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Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from activities of man. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural fresh water. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position: of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken all together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in composition of moving water and the effects of particulate suspended material. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, most probable forms of elements and ions in solution, solubility controls, expected concentration ranges and other chemical factors. Concentrations of elements that are commonly present in amounts less than a few tens of micrograms per liter cannot always be easily explained, but present information suggests many are controlled by solubility of hydroxide or carbonate or by sorption on solid particles. Chemical analyses may be grouped and statistically evaluated by averages, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among waters, probable sources of solutes, areal water-quality regimen, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrologic parameters, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 75 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also utilized in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Activities of man may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of sea water in ground-water aquifiers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural water composition is required for rational management of water quality.

Water Supply Paper↗

Development of industrial minerals in Colorado

Technology and engineering have helped make mining safer and cleaner for both humans and the environment. Inevitably, mineral development entails costs as well as benefits. Developing a mine is an environmental, engineering, and planning challenge that must conform to many Federal, State, and local regulations. Community collaboration, creative design, and best management practices of sustainability and biodiversity can be positive indicators for the mining industry. A better understanding of aesthetics, culture, economics, geology, climate, vegetation and wildlife, topography, historical significance, and regional land planning is important in resolving land-use issues and managing mineral resources wisely. Ultimately, the consuming public makes choices about product use (including water, food, highways, housing, and thousands of other items) that influence operations of the mineral industry. Land planners, resource managers, earth scientists, designers, and public groups have a responsibility to consider sound scientific information, society's needs, and community appeals in making smart decisions concerning resource use and how complex landscapes should change. An effort to provide comprehensive geosciences data for land management agencies in central Colorado was undertaken in 2003 by scientists of the U.S. Geological Survey and the Colorado Geological Survey. This effort, the Central Colorado Assessment Project, addressed a variety of land-use issues: an understanding of the availability of industrial and metallic rocks and minerals, the geochemical and environmental effects of historic mining activity on surface water and groundwater, and the geologic controls on the availability and quality of groundwater. The USDA Forest Service and other land management agencies have the opportunity to contribute to the sustainable management of natural aggregate and other mineral resources through the identification and selective development of mineral resources and the reclamation of mines on lands that they administer. The information in this Circular will help them carry out that task.

Colorado↗

Geographic Analysis and Monitoring Program

The surface of the Earth is changing rapidly, at local, regional, national, and global scales, with significant repercussions for people, the economy, and the environment. Some changes have natural causes, such as wildland fires or hurricanes, while other changes on the land, such as resource extraction, agricultural practices, and urban growth, are human-induced processes. There are other types of changes that are a combination of natural and human-induced factors; landslides and floods, for example, are fundamentally natural processes that are often intensified or accelerated by human land use practices. Whatever their cause, land-surface changes can have profound environmental and economic impacts.

Fact Sheet↗

Assessment of undiscovered oil and gas resources of the West African Costal Province, West Africa

The West African Coastal Province along the west African coastline recently was assessed for undiscovered, technically recoverable oil, natural gas, and natural gas liquids resources as part of the U.S. Geological Survey's USGS World Oil and Gas Assessment. Using a geology-based assessment methodology, the USGS estimated mean volumes of 3.2 billion barrels of oil, 23.63 trillion cubic feet of natural gas, and 721 million barrels of natural gas liquids.

Fact Sheet↗

Records of wells and chemical analyses of ground water in Charles Mix and Douglas counties, South Dakota

The U.S. Geological Survey, in cooperation with the South Dakota Department of Environmental and Natural Resources, maintains a data base of information on water resources in the State of South Dakota. The ground-water site data for Charles Mix and Douglas Counties are presented in two tables, with the data organized by county and location. The chemical data for ground-water sites also are located in a table organized by geologic unit and location.

Open-File Report↗

Geohydrology of the North Park area, Jackson County, Colorado

Increasing population in rural and suburban areas of Colorado is causing greater reliance on ground water as a source of domestic supply. In the primarily rural area of Jackson County, for example, the number of registered water wells increased from about 100 in 1972 to about 500 in 1995. Most of the new wells were drilled after 1988 and supply water to ranches and summer homes. In Jackson County, ground water is pumped from a series of shallow alluvial aquifers along principal stream valleys and from deeper, more extensive, bedrock aquifers. In much of the area, the alluvial aquifers are thin and can be dewatered by moderate water- level declines. Knowledge of the nature and extent of the alluvial and bedrock aquifers, the sources of recharge and discharge, and the effects of ground- water withdrawal on water levels in the aquifers is vital if management of the area's water resources is to ensure continued availability of a dependable water supply.

Colorado↗

USGS Science Serves Public Health

Human health so often depends on the health of the environment and wildlife around us. The presence of naturally occurring or human environmental contaminants and the emergence of diseases transferred between animals and humans are growing concerns worldwide. The USGS is a source of natural science information vital for understanding the quantity and quality of our earth and living resources. This information improves our understanding not only of how human activities affect environmental and ecological health, but also of how the quality of our environment and wildlife in turn affects human health. USGS is taking a leadership role in providing the natural science information needed by health researchers, policy makers, and the public to safeguard public health

Fact Sheet↗

Survey of roadside alien plants in Hawai`i Volcanoes National Park and adjacent residential areas 2001-2005

The sides of all paved roads of Hawai`i Volcanoes National Park (HAVO) were surveyed on foot in 2001 to 2005, and the roadside presence of 240 target invasive and potentially invasive alien plant species was recorded in mile-long increments. Buffer zones 5–10 miles (8–16 km) long along Highway 11 on either side of the Kīlauea and Kahuku Units of the park, as well as Wright Road that passed by the disjunct `Ōla`a Tract Unit, were included in the survey. Highway 11 is the primary road through the park and a major island thoroughfare. Three residential subdivisions adjacent to the park were similarly surveyed in 0.5–1 mile (0.8–1.6 km) intervals in 2003, and data were analyzed separately. Two roads to the east and northeast were also surveyed, but data from these disjunct areas were analyzed separately from park roads. In total, 174 of the target alien species were observed along HAVO roads and buffers, exclusive of residential areas, and the mean number of target aliens per mile surveyed was 20.6. Highway 11 and its buffer zones had the highest mean number of target alien plants per mile (26.7) of all park roads, and the Mauna Loa Strip Road had the lowest mean (11.7). Segments of Highway 11 adjacent to HAVO and Wright Road next to `Ōla`a Tract had mean numbers of target alien per mile (24–47) higher than those of any internal road. Alien plant frequencies were summarized for each road in HAVO. Fifteen new records of vascular plants for HAVO were observed and collected along park roads. An additional 28 alien plant species not known from HAVO were observed along the buffer segments of Highway 11 adjacent to the park. Within the adjacent residential subdivisions, 65 target alien plant species were sighted along roadsides. At least 15 potentially invasive species not currently found within HAVO were observed along residential roads, and several other species found there have been previously eliminated from the park or controlled to remnant populations. Data collected from this survey can be used by the park and other landowners to help detect and manage invasive plant species that threaten the natural resources of their lands, and survey findings will inform managers of threats from alien species established along corridors beyond park boundaries. Recommendations were made for refining the list of incipient invasive plant species to search for near the park and for the repetition of periodic roadside weed surveys in the park.

Hawaii↗

Map showing general chemical quality of surface water in the Richfield Quadrangle, Utah

This is one of a series of maps that describe the geology and related natural resources of the Richfield 2° quadrangle, Utah. The purpose of this map is to show the general chemical quality of surface water in the area by ranges of dissolved-solids concentrations. Data used to compile this map were collected by the U.S. Geological Survey in cooperation with the Utah Department of Natural Resources, Division of Water Rights. In those areas where little or no surface-water-quality data are available, ranges of dissolved-solids concentrations of the water are inferred on the basis of such factors as geology (Stokes, 1964), precipitation, topography, known ground-water quality, and water uses – all of which affect the chemical quality of surface water. Additional information about the chemical quality of surface water in various parts of the Richfield 2° quadrangle may be found in the following reports: Hahl and Cabell (1965), Hahl and Mundorff (1968), Stephens (1974, 1976), Cruff and Mower (1976), and Cruff(1977)

Utah↗

Selected water-level records for Oklahoma, 1979-80

A systematic program to collect water-level records in Oklahoma began in 1937. The objectives of this program are (1) to provide long-term records of water-level fluctuations in representative wells, (2) to facilitate the prediction of water-level trends and indicate future availability of ground-water supplies, and (3) to provide information for use in basic research. Water-level data in table 1 are from wells that are measured annually, prior to the irrigation season to achieve the most natural representation of the static water level. Water level measurements listed in the column under 1979 may have been made during December 1978 or January, February, March, April, or May 1979. Measurements listed in the column 1980 may have been made during December 1979 or January, February, March, or April 1980. Figure 1 shows the counties and number of wells therein, where data were obtained for this report. Records of water levels in Oklahoma are obtained through a cooperative program by the Oklahoma Water Resources Board and the U.S. Geological Survey. The Oklahoma Water Resources Board collects water level data for all counties in the State and the records are tabulated and published by the U.S. Geological Survey on an annual basis. The stratigraphic nomenclature and age determinations used in this report are those accepted by the Oklahoma Geological Survey and do not necessarily agree with those at the U.S. Geological Survey except for the Cheyenne Sandstone which is considered to be Purgatoire Sandstone by the Oklahoma Geological Survey (Robert O. Fay, Personal Communication, August 9, 1979).

Open-File Report↗

Water resources data for New Mexico, water year 1968; Part 1. Surface water records

The surface-water records for the 1968 water year for gaging stations, partial record stations, and miscellaneous sites within the State of New Mexico are given in this report. For convenience there are also included records for a few pertinent gaging stations in bordering States. The records were collected and computed by the Water Resources Division of the U. S. Geological Survey, under the direction of W. E. Hale, District Chief, Water Resources Division. This report is the eighth in a series presenting, annually, basic data on surfacewater records by States. Through September 30, 1960, "the records of discharge and stage of streams and contents and stage of lakes or reservoirs were published in an annual series of U. S. Geological Survey water-supply papers entitled "Surface Water Supply of the United States.!! Since 1951 there have been 20 volumes in the series; each volume covered an area whose boundaries coincided with those of certain natural drainage areas. The records in New Mexico were contained in Parts 7, 8, and 9 of that series. Beginning with the 1961 water year, streamflow records and related data have been released by the Geological Survey in annual reports on a State-boundary basis. Distribution of these basic-data reports is limited and primarily for local needs. The records will be published in Geological Survey water-supply papers at 5-year intervals. These 5-year water-supply papers will show daily discharge and will be compiled on the same geographical areas previously used for the annual series; however, some of the 14 parts of conterminous United States will be further subdivided.

New Mexico↗

Ground water in the Cuyama Valley, California

This is the fourth of a series of interpretive reports on the water resources of the major valleys of Santa Barbara County, Calif., prepared by the Geological Survey, United States Department of the Interior, in cooperation with Santa Barbara County. The first three reports described the other major valleys in the county: the south-coast basins, Goleta and Carpinteria, and the Santa Maria and Santa Ynez River valleys. This report deals with the Cuyama Valley in the northeastern part of the county and adjoining parts of San Luis Obispo, Kern, and Ventura Counties. It includes estimates of natural discharge, pumpage, and yield of ground water, and all data on water levels, well records, and water quality that were available up to June 1946.

California↗

Results of a modeling workshop concerning economic and environmental trends and concomitant resource management issues in the Mobile Bay area

During the past decade, the southern regions of the U.S. have experienced rapid change which is expected to continue into the foreseeable future. Growth in population, industry, and resource development has been attributed to a variety of advantages such as an abundant and inexpensive labor force, a mild climate, and the availability of energy, water, land, and other natural resources. While this growth has many benefits for the region, it also creates the potential for increased air, water, and solid waste pollution, and modification of natural habitats. A workshop was convened to consider the Mobile Bay area as a site-specific case of growth and its environmental consequences in the southern region. The objectives of the modeling workshop were to: (1) identify major factors of economic development as they relate to growth in the area over the immediate and longer term; (2) identify major environmental and resource management issues associated with this expected growth; and (3) identify and characterize the complex interrelationships among economic and environmental factors. This report summarizes the activities and results of a modeling workshop concerning economic growth and concomitant resource management issues in the Mobile Bay area. The workshop was organized around construction of a simulation model representing the relationships between a series of actions and indicators identified by participants. The workshop model had five major components. An Industry Submodel generated scenarios of growth in several industrial and transportation sectors. A Human Population/Economy Submodel calculated human population and economic variables in response to employment opportunities. A Land Use/Air Quality Submodel tabulated changes in land use, shoreline use, and air quality. A Water Submodel calculated indicators of water quality and quantity for fresh surface water, ground water, and Mobile Bay based on discharge information provided by the Industry and Human Population/Economy Submodels. Finally, a Fish Submodel calculated indicators of habitat quality for finfish and shellfish, utilizing information on water quality and wetlands acreage. The workshop was successful in identifying many of the critical interrelations between components of the Mobile area system. Not all of those interactions, such as the feedback of air quality as a limitation on development, could be incorporated into the workshop model because of the model's broad spatial scale and because of uncertainties or data gaps. Thus, the value of the modeling workshop was in the areas outlines below, rather than in the predictive power of the initial model developed at the workshop. First, participants developed a holistic perspective on the interactions which will determine future economic and environmental trends within the Mobile Bay area. Potential environmental consequences and limitations to grown identified at the workshop included: shoreline and water access; water quality of Mobile Bay; finfish and shellfish habitat quality with respect to dissolved oxygen and coliforms; air quality; and acreage of critical wetland habitat. Second, the model's requirements for specific, quantitative information stimulated supporting analyses, such as economic input-output calculations, which provide additional insight into the Mobile Bay area system. Third, the perspective of the Mobile area as an interacting system was developed in an open, cooperative forum which my provide a foundation for conflict resolution based on common understanding. Finally, the identification of model limitations and uncertainties should be useful in guiding the efficient allocation of future research effort.

Alabama↗

Streamflow and sediment dynamics of the Middle Rio Grande Valley, New Mexico, in the context of cottonwood recruitment

The cottonwood gallery forests of the Middle Rio Grande floodplain in New Mexico provide important habitats for birds and other animals. Over the last century, these forests have changed significantly due to invasion of exotics such as salt cedar and Russian olive, which compete with native cottonwoods, and changes in water use both in the valley and upstream. To successfully germinate and establish, cottonwoods require an adequate water supply, abundant sunlight, and bare, litter-free substrate. Native cottonwoods are adapted to a natural snowmelt hydrograph characterized by spring floods in late May or early June and gradually receding streamflows throughout the remainder of the summer. The natural streamflow pattern has been significantly modified by water management in the Rio Grande basin. The modified pattern is less conducive to establishment of cottonwoods than the natural pattern. In addition, exotic species now compete with native cottonwoods, and the modified flow pattern may favor these exotics. The overall objective of this study was to investigate the possibility of enhancing cottonwood establishment and recruitment along the Middle Rio Grande through streamflow manipulation and reservoir releases. The work integrates concepts of cottonwood establishment, water resources management, and river morphology, and investigates how water management might be used to preserve and enhance cottonwood gallery forests along the river. Specific objectives of the work reported herein were to: (1) develop a technique to calculate flows that will produce channel characteristics necessary to restore and sustain cottonwood gallery forests; (2) develop a model to determine a flow pattern, or sequence of flows, that will improve the potential for cottonwood establishment and recruitment; and (3) determine if the water resources can be managed to produce the desired channel characteristics and flow pattern identified in (1) and (2).

Report↗

James Tributary summary: A summary of trends in tidal water quality and associated factors, 1985-2021

The James Tributary Summary outlines change over time for a suite of monitored tidal water quality parameters and associated potential drivers of those trends for the period 1985 – 2021 and provides a brief description of the current state of knowledge explaining these observed changes. Water quality parameters described include surface (above pycnocline) total nitrogen (TN), surface total phosphorus (TP), surface water temperature (WTEMP), spring and summer (June, July, August) surface chlorophyll a, summer bottom (below pycnocline) dissolved oxygen (DO) concentrations, and Secchi disk depth (a measure of water clarity). Results for annual bottom TP, bottom TN, surface ortho-phosphate (PO4), surface dissolved inorganic nitrogen (DIN), surface total suspended solids (TSS), and summer surface DO concentrations are provided in an Appendix. Drivers discussed include physiographic watershed characteristics, changes in TN, TP, and sediment loads from the watershed to tidal waters, expected effects of changing land use, and implementation of nutrient management and natural resource conservation practices. Factors internal to estuarine waters that also play a role as drivers are described including biogeochemical processes, physical forces such as wind-driven mixing of the water column and increase in rainfall intensity and volume, and biological factors such as phytoplankton biomass and the presence of submerged aquatic vegetation. Continuing to track water quality response and investigating these influencing factors are important steps to understanding water quality patterns and changes in the James River. The intended audiences for this report include, but are not limited to, 1) technical managers within jurisdictions who are looking at tidal water quality data and trying to understand why patterns are occurring, 2) local watershed organizations that are trying to understand these analyses and working to connect them to their local area(s), and 3) federal, state, and academic researchers. Figure 1 presents a conceptual model highlighting these intended audiences. Our goal is for the Tributary Summary documents to be sources of readily available background for change over time in tidal water quality observed with monitoring data. The intended purpose of the Tributary Summary documents is to help answer questions related to water quality, show how landscape factors drive water quality change over time, provide support for management decisions that may alter water quality trends and living resources conditions, and highlight where there may be information or knowledge gaps.

Virginia↗

Surface-water-quality assessment of the lower Kansas River Basin, Kansas and Nebraska: Suspended-sediment conditions, May 1987 through April 1990, and trends, 1963 through April 1990

Median suspended-sediment concentrations ranged from 100 to 110 milligrams per liter for 3 stations on the Kansas River and from 4 to 110 milligrams per liter for 10 stations on tributary streams during May 1987 through April 1990. For tributary stream stations upstream from large reservoirs, concen- trations in the 90th percentile ranged from 240 to 3,200 milligrams per liter. The larger median and 90th-percentile concentrations were associated with high-density irrigated cropland with gradual slopes and nonirrigated cropland with steeper slopes. Smaller median and 90th-percentile concentrations upstream from reservoirs were from areas of little or no row-crop cultivation or areas of substantially less-than-normal precipitation and streamflow. Suspended-sediment concentrations followed a con- sistent seasonal pattern; after accounting for the effect of flow, concentrations were typically smallest during January-February and largest during July-August. Mean annual suspended-sediment transport in the Kansas River from May 1987 through April 1990 increased in the downstream direction from 1,700,000 to 4,100,000 tons per year. Suspended-sediment yields for tributary streams ranged from 17 to 260 tons per square mile per year. Because of abnormal climatic conditions and other factors, no conclusions could be reached con- cerning relations of suspended-sediment transport or yield to natural or human factors. Only one upward and one downward trend in flow-adjusted, suspended-sediment concentrations were statistically significant. The trend-test results could not be explained by data on cropland removed from production or the effect of detention structures.

Kansas, Nebraska↗

Magnitude and frequency of floods in the Suwannee River Water Management District, Florida

Flood-frequency statistics for 2-, 5-, 10-, 25-, 50-. 100-, 200-, and 500-year recurrence intervals, based on three methods of analysis, are presented for 25 continuous-record and seven peak flow partial-record gaging stations in the Suwannee River Water Management District. The first method, for gaged stations, utilizes station records; the second method, for ungaged sites, utilizes regional regression analysis; and the third method uses a weighted combination of the station and regional values. Because the weighted values utilize two more or less independent estimates of the peak flow statistic, they are considered more accurate than the station estimates or the regression estimates alone. Also, the use of another weighting scheme to improve estimates of flood frequency statistics at ungaged sites is demonstrated. The karstic nature of much of the Suwannee River Water Management District significantly attenuates flood peaks in some streams by providing substantial subsurface storage when river stages are high. At such times, springs discharging into rivers may reverse flow temporarily and become sinks.

Florida↗

Copper avoidance and mortality of juvenile brown trout ( Salmo trutta ) in tests with copper-sulfate-treated water from West Branch Reservoir, Putnam County, New York

Copper-avoidance tests and acute-toxicity (mortality) tests on hatchery-reared, young-of- the-year brown trout ( salmo trutta ) were conducted with water from West Branch Reservoir to assess the avoidance response to copper sulfate treatment, which is used occasionally by New York City Department of Environmental Protection to decrease phytoplankton populations in the reservoir. Avoidance-test results indicate that juvenile brown trout tend to avoid dissolved copper concentrations greater than about 55 μg/L (micrograms per liter), which is the approximate avoidance-response threshold. The mean net avoidance response of brown trout to dissolved copper concentrations of 70 and 100 μg/L, and possibly 80 μg/L, was significantly different (at α= 0.1) from the mean net avoidance response of fish to control (untreated) water and to treated water at most other tested concentrations. Mortality-test results indicate that the 96-hr median lethal concentration (LC 50 ) of dissolved copper was 61.5 μg/L. All (100 percent) of the brown trout died at a dissolved copper concentration of 85 μg/L, many died at concentrations of 62 μg/L and 70 μg/L, and none died in the control waters (7 μg/L) or at concentrations of 10, 20, or 45 μg/L. The estimated concentration of dissolved copper that caused fish mortality (threshold) was 53.5 μg/L, virtually equivalent to the avoidance-response threshold. Additional factors that could affect the copper-avoidance and mortality response of individual brown trout and their populations in West Branch Reservoir include seasonal variations in certain water-quality parameters, copper-treatment regimes, natural fish distributions during treatment, and increased tolerance due to acclimation. These warrant additional study before the findings from this study can be used to predict the effects that copper sulfate treatments have on resident fish populations in New York City reservoirs.

New York↗