Some of these carry abundant inclusions, indicating a widespread shattering of the wall rock shortly before final emplacement. From time to time local movements caused the injections of the different granodiorites. When the deep-seated magma reached the composition of a light-colored granodiorite, widespread diastrophism moved the main granodiorite upward. Further local movement caused the emplacement of the many local granodiorites and granites.

California↗

Time, space, and composition relations among northern Nevada intrusive rocks and their metallogenic implications

Northern Nevada contains ∼360 igneous intrusions subequally distributed among three age groups: middle Tertiary, Cretaceous, and Jurassic. These intrusions are dominantly granodiorite and monzogranite, although some are more mafic. Major-oxide and trace-element compositions of intrusion age groups are remarkably similar, forming compositional arrays that are continuous, overlapping, and essentially indistinguishable. Within each age group, compositional diversity is controlled by a combination of fractional crystallization and two-component mixing. Mafic intrusions represent mixing of mantle-derived magma and assimilated continental crust, whereas intermediate to felsic intrusions evolved by fractional crystallization. Several petrologic parameters suggest that the northern Nevada intrusion age groups formed in a variety of subduction-related, magmatic arc settings: Jurassic intrusions were likely formed during backarc, slab-window magmatism related to breakoff of the Mezcalera plate; Cretaceous magmatism was related to rapid, shallow subduction of the Farallon plate and consequent inboard migration of arc magmatism; and Tertiary magmatism initially swept southward into northern Nevada in response to foundering of the Farallon plate and was followed by voluminous Miocene bimodal magmatism associated with backarc continental rifting. Nearly 3000 hydrothermal mineral deposits (many only small uneconomic occurrences), of diverse size and type, are spatially and (or) genetically associated with northern Nevada intrusions; significantly, the largest and most important deposits are aligned along prominent mineral-deposit trends. Because northern Nevada is a globally significant metallogenic province, determining whether age, modal composition, and geochemical features of associated intrusive rocks discriminate productive intrusions is important. Mineral-deposit types, including W vein and skarn, polymetallic vein, distal disseminated Au-Ag, porphyry Cu-Mo-W-Au, and epithermal Ag-Au deposits, all spatially and genetically associated with intrusions and known to involve magmatic inputs, are emphasized in this analysis. In addition, although evidence for a direct magmatic input, other than heat, is scarce for Carlin-type gold deposit formation, this deposit type was included because of its economic significance. Consequently, intrusions along mineral-deposit trends, in particular those associated with the largest and economically most significant mineral deposits, were a focus of the investigation. Importantly, modal composition, age, and geochemical characteristics of intrusions associated with large mineral deposits along the trends, are indistinguishable from non-mineralized intrusions in northern Nevada and thus do not identify intrusions associated with significant deposits. Moreover, intrusion age and composition show little correlation with mineral-deposit type, abundance, and size. Given the lack of diagnostic characteristics for intrusions associated with deposits, it is uncertain whether age, modal composition, and geochemical data can identify intrusions associated with mineral deposits. These findings suggest that associations between northern Nevada intrusions and mineral deposits reflect superimposition of many geologic factors, none of which was solely responsible for mineral-deposit formation. These factors might include intrusion size, efficiency of fluid and metal extraction from magma, prevailing redox and sulfidation conditions, or derivation of metals and ligands from host rocks and groundwater. The abundance and diversity of mineral deposits in northern Nevada may partly reflect geochemical inheritance, for example, along the mineral trends rather than the influence of petrologically unique magma or associated fluids.

Nevada↗

Titanium

Titanium is a mineral commodity that is essential to the smooth functioning of modern industrial economies. Most of the titanium produced is refined into titanium dioxide, which has a high refractive index and is thus able to impart a durable white color to paint, paper, plastic, rubber, and wallboard. Because of their high strength-to-weight ratio and corrosion resistance, titanium metal and titanium metal alloys are used in the aerospace industry as well as for welding rod coatings, biological implants, and consumer goods. Ilmenite and rutile are currently the principal titanium-bearing ore minerals, although other minerals, including anatase, perovskite, and titanomagnetite, could have economic importance in the future. Ilmenite is currently being mined from two large magmatic deposits hosted in rocks of Proterozoic-age anorthosite plutonic suites. Most rutile and nearly one-half of the ilmenite produced are from heavy-mineral alluvial, fluvial, and eolian deposits. Titanium-bearing minerals occur in diverse geologic settings, but many of the known deposits are currently subeconomic for titanium because of complications related to the mineralogy or because of the presence of trace contaminants that can compromise the pigment production process. Global production of titanium minerals is currently dominated by Australia, Canada, Norway, and South Africa; additional amounts are produced in Brazil, India, Madagascar, Mozambique, Sierra Leone, and Sri Lanka. The United States accounts for about 4 percent of the total world production of titanium minerals and is heavily dependent on imports of titanium mineral concentrates to meet its domestic needs. Titanium occurs only in silicate or oxide minerals and never in sulfide minerals. Environmental considerations for titanium mining are related to waste rock disposal and the impact of trace constituents on water quality. Because titanium is generally inert in the environment, human health risks from titanium and titanium mining are minimal; however, the processes required to extract titanium from titanium feedstock can produce industrial waste.

Professional Paper↗

Mineral potential for sediment-hosted copper deposits in the Islamic Republic of Mauritania (phase V, deliverable 75)

The presence of Neoproterozoic through Cambrian, continental, siliciclastic sedimentary rocks interbedded with dolomitic carbonates, shales, and glacial tillites similar to the Katanga Supergroup host rocks of the Central African Copperbelt and other sediment-hosted copper-bearing Proterozoic sequences worldwide, is first order criteria for consideration of the Neoproterozoic units of the Taoudeni Basin in Mauritania as prospective for sediment-hosted copper deposits. Review of the National Mineral Occurrences Database (Marsh and Anderson, 2015) and previous literature suggest that only a handful of small sediment-hosted copper occurrences have been found to date in Mauritania and that the resource potential for this deposit type is low. In the northern Taoudeni Basin, the most important occurrence is at Taradent. This occurrence consists of three mineralized horizons in the lower Neoproterozoic Char Group in three outcrop areas separated by alluvium over a strike length of 12 kilometers (km). The most extensively mineralized horizon consists of malachite and disseminated copper sulfides, and is concentrated at the base of a dolomitic interval, consistent with a reduced faciestype sediment-hosted copper deposit model. Additional and poorly described copper occurrences in the Taoudeni Basin margin sedimentary rocks in northeastern Mauritania, such as Chegga Guettatira and Sidi Bara, may be sediment-hosted copper occurrences and extend the potential throughout this portion of the Basin. Additional potential for sediment-hosted copper deposits is indicated in reports by the British Geological Survey (BGS; Gunn and others, 2004) and BRGM (Salpeteur, 2005) in the Neoproterozoic-Cambrian sedimentary rocks (Teniagouri Group) of the central and southern Taoudeni Basin at a number of occurrences in the vicinity of Fouges, Weringuel, and Gig Zig. These occurrences exhibit characteristics consistent with a reduced-facies-type sediment-hosted copper deposit model and based on correlation of similar host rocks extend the potential throughout the entire Taoudeni Basin margin. Very poorly described copper occurrences in the northeastern and southeastern part of the Basin at Kreb en Naga, Kreb en Naga SW, Berbere, Dhar Nema, Dhar Nema 2, Saile, and Nejam-Medroume all are described as occurring in sedimentary rocks and are hosted by or are in close proximity to voluminous outcrops of Jurassic microgabbros (also referred to as dolerite or diabase). Uncertainty exists as to whether they are sediment-hosted copper occurrences. They are likely more closely analogous to copper occurrences associated with mafic igneous activity. The determination of whether reported copper occurrences and associated sedimentary rocks at Kreb en Naga and Kreb en Naga SW in the northeastern Taoudeni Basin and the Dhar Nema occurrences in the southeastern Taoudeni are permissive of sediment-hosted copper mineralization was inconclusive due to the absence of copper showings. While sedimentary host rocks at these locations must be broadly considered permissive, the absence of other favorable geologic features in these areas indicates that the potential for mineral deposits of this type is low. The widespread presence of mafic sills and dikes of Jurassic age throughout these areas and descriptions of associated minor copper mineralization suggests that many of the copper occurrences in these areas are not of the sediment-hosted copper type. Highly speculative potential exists in the Coastal Basin for Revett-type copper deposits in unexposed Jurassic-Cretaceous sandstones that may contain structural traps with gas accumulations. Eocene continental red bed sandstones of the Gorgol Formation, where overlain by the shallow marine sedimentary rocks of the Rinndiao Formation, represent an additional low potential rock sequence within the southeastern portion of the Coastal Basin that is permissive of sediment-hosted copper deposits. Field examinations of outcrop areas in the vicinity of many of the known occurrences were performed in late 2007 to provide additional criteria for evaluating the potential for this type of mineralization in Mauritania. In general, the geographic coordinates of occurrences are imprecise and many of the occurrences could not be located. Examination of outcrops of the Char Group in the Taradent area confirms the permissive nature of these rocks for reduced-facies-type sediment-hosted copper deposits. Inspection of weak copper mineralization hosted by black shales at several occurrences in the Gadel-Maylime area confirms that these occurrences are also of the reduced-faciestype and that the black and green shales of the Bouly and Ould Yenje Formations are permissive. Reported copper analyses up to 0.75 percent copper at Taradent and a single analysis of mineralized shale in the Gadel-Maylime area containing 0.55 percent copper indicate that low grade ore material exists at these locations. However indications that such copper grades are continuous over significant intervals and present in large tonnages are lacking. Although mineral occurrence data and descriptive geological information are adequate to delineate areas favorable for sediment-hosted copper deposits, this review indicates that potential for this type of deposit in Mauritania is low.

Open-File Report↗

Correlation of clayey gouge in a surface exposure of the San Andreas fault with gouge at depth from SAFOD: Implications for the role of serpentinite in fault mechanics

Magnesium-rich clayey gouge similar to that comprising the two actively creeping strands of the San Andreas Fault in drill core from the San Andreas Fault Observatory at Depth (SAFOD) has been identified in a nearby outcrop of serpentinite within the fault zone at Nelson Creek. Each occurrence of the gouge consists of porphyroclasts of serpentinite and sedimentary rocks dispersed in a fine-grained, foliated matrix of Mg-rich smectitic clays. The clay minerals in all three gouges are interpreted to be the product of fluid-assisted, shear-enhanced reactions between quartzofeldspathic wall rocks and serpentinite that was tectonically entrained in the fault from a source in the Coast Range Ophiolite. We infer that the gouge at Nelson Creek connects to one or both of the gouge zones in the SAFOD core, and that similar gouge may occur at depths in between. The special significance of the outcrop is that it preserves the early stages of mineral reactions that are greatly advanced at depth, and it confirms the involvement of serpentinite and the Mg-rich phyllosilicate minerals that replace it in promoting creep along the central San Andreas Fault.

California↗

Sedimentary facies of iron-formation

The sedimentary iron -formations of Precambrian age in the Lake Superior region can be divided on the basis of the dominant original iron mineral into four principal facies : sulfide, carbonate, oxide, and silicate. As chemical sediments, these rocks reflect certain aspects of the chemistry of the depositional environments. The major control, at least for the sulfide, carbonate, and oxide types, probably was the oxidation potential. The evidence indicates that deposition took place in restricted basins, which were separated from the open sea by thresholds that inhibited free circulation and permitted development of abnormalities in oxidation potential and water composition. The sporadic distribution of metamorphism and of later oxidation permits description of the primary facies on the basis of unoxidized, essentially unmetamorphosed material. The sulfide facies is represented by black slates in which pyrite may make up as much as 40 percent of the rock. The free-carbon content of these rocks typically ranges from 5 to 15 percent, indicating that ultra-stagnant conditions prevailed during deposition. Locally, the pyritic rocks contain layers of iron -rich carbonate. The carbonate facies consists, in its purer form, of interbedded iron -rich carbonate and chert. It is a product of an environment in which oxygen concentration was sufficiently high to destroy most of the organic material but not high enough to permit formation of ferric compounds. The oxide facies is found as two principal types, one characterized by magnetite and the other by hematite. Both minerals appear to be of primary origin. The magnetite-banded rock is one of the dominant lithologies in the region; it consists typically of magnetite interlayered with chert, carbonate, or iron silicate, or combinations of the three. Its mineralogy and association suggest origin under weakly oxidizing to moderately reducing conditions, but the mode of precipitation of magnetite is not clearly understood. The hematite-banded rocks consist of finely crystalline hematite interlayered with chert or jasper. Oolitic structure is common. This facies doubtless accumulated in a strongly oxidizing, probably near-shore, environment similar to that in which younger hema-titic ironstones such as the Clinton oolite were deposited. The silicate facies contains one or more of the hydrous ferrous silicates (greenalite, minnesotaite, stilpnomelane, chlorite) as a major constituent. Granule structure, similar to that of glauconite, is typical of some varieties; others are nongranular and finely laminated. The most common association of the silicate rocks is with either carbonate- or magnetite-bearing rocks, which suggests that the optimum conditions for deposition ranged from slightly oxidizing to slightly reducing. The relationship between the iron -rich rocks and volcanism, stressed by many authors, is considered by the writer to be structural, not chemical: in the Lake Superior region both iron -deposition and volcanism are believed to be related to geosynclinal development during Huronian time. In Michigan, the lower Huronian rocks are iron -poor quartzite and dolomite-typical "stable-shelf" deposits; much of the upper Huronian consists of iron -poor graywacke and slate with associated volcanic rocks -a typical "geosynclinal" assemblage. Thus the iron -rich beds of the middle Huronian and lower part of the upper Huronian were deposited during a transitional stage in structural history. The major environmental requirement for deposition of iron - formation is the closed or restricted basin; this requirement coincides in time with what would be a normal stage in evolution of the geosyncline: namely, structural development of offshore buckles or swells that subsequently develop into island arcs characterized by volcanism.

Lake Superior↗

Isotopic analysis of radium geochemistry at discrete intervals in the Midwestern Cambrian-Ordovician aquifer system

Radium (Ra) is a geogenic radioactive contaminant that frequently occurs at elevated levels in the Midwestern Cambrian-Ordovician aquifer system (MCOAS). Geochemical indicators (e.g., redox conditions or total dissolved solids) can broadly characterize conditions associated with elevated Ra levels in groundwater, but do not consistently correlate to elevated Ra within specific stratigraphic horizons. A coupled geochemical and isotopic study of groundwater and aquifer solids for major and trace elements, Ra, and uranium (U) at discrete intervals in the MCOAS was used to elucidate processes that may be responsible for this disconnect, via analysis of groundwater as well as extracted and digested solid aquifer samples. We find that the potential for Ra mobilization varies by stratigraphic unit, as observed by whole-rock 226 Ra/ 238 U (dis)equilibrium. Overall, the examined aqueous geochemical characteristics (e.g., redox conditions, total dissolved solids) do not explain Ra concentrations within the system, suggesting that alternative factors, like solid-phase associations or the extent of alpha recoil damage, may be more important. A relation between aqueous 87 Sr/ 86 Sr and 226 Ra suggests that minerals with radiogenic 87 Sr/ 86 Sr are more likely to release 226 Ra to the aqueous system. Overall, the release of U and Ra due to water-rock interaction varies with discrete stratigraphy, depending on aqueous geochemistry and available mineral associations. Due to complex Ra-rock interactions and the heterogeneous geology of the MCOAS, aqueous geochemistry does not fully predict the mobilization and concentration of Ra in groundwater. As sources and sinks of Ra within the MCOAS vary across stratigraphy, knowledge of aqueous geochemistry, available solid-phase associations, and nuclide leachability all are important to consider for understanding elevated Ra occurrence in aquifer systems.

Wisconsin↗

U-Pb, Re-Os, and Ar/Ar geochronology of rare earth element (REE)-rich breccia pipes and associated host rocks from the Mesoproterozoic Pea Ridge Fe-REE-Au deposit, St. Francois Mountains, Missouri

Rare earth element (REE)-rich breccia pipes (600,000 t @ 12% rare earth oxides) are preserved along the margins of the 136-million metric ton (Mt) Pea Ridge magnetite-apatite deposit, within Mesoproterozoic (~1.47 Ga) volcanic-plutonic rocks of the St. Francois Mountains terrane in southeastern Missouri, United States. The breccia pipes cut the rhyolite-hosted magnetite deposit and contain clasts of nearly all local bedrock and mineralized lithologies. Grains of monazite and xenotime were extracted from breccia pipe samples for SHRIMP U-Pb geochronology; both minerals were also dated in one polished thin section. Monazite forms two morphologies: (1) matrix granular grains composed of numerous small (<50 μ m) crystallites intergrown with rare xenotime, thorite, apatite, and magnetite; and (2) coarse euhedral, glassy, bright-yellow grains similar to typical igneous or metamorphic monazite. Trace element abundances (including REE patterns) were determined on selected grains of monazite (both morphologies) and xenotime. Zircon grains from two samples of host rhyolite and two late felsic dikes collected underground at Pea Ridge were also dated. Additional geochronology done on breccia pipe minerals includes Re-Os on fine-grained molybdenite and 40 Ar/ 39 Ar on muscovite, biotite, and K-feldspar. Ages (±2 σ errors) obtained by SHRIMP U-Pb analysis are as follows: (1) zircon from the two host rhyolite samples have ages of 1473.6 ± 8.0 and 1472.7 ± 5.6 Ma; most zircon in late felsic dikes is interpreted as xenocrystic (age range ca. 1522–1455 Ma); a population of rare spongy zircon is likely of igneous origin and yields an age of 1441 ± 9 Ma; (2) pale-yellow granular monazite—1464.9 ± 3.3 Ma (no dated xenotime); (3) reddish matrix granular monazite—1462.0 ± 3.5 Ma and associated xenotime—1453 ± 11 Ma; (4) coarse glassy-yellow monazite—1464.8 ± 2.1, 1461.7 ± 3.7 Ma, with rims at 1447.2 ± 4.7 Ma; and (5) matrix monazite (in situ)—1464.1 ± 3.6 and 1454.6 ± 9.6 Ma, and matrix xenotime (in situ)—1468.0 ± 8.0 Ma. Two slightly older ages of cores are about 1478 Ma. The young age of rims on the coarse glassy monazite coincides with an Re-Os age of 1440.6 ± 9.2 Ma determined in this study for molybdenite intergrown with quartz and allanite, and with the age of monazite inclusions in apatite from the magnetite ore ( Neymark et al., 2016 ). A 40 Ar/ 39 Ar age of 1473 ± 1 Ma was obtained for muscovite from a breccia pipe sample. Geochronology and trace element geochemical data suggest that the granular matrix monazite and xenotime (in polygonal texture), and cores of coarse glassy monazite precipitated from hydrothermal fluids during breccia pipes formation at about 1465 Ma. The second episode of mineral growth at ca. 1443 Ma may be related to faulting and fluid flow that rebrecciated the pipes. The ca. 10-m.y. gap between the ages of host volcanic rocks and breccia pipe monazite and xenotime suggests that breccia pipe mineral formation cannot be related to the felsic magmatism represented by the rhyolitic volcanic rocks, and hence is linked to a different magmatic-hydrothermal system.

Missouri↗

Bokan Mountain peralkaline granitic complex, Alexander terrane (southeastern Alaska): evidence for Early Jurassic rifting prior to accretion with North America

The circular Bokan Mountain complex (BMC) on southern Prince of Wales Island, southernmost Alaska, is a Jurassic peralkaline granitic intrusion about 3 km in diameter that crosscuts igneous and metasedimentary rocks of the Alexander terrane. The BMC hosts significant rare metal (rare earth elements, Y, U, Th, Zr, and Nb) mineralization related to the last stage of BMC emplacement. U–Pb (zircon) and 40 Ar/ 39 Ar (amphibole and whole-rock) geochronology indicates the following sequence of intrusive activity: ( i ) a Paleozoic basement composed mainly of 469 ± 4 Ma granitic rocks; ( ii ) intrusion of the BMC at 177 ± 1 Ma followed by rapid cooling through ca. 550 °C at 176 ± 1 Ma that was synchronous with mineralization associated with vertical, WNW-trending pegmatites, felsic dikes, and aegirine–fluorite veins and late-stage, sinistral shear deformation; and ( iii ) intrusion of crosscutting lamprophyre dikes at >150 Ma and again at ca. 105 Ma. The peralkaline nature of the BMC and the WNW trend of associated dikes suggest intrusion during NE–SW rifting that was followed by NE–SW shortening during the waning stages of BMC emplacement. The 177 Ma BMC was synchronous with other magmatic centres in the Alexander terrane, such as (1) the Dora Bay peralkaline stock and (2) the bimodal Moffatt volcanic suite located ∼30 km north and ∼100 km SE of the BMC, respectively. This regional magmatism is interpreted to represent a regional extensional event that precedes deposition of the Late Jurassic – Cretaceous Gravina sequence that oversteps the Wrangellia and Alexander exotic accreted terranes and the Taku and Yukon–Tanana pericratonic terranes of the Canadian–Alaskan Cordillera.

Alaska↗

Prehnite- and pumpellyite-bearing mineral assemblages, west side of the Appalachian metamorphic belt, Pennsylvania to Newfoundland

Prehnite- and/or pumpellyite-bearing meta-igneous rocks are found on the west side of the Appalachian metamorphic belt (1) near Jonestown, south-eastern Pennsylvania; (2) on Rensselaer Plateau, eastern New York; (3) near Quebec City, Quebec; and (4) at Little Port, Humber Arm, western Newfoundland. The assemblages critical to determining the conditions of metamorphism are (1) chlorite-epidote-hematite-pumpellyite-prehnite; actinolite-chlorite-hematite-pumpellyite-stilpnomelane; (2) actinolite-chlorite-epidote-stilpnomelane; chlorite-epidote-pumpellyite-stilpnomelane; chlorite-epidote-hematite-pumpellyite; (3) chlorite-epidote-hematite-pumpellyite-stilpnomelane; chlorite-epidote-pumpellyite-prehnite; and (4) chlorite-epidote-prehnite; chlorite-prehnite-stilpnomelane; chlorite-epidote-pumpellyite-prehnite. One pumpellyite-bearing rock from western Newfoundland shows a later vein of analcime-calcite. All the assemblages also include quartz, sphene, calcite, K-mica, and albite. Analysis of the mineral assemblages by the Schreinemakers method for the phases actinolite-chlorite-epidote-hematite-prehnite-pumpellyite-stilpnomelane shows that the different localities can be assigned different metamorphic grades. Though the detailed results of the Schreinemakers analysis depend on the assumed source of ferric iron in epidote, the major conclusions are not affected. The thermodynamic role of calcite is more problematic, but it appears that CO 2 did not behave as a boundary-value component during metamorphism. If calcite is treated as an excess phase, the Schreinemakers bundle decomposes to a net in a multisystem. Plotted on such a net, the various localities again occupy different parts signifying different metamorphic grades. The occurrence of pumpellyite-bearing assemblages on the west flank of the northern Appalachian metamorphic belt might suggest that these assemblages, contrary to the ideas of Miyashiro and of others, do not indicate high-pressure and low-temperature type of metamorphism. These assemblages, however, are compatible with an alternative interpretation as remnants of a high-pressure, low-temperature Taconic metamorphic regime, whose imprint within most of the Appalachian metamorphic belt has been obliterated by later events. Such a reconstruction is compatible with the suggestion that this zone, lying near the margin of the early Paleozoic craton, was an active subduction zone during the Taconic orogeny.

Appalachian metamorphic belt↗

Antimony ore in the Fairbanks district, Alaska

Antimony-bearing ores in the Fairbanks district, Alaska, are found principally in two areas, the extremities of which are at points 10 miles west and 23 miles northeast of Fairbanks; and one of two minor areas lies along this same trend 30 miles farther to the northeast. These areas are probably only local manifestations of mineralization that affected a much broader area and formed antimony-bearing deposits in neighboring districts, the closest of which is 50 miles away. The ores were exposed largely as a result of lode gold mining, but at two periods in the past, high prices for antimony ore warranted an independent production and about 2500 tons of stibnite ore was shipped. The sulfide deposits occupy the same fractures along which a gold-quartz mineralization of greater economic importance occurred; and both are probably genetically related to igneous rocks which intrude the schistose country rock. The sulfide is in part contemporaneous with some late-stage quartz in which it occurs as disseminated crystals; and in part the latest filling in the mineralized zones where it forms kidney-shaped masses of essentially solid sulfide. One extremely long mass must have contained nearly 100 tons of ore, but the average of the larger kidneys is closer to several tons. Much of the ore is stibnite, with quartz as a minor impurity, and assays show the tenor to vary from 40 to 65 percent antimony. Sulphantimonites are less abundant but likewise occur as disseminated crystals and as kidney-shaped bodies. Antimony oxides appear on the weathered surface and along fractures within the sulfide ore. Deposits containing either stibnite or sulphantimonite are known at more than 50 localities, but only eighteen have produced ore and the bulk of this came from the mines. The geology of the deposit, and the nature, extent, and period of the workings are covered in the detailed descriptions of individual occurrences. Several geologic and economic factors, which greatly affect prospecting and mining for stibnite ore in the area, are outlined. The principal available ore and reserves are considered to be ores earlier mined but never shipped, ore minable from near-surface deposits, and ores recoverable as a by-product of future gold mining. The outlook for stibnite production in the district is very uncertain. Apparently the greater portion of stibnite ore has already been recovered and present operations will strip the two principal areas of the district. This conclusion is based on the scanty discoveries since the last war and the fact that the areas are so pock-marked with prospects that there is little likelihood that any other large near-surface bodies remain to be discovered. Future prospecting would essentially be limited to attempts to seek the continuation of lodes previously having high yields of stibnite.

Open-File Report↗

Magnesite and brucite in the United States, exclusive of Alaska and Hawaii

The important deposits of magnesite (MgCO 3 ) and brucite (MgO.H 2 O) in the United States (exclusive of Alaska and Hawaii) are shown on the accompanying map. Single deposits and groups of deposits are shown by geometric symbols according to four size categories based on estimated production plus reserves. These categories are: less than 10,000 tons, 10,000 to 100,000 tons, 100,000 to 1,000,000 tons, and more than 1,000,000 tons. Occurrences of mineralogic interest only are not shown. All map locations are numbered consecutively in each State and keyed to the locality index. The geographical coordinates in the locality index represent the centers of the geometric symbols. Thus, the same coordinates are assigned to all deposits covered by a group symbol. The map was compiled from published reports and data in the files of the United States Geological Survey. The names, geographic coordinates, and geologic types of deposits are given in the locality index. The principal published reports used in compiling the map are listed in the selected references. The main types of commercial deposits of magnesite in the United States are: (1) replacement bodies in limestone and dolomite; (2) replacements and veins in serpentine; and (3) sedimentary beds. Other magnesite deposits of varied origin and less common occurrence include beds associated with talc, chlorite, and mica schists; and veins and lenses in altered tuffs. Brucite is a relatively rare mineral of secondary origin which usually accompanies other magnesian minerals, particularly magnesite and hydromagnesite, and is associated with carbonate rocks and serpentine. Magnesite was first mined in California in 1886, and the State was the only domestic producer until the development of the Washington deposits began in 1916. In recent years, the main production of magnesite has been from Stevens County, Washington, and Nye County, Nevada. Production in California has been intermittent since 1945. Magnesite deposits in Texas were mined during and immediately after World War II. At present (1961) the only brucite deposits being worked are those at Gabbs, Nye County, Nevada. They have been mined almost continuously since 1935.

Mineral Investigations Resource Map↗

Element partitioning in magnetite under low-grade metamorphic conditions – A case study from the Proterozoic Belt Supergroup, USA

The distribution and partitioning of elements in igneous rocks is well established for various melt –(fluid) –solid pairs and provides important insights into the petrogenesis of these rocks. Studies of the partitioning behavior of elements under metamorphic conditions are scarce and commonly focus on high-grade metamorphic facies. Little is known about the partitioning behavior of elements under low-grade metamorphic conditions. Greenschist-facies metasedimentary rocks of the North American Belt Supergroup host magnetite that displays equilibrium features with co-existing mineral phases such as quartz and carbonate. Magnetite is an ideal target for geochemical investigations because it can incorporate a large number of cations and is sensitive to changes in temperature, oxygen fugacity, pressure, whole-rock composition, and cooling trends. Whole-rock major and trace element analyses have been undertaken on representative samples from Belt Supergroup metasedimentary rocks using X-ray luorescence. Electron microprobe and laser ablation ICP-MS were used to obtain major and trace element concentrations for magnetite hosted in these rocks. Stable-isotope geothermometry of magnetite–quartz and magnetite–carbonate pairs constrain metamorphic temperatures to ca. 390°C. Partition coefficients (D) for magnetite–matrix pairs presumably reflect equilibrium at these low-grade metamorphic conditions. Except for Mn and Ni, which show comparable partition coefficients, the calculated values are one to two orders of magnitude lower than those for igneous magnetite. Aluminum displays the lowest calculated partition coefficient with a value of 0.006 and Ni and Fe the highest values with 6.3 and 20.9, respectively. Of the elements that commonly occur in spinel-group minerals, two groups can be distinguished: (1) elements that preferentially partition into the host rock (D<1): Al, Mg, Pb, and Ti and (2) elements that show a preference to partition into magnetite (D>1): Zn, Mn, Cr, V, Ni, and Fe.

European Journal of Mineralogy↗

Central Colorado Assessment Project (CCAP)-Geochemical data for rock, sediment, soil, and concentrate sample media

This database was initiated, designed, and populated to collect and integrate geochemical data from central Colorado in order to facilitate geologic mapping, petrologic studies, mineral resource assessment, definition of geochemical baseline values and statistics, environmental impact assessment, and medical geology. The Microsoft Access database serves as a geochemical data warehouse in support of the Central Colorado Assessment Project (CCAP) and contains data tables describing historical and new quantitative and qualitative geochemical analyses determined by 70 analytical laboratory and field methods for 47,478 rock, sediment, soil, and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed either in the analytical laboratories of the USGS or by contract with commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects. In addition, geochemical data from 7,470 sediment and soil samples collected and analyzed under the Atomic Energy Commission National Uranium Resource Evaluation (NURE) Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) program (henceforth called NURE) have been included in this database. In addition to data from 2,377 samples collected and analyzed under CCAP, this dataset includes archived geochemical data originally entered into the in-house Rock Analysis Storage System (RASS) database (used by the USGS from the mid-1960s through the late 1980s) and the in-house PLUTO database (used by the USGS from the mid-1970s through the mid-1990s). All of these data are maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB and from the NURE database were used to generate most of this dataset. In addition, USGS data that have been excluded previously from the NGDB because the data predate earliest USGS geochemical databases, or were once excluded for programmatic reasons, have been included in the CCAP Geochemical Database and are planned to be added to the NGDB.

Colorado↗

Porosity variability in limestone sequences

Porosity is the state of being porous, as measured by the percentage of bulk volume of a rock or soil that is occupied by space, whether isolated or connected. In hydrocarbon-bearing limestone settings, subsurface porous strata containing the oil or gas usually underlie non-porous caprock through which hydrocarbons cannot pass. In settings, subsurface freshwater aquifers beneath caprock can become contaminated by saltwater intrusion during periods of drought. Islands of the Florida Keys consist of two types of emergent 125-ka limestone, a highly porous fossil coral reef with large voids and a less porous oolite with small grains and interstices. Both limestones are capped by impervious laminated Holocene calcrete whose dimensions differ greatly (Figure 1a and b). Porosity variability in the limestones is thought to be the cause. The less permeable oolite retained rainfall moisture longer, allowing longer periods of calcrete buildup. Reddish and brownish layers in both illustrated calcrete samples represent periods of influx of non-carbonate minerals on African dust. The hiatus or gap in these rock records represents an interval of >115 kyr during which no marine or terrestrial deposition is recorded.

Book chapter↗

Geology of the Cooper Ridge NE Quadrangle, Sweetwater County, Wyoming

The Cooper Ridge NE 7?-minute quadrangle is 18 miles southeast of Rock Springs, Wyo., on the east flank of the Rock Springs uplift. Upper Cretaceous rocks composing the Rock Springs Formation, Ericson Sandstone, Almond Formation, Lewis Shale, Fox Hills Sandstone, and Lance Formation, Paleocene rocks composing the Fort Union Formation, and Eocene rocks composing the Wasatch Formation are exposed and dip 5?-8? southeast. Outcrops are unfaulted and generally homoclinal, but a minor cross-trending fold, the Jackknife Spring anticline, plunges southeastward and interrupts the northeast strike of beds. Older rocks in the subsurface are faulted and folded, especially near the Brady oil and gas field. Coal beds are present in the Almond, Lance, and Fort Union Formations. Coal resources are estimated to be more than 762 million short tons in 16 beds more than 2.5 feet thick, under less than 3,000 ft of overburden. Nearly 166 million tons are under less than 200 ft of overburden and are recoverable by strip mining. Unknown quantities of oil and gas are present in the Cretaceous Rock Springs, Blair, and Dakota Formations, Jurassic sandstone (Entrada Sandstone of drillers), Jurassic(?) and Triassic(?) Nugget Sandstone, Permian Park City Formation, and Pennsylvanian and Permian Weber Sandstone at the Brady field, part of which is in the southeast corner of the quadrangle, and in the Dakota Sandstone at the Prenalta Corp. Bluewater 33-32 well near the northern edge of the quadrangle. Other minerals include uranium in the Almond Formation and titanium in the Rock Springs Formation.

Professional Paper↗

Links between tectonics, magmatism, and mineralization in the formation of Late Cretaceous porphyry systems in the Yukon-Tanana upland, eastern Alaska, USA

Cretaceous-Paleocene porphyry Cu(±Mo±Au) occurrences are scattered throughout the Yukon-Tanana upland in eastern Alaska. Known occurrences in eastern Alaska are poorly characterized, despite a resurgence in exploration. Porphyry deposits in the upland are emplaced into structurally complex metamorphic rocks representing a variety of tectonic environments, resulting in diverse alteration and mineralization assemblages. New mapping, drill core logging, petrography, geochemistry, geochronology, and structural analysis allow improved characterization of the parameters of porphyry systems and identify key linkages to regional tectonic and magmatic events. New sericite 40 Ar/ 39 Ar and zircon U/Pb dates constrain porphyry systems to the Late Cretaceous-earliest Paleocene (ca. 71-63 Ma). Zircon Hf-isotope ratios and Ce and Eu concentrations indicate that Late Cretaceous-Paleocene intrusions emplaced into basement dominated by Triassic and Jurassic plutons are more isotopically juvenile, reflecting more oxidized conditions. In contrast, those emplaced into basement dominated by mid-Cretaceous plutons are more reduced crustal geochemical-affinity. Diversity in mineral assemblages in contrasting systems may reflect emplacement into crustal domains of varying compositions and oxidation states. Those formed within a domain containing more-oxidized Triassic and Jurassic plutons are molybdenite-rich and apparently lack gold. In contrast, systems formed within domains dominated by more reduced mid-Cretaceous plutons contain lower-sulfidation state mineral assemblages with reported gold.

Alaska, Yukon↗

Environmental effects of hydrothermal alteration and historical mining on water and sediment quality in Central Colorado

The U.S. Geological Survey conducted an environmental assessment of 198 catchments in a 54,000-km2 area of central Colorado, much of which is on Federal land. The Colorado Mineral Belt, a northeast-trending zone of historical base- and precious-metal mining, cuts diagonally across the study area. The investigation was intended to test the hypothesis that degraded water and sediment quality are restricted to catchments in which historical mining has occurred. Water, streambed sediment, and aquatic insects were collected from (1) catchments underlain by single lithogeochemical units, some of which were hydrothermally altered, that had not been prospected or mined; (2) catchments that contained evidence of prospecting, most of which contain hydrothermally altered rock, but no historical mining; and (3) catchments, all of which contain hydrothermally altered rock, where historical but now inactive mines occur. Geochemical data determined from catchments that did not contain hydrothermal alteration or historical mines met water quality criteria and sediment quality guidelines. Base-metal concentrations from these types of catchments showed small geochemical variations that reflect host lithology. Hydrothermal alteration and mineralization typically are associated with igneous rocks that have intruded older bedrock in a catchment. This alteration was regionally mapped and characterized primarily through the analysis of remote sensing data acquired by the ASTER satellite sensor. Base-metal concentrations among unaltered rock types showed small geochemical variations that reflect host lithology. Base-metal concentrations were elevated in sediment from catchments underlain by hydrothermally altered rock. Classification of catchments on the basis of mineral deposit types proved to be an efficient and accurate method for discriminating catchments that have degraded water and sediment quality. Only about 4.5 percent of the study area has been affected by historical mining, whereas a larger part of the study area is underlain by hydrothermally altered rock that has weathered to produce water and sediment with naturally elevated geochemical baselines.

Colorado↗