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Ground-water levels and directions of flow in Geauga County, Ohio, September 1994, and changes in ground-water levels, 1986-94

This report presents the results of a study by the U.S. Geological Survey, in cooperation with the Geauga County Planning Commission and Board of County Commissioners, to determine directions of ground-water flow and to assess differences from 1986 to 1994 in groundwater levels in the glacial deposits and Pottsville Formation, Cuyahoga Group, and the Berea Sandstone. Water levels were measured in 219 wells in Geauga County, Ohio, in September 1994. Water levels measured in January and February 1986 in 88 of the 219 wells were used for comparison. Water-level maps constructed from measurements made in September 1994 show that ground-water levels in the Pottsville Formation and the glacial deposits generally correspond to the land-surface configuration and that ground water flows from the uplands to adjacent streams and buried valleys. Ground-water flow in the Cuyahoga Group is generally downward from the Pottsville Formation to the Berea Sandstone. Directions of ground-water flow in the Berea Sandstone are toward outcrop areas at the north and east edges of Geauga County and toward subcrops beneath buried glacial valley deposits in Chardon, Chester, Munson, and Russell Townships and along the west edge of the county. A comparison of water level measurements in 1986 and 1994 indicates that water levels declined in 70 percent of the measured wells and increased in 30 percent. The change in water levels from 1986 to 1994 ranged from an increase of 13.58 feet to a decrease of 29.25 feet. Thirty percent of all water-level changes were less than 1 foot in magnitude. In nearly 80 percent of the wells, water-level changes were within the range of plus or minus 5 feet. Among the wells for which two or more historical measurements were available, the 1994 water levels in 54 percent were outside the range of water-levels observed in previous studies (only 24 percent were greater than 1 foot outside of the previously-observed range). Water-level declines of greater than 10 feet were primarily in the Cuyahoga Group and Berea Sandstone. Some factors considered in the analysis of the differences in water levels in 1986 and 1994 were changes in water use, population, and the amount of available recharge. Water level differences could not be correlated to population changes between the 1980 and 1990 censuses. A decrease in the available recharge from 1986 to 1994 may be part of the cause for the decrease in water levels observed in two-thirds of the wells in and adjacent to Geauga County. Effects of withdrawal rates due to population increase on water levels, if present, are overshadowed by the effects of annual variations in precipitation.

Ohio↗

Hydrogeology and simulation of ground-water flow in the Paluxy aquifer in the vicinity of Landfills 1 and 3, U.S. Air Force Plant 4, Fort Worth, Texas

Ground-water contamination of the surficial terrace alluvial aquifer has occurred at U.S. Air Force Plant 4, a government-owned, contractor-operated facility, northwest of Fort Worth, Texas. A poorly constructed monitoring well, P–22M, open to the underlying middle zone of the Paluxy aquifer was installed at landfill 3, October 1987, allowing leakage of contaminated ground water to reach the Paluxy aquifer. This well was plugged and abandoned in November 1995. Additionally, volatile organic compounds have been detected in fractures in the Goodland-Walnut confining unit, the hydrogeologic unit separating the terrace alluvial aquifer from the underlying Paluxy aquifer, beneath the western part of landfill 1. Volatile organic compounds in concentrations near the analytical detection limit were detected in the upper Paluxy prior to the drilling of well P–22M. The ground-water-flow simulation model described in this report was developed to examine the best logistically feasible location to install recovery wells to capture the low concentration (less than 100 micrograms per liter) trichloroethylene plume beneath landfills 1 and 3 (west Paluxy plume). Once the recovery wells were installed (1996), the simulation model was recalibrated with new data. This report documents the capture area of the installed recovery wells. Four geologic units are pertinent to this site-specific model. From oldest to youngest, these are the Glen Rose Formation, Paluxy Formation, Walnut Formation, and Goodland Limestone. The Glen Rose Formation is relatively impermeable in the study area and forms the confining unit underlying the Paluxy Formation. The Paluxy Formation forms the Paluxy aquifer, which is a public drinking water supply for the City of White Settlement. The Walnut Formation and Goodland Limestone form the Goodland-Walnut confining unit overlying the Paluxy aquifer. Near landfill 3, gamma-ray logs indicate three distinct zones of the Paluxy Formation; upper, middle, and lower. The formation is about 170-feet thick near landfill 3, and each zone is about 57-feet thick. Two steady-state simulations using the computer program MODFLOW were analyzed using the particle-tracking computer program, MODPATH. One simulation is the calibration simulation using Paluxy aquifer water-level data for May 1993. The second simulation includes the installed recovery wells. A variably spaced grid was designed for the model. The smallest grid cells, 25 by 25 feet, are in the vicinity of landfills 1 and 3. The largest cells, 4,864.5 by 1,441.5 feet, are at the northwestern corner of the model grid near the Parker-Tarrant County line. The modeling was accomplished with three layers representing the upper, middle, and lower zones of the Paluxy aquifer. Particles, which represent contaminant molecules moving in solution with the ground water, were tracked from well P–22M and an area below landfill 1, at the top of the upper zone of the Paluxy aquifer, for 9 years (forward tracking). The forward tracking estimates where contaminants might move by advection from 1987 to 1996. Analysis of backward tracking from the new recovery wells indicates that the simulated contributing area to the recovery wells intercepts the contaminant plume, minimizing off-site migration of the west Paluxy plume. To determine the effectiveness of the recovery wells, monitoring wells southeast of Building 14 have been installed (1996–97) for sampling.

Texas↗

Biodegradation of chlorinated ethenes at a karst site in middle Tennessee

This report presents results of field and laboratory investigations examining the biodegradation of chlorinated ethenes in a karst aquifer contaminated with trichloroethylene (TCE). The study site, located in Middle Tennessee, was selected because of the presence of TCE degradation byproducts in the karst aquifer and available site hydrologic and chlorinated-ethene information. Additional chemical, biological, and hydrologic data were gathered to evaluate whether the occurrence of TCE degradation byproducts in the karst aquifer was the result of biodegradation within the aquifer or simply transport into the aquifer. Geochemical analysis established that sulfate-reducing conditions, essential for reductive dechlorination of chlorinated solvents, existed in parts of the contaminated karst aquifer. Other areas of the aquifer fluctuated between anaerobic and aerobic conditions and contained compounds associated with cometabolism, such as ethane, methane, ammonia, and dissolved oxygen. A large, diverse bacteria population inhabits the contaminated aquifer. Bacteria known to biodegrade TCE and other chlorinated solvents, such as sulfate-reducers, methanotrophs, and ammonia-oxidizers, were identified from karst-aquifer water using the RNA-hybridization technique. Results from microcosms using raw karst-aquifer water found that aerobic cometabolism and anaerobic reductive-dechlorination degradation processes were possible when appropriate conditions were established in the microcosms. These chemical and biological results provide circumstantial evidence that several biodegradation processes are active in the aquifer. Additional site hydrologic information was developed to determine if appropriate conditions persist long enough in the karst aquifer for these biodegradation processes to be significant. Continuous monitoring devices placed in four wells during the spring of 1998 indicated that pH, specific conductance, dissolved oxygen, and oxidation-reduction potentials changed very little in areas isolated from active ground-water flow paths. These stable areas in the karst aquifer had geochemical conditions and bacteria conducive to reductive dechlorination of chlorinated ethenes. Other areas of the karst aquifer were associated with active ground-water flow paths and fluctuated between anaerobic and aerobic conditions in response to rain events. Associated with this dynamic environment were bacteria and geochemical conditions conducive to cometabolism. In summary, multiple lines of evidence developed from chemical, biological, and hydrologic data demonstrate that a variety of biodegradation processes are active in this karst aquifer.

Tennessee↗

Techniques for estimating peak-flow frequency relations for North Dakota streams

This report presents techniques for estimating peak-flow frequency relations for North Dakota streams. In addition, a generalized skew coefficient analysis was completed for North Dakota to test the validity of using the generalized skew coefficient map in Bulletin 17B of the Hydrology Subcommittee of the Interagency Advisory Committee on Water Data, 1982, "Guidelines for Determining Flood Flow Frequency." The analysis indicates that the generalized skew coefficient map in Bulletin 17B provides accurate estimates of generalized skew coefficient values for natural-flow streams in North Dakota. Peak-flow records through 1988 for 192 continuous- and partial-record streamflow gaging stations that had 10 or more years of record were used in a generalized least-squares regression analysis that relates peak flows for selected recurrence intervals to selected basin characteristics. Peak-flow equations were developed for recurrence intervals of 2, 10, 15, 25, 50, 100, and 500 years for three hydrologic regions in North Dakota. The peak-flow equations are applicable to natural-flow streams that have drainage areas of less than or equal to 1,000 square miles. The standard error of estimate for the three hydrologic regions ranges from 60 to 70 percent for the 100-year peak-flow equations. Methods are presented for transferring peak-flow data from gaging stations to ungaged sites on the same stream and for determining peak flows for ungaged sites on ungaged streams. Peak-flow relations, weighted estimates of peak flow, and selected basin characteristics are tabulated for the 192 gaging stations used in the generalized skew coefficient and regression analyses. Peak-flow relations also are provided for 63 additional gaging stations that were not used in the generalized skew coefficient and regression analyses. These 63 gaging stations generally represent streams that are significantly controlled by regulation and those that have drainage areas greater than 1,000 square miles.

North Dakota↗

Spatial and temporal variations in streamflow, dissolved solids, nutrients, and suspended sediment in the Rio Grande Valley study unit, Colorado, New Mexico, and Texas, 1993–95

Streamflow and water quality vary spatially and temporally in the Rio Grande from Del Norte, Colorado, to El Paso, Texas. The variations in streamflow and in concentrations of selected waterquality constituents—dissolved solids, dissolved nitrite plus nitrate as nitrogen, total phosphorus, and suspended sediment—are described in this report. A multivariate linear regression model, ESTIMATOR2000, was used to estimate loads for selected constituents. Streamflow decreases in the downstream direction throughout most of the basin because outflows (due to agricultural use, leakage to ground water, and evapotranspiration) are greater than inflows. Streamflow increases between Rio Grande above the mouth of Trinchera Creek, near Lasauses, Colorado, to Rio Grande at Otowi Bridge, near San Ildefonso, New Mexico, because ground-water and tributary inflow are greater than outflow. Concentrations of dissolved solids, dissolved nitrite plus nitrate, total phosphorus, and suspended sediment generally increase in the downstream direction. Concentrations of dissolved solids, dissolved nitrite plus nitrate, and total phosphorus decrease between Rio Grande above the mouth of Trinchera Creek, near Lasauses, Colorado, and Rio Grande at Otowi Bridge, near San Ildefonso, New Mexico, because of dilution by tributary inflow. Concentrations of dissolved nitrite plus nitrate, total phosphorus, and suspended sediment decrease between Rio Grande Floodway at San Marcial, New Mexico, and Rio Grande below Leasburg Dam, near Leasburg, New Mexico, because of reservoir effects (nutrient uptake and settling of sediment). Several instances of decreasing streamflow and increasing loads indicate the presence of inflows with large constituent concentrations (relative to those of the Rio Grande immediately upstream from that inflow); this occurs (1) between Rio Grande near Del Norte, Colorado, and Rio Grande above the mouth of Trinchera Creek, near Lasauses, Colorado, for dissolved solids, (2) between Rio Grande at Otowi Bridge, near San Ildefonso, New Mexico, and Rio Grande Floodway at San Marcial, NewMexico, for all constituents, and (3) between Rio Grande below Leasburg Dam, near Leasburg, New Mexico, and Rio Grande at El Paso, Texas, for all constituents. Streamflow increases along every reach of the Rio Grande between the streamflow-gaging station Rio Grande above the mouth of Trinchera Creek, near Lasauses, Colorado, and the station Rio Grande at Otowi Bridge, near San Ildefonso, NewMexico. These increases in streamflow result in increases in the loads of dissolved solids, total phosphorus, and suspended sediment regardless of changes in concentrations.

Water-Resources Investigations Report↗

Effects of urban flood-detention reservoirs on peak discharges and flood frequencies, and simulation of flood-detention reservoir outflow hydrographs in two watersheds in Albany, Georgia

This report describes the effects of flood-detention reservoirs on downstream peak discharges of two urban tributaries to Kinchafoonee Creek (tributaries 1 and 2) in Albany, Georgia and presents simulated flood-detention reservoir outflow hydrographs. Rainfall-runoff data were collected for six years at two stations in these two urban watersheds. Tributary number 1 basin has a drainage area of 0.12 square miles, contains 23.8 percent impervious area, and contains two detention reservoirs. Tributary number 2 basin has a drainage area of 0.09 square miles, contains 12.9 percent impervious area, and has one detention reservoir. The Distributed Routing Rainfall-Runoff Model (DR3M) was calibrated using rainfall-runoff data collected during 1987- 92 at each station. DR3M was then used to simulate long-term (1906-33, 1941-73) peak discharges for these stations for conditions ranging from the existing condition with all detention reservoirs in place to the condition of no detention reservoirs. Flood-frequency relations based on the long-term peak discharges were developed for each simulation by fitting the logarithms of the annual peak discharge data to a Pearson type III distribution curve. The effect of detention reservoirs on peak discharge data to a Pearson type III distribution curve. The effect of detention reservoirs on peak discharges was determined by comparison of simulated flood-frequency peak discharges for conditions with and without the detention reservoirs. The comparisons indicated that the removal of flood-detention reservoirs from the tributary number 1 basin would increase the 10-, 50-, and 100-year peak discharges by 164 to 204 percent. Removal of the reservoir from tributary number 2 basin would increase these discharges by about 145 percent.

Georgia↗

Ground-water discharge determined from measurements of evapotranspiration, other available hydrologic components, and shallow water-level changes, Oasis Valley, Nye County, Nevada

Oasis Valley is an area of natural ground-water discharge within the Death Valley regional ground-water flow system of southern Nevada and adjacent California. Ground water discharging at Oasis Valley is replenished from inflow derived from an extensive recharge area that includes the northwestern part of the Nevada Test Site (NTS). Because nuclear testing has introduced radionuclides into the subsurface of the NTS, the U.S. Department of Energy currently is investigating the potential transport of these radionuclides by ground water flow. To better evaluate any potential risk associated with these test-generated contaminants, a number of studies were undertaken to accurately quantify discharge from areas downgradient in the regional ground-water flow system from the NTS. This report refines the estimate of ground-water discharge from Oasis Valley. Ground-water discharge from Oasis Valley was estimated by quantifying evapotranspiration (ET), estimating subsurface outflow, and compiling ground-water withdrawal data. ET was quantified by identifying areas of ongoing ground-water ET, delineating areas of ET defined on the basis of similarities in vegetation and soil-moisture conditions, and computing ET rates for each of the delineated areas. A classification technique using spectral-reflectance characteristics determined from satellite imagery acquired in 1992 identified eight unique areas of ground-water ET. These areas encompass about 3,426 acres of sparsely to densely vegetated grassland, shrubland, wetland, and open water. Annual ET rates in Oasis Valley were computed with energy-budget methods using micrometeorological data collected at five sites. ET rates range from 0.6 foot per year in a sparse, dry saltgrass environment to 3.1 feet per year in dense meadow vegetation. Mean annual ET from Oasis Valley is estimated to be about 7,800 acre-feet. Mean annual ground-water discharge by ET from Oasis Valley, determined by removing the annual local precipitation component of 0.5 foot, is estimated to be about 6,000 acre-feet. Annual subsurface outflow from Oasis Valley into the Amargosa Desert is estimated to be between 30 and 130 acre-feet. Estimates of total annual ground-water withdrawal from Oasis Valley by municipal and non-municipal users in 1996 and 1999 are 440 acre-feet and 210 acre-feet, respectively. Based on these values, natural annual ground-water discharge from Oasis Valley is about 6,100 acre-feet. Total annual discharge was 6,500 acre-ft in 1996 and 6,300 acre-ft in 1999. This quantity of natural ground-water discharge from Oasis Valley exceeds the previous estimate made in 1962 by a factor of about 2.5. Water levels were measured in Oasis Valley to gain additional insight into the ET process. In shallow wells, water levels showed annual fluctuations as large as 7 feet and daily fluctuations as large as 0.2 foot. These fluctuations may be attributed to water loss associated with evapotranspiration. In shallow wells affected by ET, annual minimum depths to water generally occurred in winter or early spring shortly after daily ET reached minimum rates. Annual maximum depths to water generally occurred in late summer or fall shortly after daily ET reached maximum rates. The magnitude of daily water-level fluctuations generally increased as ET increased and decreased as depth to water increased.

Nevada↗

Streambed adjustment and channel widening in eastern Nebraska

In eastern Nebraska, stream straightening and dredging efforts since the 1890s have disturbed the natural equilibrium of stream channels and have led to streambed adjustment by degradation and subsequent channel widening. This report describes a study to evaluate the effect these disturbances have had on stream channels in eastern Nebraska. Two sets of survey data were collected approximately 2 years apart during 1996-99 at 151 primary sites. Additionally, historical streambed-elevation data (dating back to the 1890s) were compiled from several sources for the primary sites and 45 supplemental sites, and relevant disturbances were identified for each of eight basin groupings. Streambed-elevation data sets were used to estimate the amount of change to the streambed at the sites over the time period of the data. Recent channel widening was documented for 73 of the primary sites by comparing the two survey sets. The majority of observed streambed-gradation responses appear to be related to the various straightening efforts and to the effects of grade-control structures in the study area. Channel responses were complicated by the presence of multiple disturbances. However, in many cases, the streambed-elevation data sets provide a reliable representation of the past streambed gradation, with some sites showing 6 to 7 meters of degradation since they were straightened. Many sites that had been straightened showed considerable degradation following the disturbance. This indicates that eastern Nebraska stream channels can regain equilibrium mainly through the slope adjustment process of head-ward-progressing degradation. Bank failures were documented at sites in all eight of the basin groupings analyzed, and widening rates were computed at 64 of 73 sites. Observed bank widening in the Big Blue River Basin, a relatively unstraightened basin, indicates that other disturbances besides stream-channel straightening may be causing channel responses in the basin and possibly in the entire study area.

Water-Resources Investigations Report↗

Simulation of flood hydrographs for Georgia streams

Flood hydrographs are needed for the design of many highway drainage structures and embankments. A method for simulating these flood hydrographs at ungaged sites in Georgia is presented in this report. The O'Donnell method was used to compute unit hydrographs and lagtimes for 355 floods at 80 gaging stations. An average unit hydrograph and an average lagtime were computed for each station. These average unit hydrographs were transformed to unit hydrographs having durations of one-fourth, one-third, one-half, and three-fourths lagtime, then reduced to dimensionless terms by dividing the time by lagtime and the discharge by peak discharge. Hydrographs were simulated for these 355 floods and their widths were compared with the widths of the observed hydrographs at 50 and 75 percent of peak flow. The dimensionless hydrograph based on one-half lagtime duration provided the best fit of the observed data. Multiple-regression analysis was then used to define relations between lagtime and certain physical basin characteristics, of which drainage area and slope were found to be significant for the rural-stream equations, and drainage area, slope, and impervious area were found to be significant for the Atlanta urban-stream equation. A hydrograph can be simulated from the dimensionless hydrograph, the peak discharge of a specific recurrence interval, and the lagtime obtained from regression equations for any site with less than a 500 square mile drainage area in Georgia. For simulating hydrographs at sites with basins larger than 500 square miles, the U.S. Geological Survey computer model CONROUT can be used. This model routes streamflow from an upstream channel location to a user-defined location downstream. The product of CONROUT is a simulated discharge hydrograph for the downstream site, which has a peak discharge of a specific recurrence interval. The diffusion-analogy routing method with single linearization was used in this study.

Georgia↗

Iron in the aquifer system of Suffolk County, New York, 1990-98

High concentrations of dissolved iron in ground water contribute to the biofouling of public-supply wells, and the treatment and remediation of biofouling are costly. Water companies on Long Island, N.Y., spend several million dollars annually to recondition, redevelop, and replace supply wells and distribution lines; treat dissolved iron with sequestering agents or by filtration; and respond to iron-related complaints by customers. This report summarizes the results of studies done by the U.S. Geological Survey, in cooperation with the Suffolk County Water Authority, to characterize the geochemistry and microbiology of iron in the aquifer system of Suffolk County. This information should be helpful for the siting and operation of supply wells. Concentrations of dissolved iron in Long Island's ground water, and the frequency of iron biofouling of wells, are highest in ground-water-discharge zones, particularly near the south shore. Ground water along a deep north-south flowpath of the Magothy aquifer in southwestern Suffolk County becomes anaerobic (oxygen deficient) and Fe(III) reducing at a distance of 8 to 10 kilometers south of the ground-water divide, and this change coincides with the downgradient increase in dissolved iron concentrations. The distribution of organic carbon, and the distribution and local variations in reactivity of Fe(III), in Magothy aquifer sediments have resulted in localized differences in redox microenvironments. For example, Fe(III)-reducing zones are associated with anaerobic conditions, where relatively large amounts of Fe(III) oxyhydroxide grain coatings are present, whereas sulfate-reducing zones are associated with lignite-rich lenses of silt and clay and appear to have developed in response to the depletion of available Fe(III) oxyhydroxides. The sulfate-reducing zones are characterized by relatively low concentrations of dissolved iron (resulting from iron-disulfide precipitation) and may be large enough to warrant water-supply development. Specific-capacity and water-quality data from wells screened in the Magothy aquifer indicate that water from biofouled wells contains higher median concentrations of total and dissolved iron and manganese, total phosphate, and dissolved sulfate, and lower median concentrations of dissolved oxygen and alkalinity, and lower pH, than does water from unaffected wells. Corresponding data from wells screened in the upper glacial aquifer indicate that water from biofouled wells contains higher median concentrations of total and dissolved manganese and dissolved sulfate, and lower pH, than does water from unaffected wells. Filamentous bacteria were detected in 31 (or 72 percent) of the 43 biofilm samples obtained from biofouled wells during reconditioning. The predominant filamentous organism was Gallionella ferruginea, a major biofouling agent in the upper glacial and Magothy aquifers throughout Suffolk County. Mineral-saturation indices indicate that most of the well-encrusting material is deposited when the wells are shut down. Furthermore, the use of treated water (which has a high pH and sometimes high concentrations of dissolved iron) for pump prelubrication when wells are shut down could greatly increase the rate of iron oxidation.

New York↗

Summary of Flow Loss between Selected Cross Sections on the Rio Grande in and near Albuquerque, New Mexico

The upper middle Rio Grande Basin, as defined by the U.S. Army Corps of Engineers, extends from the headwaters of the Rio Grande in southwestern Colorado to Fort Quitman, Texas. Most of the basin has a semiarid climate typical of the southwestern United States. This climate drives a highly variable streamflow regime that contributes to the complexity of water management in the basin. Currently, rapid population growth in the basin has resulted in increasing demands on the hydrologic system. Water management decisions have become increasingly complex because of the broad range of interests and issues. For these reasons, the U.S. Geological Survey, in cooperation with the City of Albuquerque, New Mexico, conducted paired flow measurements at two cross sections to determine cross-sectional loss in the Albuquerque reach of the Rio Grande. This report statistically summarizes flow losses in the Albuquerque reach of the Rio Grande during the winter nonirrigation season from December 1996 to February 2000. The two previous flow-loss investigations are statistically summarized. Daily mean flow losses are calculated for the winter nonirrigation season using daily mean flows at three selected Rio Grande streamflow-gaging stations.For the winter nonirrigation season cross-sectional measurements (1996-2000), an average of 210 cubic feet per second was returned to the river between the measurement sites, of which 165 cubic feet per second was intercepted by riverside drains along the 21.9-mile reach from the Rio Grande near Bernalillo to the Rio Grande at Rio Bravo Bridge streamflow-gaging stations. Total cross-sectional losses in this reach averaged about 90 cubic feet per second. Regression equations were determined for estimating downstream total outflow from upstream total inflow for all three paired measurement studies. Regression equations relating the three daily mean flow recording stations also were determined. In each succeeding study, additional outside variables were controlled, which provided more accurate flow-loss measurements. Regression-equation losses between measurement cross sections ranged from 1.9 to 7.9 percent during the nonirrigation season and from about 5.9 to 6.4 percent during the irrigation season. Mean and median loss by reach length for all three daily mean flow stations and all three cross-sectional measurement reaches showed consistent flow loss per mile by season with allowance for nonideal river conditions for the initial measurement studies. Unsteady measurement conditions were reflected in the regression equation mean-square errors and ultimately in the change in daily mean discharge at the Rio Grande at Albuquerque gaging station during the measurement periods.

Water-Resources Investigations Report↗

Hydrogeology of glacial deposits in a preglacial bedrock valley, Waukesha County, Wisconsin

This report describes the areal extent, thickness, and hydraulic properties of glacial deposits in a preglacial bedrock valley south of the city of Waukesha in southeastern Wisconsin. In the 40- square-mile study area, the preglacial bedrock valley underlies an area across which the Fox River flows. A previous regional study of the area indicated that extensive glacial sand and gravel deposits may exist in the preglacial bedrock valley. New test-hole, well-construction, and seismic data collected from 1986 through 1991 showed that the preglacial bedrock valley immediately south of the city of Waukesha is narrower and shallower than previously thought. However, these data indicate that thicknesses of saturated glacial deposits in excess of 250 feet exist in a 1- to 2-mile-wide part of the valley in the southern part of the study area. Test-hole logs indicate that clean sand and gravel deposits are present in a shallow part of the preglacial bedrock valley. Fifty to sixty feet of silty and clayey sand and gravel deposits appear to underlie varying thicknesses of relatively impermeable clay till in the center of the study area. Ground water flows from upland areas on the eastern and western sides of the Fox River and discharges to the Fox River and wetlands adjacent to the river. Results of a 6.5-hour aquifer test indicate that the silty sand and gravel deposits have an average transmissivity of about 140 feet squared per day and an average storage coefficient of about 1.2x10"3 at one location. The horizontal hydraulic conductivity of these deposits averages about 4 feet per day. Analysis of drawdown indicates that these deposits are part of a leaky confined-aquifer system and that some water is derived from storage in an overlying clay layer. The transmissivity value determined from this aquifer test and a lack of clean sand and gravel encountered in other test holes indicate that glacial deposits at these sites may not yield enough water for a large municipal water supply. Sand and gravel deposits, capable of development as a municipal supply, may be present in the southern part of the study area. However, additional test holes are needed to determine whether adequate sand and gravel deposits underlie this area.

Wisconsin↗

Estimation of flood flows on the Big Sioux River between Akron, Iowa, and North Sioux City, South Dakota

This report presents estimated flood flows for specified frequencies at selected locations on the Big Sioux River between the Akron, Iowa, streamflow-gaging station and North Sioux City, South Dakota. The selected locations include: at the Akron gaging station, downstream from the Richland-Westfield Creek Basins, downstream from the Brule Creek Basin, downstream from the Upper West Boundary Big Ditch and Rock Creek Basins, downstream from Broken Kettle Basin, and downstream from North Sioux City. The flood flows for the 10-, 50-, 100-, and 500-year recurrence intervals will be used to support a Federal Emergency Management Agency Flood Insurance Study. Four methods were used to estimate the flood flows. The first method involved the use of drainage-area ratios raised to specified exponents to transfer the flood-frequency relation from the Akron gage to the selected downstream locations. The second method was a flood-frequency analysis based on a summation of the Akron gaging-station peak flows and concurrent tributary daily flows from within the various study reaches. The third method was an independence/dependence analysis of the Akron gaging-station flows and the tributary flows from the various study reaches. The fourth method was a flood-frequency analysis assuming complete dependence of the Akron peak flows and the tributary peak flows from the various study reaches. Based on the various analyses that were done, the drainage-area-ratio method best estimated the flood flows for the Akron to North Sioux City reach of the Big Sioux River. The best estimates of 10-, 50-, 100-, and 500-year flood flows at the location downstream from North Sioux City are 35,300, 70,400, 89,100, and 142,000 cubic feet per second, respectively.

Water-Resources Investigations Report↗

Historical contributions of phosphorus from natural and agricultural sources and implications for stream water quality, Cheney Reservoir watershed, south-central Kansas

An examination of soil cores collected from 43 nonagricultural coring sites in the Cheney Reservoir watershed of south-central Kansas was conducted by the U.S. Geological Survey in September 1999. The cores were collected as part of an ongoing cooperative study with the city of Wichita, Kansas. The 43 sites (mostly cemeteries) were thought to have total phosphorus concentrations in the soil that are representative of natural conditions (unaffected by human activity). The purpose of this report is to present the analysis and evaluation of these soil cores, to quantify the phosphorus contributions to Cheney Reservoir from natural and agricultural sources, and to provide estimates of stream-water-quality response to natural concentrations of total phosphorus in the soil. Analysis of soil cores from the 43 sites produced natural concentrations of total phosphorus that ranged from 74 to 539 milligrams per kilogram with a median concentration of 245 milligrams per kilogram in 2-inch soil cores and from 50 to 409 milligrams per kilogram with a median concentration of 166 milligrams per kilogram in 8-inch soil cores. Natural concentrations of total phosphorus in soil were statistically larger in samples from coring sites in the eastern half of the watershed than in samples from coring sites in the western half of the watershed. This result partly explains a previously determined west-to-east increase in total phosphorus yields in streams of the Cheney Reservoir watershed. A comparison of total phosphorus concentrations in soil under natural conditions to the historical mean total phosphorus concentration in agriculturally enriched bottom sediment in Cheney Reservoir indicated that agricultural activities within the watershed have increased total phosphorus concentrations in watershed soil that is transported in streams to about 2.9 times natural concentrations. Retention efficiencies for phosphorus and sediment historically transported to Cheney Reservoir were calculated at 92 and 99 percent, respectively. Most of the phosphorus was retained in bottom sediment. Sediment accumulation in Cheney Reservoir was less than reservoir design-life specifications on the basis of the age of the reservoir. Estimates of mean total phosphorus concentrations for selected streams in the Cheney Reservoir watershed under natural concentrations of total phosphorus in soil and a historic set of watershed conditions indicate that water from two of the five streamflow sampling sites would not meet the total phosphorus water-quality goal of 0.10 milligram per liter established by the Cheney Reservoir Watershed Task Force Committee. These results imply that the water-quality goal for total phosphorus in some streams of the watershed may not be met simply by reducing the amount of phosphorus applied. Instead, meeting the goal could involve a combination of approaches-for example, reducing the agricultural distribution of phosphorus and implementing changes in watershed activities to mitigate phosphorus movement to surface water.

Kansas↗

Water-quality characteristics in the Black Hills area, South Dakota

This report summarizes the water-quality characteristics of ground-water and surface-water in the Black Hills area. Differences in groundwater quality by aquifer and differences in surfacewater quality by water source are presented. Ground-water characteristics are discussed individually for each of the major aquifers in the Black Hills area, referred to herein as the Precambrian, Deadwood, Madison, Minnelusa, Minnekahta, and Inyan Kara aquifers. Characteristics for minor aquifers also are discussed briefly. Surface-water characteristics are discussed for hydrogeologic settings including headwater springs, crystalline core sites, artesian springs, and exterior sites. To characterize the water quality of aquifers and streams in the Black Hills area, data from the U.S. Geological Survey National Water Information System water-quality database were examined. This included samples collected as part of the Black Hills Hydrology Study as well as for other studies within the time frame of October 1, 1930, to September 30, 1998. Tables of individual results are not presented in this report, only summaries. Constituents summarized and discussed include physical properties, common ions, nutrients, trace elements, and radionuclides. Comparisons of concentration levels are made to drinking-water standards as well as beneficial-use and aquatic-life criteria. Ground water within the Black Hills and surrounding area generally is fresh and hard to very hard. Concentrations exceeding various Secondary and Maximum Contaminant Levels may affect the use of the water in some areas for many aquifers within the study area. Concentrations that exceed Secondary Maximum Contaminant Levels (SMCL's) generally affect the water only aesthetically. Radionuclide concentrations may be especially high in some of the major aquifers used within the study area and preclude the use of water in some areas. The sodiumadsorption ratio and specific conductance may affect irrigation use for some wells. High concentrations of iron and manganese are the only concentrations that may hamper the use of water from Precambrian aquifers. The principal deterrents to use of water from the Deadwood aquifer are the high concentrations of radionuclides as well as iron and manganese. Iron, manganese, and hardness may deter use of water from the Madison aquifer as well as dissolved solids and sulfate in downgradient wells (generally deeper than 2,000 feet). Iron, manganese, and hardness may also deter use of the Minnelusa aquifer. Water from the Minnekahta aquifer generally is suitable for all water uses although it is hard to very hard. High concentrations of dissolved solids, iron, sulfate, and manganese may hamper the use of water from the Inyan Kara aquifer. In the southern Black Hills, radium-226 and uranium concentrations also may preclude use of water from the Inyan Kara aquifer. Suitability for irrigation may be affected by high specific conductance and sodium-adsorption ratio for the Inyan Kara. Surface-water quality within the Black Hills and surrounding area generally is very good but the water is hard to very hard. Concentrations of some constituents in the study area tend to be higher exterior to the Black Hills, primarily due to influences from the Cretaceous-age marine shales, including dissolved solids, sodium, sulfate, selenium, and uranium. Headwater springs have relatively constant discharge, specific conductance, dissolved solids, and concentrations of most other constituents. Concentrations at crystalline core sites are very similar to those found in samples from Precambrian aquifers. Some high nitrate concentrations greater than the Maximum Contaminant Level (MCL) of 10 mg/L (milligrams per liter) have occurred at Annie Creek near Lead, which have been attributed to mining impacts. Trace elements generally are low with the exception of arsenic, for which 60 percent of samples exceed the proposed MCL of 10 ug/L (micrograms per liter) and one sample

Water-Resources Investigations Report↗

Flow origin, drainage area, and hydrologic characteristics for headwater streams in the mountaintop coal-mining region of Southern West Virginia, 2000-01

Characteristics of perennial and intermittent headwater streams were documented in the mountaintop removal coal-mining region of southern West Virginia in 2000?01. The perennial-flow origin points were identified in autumn during low base-flow conditions. The intermittent-flow origin points were identified in late winter and early spring during high base-flow conditions. Results of this investigation indicate that the median drainage area upstream of the origin of intermittent flow was 14.5 acres, and varied by an absolute median of 3.4 acres between the late winter measurements of 2000 and early spring measurements of 2001. Median drainage area in the northeastern part of the study unit was generally larger (20.4 acres), with a lower median basin slope (322 feet per mile) than the southwestern part of the study unit (12.9 acres and 465 feet per mile, respectively). Both of the seasons preceding the annual intermittent flow visits were much drier than normal. The West Virginia Department of Environmental Protection reports that the median size of permitted valley fills in southern West Virginia is 12.0 acres, which is comparable to the median drainage area upstream of the ephemeralintermittent flow point (14.5 acres). The maximum size of permitted fills (480 acres), however, is more than 10 times the observed maximum drainage area upstream of the ephemeral-intermittent flow point (45.3 acres), although a single valley fill may cover more than one drainage area. The median drainage area upstream of the origin of perennial flow was 40.8 acres, and varied by an absolute median of 18.0 acres between two annual autumn measurements. Only basins underlain with mostly sandstone bedrock produced perennial flow. Perennial points in the northeast part of the study unit had a larger median drainage area (70.0 acres) and a smaller median basin slope (416 feet per mile) than perennial points in the southwest part of the study unit (35.5 acres and 567 feet per mile, respectively). Some streams were totally dry for one or both of the annual October visits. Both of the seasons preceding the October visits had near normal to higher than normal precipitation. These dry streams were adjacent to perennial streams draining similarly sized areas, suggesting that local conditions at a firstorder- stream scale determine whether or not there will be perennial flow. Headwater-flow rates varied little from year to year, but there was some variation between late winter and early spring and autumn. Flow rates at intermittent points of flow origin ranged from 0.001 to 0.032 cubic feet per second, with a median of 0.017 cubic feet per second. Flow rates at perennial points of flow origin ranged from 0.001 to 0.14 cubic feet per second, with a median of 0.003 cubic feet per second.

Water-Resources Investigations Report↗

Relation of periphyton and benthic invertebrate communities to environmental factors and land use at selected sites in part of the upper Mississippi River basin, 1996-98

The Upper Mississippi River Basin is one of the hydrologic systems selected for study by the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey. NAWQA utilizes a multi-disciplinary approach to explain factors that affect water quality. Part of the NAWQA design addresses the relation of land use and environmental factors to periphyton and benthic invertebrate communities in streams. This report focuses on a 122,000 square kilometer area of the Mississippi River Basin, including the Twin Cities metropolitan area (TCMA). The northeastern part of the study area is forested, the southwestern part is agricultural, and the central part is transitional between forest and agriculture. Sampling sites were selected based on a process that identified small streams in predominantly forested, agricultural, and urban settings, and large river sites on the Mississippi River and major tributaries. Periphyton and benthic invertebrate communities were evaluated at each site. Compared to the forested site, periphyton density and biovolume in small streams generally increased as nutrient concentrations associated with urban and agricultural land use increased. Periphyton communities varied within agricultural and urban streams, indicating that physical and chemical factors other than land use also affect periphyton communities. Benthic invertebrate communities also are affected by land use and associated stream habitat. There were few intolerant taxa (Ephemeroptera and Plecoptera) in urban streams, potentially due to high streamflow variability and contaminants from runoff. Ephemeroptera taxa richness was greatest in the agricultural streams. The most abundant Ephemeroptera taxa were those tolerant to high concentrations of suspended sediment. Richness of Plecoptera and Trichoptera taxa were greatest in the forested stream. Biological communities in the St. Croix and Minnesota River generally reflected relatively homogeneous land uses. Biological communities in the Mississippi River reflected changes in water quality and physical habitat as the Minnesota and St. Croix Rivers join the Mississippi River. Periphyton density and biovolume, and the relative abundance of blue-green algae density increased in the Mississippi River at the confluence compared to the Minnesota and St. Croix Rivers. Relative abundance of benthic invertebrate taxa richness and diversity generally decreased downstream in the large rivers as urban and agricultural land use become more prevalent. Impoundments and dredging of the Mississippi River in and downstream from the TCMA exacerbate effects of increasing river size to produce a more lake-like system.

Iowa, Minnesota, North Dakota, South Dakota, Wisco↗

Floods of September 16, 1975 in the Tallaboa Valley, Puerto Rico

This report provides a record of the flood of September 16, 1975, and associated hydrologic data. These data can be used in making rational decisions in formulating effective flood-plain regulations that would minimize flood problems in the Tallaboa Valley. The Tallaboa Valley (fig. 1) lies on the southwestern coast of Puerto Rico about 12 km (7.5 mi) west of the city of Ponce. The climate is semiarid with a mean annual precipitation of about 1,020 mm (40 in). It is a relatively small valley which until the late fifties was dedicated mainly to the product ion of sugarcane. Since then, the economy started changing from agriculture to industry. At present the lower part of the valley is completely industrialized. The upper part of the valley is used for agriculture--mostly as pastureland. The reach from Highway 132 downstream to the new Highway 2 is mainly agricultural with a few scattered communities. The lower part of the valley that includes the area from the Highway 2 bridge to the mouth is covered with heavy industry concerned with the refinement of oil, and associated industries. The continuous growth of industry and consequently of the urban area of Peñuelas has encouraged growth onto the flood plain. The study area is subject to flooding by the Rio Tallaboa and the Rio Guayanes, its main tributary. The Rio Guayanes is the- cause of flooding in the urban area of Penuelas, encompassing the reach from the northern edge of town downstream to Highway 132 where it joins the Rio Tallaboa. Data are generally referred to in SI (International System) units followed by corresponding inch-pound units in parentheses. The SI units.may be converted to inch-pound units by multiplying the units given by the factors shown.

Tallaboa Valley↗