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Public participation GIS: a method for identifying ecosystems services

This study evaluated the use of an Internet-based public participation geographic information system (PPGIS) to identify ecosystem services in Grand County, Colorado. Specific research objectives were to examine the distribution of ecosystem services, identify the characteristics of participants in the study, explore potential relationships between ecosystem services and land use and land cover (LULC) classifications, and assess the methodological strengths and weakness of the PPGIS approach for identifying ecosystem services. Key findings include: (1) Cultural ecosystem service opportunities were easiest to identify while supporting and regulatory services most challenging, (2) participants were highly educated, knowledgeable about nature and science, and have a strong connection to the outdoors, (3) some LULC classifications were logically and spatially associated with ecosystem services, and (4) despite limitations, the PPGIS method demonstrates potential for identifying ecosystem services to augment expert judgment and to inform public or environmental policy decisions regarding land use trade-offs.

Society and Natural Resources↗

U.S. Geological Survey World Wide Web Information

The U.S. Geological Survey (USGS) invites you to explore an earth science virtual library of digital information, publications, and data. The USGS Internet World Wide Web sites offer an array of information that reflects scientific research and monitoring programs conducted in the areas of natural hazards, environmental resources, and cartography. This list provides gateways to access a cross section of the digital information on the USGS World Wide Web sites.

Fact Sheet↗

U.S. Geological Survey World Wide Web information

The U.S. Geological Survey (USGS) invites you to explore an earth science virtual library of digital information, publications, and data. The USGS Internet World Wide Web sites offer an array of information that reflects scientific research and monitoring programs conducted in the areas of natural hazards, environmental resources, and cartography. This list provides gateways to access a cross section of the digital information on the USGS World Wide Web sites.

Fact Sheet↗

Virginia and Landsat

From the shores of Jamestown and spreading north, south, and west, the lands that became the State of Virginia were some of the first in North America top experience rapid landscape change from European settlement. Imagery and data from the USGS Landsat series of satellites offer an unparalleled resource for the study, understanding, and preservation of Virginia’s land and water resources. From monitoring the health of water bodies to managing invasive species to planning for a range of climate change effects, the USGS National Land Imaging Program’s stewardship and public delivery of Landsat data have benefitted Virginians in myriad ways.

Virginia↗

New England Water Science Center—Bringing quality and reliable water science to New England

The U.S. Geological Survey (USGS) New England Water Science Center provides timely and reliable information to Federal, State, Tribal, and local stakeholders on the water resources of Connecticut, Maine, Massachusetts, New Hampshire, Rhode Island, and Vermont. This information product broadly describes the center’s research priorities and monitoring network and how its work benefits the public and environment.

Connecticut, Maine, Massachusetts, New Hampshire, ↗

Field Methods and Quality-Assurance Plan for Quality-of-Water Activities, U.S. Geological Survey, Idaho National Laboratory, Idaho

Water-quality activities conducted by the staff of the U.S. Geological Survey (USGS) Idaho National Laboratory (INL) Project Office coincide with the USGS mission of appraising the quantity and quality of the Nation's water resources. The activities are conducted in cooperation with the U.S. Department of Energy's (DOE) Idaho Operations Office. Results of the water-quality investigations are presented in various USGS publications or in refereed scientific journals. The results of the studies are highly regarded, and they are used with confidence by researchers, regulatory and managerial agencies, and interested civic groups. In its broadest sense, quality assurance refers to doing the job right the first time. It includes the functions of planning for products, review and acceptance of the products, and an audit designed to evaluate the system that produces the products. Quality control and quality assurance differ in that quality control ensures that things are done correctly given the 'state-of-the-art' technology, and quality assurance ensures that quality control is maintained within specified limits.

Open-File Report↗

U.S. Department of the Interior Climate Science Centers and U.S. Geological Survey National Climate Change and Wildlife Science Center—Annual report for 2016

Introduction 2016 was an exciting year for the Department of the Interior (DOI) Climate Science Centers (CSCs) and the U.S. Geological Survey (USGS) National Climate Change and Wildlife Science Center (NCCWSC). In recognition of our ongoing efforts to raise awareness and provide the scientific data and tools needed to address the impacts of climate change on fish, wildlife, ecosystems, and people, NCCWSC and the CSCs received an honorable mention in the first ever Climate Adaptation Leadership Award for Natural Resources sponsored by the National Fish, Wildlife, and Plant Climate Adaptation Strategy’s Joint Implementation Working Group. The recognition is a reflection of our contribution to numerous scientific workshops and publications, provision of training for students and early career professionals, and work with Tribes and indigenous communities to improve climate change resilience across the Nation. In this report, we highlight some of the activities that took place throughout the NCCWSC and CSC network in 2016.

Open-File Report↗

Hydraulic, geochemical, and thermal monitoring of an aquifer system in the vicinity of Mammoth Lakes, Mono County, California, 2015–17

Since 2014, the U.S. Geological Survey has been working in cooperation with the Bureau of Land Management, Mono County, Ormat Technologies, Inc., and the Mammoth Community Water District to design and implement a groundwater-monitoring program for the proposed Casa Diablo IV Geothermal Power Project in Long Valley Caldera, California, to characterize baseline groundwater-level, water-temperature, and water-chemistry conditions at dedicated monitoring wells and municipal supply wells. The publicly available data and the analyses provided here represent quality-assured and peer-reviewed information to help with the management of the thermal and non-thermal water resources beneath and in the vicinity of the town of Mammoth Lakes, California. The methods of data collection for continuous water levels and quarterly water-temperature profiles for two 600-foot-deep monitoring wells during 2016 through 2017 are discussed. Also discussed are the methods of water-sample collection and characterizations of the water chemistry in numerous wells in the multilayered aquifer system beneath Mammoth Lakes. Additionally, the methodology used to develop digital (mathematical) filters to remove or reduce the effects of barometric pressure and solid Earth tides on the continuous water-level records is discussed. Digitally filtered water levels for a 2017 flow test of a deep geothermal production well are described, and various aquifer responses observed during the flow test are discussed. These are further considered in a companion evaluation of potential physical and chemical influences on the water-level data collected during the flow test. The digitally filtered water-level data indicated that some hydraulic communication exists between the deep geothermal aquifer and shallow groundwater aquifer at the location of the flow test, northeast of Mammoth Lakes. Groundwater-chemistry data from three wells indicated that shallow groundwater naturally mixes with a small component of geothermal water along the northern periphery of the shallow aquifer system at Mammoth Lakes.

California↗

Ground water in Oklahoma

One of the first requisites for the intelligent planning of utilization and control of water and for the administration of laws relating to its use is data on the quantity, quality, and mode of occurrence of the available supplies. The collection, evaluation and interpretation, and publication of such data are among the primary functions of the U. S. Geological Survey, Since 1895 the Congress has made appropriations to the Survey for investigation of the water resources of the Nation. In 1929 the Congress adopted the policy of dollar-for-dollar cooperation with the States and local governmental agencies in water resources investigations of the U. S. Geological Survey, In 1937 a program of ground-water investigations was started in cooperation with the Oklahoma Geological Survey, and in 1949 this program was expanded to include cooperation with the Oklahoma Planning and Resources Board, In 1957 the State Legislature created the Oklahoma Water Resources Board as the principal State water agency and it became the principal local cooperator.

Oklahoma↗

Geochemical data for stream-sediment, heavy-mineral-concentrate, and rock samples collected from the Fortyseven Creek gold-arsenic-antimony-tungsten prospect, southwestern Alaska

In the summer of 1991, we conducted a reconnaissance geochemical survey around the Fortyseven Creek Au-As-Sb-W prospect that is located in the southwestern part of the Sleetmute quadrangle. At that time, this project was a small part of a more comprehensive Alaska Mineral Resource Assessment Program (AMRAP) study of the Sleemute quadrangle. AMRAP studies were conducted by the U.S. Geological Survey (USGS) to fulfill requirements of the Alaska National Interests Lands Conservation Act (Public Law 96-487, 1980) to survey certain federal lands to determine their mineral potential. Although AMRAP is no longer in operation, this study represents a small topical study that was conducted during the Sleetmute quadrangle AMRAP study. The objective of the Fortyseven Creek work was to characterize the geochemistry of samples collected downstream from the Fortyseven Creek prospect, as well as mineralized and altered rock samples collected from the prospect. In this report, we describe the samples collected in 1991, the methods used for the analysis of the samples, and the geochemical data for these samples. The data in this report are also available in digital form on computer diskette in Gray and others (1999). An interpretation of these data appears in Gray and others (1998).

Alaska↗

Characterization of salinity loads and selenium loads in the Smith Fork Creek region of the Lower Gunnison River Basin, western Colorado, 2008-2009

The lower Gunnison River Basin of the Colorado River Basin has elevated salinity and selenium levels. The Colorado River Basin Salinity Control Act of June 24, 1974 (Public Law 93–320, amended by Public Law 98–569), authorized investigation of the Lower Gunnison Basin Unit Salinity Control Project by the U.S. Department of the Interior. The Bureau of Reclamation (Reclamation) and the Natural Resources Conservation Service are responsible for assessing and implementing measures to reduce salinity and selenium loading in the Colorado River Basin. Cost-sharing programs help farmers, ranchers, and canal companies improve the efficiency of water delivery systems and irrigation practices. The delivery systems (irrigation canals) have been identified as potential sources of seepage, which can contribute to salinity loading. Reclamation wants to identify seepage from irrigation systems in order to maximize the effectiveness of the various salinity-control methods, such as polyacrylamide lining and piping of irrigation canals programs. The U.S. Geological Survey, in cooperation with Reclamation, developed a study to characterize the salinity and selenium loading of seven subbasins in the Smith Fork Creek region and identify where control efforts can be maximized to reduce salinity and selenium loading. Total salinity loads ranged from 27.9±19.1 tons per year (t/yr) to 87,500±80,500 t/yr. The four natural subbasins—BkKm, RCG1, RCG2, and SF1—had total salinity loads of 27.9±19.1 t/yr, 371±248 t/yr, 2,180±1,590 t/yr, and 4,200±2,720 t/yr, respectively. The agriculturally influenced sites had salinity loads that ranged from 7,580±6,900 t/yr to 87,500±80,500 t/yr. Salinity loads for the subbasins AL1, B1, CK1, SF2, and SF3 were 7,580±6,900 t/yr; 28,300±26,700 t/yr; 48,700±36,100 t/yr; 87,500±80,900 t/yr; and 52,200±31,800 t/yr, respectively. The agricultural salinity load was separated into three components: tail water, deep percolation, and canal seepage. Annual tail-water salinity loads ranged from 48.0 to 2,750 tons in the Smith Fork Creek region. The largest tail-water salinity load was in subbasin SF3, and the lowest salinity load from tail water was in subbasin R1. The remaining four agricultural subbasins—AL1, B1, CK1, and SF2—had tail-water loads of 285 t/yr, 180 t/yr, 333 t/yr, and 1,700 t/yr, respectively. The deep percolation component of the agricultural salinity load ranged from 3,300 t/yr in subbasin AL1 to 51,800 t/yr in subbasin SF2. Subbasins R1, B1, CK1, and SF3 had deep percolation salinity loads of 4,940 t/yr, 15,200 t/yr, 21,200 t/yr, and 23,600 t/yr, respectively. The canal seepage component of the agricultural salinity load ranged from 1,100 t/yr in subbasin AL1 to 15,300 t/yr in subbasin CK1. Subbasins B1, R1, SF2, and SF3 had canal seepage salinity loads of 6,610 t/yr, 3,890 t/yr, 9,430 t/yr, and 12,100 t/yr, respectively. Four natural subbasins—RCG1, RCG2, SF1, and BkKm—were used to calculate natural salinity yields for the remaining subbasins. The appropriate salinity yield was applied to the corresponding number of acres and resulted in a natural salinity load for each subbasin. The annual salinity yields for the Dakota Sandstone and Burro Canyon Formation, Mancos Shale, and crystalline geologies are 0.217 tons per acre (t/acre), 0.113 t/acre, and 0.151 t/acre, respectively. Three of the four natural subbasins had little to no selenium load based on the measured data and calculated selenium loads. Subbasins RCG1 and RCG2 had surface-water selenium loads of 0.106±0.024 pounds (lb) and 0.00 lb, respectively. Subbasin BkKm did not have an estimated surface-water selenium load because of the lack of any water-quality samples during the study period. The subbasin designated by site CK1 had the highest selenium load with 135±38.7 lb, and the next highest subbasins in decreasing order are B1, SF3, AL1, SF1, and R1 with selenium loads of 69.6±28.4 lb, 56.5±23.8 lb, 30.5±16.6 lb, 26.8±6.95 lb, and 15.6±27.7 lb, respectively.

Colorado↗

Water-quality indicators of surface-water-influenced groundwater supplies in the Ohio River alluvial aquifer of West Virginia

The U.S. Geological Survey, in cooperation with the West Virginia Department of Health and Human Resources, studied surface-water-influenced groundwater supplies in the Ohio River alluvial aquifer of West Virginia for the purpose of understanding the influence of surface water on groundwater chemistry. Public groundwater supplies obtained from these aquifers receive substantial recharge from surface-water sources and are highly susceptible to degradation from water-soluble contaminants. Water samples were collected from 4 sites in the Ohio River and 23 groundwater wells in the alluvial aquifer from June 2019 to January 2020. Surface-water influence was assessed through characterization of groundwater quality, determination of recharge sources, estimation of groundwater age, and estimation of the fraction of Ohio River water entering groundwater pumped by wells in the alluvial aquifers. Hydrogeochemical processes controlling solute concentrations in the Ohio River alluvial aquifer were evaluated with multivariate statistical analysis and identified to be primarily controlled by redox processes, input from sources of salinity, and carbonate dissolution. Meteoric recharge from the Ohio River and precipitation on the alluvium are the main sources of water entering the aquifer. The age of groundwater in the system was determined to be primarily from a modern source. Groundwater samples from every well included in this study had detections for at least one geochemical indicator of surface-water influence, and every well was determined to be susceptible and vulnerable to contamination from surface sources. Results from binary mixing models and inverse geochemical models showed that sulfate, silica, and bicarbonate concentrations predict the fraction of Ohio River water entering alluvial wells for preliminary determination of surface-water influence when compared to fractions predicted using a numerical groundwater-flow model. In the absence of extensive analytes and geochemical or groundwater modeling capabilities, preliminary assessment of the fraction of Ohio River water entering groundwater wells in the Ohio River alluvium can be estimated for most sites using a linear relation between the equivalent ratio of bicarbonate to sulfate and the fraction of water computed by the average of the three geochemical models presented in this report. This approximation of the fraction of Ohio River water, coupled with information on the hydrogeological framework and geochemical indicators of surface-water influence, may be sufficient for preliminary assessment of surface-water influence in the absence of more detailed site information or reaction-transport models.

West Virginia↗

Geohydrology of the glacial-outwash aquifer in the Baldwinsville area, Seneca River, Onondaga County, New York

Seven sheets of map data comprise this geohydrologic report. Sheet 1, surficial geology, illustrates the distribution of: open water areas; artificial fill; made land; urban land; alluvial silt and sand; alluvial sand and gravel; peat, marl, muck and clay; lake silt and/or clay; delta sand and gravel; beach sand and gravel; outwash sand and gravel; ice contact sand and ground; thick till cover bedrock; and thin till over bedrock over the Baldwinsville Area. Sheet 2, geologic sections, shows the layering of the aforementioned components below the surface layer. Sheet 3 illustrates the water infiltration of soil zone. Sheet 4 depicts the aquifer thickness. Sheet 5 illustrates the potentiometric surface, and Sheet 6 the well yield. Finally, Sheet 7 shows the land use in the region, specifically: industrial and extractive; commercial and services; transportation; farmland; forestland; residential; open public land; and water and wetlands. (Lantz-PTT)

Water-Resources Investigations Report↗

Hydrogeology and extent of saltwater intrusion of the Great Neck peninsula, Great Neck, Long Island, New York

Great Neck, a peninsula, in the northwestern part of Nassau County, N.Y., is underlain by unconsolidated deposits that form a sequence of aquifers and confining units. Seven public-supply wells have been affected by the intrusion of saltwater from the surrounding embayments (Little Neck Bay, Long Island Sound, Manhasset Bay). Fifteen observation wells were drilled in 1991–96 for the collection of hydrogeologic, geochemical, and geophysical data to delineate the subsurface geology and extent of saltwater intrusion within the peninsula. Continuous high-resolution seismic-reflection surveys in the embayments surrounding the Great Neck peninsula and the Manhasset Neck peninsula to the east were completed in 1993 and 1994. Two hydrogeologic units are newly proposed herein.the North Shore aquifer and the North Shore confining unit. The new drill-core data collected in 1991–96 indicate that the Lloyd aquifer, the Raritan confining unit, and the Magothy aquifer have been completely removed from the northern part of the peninsula by extensive glacial erosion. Water levels at selected observation wells were measured quarterly throughout the study. The results from two studies of the effects of tides on ground-water levels in 1992 and 1993 indicate that water levels at wells screened within the North Shore and Lloyd aquifers respond to tides and pumping effects, but those in the overlying upper glacial aquifer (where the water table is located) do not. Data from quarterly water-level measurements and the tidal-effect studies indicate the North Shore and Lloyd aquifers to be hydraulically connected. Offshore seismic-reflection surveys in the surrounding embayments indicate at least two glacially eroded buried valleys with subhorizontal, parallel reflectors indicative of draped bedding that is interpreted as infilling by silt and clay. The buried valleys (1) truncate the surrounding coarse-grained deposits, (2) are asymmetrical and steep sided, (3) trend northwest-southeast, (4) are 2-4 miles long and about 1 mile wide, and (5) extend to more than 200 feet below sea level. Water from six public-supply wells screened in the Magothy and upper glacial aquifers contained volatile organic compounds in concentrations above the New York State Department of Health Drinking Water Maximum Contaminant Levels, as did water from one public-supply well screened in the Lloyd aquifer, and from three observation wells screened in the upper glacial and Magothy aquifers. Four distinct wedge-shaped areas of saltwater intrusion have been delineated within the aquifers in Great Neck; three areas extend into the Lloyd and North Shore aquifers, and the fourth area extends into the upper glacial aquifer. Three other areas of saltwater intrusion also have been detected. Borehole-geophysical-logging data indicate that four of these saltwater wedges range from 20 to 125 feet in thickness and have sharp freshwater-saltwater interfaces, and that maximum chloride concentrations in 1996 ranged from 141 to 13,750 milligrams per liter. Seven public-supply wells have either been shut down or are currently being affected by saltwater intrusion.

Water-Resources Investigations Report↗

Managing state lands for wildlife

State-owned lands are a vital component of state fish and wildlife management programs because they contain valuable habitats for a diversity of wild species and often provide important public access. The Association of Fish and Wildlife Agencies (AFWA 2017) reported state agencies manage or administer approximately 188 million hectares of land, including 10 million hectares under fee title ownership with the remainder of those lands leased or licensed in conservation agreements, grazing allotments, or rights-of-ways. State agencies commonly strive to enhance wildlife habitats within their purview, but have also improved areas not directly owned by them. In total, an estimated 22,953,364 additional hectares have been improved by state fish and wildlife agencies through private landowner agreements (AFWA 2017). States also own 192,000 individual water rights and have developed at least 53,000 formal partnership agreements to conserve wildlife. Today, there are a plethora of state land categories including wildlife refuges, wildlife management areas, state forests, parks and trails, state trust lands, research and natural areas, and public fishing areas. Acquisition and/or leasing of properties to provide access for fishing and hunting are often vitally important in meeting local constituents’ desires for consumptive uses of their natural resources. However, state agencies also provide areas for forest conservation, boating, camping, hiking, rock hounding, skiing, wildlife viewing, and other nonconsumptive recreational pursuits. Lastly, states often acquire properties primarily for wildlife habitat management/conservation or to preserve areas of cultural and historic value to their citizens.

Book chapter↗

Hydrologic data for urban studies in the San Antonio, Texas, metropolitan area, 1979-80

Hydrologic investigations of urban drainage basins in Texas were begun by the U.S. Geological Survey in 1954. These studies are now in progress in Austin, Houston, and San Antonio. Studies were completed in the Fort Worth metropolitan area at the end of the 1977 water year, and in the Dallas metropolitan area at the end of the 1979 water year. The Geological Survey, in cooperation with the Texas Department of Water Resources, expanded the existing streamflow network in the San Antonio metropolitan area in May 1968 to begin urban hydrology studies in this area. In September 1968, the program was further expanded to include the collection of water-quality data. The operation and maintenance of stations 08178000, San Antonio River at San Antonio; 08178700, Salado Creek (upper station) at San Antonio; and 08178800, Sal ado Creek (lower station) at San Antonio are funded by the San Antonio River Authority in conjunction with the Texas Department of Water Resources and the U.S. Geological Survey. The operation and maintenance and collection of water-quality data at station 08178720, Lorence Creek at Thousand Oaks Blvd., San Antonio, station 08178640, West Elm Creek at San Antonio, and station 08178645, East Eln Creek at San Antonio, are funded by the Edwards Underground Water District in cooperation with the Texas Department of Water Resources and the U.S. Geological Survey. Station 08178640, West Elm Creek at San Antonio, and station 08178645, East Elm Creek at San Antonio will provide hydrologic data on similar and adjacent watersheds. The West Elm watershed is still predominately rural but is undergoing extensive urbanization in some areas. The East Elm watershed is relatively stable and undeveloped. The objectives of the San Antonio urban hydrology study are: To provide data showing the effects of various stages of urbanization on flood discharge and runoff. To provide water-quality data on surface-water runoff from floods of various magnitudes, during all seasons of the year from areas with different types of urban development. Annual publication of the San Antonio urban studies was initiated in 1969. A defination of terms related to streamflow, water quality, and other hydrologic data, as used in this report, are defined in the U.S. Geological Survey's 1979 and 1980 "Water resources data for Texas" reports.

Texas↗

Status and understanding of groundwater quality in the South Coast Range-Coastal study unit, 2008: California GAMA Priority Basin Project

Groundwater quality in the South Coast Range–Coastal (SCRC) study unit was investigated from May through November 2008 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in the Southern Coast Range hydrologic province and includes parts of Santa Barbara and San Luis Obispo Counties. The GAMA Priority Basin Project is conducted by the U.S. Geological Survey (USGS) in collaboration with the California State Water Resources Control Board and the Lawrence Livermore National Laboratory. The GAMA Priority Basin Project was designed to provide a statistically unbiased, spatially distributed assessment of untreated groundwater quality within the primary aquifer system. The primary aquifer system is defined as that part of the aquifer corresponding to the perforation interval of wells listed in the California Department of Public Health (CDPH) database for the SCRC study unit. The assessments for the SCRC study unit were based on water-quality and ancillary data collected in 2008 by the USGS from 55 wells on a spatially distributed grid, and water-quality data from the CDPH database. Two types of assessments were made: (1) status, assessment of the current quality of the groundwater resource, and (2) understanding, identification of the natural and human factors affecting groundwater quality. Water-quality and ancillary data were collected from an additional 15 wells for the understanding assessment. The assessments characterize untreated groundwater quality, not the quality of treated drinking water delivered to consumers by water purveyors. The first component of this study, the status assessment of groundwater quality, used data from samples analyzed for anthropogenic constituents such as volatile organic compounds (VOCs) and pesticides, as well as naturally occurring inorganic constituents such as major ions and trace elements. Although the status assessment applies to untreated groundwater, Federal and California regulatory and non-regulatory water-quality benchmarks that apply to drinking water are used to provide context for the results. Relative-concentrations (sample concentration divided by benchmark concentration) were used for evaluating groundwater. A relative-concentration greater than (>) 1.0 indicates a concentration greater than the benchmark and is classified as high. Inorganic constituents are classified as moderate if relative-concentrations are >0.5 and less than or equal to (≤) 1.0, or low if relative-concentrations are ≤0.5. For organic constituents, the boundary between moderate and low relative-concentrations was set at 0.1. Aquifer-scale proportion was used in the status assessment as the primary metric for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the areal percentage of the primary aquifer system with a high relative-concentration for a particular constituent or class of constituents. Moderate and low aquifer-scale proportions were defined as the areal percentage of the primary aquifer system with moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based and spatially weighted—were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. Grid-based and spatially weighted estimates were comparable for the study (within 90 percent confidence intervals). For inorganic constituents with human-health benchmarks, relative-concentrations were high for at least one constituent for 33 percent of the primary aquifer system in the SCRC study unit. Arsenic, molybdenum, and nitrate were the primary inorganic constituents with human-health benchmarks that were detected at high relative-concentrations. Inorganic constituents with aesthetic benchmarks, referred to as secondary maximum contaminant levels (SMCLs), had high relative-concentrations for 35 percent of the primary aquifer system. Iron, manganese, total dissolved solids (TDS), and sulfate were the inorganic constituents with SMCLs detected at high relative-concentrations. In contrast to inorganic constituents, organic constituents with human-health benchmarks were not detected at high relative-concentrations in the primary aquifer system in the SCRC study unit. Of the 205 organic constituents analyzed, 21 were detected—13 with human-health benchmarks. Perchloroethene (PCE) was the only VOC detected at moderate relative-concentrations. PCE, dichlorodifluoromethane (CFC-12), and chloroform were detected in more than 10 percent of the primary aquifer system. Of the two special-interest constituents, one was detected; perchlorate, which has a human-health benchmark, was detected at moderate relative-concentrations in 29 percent of the primary aquifer system and had a detection frequency of 60 percent in the SCRC study unit. The second component of this study, the understanding assessment, identified the natural and human factors that may have affected groundwater quality in the SCRC study unit by evaluating statistical correlations between water-quality constituents and potential explanatory factors. The potential explanatory factors evaluated were land use, septic tank density, well depth and depth to top-of-perforations, groundwater age, density and distance to the nearest formerly leaking underground fuel tank (LUFT), pH, and dissolved oxygen (DO) concentration. Results of the statistical evaluations were used to explain the occurrence and distribution of constituents in the study unit. DO was the primary explanatory factor influencing the concentrations of many inorganic constituents. Arsenic, iron, and manganese concentrations increased as DO concentrations decreased, consistent with patterns expected as a result of reductive dissolution of iron and (or) manganese oxides in aquifer sediments. Molybdenum concentrations increased in anoxic conditions and in oxic conditions with high pH, reflecting two mechanisms for the mobilization of molybdenum—reductive dissolution and pH-dependent desorption under oxic conditions from aquifer sediments. Nitrate concentrations decreased as DO concentrations decreased which would be consistent with degradation of nitrate under anoxic conditions (denitrification). It also is possible that nitrate concentrations decreased in relation to increasing depth and groundwater age and not as a result of denitrification. Groundwater age was another explanatory factor frequently correlated to several inorganic constituents. Iron and manganese concentrations were higher in pre-modern (water recharged before 1952) or mixed-age groundwater. This correlation is one indication that iron and manganese are from natural sources. Nitrate, TDS, and sulfate concentrations were higher in modern groundwater (water recharged since 1952) and may indicate that human activities increase concentrations of nitrate, TDS, and sulfate. Land use was a third explanatory factor frequently correlated with inorganic constituents. Nitrate, TDS, and sulfate concentrations were higher in agricultural land-use areas than in natural land-use areas, indicating that increased concentrations may be a result of agricultural practices. Organic constituents usually were detected at low relative-concentrations; therefore, statistical analyses of relations to explanatory factors usually were done for classes of constituents (for example, pesticides or solvents) as well as for selected constituents. The number of VOCs detected in a well was not correlated to any of the explanatory factors evaluated. The number of pesticide and solvent detections and PCE and CFC-12 concentrations were higher in modern groundwater than in pre-modern groundwater. PCE and CFC-12 also were positively correlated to the density of LUFTs. PCE was negatively correlated to natural land use. Chloroform concentrations were positively correlated to the density of septic systems. Perchlorate concentrations were greater in agricultural areas than in urban or natural areas. Correlation of perchlorate with DO may indicate that perchlorate biodegradation under anoxic conditions may occur. Anthropogenic sources have contributed perchlorate to groundwater in the SCRC study unit, although low levels of perchlorate may occur naturally.

California↗

Investigation of the geology and hydrology of the Coconino Plateau of northern Arizona: a project of the Arizona Rural Watershed Initiative

The water resources of the Coconino Plateau in northern Arizona are under increasing demand as a result of development. The population of this arid region continues to grow, and the number of visitors to the many national and state parks and monuments in the region has increased annually. The sustainability, protection, and maintenance of springs and seeps and associated riparian habitat on the Coconino Plateau are major issues that have broad public and governmental support. Regional stakeholders agree that an improved understanding of the regional hydrogeologic system is needed to address the concerns of water supply and ground-water sustainability. The base of information required to adequately describe the hydrogeology of the Coconino Plateau currently does not exist. Hydrogeologic data is most abundant for large population centers like Flagstaff and Sedona, but is sparse for less populated areas like Williams, Tusayan, Valle, and Cameron. There are still large parts of the Coconino Plateau for which there is no basic geologic or hydrologic information available. In order to develop a hydrogeologic framework for the Coconino Plateau, a comprehensive effort is needs to compile existent data and collect additional data to fill in data gaps and reinforce limited information. In 1999, the U.S. Geological Survey (USGS) began an assessment of the hydrogeology of the Coconino Plateau in cooperation with the Arizona Department of Water Resources (ADWR) as part of the Rural Watershed Initiative, a program established by the State of Arizona and managed by the ADWR. Assessments also are underway in the upper-middle Verde River watershed (Woodhouse and others, 2002) to the south and in the Mogollon Highlands to the southeast (Parker and Flynn, 2000). Each study has as its objectives: (1) the collection, compilation, and evaluation of all existing geologic, hydrologic, and related data pertaining to the study area and the creation of a database that is readily accessible to the public and (2) the development of an understanding of the hydrogeologic framework, which is the relation between hydrologic and geologic properties, that can be used for water-resources management purposes and that will support the development of conceptual and interpretive models that can be used to evaluate the effects of climate and water use on regional water resources.

Arizona↗