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Geochemistry of fluid phases and sediments: Relevance to hydrothermal circulation in Middle Valley, ODP Legs 139 and 169

Geochemical and isotopic studies of pore fluids and solid phases recovered from the Dead Dog and Bent Hill hydrothermal sites in Middle Valley (Ocean Drilling Program Leg 169) have been compared with similar data obtained previously from these sites during Ocean Drilling Program Leg 139. Although generally the hydrothermal systems reflect non-steady state conditions, the data allow an assessment of the history of the hydrothermal processes. Sediment K/A1 ratios as well as the distribution of anhydrite in the sediments suggest that the Dead Dog hydrothermal field has been, and still is, active. In contrast, similar data in the Bent Hill hydrothermal field indicate a waning of hydrothermal activity. Pore fluid and hydrothermal vent data in the Dead Dog hydrothermal field are similar in nature to the data collected during ODP Leg 139. In the area of the Bent Hill sulfide deposit, however, the pore water data indicate that recent wholesale flushing of the sediment column with relatively unaltered seawater has obliterated a previous record of hydrothermal activity in the pore fluids. Data from the deepest part of Hole 1035A in the Bent Hill locality show the presence of hydrothermal fluids at greater depths in this area. This suggests the origin of the hydrothermal fluids found to be emanating from Hole 1035F, which constitutes one of the first man made hydrothermal vents in the Middle Valley hydrothermal system. Similarly, CORKed Hole 858G, because of seal failures, has acted as a hydrothermal vent, with sulfide deposits forming inside the CORK. ?? 2002 Elsevier Science Ltd. All rights reserved.

Applied Geochemistry↗

Geologic Settings of Subsidence

This paper reviews the role of geologic processes that contribute to subsidence in order to aid those starting investigations of ground-surface subsidence. Subsidence occurs, or at least is discovered, only infrequently, and little organized information has been available. In order to assess our present state of knowledge, the author gathered fragmentary bits of information from many sources widely scattered in the literature of geology and other earth sciences. The author cites examples for each geologic process that is a potential contributor to ground-surface subsidence together with geologic evidence for diagnosing their causes. The geologic processes involved are: (1) solution of gypsum and salt and redistribution of transient fill materials through solution cavities in calcareous rocks; (2) underground erosion of uncemented or lightly cemented silt and sand through temporary underground passageways; (3) lateral plastic flow of salt, gypsum and anhydrite, shale, and clay under loading; (4) compaction of sediments by loading, drainage, vibration, and hydrocompaction; (5) tectonic movements including primary and secondary effects of earthquakes, folding, and warping; and (6) volcanic activity. Because the first four processes may be accelerated by various engineering activities, examples have been selected to illustrate subsidence both under natural conditions and under conditions modified by man's activities. Although this extensive search for existing information on the role of geologic factors in subsidence indicates that much detailed work remains to be done, the future prospects for advancing our geologic knowledge are excellent. Methods of measuring ground-surface displacements are improving rapidly. Also, broadly based investigations of known areas of major subsidence throughout the world are developing new methods of diagnosis and treatment and are yielding quantitative data that will aid our evaluation of the rates and magnitude of present-day geologic processes.

Book chapter↗

The geologic story of Yosemite National Park

Within 150 years, Yosemite has moved from great obscurity to worldwide fame as one of the most visited of our national parks. As a remarkable place where people can enjoy unparalleled scenes of natural beauty and where many easily observed geologic features are concentrated, the park is rivaled by few other areas on the planet. The majesty and immense variety of these features have inspired artists and photographers, intrigued tourists, and stirred controversy among geologists. Field studies in the Yosemite area have contributed to the development of our ideas about geologic processes, including the different actions of streams and glaciers in the evolution of the landscape, and the formation of granite, the basic bedrock of much of the Earth's continents. The park's role as a natural laboratory for geologic research cannot be overemphasized, and its investigation has led to many landmark studies by U.S. Geological Survey geologists over the past 70 years. In 1913, the first detailed program of research on the geology of the park and the origin ofYosemite Valley was begun by Francois Matthes and Frank Calkins. Their work, along with that of later generations of Survey geologists, myself included, serves as the basis for our present understanding of the geologic history of Yosemite and of the processes that formed and continue to mold its landscape. This book, which makes available in one volume a comprehensive summary of the current geologic knowledge of Yosemite National Park, is an excellent example of the Survey's continuing effort to provide earth-science information in the public service.

California↗

Mercury and methylmercury concentrations and loads in the Cache Creek watershed, California

Concentrations and loads of total mercury and methylmercury were measured in streams draining abandoned mercury mines and in the proximity of geothermal discharge in the Cache Creek watershed of California during a 17-month period from January 2000 through May 2001. Rainfall and runoff were lower than long-term averages during the study period. The greatest loading of mercury and methylmercury from upstream sources to downstream receiving waters, such as San Francisco Bay, generally occurred during or after winter rainfall events. During the study period, loads of mercury and methylmercury from geothermal sources tended to be greater than those from abandoned mining areas, a pattern attributable to the lack of large precipitation events capable of mobilizing significant amounts of either mercury-laden sediment or dissolved mercury and methylmercury from mine waste. Streambed sediments of Cache Creek are a significant source of mercury and methylmercury to downstream receiving bodies of water. Much of the mercury in these sediments is the result of deposition over the last 100-150 years by either storm-water runoff, from abandoned mines, or continuous discharges from geothermal areas. Several geochemical constituents were useful as natural tracers for mining and geothermal areas, including the aqueous concentrations of boron, chloride, lithium and sulfate, and the stable isotopes of hydrogen and oxygen in water. Stable isotopes of water in areas draining geothermal discharges showed a distinct trend toward enrichment of 18O compared with meteoric waters, whereas much of the runoff from abandoned mines indicated a stable isotopic pattern more consistent with local meteoric water. ?? 2004 Elsevier B.V. All rights reserved.

Science of the Total Environment↗

Discussions of ODP Leg 205 and drilling of Middle America Seismogenic Zone

Erosional convergent margins, where material is removed from the base of the upper plate and subducted on the lower plate, are fundamental features of the Circum Pacific. The erosional Middle America Trench convergent Pacific margin, remarkable for its broad diversity of dynamic environments, is a natural laboratory for studying convergent margin processes and seismogenesis. These environments include a shallow and deep trench axis, shallow-to-steep-dipping plate interfaces, abnormally hot-to-cold subducting plate temperatures, and a subducting plate with smooth morphology bordering basement ridges and seamounts. The subducting topography accelerates erosion and localizes seismicity.

Middle America Trench, Pacific Ocean↗

Promoting synergy in the innovative use of environmental data—Workshop summary

From December 2 to 4, 2015, NatureServe and the U.S. Geological Survey organized and hosted a biodiversity and ecological informatics workshop at the U.S. Department of the Interior in Washington, D.C. The workshop objective was to identify user-driven future directions and areas of collaboration in advanced applications of environmental data applied to forecasting and decision making for the sustainability of biodiversity and ecosystem services. Substantial effort to recruit attendees from diverse Federal, State, and private sector organizations successfully attracted participants from 20 Federal agencies and 48 different institutions in the academic, nonprofit, State government, and commercial sectors; the total number of attendees ranged from 100 to 144 during the 3-day workshop. The first one-half of the workshop was divided into 7 plenary sessions and 3 sets of lightning talk sessions organized by sector, providing 48 oral and visual plenary presentations that shared diverse perspectives on biodiversity and ecological informatics, including original biospatial analyses from 6 graduate student map contest winners. The second one-half of the workshop focused on 10 breakout sessions with participant-driven themes from the environmental data sphere and concluded with an address by the Director of the U.S. Fish and Wildlife Service. The workshop was structured to encourage interactivity. About 80–90 percent of attendees provided direct feedback using clicker devices for specific questions related to biodiversity and ecological data uses and needs, and 10 breakout session leaders shared the highlights of their group discussions during the final workshop plenary sessions. Participants were encouraged to use the Twitter hashtag #ShareUrData. Over lunch on day 2 there were 20 simultaneous presentations of tools and apps during a special “Tools Café” session. The 10 participant-defined breakout session topics are listed below: Ecosystem services and ecological indicators Inventory and monitoring Biogeographic map of the Nation Pollinators Invasive species Remote sensing Drivers of agricultural change Citizen science Climate Hydrology and watersheds Numerous common themes that emerged from the workshop include the following: The vital importance of completing foundational environmental datasets that are nationally consistent and are essential to multiple sectors, such as the Soil Survey Geographic database high-resolution soils data, a minimum 5-meter resolution digital elevation model, national hydrographic data, high-resolution land cover data, time series high-resolution spatial climate data from historical to future time steps, and a national wetland inventory. Improved, nationally consistent environmental datasets (integrated with targeted observations) will dramatically advance forecasting capacity and support early warning systems (that is, drought, forest disease); however, multiagency coordination should focus on decision support tools that convey appropriate actions and responses to adapt to, and mitigate, potential negative consequences. Digitizing and providing access to the vast stores of underused historical data that can be leveraged for this purpose is of national importance. Modern computational techniques and the ever-increasing flow of environmental data from ground and remote observations can support improved understanding of environmental change. Success of understanding patterns of change for decision making requires establishing baselines from which change can be measured. The value of digitized historical data is greater than ever before. There is a need to recognize the multifaceted potential of citizen science to engage the public in resource stewardship, to create the next generation of science, technology, engineering, math, and environmental leaders, and to have sufficient field personnel to monitor environmental trends, including early detection of alien invasive species, phenological shifts, shifting distribution and abundance of indicator species, and species inventories. The Federal government has an essential role in creating the infrastructure to dramatically improve mobilization of citizen science (and other) data by fostering the following: creation of data standards, creation of nationally consistent framework datasets, vertical integration of observation data, visualization and dissemination of aggregated datasets, and calculation and communication of derived trends. Current and near future trends in the availability of remotely sensed data (rapid expansion of satellite fleets and drones) is revolutionizing access to near-real-time ecological data. Targeted integration with ground-based observations and instrumentation has an extremely valuable role in validating remotely sensed data, filling data gaps, improving data quality, and fully realizing the potential of the near-real-time monitoring of environmental indicator trends. Integrated management of environmental data at the landscape scale is required even as specific actions on the ground are largely local in nature. The workshop highlighted numerous success stories; however, almost every breakout group pointed out the still-too-fragmented nature of the current data landscape. Management and delivery of the necessary data, tools, and analyses to sustain our Nation’s environmental capital must be a collaborative effort between Federal, State, and local governments, academia, nonprofits, and the commercial sector, even though the responsibilities of each sector are different.

Open-File Report↗

Environmental fate of roxarsone in poultry litter. I. Degradation of roxarsone during composting

Roxarsone, 3-nitro-4-hydroxyphenylarsonic acid, is an organoarsenic compound that is used extensively in the feed of broiler poultryto control coccidial intestinal parasites, improve feed efficiency, and promote rapid growth. Nearly all the roxarsone in the feed is excreted unchanged in the manure. Poultry litter composed of the manure and bedding material has a high nutrient content and is used routinely as a fertilizer on cropland and pasture. Investigations were conducted to determine the fate of poultrylitter roxarsone in the environment. Experiments indicated that roxarsone was stable in fresh dried litter; the primary arsenic species extracted with water from dried litter was roxarsone. However, when water was added to litter at about 50 wt % and the mixture was allowed to compost at 40 o C, the speciation of arsenic shifted from roxarsone to primarily arsenate in about 30 days. Increasing the amount of water increased the rate of degradation. Experiments also suggested that the degradation process most likely was biotic in nature. The rate of degradation was directly proportional to the incubation temperature; heat sterilization eliminated the degradation. Biotic degradation also was supported by results from enterobacteriaceae growth media that were inoculated with litter slurry to enhance the biotic processes and to reduce the concomitant abiotic effects from the complex litter solution. Samples collected from a variety of litter windrows in Arkansas, Oklahoma, and Maryland also showed that roxarsone originally present had been converted to arsenate.

Environmental Science & Technology↗

Global analyses of brachiopod faunas through the Ordovician and Silurian transition: Reducing the role of the Lazarus effect

Global analyses of 88 families and 284 genera of brachiopods from middle Ashgill, Late Ordovician, to early-middle Rhuddanian, Early Silurian, indicate that 18.6% and 12.5% of families and 51.0% and 41.3% of genera were eliminated in the first and second phases of the end-Ordovician mass extinction, respectively, with the total loss of 28.4% of families and 69.0% of genera in the crisis. New investigation demonstrates that brachiopods, at both generic and familial levels, suffered greater during the first phase than during the second phase. Four groups (victims, relicts, survivors, and new arrivals) are distinguished by their stratigraphical ranges. Generic survivors, occurring in the Kosov Province during the Hirnantian, can be split into three types with respect to their changing abundance: increasing, declining, and Lazarus taxa. Among the 88 genera that survived, numerous declining genera occurred in the Hirnantian: 16 Lazarus families and 18 Lazarus genera are provisionally known and may be regarded as end members of the declining type. Comparison of the abundance, population size, and distribution patterns of declining and Lazarus taxa shows important similarities between these two types which contribute to a better understanding of the nature of Lazarus taxa. In addition to these biological attributes, taphonomic failure and generally poor preservation, together with collecting bias and inadequate systematic data, are clearly involved. More collections will undoubtedly globally reduce the number of Lazarus taxa. A single, common refugium for end-Ordovician brachiopods probably did not exist; rather, these taxa used paleogeographically scattered locations in a range of environments for survival. ?? 2006 NRC Canada.

Canadian Journal of Earth Sciences↗

Social Values for Ecosystem Services (SolVES): using GIS to include social values information in ecosystem services assessments

Ecosystem services can be defined in various ways; simply put, they are the benefits provided by nature, which contribute to human well-being. These benefits can range from tangible products such as food and fresh water to cultural services such as recreation and esthetics. As the use of these benefits continues to increase, additional pressures are placed on the natural ecosystems providing them. This makes it all the more important when assessing possible tradeoffs among ecosystem services to consider the human attitudes and preferences that express underlying social values associated with their benefits. While some of these values can be accounted for through economic markets, other values can be more difficult to quantify, and attaching dollar amounts to them may not be very useful in all cases. Regardless of the processes or units used for quantifying such values, the ability to map them across the landscape and relate them to the ecosystem services to which they are attributed is necessary for effective assessments. To address some of the needs associated with quantifying and mapping social values for inclusion in ecosystem services assessments, scientists at the Rocky Mountain Geographic Science Center (RMGSC), in collaboration with Colorado State University, have developed a public domain tool, Social Values for Ecosystem Services (SolVES). SolVES is a geographic information system (GIS) application designed to use data from public attitude and preference surveys to assess, map, and quantify social values for ecosystem services. SolVES calculates and maps a 10-point Value Index representing the relative perceived social values of ecosystem services such as recreation and biodiversity for various groups of ecosystem stakeholders. SolVES output can also be used to identify and model relationships between social values and physical characteristics of the underlying landscape. These relationships can then be used to generate predicted Value Index maps for areas where survey data are not available. RMGSC will continue to develop more robust versions of SolVES by pursuing opportunities to work with land and resource managers as well as other researchers to apply SolVES to specific ecosystem management problems.

Fact Sheet↗

Overview of the effects and influence of the activity of Mount St. Helens in the 1980s

The cataclysmic eruption of Mount St. Helens on May 18, 1980, made an enormous impact on the science of volcanology. The eruption was in daylight in clear weather, which provided an unprecedented opportunity to investigate relations among observations, products, and effects of a large explosive eruption. The May 18 events and subsequent activity stimulated perhaps the most intensive studies ever made at an active composite volcano, leading to greatly enhanced insights into both geologic and hydrologic processes operative in explosive volcanism. The eruption also disrupted much of the social and economic fabric of the Pacific Northwest. Volcanologists were called upon to explain the activity, in layman's terms, to government and corporate officials, the news media, schools, and the public at large. People eventually learned to live with the volcano and its uncertainties, and volcanologists better learned their role in helping society deal with a major natural disaster. Difficulties encountered at volcanic crises elsewhere in the world in the 1980s demonstrate that these are hard lessons. In future years, a paramount challenge for scientists will be to help society apply what has been learned at Mount St. Helens to crises both nearby and far away.

Washington↗

Geomagnetic polarity epochs: new data from Olduvai Gorge, Tanganyika

The lower lava flow of Bed I in Olduvai Gorge, Tanganyika, carries natural remanent magnetization (NRM) having normal polarity. Thermal demagnetization experiments demonstrate the stability of this NRM. Thus the Olduvai geomagnetic polarity event, which was originally named from the upper lava flow in Bed I, is represented in its type locality by two normally magnetized lavas. These lavas have been shown to be 1.9 m.y. old, and although they are distinct from each other in composition and surface structure, their eruptions appear to have been closely spaced in time.

Tanganyika↗

Lead sequestration and species redistribution during soil organic matter decomposition

The turnover of soil organic matter (SOM) maintains a dynamic chemical environment in the forest floor that can impact metal speciation on relatively short timescales. Here we measure the speciation of Pb in controlled and natural organic (O) soil horizons to quantify changes in metal partitioning during SOM decomposition in different forest litters. We provide a link between the sequestration of pollutant Pb in O-horizons, estimated by forest floor Pb inventories, and speciation using synchrotron-based X-ray fluorescence and X-ray absorption spectroscopy. When Pb was introduced to fresh forest Oi samples, it adsorbed primarily to SOM surfaces, but as decomposition progressed over two years in controlled experiments, up to 60% of the Pb was redistributed to pedogenic birnessite and ferrihydrite surfaces. In addition, a significant fraction of pollutant Pb in natural soil profiles was associated with similar mineral phases (???20-35%) and SOM (???65-80%). Conifer forests have at least 2-fold higher Pb burdens in the forest floor relative to deciduous forests due to more efficient atmospheric scavenging and slower organic matter turnover. We demonstrate that pedogenic minerals play an important role in surface soil Pb sequestration, particularly in deciduous forests, and should be considered in any assessment of pollutant Pb mobility. ?? 2008 American Chemical Society.

Environmental Science & Technology↗

Leveraging natural capital accounting to support businesses with nature-related risk assessments and disclosures

Nature loss threatens businesses, the global economy and financial stability. Understanding and addressing these risks for business will require credible measurement approaches and data. This paper explores how natural capital accounting (NCA) can support business data and information needs related to nature, including disclosures aligned with the Taskforce on Nature-related Financial Disclosures recommendations. As businesses seek to measure, manage and disclose their nature-related risks and opportunities, they will need well-organized, consistent and high-quality information regarding their dependencies and impacts on nature, which few businesses currently collect or track in-house. NCA may be useful for these purposes but has not been widely used or applied by businesses. National NCA guided by the U.N. System of Environmental-Economic Accounting may provide: (i) a useful framework for businesses in conceptualizing, organizing and managing nature-related data and statistics; and (ii) data and information that can directly support business disclosures, corporate NCA and other business applications. This paper explores these opportunities as well as synergies between national and corporate natural capital accounts. In addition, the paper discusses key barriers to advancing the wider use and benefits of NCA for business, including: awareness of NCA, data access, business capabilities related to NCA, spatial and temporal scales of data, audit and assurance considerations, potential risks, and costs and incentives.

Philosophical Transactions of the Royal Society B:↗

Worldwide occurrences of arsenic in ground water

Numerous aquifers worldwide carry soluble arsenic at concentrations greater than the World Health Organization--and U.S. Environmental Protection Agency--recommended drinking water standard of 10 mg per liter. Sources include both natural (black shales, young sediments with low flushing rates, gold mineralization, and geothermal environments) and anthropogenic (mining activities, livestock feed additives, pesticides, and arsenic trioxide wastes and stockpiles). Increased solubility and mobility of arsenic is promoted by high pH (>8.5), competing oxyanions, and reducing conditions. In this Policy Forum, Nordstrom argues that human health risks from arsenic in ground water can be minimized by incorporating hydrogeochemical knowledge into water management decisions and by more careful monitoring for arsenic in geologically high-risk areas.

Science↗

Platinum metals in magmatic sulfide ores

Platinum-group elements (PGE) are mined predominantly from deposits that have formed by the segregation of molten iron-nickel-copper sulfides from silicate magmas. The absolute concentrations of PGE in sulfides from different deposits vary over a range of five orders of magnitude, whereas those of other chalcophile elements vary by factors of only 2 to 100. However, the relative proportions of the different PGE in a given deposit are systematically related to the nature of the parent magma. The absolute and relative concentrations of PGE in magmatic sulfides are explained in terms of the degree of partial melting of mantle peridotite required to produce the parent magma and the processes of batch equilibration and fractional segregation of sulfides. The Republic of South Africa and the U.S.S.R. together possess more than 97 percent of the world PGE reserves, but significant undeveloped resources occur in North America. The Stillwater complex in Montana is perhaps the most important example.

Science↗

A combined telemetry - tag return approach to estimate fishing and natural mortality rates of an estuarine fish

A joint analysis of tag return and telemetry data should improve estimates of mortality rates for exploited fishes; however, the combined approach has thus far only been tested in terrestrial systems. We tagged subadult red drum (Sciaenops ocellatus) with conventional tags and ultrasonic transmitters over 3 years in coastal North Carolina, USA, to test the efficacy of the combined telemetry - tag return approach. There was a strong seasonal pattern to monthly fishing mortality rate (F) estimates from both conventional and telemetry tags; highest F values occurred in fall months and lowest levels occurred during winter. Although monthly F values were similar in pattern and magnitude between conventional tagging and telemetry, information on F in the combined model came primarily from conventional tags. The estimated natural mortality rate (M) in the combined model was low (estimated annual rate ?? standard error: 0.04 ?? 0.04) and was based primarily upon the telemetry approach. Using high-reward tagging, we estimated different tag reporting rates for state agency and university tagging programs. The combined telemetry - tag return approach can be an effective approach for estimating F and M as long as several key assumptions of the model are met.

Canadian Journal of Fisheries and Aquatic Sciences↗

Summary of preliminary step-trend analysis from the Interagency Whitebark Pine Long-termMonitoring Program—2004-2013

In mixed and dominant stands, whitebark pine ( Pinus albicaulis ) occurs in over two million acres within the six national forests and two national parks that comprise the Greater Yellowstone Ecosystem (GYE). Currently, whitebark pine, an ecologically important species, is impacted by multiple ecological disturbances; white pine blister rust ( Cronartium ribicola ), mountain pine beetle ( Dendroctonus ponderosae ), wildfire, and climate change all pose significant threats to the persistence of whitebark pine populations. Substantial declines in whitebark pine populations have been documented throughout its range. Under the auspices of the Greater Yellowstone Coordinating Committee (GYCC), several agencies began a collaborative, long-term monitoring program to track and document the status of whitebark pine across the GYE. This alliance resulted in the formation of the Greater Yellowstone Whitebark Pine Monitoring Working Group (GYWPMWG), which consists of representatives from the U.S. Forest Service (USFS), National Park Service (NPS), U.S. Geological Survey (USGS), and Montana State University (MSU). This groundbased monitoring program was initiated in 2004 and follows a peer-reviewed protocol (GYWPMWG 2011). The program is led by the Greater Yellowstone Inventory and Monitoring Network (GRYN) of the National Park Service in coordination with multiple agencies. More information about this monitoring effort is available at: http://science. nature.nps.gov/im/units/gryn/monitor/whitebark_pine.cfm. The purpose of this report is to provide a draft summary of the first step-trend analysis for the interagency, long-term monitoring of whitebark pine health to the Interagency Grizzly Bear Study Team (IGBST) as part of a synthesis of the state of whitebark pine in the GYE. Due to the various stages of the analyses and reporting, this is the most efficient way to provide these results to the IGBST.

Natural Resource Data Series↗

Muskoxen

Muskoxen ( Ovibos moschatus ) disappeared from Alaska in the late 1800s, but returned to the Arctic National Wildlife Refuge when animals were reestablished into areas of former range in 1969-1970 (Klein 1988). Released at Barter Island (Kaktovik) and the Kavik River, muskoxen initially moved into regions that encompassed the 1002 Area on the coastal plain of the Arctic Refuge. From 1974 to 1986 the muskox population grew rapidly. By 1987, however, numbers declined in the regions that they had first occupied (Reynolds 1998 a ). Petroleum exploration and development could occur in muskox habitat in the 1002 Area of the Arctic Refuge. Status of the muskox population and factors related to trends in local abundance need to be determined if changes resulting from natural processes are to be separated from those that might result if industrial development is permitted in the Arctic Refuge. We developed a study with the following objectives to understand the dynamics of the muskox population in and near the 1002 Area of the Arctic Refuge: 1) determine abundance and rates of population increase, production, and survival; 2) document changes in population distribution over time, and 3) evaluate factors associated with changes in the number of muskoxen.

Alaska, Northwest Territories, Yukon Territory↗