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Niobium and tantalum

Niobium and tantalum are transition metals that are almost always found together in nature because they have very similar physical and chemical properties. Their properties of hardness, conductivity, and resistance to corrosion largely determine their primary uses today. The leading use of niobium (about 75 percent) is in the production of high-strength steel alloys used in pipelines, transportation infrastructure, and structural applications. Electronic capacitors are the leading use of tantalum for high-end applications, including cell phones, computer hard drives, and such implantable medical devices as pacemakers. Niobium and tantalum are considered critical and strategic metals based on the potential risks to their supply (because current production is restricted to only a few countries) and the significant effects that a restriction in supply would have on the defense, energy, high-tech industrial, and medical sectors. The average abundance of niobium and tantalum in bulk continental crust is relatively low—8.0 parts per million (ppm) niobium and 0.7 ppm tantalum. Their chemical characteristics, such as small ionic size and high electronic field strength, significantly reduce the potential for these elements to substitute for more common elements in rock-forming minerals and make niobium and tantalum essentially immobile in most aqueous solutions. Niobium and tantalum do not occur naturally as pure metals but are concentrated in a variety of relatively rare oxide and hydroxide minerals, as well as in a few rare silicate minerals. Niobium is primarily derived from the complex oxide minerals of the pyrochlore group ((Na,Ca,Ce) 2 (Nb,Ti,Ta) 2 (O,OH,F) 7 ), which are found in some alkaline granite-syenite complexes (that is, igneous rocks containing sodium- or potassium-rich minerals and little or no quartz) and carbonatites (that is, igneous rocks that are more than 50 percent composed of primary carbonate minerals, by volume). Tantalum is derived mostly from the mineral tantalite ((Fe,Mn)(Ta,Nb) 2 O 6 ), which is found as an accessory mineral in rare-metal granites and pegmatites that are also enriched in lithium and cesium (termed lithium-cesium-tantalum (LCT)-type pegmatites). Brazil and Canada are the leading nations that produce niobium mineral concentrates, but Brazil is by far the leading producer, accounting for about 90 percent of production, which comes mostly from weathered material derived from carbonatites. Brazil and Canada also have the largest identified niobium resources; additional resources, although they are less well reported, occur in Angola, Australia, China, Greenland, Malawi, Russia, and South Africa. Australia and Brazil have been the leading producers of tantalum mineral concentrates, although recently Ethiopia and Mozambique have also been significant suppliers of tantalum. Artisanal mining of columbite-tantalite (also called coltan) is practiced in many countries, particularly Burundi, the Democratic Republic of the Congo (Congo [Kinshasa]), Nigeria, Rwanda, and Uganda. Brazil has about 40 percent of the identified tantalum resources; other countries and regions with identified tantalum resources include, in decreasing order of resources, Australia, Asia, Russia and the Middle East, Africa, North America, and Europe. Identified niobium and tantalum resources in the United States are small, low grade, and difficult to recover and process, and are thus not commercially recoverable at current prices. Consequently, the United States meets its current and expected future needs for niobium and tantalum through imports of primary mineral concentrates and alloys and through recovery from foreign and domestic alloy scrap that contain the metals. Environmentally, the main issues related to niobium and tantalum mining are land disruptions, the volume of waste materials and their disposal, and the radioactivity of some tailings and waste materials that contain thorium and uranium. Because of the relative biological inertness of niobium and tantalum, human and ecological health concerns are generally minimal under most natural conditions. Demand for both niobium and tantalum is expected to increase as the world economy continues to recover from the downturn that began in 2008. Increased demand for niobium is linked to increased consumption of microalloyed steel, which is used in the manufacture of cars, buildings, ships, and refinery equipment. Demand for these steels will likely increase with continued economic development in such countries as Brazil, China, and India. In addition, increased global demand for cars, cell phones, computers, superconducting magnets, and other high-tech devices will likely spur increased demand for both niobium and tantalum. The estimated global reserves and resources of niobium and tantalum are large and appear more than sufficient to meet global demand for the foreseeable future, possibly the next 500 years. The sale of “conflict coltan” attributed to rebel forces waging a civil war in Congo (Kinshasa) has been of recent concern and has highlighted the need for a transparent and traceable global supply chain that can exclude illegal columbite-tantalite from the conventional market while discerning legitimate artisanal mine production in central Africa.

Professional Paper↗

Evaluation of sampling methods used to estimate irrigation pumpage in Chase, Dundy, and Perkins counties, Nebraska

Combining estimates of applied irrigation water, determined for selected sample sites, with information on irrigated acreage provides one alternative for developing areal estimates of groundwater pumpage for irrigation. The reliability of this approach was evaluated by comparing estimated pumpage with metered pumpage for two years for a three-county area in southwestern Nebraska. Meters on all irrigation wells in the three counties provided a complete data set for evaluation of equipment and comparison with pumpage estimates. Regression analyses were conducted on discharge, time-of-operation, and pumpage data collected at 52 irrigation sites in 1983 and at 57 irrigation sites in 1984 using data from inline flowmeters as the independent variable. The standard error of the estimate for regression analysis of discharge measurements made using a portable flowmeter was 6.8% of the mean discharge metered by inline flowmeters. The standard error of the estimate for regression analysis of time of operation determined from electric meters was 8.1% of the mean time of operation determined from in-line and 15.1% for engine-hour meters. Sampled pumpage, calculated by multiplying the average discharge obtained from the portable flowmeter by the time of operation obtained from energy or hour meters, was compared with metered pumpage from in-line flowmeters at sample sites. The standard error of the estimate for the regression analysis of sampled pumpage was 10.3% of the mean of the metered pumpage for 1983 and 1984 combined. The difference in the mean of the sampled pumpage and the mean of the metered pumpage was only 1.8% for 1983 and 2.3% for 1984. Estimated pumpage, for each county and for the study area, was calculated by multiplying application (sampled pumpage divided by irrigated acreages at sample sites) by irrigated acreage compiled from Landsat (Land satellite) imagery. Estimated pumpage was compared with total metered pumpage for each county and the study area. Estimated pumpage by county varied from 9% less, to 20% more, than metered pumpage in 1983 and from 0 to 15% more than metered pumpage in 1984. Estimated pumpage for the study area was 11 % more than metered pumpage in 1983 and 5% more than metered pumpage in 1984. (Author 's abstract)

Water-Resources Investigations Report↗

Spatial and temporal patterns in golden eagle diets in the western United States, with implications for conservation planning

Detailed information on diets and predatory ecology of Golden Eagles ( Aquila chrysaetos ) is essential to prioritize prey species management and to develop landscape-specific conservation strategies, including mitigation of the effects of energy development across the western United States. We compiled published and unpublished data on Golden Eagle diets to (1) summarize available information on Golden Eagle diets in the western U.S., (2) compare diets among biogeographic provinces, and (3) discuss implications for conservation planning and future research. We analyzed 35 studies conducted during the breeding season at 45 locations from 1940–2015. Golden Eagle diet differed among western ecosystems. Lower dietary breadth was associated with desert and shrub-steppe ecosystems and higher breadth with mountain ranges and the Columbia Plateau. Correlations suggest that percentage of leporids in the diet is the factor driving overall diversity of prey and percentage of other prey groups in the diet of Golden Eagles. Leporids were the primary prey of breeding Golden Eagles in 78% of study areas, with sciurids reported as primary prey in 18% of study areas. During the nonbreeding season, Golden Eagles were most frequently recorded feeding on leporids and carrion. Golden Eagles can be described as both generalist and opportunistic predators; they can feed on a wide range of prey species but most frequently feed on abundant medium-sized prey species in a given habitat. Spatial variations in Golden Eagle diet likely reflect regional differences in prey community, whereas temporal trends likely reflect responses to long-term change in prey populations. Evidence suggests dietary shifts from traditional (leporid) prey can have adverse effects on Golden Eagle reproductive rates. Land management practices that support or restore shrub-steppe ecosystem diversity should benefit Golden Eagles. More information is needed on nonbreeding-season diet to determine what food resources, such as carrion, are important for overwinter survival.

Journal of Raptor Research↗

Tracking heat in the Willamette River system, Oregon

The Willamette River Basin in northwestern Oregon is home to several cold-water fish species whose habitat has been altered by the Willamette Valley Project, a system of 13 dams and reservoirs operated by the U.S. Army Corps of Engineers. Water-resource managers use a variety of flow- and temperature-management strategies to ameliorate the effects of upstream Willamette Valley Project dams on the habitat and viability of these anadromous and native fish. In this study, new capabilities were added to the CE-QUAL-W2 two-dimensional flow and water-quality model to inform those flow- and temperature-management strategies by tracking the quantities and ages of water and heat from individual upstream sources to downstream locations in the Willamette River system. Specifically, the fraction of water and heat attributable to upstream dam releases or other water inputs, and the fraction of heat sourced from environmental heat fluxes across the water and sediment surfaces, were tracked and quantified in the river at all locations and times simulated by the model. Applying the updated CE-QUAL-W2 models to the Willamette River system for the months of March through October in the years 2011 (cool and wet), 2015 (hot and dry), and 2016 (warm and somewhat dry) demonstrated that the influence of upstream dam releases on downstream water temperature diminished within a few days as water moved downstream. At sites that are roughly two or more days of travel from upstream dams (Albany and downstream), the July–August fraction of riverine heat content that could be tracked back to upstream dam releases typically diminished to less than 20 percent, despite the fact that roughly 50 percent of July–August streamflow could be attributed to upstream dam releases at the same sites. In contrast, the fraction of riverine heat content that could be attributed to environmental energy fluxes continued to increase with downstream distance, from about 59 to 67 percent at Albany during July–August to 62 to 73 percent at Keizer and 68 to 79 percent at Newberg. At locations sufficiently far downstream, upstream dam releases affect water temperature mainly through a decrease in travel time (less time for environmental heat fluxes to warm the river during summer) and an increase in thermal mass (more water to dilute and buffer incoming heat fluxes) rather than through the simple transport of heat content (water temperature) released from the dams. This concept was explored not only for the baseline conditions that occurred in March–October of 2011, 2015, and 2016, but also for a hypothetical high-flow release during August 2016 and an actual high-flow release during August 2017. In these high-flow releases, an extra 2,500 cubic feet per second (roughly) was released from Dexter Dam on the Middle Fork Willamette River, and downstream effects were measured (2017, actual) and simulated (2016, hypothetical). Results of the simulations were consistent with insights gained from the baseline conditions, such that temperature changes caused by flow augmentation were substantial in upstream reaches (measured cooling of about 1.5 °C near Harrisburg [43 miles downstream] and Albany [84 miles downstream] in 2017, and cooling of about 0.5 °C near Albany in 2016) and diminished farther downstream, but still measurable (more than a few tenths of a degree Celsius) even at Newberg, which is about 154 miles downstream. The direct downstream effects of dam releases on the river heat content attributable to those releases were increased by the hypothetical flow augmentation, with increases of 20 percent at Harrisburg and 12 percent at Keizer. Even with a decreased influence of environmental energy fluxes on river heat content, however, the fraction of heat content attributable to such fluxes was still more than 50 percent at and downstream of Albany and more than 70 percent at Newberg, where the river temperature was less affected by upstream dam-release temperatures and instead was affected primarily by a decreased travel time and increased thermal mass.

Oregon↗

Mapping surface disturbance of energy-related infrastructure in southwest Wyoming--An assessment of methods

We evaluated how well three leading information-extraction software programs (eCognition, Feature Analyst, Feature Extraction) and manual hand digitization interpreted information from remotely sensed imagery of a visually complex gas field in Wyoming. Specifically, we compared how each mapped the area of and classified the disturbance features present on each of three remotely sensed images, including 30-meter-resolution Landsat, 10-meter-resolution SPOT (Satellite Pour l'Observation de la Terre), and 0.6-meter resolution pan-sharpened QuickBird scenes. Feature Extraction mapped the spatial area of disturbance features most accurately on the Landsat and QuickBird imagery, while hand digitization was most accurate on the SPOT imagery. Footprint non-overlap error was smallest on the Feature Analyst map of the Landsat imagery, the hand digitization map of the SPOT imagery, and the Feature Extraction map of the QuickBird imagery. When evaluating feature classification success against a set of ground-truthed control points, Feature Analyst, Feature Extraction, and hand digitization classified features with similar success on the QuickBird and SPOT imagery, while eCognition classified features poorly relative to the other methods. All maps derived from Landsat imagery classified disturbance features poorly. Using the hand digitized QuickBird data as a reference and making pixel-by-pixel comparisons, Feature Extraction classified features best overall on the QuickBird imagery, and Feature Analyst classified features best overall on the SPOT and Landsat imagery. Based on the entire suite of tasks we evaluated, Feature Extraction performed best overall on the Landsat and QuickBird imagery, while hand digitization performed best overall on the SPOT imagery, and eCognition performed worst overall on all three images. Error rates for both area measurements and feature classification were prohibitively high on Landsat imagery, while QuickBird was time and cost prohibitive for mapping large spatial extents. The SPOT imagery produced map products that were far more accurate than Landsat and did so at a far lower cost than QuickBird imagery. Consideration of degree of map accuracy required, costs associated with image acquisition, software, operator and computation time, and tradeoffs in the form of spatial extent versus resolution should all be considered when evaluating which combination of imagery and information-extraction method might best serve any given land use mapping project. When resources permit, attaining imagery that supports the highest classification and measurement accuracy possible is recommended.

Wyoming↗

Historical methane hydrate project review

In 1995, U.S. Geological Survey made the first systematic assessment of the volume of natural gas stored in the hydrate accumulations of the United States. That study, along with numerous other studies, has shown that the amount of gas stored as methane hydrates in the world greatly exceeds the volume of known conventional gas resources. However, gas hydrates represent both a scientific and technical challenge and much remains to be learned about their characteristics and occurrence in nature. Methane hydrate research in recent years has mostly focused on: (1) documenting the geologic parameters that control the occurrence and stability of gas hydrates in nature, (2) assessing the volume of natural gas stored within various gas hydrate accumulations, (3) analyzing the production response and characteristics of methane hydrates, (4) identifying and predicting natural and induced environmental and climate impacts of natural gas hydrates, and (5) analyzing the effects of methane hydrate on drilling safety. Methane hydrates are naturally occurring crystalline substances composed of water and gas, in which a solid water-­‐lattice holds gas molecules in a cage-­‐like structure. The gas and water becomes a solid under specific temperature and pressure conditions within the Earth, called the hydrate stability zone. Other factors that control the presence of methane hydrate in nature include the source of the gas included within the hydrates, the physical and chemical controls on the migration of gas with a sedimentary basin containing methane hydrates, the availability of the water also included in the hydrate structure, and the presence of a suitable host sediment or “reservoir”. The geologic controls on the occurrence of gas hydrates have become collectively known as the “methane hydrate petroleum system”, which has become the focus of numerous hydrate research programs. Recognizing the importance of methane hydrate research and the need for a coordinated effort, the U.S. Congress enacted Public Law 106-­‐193, the Methane Hydrate Research and Development Act of 2000. This Act called for the Secretary of Energy to begin a methane hydrate research and development program in consultation with other U.S. federal agencies. At the same time a new methane hydrate research program had been launched in Japan by the Ministry of International Trade and Industry to develop plans for a methane hydrate exploratory drilling project in the Nankai Trough. Since this early start we have seen other countries including India, China, Canada, and the Republic of Korea establish large gas hydrate research and development programs. These national led efforts have also included the investment in a long list of important scientific research drilling expeditions and production test studies that have provided a wealth of information on the occurrence of methane hydrate in nature. The most notable expeditions and projects have including the following: -­‐Ocean Drilling Program Leg 164 (1995) -­‐Japan Nankai Trough Project (1999-­‐2000) -­‐Ocean Drilling Program Leg 204 (2004) -­‐Japan Tokai-­‐oki to Kumano-­‐nada Project (2004) -­‐Gulf of Mexico JIP Leg I (2005) -­‐Integrated Ocean Drilling Program Expedition 311 (2005) -­‐Malaysia Gumusut-­‐Kakap Project (2006) -­‐India NGHP Expedition 01 (2006) -­‐China GMGS Expedition 01 (2007) -­‐Republic of Korea UBGH Expedition 01 (2007) -­‐Gulf of Mexico JIP Leg II (2009) -­‐Republic of Korea UBGH Expedition 02 (2010) -­‐MH-­‐21 Nankai Trough Pre-­‐Production Expedition (2012-­‐2013) -­‐Mallik Gas Hydrate Testing Projects (1998/2002/2007-­‐2008) -­‐Alaska Mount Elbert Stratigraphic Test Well (2007) -­‐Alaska Iġnik Sikumi Methane Hydrate Production Test Well (2011-­‐2012) Research coring and seismic programs carried out by the Ocean Drilling Program (ODP) and Integrated Ocean Drilling Program (IODP), starting with the ODP Leg 164 drilling of the Blake Ridge in the Atlantic Ocean in 1995, have also contributed greatly to our understanding of the geologic controls on the formation, occurrence, and stability of gas hydrates in marine environments. For the most part methane hydrate research expeditions carried out by the ODP and IODP provided the foundation for our scientific understanding of gas hydrates. The methane hydrate research efforts under ODP-­‐IODP have mostly dealt with the assessment of the geologic controls on the occurrence of gas hydrate, with a specific goal to study the role methane hydrates may play in the global carbon cycle. Over the last 10 years, national led methane hydrate research programs, along with industry interest have led to the development and execution of major methane hydrate production field test programs. Two of the most important production field testing programs have been conducted at the Mallik site in the Mackenzie River Delta of Canada and in the Eileen methane hydrate accumulation on the North Slope of Alaska. Most recently we have also seen the completion of the world’s first marine methane hydrate production test in the Nankai Trough in the offshore of Japan. Industry interest in gas hydrates has also included important projects that have dealt with the assessment of geologic hazards associated with the presence of hydrates. The scientific drilling and associated coring, logging, and borehole monitoring technologies developed in the long list of methane hydrate related field studies are one of the most important developments and contributions associated with methane hydrate research and development activities. Methane hydrate drilling has been conducted from advanced scientific drilling platforms like the JOIDES Resolution and the D/V Chikyu, which feature highly advanced integrated core laboratories and borehole logging capabilities. Hydrate research drilling has also included the use of a wide array of industry, geotechnical and multi-­‐service ships. All of which have been effectively used to collect invaluable geologic and engineering data on the occurrence of methane hydrates throughout the world. Technologies designed specifically for the collection and analysis of undisturbed methane hydrate samples have included the development of a host of pressure core systems and associated specialty laboratory apparatus. The study and use of both wireline conveyed and logging-­‐while-­‐drilling technologies have also contributed greatly to our understanding of the in-­‐situ nature of hydrate-­‐bearing sediments. Recent developments in borehole instrumentation specifically designed to monitor changes associated with hydrates in nature through time or to evaluate the response of hydrate accumulations to production have also contributed greatly to our understanding of the complex nature and evolution of methane hydrate systems. Our understanding of how methane hydrates occur and behave in nature is still growing and evolving – we do not yet know if methane hydrates can be economically produced, nor do we know fully the role of hydrates as an agent of climate change or as a geologic hazard. But it is known for certain that scientific drilling has contributed greatly to our understanding of hydrates in nature and will continue to be a critical source of the information to advance our understanding of methane hydrates.

Report↗

Land use and habitat conditions across the southwestern Wyoming sagebrush steppe: development impacts, management effectiveness and the distribution of invasive plants

For the past several years, USGS has taken a multi-faceted approach to investigating the condition and trends in sagebrush steppe ecosystems. This recent effort builds upon decades of work in semi-arid ecosystems providing a specific, applied focus on the cumulative impacts of expanding human activities across these landscapes. Here, we discuss several on-going projects contributing to these efforts: (1) mapping and monitoring the distribution and condition of shrub steppe communities with local detail at a regional scale, (2) assessing the relationships between specific, land-use features (for example, roads, transmission lines, industrial pads) and invasive plants, including their potential (environmentally defined) distribution across the region, and (3) monitoring the effects of habitat treatments on the ecosystem, including wildlife use and invasive plant abundance. This research is focused on the northern sagebrush steppe, primarily in Wyoming, but also extending into Montana, Colorado, Utah and Idaho. The study area includes a range of sagebrush types (including, Artemisia tridentata ssp. tridentata, Artemisia tridentata ssp. wyomingensis, Artemisia tridentata ssp. vaseyana, Artemisia nova) and other semi-arid shrubland types (for example, Sarcobatus vermiculatus, Atriplex confertifolia, Atriplex gardneri), impacted by extensive interface between steppe ecosystems and industrial energy activities resulting in a revealing multiple-variable analysis. We use a combination of remote sensing (AWiFS (1 Any reference to platforms, data sources, equipment, software, patented or trade-marked methods is for information purposes only. It does not represent endorsement of the U.S.D.I., U.S.G.S. or the authors), Landsat and Quickbird platforms), Geographic Information System (GIS) design and data management, and field-based, replicated sampling to generate multiple scales of data representing the distribution of shrub communities for the habitat inventory. Invasive plant sampling focused on the interaction between human infrastructure and weedy plant distributions in southwestern Wyoming, while also capturing spatial variability associated with growing conditions and management across the region. In a separate but linked study, we also sampled native and invasive composition of recent and historic habitat treatments. Here, we summarize findings of this ongoing work, highlighting patterns and relationships between vegetation (native and invasive), land cover, landform, and land-use patterns in the sagebrush steppe.

Wyoming↗

Modeling Water-Surface Elevations and Virtual Shorelines for the Colorado River in Grand Canyon, Arizona

Using widely-available software intended for modeling rivers, a new one-dimensional hydraulic model was developed for the Colorado River through Grand Canyon from Lees Ferry to Diamond Creek. Solving one-dimensional equations of energy and continuity, the model predicts stage for a known steady-state discharge at specific locations, or cross sections, along the river corridor. This model uses 2,680 cross sections built with high-resolution digital topography of ground locations away from the river flowing at a discharge of 227 m3/s; synthetic bathymetry was created for topography submerged below the 227 m3/s water surface. The synthetic bathymetry was created by adjusting the water depth at each cross section up or down until the model?s predicted water-surface elevation closely matched a known water surface. This approach is unorthodox and offers a technique to construct one-dimensional hydraulic models of bedrock-controlled rivers where bathymetric data have not been collected. An analysis of this modeling approach shows that while effective in enabling a useful model, the synthetic bathymetry can differ from the actual bathymetry. The known water-surface profile was measured using elevation data collected in 2000 and 2002, and the model can simulate discharges up to 5,900 m3/s. In addition to the hydraulic model, GIS-based techniques were used to estimate virtual shorelines and construct inundation maps. The error of the hydraulic model in predicting stage is within 0.4 m for discharges less than 1,300 m3/s. Between 1,300-2,500 m3/s, the model accuracy is about 1.0 m, and for discharges between 2,500-5,900 m3/s, the model accuracy is on the order of 1.5 m. In the absence of large floods on the flow-regulated Colorado River in Grand Canyon, the new hydraulic model and the accompanying inundation maps are a useful resource for researchers interested in water depths, shorelines, and stage-discharge curves for flows within the river corridor with 2002 topographic conditions.

Arizona↗

Dynamic hyporheic exchange at intermediate timescales: testing the relative importance of evapotranspiration and flood pulses

Hyporheic fluxes influence ecological processes across a continuum of timescales. However, few studies have been able to characterize hyporheic fluxes and residence time distributions (RTDs) over timescales of days to years, during which evapotranspiration (ET) and seasonal flood pulses create unsteady forcing. Here we present a data-driven, particle-tracking piston model that characterizes hyporheic fluxes and RTDs based on measured vertical head differences. We used the model to test the relative influence of ET and seasonal flood pulses in the Everglades (FL, USA), in a manner applicable to other low-energy floodplains or broad, shallow streams. We found that over the multiyear timescale, flood pulses that drive relatively deep (∼1 m) flow paths had the dominant influence on hyporheic fluxes and residence times but that ET effects were discernible at shorter timescales (weeks to months) as a break in RTDs. Cumulative RTDs on either side of the break were generally well represented by lognormal functions, except for when ET was strong and none of the standard distributions applied to the shorter timescale. At the monthly timescale, ET increased hyporheic fluxes by 1–2 orders of magnitude; it also decreased 6 year mean residence times by 53–87%. Long, slow flow paths driven by flood pulses increased 6 year hyporheic fluxes by another 1–2 orders of magnitude, to a level comparable to that induced over the short term by shear flow in streams. Results suggest that models of intermediate-timescale processes should include at least two-storage zones with different RTDs, and that supporting field data collection occur over 3–4 years.

Florida↗

Influence of invasive submerged aquatic vegetation (E. densa) on currents and sediment transport in a freshwater tidal system

We present a field study combining measurements of vegetation density, vegetative drag, and reduction of suspended-sediment concentration (SSC) within patches of the invasive submerged aquatic plant Egeria densa . Our study was motivated by concern that sediment trapping by E. densa , which has proliferated in the Sacramento–San Joaquin Delta, is impacting marsh accretion and reducing turbidity. In the freshwater tidal Delta, E. densa occupies shallow regions, frequently along channel margins. We investigated two sites: Lindsey Slough, a muddy low-energy backwater, and the lower Mokelumne River, with stronger currents and sandy bed sediments. At the two sites biomass density, frontal area, and areal density of the submerged aquatic vegetation (SAV) were similar. Current attenuation within E. densa exceeded 90% and the vegetative drag coefficient followed , where is stem Reynolds number. The SAV reduced SSC by an average of 18% in Lindsey Slough. At Mokelumne River the reduction ranged 0–40%, with greatest trapping when discharge and SSC were elevated. This depletion of SSC decreases the transport of sediment to marshes by the same percentage, as the rising tide must pass through fringing SAV before reaching marshes. Sediment trapping in E. densa in the Delta is limited by low flux through the canopy and low settling velocity of suspended sediment (mostly flocculated mud). Sediment trapping by SAV has the potential to reduce channel SSC, but the magnitude and sign of the effect can vary with local factors including vegetative coverage and the depositional or erosional nature of the setting.

California↗

Role of stranded gas in increasing global gas supplies

This report synthesizes the findings of three regional studies in order to evaluate, at the global scale, the contribution that stranded gas resources can make to global natural gas supplies. Stranded gas, as defined for this study, is natural gas in discovered conventional gas and oil fields that is currently not commercially producible for either physical or economic reasons. The regional studies evaluated the cost of bringing the large volumes of undeveloped gas in stranded gas fields to selected markets. In particular, stranded gas fields of selected Atlantic Basin countries, north Africa, Russia, and central Asia are screened to determine whether the volumes are sufficient to meet Europe’s increasing demand for gas imports. Stranded gas fields in Russia, central Asia, Southeast Asia, and Australia are also screened to estimate development, production, and transport costs and corresponding gas volumes that could be supplied to Asian markets in China, India, Japan, and South Korea. The data and cost analysis presented here suggest that for the European market and the markets examined in Asia, the development of stranded gas provides a way to meet projected gas import demands for the 2020-to-2040 period. Although this is a reconnaissance-type appraisal, it is based on volumes of gas that are associated with individual identified fields. Individual field data were carefully examined. Some fields were not evaluated because current technology was insufficient or it appeared the gas was likely to be held off the export market. Most of the evaluated stranded gas can be produced and delivered to markets at costs comparable to historical prices. Moreover, the associated volumes of gas are sufficient to provide an interim supply while additional technologies are developed to unlock gas diffused in shale and hydrates or while countries transition to making a greater use of renewable energy sources.

Open-File Report↗

A compartmentalized solute transport model for redox zones in contaminated aquifers: 1. Theory and development

This paper, the first of two parts [see Abrams and Loague , this issue], takes the compartmentalized approach for the geochemical evolution of redox zones presented by Abrams et al . [1998] and embeds it within a solute transport framework. In this paper the compartmentalized approach is generalized to facilitate the description of its incorporation into a solute transport simulator. An equivalent formulation is developed which removes any discontinuities that may occur when switching compartments. Rate‐limited redox reactions are modeled with a modified Monod relationship that allows either the organic substrate or the electron acceptor to be the rate‐limiting reactant. Thermodynamic constraints are used to inhibit lower‐energy redox reactions from occurring under infeasible geochemical conditions without imposing equilibrium on the lower‐energy reactions. The procedure used allows any redox reaction to be simulated as being kinetically limited or thermodynamically limited, depending on local geochemical conditions. Empirical reaction inhibition methods are not needed. The sequential iteration approach (SIA), a technique which allows the number of solute transport equations to be reduced, is adopted to solve the coupled geochemical/solute transport problem. When the compartmentalized approach is embedded within the SIA, with the total analytical concentration of each component as the dependent variable in the transport equation, it is possible to reduce the number of transport equations even further than with the unmodified SIA. A one‐dimensional, coupled geochemical/solute transport simulation is presented in which redox zones evolve dynamically in time and space. The compartmentalized solute transport (COMPTRAN) model described in this paper enables the development of redox zones to be simulated under both kinetic and thermodynamic constraints. The modular design of COMPTRAN facilitates the use of many different, preexisting solute transport and geochemical codes. The companion paper [ Abrams and Loague , this issue] presents examples of the application of COMPTRAN to field‐scale problems.

Water Resources Research↗

GPS tracking data reveals daily spatio-temporal movement patterns of waterfowl

Background Spatio-temporal patterns of movement can characterize relationships between organisms and their surroundings, and address gaps in our understanding of species ecology, activity budgets, bioenergetics, and habitat resource management. Highly mobile waterfowl, which can exploit resources over large spatial extents, are excellent models to understand relationships between movements and resource usage, landscape interactions and specific habitat needs. Methods We tracked 3 species of dabbling ducks with GPS-GSM transmitters in 2015–17 to examine fine-scale movement patterns over 24 h periods (30 min interval), dividing movement pathways into temporally continuous segments and spatially contiguous patches. We quantified distances moved, area used and time allocated across the day, using linear and generalized linear mixed models. We investigated behavior through relationships between these variables. Results Movements and space-use were small, and varied by species, sex and season. Gadwall ( Mareca strepera ) generally moved least (FFDs: 0.5–0.7 km), but their larger foraging patches resulted from longer within-area movements. Pintails ( Anas acuta ) moved most, were more likely to conduct flights > 300 m, had FFDs of 0.8–1.1 km, used more segments and patches per day that they revisited more frequently, resulting in the longest daily total movements. Females and males differed only during the post-hunt season when females moved more. 23.6% of track segments were short duration (1–2 locations), approximately 1/3 more than would be expected if they occurred randomly, and were more dispersed in the landscape than longer segments. Distance moved in 30 min shortened as segment duration increased, likely reflecting phases of non-movement captured within segments. Conclusions Pacific Flyway ducks spend the majority of time using smaller foraging and resting areas than expected or previously reported, implying that foraging areas may be highly localized, and nutrients obtainable from smaller areas. Additionally, movement reductions over time demonstrates behavioral adjustments that represent divergent energetic demands, the detection of which is a key advantage of higher frequency data. Ducks likely use less energy for movement than currently predicted and management, including distribution and configuration of essential habitat, may require reconsideration. Our study illustrates how fine-scale movement data from tracking help understand and inform various other fields of research.

California↗

Recent trends in the nonfuel minerals industry of Iran

Summary In response to the recent removal of international sanctions on Iran, including the lifting of “secondary” sanctions by the United States on investment into and trade with Iran, the U.S. Geological Survey National Minerals Information Center compiled and analyzed available information on the current state of Iran’s nonfuel minerals industry. This Circular features a new map and table that identify existing mines and mineral-processing facilities and provide information on location, ownership, and capacity for metals and industrial minerals whose output levels may substantially change in the near future. Additionally, the report covers Iran’s mineral resources and reserves, official mineral production targets for 2025, and current output and share of global mineral production. Recent trends and developments in individual mineral commodities are discussed, including mineral exploration and partnerships with foreign investors. The U.S. Geological Survey estimated that Iran held globally significant reserves of feldspar (2d largest in the world), barite (5th largest), gypsum (5th largest), fluorspar (8th largest), and iron ore (10th largest). The Government of Iran claimed to also have significant reserves of chromium, copper, gold, manganese, phosphate rock, and zinc. In 2014, Iran was the second-leading producer of gypsum and the sixth-leading producer of barite, with 6.1 percent and 3.6 percent of world output, respectively. Iran was also the world’s 7th-leading producer of cement, feldspar, and fluorspar; 8th-leading producer of bentonite; 9th-leading producer of molybdenum; 11th-leading producer of iron ore; and 14th-leading producer of crude steel. The Government of Iran plans to quadruple the output of aluminum, copper cathode, direct-reduced iron, and iron ore pellets; triple that of crude steel and gold; and double that of cement, pig iron, and zinc by 2025. It also plans to double the contribution of mining and to quadruple that of mineral processing to the national economy in the next decade. In order to achieve these major goals, the construction and expansion of several mines and mineral facilities are planned or under development. Whether Iran’s annual mineral production increases as rapidly as envisioned by the Government will depend largely on the amount of foreign investment into the minerals industry; integration of modern technology into mineral facilities; and availability of energy to aluminum, copper, and steel plants at competitive prices to international investors.

Circular↗

Documentation and verification of VST2D; a model for simulating transient, Variably Saturated, coupled water-heat-solute Transport in heterogeneous, anisotropic 2-Dimensional, ground-water systems with variable fluid density

This report describes a model for simulating transient, Variably Saturated, coupled water-heatsolute Transport in heterogeneous, anisotropic, 2-Dimensional, ground-water systems with variable fluid density (VST2D). VST2D was developed to help understand the effects of natural and anthropogenic factors on quantity and quality of variably saturated ground-water systems. The model solves simultaneously for one or more dependent variables (pressure, temperature, and concentration) at nodes in a horizontal or vertical mesh using a quasi-linearized general minimum residual method. This approach enhances computational speed beyond the speed of a sequential approach. Heterogeneous and anisotropic conditions are implemented locally using individual element property descriptions. This implementation allows local principal directions to differ among elements and from the global solution domain coordinates. Boundary conditions can include time-varying pressure head (or moisture content), heat, and/or concentration; fluxes distributed along domain boundaries and/or at internal node points; and/or convective moisture, heat, and solute fluxes along the domain boundaries; and/or unit hydraulic gradient along domain boundaries. Other model features include temperature and concentration dependent density (liquid and vapor) and viscosity, sorption and/or decay of a solute, and capability to determine moisture content beyond residual to zero. These features are described in the documentation together with development of the governing equations, application of the finite-element formulation (using the Galerkin approach), solution procedure, mass and energy balance considerations, input requirements, and output options. The VST2D model was verified, and results included solutions for problems of water transport under isohaline and isothermal conditions, heat transport under isobaric and isohaline conditions, solute transport under isobaric and isothermal conditions, and coupled water-heat-solute transport. The first three problems considered in model verification were compared to either analytical or numerical solutions, whereas the coupled problem was compared to measured laboratory results for which no known analytic solutions or numerical models are available. The test results indicate the model is accurate and applicable for a wide range of conditions, including when water (liquid and vapor), heat (sensible and latent), and solute are coupled in ground-water systems. The cumulative residual errors for the coupled problem tested was less than 10–8 cubic centimeter per cubic centimeter, 10-5 moles per kilogram, and 102 calories per cubic meter for liquid water content, solute concentration and heat content, respectively. This model should be useful to hydrologists, engineers, and researchers interested in studying coupled processes associated with variably saturated transport in ground-water systems.

Water-Resources Investigations Report↗

Geophysical well log analysis of fractured granitic rocks at Atikokan, Ontario, Canada

Two boreholes, drilled to approximate depths of 750 and 1,260 m in a granitic intrusion located near Atikokan, Ontario, were studied by obtaining a full suite of conventional borehole geophysical logs. In addition, selected intervals in these boreholes were logged with a borehole acoustic televiewer that produces a high-resolution image of the borehole wall, an acoustic waveform-logging system using 34-kiloHertz magnetostrictive and 5-kiloHertz sparker sources, and a highly sensitive heat-pulse flowmeter. Emphasis was on identifying and characterizing fracture zones that represent groundwater conduits in deeper portions of the granite, and on characterizing the properties of the largest intervals of unfractured granite. Major fracture zones were indicated by correlating geophysical log anomalies detected on the suite of conventional logs (unpublished data from Atomic Energy of Canada). However, several other anomalies, were identified as mafic intrusions of approximately the same thickness as major fracture zones. Geophysical log anomalies were compared for all major fracture zones that could serve as significant groundwater conduits, and fracture zone permeability is estimated on the basis of acoustic tube-wave attenuation in these intervals. Acoustic televiewer logs obtained at depths below 1,000 m in the deeper well indicate that most of the few fractures identified on core at these depths do not remain open enough under in situ conditions to produce detectable anomalies in acoustic refraction. Flowmeter data indicate that some groundwater circulation occurs in the upper portion of both boreholes. Water in the shallower of the two holes was observed to flow at 2.0 L/min; most of this flow entered the borehole at a depth < 25 m, and no flow occurred below a depth of 100 m. Downflow at rates < 0.5 L/min was determined to enter the deeper borehole within 20 m of the surface, and to exist at various fractures down to a depth of 250 m. (Author 's abstract)

Water-Resources Investigations Report↗

Operational evapotranspiration mapping using remote sensing and weather datasets: A new parameterization for the SSEB approach

The increasing availability of multi-scale remotely sensed data and global weather datasets is allowing the estimation of evapotranspiration (ET) at multiple scales. We present a simple but robust method that uses remotely sensed thermal data and model-assimilated weather fields to produce ET for the contiguous United States (CONUS) at monthly and seasonal time scales. The method is based on the Simplified Surface Energy Balance (SSEB) model, which is now parameterized for operational applications, renamed as SSEBop. The innovative aspect of the SSEBop is that it uses predefined boundary conditions that are unique to each pixel for the "hot" and "cold" reference conditions. The SSEBop model was used for computing ET for 12 years (2000-2011) using the MODIS and Global Data Assimilation System (GDAS) data streams. SSEBop ET results compared reasonably well with monthly eddy covariance ET data explaining 64% of the observed variability across diverse ecosystems in the CONUS during 2005. Twelve annual ET anomalies (2000-2011) depicted the spatial extent and severity of the commonly known drought years in the CONUS. More research is required to improve the representation of the predefined boundary conditions in complex terrain at small spatial scales. SSEBop model was found to be a promising approach to conduct water use studies in the CONUS, with a similar opportunity in other parts of the world. The approach can also be applied with other thermal sensors such as Landsat.

Journal of the American Water Resources Associatio↗

Evaluating the potential for remote bathymetric mapping of a turbid, sand-bed river: 1. Field spectroscopy and radiative transfer modeling

Remote sensing offers an efficient means of mapping bathymetry in river systems, but this approach has been applied primarily to clear-flowing, gravel bed streams. This study used field spectroscopy and radiative transfer modeling to assess the feasibility of spectrally based depth retrieval in a sand-bed river with a higher suspended sediment concentration (SSC) and greater water turbidity. Attenuation of light within the water column was characterized by measuring the amount of downwelling radiant energy at different depths and calculating a diffuse attenuation coefficient, K d . Attenuation was strongest in blue and near-infrared bands due to scattering by suspended sediment and absorption by water, respectively. Even for red wavelengths with the lowest values of K d , only a small fraction of the incident light propagated to the bed, restricting the range of depths amenable to remote sensing. Spectra recorded above the water surface were used to establish a strong, linear relationship ( R 2 = 0.949) between flow depth and a simple band ratio; even under moderately turbid conditions, depth remained the primary control on reflectance. Constraints on depth retrieval were examined via numerical modeling of radiative transfer within the atmosphere and water column. SSC and sensor radiometric resolution limited both the maximum detectable depth and the precision of image-derived depth estimates. Thus, although field spectra indicated that the bathymetry of turbid channels could be remotely mapped, model results implied that depth retrieval in sediment-laden rivers would be limited to shallow depths (on the order of 0.5 m) and subject to a significant degree of uncertainty.

Water Resources Research↗