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Stratiform chromite deposit model

A new descriptive stratiform chromite deposit model was prepared which will provide a framework for understanding the characteristics of stratiform chromite deposits worldwide. Previous stratiform chromite deposit models developed by the U.S. Geological Survey (USGS) have been referred to as Bushveld chromium, because the Bushveld Complex in South Africa is the only stratified, mafic-ultramafic intrusion presently mined for chromite and is the most intensely researched. As part of the on-going effort by the USGS Mineral Resources Program to update existing deposit models for the upcoming national mineral resource assessment, this revised stratiform chromite deposit model includes new data on the geological, mineralogical, geophysical, and geochemical attributes of stratiform chromite deposits worldwide. This model will be a valuable tool in future chromite resource and environmental assessments and supplement previously published models used for mineral resource evaluation. Stratiform chromite deposits are found throughout the world, but the chromitite seams of the Bushveld Complex, South Africa, are the largest and most intensely researched. The chromite ore is located primarily in massive chromitite seams and, less abundantly, in disseminated chromite-bearing layers, both of which occur in the ultramafic section of large, layered mafic-ultramafic stratiform complexes. These mafic-ultramafic intrusions mainly formed in stable cratonic settings or during rift-related events during the Archean or early Proterozoic, although exceptions exist. The chromitite seams are cyclic in nature as well as laterally contiguous throughout the entire intrusion. Gangue minerals include olivine, pyroxenes (orthopyroxene and clinopyroxene), plagioclase, sulfides (pyrite, chalcopyrite, pyrrhotite, pentlandite, bornite), platinum group metals (mainly laurite, cooperite, braggite), and alteration minerals. A few deposits also contain rutile and ilmenite. The alteration phases include serpentine, chlorite, talc, magnetite, kaemmererite, uvarovite, hornblende, and carbonate minerals, such as calcite and dolomite. Stratiform chromite deposits are primarily hosted by peridotites, harzburgites, dunites, pyroxenites, troctolites, and anorthosites. Although metamorphism may have altered the ultramafic regions of layered intrusions postdeposition, only igneous processes are responsible for formation. From a diagnostic standpoint and for assessment purposes, they have no temporal or spatial relation to sedimentary rocks. The exact mechanisms responsible for the development of stratiform chromite deposits and the large, layered mafic-ultramafic intrusions where they are found are highly debated. The leading argument postulates that a parent magma mixed with a more primitive magma during magma chamber recharge. The partially differentiated magma could then be forced into the chromite stability field, resulting in the massive chromitite layers found in stratiform complexes. Contamination of the parent magma by localized assimilation of felsic country rock at the roof of the magma chamber has also been proposed as a mechanism of formation. Others suggest that changes in pressure or oxygen fugacity may be responsible for the occurrence of massive chromitite seams in layered mafic, ultramafic intrusions. The massive chromitite layers contain high levels of chromium and strong associations with platinum group elements. Anomalously high magnesium concentrations as well as low sodium, potassium, and phosphorus concentrations are also important geochemical features of stratiform chromite deposits. The presence of orthopyroxenite in many of the deposits suggests high silica and high magnesium concentrations in the parent magma. Most environmental concerns associated with the mining and processing of chromite ore focus on the solubility of chromium and its oxidation state. Although trivalent chromium (Cr 3+ ) is an essential micronutrient for humans, hexavalent chromium (Cr 6+ ) is highly toxic. Chromium-bearing solid phases that occur in the chromite ore-processing residue, for example, can effect the geochemical behavior and oxidation state of chromium in the environment.

Scientific Investigations Report↗

The future of nearshore processes research

The nearshore is the transition region between land and the continental shelf including (from onshore to offshore) coastal plains, wetlands, estuaries, coastal cliffs, dunes, beaches, surf zones (regions of wave breaking), and the inner shelf (Figure ES-1). Nearshore regions are vital to the national economy, security, commerce, and recreation. The nearshore is dynamically evolving, is often densely populated, and is under increasing threat from sea level rise, long-term erosion, extreme storms, and anthropogenic influences. Worldwide, almost one billion people live at elevations within 10 m of present sea level. Long-term erosion threatens communities, infrastructure, ecosystems, and habitat. Extreme storms can cause billions of dollars of damage. Degraded water quality impacts ecosystem and human health. Nearshore processes, the complex interactions between water, sediment, biota, and humans, must be understood and predicted to manage this often highly developed yet vulnerable nearshore environment. Over the past three decades, the understanding of nearshore processes has improved. However, societal needs are growing with increased coastal urbanization and threats of future climate change, and significant scientific challenges remain. To address these challenges, members of academia, industry, and federal agencies (USGS, USACE, NPS, NOAA, FEMA, ONR) met at the “The Past and Future of Nearshore Processes Research: Reflections on the Sallenger Years and a New Vision for the Future” workshop to develop a nearshore processes research vision where societal needs and science challenges intersect. The resulting vision is comprised of three broad research themes: Long-term coastal evolution due to natural and anthropogenic processes: As global climate change alters the rates of sea level rise and potentially storm patterns and coastal urbanization increases over the coming decades, an understanding of coastal evolution is critical. Improved knowledge of long-term morphological, ecological, and societal processes and their interactions will result in an improved ability to simulate coastal change. This will enable proactive solutions for resilient coasts and better guidance for reducing coastal vulnerability. Extreme Events: Flooding, erosion, and the subsequent recovery: Hurricane Sandy caused flooding and erosion along hundreds of miles of shoreline, flooded New York City, and impacted communities and infrastructure. Overall U.S. coastal extreme event related economic losses have increased substantially. Furthermore, climate change may cause an increase in coastal extreme events and rising sea levels could increase the occurrence of extreme events. Addressing this research theme will result in an improved understanding of the physical processes during extreme events, leading to improved models of flooding, erosion, and recovery. The resulting societal benefit will be more resilient coastal communities. The physical, biological and chemical processes impacting human and ecosystem health: Nearshore regions are used for recreation, tourism, and human habitation, and provide habitat and valuable ecosystem services. These areas must be sustained for future generations, however overall coastal water quality is declining due to microbial pathogens, fertilizers, pesticides, and heavy metal contamination, threatening ecosystem and human health. To ensure sustainable nearshore regions, predictive real-time water- and sediment-based based pollutant modeling capabilities must be developed, which requires expanding our knowledge of the physics, chemistry, and biology of the nearshore. The resulting societal benefits will include better beach safety, healthier ecosystems, and improved mitigation and regulatory policies. The scientists and engineers of the U.S. nearshore community are poised to make significant progress on these research themes, which have significant societal impact. The U.S. nearshore community, including academic, government, and industry colleagues, recommends multi-agency investment into a coordinated development of observational and modeling research infrastructure to address these themes, as discussed in the whitepaper. The observational infrastructure should include development of new sensors and methods, focused observational programs, and expanded nearshore observing systems. The modeling infrastructure should include improved process representation, better model coupling, incorporation of data assimilation techniques, and testing of real-time models. The observations will provide test beds to compare and improve models.

Report↗

Assessment of prerestoration water quality in the Herring River to support adaptive management at the Cape Cod National Seashore

In 2020 and 2021, the U.S. Geological Survey, Cape Cod National Seashore of the National Park Service, and Friends of Herring River cooperated to assess nutrient and suspended sediment concentrations across the ocean-estuary boundary at a dike on the Herring River on Chequessett Neck Road in Wellfleet, Massachusetts, that has restricted saltwater inputs by regulating water inflow through three culverts or sluiceways into the watershed for more than 100 years. The dike is slated to be removed, and the purpose of this project was to characterize natural variability of nutrient and suspended sediment concentration during flood tide and ebb tide conditions at the dike based on seasonal and environmental variables. This baseline can be used to assess if removal of the dike is likely to result in measurable changes in water quality. Data from the current [2023] study were aggregated with previously published data from November 2015 through September 2018 to provide a long-term record. Samples for the current [2023] study were collected from flood and following ebb tides approximately twice per month from June 2020 through December 2021 at fixed time intervals after the beginning of the tides. Samples were analyzed for nitrate plus nitrite, ammonium, total dissolved nitrogen, total nitrogen, orthophosphate, total dissolved phosphorus, total phosphorus, silica, dissolved organic carbon, and suspended sediment. Constituent concentrations generally were lower using fixed time sampling than in previous studies that used flow-weighted composite sampling, except for nitrate plus nitrite and orthophosphate. Concentrations of nitrate plus nitrite, ammonium, total nitrogen, total dissolved nitrogen, silica, and dissolved organic nitrogen generally were higher on the ebb tide than on the flood tide. By contrast, concentrations of orthophosphate, total phosphorus, and total dissolved phosphorus were generally similar between flood and ebb tides. Most nutrient concentrations except silica and ammonium varied seasonally on flood and ebb tides. Phosphorus species, total nitrogen, and dissolved organic carbon concentrations generally peaked in mid- to late summer and were lowest in winter. For nitrate, the reverse was true. Nutrient concentrations generally were higher on the ebb tide than on the flood tide except for total dissolved phosphorus and total phosphorus where differences between flood and ebb tide depended on season. Constituent concentrations were similar between spring, neap, and midamplitude tides on both the flood and ebb tides. Nitrate, ammonium, total nitrogen, and silica concentrations were positively correlated with precipitation and runoff. Orthophosphate, total dissolved phosphorus, total phosphorus, and dissolved organic carbon were positively correlated with surface air temperature, downwelling shortwave radiation, and ocean water temperature. Nitrate, ammonium, and silica concentration were negatively correlated with surface air temperature and ocean water temperature. Orthophosphate and total dissolved phosphorus were negatively correlated with runoff. Nitrate plus nitrite, ammonium, and silica concentrations were negatively correlated with downwelling shortwave radiation.

Massachusetts↗

Wildland fire effects on sediment, salinity, and selenium yields in a basin underlain by Cretaceous marine shales near Rangely, Colorado

Understanding and quantifying soil erosion from rangelands is a high priority for land managers, especially in areas underlain by Cretaceous Mancos Shale, which is a natural source of sediment, salinity, and selenium to surface waters in many areas of western Colorado and eastern Utah. The purpose of this report is to present the results of a U.S. Geological Survey study that assessed sediment, salinity, and selenium yields after the Dead Dog wildfire (fire began June 11, 2017) in northwestern Colorado. Two methodologies were used to quantify erosion, with different data requirements and analytical complexity. The first approach was the use of a process-based erosion model, the Watershed Erosion Prediction Project, which uses inputs of climate, topography, vegetation, and soils data from existing datasets to predict erosion, making this approach easily extensible to other areas. The second approach required more complex data collection and was used to measure erosion and deposition by differencing digital elevation models created from uncrewed aerial vehicle imagery collected in 2016 (pre-fire) and 2021 (post-fire). Sediment, salinity, and selenium yields were calculated from the volumetric estimates of erosion from both methods, and a discussion of factors that may have contributed to overall findings, including vegetation, fire effects, and soil characteristics, is included. The two approaches yielded different outputs. Results from the Watershed Erosion Prediction Project model indicated that almost no erosion occurred after the Dead Dog fire. However, morphological changes in the study basin after the Dead Dog fire were visible in the pre- and post-fire imagery and measured in the digital elevation model differencing technique, with net erosion occurring in channel and landscape extents, though calculated erosion rates and salinity and selenium yields were relatively small. Visible and measured morphological changes consisted primarily of incision and deposition within stream channels and rill incision and expansion on steeper slopes. Widespread sheet erosion was not evident. Much of the new erosion originated within, and immediately below, previously vegetated areas that were then burned by the wildfire. Greater erosion rates and salinity and selenium yields were measured in the channel extent relative to the landscape extent. Calculated erosion rates ranged from 0.24 to 0.45 megagrams per hectare per year. These results indicate that the Dead Dog fire resulted in increased erosion in the study basin, yet these effects were relatively small based on the overall magnitude of modeled and measured erosion from the Watershed Erosion Prediction Project and the digital elevation model differencing technique. Minimal erosion in the basin is likely due to local site characteristics typical of soils derived from Mancos Shale, including the presence of robust physical crusts and biological soil crusts, and limitations of the methods based on data availability. Focusing uncrewed aerial vehicle flights on key areas (individual steep slopes, high-intensity burn areas, specific stream reaches) could likely increase understanding of erosional process with less effort and error than doing landscape-level flights.

Colorado↗

Analysis of remedial scenarios affecting plume movement through a sole-source aquifer system, southeastern Nassau County, New York

A steady-state three-dimensional groundwater-flow model based on present conditions is coupled with the particle-tracking program MODPATH to assess the fate and transport of volatile organic-compound plumes within the Magothy and upper glacial aquifers in southeastern Nassau County, New York. Particles are forward tracked from locations within plumes defined by surfaces of equal concentration. Particles move toward ultimate well capture and discharge to the general head and drain boundaries representing natural receptors in the models. Because rates of advection within coarse-grained sediments typically exceed 0.1 foot per day, mechanisms of dispersion and diffusion were assumed to be negligible. Resulting particle pathlines are influenced by hydrogeologic framework features and the interplay of nearby hydrologic stresses. Simulated hydrologic effects include cones of depression near pumping wells and water-table mounding near points of treated water recharge; however, remedial pumping amounts are balanced by treated-water return, and net effects at distant regional boundaries, including freshwater/saltwater interfaces, are minor. Once a steady-state model was developed and calibrated, eight hypothetical remedial scenarios were evaluated to hydraulically contain the volatile organic-compound plumes. Specifically, the remedial scenarios were optimized to achieve full containment by altering the pumping-well locations, adjusting the pumping rates, and adjusting the discharge locations and rates. Based on the results, total hypothetical extraction rates varied from about 5,462 gallons per minute during an anticipated near-future condition to about 13,340 gallons per minute during full hydraulic containment of all site-related compounds identified by the New York State standards, criteria, and guidance for environmental investigations and cleanup. Targeting of high-concentration zones of the plume increases the total amount of remedial pumpage necessary to capture all parts of the plume but may decrease the total amount of time necessary to operate a remedial system. Simulated time frames of advective transport ranged from about 12 years to capture zones with elevated concentrations of volatile organic compounds (mean particle travel time plus the standard deviation of travel time) to more than 100 years to capture all zones. Groundwater-flow model analysis indicates that all the optimal plume-containment scenarios would have negligible effects on streams and the saltwater-freshwater interface along the south shore of Long Island. Massapequa, Bellmore, Seaman, and Seaford Creeks are represented by using MODFLOW drain-boundary conditions. Saltwater-freshwater interfaces are represented by using MODFLOW general head-boundary conditions where the Magothy aquifer discharges upward into saline groundwater across the Gardiners clay confining unit and the Lloyd aquifer discharges upward into saline groundwater across the Raritan confining unit.

New York↗

Field Surveys of Rare Plants on Santa Cruz Island, California, 2003-2006: Historical Records and Current Distributions

Santa Cruz Island is the largest of the northern Channel Islands located off the coast of California. It is owned and managed as a conservation reserve by The Nature Conservancy and the Channel Islands National Park. The island is home to nine plant taxa listed in 1997 as threatened or endangered under the federal Endangered Species Act, because of declines related to nearly 150 years of ranching on the island. Feral livestock were removed from the island as a major conservation step, which was part of a program completed in early 2007 with the eradication of pigs and turkeys. For the first time in more than a century, the rare plants of Santa Cruz Island have a chance to recover in the wild. This study provides survey information and living plant materials needed for recovery management of the listed taxa. We developed a database containing information about historical collections of the nine taxa and used it to plan a survey strategy. Our objectives were to relocate as many of the previously known populations as possible, with emphasis on documenting sites not visited in several decades, sites that were poorly documented in the historical record, and sites spanning the range of environmental conditions inhabited by the taxa. From 2003 through 2006, we searched for and found 39 populations of the taxa, indicating that nearly 80 percent of the populations known earlier in the 1900s still existed. Most populations are small and isolated, occupying native-dominated habitat patches in a highly fragmented and invaded landscape; they are still at risk of declining through population losses. Most are not expanding beyond the edges of their habitat patches. However, most taxa appeared to have good seed production and a range of size classes in populations, indicating a good capacity for plant recruitment and population growth in these restricted sites. For these taxa, seed collection and outplanting might be a good strategy to increase numbers of populations for species recovery. Several taxa have particular problems evidenced by lack of fruit set, very small population sizes, or unstable habitats. We collected seeds of all but two taxa for seed banking, and live cuttings of two clonal shrubs for cultivation at the Santa Barbara Botanic Garden. The survey data, seeds and cuttings provide a baseline and a foundation for planning, conducting, and tracking recovery of the nine federally listed plant taxa of Santa Cruz Island.

Scientific Investigations Report↗

Water-quality response to changes in phosphorus loading of the Winnebago Pool Lakes, Wisconsin, with special emphasis on the effects of internal loading in a chain of shallow lakes

The Winnebago Pool is a chain of four shallow lakes (Lake Poygan, Lake Winneconne, Lake Butte des Morts, and Lake Winnebago) that are fed primarily by the Fox and Wolf Rivers, two large agriculturally dominated rivers in Wisconsin, United States. Because the lakes have received extensive phosphorus inputs from their watershed, they have become highly eutrophic with much phosphorus in the water column as well as trapped in their sediments. Each of the four Winnebago Pool lakes has been included on the Wisconsin Department of Natural Resources impaired waters list because of their high total phosphorus concentrations, water-quality use restrictions, and excess algal growth. The study described in this report is part of a Total Maximum Daily Load investigation to determine what actions are needed to improve the water quality (trophic status) of these lakes and thus be able to be removed from the impaired waters list and restore their designated uses. As part of this study, data were collected to describe the existing water quality of the lakes, detailed phosphorus budgets were developed for each of the lakes to describe the different sources of the phosphorus, and two eutrophication models (BATHTUB and Jensen models) were used to determine how much of the phosphorus being input to the lakes needs to be reduced for the lakes to be removed from the impaired waters list and restore their designated uses. In-lake water-quality data indicated that each of the lakes had extensive vertical mixing that resulted in their water quality deteriorating throughout summer. Each of the lakes had mean summer total phosphorus concentrations exceeding 0.088 milligram per liter (mg/L), well above the 0.040 mg/L criterion for the lakes. Detailed phosphorus budgets for the lakes indicated that the primary sources of phosphorus were from their tributaries (for the most upstream lake in the Winnebago Pool–Lake Poygan) or from a combination of input from the upstream lakes and phosphorus release from the bottom sediment when only the summer months were considered (for the other three lakes). Model simulations with the BATHTUB and Jensen models indicated that (1) the lakes should have almost linear response in their total phosphorus concentrations to changes in their phosphorus inputs; (2) phosphorus inputs need to be reduced by about 60 percent to the Upper Pool Lakes and 69–73 percent to Lake Winnebago to reduce their mean summer total phosphorus concentrations to 0.040 mg/L; and (3) if all the anthropogenic phosphorus inputs to the lakes could be eliminated, their best possible mean summer total phosphorus concentrations should decrease to about 0.022–0.028 mg/L in the Upper Pool Lakes and to 0.032–0.033 mg/L in Lake Winnebago. The effects of any reduction in phosphorus loading will take many years (50 to more than 75 years) to be fully realized in lake water quality because of phosphorus release from the lake sediments. The effects of nutrient reductions in the watershed of a chain of lakes, such as the Winnebago Pool, gradually cascades down the chain, which has beneficial and detrimental effects. Any action made in the watershed of upstream lakes to reduce phosphorus inputs should improve the water quality of all downstream lakes; however, the upstream lakes delay the response in the downstream lakes, especially in lakes where internal phosphorus loading is important.

Wisconsin↗

Assessment of soil and water contaminants from selected locations in and near the Idaho Army National Guard Orchard Training Area, Ada County, Idaho, 2001-2003

In 2001, the National Guard Bureau and the U.S. Geological Survey began a project to compile hydrogeologic data and determine presence or absence of soil, surface-water, and ground-water contamination at the Idaho Army National Guard Orchard Training Area in southwestern Idaho. Between June 2002 and April 2003, a total of 114 soil, surface-water, ground-water, precipitation, or dust samples were collected from 68 sample sites (65 different locations) in the Orchard Training Area (OTA) or along the vehicle corridor to the OTA. Soil and water samples were analyzed for concentrations of selected total trace metals, major ions, nutrients, explosive compounds, semivolatile organics, and petroleum hydrocarbons. Water samples also were analyzed for concentrations of selected dissolved trace metals and major ions. Distinguishing naturally occurring large concentrations of trace metals, major ions, and nutrients from contamination related to land and water uses at the OTA was difficult. There were no historical analyses for this area to compare with modern data, and although samples were collected from 65 locations in and near the OTA, sampled areas represented only a small part of the complex OTA land-use areas and soil types. For naturally occurring compounds, several assumptions were made?anomalously large concentrations, when tied to known land uses, may indicate presence of contamination; naturally occurring concentrations cannot be separated from contamination concentrations in mid- and lower ranges of data; and smallest concentrations may represent the lowest naturally occurring range of concentrations and (or) the absence of contaminants related to land and water uses. Presence of explosive, semivolatile organic (SVOC), and petroleum hydrocarbon compounds in samples indicates contamination from land and water uses. In areas along the vehicle corridor and major access roads within the OTA, most trace metal, major ion, and nutrient concentrations in soil samples were not in the upper 10th percentile of data, but concentrations of 25 metals, ions, or nutrients were in the upper 10th percentile in a puddle sample near the heavy equipment maneuvering area, MPRC-H. The largest concentrations of tin, ammonia, and nitrite plus nitrate (as nitrogen) in water from the OTA were detected in a sample from this puddle. Petroleum hydrocarbons were the most common contaminant, detected in all soil and surface-water samples. An SVOC, bis (2-ethylhexyl) phthalate, a plasticizer, was detected at a site along the vehicle corridor. In Maneuver Areas within the OTA, many soil samples contained at least one trace metal, major ion, or nutrient in the upper 10th percentile of data, and the largest concentrations of cobalt, iron, mercury, titanium, sodium, ammonia, or total phosphorus were detected in 6 of 13 soil samples outside the Tadpole Lake area. The largest concentrations of aluminum, arsenic, beryllium, nickel, selenium, silver, strontium, thallium, vanadium, chloride, potassium, sulfate, and nitrite plus nitrate were detected in soil samples from the Tadpole Lake area. Water from Tadpole Lake contained the largest total concentrations of 19 trace metals, 4 major ions, and 1 nutrient. Petroleum hydrocarbons were detected in 5 soil samples and water from Tadpole Lake. SVOCs related to combustion of fuel or plasticizers were detected in 1 soil sample. Explosive compounds were detected in 1 precipitation sample.In the Impact Area within the OTA, most soil samples contained at least one trace metal, major ion, or nutrient in the upper 10th percentile of data, and the largest concentrations of barium, chromium, copper, manganese, lead, or orthophosphate were detected in 6 of the 18 soil samples. Petroleum hydrocarbons were detected in 4 soil samples, SVOCs in 6 samples, and explosive compounds in 4 samples. In the mobilization and training equipment site (MATES) compound adjacent to the OTA, all soil and water samples contained at lea

Scientific Investigations Report↗

Streamflow gain and loss and water quality in the upper Nueces River Basin, south-central Texas, 2008-10

The U.S. Geological Survey-in cooperation with the U.S. Army Corps of Engineers, The Nature Conservancy, the Real Edwards Conservation and Reclamation District, and the Texas Parks and Wildlife Department-investigated streamflow gain and loss and water quality in the upper Nueces River Basin, south-central Texas, specifically in the watersheds of the West Nueces, Nueces, Dry Frio, Frio, and Sabinal Rivers upstream from the Edwards aquifer outcrop. Streamflow in these rivers is sustained by groundwater contributions (for example, from springs) and storm runoff from rainfall events. To date (2012), there are few data available that describe streamflow and water-quality conditions of the rivers within the upper Nueces River Basin. This report describes streamflow gain-loss characteristics from three reconnaissance-level synoptic measurement surveys (hereinafter referred to as "surveys") during 2008-10 in the upper Nueces River Basin. To help characterize the hydrology, groundwater-level measurements were made, and water-quality samples were collected from both surface-water and groundwater sites in the study area from two surveys during 2009-10. The hydrologic (streamflow, springflow, and groundwater) measurements were made during three reconnaissance-level synoptic measurement surveys occurring in July 21-23, 2008; August 8-18, 2009; and March 22-24, 2010. These survey periods were selected to represent different hydrologic conditions. Streamflow gains and losses were based on streamflow and springflow measurements made at 74 sites in the study area, although not all sites were measured during each survey. Possible water chemistry relations among sample types (streamflow, springflow, or groundwater), between surveys, and among watersheds were examined using water-quality samples collected from as many as 20 sites in the study area. During the three surveys, reaches of gaining, losing, or no verifiable change in streamflow were observed in the watersheds in the study area. Reaches of generally consistent gaining or losing streamflow were identified in the Nueces, Frio, and Sabinal River watersheds. The water-quality data indicate that the streamflow, springflow, and groundwater have similar major ion chemical characteristics and generally can be categorized as a calcium-carbonate water type. Those data also indicate that the major ion chemistry was similar during the 2009 and 2010 surveys. Graphical comparisons among ratios of major ions, trace elements, and isotopes (for example, magnesium/calcium ratios to strontium isotopic ratios) indicate that samples collected from each watershed generally clustered together. Determining the source areas and other possible contributors on the basis of these data is not possible because of the small sample size of the water-quality dataset (both in number of samples and spatial distribution of samples). The different relations among the water-quality data indicate that the surface water in the different watersheds is likely influenced by differences in source areas, geochemical evolution, groundwater flow paths and residence time, local stratigraphy, or some combination thereof.

Texas↗

USGS—An Unparalleled Scientific Asset

The U.S. Geological Survey (USGS) delivers information critical to powering our economy, managing our natural resources, and keeping Americans safe and healthy. 1 Mapping the Nation $21B Geologic maps save users an estimated 15% in annual costs: a value of between $14B and $21B. $25.6B in annual value to users of imagery from Landsat satellites, which were codeveloped by NASA and the USGS and operated through their lifespans by the USGS. $13.5B in annual benefits is generated by the USGS's 3D Elevation Program. Securing America’s Energy Independence 44% USGS-identified undiscovered geothermal energy is equal to 44% of current U.S. electricity generation. 29.4B barrels of oil and 391.6 trillion cubic feet of gas in recoverable resources are available on U.S. public lands based on USGS assessments. Protecting Americans’ Health and Safety $424B in recent wildland fire damages highlight the need for USGS fire science, which supports efforts to protect communities and reduce risk. USGS earthquake, volcano, landslide, and coastal hazard monitoring and information save lives and minimize costs; for example, $2.8M can be saved because of USGS enhanced information about a Mauna Loa eruption. $4.5B is the estimated cost of annual flooding. Through a network of over 11,885 streamgages, the USGS supports public safety and enables forecasts, early warning systems, and management actions that protect lives and property. Supporting National Security $3.1B The USGS identified a $3.1B risk to the American economy if China restricts gallium imports. This is one example underscoring the importance of the USGS mapping critical minerals, investigating supply chains, and producing the Nation’s critical minerals list. Enhancing Our Lands and Waters $21B in estimated annual costs results from invasive species. The USGS’s invasive species research informs approaches used to reduce their effects on agriculture, water infrastructure, disease transmission, fisheries, and outdoor recreation. USGS innovations support early warnings for harmful algal blooms—over $2M in yearly benefits are provided to Kansas alone. $45B USGS science informs the management of big game (such as deer and elk). The big-game hunting industry contributes $45B to the U.S. economy. Fostering American Prosperity $4.1T Mineral commodities are necessary for the $4.1T in value added to the GDP by major industries that consume processed mineral materials and employ 1 million workers. Because of this, USGS data on mineral supply, demand, and trade are highly valued. 45,000 metric tons Rare earths power the growing technology economy, including cell phones, electric vehicles, and medical devices. For over 70 years, USGS work has supported the discovery of rare earth resources in California’s Mountain Pass area, which produced 45,000 metric tons of rare earth concentrates in 2024—over 11% of the global supply. Guarding American Food Security $70.2B USGS science informs early warning systems and management strategies to mitigate disease outbreaks in agriculture—critical research on highly pathogenic avian influenza, for example, helps safeguard the $70B value in poultry and egg production. $11.8B USGS groundwater tools are vital for agriculture; for example, in the Mississippi Alluvial Plain, 65% of farming relies on groundwater to support its $11.8B annual industry. 1 Values throughout are given in billions (B), millions (M), and trillions (T) of U.S. dollars. GDP is “Gross Domestic Product.” Percentages are shown as %.

General Information Product↗

Status and understanding of groundwater quality in the North San Francisco Bay groundwater basins, 2004: California GAMA Priority Basin Project

Groundwater quality in the approximately 1,000-square-mile (2,590-square-kilometer) North San Francisco Bay study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in northern California in Marin, Napa, and Sonoma Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA North San Francisco Bay study was designed to provide a spatially unbiased assessment of untreated groundwater quality in the primary aquifer systems. The assessment is based on water-quality and ancillary data collected by the USGS from 89 wells in 2004 and water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer systems (hereinafter referred to as primary aquifers) were defined by the depth interval of the wells listed in the CDPH database for the North San Francisco Bay study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifers; shallower groundwater may be more vulnerable to surficial contamination. The first component of this study, the status of the current quality of the groundwater resource, was assessed by using data from samples analyzed for volatile organic compounds (VOC), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources within the primary aquifers of the North San Francisco Bay study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal and (or) California benchmarks. A relative-concentration greater than (>) 1.0 indicates a concentration above a benchmark, and less than or equal to (≤) 1.0 indicates a concentration equal to or below a benchmark. Relative-concentrations of organic and special interest constituents were classified as “high” (relative-concentration > 1.0), “moderate” (0.1 < relative-concentration ≤ 1.0), or “low” (relative-concentration ≤ 0.1). Inorganic constituent relative-concentrations were classified as “high” (relative-concentration > 1.0), “moderate” (0.5 < relative-concentration ≤ 1.0), or “low” (relative-concentration ≤ 0.5). Aquifer-scale proportion was used as a metric for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the primary aquifers that have a relative-concentration greater than 1.0; proportion is calculated on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifers that have moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based and spatially-weighted—were used to evaluate aquifer-scale proportion for individual constituents and classes of constituents. Grid-based and spatially-weighted estimates were comparable in the North San Francisco Bay study unit (90-percent confidence intervals). For inorganic constituents with human-health benchmarks, relative-concentrations were high in 14.0 percent of the primary aquifers, moderate in 35.8 percent, and low in 50.2 percent. The high aquifer-scale proportion of inorganic constituents primarily reflected high aquifer-scale proportions of arsenic (10.0 percent), boron (4.1 percent), and lead (1.6 percent). In contrast, relative-concentrations of organic constituents (one or more) were high in 1.4 percent, moderate in 4.9 percent, and low in 93.7 percent (not detected in 64.8 percent) of the primary aquifers. The high aquifer-scale proportion of organic constituents primarily reflected high aquifer-scale proportions of PCE (1.3 percent), TCE (0.1 percent), and 1,1-dichloroethene (0.1 percent). The inorganic constituents with secondary maximum contaminant levels (SMCL), manganese and iron, had relative-concentrations that were high in 40.8 percent and 24.4 percent of the primary aquifers, respectively. Of the 255 organic and special-interest constituents analyzed for, 26 constituents were detected. Two organic constituents were frequently detected (in 10 percent or more of samples), the trihalomethane chloroform and the herbicide simazine, but both were detected at low relative-concentrations. The second component of this study, the understanding assessment, identified the natural and human factors that affect groundwater quality by evaluating land use, physical characteristics of the wells, geochemical conditions of the aquifer, and water temperature. Results from these evaluations were used to explain the occurrence and distribution of constituents in the study unit. The understanding assessment indicated that a majority of the wells that contained nitrate also had an urban or agricultural land-use classification, had a modern or mixed age classification, and had depths to their top perforations <100 ft (30 m). Geochemical data are consistent with partial denitrification of nitrate in some reducing groundwaters in the terminal and deeper parts of the flow system. High and moderate relative-concentrations of arsenic may be attributed to reductive dissolution of manganese or iron oxides, or to desorption or inhibition of arsenic sorption under alkaline conditions. Arsenic concentrations increased with increasing depth and groundwater age in the North San Francisco Bay study unit. High to moderate relative-concentrations of boron were primarily associated with hydrothermal activity or high-salinity waters in the Napa Sonoma lowlands. Simazine was detected in groundwater classified as modern and mixed age more often than in groundwater classified as pre-modern age, while chloroform was detected most often in groundwater classified as mixed age. Simazine and chloroform also were observed in wells that had surrounding land use classified as agricultural or land use classified as urban, and top of perforation depths less than 100 ft (30 m). Together, the occurrence of chloroform and simazine in shallow wells with modern or mixed groundwater located in urban or agricultural areas suggests that these constituents result from anthropogenic activities during the last 50 years. Tritium, helium-isotope, and carbon-14 data were used to classify the predominant age of groundwater samples into three categories: modern (water that has entered the aquifer in the last 50 years), pre-modern (water that entered the aquifer more than 50 years to tens of thousands of years ago), and mixed (mixtures of modern- and pre-modern-age waters). Arsenic, iron, and total dissolved solids (TDS) concentrations were significantly greater in groundwater having pre-modern-age classification than modern, suggesting that these constituents accumulate with groundwater residence time.

California↗

The occurrence of trace elements in bed sediment collected from areas of varying land use and potential effects on stream macroinvertebrates in the conterminous western United States, Alaska, and Hawaii, 1992-2000

As part of the National Water-Quality Assessment Program of the U.S. Geological Survey, this study examines the occurrence of nine trace elements in bed sediment of varying mineralogy and land use and assesses the possible effects of these trace elements on aquatic-macroinvertebrate community structure. Samples of bed sediment and macroinvertebrates were collected from 154 streams at sites representative of undeveloped, agricultural, urban, mined, or mixed land-use areas and 12 intermediate-scale ecoregions within the conterminous western United States, Alaska, and Hawaii from 1992 to 2000. The nine trace elements evaluated during this study—arsenic (As), cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), mercury (Hg), nickel (Ni), selenium (Se), and zinc (Zn)—were selected on the basis of potential ecologic significance and availability of sediment-quality guidelines. At most sites, the occurrence of these trace elements in bed sediment was at concentrations consistent with natural geochemical abundance, and the lowest concentrations were in bed-sediment samples collected from streams in undeveloped and agricultural areas. With the exception of Zn at sampling sites influenced by historic mining-related activities, median concentrations of all nine trace elements in bed sediment collected from sites representative of the five general land-use areas were below concentrations predicted to be harmful to aquatic macroinvertebrates. The highest concentrations of As, Cd, Pb, and Zn were in bed sediment collected from mined areas. Median concentrations of Cu and Ni in bed sediment were similarly enriched in areas of mining, urban, and mixed land use. Concentrations of Cr and Ni appear to originate largely from geologic sources, especially in the western coastal states (California, Oregon, and Washington), Alaska, and Hawaii. In these areas, naturally high concentrations of Cr and Ni can exceed concentrations that may adversely affect aquatic macroinvertebrates. Generally, Hg concentrations were below the sediment-quality guideline for this trace element but appeared elevated in urbanized areas and at sites contaminated by historic mining practices. Lastly, although there was no distinctive pattern in Se concentrations with land use, median bed-sediment concentrations were slightly elevated in urbanized areas. Macroinvertebrate community structure was influenced by topographic, geologic, climatic, and in-stream characteristics. To account for inherent distribution patterns resulting from these influences, samples of macroinvertebrates were stratified by ecoregion to assess the influence of trace elements on community structure. Cumulative toxic units (CTUs) were used to evaluate gradients in trace-element concentrations in mixture. Correlation analyses among the trace elements under different land-use conditions indicate that trace-element mixtures vary among bed sediment and can have a marked influence on CTU composition. Macroinvertebrate response to bed-sediment trace-element exposure was evident only at the most highly contaminated sites, notably at sites classified as contaminated by the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) as a result of historic mining activities. Results of this study agree with the findings of other studies evaluating trace-element exposure to in-stream macroinvertebrate community structure in that generally lower richness metrics and taxa dominance occur in streams where high trace-element enrichment occurs; however, not all streams in all areas have the same characterizing taxa. In the mountain and xeric ecosystems, the mayfly, Baetis sp.; the Diptera, Simulium sp.; caddisflies in the family Hydropsychiidae; midges in the family Orthocladiinae; and the worms belonging to Turbellaria and Naididae all demonstrated resilience to trace-element exposure and, in some cases, possible changes in physical habitat within stream ecosystems. The taxa characteristics within the Ozark Highland ecoregion were different than other ecoregions as evidenced by generally more diverse mayfly populations. In addition, Baetis sp. was common and dominated many of the mayfly populations found in the Rocky Mountain streams within the Mountain Southern Rockies and Mountain Northern Rockies ecoregions; however, within the Ozark Highland ecoregion, Tricorythodes sp. appeared to be more common than Baetis sp.

Alaska, Arizona, California, Colorado, Hawai'i, Id↗

Simulation of daily streamflow for nine river basins in eastern Iowa using the Precipitation-Runoff Modeling System

The U.S. Geological Survey, in cooperation with the Iowa Department of Natural Resources, constructed Precipitation-Runoff Modeling System models to estimate daily streamflow for nine river basins in eastern Iowa that drain into the Mississippi River. The models are part of a suite of methods for estimating daily streamflow at ungaged sites. The Precipitation-Runoff Modeling System is a deterministic, distributed- parameter, physical-process-based modeling system developed to evaluate the response of streamflow and general drainage basin hydrology to various combinations of climate and land use. Calibration and validation periods used in each basin mostly were October 1, 2002, through September 30, 2012, but differed depending on the period of record available for daily mean streamflow measurements at U.S. Geological Survey streamflow-gaging stations. A geographic information system tool was used to delineate each basin and estimate values for model parameters based on basin physical and geographical features. A U.S. Geological Survey auto-calibration tool that uses a shuffled complex evolution algorithm was used for initial calibration, and then manual modifications were made to parameter values to complete the calibration of each basin model. The main objective of the calibration was to match daily discharge values of simulated streamflow to measured daily discharge values. The accuracy of Precipitation-Runoff Modeling System model streamflow estimates of nine river basins in eastern Iowa as compared to measured values at U.S. Geological Survey streamflow-gaging stations varied. The Precipitation-Runoff Modeling System models of nine river basins in eastern Iowa were satisfactory at estimating daily streamflow at 57 of the 79 calibration sites and 13 of the 14 validation sites based on statistical results. Unsatisfactory performance can be contributed to several factors: (1) low flow, no flow, and flashy flow conditions in headwater subbasins having a small drainage area; (2) poor representation of the groundwater and storage components of flow within a basin; (3) lack of accounting for basin withdrawals and water use; and (4) the availability and accuracy of meteorological input data. The Precipitation- Runoff Modeling System models of nine river basins in eastern Iowa will provide water-resource managers with a consistent and documented method for estimating streamflow at ungaged sites and aid in environmental studies, hydraulic design, water management, and water-quality projects.

Iowa↗

Streamflow gains and losses in New Fork and Green Rivers, upstream from Fontenelle Reservoir, Wyoming, October 2015

The Wyoming Landscape Conservation Initiative is a program created to implement a long-term, science-based program of assessing natural resources while facilitating responsible energy and other development and does studies in much of southwestern Wyoming, including all or parts of Lincoln, Sublette, Fremont, Sweetwater, and Carbon Counties. A synoptic study was completed by the U.S. Geological Survey as part of ongoing contributions to the Wyoming Landscape Conservation Initiative to better understand the streamflow dynamics in the New Fork and Green Rivers in an area with historical, current, and future energy development. Streamflow measurements were collected October 19–22, 2015, at 19 sites on the New Fork and Green Rivers in Wyoming to determine changes in streamflow and, where applicable, describe the inflow and outflow of groundwater. Streamflow in the New Fork River generally increased from 50 cubic feet per second (ft 3 /s) at the most upstream site near Pinedale, Wyoming, to 350 ft 3 /s at the mouth of the river. Streamflow in the Green River generally increased downstream from 250 ft 3 /s at the most upstream site at Warren Bridge to around 800 ft 3 /s at the most downstream site near La Barge, Wyo., upstream from Fontenelle Reservoir. Estimated streamflow gains and losses were calculated for five reaches on the New Fork River. Four of the five reaches on the New Fork River had a change greater than the associated measurement error and were gaining reaches; the reach with the largest gain was the most upstream reach. One reach, the most downstream reach, had a calculated change in streamflow less than the associated measurement error. Estimated streamflow gains and losses were calculated for four reaches on the Green River. One reach was determined to be a gaining reach, one was a losing reach, and two reaches had changes less than the associated measurement error. Comparing the annual streamflow hydrographs for three long-term streamgages likely showed the effects of applying irrigation water to the upstream areas of land draining to the Green and New Fork Rivers. Streamflows in the New Fork River near Big Piney and the Green River near La Barge, Wyo., are sustained later in the season compared to the upstream site of Green River at Warren Bridge, which has few diversions and minimal irrigation.

Wyoming↗

Methods for estimating selected low-flow frequency and mean annual flow statistics at gaged and ungaged locations on streams in Georgia, North Carolina, and South Carolina

The U.S. Geological Survey, in cooperation with the Georgia Department of Natural Resources (Environmental Protection Division), North Carolina Department of Environmental Quality (Division of Water Resources), North Carolina Department of Public Safety (Office of Recovery and Resiliency), and South Carolina Department of Environmental Services, updated low-flow frequency, mean annual flow, and flow-duration statistics at 843 streamgages in and near Georgia, North Carolina, and South Carolina. The low-flow frequency statistics are annual minimum 1-day average flow with a 10-year recurrence interval (1Q10), annual minimum 7-day average flow for 2- and 10-year recurrence intervals (7Q2 and 7Q10, respectively), and annual minimum 30-day average flow with 2- and 3-year recurrence intervals (30Q2 and 30Q3, respectively). Monthly 1Q10 and 7Q10, and W7Q10 flow statistics for the winter period (November–March) also are presented. By using data from 604 of the streamgages on streams with streamflows that are not substantially affected by regulation or diversion and are not tidally influenced, regional regression equations were developed to predict flow statistics with prediction intervals at ungaged locations on streams with those same criteria. The regional regression analysis included data from 132 streamgages from adjacent States Alabama, Florida, Tennessee, and Virginia. The final regional regression equations include variables such as drainage area, streamflow variability, precipitation, percentage of impervious area, and percentage of the basin in various ecoregions. The low-flow statistics for the streamgages analyzed and the regional regression equations will be integrated into the U.S. Geological Survey StreamStats application ( https://www.usgs.gov/streamstats ) for Georgia, North Carolina, and South Carolina. StreamStats generates basin characteristics needed to compute low-flow frequency statistics for ungaged locations. A trend analysis of annual minimum 7-day average flows was done for 78 streamgages with at least 30 years of continuous record. Trends were evaluated for 30-, 50‑, 70-, and 90-year periods, ending in climate year 2021, and independence and short- and long-term persistence assumptions were considered. For all trend analysis assumptions, most streamgages did not exhibit significant trends in annual minimum 7-day average flows. Trends in annual precipitation and air temperature were similarly evaluated for the period 1895–2021 to assess the variability of climate for Georgia, North Carolina, and South Carolina.

Georgia, North Carolina, South Carolina↗

Fate and transport of petroleum hydrocarbons in the subsurface near Cass Lake, Minnesota

The U.S. Geological Survey (USGS) investigated the natural attenuation of subsurface petroleum hydrocarbons leaked over an unknown number of years from an oil pipeline under the Enbridge Energy Limited Partnership South Cass Lake Pumping Station, in Cass Lake, Minnesota. Three weeks of field work conducted between May 2007 and July 2008 delineated a dissolved plume of aromatic hydrocarbons and characterized the biodegradation processes of the petroleum. Field activities included installing monitoring wells, collecting sediment cores, sampling water from wells, and measuring water-table elevations. Geochemical measurements included concentrations of constituents in both spilled and pipeline oil, dissolved alkylbenzenes and redox constituents, sediment bioavailable iron, and aquifer microbial populations. Groundwater in this area flows east-southeast at approximately 26 meters per year. Results from the oil analyses indicate a high degree of biodegradation, characterized by nearly complete absence of n-alkanes. Cass Lake oil samples were more degraded than two oil samples collected in 2008 from the similarly contaminated USGS Bemidji, Minnesota, research site 40 kilometers away. Based on 19 ratios developed for comparing oil sources, the conclusion is that the oils at the two sites appear to be from the same hydrocarbon source. In the Cass Lake groundwater plume, benzene concentrations decrease by three orders of magnitude within 150 meters (m) downgradient from the oil body floating on the water table (between well MW-10 and USGS-4 well nest). The depths of the highest benzene concentrations increase with distance downgradient from the oil, a condition typical of plumes in shallow, unconfined aquifers. Background groundwater, which is nearly saturated with oxygen, becomes almost entirely anaerobic in the plume. As at the Bemidji site, the most important biodegradation processes are anaerobic and dominated by iron reduction. The similarity between the Cass Lake and Bemidji benzene degradation rates, redox conditions, and aquifer material all support a hypothesis that the Cass Lake plume, like the Bemidji plume, is decades old. As concentrations of alkylbenzenes in the oil decrease over time, the benzene concentrations in the groundwater plume will also decrease and the plume is expected to shrink. The Fox Creek wetland, about 250 m south of the Cass Lake site, is the nearest receptor to the south.

Scientific Investigations Report↗

Assessment of fecal contamination sources to Alley Creek, Queens County, New York, August 2020–June 2021

Alley Creek, a tributary to Little Neck Bay in Queens County, New York, has been designated by the New York State Department of Environmental Conservation as impaired (Class I) for fecal coliform because of pollution from combined sewer overflow, including stormwater runoff. The U.S. Geological Survey, in cooperation with the New York City Department of Environmental Protection, conducted a 1-year study from August 2020 to June 2021 using microbial source tracking (MST) methods to assess potential host sources of fecal contamination (for example, human, canine, and waterfowl) from the following: three outfall sites, TI–025, TI–008, and TI–024; an artesian well (Q277) adjacent to Alley Creek; and natural waters within the Alley Creek watershed and Little Neck Bay. In addition to analyzing for MST markers, field measurements such as water temperature and specific conductance, samples for total suspended solids, and fecal indicator bacteria (FIB; enterococci and fecal coliform) were collected. Pharmaceutical compounds were also collected for analysis, and the results of sampling were compared spatially and temporally to help support management decisions related to mitigation of fecal sources to Alley Creek. Factors that could affect concentrations, including tidal conditions, seasonality, and weather conditions, also were assessed. A sediment resuspension laboratory experiment was designed to replicate tidal activity in Alley Creek using sediment collected in the sewers and on the shoreline, as well as water collected from Oakland Lake. These sediment samples were assessed to understand the relation between sediment resuspension and FIB in the water column. The human MST markers used for this study, Bacteroides HF183/BacR287, and crAssphage CPQ_056 and CPQ_064, were detected in most samples (27 of 28) collected at the three outfall sites along Alley Creek, whereas the canine marker BacCan was less prevalent (20 of 28 samples) but exhibited a pattern of relative concentrations similar to the human markers. The waterfowl MST GFD marker was detected in 7 of 28 samples collected at the three outfall sites. Human MST markers were not detected at Oakland Lake (which drains through a combined sewer line to Alley Creek at TI–008), indicating minimal or nonexistent influence of sewage contamination in the lake. Groundwater samples collected from Q277 did not contain any MST markers, and concentrations of fecal coliform were less than 10 colony forming units per 100 milliliters. Although FIB did not correlate well with total suspended solids for individual sample sets, samples collected following precipitation and high-turbidity events were typically found to have higher concentrations of FIB than dry-weather samples. Results from the pharmaceutical compounds analysis provided additional evidence for determining known and suspected human sources when coupled with MST markers. Together, the MST, pharmaceutical, and FIB data generated by this study, along with supplementary data such as locations of point sources, locations of wildlife populations, and tidal exchange data, may provide reliable information on source identification and transport mechanisms of fecal contamination to Alley Creek.

New York↗

Hydrogeology and Simulated Ground-Water Flow in the Salt Pond Region of Southern Rhode Island

The Salt Pond region of southern Rhode Island extends from Westerly to Narragansett Bay and forms the natural boundary between the Atlantic Ocean and the shallow, highly permeable freshwater aquifer of the South Coastal Basin. Large inputs of fresh ground water coupled with the low flushing rates to the open ocean make the salt ponds particularly susceptible to eutrophication and bacterial contamination. Ground-water discharge to the salt ponds is an important though poorly quantified source of contaminants, such as dissolved nutrients. A ground-water-flow model was developed and used to delineate the watersheds to the salt ponds, including the areas that contribute ground water directly to the ponds and the areas that contribute ground water to streams that flow into ponds. The model also was used to calculate ground-water fluxes to these coastal areas for long-term average conditions. As part of the modeling analysis, adjustments were made to model input parameters to assess potential uncertainties in model-calculated watershed delineations and in ground-water discharge to the salt ponds. The results of the simulations indicate that flow to the salt ponds is affected primarily by the ease with which water is transmitted through a glacial moraine deposit near the regional ground-water divide, and by the specified recharge rate used in the model simulations. The distribution of the total freshwater flow between direct ground-water discharge and ground-water-derived surface-water (streamflow) discharge to the salt ponds is affected primarily by simulated stream characteristics, including the streambed-aquifer connection and the stream stage. The simulated position of the ground-water divide and, therefore, the model-calculated watershed delineations for the salt ponds, were affected only by changes in the transmissivity of the glacial moraine. Selected changes in other simulated hydraulic parameters had substantial effects on total freshwater discharge and the distribution of direct ground-water discharge and ground-water-derived surface-water (streamflow) discharge to the salt ponds, but still provided a reasonable match to the hydrologic data available for model calibration. To reduce the uncertainty in predictions of watershed areas and ground-water discharge to the salt ponds, additional hydrogeologic data would be required to constrain the model input parameters that have the greatest effect on the simulation results.

Scientific Investigations Report↗