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At least 1,531 records · Page 85Linked to original sources

USGS2000

Implementation strategy for production of National Land-Cover Data (NLCD) from the Landsat 7 Thematic Mapper satellite

As environmental programs within and outside the federal government continue to move away from point-based studies to larger and larger spatial (not cartographic) scale, the need for land-cover and other geographic data have become ineluctable. The national land-cover mapping project of MRLC marks the first consistently classified conterminous land-cover data set, effectively replacing USGS' Land Use Data Analysis (LUDA) system derived from high altitidue aerial photography acquired in the early 1970's. Because of the continually changing nature of the earth's surface due to anthropogenic activities and other factors, a single point-in-time land-cover product is insufficient for many applications. Production of a second point-in-time land-cover product is proposed as a database. That proposed database design includes: (1) second, independently classified land-cover data set derived from Landsat 7 Thematic Mapper data; (2) the land-cover product being produced under the current effort, (3) selected spectral-based change estimates (e.g., temporal NDVI), (4) thirty-meter DEMS; and (5) selected landscape metrics. Development of the database for the conterminous United States will start after evaluation of the prototype.

Technical Report↗

USGS2014

Description of landscape features, summary of existing hydrologic data, and identification of data gaps for the Osage Nation, northeastern Oklahoma, 1890-2012

The Osage Nation of northeastern Oklahoma, conterminous with Osage County, is characterized by gently rolling uplands and incised stream valleys that have downcut into underlying sedimentary rock units of Pennsylvanian through Permian age. Cattle ranching and petroleum and natural-gas extraction are the principal land uses in this rural area. Freshwater resources in the Osage Nation include water flowing in the Arkansas River and several smaller streams, water stored in several lakes, and groundwater contained in unconsolidated alluvial aquifers and bedrock aquifers. The Vamoosa-Ada aquifer is the primary source of fresh groundwater in this area. Fresh groundwater is underlain by saline groundwater in aquifers underlying the Osage Nation. Because of the potential for future population increases, demands for water from neighboring areas such as the Tulsa metropolitan area, and expansion of petroleum and natural-gas extraction on water resources of this area, the U.S. Geological Survey, in cooperation with the Osage Nation, summarized existing hydrologic data and identified data gaps to provide information for planning of future development of water resources in the Osage Nation. Streamflows in the Osage Nation are substantially affected by precipitation. During the relatively wet periods from the 1970s to 2000, the annual streamflows in the Osage Nation increased by as much as a factor of 2 relative to preceding decades, with subsequent decreases in streamflow of as much as 50 percent being recorded during intermittent drier years of the early 2000s. This report summarizes hydrologic data from 3 surface-water sites and 91 wells distributed across the Osage Nation. Data collected at those sites indicate that surface water in the Osage Nation generally has sufficient dissolved oxygen for survival of both coldwater and warmwater aquatic biota. Total dissolved solids concentration exceeded the secondary drinking-water standard of 500 milligrams per liter (mg/L) in up to 75 percent of the surface-water samples, indicating limited availability of potable water at some sites. Some surface-water samples collected in the Osage Nation contained dissolved chloride concentrations exceeding the secondary drinking-water standard of 250 mg/L, with greater chloride concentrations in selected basins appearing to be associated with greater densities of petroleum well locations. Several lakes sampled in the Osage Nation from 2011–12 contained sufficient chlorophyll-a concentrations to be ranked as mesotrophic to eutrophic, indicating impairment by nutrients. Relatively large dissolved phosphorus concentrations in many surface-water samples, compared to water-quality standards, indicate that eutrophication can occur in local streams and lakes. The amount of fresh groundwater stored in alluvial aquifers and the Vamoosa-Ada bedrock aquifer is adequate for domestic and other purposes in the Osage Nation at the current rate of usage. In areas where these aquifers are absent, groundwater must be pumped from minor bedrock aquifers that produce smaller volumes of water. About 30 and 60 percent of 32 and 54 water samples collected from the alluvial and Vamoosa-Ada aquifers, respectively, contained total dissolved solids concentrations larger than the secondary drinking-water standard of 500 mg/L. Local factors, such as natural seepage of brines or leakage from petroleum and natural-gas extraction activities, may cause substantial variations in dissolved chloride concentration in groundwater in the Osage Nation. Total phosphorus concentrations measured in groundwater samples were similar to dissolved phosphorus concentrations measured in the base flow of several streams. Total fresh surface-water withdrawals (use) and fresh groundwater withdrawals in the Osage Nation were estimated to have increased from 0.75 to 16.19 million gallons per day and from 0.13 to 2.39 million gallons per day, respectively, over the period from 1890 through 2010. Estimated saline-groundwater reinjection volumes at the heavily developed Burbank Oil Field in the Osage Nation from 1950 through 2012 were many times larger than the total amounts of freshwater withdrawn in this area, with estimated increases in saline-groundwater reinjection in the 2000s probably being related to increased petroleum extraction. Estimates of freshwater resources in local streams, lakes, and freshwater aquifers and of net annual precipitation indicate that less than 1 percent of freshwater resources and net annual precipitation currently is being withdrawn annually in the Osage Nation. In addition to freshwater resources, the Osage Nation may be underlain by 45,000,000 million gallons of brines, a small portion of which are withdrawn and reinjected during petroleum and natural-gas extraction. Ongoing development of desalinization technology may lead to the ability to expand use of these saline waters in the future. Several additional studies could improve understanding of the hydrologic resources of the Osage Nation. Development of computer models (simulations) of groundwater and surface-water flow for this area could enable testing of scenarios of localized and widespread effects of future climate variations and water-use changes on streamflows, lake-water levels, and groundwater levels in the Osage Nation. Installation of additional long-term streamflow and water-quality sampling stations, some with continuous water-quality monitors, could expand and improve understanding of surface-water quality. Periodic measurement of groundwater levels and sampling of water from a network of wells could provide better information about trends of groundwater quantity and quality with time. Measurement of water withdrawals at selected sites could enable more accurate estimates of water use. Lastly, better understanding of aquifer properties and spatial distribution of saline groundwater provided by geophysical surveys could improve understanding of fresh and saline groundwater resources underlying the Osage Nation.

Oklahoma↗

USGS2021

Applying assessments of adaptive capacity to inform natural-resource management in a changing climate

Adaptive capacity (AC)—the ability of a species to cope with or accommodate climate change—is a critical determinant of species vulnerability. Using information on species’ AC in conservation planning is key to ensuring successful outcomes. We identified connections between a list of species’ attributes (e.g., traits, population metrics, and behaviors) that were recently proposed for assessing species’ AC and management actions that may enhance AC for species at risk of extinction. Management actions were identified based on evidence from the literature, a review of actions used in other climate adaptation guidance, and our collective experience in diverse fields of global-change ecology and climate adaptation. Selected management actions support the general AC pathways of persist in place or shift in space, in response to contemporary climate change. Some actions, such as genetic manipulations, can be used to directly alter the ability of species to cope with climate change, whereas other actions can indirectly enhance AC by addressing ecological or anthropogenic constraints on the expression of a species’ innate abilities to adapt. Ours is the first synthesis of potential management actions directly linked to AC. Focusing on AC attributes helps improve understanding of how and why aspects of climate are affecting organisms, as well as the mechanisms by which management interventions affect a species’ AC and climate change vulnerability. Adaptive-capacity-informed climate adaptation is needed to build connections among the causes of vulnerability, AC, and proposed management actions that can facilitate AC and reduce vulnerability in support of evolving conservation paradigms.

Conservation Biology↗

USGS1972

Microcrystalline sphalerite in resin globules suspended in Lake Kivu, East Africa

The origin and chemical nature of micron-sized spheres found as suspended particles in Lake Kivu are examined. It can be shown that the hollow spheres, with a wall thickness of 500 Å, consist of a complex polymeric resinous material which has little functionality, except for hydroxyl groups. The spheres arise in the process of degassing of water samples at depth. Tiny gas bubbles, about 1 micron in size, act as scavengers of dissolved resinous material. The newly created resinous membrane promotes the selective coordination of zinc dissolved in the water column. In the prevailing H 2 S regime, formation of sphalerite crystals in induced. The size range of the crystals, 5 to 50 Å, corresponds to 1 to 10 unit cells and suggests that the resinous membrane also acts as a template in sphalerite growth processes. The sources of the zinc and dissolved gases (CO 2 , CH 4 , H 2 S) are hydrothermal springs seeping from the lake bottom into the basin. Water discharge is substantial; about 100 years are required to fill the lake to its present level (ca. 550 km 3 water). The average Kivu water contains 2 ppm zinc. Thus, 1 million tons of zinc are contained in Lake Kivu in the form of sphalerite.

Lake Kivu↗

USGS2009

Depth-dependent sampling to identify short-circuit pathways to public-supply wells in multiple aquifer settings in the United States

Depth-dependent water-quality and borehole flow data were used to determine where and how contamination enters public-supply wells (PSWs) at study sites in different principal aquifers of the United States. At each of three study sites, depth-dependent samples and wellbore flow data were collected from multiple depths in selected PSWs under pumping conditions. The chemistry of these depth-dependent samples, along with samples of the surface discharge from the PSWs, was compared to that of adjacent nested monitoring wells. The results of depth-dependent analyses from sites in Modesto (California), York (Nebraska), and Tampa (Florida) are summarized and compared. Although the exact mechanisms for transport of contaminants to the PSWs varied among these hydrogeologic settings, in all three settings the presence of wells or boreholes or natural preferential flow paths allowed water and contaminants to bypass substantial portions of the aquifer and to reach PSWs or depths in the aquifer more quickly than would have occurred in the absence of these short-circuiting flow paths. The chemistry and flow data from multiple depths was essential to developing an understanding of the dominant flow paths of contaminants to PSW in all three settings. This knowledge contributes to developing effective strategies for monitoring and protection.

Hydrogeology Journal↗

USGS2003

Database of historically documented springs and spring flow measurements in Texas

Springs are naturally occurring features that convey excess ground water to the land surface; they represent a transition from ground water to surface water. Water issues through one opening, multiple openings, or numerous seeps in the rock or soil. The database of this report provides information about springs and spring flow in Texas including spring names, identification numbers, location, and, if available, water source and use. This database does not include every spring in Texas, but is limited to an aggregation of selected digital and hard-copy data of the U.S. Geological Survey (USGS), the Texas Water Development Board (TWDB), and Capitol Environmental Services.

Texas↗

USGS2023

Guidelines for field-measured water-quality properties

The “National Field Manual for the Collection of Water-Quality Data” (NFM) provides guidelines and procedures for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation’s surface-water and groundwater resources. This chapter, NFM A6.0, provides guidance and protocols for the measurement of field parameters on site, which include the selection of sites and methods for measurement in groundwater and surface water and procedures for measurement and reporting. It updates and supersedes USGS Techniques of Water-Resources Investigations, book 9, chapter A6.0, version 2.0, by Franceska D. Wilde. Field parameters are routinely measured when water samples are collected, are often measured continually at USGS streamgages, and are regularly measured during laboratory and field experiments. The field methods for measuring field parameters described in this chapter are applicable to most natural waters. Before 2017, the NFM chapters were released in the USGS Techniques of Water-Resources Investigations series. Effective in 2018, new and revised NFM chapters are being released in the USGS Techniques and Methods series; this series change does not affect the content and format of the NFM. More information is in the general introduction to the NFM (USGS Techniques and Methods, book 9, chapter A0) at https://doi.org/10.3133/tm9A0 . The authoritative current versions of NFM chapters are available in the USGS Publications Warehouse at https://pubs.er.usgs.gov/ . Comments, questions, and suggestions related to the NFM can be addressed to nfm@usgs.gov .

Techniques and Methods↗

USGS1995

Sea otters and kelp forests in Alaska: Generality and variation in a community ecological paradigm

Multiscale patterns of spatial and temporal variation in density and population structure were used to evaluate the generality of a three—trophic—level cascade among sea otters (Enhydra lutris), invertebrate herbivores, and macroalgae in Alaska. The paradigm holds that where sea otters occur herbivores are rare and plants are abundant, whereas when sea otters are absent herbivores are relatively common and plants are rare. Spatial patterns were based on 20 randomly placed quadrats at 153 randomly selected sites distributed among five locations with and four locations without sea otters. Both sea urchin and kelp abundance differed significantly among locations with vs. without sea otters in the Aleutian Islands and southeast Alaska. There was little (Aleutian Islands) or no (southeast Alaska) overlap between sites with and without sea otters, in plots of kelp density against urchin biomass. Despite intersite variation in the abundance of kelps and herbivores, these analyses demonstrate that sea otter predation has a predictable and broadly generalizable influence on the structure of Alaskan kelp forests. The percent cover of algal turf and suspension feeder assemblages also differed significantly (although less dramatically) between locations with and without sea otters. Temporal variation in community structure was assessed over periods of from 3 to 15 yr at sites in the Aleutian Islands and southeast Alaska where sea otters were 1) continuously present, 2) continuously absent, or 3) becoming reestablished because of natural range expansion. Kelp and sea urchin abundance remained largely unchanged at most sites where sea otters were continuously present or absent, the one exception being at Torch Bay (southeast Alaska), where kelp abundance varied significantly through time and urchin abundance varied significantly among sites because of episodic and patchy disturbances. In contrast, kelp and sea urchin abundances changed significantly, and in the expected directions, at sites that were being recolonized by sea otters. Sea urchin biomass declined by 50% in the Aleutian Islands and by nearly 100% in southeast Alaska following the spread of sea otters into previously unoccupied habitats. In response to these different rates and magnitudes of urchin reduction by sea otter predation, increases in kelp abundance were abrupt and highly significant in southeast Alaska but much smaller and slower over similar time periods in the Aleutian Islands. The different kelp colonization rates between southeast Alaska and the Aleutian Islands appear to be caused by large—scale differences in echinoid recruitment coupled with size—selective predation by sea otters for larger urchins. The length of urchin jaws (correlated with test diameter, r 2 = 0.968) in sea otter scats indicates that sea urchins <15—20 mm test diameter are rarely eaten by foraging sea otters. Sea urchin populations in the Aleutian Islands included high densities of small individuals (<20 mm test diameter) at all sites and during all years sampled, whereas in southeast Alaska similarly sized urchins were absent from most populations during most years. Small (<30—35 mm test diameter) tetracycline—marked urchins in the Aleutian Islands grew at a maximum rate of °10 mm/yr; thus the population must have significant recruitment annually, or at least every several years. In contrast, echinoid recruitment in southeast Alaska was more episodic, with many years to perhaps decades separating significant events. Our findings help explain regional differences in recovery rates of kelp forests following recolonization by sea otters.

Alaska↗

USGS1961

Occurrence of minor elements in water

Three basic studies, using spectrographic methods, have been used to establish the occurrence of minor elements in natural waters. One study, of oceanborne chemicals in principal rivers, has established a method for the quantitative analysis of many minor elements. Strontium, barium, lithium, rubidium, chromium, nickel, copper, lead, boron, titanium, molybdenum, manganese, and vanadium occur most frequently in measurable quantities. Reconnaissance of the strontium in surface waters of the United States, shows that surface waters in parts of northern and western Texas and southern New Mexico and Arizona are comparatively high in strontium. A study of minor elements in selected waters of California is continuing. Assessment of preliminary data on uranium and radium in waters is facilitated by grouping data for 10 geotectonic regions of the United States.

Circular↗

USGS2019

Chapter A6.3. Specific Conductance

The “National Field Manual for the Collection of Water-Quality Data” (NFM) provides guidelines and procedures for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation’s surface-water and groundwater resources. This chapter, NFM A6.3, provides guidance and protocols for the measurement of specific conductance of a water sample, which include the scientific basis of the measurement, selection and maintenance of equipment, calibration, troubleshooting, and procedures for measurement and reporting. It updates and supersedes USGS Techniques of Water-Resources Investigations, book 9, chapter A6.3, version 1.2, by D.B. Radtke, J.V. Davis, and F.D. Wilde. Specific conductance is routinely measured when water samples are collected, is often measured continually at USGS streamgages, and is a parameter regularly measured during laboratory and field experiments. The field method for measuring specific conductance described in this chapter is applicable to most natural waters. Before 2017, the NFM chapters were released in the USGS Techniques of Water-Resources Investigations series. Effective in 2018, new and revised NFM chapters are being released in the USGS Techniques and Methods series; this series change does not affect the content and format of the NFM. More information is in the general introduction to the NFM (USGS Techniques and Methods, book 9, chapter A0) at https://doi.org/10.3133/tm9A0 . The authoritative current versions of NFM chapters are available in the USGS Publications Warehouse at https://pubs.er.usgs.gov. Comments, questions, and suggestions related to the NFM can be addressed to nfm@usgs.gov .

Techniques and Methods↗

USGS1994

Estimation of low-flow duration discharges in Massachusetts

Equations for estimating the 95-, 98-, and 99-percent duration discharges for streams in Massachusetts with natural flow conditions were developed by use of weighted-least-squares regression analyses. Record extension methods were used to estimate the low-flow statistics for sites used in the regression analyses that were lacking complete record during the base period of October 1, 1962 through September 30, 1987. Basin characteristics used as independent variables in the regression analyses were measured by use of a computerized geographic information system. The equations were used to estimate the duration discharges for 72 selected sites in eastern Massachusetts.

Water Supply Paper↗

USGS2011

Resource selection by black-footed ferrets in South Dakota and Montana

The black-footed ferret (Mustela nigripes), once extinct in the wild, remains one of the most critically endangered mammals in North America despite 18 years of reintroduction attempts. Because black-footed ferrets are specialized predators of prairie dogs (Cynomys sp.), a better understanding of how black-footed ferrets select resources might provide insight into how best to identify and manage reintroduction sites. We monitored ferret resource selection at two reintroduction sites with different densities of prairie dog populations-one that contained a high density of prairie dogs (Conata Basin, South Dakota) and one that was lower (UL Bend, Montana). We evaluated support for hypotheses about ferret resource selection as related to the distribution of active burrows used by black-tailed prairie dogs (Cynomys ludovicianus), interactions between ferrets, and habitat edge effects. We found support for all three factors within both populations; however, they affected ferret resource selection differently at each site. Ferrets at Conata Basin tended to select areas with high prairie dog burrow density, closer to the colony edge, and that overlapped other ferret ranges. In contrast, ferrets at UL Bend tended not to select areas of high active prairie dog burrow density, avoided areas close to edge habitat, and females avoided areas occupied by other ferrets. The differences observed between the two sites might be best explained by prairie dog densities, which were higher at Conata Basin (119.3 active burrows per ha) than at UL Bend (44.4 active burrows per ha). Given the positive growth of ferret populations at Conata Basin, management that increases the density of prairie dogs might enhance ferret success within natural areas. To achieve long-term recovery of ferrets in the wild, conservationists should increasingly work across and outside natural area boundaries to increase prairie dog populations.

Natural Areas Journal↗

USGS2002

The exotic mute swan (Cygnus olor) in Chesapeake Bay, USA

The exotic mute swan (Cygnus olor) has increased its population size in Chesapeake Bay (Maryland and Virginia) to approximately 4,500 since 1962 when five swans were released in the Bay. The Bay population of mute swans now represents 30% of the total Atlantic Flyway population (12,600) and has had a phenomenal increase of 1,200% from 1986 to 1999. Unlike the tundra swans (Cygnus columbianus) that migrate to the Bay for the winter, the mute swan is a year-long resident, and, therefore, reports of conflicts with nesting native waterbirds and the consumption of submerged aquatic vegetation (SAV) have raised concerns among resource managers. Populations of black skimmers (Rynchops niger) and least terns (Sterna antillarum) nesting on beaches and oyster shell bars have been eliminated by molting mute swans. Although data on the reduction of SAV by nesting mute swans and their offspring during the spring and summer are limited, food habits data show that mute swans rely heavily on SAV during these months. Widgeon grass (Ruppia maritima) constituted 56% and eel grass (Zostera marina) constituted 43% of the gullet food of mute swans. Other SAV and invertebrates (including bryozoans, shrimp, and amphipods) formed a much smaller amount of the food percentage (1%). Invertebrates are believed to have been selected accidently within the vegetation eaten by the swans. Corn (Zea mays) fed to swans by Bay residents during the winter probably supplement limited vegetative food resources in late winter. A program to control swan numbers by the addling of eggs and the killing of adult swans has been a contentious issue with some residents of the Bay area. A management plan is being prepared by a diverse group of citizens appointed by the Governor to advise the Maryland Department of Natural Resources on viable and optimum options to manage mute swans in the Maryland portion of Chesapeake Bay. Hopefully, the implementation of the plan will alleviate the existing conflicts to the betterment of all resources.

Book chapter↗

USGS2016

Baseline assessment of groundwater quality in Wayne County, Pennsylvania, 2014

The Devonian-age Marcellus Shale and the Ordovician-age Utica Shale, geologic formations which have potential for natural gas development, underlie Wayne County and neighboring counties in northeastern Pennsylvania. In 2014, the U.S. Geological Survey, in cooperation with the Wayne Conservation District, conducted a study to assess baseline shallow groundwater quality in bedrock aquifers in Wayne County prior to potential extensive shale-gas development. The 2014 study expanded on previous, more limited studies that included sampling of groundwater from 2 wells in 2011 and 32 wells in 2013 in Wayne County. Eighty-nine water wells were sampled in summer 2014 to provide data on the presence of methane and other aspects of existing groundwater quality throughout the county, including concentrations of inorganic constituents commonly present at low levels in shallow, fresh groundwater but elevated in brines associated with fluids extracted from geologic formations during shale-gas development. Depths of sampled wells ranged from 85 to 1,300 feet (ft) with a median of 291 ft. All of the groundwater samples collected in 2014 were analyzed for bacteria, major ions, nutrients, selected inorganic trace constituents (including metals and other elements), radon-222, gross alpha- and gross beta-particle activity, selected man-made organic compounds (including volatile organic compounds and glycols), dissolved gases (methane, ethane, and propane), and, if sufficient methane was present, the isotopic composition of methane. Results of the 2014 study show that groundwater quality generally met most drinking-water standards, but some well-water samples had one or more constituents or properties, including arsenic, iron, pH, bacteria, and radon-222, that exceeded primary or secondary maximum contaminant levels (MCLs). Arsenic concentrations were higher than the MCL of 10 micrograms per liter (µg/L) in 4 of 89 samples (4.5 percent) with concentrations as high as 20 µg/L; arsenic concentrations were higher than the Health Advisory level of 2 µg/L in 27 of 89 samples (30 percent). Total iron concentrations exceeded the secondary maximum contaminant level (SMCL) of 300 µg/L in 9 of 89 samples (10 percent). The pH ranged from 5.4 to 9.3 and did not meet the SMCL range of greater than 6.5 to less than 8.5 in 27 samples (30 percent); 22 samples had pH values less than 6.5, and 5 samples had pH values greater than 8.5. Total coliform bacteria were detected in 22 of 89 samples (25 percent); Escherichia coli were detected in only 2 of those 22 samples. Radon-222 activities ranged from 25 to 7,400 picocuries per liter (pCi/L), with a median of 2,120 pCi/L, and exceeded the proposed drinking-water standard of 300 pCi/L in 86 of 89 samples (97 percent); radon-222 activities were higher than the alternative proposed standard of 4,000 pCi/L in 12 of 89 samples (13.5 percent). Water from 8 of the 89 wells (9 percent) had concentrations of methane greater than the reporting level of 0.24 milligrams per liter (mg/L) with the detectable methane concentrations ranging from 0.74 to 9.6 mg/L. Of 16 replicate samples submitted to another laboratory with a lower reporting level of 0.0002 mg/L, 15 samples had detectable methane concentrations that ranged from 0.0011 to 9.7 mg/L. Of these 15 samples, low levels of ethane (0.00032 to 0.0017 mg/L) were detected in 6 of 7 samples with methane concentrations greater than 0.75 mg/L. The isotopic composition of methane in 6 of 8 samples with sufficient dissolved methane (about 1 mg/L) for isotopic analysis is consistent with a predominantly thermogenic methane source (sample carbon isotopic ratio δ13C CH4 values ranging from -56.36 to -45.97 parts per thousand (‰) and hydrogen isotopic ratio δD CH4 values ranging from -233.1 to -141.1 ‰). However, the low levels of ethane relative to methane indicate that the methane may be of microbial origin and subsequently underwent oxidation. Isotopic compositions indicated a possibly mixed thermogenic and microbial source (carbon dioxide reduction process) for the methane in 1 of the 8 samples (δ 13 C CH4 of -63.72 and δD CH4 of -192.3 ‰) and potential oxidation of microbial and (or) thermogenic methane in the remaining sample (δ 13 C CH4 of -46.56 and δD CH4 of -79.7 ‰). Groundwater samples with relatively elevated methane concentrations (near or greater than 1 mg/L) had a chemical composition that differed in some respects (pH, selected major ions, and inorganic trace constituents) from groundwater with relatively low methane concentrations (less than 0.75 mg/L). The seven well-water samples with the highest methane concentrations (from about 1 to 9.6 mg/L) also had among the highest pH values (8.1 to 9.3, respectively) and the highest concentrations of sodium, lithium, boron, fluoride, arsenic, and bromide. Relatively elevated concentrations of some other constituents, such as barium, strontium, and chloride, commonly were present in, but not limited to, those well-water samples with elevated methane. Groundwater samples with the highest methane concentrations had chloride/bromide ratios that indicate mixing with a small amount of brine (0.02 percent or less, by volume) similar in composition to that reported for gas and oil well brines in Pennsylvania. Most other samples with low methane concentrations (less than about 1 mg/L) had chloride/bromide ratios that indicate predominantly man-made sources of chloride, such as road salt, septic systems, and (or) animal waste. Although naturally occurring brines may originate from deeper parts of the aquifer system, the man-made sources are likely to affect shallow groundwater. Geochemical modeling showed that the water chemistry of samples with elevated pH, sodium, lithium, bromide, and alkalinity could result from dissolution of calcite (calcium carbonate) combined with cation exchange and mixing with a small amount of brine. Through cation exchange reactions (which are equivalent to processes in a water softener) calcium ions released by calcite dissolution are exchanged for sodium ions on clay minerals. The spatial distribution of groundwater compositions generally shows that (1) relatively dilute, slightly acidic, oxygenated, calcium-carbonate type waters tend to occur in the uplands along the western border of Wayne County; (2) waters of near neutral pH with the highest amounts of hardness (calcium and magnesium) generally occur in areas of intermediate altitudes; and (3) waters with pH values greater than 8, low oxygen concentrations, and the highest arsenic, sodium, lithium, bromide, and methane concentrations can occur in deep wells in uplands but most frequently occur in stream valleys, especially at low elevations (less than about 1,200 ft above North American Vertical Datum of 1988) where groundwater may be discharging regionally, such as to the Delaware River. Thus, the baseline assessment of groundwater quality in Wayne County prior to gas-well development shows that shallow (less than about 1,000 ft deep) groundwater is generally of good quality, but methane and some constituents present in high concentrations in brine (and produced waters from gas and oil wells) may be present at low to moderate concentrations in some parts of Wayne County.

Pennsylvania↗

USGS2005

Occurrence of fecal-indicator bacteria and protocols for identification of fecal-contamination sources in selected reaches of the West Branch Brandywine Creek, Chester County, Pennsylvania

The presence of fecal-indicator bacteria indicates the potential presence of pathogens originating from the fecal matter of warm-blooded animals. These pathogens are responsible for numerous human diseases ranging from common diarrhea to meningitis and polio. The detection of fecal-indicator bacteria and interpretation of the resultant data are, therefore, of great importance to water-resource managers. Current (2005) techniques used to assess fecal contamination within the fluvial environment primarily assess samples collected from the water column, either as grab samples or as depth- and (or) width-integrated samples. However, current research indicates approximately 99 percent of all bacteria within nature exist as attached, or sessile, bacteria. Because of this condition, most current techniques for the detection of fecal contamination, which utilize bacteria, assess only about 1 percent of the total bacteria within the fluvial system and are, therefore, problematic. Evaluation of the environmental factors affecting the occurrence and distribution of bacteria within the fluvial system, as well as the evaluation and modification of alternative approaches that effectively quantify the larger population of sessile bacteria within fluvial sediments, will present water-resource managers with more effective tools to assess, prevent, and (or) eliminate sources of fecal contamination within pristine and impaired watersheds. Two stream reaches on the West Branch Brandywine Creek in the Coatesville, Pa., region were studied between September 2002 and August 2003. The effects of sediment particle size, climatic conditions, aquatic growth, environmental chemistry, impervious surfaces, sediment and soil filtration, and dams on observed bacteria concentrations were evaluated. Alternative approaches were assessed to better detect geographic sources of fecal contamination including the use of turbidity as a surrogate for bacteria, the modification and implementation of sandbag bacteria samplers, and the use of optical brighteners. For the purposes of this report, sources of bacteria were defined as geographic locations where elevated concentrations of bacteria are observed within, or expected to enter, the main branch of the West Branch Brandywine Creek. Biologic sources (for example, waterfowl) were noted where applicable; however, no specific study of biologic sources (such as bacterial source tracking) was conducted. Data indicated that specific bacterial populations within fluvial sediments could be related to specific particle-size ranges. This relation is likely the result of the reduced porosity and permeability associated with finer sediments and the ability of specific bacteria to tolerate particular environments. Escherichia coli (E. coli) showed a higher median concentration (2,160 colonies per gram of saturated sediment) in the 0.125 to 0.5-millimeter size range of natural sediments than in other ranges, and enterococcus bacteria showed a higher median concentration (61,830 colonies per gram of saturated sediment) in the 0.062 to 0.25-millimeter size range of natural sediments than in other ranges. There were insufficient data to assess the particle-size relation to fecal coliform bacteria and (or) fecal streptococcus bacteria. Climatic conditions were shown to affect bacteria concentrations in both the water column and fluvial sediments. Drought conditions in 2002 resulted in lower overall bacteria concentrations than the more typically wet year of 2003. E. coli concentrations in fluvial sediment along the Coatesville study reach in 2002 had a median concentration of 92 colonies per gram of saturated sediment; in 2003, the median concentration had risen to 4,752 colonies per gram of saturated sediment. Symbiotic relations between bacteria and aquatic growth were likely responsible for increased bacteria concentrations observed within an impoundment area on the Coatesville study reach. This reach showed evidence of elevated aquatic growth and sharp increases in E. coli concentrations from upstream to downstream through the impoundment area in both 2002 and 2003. In 2003, E. coli concentrations within the waters column increased from 940 colonies per 100 milliliters upstream to 6,000 colonies per 100 milliliters at the dam crest. Given that these bacteria likely resulted from natural bacterial regrowth, the use of E. coli as an indicator of fecal contamination was severely impaired. Variable environmental conditions along the West Branch Brandywine Creek made the common field-chemical parameters of specific conductance, temperature, pH, and dissolved oxygen ineffective and (or) impossible to use for the determination of inputs of fecal contamination. Extreme variations in chemical gradients commonly were related to the urban/industrial signature of the watershed. For example, during base-flow sampling in 2002, specific-conductance values exceeding 1,000 microsiemens per centimeter observed in effluent from a local steel mill. This effluent raised the specific conductance within the West Branch Brandywine from just above 200 microsiemens per centimeter upstream from the outfall to just below 500 microsiemens per centimeter downstream from the outfall. These chemical gradients also, likely, had an effect on the initial colonization of bacteria, the formation of biofilms, and the persistence of certain types of bacteria along the study reach. Data collected in 2003 indicated that nutrients increased during both base-flow and stormflow conditions along the Coatesville study reach. For example, during base-flow sampling in 2003, 20 pounds of phosphorus was shown to enter the West Branch Brandywine Creek along the Coatesville study reach. The largest contributors to this base-flow nutrient load were likely two wastewater-treatment facilities adjacent to the study reach. During stormflow sampling in 2003, 480 pounds of phosphorus was shown to enter the West Branch Brandywine Creek along the Coatesville study reach. Data, along with other research, indicated the largest contributor to this stormflow nutrient load was likely remobilized sediment originating from a large dam impoundment. These elevated nutrient concentrations were considered sufficient to promote accelerated aquatic growth along the reach. Data collected in 2003 showed that wastewater constituents entered the West Branch Brandywine Creek largely from urban storm-sewer systems. Samples from the primary storm sewer for the city of Coatesville had detections for 20 of 69 wastewater constituents. These constituents included both strong and weak indicators of fecal contamination and generally indicated the storm-sewer system along the Coatesville study reach was a likely source of fecal-indicator bacteria and fecal contamination under base-flow conditions. By comparison, 5 constituents were detected in samples from the upstream end of the reach, and 10 constituents were detected in samples from the downstream end of the reach. During stormflow, numbers of detections were similar along the entire length of the study reach-five in samples from the upstream end, eight in samples from the center of the reach, and seven in samples from the downstream end of the reach. These data indicate that point sources (such as culverts and pipes, septic systems, and wastewater-treatment facilities) are not likely the origin of bacteria contamination during stormflow. The bacteria concentrations observed during stormflow events probably result from remobilized sessile bacteria stored within fluvial sediments. In this case, these bacteria should not be considered indicators of current fecal contamination. Impervious surfaces were found to increase bacteria concentrations along the West Branch Brandywine Creek because contaminated runoff from impervious areas generally flows into, and is concentrated within, the confines of the local storm-sewer system. During 2002, storm-sewer outfalls draining impervious areas were associated with all major locations of elevated bacterial concentrations (greater than 1,200 colonies per gram of saturated sediment) in fluvial sediments. During 2003, wetter conditions and overall bacteria concentrations higher than in 2002 resulted in point sources of bacterial contamination becoming less pronounced; however, the storm-sewer system, draining adjacent impervious areas, was still observed to be the primary source of bacteria along the reach. Where stormwater and (or) other runoff from these areas was allowed to infiltrate and (or) flow through wetland and riparian buffers, bacteria concentrations were not observed to be elevated above background levels commonly observed throughout similar areas of the same reach. Two run-of-the-river dams along the Coatesville study reach were evaluated for their effects on observed bacterial concentrations. These dams were shown to have greater or lesser effects on bacterial concentrations depending on the size of the structure and the capacity of the structure to impede flows. The smaller upstream dam had an approximate height of 3 feet and showed little observed effect on measured turbidity values; these data indicated that the dam did not effectively impede the flow of water or sediment within the West Branch Brandywine Creek. Consequently, this small dam did not show any observed effect on bacterial concentrations either upstream or downstream of the structure. The larger dam, near the middle of the reach, had an approximate height of 20 feet and showed greater effects on both turbidity and bacteria concentrations. The capacity of the larger dam to impede flows, combined with nutrients entering the reach, resulted in increased biologic activity throughout the impoundment area. Within this larger impoundment, enterococcus bacteria populations were observed to decrease sharply and E. coli bacteria populations were observed to increase sharply as flow approached the dam crest. All bacteria levels were then observed to drop to background levels, in both the water column and fluvial sediment, immediately downstream from the dam crest. Additional study is required to determine the cause for this rapid die off. Turbidity was assessed as a potential surrogate for E. coli bacteria. Regression analysis indicated higher turbidity levels usually can indicate higher concentrations of bacteria (R2 = 0.67), but the relation was too sporadic on the West Branch Brandywine Creek to use turbidity as a surrogate for estimated bacteria concentrations. Evaluation of data from individual base-flow and stormflow events resulted in variable and generally poor statistical relations between E. coli bacteria and turbidity (R2 values ranged from 0.02 to 0.94). Sandbag samplers were used in 2003 to determine their suitability for the assessment of fecal contamination. Sandbag samplers rely on the ability of bacteria to attach to surfaces and use the larger sessile bacteria populations instead of the more commonly used planktonic bacteria populations. E. coli bacteria concentrations observed in the sandbag samplers, after 1 week in place, were similar to those found within natural sediments collected concurrently. Enterococcus bacteria concentrations within the same sandbag samplers were not similar, and were generally lower, than those observed within the natural sediments. This discrepancy was likely because sand within the samplers was sieved to a size that was likely too coarse for enterococcus bacteria to persist. Optical-brightener samplers were installed along with each sandbag sampler. Optical brighteners are additives used in common household detergents; therefore, detection of optical brighteners, along with elevated fecal-indicator bacteria concentrations, strongly indicates a link to humans. Positive results for optical brighteners were detected only at the outfalls of two sewage-treatment facilities; because of treatment of the effluent from these facilities, these samples did not have elevated bacteria concentrations. The lack of additional positive results was largely because this method is not sensitive to low concentrations of optical brighteners.

Pennsylvania↗

USGS2019

Chemical controls for an integrated pest management program

Chemical controls ranging from natural products to synthesized chemicals are widely used in aquatic pest management activities. Chemicals can be used to lure organisms to traps or can cause direct mortality by altering the physiological function of an organism. Much of what is known about controlling pests with chemicals is from research done on terrestrial pesticides. This paper focuses on how chemicals might be used as aquatic pesticides to control or eradicate aquatic invasive species. Current control tools are described, as are new technologies designed to selectively target the pest to reduce risks to nontarget organisms and the environment.

North American Journal of Fisheries Management↗

USGS2010

Selection, trans-species polymorphism, and locus identification of major histocompatibility complex class IIβ alleles of New World ranid frogs

Genes encoded by the major histocompatibility complex (MHC) play key roles in the vertebrate immune system. However, our understanding of the evolutionary processes and underlying genetic mechanisms shaping these genes is limited in many taxa, including amphibians, a group currently impacted by emerging infectious diseases. To further elucidate the evolution of the MHC in frogs (anurans) and develop tools for population genetics, we surveyed allelic diversity of the MHC class II ??1 domain in both genomic and complementary DNA of seven New World species in the genus Rana (Lithobates). To assign locus affiliation to our alleles, we used a "gene walking" technique to obtain intron 2 sequences that flanked MHC class II?? exon 2. Two distinct intron sequences were recovered, suggesting the presence of at least two class II?? loci in Rana. We designed a primer pair that successfully amplified an orthologous locus from all seven Rana species. In total, we recovered 13 alleles and documented trans-species polymorphism for four of the alleles. We also found quantitative evidence of selection acting on amino acid residues that are putatively involved in peptide binding and structural stability of the ??1 domain of anurans. Our results indicated that primer mismatch can result in polymerase chain reaction (PCR) bias, which influences the number of alleles that are recovered. Using a single locus may minimize PCR bias caused by primer mismatch, and the gene walking technique was an effective approach for generating single-copy orthologous markers necessary for future studies of MHC allelic variation in natural amphibian populations. ?? 2010 Springer-Verlag.

Immunogenetics↗

USGS1996

Organic geochemistry applied to environmental assessments of Prince William Sound, Alaska, after the Exxon Valdez oil spill—a review

Organic geochemistry played a major role in the environmental assessments conducted following the Exxon Valdez oil spill, which occurred on March 24, 1989, and released about 258,000 bbls (41 million liters) of Alaska North Slope crude oil into Prince William Sound. Geochemical analyses of more than 15,000 sediment, tar, and biological samples and about 5000 water samples provide the largest database yet collected on oil-spill chemistry, and we review the results here. The marine environment of the Sound has a complex background of petrogenic, pyrogenic, and biogenic hydrocarbons from natural and anthropogenic sources. Geochemical evaluation of the fate and effects of the spilled oil required that this oil and its residues be distinguished from the background. A variety of molecular and isotopic techniques were employed to identify various hydrocarbon sources and to distinguish quantitatively among mixed sources in the samples. Although the specific criteria used to distinguish multiple sources in the region affected by the Exxon Valdez spill are not necessarily applicable to all spill situations, the principles that governed their selection are. Distributions of polycyclic aromatic hydrocarbons (PAH) and dibenzothiophenes distinguish Exxon Valdez oil and its weathered residues from background hydrocarbons in benthic sediments. Ratios of C 2 -dibenzothiophene C 2 -phenanthrene "> C 2 -dibenzothiopheneC 2 -phenanthrene and C 3 -dibenzothiophene C 3 -phenanthrene "> C 3 -dibenzothiopheneC 3 -phenanthrene were particularly useful. Carbon isotopes and terpane distributions distinguished Exxon Valdez residues found on shorelines from tars from other sources. Diesel and diesel soot were identified by the absence of alkylated chrysenes and a narrow distribution of n -alkanes, whereas pyrogenic products were distinguished by the dominance of 4- to 6-ring PAH over 2- to 3-ring PAH and by the dominance of non-alkylated over alkylated homologues of each PAH series. The presence of 18α(H)-oleanane in benthic sediments, coupled with its absence in Exxon Valdez oil and its residues, confirm another petrogenic source. Results of geochemical studies suggest that the petrogenic component in the background of benthic sediments is derived from oil seeps in the eastern Gulf of Alaska. In 1990 and 1991, Exxon Valdez residues, generally forming a small increment to the pre-spill background, were found to be only sporadically distributed in some shallow, near shore sediments adjacent to shorelines that had been heavily oiled in 1989. In 1994, occurrences of Exxon Valdez tars on shoreline surfaces were rare, although residues could be found buried in shoreline sediments at some isolated locations along the spill path where they were protected from wave action. Spilled oil residues collected 16 months after the spill were degraded, on average, by nearly 50%. Shoreline residues from sources other than the spill were also identified and are widespread throughout the Sound. These residues include (1) geochemically distinct tars and oils imported from California oil fields to Alaska for fuel and construction purposes prior to the discovery of the Cook Inlet and North Slope oil fields, (2) diesel and diesel soot, and (3) more highly refined products. Of the more than 2700 chemical analyses of biological samples of higher life forms (fish, birds, and mammals) about 150 (6%) indicate recognizable residues of Exxon Valdez oil, which were identified by their distribution of polycyclic aromatic hydrocarbons (PAH). Most of these samples (138) were collected in 1989 and most were associated with external surfaces or the gastrointestinal tract. Rarely do internal tissues or fluids contain recognizable fingerprints of spilled oil. This observation includes samples from marine mammals that were visibly oiled externally. Other hydrocarbon sources, including diesel and a non-petroleum artifact that occurs when concentrations of individual PAH are at or near their method detection limit, are also identified in biological samples.

Alaska↗