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Calibrated simulation of the long-term average surficial groundwater system and derived spatial distributions of its characteristics for the contiguous United States

While the physical processes governing groundwater flow are well understood, and the computational resources now exist for solving the governing equations in three dimensions over continental-scale domains, there remains substantial uncertainty about the subsurface distribution of the properties that control groundwater flow and transport for much of the contiguous United States (CONUS). The transmissivity of the shallow subsurface is a key parameter for the simulation of water table position, shallow groundwater flow, and base-flow discharge, but is not well-characterized at large regional to continental scales. We used a process-based inversion of CONUS-extent groundwater information to generate national data sets of (a) the transmissivity of the shallow groundwater system, (b) the depth to the water table, (c) groundwater discharge as base-flow, and (d) long-term average water content in the unsaturated zone. CONUS-extent coverage was developed in the form of 75 subdomain models, with the spatial distribution of long-term average transmissivity for each subdomain model calibrated against water-levels derived from U.S. Geological Survey (USGS) observation wells, NHDPlusV2 first-order perennial streams, and National Wetlands Inventory (NWI) freshwater wetlands. Estimated transmissivities were lower in the western CONUS than the eastern CONUS, and across the CONUS both transmissivity and depth to water correlate with recharge, elevation, and topographic slope. These generated data sets provide spatially distributed, long-term average estimates of subsurface properties and hydrological states that we anticipate will complement other environmental modeling efforts as explanatory variables, boundary conditions, or transport pathways.

contiguous United States↗

Groundwater flow conceptualization of the Pahute Mesa–Oasis Valley Groundwater Basin, Nevada—A synthesis of geologic, hydrologic, hydraulic-property, and tritium data

This report provides a groundwater-flow conceptualization that integrates geologic, hydrologic, hydraulic-property, and radionuclide data in the Pahute Mesa–Oasis Valley (PMOV) groundwater basin, southern Nevada. Groundwater flow in the PMOV basin is of interest because 82 underground nuclear tests were detonated, most near or below the water table. A potentiometric map and nine sets of hydrostratigraphic and hydrologic cross sections supplement the conceptualization. Potentiometric contours indicate that groundwater in the PMOV basin generally flows south-southwest and discharges at Oasis Valley. Groundwater encounters an alternating sequence of low- and high-transmissivity rocks, referred to as dams and pools, respectively, as it moves from east to west across eastern Pahute Mesa. Flow from all Pahute Mesa nuclear tests is to Oasis Valley and is well-constrained by water-level data. Flow converges along a corridor of high transmissivity between Pahute Mesa and Oasis Valley. The location of the lateral PMOV basin boundary is well defined, and this boundary, with a few minor exceptions, represents a no-flow boundary. Some boundary uncertainty exists in the northeastern part of the basin, but potential flow-rate estimates across the northeastern boundary resulting from this uncertainty are small relative to the basin groundwater budget. Recharge in the PMOV basin is derived from episodic pulses of modern water and the diffuse percolation of old water (greater than 1,000 years). Episodic recharge is a minor recharge component observed as a rise in groundwater levels that occurs 3 months to 1 year following a wet winter. Minor amounts of episodic recharge through an unsaturated zone in excess of 1,000 feet (ft) requires preferential flow through faults and fractures. The dominant recharge component is slow, steady, diffuse percolation of old water through the unsaturated zone. A large component of old water recharging the groundwater system is consistent with observations of isotopically light deuterium and oxygen 18 compositions in water from wells on Pahute Mesa and central Oasis Valley. About half the recharge in the PMOV basin is derived from the eastern Pahute Mesa area. The remaining recharge is derived primarily from other highland areas including Timber Mountain, Belted and Kawich Ranges, and Black Mountain. The PMOV groundwater system is nearly steady state, where recharge is balanced by the 5,900 acre-feet per year of natural discharge at Oasis Valley. This assumption is reasonable because the basin is dominated by steady-state conditions, where long-term changes in groundwater storage are minimal. Total groundwater withdrawals from 1963 to 2018 have amounted to less than 10 percent of annual groundwater discharge and less than 0.2 percent of the basin’s groundwater storage. Therefore, present-day (2020) conditions are considered representative of predevelopment (pre-1950) conditions in nearly all areas of the basin. The lower PMOV basin boundary is defined at 4,000 ft below the water table to encompass all underground nuclear tests and tritium plumes. This boundary defines the lower boundary of radionuclide migration. However, nearly all flow and tritium transport occur in the upper 1,600 ft of the saturated zone because a transmissivity-with-depth relation indicates that greater than 90 percent of the transmissivity contributing to groundwater flow occurs within 1,600 ft of the water table. Rocks at deeper depths have low transmissivity because argillic and mineralized alterations plug the fractures. Volcanic rocks form the primary aquifers and confining units in the PMOV basin. Volcanic hydrogeologic units (HGUs) and hydrostratigraphic units (HSUs) have transmissivity distributions that span up to eight orders of magnitude with considerable overlap between distributions. Despite the large overlap between units, mean transmissivities of aquifers are one-to-two orders of magnitude greater than the confining units. However, all volcanic-rock HGUs and HSUs are composite units, meaning that they can function spatially as either an aquifer or confining unit .

Nevada↗

Assessment of the role of bottomland hardwoods in sediment and erosion control

Drainage and clearing of bottomland hardwoods have long been recognized by the U.S. Environmental Protection Agency (EPA) and the U.S. Fish and Wildlife Service (Service) as important impacts of Federal water projects in the lower Mississippi River Valley. More recently, the water quality impacts of such projects (e.g., increases in sediments, nutrients, and pesticides) have also become of concern. In 1984, in an effort to better define problems concerning wetland losses and water degradation, EPA initiated a cooperative project with the Western Energy and Land Use Team (now the National Ecology Research Center) of the Service. Three phases of the project were identified: 1. To collect existing literature and data; 2. To select, develop, and test the utility of methods to quantify the relationships between land use, cover types, soils, hydrology, and water quality (as represented by sediment); and 3. To apply selected methodologies to several sites within the Yazoo Basin of Mississippi to determine the, potential effectiveness of various management alternatives to reduce sediment yield, increase sediment deposition, and improve water quality. Methods development focused on linking a simulation of water and sediment movement to a computerized geographic information system. We had several objectives for the resulting model. We desired that it should: 1. Estimate the importance of bottomland and hardwoods as a cover type that performs the functions of erosion and sediment control, 2. Simulate effects of proportions of ' various cover types and their specific spatial configurations, 3. Be applicable to moderately large spatial areas with minimal site-specific calibration, 4. Simulate spatial patterns of sediment loss-gain over time, and 5. Represent both sediment detachment and transport. While it was recognized that impacts and management alternatives could be sorted roughly into landscape measures and channel measures, the decision was made to focus study efforts mainly on landscape measures. Landscape measures include altered drainage and flooding patterns, altered cover types (e.g., conversion of bottomland hardwoods to agricultural crops, reforestation of cropland to bottomland hardwoods, and creation of riparian buffer strips), altered cropping and tillage patterns, altered routing of water, and creation of buffer strips along wetlands and channel margins. Channel measures include vegetative bank stabilization, grade control structures, and regulation of channel water volume and velocity. During the first year of the study, EPA decided not to fund the third phase of the project. This required considerable rescoping of the project with the result that application of the sediment mobilization, routing, and deposition models to various management alternatives and portions of the Yazoo Basin was somewhat restricted. We believe, however, that this report will provide a good understanding of the various modes of sediment mobilization, transport, and deposition within the Yazoo Basin, as well as of the role of bottomland hardwoods. The model developed in this study could be applied to a variety of management or mitigation alternatives prior to implementation to determine their relative effectiveness. Policy, political, and socio-economic consequences of any proposed management/mitigation practice, however, must ultimately be taken into consideration by those charged with management of water resources within the Yazoo Basin before any practice is implemented. This study makes no effort to judge the feasibility of management alternatives in this regard.

Report↗

Groundwater hydrology and chemistry of Jamestown Island, Virginia—Potential effects of tides, storm surges, and sea-level rise on archaeological, cultural, and ecological resources

As the site of the first permanent English settlement in North America in 1607, Jamestown Island, Colonial National Historical Park (COLO), Virginia, contains a rich archaeological record that extends from the Paleoindian period (15,000 to 8,000 years ago) through the 20th century. The island is located on the lower James River near the mouth of Chesapeake Bay. Jamestown Island vegetation is dominated by upland forests surrounded by tidal, freshwater-to-oligohaline marshes. Along the Virginia coast, relative sea-level rise was more than 2.5 times the global average during the 20th century. Consequently, the National Park Service (NPS) has identified COLO as one of the 25 national parks most threatened by climate change. Surface waters across the island are hydraulically connected to the laterally continuous Surficial aquifer. The land-surface altitude of the island is low, with two-thirds of the island less than 5 feet (ft) above the North American Vertical Datum of 1988 (NAVD 88). Consequently, sea-level rise, combined with tides and storm surges, threatens the island and its resources as surface-water and groundwater levels rise, saltwater enters the Surficial aquifer, and groundwater chemistry changes. The impact of sea-level rise on the island’s surface-water resources has been well studied, but groundwater effects have been largely ignored. Quantifying the effects of tides, storm surges, and sea-level rise on groundwater levels and chemistry is essential to developing an effective strategy for managing climate-induced changes. The first step in developing a response strategy includes a parkwide general risk assessment for archaeological sites on the island, so that sites can be prioritized for management actions. The U.S. Geological Survey and the NPS began a study in 2015 to develop a long-term groundwater-monitoring program to evaluate this risk and to develop an updated management strategy. The groundwater-monitoring program consists of 45 wells and piezometers in two individual clusters and three transects across the island in different hydrologic and chemical settings. Samples for water quality were collected from the wells and piezometers from October 2015 through September 2018 at variable time intervals. Results of the monitoring identified disparate hydrologic and chemical responses to saltwater intrusion across the island. Specific conductance (an indicator of salinity) of groundwater beneath several marshes responded differently to changes in James River salinity. Groundwater response to changes in James River specific conductance appeared to be controlled by land-surface altitude and slope, differences in lateral and vertical sediment characteristics, distance from surface waters, and the degree of surface water/groundwater connectivity between channels and the aquifer. Groundwater chemistry data from monitoring wells at Black Point, a low-altitude, upland setting, are in contrast with conditions observed in Island House observation wells, a high-altitude, upland setting. Specific conductance (less than 200 microsiemens per centimeter [μS/cm]) and pH (greater than 5.0) of groundwater beneath much of the uplands that characterize the Island House observation wells are typical of groundwater in noncarbonate sedimentary aquifers recharged by precipitation. At Black Point, specific conductance ranged from 2,490 to 15,200 μS/cm, and pH ranged from 3.1 to 6.6 standard units. At the Black Point observation wells, the most saline and dense water was at the water table rather than deeper in the aquifer, causing a density inversion that persisted throughout the study. The density inversion likely resulted from differences in permeability between the shallow clay and fine-grained sands and the deeper coarse-grained sand and gravel. Groundwater with the lowest pH was at the water table. As saline groundwater flows through organic sediment beneath the marshes, bacterial biodegradation of organic matter creates anoxic conditions. Continued biodegradation concomitantly reduces iron-oxide minerals in the sediment and sulfate in saline water. When oxygen is reintroduced into groundwater, iron and sulfur can reoxidize to form sulfuric acid, locally lowering the pH of the water. This report describes the groundwater monitoring network design, rationale for site selection, monitoring approach, and results of monitoring from October 2015 through September 2018. Maps of inundation at selected water-level altitudes are included to identify the risk to archaeological, cultural, and ecological resources. The monitoring results of the hydrology and chemistry data are interpreted, and the different hydrologic and chemical settings are described. The implications of the study results for management decisions are presented, and suggestions for improving the monitoring network are included.

Virginia↗

Water-level data for the Albuquerque Basin and adjacent areas, central New Mexico, period of record through September 30, 2015

The Albuquerque Basin, located in central New Mexico, is about 100 miles long and 25–40 miles wide. The basin is hydrologically defined as the extent of consolidated and unconsolidated deposits of Tertiary and Quaternary age that encompasses the structural Rio Grande Rift between San Acacia to the south and Cochiti Lake to the north. Drinking-water supplies throughout the basin were obtained solely from groundwater resources until December 2008, when the Albuquerque Bernalillo County Water Utility Authority (ABCWUA) began treatment and distribution of surface water from the Rio Grande through the San Juan-Chama Drinking Water Project. A 20-percent population increase in the basin from 1990 to 2000 and a 22-percent population increase from 2000 to 2010 may have resulted in an increased demand for water in areas within the basin. An initial network of wells was established by the U.S. Geological Survey (USGS) in cooperation with the City of Albuquerque from April 1982 through September 1983 to monitor changes in groundwater levels throughout the Albuquerque Basin. In 1983, this network consisted of 6 wells with analog-to-digital recorders and 27 wells where water levels were measured monthly. The network currently (2015) consists of 124 wells and piezometers. (A piezometer is a specialized well open to a specific depth in the aquifer, often of small diameter and nested with other piezometers open to different depths.) The USGS, in cooperation with the ABCWUA, currently (2015) measures and reports water levels from the 124 wells and piezometers in the network; this report presents water-level data collected by USGS personnel at those 124 sites through water year 2015 (October 1, 2014, through September 30, 2015).

New Mexico↗

Geohydrology of the Navajo sandstone in western Kane, southwestern Garfield, and southeastern Iron counties, Utah

The upper Navajo and Lamb Point aquifers in the Navajo Sandstone are the principal source of water for the city of Kanab, irrigation, stock, and for rural homes in the study area. Well logs and outcrop descriptions indicate the Navajo Sandstone consists of the Lamb Point Tongue and an unnamed upper member that are separated by the Tenney Canyon Tongue of the Kayenta Formation. The main Kayenta Formation underlies the Lamb Point Tongue. The Lamb Point Tongue and the upper member of the Navajo Sandstone are saturated and hydraulically connected through the Tenney Canyon Tongue. Available data indicate that precipitation percolates to the groundwater reservoir where the Navajo Sandstone crops out. Estimates of the rate of recharge at the outcrop range from 0.1 to as much as 2.8 in/yr. Water level data indicate that water moves from the upper member of the Navajo Sandstone, through the Tenney Canyon Tongue, and into the Lamb Point Tongue. Lateral flow is generally from the outcrop areas toward the incised canyons formed by tributaries of Kanab Creek and Johnson Wash. Direction and rate of groundwater movement and the location and character of the natural hydrologic boundaries in the northern part of the area where the Navajo Sandstone is buried cannot be determined conclusively without additional water level data. (Author 's abstract)

Water-Resources Investigations Report↗

Distribution of major herbicides in ground water of the United States

Information on the concentrations and spatial distributions of pesticides and their transformation products, or degradates, in the hydrologic system is essential for managing pesticide use in both agricultural and nonagricultural settings to protect water resources. This report examines the occurrence of selected herbicides and their degradates in ground water, primarily on the basis of results from two large-scale, multistate investigations by the U.S. Geological Survey&mdash;the National Water-Quality Assessment (NAWQA) Program and the Midwest Pesticide Study (MWPS). The NAWQA pesticide data were derived from 2,227 sites (wells and springs) sampled in 20 major hydrologic basins across the United States from 1993 to 1995; the MWPS data were obtained from the sampling of 303 wells in a 12-state area of the northern midcontinent from 1991 to 1994. Data are presented for seven high-use herbicides: five of current interest to the U.S. Environmental Protection Agency for designing Pesticide Management Plans (atrazine, cyanazine, simazine, alachlor and metolachlor), a largely nonagricultural herbicide (prometon), and an agricultural herbicide first registered in 1994 for use in the United States (acetochlor). Six of the herbicides (all except acetochlor) were detected by the U.S. Geological Survey studies in shallow ground water&mdash;that is, ground water recharged within the past 10 years&mdash;in a variety of agricultural and nonagricultural settings, as well as in several aquifers that are sources of drinking-water supply. Acetochlor was not detected by the MWPS in the summer of 1994, but was detected in shallow ground water during the NAWQA Program by early 1995, and during another U.S. Geological Survey study in Iowa during the summers of 1995 and 1996. The acetochlor observations suggest that, in agreement with results from previous field studies, some pesticides may be detected in shallow ground water within 1 year following their application. In accord with the results from other largescale multistate studies of pesticides in ground water, more than 98 percent of the detections during the NAWQA and MWPS investigations were at concentrations of less than 1 microgram per liter. Consequently, water quality criteria for drinking water&mdash;that is, standards established to protect human health&mdash;were exceeded at fewer than 0.1 percent of the sites sampled by NAWQA (all of these exceedances involving atrazine alone) and at none of those sampled in 1992 by the MWPS. These criteria, however, may not accurately reflect the overall health risks associated with pesticide detections in water resources because they have been established only for a relatively small number of pesticides and they do not account for the additive or synergistic effects of mixtures, impacts on the health of aquatic ecosystems, or the effects of pesticide degradates. Among the sites sampled during the NAWQA and MWPS investigations, 19.7 and 13.8 percent, respectively, had detections of two or more of the herbicides of interest. Furthermore, for most of the herbicides for which degradates were examined, detection frequencies for major degradates were typically higher than for their respective parent compounds, particularly for the herbicides that are less persistent in aerobic soil. Frequencies of detection at or above 0.01 microgram per liter in shallow ground water beneath agricultural areas during the NAWQA study were significantly correlated with agricultural use in those areas for atrazine, cyanazine, alachlor, and metolachlor (P<0.05; Spearman rank correlations), but not for simazine (P>0.05). In urban areas, overall frequencies of detection of these five herbicides in shallow ground water were positively correlated with their total nonagricultural use nationwide (P=0.026; simple linear correlation). Multivariate statistical analysis indicated that frequencies of detection in shallow ground water beneath agricultural areas were positively correlated with half-lives for transformation in aerobic soil and agricultural use of the compounds (P&le;0.0001 for both parameters). Although frequencies of detection were not significantly correlated with their subsurface mobility (K oc ; P=0.19) or the median well depths of the sampled networks (P=0.72), the range of K oc values among the five herbicides and the range of well depths were limited.

Water-Resources Investigations Report↗

Evaluation of Sources of Nitrate Beneath Food Processing Wastewater-Application Sites near Umatilla, Oregon

Water samples from wells were collected beneath and downgradient of two food-processing wastewater-application sites near Umatilla, Oregon. These samples were analyzed for nitrate stable isotopes, nutrients, major ions, and age-dating constituents to determine if nitrate-stable isotopes can be used to differentiate food-processing waste from other potential sources of nitrate. Major-ion data from each site were used to determine which samples were associated with the recharge of the food-processing wastewater. End-member mixing analysis was used to determine the relative amounts of each identified end member within the samples collected from the Terrace Farm site. The delta nitrogen-15 (delta 15N) of nitrate generally ranged between +2 and +9 parts per thousand and the delta oxygen-18 (delta 18O) of nitrate generally ranged between -2 and -7 parts per thousand. None of the samples that were determined to be associated with the wastewater were different from the samples that were not affected by the wastewater. The nitrate isotope values measured in this study are also characteristic of ammonium fertilizer, animal and human waste, and soil nitrate; therefore, it was not possible to differentiate between food-processing wastewater and the other nitrate sources. Values of delta 15N and delta 18O of nitrate provided no more information about the sources of nitrate in the Umatilla River basin than did a hydrologic and geochemical understanding of the ground-water system derived from interpreting water-level and major-ion chemistry data.

Scientific Investigations Report↗

Rapid-response unsaturated zone hydrology: Small-scale data, small-scale theory, big problems

The unsaturated zone (UZ) extends across the Earth’s terrestrial surface and is central to many problems related to land and water resource management. Flow of water through the UZ is typically thought to be slow and diffusive, such that it could attenuate fluxes and dampen variability between atmospheric inputs and underlying aquifer systems. This would reduce water resource vulnerability to contaminants and water-related hazards. Reducing or negating that effect, however, spatially concentrated and rapid flow and transport through the unsaturated zone is surprisingly common and becoming more so with the increasing frequency and magnitude of extreme hydroclimatic events. Arising from the wide range in the rates and complex modes of nonlinear flow processes, these effects are among the most poorly characterized hydrologic phenomena. Issues of scale present additional difficulties. Equations representing unsaturated processes have been developed and tested on the basis of field and laboratory measurements typically made at scales from pore size to plot size. In contrast, related problems of significant interest to society, including floods, aquifer recharge, landslides, and groundwater contamination, range from watershed to regional scales. The disparity between the scale of our understanding and the scale of interest for societal problems has spurred application of these model equations at increasingly coarse resolutions over larger areas than can be justified by existing measurements or theory. This mismatch in scales requires an assumption that spatially averaging slow diffusive flow and rapid preferential flow can effectively represent the influence of both processes across vast areas. Given the currently inadequate recognition and quantitative characterization of focused and rapid processes in unsaturated flow, these phenomena are critically in need of expanded attention and effort.

Frontiers in Earth Science↗

The application of an analytic element model to investigate groundwater-lake interactions at Pretty Lake, Wisconsin

Pretty Lake is a 64 acre, sandy-bottomed groundwater flow-through lake that has a history of hydrologic disturbance. Residents and regulators require a better understanding of lake-groundwater interaction to develop measures to protect the lake's hydrologic system and water quality. A groundwater flow model was constructed as a tool to synthesize field data collected at the site, delineate recharge areas that supply groundwater to the lake, and predict die effect of dredging an adjacent drainage ditch. The one layer, two-dimensional steady-state areal model used analytic element (AE) methods because they are quick to apply and include sophisticated simulation of groundwater-surface water interaction. The model calibrated well to groundwater heads (mean absolute difference = 0.05 m), lake stage (within 0.05 m) and ditch fluxes (mean absolute difference = 0.0023 m 3 &middot;s &minus;1 ). Model results showed that a single 1000 m wide recharge area supplies all the groundwater inflow to the lake. In addition, the model predicted that dredging an adjacent ditch by 3.0 m would lower the lake level by 0.31 m. The analytic element model was verified using a widely accepted finite-difference (FD) code; differences were less than &plusmn;0.015 m near die lake area and reached a maximum of 0.08 m at far corners of the FD grid. These differences are likely a result of die nodal interpolation inherent to FD techniques and error associated with applying a discrete boundary to die AE infinite aquifer. Although developed recently, AE methods have great potential to aid characterizations of groundwater-lake systems.

Wisconsin↗

Hydrologic and biogeochemical controls of river subsurface solutes under agriculturally enhanced ground water flow

The relative influences of hydrologic processes and biogeochemistry on the transport and retention of minor solutes were compared in the riverbed of the lower Merced River (California, USA). The subsurface of this reach receives ground water discharge and surface water infiltration due to an altered hydraulic setting resulting from agricultural irrigation. Filtered ground water samples were collected from 30 drive point locations in March, June, and October 2004. Hydrologic processes, described previously, were verified by observations of bromine concentrations; manganese was used to indicate redox conditions. The separate responses of the minor solutes strontium, barium, uranium, and phosphorus to these influences were examined. Correlation and principal component analyses indicate that hydrologic processes dominate the distribution of trace elements in the ground water. Redox conditions appear to be independent of hydrologic processes and account for most of the remaining data variability. With some variability, major processes are consistent in two sampling transects separated by 100 m.

Journal of Environmental Quality↗

Multiple-well monitoring site adjacent to the Midway- Sunset and Buena Vista Oil Fields, Kern County, California

Groundwater quality in and around oil fields in the Southern San Joaquin Valley is of interest to many California residents that rely heavily on groundwater for domestic, commercial, and agricultural use. To help assess the effects of historical oil-field activities and natural geologic sources on groundwater near the southwest margins of the Kern County Groundwater Subbasin, a multiple-well monitoring site was installed near the administrative boundary between the Midway-Sunset and Buena Vista Oil Fields in Kern County, California. The installation of the Midway-Sunset Buena Vista multiple-well monitoring site (MSBV) supports regional analysis of the relations of oil and gas sources to groundwater quality by providing information about the geology, hydrology, geophysical properties, and water quality of the alluvial and upper Tulare aquifers in areas where groundwater data were limited. Data collected from the site included drill cuttings, whole core samples, sidewall core samples, mud-gas analysis, borehole geophysical logs, depth to water measurements, and water quality samples. Whole cores were scanned using dual energy computed tomography. Subsamples of selected cores were analyzed for density, porosity, specific retention, and bulk minerology. Thin sections of the subsamples were prepared, photographed, and examined. Two samples were analyzed using scanning electron microscope technology to examine the microporosity of diatomite laden sediment. Instrumentation installed in the wells collect hourly depth to water measurements. Analysis of the data show there is 355 feet of alluvium overlying the Tulare Formation at the well site. The contact between the two formations is an aquitard resulting in a perched aquifer in the alluvium and unconfined aquifer in the Tulare Formation. The alluvium is more heterogenous and finer grained than the Tulare Formation resulting in markedly higher porosity in the alluvium compared to the Tulare Formation. Higher specific retention observed in the alluvium is attributed to the finer grained sediment and greater abundance of reworked diatomite (as represented by opal-CT [cristobalite-tridymite]) compared to the Tulare Formation. Total dissolved solids (TDS) approached or exceeded 10,000 milligrams per liter (mg/L) in the alluvium from approximately 176 to 242 feet below land surface and at the top of the Amnicola clay at approximately 670 feet below land surface within the Tulare Formation. Elevated TDS, chloride, and boron concentrations in the alluvium and on top of the Amnicola clay likely reflect groundwater that is mixed with oil-field water. Water chemistry and modern-aged groundwater in the alluvial monitoring well (MSBV #3) are consistent with the oil-field water in the alluvium being derived from documented historical surface disposal of oil-field water upslope (northwest) of the site. Water chemistry and pre-modern groundwater age in the deeper Tulare monitoring well (MSBV #1) on top of the Amnicola clay are consistent with oil-field fluids derived from upslope natural geologic sources or old oil wells that leak in the subsurface. Shallow groundwater in the Tulare (MSBV #2) is not affected by mixing with oil-field sources.

EarthArXiv↗

Map showing length of freeze-free season in the Salina quadrangle, Utah

In general, long freeze-free periods occur at low elevations, and short freeze-free periods occur at high elevations. But some valley floors have shorter freeze-free seasons than the glancing foothills because air cooled at high elevations flows downward and is trapped in the valleys. This temperature pattern occurs in the western part of the quadrangle in Rabbit Valley, Grass Valley, and the Sevier River Valley near Salina. Because year-round weather stations are sparse in Utah, a special technique for estimating length of freeze-free season was developed by Dr. Gaylen L. Ashcroft, Assistant Professor of Climatology, Utah State University, and E. Arlo Richardson, State Climatologist, U.S. Weather Bureau, based on average annual temperature, average annual temperature range, average daily temperature range, and average july maximum temperature. This technique was used in preparation of the map showing “Length of 32°F freeze-free season for Utah,” figure 23 in Hydrologic Atlas of Utah (Utah State University and Utah Division of Water Resources, 1968), from which the data for this map were taken.

Utah↗

Selected hydrologic data for the central Virgin River basin area, Washington and Iron Counties, Utah, 1915-97

Hydrologic data were collected in Washington and Iron Counties, Utah, from 1995 to 1997 to better understand the hydrologic system. Data from earlier years also are presented. Data collected from wells include well-completion data, water-level measurements, and physical properties of the water. Data collected from springs and surface-water sites include discharge and physical properties of the water. Selected water samples collected from ground- and surface-water sites were analyzed for isotopes, chlorofluorocarbons, and dissolved gases.

Utah↗

Hydrology of two small river basins in Pennsylvania before urbanization, with a section on observation of stream fauna

Basic data on water quantity, chemical quality, and suspended sediment are tabulated to record the conditions existing in two basins near Philadelphia, each about 32 square miles in area. The basins in 1970 are agricultural land for the most part, but urban and industrial development is imminent as the Philadelphia metropolitan area expands. Hopefully, as changes caused by urbanization occur in future years, data published herein will be useful as a base for comparison. Pickering Creek basin has a higher population than the upper East Branch Brandywine Creek basin. The two are comparable in discharge characteristics and in shapes and sizes of channels, but the Pickering Creek basin is producing a considerably larger suspended-sediment load. Also the effects of urbanization are discernible in some chemical parameters. During the study, a small subbasin, one-half square mile in area, was converted from agricultural use to an industrial park. This change resulted in a marked increase in sulfates, nitrates, chlorides, and dissolved solids in the streamflow.

Pennsylvania↗

Water quality of the St. Clair River, Lake St. Clair, and their U.S. tributaries, 1946-2005

The St. Clair River/Lake St. Clair waterway forms an international boundary between the United States and Canada. The waters of the area are an important part of the cultural heritage of the area and serves as an important water-supply and power-generating resource; the waterway also supports an economy based largely on recreation, agriculture, and manufacturing. This report was undertaken as part of the Lake St. Clair Regional Monitoring Project for the purpose of providing a comprehensive assessment of the hydrological, chemical, and physical state of the surface water of Lake St. Clair and its tributaries. The data varied in focus and density over the period of compilation which in many cases this variation prevented the completion of statistical analyses because data did not meet minimum comparability or quality requirements for those tests. Comparison of water quality of the Belle, Black, Clinton, and Pine River Basins, as well as basins of minor rivers in the study area, showed that water quality in many of the tributaries, particularly the Clinton River and some of the minor rivers, was degraded compared to the water quality of the St. Clair River/Lake St. Clair waterway. Data analyses included comparison of nutrients, chloride, specific conductance, turbidity, biochemical oxygen demand (BOD), and pesticides among the basins and the St. Clair River. Median concentrations of total nitrate were well below the recommended USEPA total nitrogen ambient water-quality criterion of 0.54 mg/L as N for nutrient ecoregion VII for all study-area streams except the Clinton River. More than 93 percent of the phosphorus concentrations for the Belle, Black, Pine and minor river basins and 84 percent of the phosphorus concentrations for the Clinton River Basin are greater than the USEPA recommended ambient total phosphorus criterion of 0.033 mg/L for rivers and streams. Nine chloride concentrations exceeded the USEPA criterion maximum concentration (CMC) for chloride set at 860 mg/L for all study-area streams, with the six largest being in the Belle River Basin. Higher chloride concentrations were increasingly common from 2002 to 2005. The urban minor river basins had the highest median specific conductance, whereas the agricultural Pine River Basin had the lowest median specific conductance. The median values of BOD for the five basins in the study area ranged from 2.4 mg/L for the Pine River Basin to 3.2 mg/L for the Black and Clinton River Basins, whereas the median for the St. Clair River was 0.5 mg/L. In 1985, the highest concentrations of pesticides were found in samples from the mouth of the Clinton River; however, in 1996–98, the majority of high pesticide concentrations were found in samples from the Black River. Changing land-use patterns, specifically conversion of agricultural lands to urban/residential lands in the Clinton River Basin, may explain this difference. Trend analysis was done for four stream sites where adequate data were available. These analyses identified no significant water-quality changes at a stream site on the Black River, where land-use patterns have changed little in the past few decades. This stands in marked contrast to trend analysis for three stream sites in the Clinton River Basin, which has undergone significant land-use change. The changes at the Clinton River stream sites, ranging from 5 to 13 significant trends, were generally decreases in nutrients and increases in total dissolved solids (TDS) and chloride. The greater flow volume of the St. Clair River/Lake St. Clair waterway is able to assimilate incoming dissolved and suspended constituents from tributaries with little effect upon its overall water quality, although incomplete mixing may result in localized water-quality impairment downstream from tributary confluences. Mixing effects on Lake St. Clair water quality was also demonstrated in analysis of Escherichia coli ( E. coli ) data collected at paired nearshore/offshore sites, which reflected similarity in water quality among many paired sites.

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