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USGS2006

Sea-cave temperature measurements and amino acid geochronology of British Late Pleistocene Sea stands

‘Calibrating’ amino acid ratios with uranium-series dates requires an accurate knowledge of current mean annual temperatures (CMATs) over the region studied. To measure these, test-tube sized ‘diffusion sensors’ were emplaced for 1 year (in 1984, 1985 and 1986), both outside and inside Minchin Hole sea-cave in South Wales and Belle Hougue sea-cave in Jersey, both of which have yielded Oxygen Isotope Substage 5e uranium-series ages on speleothems. Our outside temperatures agreed with meteorological ones. Our inside temperatures were over 1°C lower. To allow for this, a mean of ‘empirical’, ‘linear’ and ‘parabolic’ epimerisation calculations suggests that ratios from molluscs inside the caves should be multiplied by over 1.1 for comparison with outside ratios. This raises Bowen et al .'s ‘Pennard’ stage ratios from inside Minchin (and Bacon) Hole up towards the ‘Unnamed’ stage ratios outside, and suggests that the Unnamed sites are also from Oxygen Isotope Substage 5e, as proposed by Proctor and Smart. The same conclusion is reached more strongly by comparisons with the ratios and temperatures inside Belle Hougue to the south, and at Eemian (assumed 5e) sites in The Netherlands, Germany and Denmark to the east. The Pennard ratios from outside sites may provide further evidence for global sea stands close to the present level later in Oxygen Isotope Stage 5.

Journal of Quaternary Science↗

USGS2012

MiniSipper: A new in situ water sampler for high-resolution, long-duration acid mine drainage monitoring

Abandoned hard-rock mines can be a significant source of acid mine drainage (AMD) and toxic metal pollution to watersheds. In Colorado, USA, abandoned mines are often located in remote, high elevation areas that are snowbound for 7–8 months of the year. The difficulty in accessing these remote sites, especially during winter, creates challenging water sampling problems and major hydrologic and toxic metal loading events are often under sampled. Currently available automated water samplers are not well suited for sampling remote snowbound areas so the U.S. Geological Survey (USGS) has developed a new water sampler, the MiniSipper, to provide long-duration, high-resolution water sampling in remote areas. The MiniSipper is a small, portable sampler that uses gas bubbles to separate up to 250 five milliliter acidified samples in a long tubing coil. The MiniSipper operates for over 8 months unattended in water under snow/ice, reduces field work costs, and greatly increases sampling resolution, especially during inaccessible times. MiniSippers were deployed in support of an U.S. Environmental Protection Agency (EPA) project evaluating acid mine drainage inputs from the Pennsylvania Mine to the Snake River watershed in Summit County, CO, USA. MiniSipper metal results agree within 10% of EPA-USGS hand collected grab sample results. Our high-resolution results reveal very strong correlations (R 2 > 0.9) between potentially toxic metals (Cd, Cu, and Zn) and specific conductivity at the Pennsylvania Mine site. The large number of samples collected by the MiniSipper over the entire water year provides a detailed look at the effects of major hydrologic events such as snowmelt runoff and rainstorms on metal loading from the Pennsylvania Mine. MiniSipper results will help guide EPA sampling strategy and remediation efforts in the Snake River watershed.

Colorado↗

USGS2018

Factors affecting mercury stable isotopic distribution in piscivorous fish of the Laurentian Great Lakes

Identifying the sources of methylmercury (MeHg) and tracing the transformations of mercury (Hg) in the aquatic food web are important components of effective strategies for managing current and legacy Hg sources. In our previous work, we measured stable isotopes of Hg (δ 202 Hg, Δ 199 Hg, and Δ 200 Hg) in the Laurentian Great Lakes and estimated source contributions of Hg to bottom sediment. Here, we identify isotopically distinct Hg signatures for Great Lakes trout ( Salvelinus namaycush ) and walleye ( Sander vitreus ), driven by both food-web and water-quality characteristics. Fish contain high values for odd-isotope mass independent fractionation (MIF) with averages ranging from 2.50 (western Lake Erie) to 6.18‰ (Lake Superior) in Δ 199 Hg. The large range in odd-MIF reflects variability in the depth of the euphotic zone, where Hg is most likely incorporated into the food web. Even-isotope MIF (Δ 200 Hg), a potential tracer for Hg from precipitation, appears both disconnected from lake sedimentary sources and comparable in fish among the five lakes. We suggest that similar to the open ocean, water-column methylation also occurs in the Great Lakes, possibly transforming recently deposited atmospheric Hg deposition. We conclude that the degree of photochemical processing of Hg is controlled by phytoplankton uptake rather than by dissolved organic carbon quantity among lakes.

Environmental Science & Technology↗

USGS2020

Shale gas development has limited effects on stream biology and geochemistry in a gradient-based, multiparameter study in Pennsylvania

The number of horizontally drilled shale oil and gas wells in the United States has increased from nearly 28,000 in 2007 to nearly 127,000 in 2017, and research has suggested the potential for the development of shale resources to affect nearby stream ecosystems. However, the ability to generalize current studies is limited by the small geographic scope as well as limited breadth and integration of measured chemical and biological indicators parameters. This study tested the hypothesis that a quantifiable, significant relationship exists between the density of oil and gas (OG) development, increasing streamwater concentrations of known geochemical tracers of OG extraction, and the composition of benthic macroinvertebrate and microbial communities. 25 headwater streams that drain lands across a gradient of shale gas development intensity were sampled. Our strategy included comprehensive measurements across multiple seasons of sampling to account for temporal variability of geochemical parameters, including known shale OG geochemical tracers, and microbial and benthic macroinvertebrate communities. No significant relationships were found between the intensity of OG development, shale OG geochemical tracers, or benthic macroinvertebrate or microbial community composition, whereas significant seasonal differences in stream chemistry were observed. These results highlight the importance of considering spatial and temporal variability in stream chemistry and biota and not only the presence of anthropogenic activities in a watershed. This comprehensive, integrated study of geochemical and biological variability of headwater streams in watersheds undergoing OG development provides a robust framework for examining the effects of energy development at a regional scale.

Pennsylvania↗

USGS2012

Development and evaluation of a boat-mounted RFID antenna for monitoring freshwater mussels

Development of radio frequency identification (RFID) technology and passive integrated transponder (PIT) tags has substantially increased the ability of researchers and managers to monitor populations of aquatic organisms. However, use of transportable RFID antenna systems (i.e., backpack-mounted) is currently limited to wadeable aquatic environments (<1.4 m water depth). We describe the design, construction, and evaluation of a boat-mounted RFID antenna to detect individually PIT-tagged benthic aquatic organisms (mussels). We evaluated the effects of tag orientation on detection distances in water with a 32-mm half-duplex PIT tag. Detection distances up to 50 cm from the antenna coils were obtained, but detection distance was dependent on tag orientation. We also evaluated detection distance of PIT tags beneath the sediment to simulate detection of burrowing mussels with 23- and 32-mm tags. In sand substrate, the maximum detection distance varied from 3.5 cm and 4.5 cm (vertical tag orientation) to 24.7 cm and 39.4 cm (45° tag orientation) for the 23- and 32-mm PIT tags, respectively. Our results suggest a 1.4-m total detection width for tagged mussels on the substrate surface by the boat-mounted antenna system regardless of tag orientation. However, burrowed mussels may require multiple passes to increase detection that would be influenced by depth, tag orientation, and tag size. Construction of the boat-mounted antenna was relatively low in cost (<500 USD) and had several advantages (less labor and time intensive, increased safety) over traditional mussel sampling techniques (diving, snorkeling) in nonwadeable habitats.

Freshwater Science↗

USGS2024

Special topic—Rapid-response instrumentation

Introduction Based on the reports of Ewert and others (2005, 2018) and Moran and others (2008), most U.S. volcanoes are currently under-monitored and are likely to remain so until the goals of the National Volcano Early Warning System are fulfilled. In addition, volcanoes determined to have low to moderate threat levels (Ewert and others 2005, 2018) could awaken suddenly and, as a result, may need to have instrumentation installed rapidly. For these reasons, equipment caches would ideally be readily available for rapid response in the event of unrest at under-monitored volcanoes or during a volcanic crisis. Given that volcanoes in Alaska and Hawai‘i are frequently active, it is likely that several U.S. volcanoes could experience unrest simultaneously, as happened in 2018, 2019, and 2020, when unrest or eruptions occurred at Great Sitkin Volcano, Alaska; Mauna Loa, Hawai‘i; Mount Cleveland, Alaska; Semisopochnoi Island, Alaska; Shishaldin Volcano, Alaska; Mount Veniaminof, Alaska, as well as the most destructive documented eruption of Kīlauea, Hawai‘i. Therefore, we recommend that sufficient numbers of seismometers, infrasound sensors, Global Navigation Satellite System (GNSS) receivers, remote cameras, gas-monitoring instruments, and airborne and ground-based remote-sensing systems be made available and placed in a state of readiness at each observatory with the capability of bringing a level-2 monitoring network to near level-4 readiness. These rapid-response caches would ideally include sufficient equipment to provide real-time data telemetry, including satellite telemetry, where available, applicable, and appropriate. Rapid-response caches would be maintained in a state of readiness so that instruments can be deployed within several hours to days. Although the primary focus of the caches would be to enable rapid increases to a volcano observatory’s real-time monitoring capabilities, not all scenarios of volcanic unrest are conducive to rapid deployment of real-time data telemetry. Non-telemetered, campaign instruments, particularly seismometers and GNSS stations, can also be deployed to aid in detection of early signs of volcanic unrest given the data can be recovered in a timely fashion. Given the geographic separation of the U.S. Geological Survey Volcano Science Center’s (VSC) four volcano observatory offices, the logistical difficulties in shipping equipment rapidly between them in response to unrest, the possible scenario that a volcano could reawaken with just hours or days of precursory unrest, and the difference in operating environments (for example, tropical Hawai‘i compared to subarctic Alaska), we recommend three rapid-response instrument caches—for Hawai‘i, Alaska, and the lower 48 States. For the lower 48 States, a single cache shared among the Cascades Volcano Observatory, Yellowstone Volcano Observatory, and the California Volcano Observatory could be warehoused in California or Washington. Although these rapid-response caches would be located at one of the observatories, they would ideally be owned and maintained by VSC, and together form a flexible VSC-wide instrument pool. To maintain continuity of monitoring capabilities, this rapid-response cache could also serve to replace instruments destroyed during an on-going eruption. However, to retain eruption-response readiness, we recommend instruments in the rapid-response cache not be permanently reallocated to an observatory’s monitoring network unless they are replaced.

Scientific Investigations Report↗

USGS2007

Multi-scale responses of vegetation to removal of horse grazing from Great Basin (USA) mountain ranges

Although free-roaming equids occur on all of the world's continents except Antarctica, very few studies (and none in the Great Basin, USA) have either investigated their grazing effects on vegetation at more than one spatial scale or compared characteristics of areas from which grazing has been removed to those of currently grazed areas. We compared characteristics of vegetation at 19 sites in nine mountain ranges of the western Great Basin; sites were either grazed by feral horses (Equus caballus) or had had horses removed for the last 10-14 years. We selected horse-occupied and horse-removed sites with similar aspect, slope, fire history, grazing pressure by cattle (minimal to none), and dominant vegetation (Artemisia tridentata). During 1997 and 1998, line-intercept transects randomly located within sites revealed that horse-removed sites exhibited 1.1-1.9 times greater shrub cover, 1.2-1.5 times greater total plant cover, 2-12 species greater plant species richness, and 1.9-2.9 times greater cover and 1.1-2.4 times greater frequency of native grasses than did horse-occupied sites. In contrast, sites with horses tended to have more grazing-resistant forbs and exotic plants. Direction and magnitude of landscape-scale results were corroborated by smaller-scale comparisons within horse-occupied sites of horse-trail transects and (randomly located) transects that characterized overall site conditions. Information-theoretic analyses that incorporated various subsets of abiotic variables suggested that presence of horses was generally a strong determinant of those vegetation-related variables that differed significantly between treatments, especially frequency and cover of grasses, but also species richness and shrub cover and frequency. In contrast, abiotic variables such as precipitation, site elevation, and soil erodibility best predicted characteristics such as forb cover, shrub frequency, and continuity of the shrub canopy. We found species richness of plants monotonically decreased across sites as grazing disturbance increased, suggesting that either the bell-shaped diversity-disturbance curve of the intermediate-disturbance hypothesis does not apply in this system or that most sites are already all on the greater-disturbance slope of the curve. In our study, numerous vegetation properties of less-grazed areas and sites differed notably from horse-grazed sites at local and landscape scales during a wetter and an average-precipitation year. ?? 2007 Springer Science+Business Media B.V.

Plant Ecology↗

USGS2007

Response of the St. Joseph River to lake level changes during the last 12,000 years in the Lake Michigan basin

The water level of the Lake Michigan basin is currently 177 m above sea level. Around 9,800 14C years B.P., the lake level in the Lake Michigan basin had dropped to its lowest level in prehistory, about 70 m above sea level. This low level (Lake Chippewa) had profound effects on the rivers flowing directly into the basin. Recent studies of the St. Joseph River indicate that the extreme low lake level rejuvenated the river, causing massive incision of up to 43 m in a valley no more than 1.6 km wide. The incision is seen 25 km upstream of the present shoreline. As lake level rose from the Chippewa low, the St. Joseph River lost competence and its estuary migrated back upstream. Floodplain and channel sediments partially refilled the recently excavated valley leaving a distinctly non-classical morphology of steep sides with a broad, flat bottom. The valley walls of the lower St. Joseph River are 12-18 m tall and borings reveal up to 30 m of infill sediment below the modern floodplain. About 3 ?? 108 m3 of sediment was removed from the St. Joseph River valley during the Chippewa phase lowstand, a massive volume, some of which likely resides in a lowstand delta approximately 30 km off-shore in Lake Michigan. The active floodplain below Niles, Michigan, is inset into an upper terrace and delta graded to the Calumet level (189 m) of Lake Chicago. In the lower portion of the terrace stratigraphy a 1.5-2.0 m thick section of clast-supported gravel marks the entry of the main St. Joseph River drainage above South Bend, Indiana, into the Lake Michigan basin. This gravel layer represents the consolidation of drainage that probably occurred during final melting out of ice-marginal kettle chains allowing stream piracy to proceed between Niles and South Bend. It is unlikely that the St. Joseph River is palimpsest upon a bedrock valley. The landform it cuts across is a glaciofluvial-deltaic feature rather than a classic unsorted moraine that would drape over pre-glacial topography. ?? 2006 Springer Science+Business Media B.V.

Journal of Paleolimnology↗

USGS2017

Tectonic evolution of the Central Andean Plateau and implications for the growth of plateaus

Current end-member models for the geodynamic evolution of orogenic plateaus predict ( a ) slow and steady rise during crustal shortening and ablative subduction (i.e., continuous removal) of the lower lithosphere or ( b ) rapid surface uplift following shortening, which is associated with punctuated removal of dense lower lithosphere and/or lower crustal flow. This review integrates results from recent studies of the modern lithospheric structure, geologic evolution, and surface uplift history of the Central Andean Plateau to evaluate the geodynamic processes involved in forming it. Comparison of the timing, magnitude, and distribution of shortening and surface uplift, in combination with other geologic evidence, highlights the pulsed nature of plateau growth. We discuss specific regions and time periods that show evidence for end-member geodynamic processes, including middle–late Miocene surface uplift of the southern Eastern Cordillera and Altiplano associated with shortening and ablative subduction, latest Oligocene–early Miocene and late Miocene–early Pliocene punctuated removal of dense lower lithosphere in the Eastern Cordillera and Altiplano, and late Miocene–early Pliocene crustal flow in the central and northern Altiplano.

Annual Review of Earth and Planetary Sciences↗

USGS2008

Benthic invertebrates and periphyton in the Elwha river basin: Current conditions and predicted response to dam removal

The impending removal of two dams on the Elwha River in Washington State offers a unique opportunity to study ecosystem restoration at a watershed scale. We examine how periphyton and benthic invertebrate assemblages vary across regulated and unregulated sections of the Elwha River and across different habitat types, and establish baseline data for tracking future changes following dam removal. We collected multiple years of data on physical habitat, water chemistry, periphyton, and benthic invertebrates from 52 sites on the Elwha River and a reference section on the Quinault River, a neighboring basin. We found that substrate in regulated river sections was coarser and less heterogeneous in size than in unregulated sections, and summer water temperature and specific conductivity higher. Periphyton biomass was also consistently higher in regulated than unregulated sections. Benthic invertebrate assemblage structure at sites above both dams was distinct from sites between and below the dams, due in large part to dominance of mayfly taxa compared to higher relative abundance of midges and non-insect taxa at downstream sites. Following dam removal, we anticipate that both periphyton and benthic invertebrate abundance and diversity will temporarily decrease between and below dams as a result of sediment released from behind the reservoirs. Over the long-term, increased floodplain heterogeneity and recolonization by anadromous fish will alter benthic invertebrate and periphyton assemblages via increases in niche diversity and inputs of marine-derived nutrients. The extended timeline predicted for Elwha River recovery and the complexities of forecasting ecological response highlights the need for more long-term assessments of dam removal and river restoration practices.

Northwest Science↗

USGS2014

Water quality monitoring protocol for wadeable streams and rivers in the Northern Great Plains Network

Preserving the national parks unimpaired for the enjoyment of future generations is a fundamental purpose of the National Park Service (NPS). To address growing concerns regarding the overall physical, chemical, and biological elements and processes of park ecosystems, the NPS implemented science-based management through “Vital Signs” monitoring in 270 national parks (NPS 2007). The Northern Great Plains Network (NGPN) is among the 32 National Park Service Networks participating in this monitoring effort. The NGPN will develop protocols over the next several years to determine the overall health or condition of resources within 13 parks located in Nebraska, North Dakota, South Dakota, and Wyoming. The NGPN identified water resources as a Vital Sign to monitor because water quality and quantity are important aspects of ecological processes that operate across multiple temporal and spatial scales. In the semi-arid region of the Northern Great Plains, surface-water resources within the NGPN are ecologically important. The 13 parks within the NGPN are diverse and vary greatly in size, visitation, and water resources. For example, the measured surface area of the Badlands National Park is about 243,000 acres, which represents nearly one-half of the combined acreage of all 13 NGPN park units; however, water resources within the park are scarce and the majority of streams are intermittent. The Badlands National Park annually hosts nearly 860,000 visitors. Mount Rushmore National Memorial also has limited water resources but hosts nearly 3 million visitors per year within its 1,278 acres. The Missouri National Recreational River contains the greatest portion of waterbodies within the NGPN, consisting of 139 rivers and streams within an areal extent of about 69,000 acres. Although water resources and acreage of the NGPN parks are varied, unifying factors among the parks include the relatively low population density within the Great Plains area and the strong emphasis on agrarian land use throughout the region. To address the diverse water quality concerns, NGPN received input from park staff and conducted pilot studies in 2009 and 2010. These factors, in combination with the NGPN budget allocations, resulted in development of the NGPN’s water quality monitoring protocol. This protocol will provide a context to aid park resource managers in their day-to-day decisions and allow the assessment of the status (current conditions) and trends (directional changes across time) of streams/rivers within selected NGPN parks. Data collected from integrating water resource monitoring, in combination with the inventory of additional Vital Signs, can be used to assess resources and to aid in sound managerial decisions by the NGPN parks. As recommended by Oakley et al. (2003), this protocol provides a narrative and the rationale for selection of streams and rivers within the NGPN that will be measured for water quality, including dissolved oxygen, pH, specific conductivity, and temperature. Standard operating procedures (SOPs) that detail the steps to collect, manage, and disseminate the NGPN water quality data are in an accompanying document. The sampling design documented in this protocol may be updated as monitoring information is collected and interpreted, and as refinement of methodologies develop through time. In addition, evaluation of data and refinement of the program may necessitate potential changes of program objectives. Changes to the NGPN water quality protocols and SOPs will be carefully documented in a revision history log.

Colorado, Montana, Nebraska, North Dakota, South D↗

USGS2013

Does calving matter? Evidence for significant submarine melt

During the summer in the northeast Pacific Ocean, the Alaska Coastal Current sweeps water with temperatures in excess of 12 °C past the mouths of glacierized fjords and bays. The extent to which these warm waters affect the mass balance of Alaskan tidewater glaciers is uncertain. Here we report hydrographic measurements made within Icy Bay, Alaska, and calculate rates of submarine melt at Yahtse Glacier, a tidewater glacier terminating in Icy Bay. We find strongly stratified water properties consistent with estuarine circulation and evidence that warm Gulf of Alaska water reaches the head of 40 km-long Icy Bay, largely unaltered. A 10–20 m layer of cold, fresh, glacially-modified water overlies warm, saline water. The saline water is observed to reach up to 10.4 °C within 1.5 km of the terminus of Yahtse Glacier. By quantifying the heat and salt deficit within the glacially-modified water, we place bounds on the rate of submarine melt. The submarine melt rate is estimated at >9 m d −1 , at least half the rate at which ice flows into the terminus region, and can plausibly account for all of the submarine terminus mass loss. Our measurements suggest that summer and fall subaerial calving is a direct response to thermal undercutting of the terminus, further demonstrating the critical role of the ocean in modulating tidewater glacier dynamics.

Alaska↗

USGS2022

Trace elements in olivine fingerprint the source of 2018 magmas and shed light on explosive-effusive eruption cycles at Kīlauea Volcano

Understanding magma genesis and the evolution of intensive parameters (temperature, pressure, composition, degree of melting) in the mantle source of highly active volcanic systems is crucial for interpreting magma supply changes over time and recognizing cyclic behavior to anticipate future volcanic behavior. Major and trace elements in olivine are commonly used to study variations in mantle lithologies and melting conditions (e.g., temperature, pressure, oxygen fugacity) affecting the mantle over time. Here, we track the temporal evolution of primary melts through the most recent cycle of explosive and effusive eruptions at Kīlauea (Hawai‘i), which spans the last ∼500 years. We report major and trace elements in olivine from the last explosive period (∼1500 – early 1820’s Keanakāko‘i Tephra) and the most recent decade of the current effusive period (2018 LERZ, 2015–2018 Pu‘u‘ō‘ō, 2008–2018 lava lake and 2020 eruption in Halema‘uma‘u). Scandium concentrations in olivine allow characterizing changes in mantle source between 1500 and 2018, and suggest that the recent (2015–2018) magma feeding the Pu‘u‘ō‘ō cone did not significantly interact with the magma that erupted in the LERZ in 2018. The evolution of olivine and melt compositions over the past 500 years is not easily reconcilable with variations in mantle potential temperature, pressure of mantle melt pooling and storage, or oxygen fugacity. Instead, Sc, Mn, and Co concentrations and Ni/Mg ratio in high forsterite (Fo >87) olivine advocate for an increase in the proportion of clinopyroxene in the mantle source associated with a slightly higher degree of partial melting from 1500 to 2018. Changes in primitive melt compositions and degrees of mantle melting may well modulate magma supply to the crust and formation-replenishment of steady or ephemeral summit reservoirs, and thereby control transitions between explosive and effusive periods at Kīlauea. Analyzing trace elements in olivine at Kīlauea and elsewhere could therefore provide important clues on subtle changes occurring at the mantle level that might herald changes in volcanic behavior.

Hawaii↗

USGS2012

Atlas of nonindigenous marine and estuarine species in the North Pacific

Executive Summary Marine and estuarine nonindigenous species (NIS) are found across the world’s oceans, and designing effective management strategies to mitigate this economic, ecological and human health threat requires a basic understanding of the existing invasion patterns at regional to global scales. However, to date, syntheses at ocean basin scales have essentially been nonexistent. To fill the gap for the North Pacific, we synthesized the distributions, invasion history, environmental tolerances, and natural history of the near-coastal nonindigenous species (NIS) reported from the member countries of the North Pacific Marine Science Organization (PICES; United States, Canada, China, Republic of Korea, Japan, and Russia). The hierarchical “Marine Ecoregions of the World” (MEOW) biogeographic schema was used as the framework for assessing species’ distributions, with the modification that we added a “region” level to differentiate eastern and western sides of oceans. The two North Pacific regions are the Northeast Pacific (NEP), which extends from the Gulf of California to the Aleutian Islands, and the Northwest Pacific (NWP), which extends from the East China Sea to the Kamchatka Shelf. To have complete coverage of the United States, we included the MEOW Hawaii Ecoregion as a separate reporting unit. To have complete coverage of Japan and China, we combined five MEOW ecoregions in southern China and Japan into the North Central-Indo Pacific (NCIP) Region. The various types of information were synthesized in a Microsoft Access database, the “PICES Nonindigenous Species Information System”, which is further described in the “User’s Guide and Metadata for the PICES Nonindigenous Species Information System” (Lee et al., 2012). The PICES database was then used to generate two-page “species profiles” that map the native and introduced distributions of each species and provide a standardized summary of its invasion history, environmental tolerances, and natural history. These species profiles form the bulk of the “Atlas of Nonindigenous Marine and Estuarine Species in the North Pacific”. A total of 747 near-coastal nonindigenous species were identified in the PICES countries, with four phyla (Arthropoda, Chordata, Mollusca, and Annelida) constituting more than 70% of these invaders. The NEP and Hawaii have similar numbers of reported nonindigenous species, 368 and 347, respectively. In comparison, the NWP has about 60% of the number of reported NIS, 208. The NCIP contains only 73 NIS, though there is limited information for these ecoregions. When evaluated at an individual MEOW ecoregion scale, the Hawaii Ecoregion was the most invaded with 347 invaders, followed by the Northern California Ecoregion, which includes the San Francisco Estuary, with 287 NIS. The most invaded ecoregion in the NWP was the Central Kuroshio Current Ecoregion, which includes Tokyo Bay, with 87 reported NIS. Eight potential reasons for this geographical discrepancy in the extent of invasion were considered. The two most important appear to be: 1) the milder temperature regimes in the NEP and Hawaii are more conducive for NWP species to invade the NEP and Hawaii than the reverse and 2) there has been a greater search effort for NIS in Hawaii and the NEP at least for certain taxonomic groups. In terms of how the NIS were transported, hull fouling was potentially the most important vector in the NEP, NWP, and Hawaii, with ballast water discharges the second most important in all three regions. Intentional stocking and aquaculture escapees were relatively more important in the NWP than the NEP or Hawaii, reflecting the extensive aquaculture in Asia. Aquaculture associated species (i.e., aquaculture hitchhikers) was relatively important in the NEP, reflecting the historical influx of invaders with the importation of Atlantic and Pacific oysters.

Report↗

USGS2021

Groundwater discharges as a source of phytoestrogens and other agriculturally derived contaminants to streams

Groundwater discharge zones in streams are important habitats for aquatic organisms. The use of discharge zones for thermal refuge and spawning by fish and other biota renders them susceptible to potential focused discharge of groundwater contamination. Currently, there is a paucity of information about discharge zones as a potential exposure pathway of chemicals to stream ecosystems. Using thermal mapping technologies to locate groundwater discharges, shallow groundwater and surface water from three rivers in the Chesapeake Bay Watershed, USA were analyzed for phytoestrogens, pesticides and their degradates, steroid hormones, sterols and bisphenol A. A Bayesian censored regression model was used to compare groundwater and surface water chemical concentrations. The most frequently detected chemicals in both ground and surface water were the phytoestrogens genistein (79%) and formononetin (55%), the herbicides metolachlor (50%) and atrazine (74%), and the sterol cholesterol (88%). There was evidence suggesting groundwater discharge zones could be a unique exposure pathway of chemicals to surface water systems, in our case, metolachlor sulfonic acid (posterior mean concentration = 150 ng/L in groundwater and 4.6 ng/L in surface water). Our study also demonstrated heterogeneity of chemical concentration in groundwater discharge zones within a stream for the phytoestrogen formononetin, the herbicides metolachlor and atrazine, and cholesterol. Results support the hypothesis that discharge zones are an important source of exposure of phytoestrogens and herbicides to aquatic organisms. To manage critical resources within the Chesapeake Bay Watershed, more work is needed to characterize exposure in discharge zones more broadly across time and space.

Delaware, Maryland, New Jersey, New York, Pennsylv↗

USGS2021

Concentrations, loads, and associated trends of nutrients entering the Sacramento-San Joaquin Delta, California

Statistical modeling of water-quality data collected at the Sacramento River at Freeport and San Joaquin River near Vernalis, California, USA, was used to examine trends in concentrations and loads of various forms of dissolved and particulate nitrogen and phosphorus that entered the Sacramento–San Joaquin River Delta (Delta) from upstream sources between 1970 and 2019. Ammonium concentrations and loads decreased at the Sacramento River site from the mid-1970s through 1990 because of the consolidation of wastewater treatment and continuously reduced from the mid-1970s to 2019 at the San Joaquin River site. Current ammonium concentrations are mostly below 4 µM (0.056 mg N L –1 ) at both sites, a concentration above which reductions in phytoplankton productivity or changes in algal species composition may occur. The Sacramento River at Freeport site is located upstream of the Sacramento Regional County Sanitation District’s treatment facility’s discharge point; nutrient water quality there is representative of upstream sources. Inorganic nitrogen (nitrate plus ammonium) concentrations and loading differed at both sites. At the Sacramento River location, concentrations decrease in the summer agricultural season, reducing the molar ratios of nitrogen to phosphorus. In contrast, inorganic nitrogen concentrations increase in the San Joaquin River during the agricultural season as a result of irrigation runoff, increasing the molar ratio of nitrogen to phosphorus. This increase suggests a possible nitrogen limitation in the northern Delta and a phosphorus limitation in the southern Delta, as indicated by the molar ratios of bioavailable nitrogen to bioavailable phosphorus. Planned upgrades to the Sacramento Regional Wastewater Treatment Plant (SRWTP) will reduce inorganic nitrogen inputs to the northern Delta. Consequently, the supply of bioavailable nitrogen throughout the upper estuary should diminish. Source modeling of nitrogen and phosphorus identifies agriculture, atmospheric deposition, and wastewater effluent as sources of total nitrogen in the Central Valley. In contrast, geologic sources, agriculture, and wastewater discharge are the primary sources of phosphorus.

California↗

USGS2019

A stratigraphic approach to inferring depositional ages from detrital geochronology data

With the increasing use of detrital geochronology data for provenance analyses, we have also developed new constraints on the age of otherwise undateable sedimentary deposits. Because a deposit can be no older than its youngest mineral constituent, the youngest defensible detrital mineral age defines the maximum depositional age of the sampled bed. Defining the youngest `defensible' age in the face of uncertainty (e.g., analytical and geological uncertainty, or sample contamination) is challenging. The current standard practice of finding multiple detrital minerals with indistinguishable ages provides confidence that a given age is not an artifact; however, we show how requiring this overlap reduces the probability of identifying the true youngest component age. Barring unusual complications, the principle of superposition dictates that sedimentary deposits must get younger upsection. This fundamental constraint can be incoporated into the analysis of depositional ages in sedimentary sections through the use of Bayesian statistics, allowing for the inference of bounded estimates of true depositional ages and uncertainties from detrital geochronology so long as some minimum age constraints are present. We present two approaches for constructing a Bayesian model of deposit ages, first solving directly for the ages of deposits with the prior constraint that the ages of units must obey stratigraphic ordering, and second describing the evolution of ages with a curve that represents the sediment accumulation rate. Using synthetic examples we highlight how this method preforms in less-than-ideal circumstances. In an example from the Magallanes Basin of Patagonia, we demonstrate how introducing other age information from the stratigraphic section (e.g., fossil assemblages or radiometric dates) and formalizing the stratigraphic context of samples provides additional constraints on and information regarding depositional ages or derived quantities (e.g., sediment accumulation rates) compared to isolated analysis of individual samples.

Frontiers in Earth Science↗

USGS2022

Seasonality of precipitation in the southwestern United States during the late Pleistocene inferred from stable isotopes in herbivore tooth enamel

The late Pleistocene was a climatically dynamic period, with abrupt shifts between cool-wet and warm-dry conditions. Increased effective precipitation supported large pluvial lakes and long-lived spring ecosystems in valleys and basins throughout the western and southwestern U.S., but the source and seasonality of the increased precipitation are debated. Increases in the proportions of C 4 /(C 4 + C 3 ) grasses in the diets of large grazers have been ascribed both to increases in summer precipitation and lower atmospheric CO 2 levels. Here we present stable carbon and oxygen isotope data from tooth enamel of late Pleistocene herbivores recovered from paleowetland deposits at Tule Spring Fossil Beds National Monument in the Las Vegas Valley of southern Nevada, as well as modern herbivores from the surrounding area. We use these data to investigate whether winter or summer precipitation was responsible for driving the relatively wet hydroclimate conditions that prevailed in the region during the late Pleistocene. We also evaluate whether late Pleistocene grass C 4 /(C 4 + C 3 ) was higher than today, and potential drivers of any changes. Tooth enamel δ 18 O values for Pleistocene Equus , Bison , and Mammuthus are generally low (average 22.0 ± 0.7‰, 2 s.e., VSMOW) compared to modern equids (27.8 ± 1.5‰), and imply lower water δ 18 O values (−16.1 ± 0.8‰) than modern precipitation (−10.5‰) or in waters present in active springs and wells in the Las Vegas Valley (−12.9‰), an area dominated by winter precipitation. In contrast, tooth enamel of Camelops (a browser) generally yielded higher δ 18 O values (23.9 ± 1.1‰), possibly suggesting drought tolerance. Mean δ 13 C values for the Pleistocene grazers (−6.6 ± 0.7‰, 2 s.e., VPDB) are considerably higher than for modern equids (−9.6 ± 0.4‰) and indicate more consumption of C 4 grass (17 ± 5%) than today (4 ± 4%). However, calculated C 4 grass consumption in the late Pleistocene is strikingly lower than the proportion of C 4 grass taxa currently present in the valley (55–60%). δ 13 C values in Camelops tooth enamel (−7.7 ± 1.0‰) are interpreted as reflecting moderate consumption (14 ± 8%) of Atriplex (saltbush), a C 4 shrub that flourishes in regions with hot, dry summers. Lower water δ 18 O values, lower abundance of C 4 grasses, and the inferred presence of Atriplex are all consistent with general circulation models for the late Pleistocene that show enhanced delivery of winter precipitation, sourced from the north Pacific, into the interior western U.S. but do not support alternative models that infer enhanced delivery of summer precipitation, sourced from the tropics. In addition, we hypothesize that dietary competition among the diverse and abundant Pleistocene fauna may have driven the grazers analyzed here to feed preferentially on C 4 grasses. Dietary partitioning, especially when combined with decreased p CO2 levels during the late Pleistocene, can explain the relatively high δ 13 C values observed in late Pleistocene grazers in the Las Vegas Valley and elsewhere in the southwestern U.S. without requiring additional summer precipitation. Pleistocene hydroclimate parameters derived from dietary and floral records may need to be reevaluated in the context of the potential effects of dietary preferences and lower p CO2 levels on the stability of C 3 vs. C 4 plants.

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