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At least 1,549 records · Page 86Linked to original sources
USGS1984

Stable isotope geochemistry of acid mine drainage: Experimental oxidation of pyrite

Sulfate and water from experiments in which pyrite was oxidized at a pH of 2.0 were analyzed for sulfur and oxygen stable isotopes. Experiments were conducted under both aerobic and anaerobic sterile conditions, as well as under aerobic conditions in the presence of Thiobacillus ferrooxidans, to elucidate the pathways of oxidation. Oxygen isotope fractionation between SO2-4 and H2O varied from +4.0 %. (anaerobic, sterile) to + 18.0 %. (aerobic, with T. ferrooxidans.). The oxygen isotope composition of dissolved oxygen utilized in both chemical and microbially-mediated oxidation was also determined (+11.4 %., by T. ferrooxidans; +18.4 %., chemical). Contributions of water-derived oxygen and dissolved oxygen to the sulfate produced in the oxidation of pyrite could thus be estimated. Water-derived oxygen constituted from 23 to ~ 100 percent of the oxygen in the sulfate produced in the experiments, and this closely approximates the range of contribution in natural acid mine drainage. Oxidation of sulfides in anaerobic, water-saturated environments occurs primarily by chemical oxidation pathways, whereas oxidation of sulfides in well-aerated, unsaturated zone environments occurs dominantly by microbially mediated pathways.

Geochimica et Cosmochimica Acta↗
USGS1990

Mechanisms controlling Cu, Fe, Mn, and Co profiles in peat of the Filson Creek Fen, northeastern Minnesota

Filson Creek Fen, located in northeastern Minnesota, overlies a Cu-Ni sulfide deposit. A site in the fen was studied to evaluate the hydrogeochemical mechanisms governing the development of Fe, Mn, Co, and Cu profiles in the peat. At the study site, surface peat approximately 1 m thick is separated from the underlying mineralized bedrock by a 6–12 m thickness of lake and glaciofluvial sediments and till. Concentrations of Fe, Mn, Co, and Cu in peat and major elements in pore water delineate a shallow, relatively oxidized, Cu-rich zone overlying a deeper, reduced, Fe-, Mn-, and Co-rich zone within the peat. Sequential metal extractions from peat samples reveal that 40–55% of the Cu in the shallow zone is associated with organic material, whereas the remaining Cu is distributed between iron-oxide, sulfide, and residual fractions. Sixty to seventy percent of the Fe, Mn, and Co concentrated in the deeper zone occur in the residual phase. The metal profiles and associations probably result from non-steady-state input of metals and detritus into the fen during formation of the peat column. The enrichment of organic-associated Cu in the upper, oxidized zone represents a combination of Cu transported into the fen with detrital plant fragments and soluble Cu, derived from weathering of outcrop and subcrop of the mineral deposit, transported into the fen, and fixed onto organic matter in the peat. The variable stratigraphy of the peat indicates that weathering processes and surface vegetation have changed through time in the fen. The Fe, Mn, and Co maxima at the base of the peat are associated with a maximum in detrital matter content of the peat resulting from a transition between the underlying inorganic sedimentary environment to an organic sedimentary environment. The chemistry of sediments and ground water collected beneath the peat indicate that mobilization of metals from sulfide minerals in the buried mineral deposit or glacial deposits is minimal. Therefore, the primary source of Cu to the peat at the study site is outcrops and shallow subcrops of the mineral deposit adjacent to the fen.

Geochimica et Cosmochimica Acta↗
USGS1994

Uranium(VI) adsorption to ferrihydrite: Application of a surface complexation model

A study of U(VI) adsorption by ferrihydrite was conducted over a wide range of U(VI) concentrations, pH, and at two partial pressures of carbon dioxide. A two-site (strong- and weak-affinity sites, Fe s OH and Fe w OH, respectively) surface complexation model was able to describe the experimental data well over a wide range of conditions, with only one species formed with each site type: an inner-sphere, mononuclear, bidentate complex of the type (FeO 2 )UO 2 . The existence of such a surface species was supported by results of uranium EXAFS spectroscopy performed on two samples with U(VI) adsorption density in the upper range observed in this study (10 and 18% occupancy of total surface sites). Adsorption data in the alkaline pH range suggested the existence of a second surface species, modeled as a ternary surface complex with UO 2 CO 3 0 binding to a bidentate surface site. Previous surface complexation models for U(VI) adsorption have proposed surface species that are identical to the predominant aqueous species, e.g., multinuclear hydrolysis complexes or several U(VI)-carbonate complexes. The results demonstrate that the speciation of adsorbed U(VI) may be constrained by the coordination environment at the surface, giving rise to surface speciation for U(VI) that is significantly less complex than aqueous speciation.

Geochimica et Cosmochimica Acta↗
USGS1994

Cyclic variations of sulfur isotopes in Cambrian stratabound Ni-Mo-(PGE-Au) ores of southern China

Cyclic variations of δ 34 S values over a range of at least 48‰ in pyrite nodules from stratabound Ni-Mo-PGE(Au) ores of southern China are attributed to biogenic reduction of seawater sulfate in an anoxic, phosphogenic, and metallogenic basin. Cyclic introduction and mixing of normal seawater into typically stagnant basin waters led to extreme variations in δ 34 S values of aqueous sulfide species present at different times. Intermittent venting of metal-laden hydrothermal fluids into such a bacteriogenic sulfide-rich environment resulted in precipitation of metal sulfides as pseudomorphous replacements of organic debris and as sulfide sediments that record large δ 34 S CDT variations from −26 to +22‰. Apatite and silica dominated the replacement of the organic debris when metals were not being introduced into the basin. The combination of abundant organic debris, localized topographic basins for accumulation of the debris, bacterial production of sulfide species, and introduction of metal-bearing hydrothermal fluids provided the environment necessary to form these unusually rich Ni-Mo ores.

Geochimica et Cosmochimica Acta↗
USGS1963

Applications of geohydrologic concepts in geology

Subsurface water, an active agent in many geologic proceses, must be considered in interpreting geologic phenomena. Principles of the occurrence, distribution, and movement of subsurface waters are well established and readily applicable. In many interpretations in geologic literature, geohydrologic principles have been employed realistically, but in many others these principles have been either ignored or violated. Explanations of genesis of underclays and associated deposits afford some examples wherein principles of movement and activity of vadose and ground water have been ignored and others in which they have been used advantageously. Postulates stating that waters percolate downward from swamp areas do not allow for the usual movement of subsurface water in such environments. The idea that sediments were leached by vadose water after uplift satisfies the geohydrologic requirements. Weathering and solution form porous and permeable zones subjacent to unconformities in dense rocks such as carbonates and granites; this illustrates the geohydrologic and economic significance of unconformities. Examples are Mohawkian carbonate aquifers of northern Illinois and oil-bearing limestones of Mississippian age of eastern Montana. The flushing effects of meteoric water and other hydrodynamic factors active during erosion periods are important elements in the genesis and concentration of brines. Explanation of the origin and occurrence of brines must include consideration of the geohydrologic environments throughout their geologic history.

Journal of Hydrology↗
USGS1973

Karst hydrology: A review

Karst regions of the world are characterized by limestones and other soluble rocks at or near land surface that have been modified by solutional erosion. Such surface features as sinks, long dry valleys, sparse streams, and bare rock and such subsurface features as caverns, arterial solution openings leading to large springs, and a deep water table are typical of karst terranes. These features result in an uneven distribution of permeability in karst systems and surface and subsurface hydrologic conditions that require special hydrogeologic studies. Local high permeability at shallow depth in mature karst regions leads to an ecology associated with a soilless and water-scarce surface environment. Many practical problems result from this high permeability, including: (1) scarcity and poor predictability of groundwater supplies; (2) scarcity of surface-water supplies; (3) instability of the ground; (4) leakage of surface reservoirs; and (5) an unreliable waste-disposal environment. Interest in karst hydrology has increased greatly in the past decade; this interest has resulted in the international exchange of numerous published reports on local areas and on special topical karst problems. Many of these reports have been used by the authors in preparing this paper, which synthesizes results of many workers and focuses attention on: (1) the development of karst features through hydrologic processes; and (2) hydrologic systems of karst terranes.

Journal of Hydrology↗
USGS1980

Neogene sedimentation on the outer continental margin, southern Bering Sea

Neogene sedimentary rocks and sediments from sites on the outer continental margin in the southern Bering Sea and on the Alaska Peninsula are dominated by volcanic components that probably were eroded from an emergent Aleutian Ridge. A mainland continental source is subordinate. Most sediment in the marine environment was transported to the depositional sites by longshore currents, debris flows, and turbidity currents during times when sea level was near the outermost continental shelf. Fluctuations of sea level are ascribed both to worldwide glacio-eustatic effects and to regional vertical tectonics. Large drainage systems, such as the Yukon and Kuskokwim Rivers, had little direct influence on sedimentation along the continental slope and Unmak Plateau in the southern Bering Sea. Sediments from those drainage systems probably were transported to the floor of the Aleutian Basin, to the numerous shelf basins that underlie the outer continental shelf, and to the Arctic Ocean after passing through the Bering Strait. Environments of deposition at the sites along the outer continental margin have not changed significantly since the middle Miocene. The site on the Alaska Peninsula, however, is now emergent following shallow-marine and transitional sedimentation during the Neogene.

Alaska↗
USGS1988

Lacustrine varve formation through time

Studies using sediment traps in lakes reveal that the seasonal flux of sediment regulates both the composition and timing of deposition of materials that reach the bottoms of lakes. If the bottom waters of a lake are partly or totally anoxic, the seasonally deposited materials are preserved as annual groupings of laminae (varves). Common components that form individual laminae consist of allochthonous clastic material derived from the drainage basin, precipitated carbonate minerals, diatom frustules, iron-rich and manganese-rich flocs, autochthonous organic detritus, and autochthonous and allochthonous materials resuspended from the bottom. The "style" of varving has changed over geologic time, reflecting changes in biologic evolution and types of materials available. Precipitated iron-rich laminations were common in the middle Precambrian. Graded sets of clastic organic laminations persisted through the Precambrian, prior to the evolution of bioturbating benthic organisms. Glaciolacustrine varves appear to have retained their distinctive character through time. Carbonate-rich varves occurred sporadically in the Precambrian and Phanerozoic. With the exception of diatoms, major components of modern lacustrine varves were present through the Paleozoic and Mesozoic, and yet varves are rare in strata of these ages, and may have accumulated in marine to brackish-water environments. Diatoms were introduced into lacustrine systems in Early Tertiary time and are common components of varves from then on. Diatom laminae, combined with a greater chance for geologic preservation of younger lake deposits, have increased the number of geologically young occurrences of varved sediments. However, seasonal associations of modern varve components, and the processes they represent, are present in ancient deposits and provide clues to the interpretation of ancient environments.

Palaeogeography, Palaeoclimatology, Palaeoecology↗
USGS1989

Dinoflagellate species and organic facies evidence of marine transgression and regression in the atlantic coastal plain

Palynological evidence is used to date and interpret depositional environments of sediments of Campanian, Maestrichtian and early Danian ages cored in three wells from South Carolina and Georgia. The evidence is usefil for distinguishing environments which lithofacies evidence indicates a range from nonmarine to coastal to inner neritic shallow shelf. Numerous dinoflagellate species and an organic facies defined abundant amoprphous debris (amorphous debris facies) distinguish shallow shelf sediments deposited during marine transgression. The nearshore amorphous debris facies of late Campanian age consists of heterogenous assemblages dominated by Palaeohystrichophora infusorioides Deflandre or Hystrichosphaerina varians (May). The farther offshore amorphous debris facies of late early Maestrichtian to late Maestrichtian age consists of heterogenous assemblages dominated by Glaphyrocysta retiintexta (Cookson) and/or Areoligera medusettiformis (Wetzel). The larger number of dinoflagellate species in the offshore facies represents the maximum transgression detected in the investigated interval. A multiple occurrence datum defined by the combination of first appearance, klast appearances and sole occurrence of dinoflagellate species at the base of each interval distinguished by the amorphous debris facies provides the first evidence of marine transgression. Relatively small organic residues consisting of intertinite and few or no palynomorphs define the inertinite facies in nonmarine deltaic and in coastal (lagoonal, tidal flat, interdistributary bary) sediments. Dinocyt{star, open}s are absent in the nonmarine sediments and are represented by few species and few specimens in the coastal inertinite faceis. A third organic facies (vascular tissue facies) is defined by the abundance of land plant tissue. Sporomorph species, including those of the Normapolles pollen group and of pteridophyte spores, comprise a large proportion of the total palynomorph flora in the inertinite and vascular tissue facies. The vascular tissue facies occurs in the proximal prodelta and nearshore shallow shelf lithofacies of early Maestrichtian age. Baed in the sequence of organuic facies, dinoflagellate species abundance, and lithofacies in the investigated wells, the nonmarine and coastal inertinite facies was first deposited and was followed during the late Campanian by a marine trangression when the nearshore amorphous debris facies was deposited. This was followed in the early Maestrichtian by the influx of terrigenous organic matter (vascular tissue facies) in response to deltaic progradation on the shallow shelf. A marine regression occurred towards the close of the early Maestrichtian, emplacing the coastal inertinite facies. The major marine transgression occurred near the end of the early Maestrichtian, developing a farther offshore amorphous debris facies on an expanded continental shelf which persisted through the late Maestrichtian. The inertinite facies returned during marine regression in the approximate position of the Maestrichtian/Danian boudnary. ?? 1989.

Palaeogeography, Palaeoclimatology, Palaeoecology↗
USGS1992

Accuracy of post-bomb 137Cs and 14C in dating fluvial deposits

The accuracy and precision of 137Cs and 14C for dating post-1950 alluvial deposits were evaluated for deposits from known floods on two rivers in Arizona. The presence of 137Cs reliably indicates that deposition occurred after intensive above-ground nuclear testing was initiated around 1950. There was a positive correlation between the measured level of 137Cs activity and the clay content of the sediments, although 137Cs was detected even in sandy flood sediments with low clay content. 137Cs is a valuable dating tool in arid environments where organic materials for 14C or tree-ring dating are scarce and observational records are limited. The 14C activity measured in different types of fine organic detritus yielded dates within 1 to 8 yr of a 1980 flood deposit, and the accuracy was species-dependent. However, undifferentiated mixtures of fine organic materials from several post-bomb deposits of various ages repeatedly yielded dates between 1958 and 1962, and detrital charcoal yielded a date range of 1676-1939. In semiarid environments, the residence time of most types of organic debris precludes accurate annual resolution of post-bomb 14C dates. ?? 1992.

Quaternary Research↗
USGS1990

A dolomitized shelfedge hardground in the northern Gulf of Mexico

An elongated calcareous hardground occurs on the shelfedge northeast of the Mississippi Trough. High-resolution seismic reflection profiles show that the hardground is in 90-110 m of water, is 70-250 m wide, at least 2.3 km long, and of low relief (5-10 m). The hardground is composed of dolostone and coquinoid limestone, and exhibits a dead biofacies of nodular and encrusting calcium carbonate-secreting organisms that are significantly different from those forms living in the adjacent unconsolidated sediments. Cementation of the hardground substrate by primary dolomite was initiated during early diagenesis close to the sea floor and progressed by concretionary growth under an interstitial environment partially open to marine molecular fluxes. The bicarbonate necessary to form the dolomite came from an admixture of isotopically light thermogenic and sedimentary organic carbon sources and an isotopically heavier marine source. Exposed surfaces of the dolostone, which have been heavily bioeroded, are covered by an oxidized, goethite-rich, reddish-brown rind. The coquina is primarily composed of whole and fragmented mollusk shells and was deposited in a higher-energy environment than the precursor sediments of the dolostone. The hardground was preserved during the Holocene transgression because of its lithified nature and the top has been intermittently swept free of finer detritus by current action.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS1990

Variations in fluvial deposition on an alluvial plain: An example from the Tongue River Member of the Fort Union Formation (Paleocene), southeastern Powder River Basin, Wyoming, U.S.A.

The Tongue River Member of the Paleocene Fort Union Formation is an important coal-bearing sedimentary unit in the Powder River Basin of Wyoming and Montana. We studied the depositional environments of a portion of this member at three sites 20 km apart in the southeastern part of the basin. Six lithofacies are recognized that we assign to five depositional facies categorized as either channel or interchannel-wetlands environments. (1) Type A sandstone is cross stratified and occurs as lenticular bodies with concave-upward basal surfaces; these bodies are assigned to the channel facies interpreted to be the product of low-sinuosity streams. (2) Type B sandstone occurs in parallel-bedded units containing mudrock partings and fossil plant debris; these units constitute the levee facies. (3) Type C sandstone typically lacks internal structure and occurs as tabular bodies separating finer grained deposits; these bodies represent the crevasse-splay facies. (4) Gray mudrock is generally nonlaminated and contains ironstone concretions; these deposits constitute the floodplain facies. (5) Carbonaceous shale and coal are assigned to the swamp facies. We recognize two styles of stream deposition in our study area. Laterally continuous complexes of single and multistoried channel bodies occur at our middle study site and we interpret these to be the deposits of sandy braided stream systems. In the two adjacent study sites, single and multistoried channel bodies are isolated in a matrix of finer-grained interchannel sediment suggesting deposition by anastomosed streams. A depositional model for our study area contains northwest-trending braided stream systems. Avulsions of these systems created anastomosed streams that flowed into adjacent interchannel areas. We propose that during late Paleocene a broad alluvial plain existed on the southeastern flank of the Powder River Basin. The braided streams that crossed this surface were tributaries to a northward-flowing, basin-axis trunk stream that existed to the west.

Wyoming↗
USGS1992

Effect of membrane filtration artifacts on dissolved trace element concentrations

Among environment scientists, the current and almost universally accepted definition of dissolved constituents is an operational one-only those materials which pass through a 0.45-μm membrane filter are considered to be dissolved. Detailed laboratory and field studies on Fe and Al indicate that a number of factors associated with filtration, other than just pore size, can substantially alter “dissolved” trace element concentrations; these include: filter type, filter diameter, filtration method, volume of sample processed, suspended sediment concentration, suspended sediment grain-size distribution, concentration of colloids and colloidally-associated trace elements and concentration of organic matter. As such, reported filtered-water concentrations employing the same pore size filter may not be equal. Filtration artifacts may lead to the production of chemical data that indicate seasonal or annual “dissolved” chemical trends which do not reflect actual environmental conditions. Further, the development of worldwide averages for various dissolved chemical constituents, the quantification of geochemical cycles, and the determination of short- or long-term environmental chemical trends may be subject to substantial errors, due to filtration artifacts, when data from the same or multiple sources are combined. Finally, filtration effects could have a substantial impact on various regulatory requirements.

Georgia↗
USGS1981

Physical-chemical conditions of ore deposition

Ore deposits form under a wide range of physical and chemical conditions, but those precipitating from hot, aqueous fluids—i.e. the hydrothermal deposits—form generally below 700°C and at pressures of only 1 or 2 kbar or less. Natural aqueous fluids in rocks may extract metal and sulfur from a variety of rock types or may acquire them as a residual heritage from a crystallizing silicate magma. Ore-forming hydrothermal fluids never appear as hot springs (except in deep, submarine situations) because they boil, mix with surface waters, and cool, thereby losing their ore-bearing ability before reaching the surface. Mineral systems function as chemical buffers and indicators just as buffers and indicators function in a chemical laboratory. By reading the record written in the buffer/indicator assemblages of minerals one can reconstruct many aspects of the former chemical environment. By studying the record of changing conditions one may deduce information regarding the processes functioning to create the succession of chemical environments and the ore deposits they represent. The example of the OH vein at Creede, Colorado, shows a pH buffered by the K-feldspar + muscovite + quartz assemblage and the covariation of S 2 and O 2 buffered by the assemblage chlorite + pyrite + quartz. Boiling of the ore fluid led to its oxidation to hematite-bearing assemblages and simultaneously produced an intensely altered, sericitic capping over the vein in response to the condensation of vapors bearing acidic components. The solubility of metals as calculated from experimental and theoretical studies of mineral solubility appears too low by at least one or two powers of ten to explain the mineralization at Creede. In contrast to Creede where the mineral stabilities all point to a relatively consistent chemistry, the Mississippi Valley type deposits present a puzzle of conflicting chemical clues that are impossible to reconcile with any single equilibrium situation. Thus we must seriously consider metastable equilibria; those most likely involve redox disequilibrium among the sulfur species in solution and perhaps also involve organic compounds.

Physics and Chemistry of the Earth↗
USGS1984

Losses from effluent taxes and quotas under uncertainty

Recent theoretical papers by Adar and Griffin ( J. Environ. Econ. Manag. 3 , 178–188 (1976)), Fishelson ( J. Environ. Econ. Manag. 3 , 189–197 (1976)), and Weitzman ( Rev. Econ. Studies 41 , 477–491 (1974)) show that, different expected social losses arise from using effluent taxes and quotas as alternative control instruments when marginal control costs are uncertain. Key assumptions in these analyses are linear marginal cost and benefit functions and an additive error for the marginal cost function (to reflect uncertainty). In this paper, empirically derived nonlinear functions and more realistic multiplicative error terms are used to estimate expected control and damage costs and to identify (empirically) the mix of control instruments that minimizes expected losses.

Journal of Environmental Economics and Management↗
USGS1981

Aliphatic structure of humic acids; a clue to their origin

Nuclear magnetic resonance spectra (both 1 H and 13 C) of humic acids from diverse depositional environments indicate the presence of aromatic chemical structures, most likely derived from lignin of vascular plants, and complex, paraffinic structures, most likely derived from algal or microbial sources. The latter components account for a major fraction of humic acid structures in both terrestrial and aquatic environments, suggesting that algae or microbes play a large role in humification of organic remains from both systems.

Organic Geochemistry↗
USGS1990

Studies of angiospermous woods in Australian brown coal by nuclear magnetic resonance and analytical pyrolysis: new insight into early coalification

Many Tertiary coals contain abundant fossilized remains of angiosperms, which commonly dominated the ancient peat-swamp environments; modern analogs of such swamps can be found in tropical and subtropical regions of the world. Comparisons of angiospermous wood from Australian brown coal with similar wood buried in modern peat swamps of Indonesia have provided some new insights into coalification reactions. These comparisons were made by using solid-state 13 C nuclear magnetic resonance (NMR) techniques and pyrolsis-gas chromatography-mass spectrometry (py-gc-ms). These two modern techniques are especially suited for detailed structural evaluation of the complex macromolecules in coal. The earliest transformation (peatification) of organic matter in angiospermous wood is the degradation and removal of cellulosic components and the concomitant selective preservation of lignin-derived components. The angiospermous lignin that becomes enriched in wood as a result of cellulose degradation also is modified by coalification reactions; this modification, however, does not involve degradation and removal of the lignin. Rather, the early coalification process transforms the lignin phenols (guiacyl and syringyl) to eventually yield the aromatic structures typically found in brown coal. One such transformation, which is determined from NMR data, involves the cleavage of aryl-ether bonds that link guaiacyl and syringyl units in lignin, and this transformation leads to the formation of free lignin phenols. Another transformation, which is also determined from the NMR data, involves the loss of methoxyl groups, probably via demethylation, to produce catechol-like structures. Coincident with ether-cleavage and demethylation, the aromatic rings derived from lignin phenols become more carbon-substituted and cross linked, as determined by dipolar-dephasing NMR studies. This cross linking is probably responsible for preventing the lignin phenols, which are freed from the lignin macromolecule by ether cleavage, from being removed from the coal by dissolution. Pyrolysis data suggest that the syringyl units are altered more readily than are guaiacyl units, and this difference in resistance leads to an enrichment of the guaiacyl units in fossil angiospermous woods. Many of the coalification reactions noted above occur to some degree in all angiospermous fossil wood examined; however, some significant differences are observed in the degree of coalification of the fossil wood samples from the same burial depth in the brown coal. These differences indicate that the depth and duration of burial are probably not entirely responsible for the variations in degree of coalification. Different rates of degradation in peat may have contributed to the variations in the apparent degree of coalification; some woods may have been altered more rapidly at the peat stage than others. Although preliminary, this systematic study of botanically related wood in peat and coal results in a more detailed differentiation of coalification reactions than have previous investigations. The combined use of solid-state 13 C NMR and py-gc-ms has facilitated this detailed insight into the coalification of angiospermous wood.

International Journal of Coal Geology↗
USGS1995

The role of palynology in paleoecological analyses of Tertiary coals

Pollen, spores, and other plant microfossils are important constituents of Tertiary coals, both as petrographic components (the maceral sporinite) and as distinctive indicators of the nature of the depositional environment in which the coal-forming peat accumulated. Palynological analyses, which have been conducted on Tertiary coals since the 1930's, play an increasingly important role in modern paleoecological analyses of coals. Among the most important factors controlling the petrographic composition and facies characteristics of coal deposits are the types and relative abundances of plants that composed the peat. At present, wetland environments in which peat accumulates (mires) range from marshes and bogs to forested swamps; each is inhabited by distinctive plant communities. These plant communities are associated with varied conditions of climate, water depth, chemistry, and nutrient supply, and the floras can be indicative of these conditions. In the Tertiary Period, plant communities of mires were also highly diverse and specialized (especially as compared with those of the Carboniferous). The dominant species in some Paleocene mire floras were gymnosperms, but continuing a trend begun in Late Cretaceous time, angiosperms became increasingly prominent through the Tertiary. The diverse: angiosperm-dominated mire floras produced coals that vary significantly in facies and hence in quality. Such contrasts are evident in contemporaneous coals from different paleolatitudes, as well as among, coals of different ages within the Tertiary, as exemplified by selected deposits in the western United. States. The palynofloras of these coals reflect the floristic composition of the plant communities of the ancient mires.

International Journal of Coal Geology↗