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At least 1,531 records · Page 85Linked to original sources

Altitude and configuration of the potentiometric surface, May and June 1993, and change in water level 1983-93, in the carbonate rocks in part of East Whiteland and Charlestown Townships, Chester County, Pennsylvania

A map showing ground-water levels in the carbonate rocks of northern Chester County, Pa., was constructed on the basis of water levels in 51 wells measured in May and June 1993. The area studied underlies parts of East Whiteland and Charlestown Townships. Water-level altitudes range from about 413 feet above sea level on Phoenixville Pike to 130 feet above sea level along Route 29.

Pennsylvania↗

A compilation of sulfur dioxide and carbon dioxide emission-rate data from Cook Inlet volcanoes (Redoubt, Spurr, Iliamna, and Augustine), Alaska during the period from 1990 to 1994

Airborne sulfur dioxide (SO2) gas sampling of the Cook Inlet volcanoes (Mt. Spurr, Redoubt, Iliamna, and Augustine) began in 1986 when several measurements were carried out at Augustine volcano during the eruption of 1986 (Rose and others, 1988). More systematic monitoring for SO2 began in March 1990 and for carbon dioxide (CO2) began in June, 1990 at Redoubt Volcano (Brantley, 1990 and Casadevall and others, 1994) and continues to the present. This report contains all of the available daily SO2 and CO2 emission rates determined by the U.S. Geological Survey (USGS) from March 1990 through July 1994. Intermittent measurements (four to six month intervals) at Augustine and Iliamna began in 1990 and continues to the present. Intermittent measurements began at Mt. Spurr volcano in 1991, and were continued at more regular intervals from June, 1992 through the 1992 eruption at the Crater Peak vent to the present.

Alaska↗

Altitude and configuration of the potentiometric surface, December 6, 1994, in the carbonate rocks in part of East Whiteland and Charlestown townships, Chester County, Pennsylvania

A map showing ground-water levels in the carbonate rocks in part of East Whiteland and Charlestown Townships, Chester County, Pennsylvania, was constructed from water levels measured in 64 wells on December 6, 1994. Observed water-level altitudes range from 226 feet above sea level near Morehall Road to 400 feet above sea level near State Route 401 in East Whiteland Township.

Pennsylvania↗

Characterization of Northern California petroleum by stable carbon isotopes

The purpose of this study is to characterize natural occurrences of petroleum at the surface and in the subsurface within northern California in order to define and map petroleum systems for U.S. Geological Survey energy resource assessments. Furthermore, the chemical characterization and mapping of natural petroleum occurrences could also be used to discriminate natural occurrences from accidental oil spills during the activities of extraction or transportation of petroleum. Samples include petroleum from exploratory well tests, producing fields, natural seeps, and oil-stained rocks, and condensates from gas wells. Most of the sample localities are in northern California but a few samples from central and southern California are included for comparison (table 1). Even though other analyses were performed, only stable carbon isotope (δ13C) data are presented here for brevity and because δ13C values are one of the most discriminating characteristics of California petroleum.

California↗

Regional potentiometric-surface map of the Great Basin carbonate and alluvial aquifer system in Snake Valley and surrounding areas, Juab, Millard, and Beaver Counties, Utah, and White Pine and Lincoln Counties, Nevada

Water-level measurements from 190 wells were used to develop a potentiometric-surface map of the east-central portion of the regional Great Basin carbonate and alluvial aquifer system in and around Snake Valley, eastern Nevada and western Utah. The map area covers approximately 9,000 square miles in Juab, Millard, and Beaver Counties, Utah, and White Pine and Lincoln Counties, Nevada. Recent (2007-2010) drilling by the Utah Geological Survey and U.S. Geological Survey has provided new data for areas where water-level measurements were previously unavailable. New water-level data were used to refine mapping of the pathways of intrabasin and interbasin groundwater flow. At 20 of these locations, nested observation wells provide vertical hydraulic gradient data and information related to the degree of connection between basin-fill aquifers and consolidated-rock aquifers. Multiple-year water-level hydrographs are also presented for 32 wells to illustrate the aquifer system's response to interannual climate variations and well withdrawals.

Utah, Nevada↗

Microbial and dissolved organic carbon characterization of stormflow in the Santa Ana River at Imperial Highway, Southern California, 1999-2002

The Santa Ana River drains about 2,670 square miles of densely populated coastal southern California, near Los Angeles. Almost all the flow in the river, more than 200,000 acre-feet annually, is diverted to ponds where it infiltrates and recharges underlying aquifers pumped to supply water for more than 2 million people. Base flow in the river is almost entirely treated municipal wastewater discharged from upstream treatment plants and, in the past, stormflow was considered a source of high-quality water suitable for use as a source of ground-water recharge that would dilute poorer quality water recharged during base flow. Stormflow in the Santa Ana River at the Imperial Highway diversion contains total coliform bacteria concentrations as high as 3,400,000 colonies per 100 mL (milliliters). Fecal indicator bacteria concentrations, including fecal coliforms, Escherichia coli, and enterococci, were as high as 310,000, 84,000, and 102,000 colonies per 100 mL, respectively. Although concentrations were high owing to urban runoff during the first stormflow of the rainy season, the highest concentrations occurred during the recessional flows of the first stormflow of the rainy season after streamflow returned to pre-storm conditions. Molecular indicators of microbiological organisms in stormflow, including phospholipid fatty acid (PLFA) and genetic data, show that the diversity of the total microbial population decreases during stormflow while fecal indicator bacteria concentrations increase. This suggests that the source of the bacteria must be poorly diverse and dominated by only a few types of bacteria. Although direct runoff of fecal indicator bacteria from urban areas occurs, this process cannot explain the very high concentrations of fecal indicator bacteria in runoff from upstream parts of the basin characterized by urban, agricultural (including more than 300,000 head of dairy cattle), and other land uses. Although other explanations are possible, fecal indicator bacteria concentrations and molecular microbiological data indicate accumulation and extended survival of bacteria in streambed sediments, and subsequent mobilization of those sediments and associated bacteria during stormflow. Both PLFA and genetic data indicate that water from dairy-waste storage ponds was not present during sampled stormflows. This is consistent with the relatively dry conditions and the absence of large stormflows during the study. Dissolved organic carbon (DOC) concentrations in stormflow ranged from 3 to 15.3 mg/L. In general, concentrations increased during stormflow and were distributed across the stormflow hydrograph in a manner similar to that of fecal indicator bacteria. DOC concentrations typically remained high for several days after flow returned to pre-storm conditions. Ultraviolet absorbance, excitation emission spectroscopy, and sequential fractionation of DOC using XAD-8 and XAD-4 resins showed that the composition of DOC changed rapidly during stormflow. Hydrophobic and hydrophilic acids were the largest fraction of DOC composing between 27 and 45 percent and between 24 and 37 percent of the DOC, respectively. The fraction of DOC composed of hydrophobic acids decreased due to urban runoff and increased during the recession of the first stormflow of the rainy season; the hydrophilic-acid fraction generally decreased throughout the stormflow hydrograph; the transhydrophilic-acid fraction did not vary greatly during stormflow; and the hydrophobic-neutral fraction increased from low values in base flow to almost 30 percent of the DOC after more soluble and more mobile hydrophobic and hydrophilic acids were washed from urban areas. Comparison of ultraviolet absorbance data with data collected during previous studies shows that the optical properties and, presumably, the composition of the DOC were different in this study than DOC collected during wetter periods. Samples of shallow ground water collec

California↗

Methane gas concentration in soils and ground water, Carbon and Emery Counties, Utah, 1995-2003

The release of methane gas from coal beds creates the potential for it to move into near-surface environments through natural and human-made pathways. To help ensure the safety of communities and determine the potential effects of development of coal-bed resources, methane gas concentrations in soils and ground water in Carbon and Emery Counties, Utah, were monitored from 1995 to 2003. A total of 420 samples were collected, which contained an average methane concentration of 2,740 parts per million by volume (ppmv) and a median concentration of less than 10 ppmv. On the basis of spatial and temporal methane concentration data collected during the monitoring period, there does not appear to be an obvious, widespread, or consistent migration of methane gas to the near-surface environment.

Utah↗

Hydrologic conditions and water-quality conditions following underground coal mining in the North Fork of the Right Fork of Miller Creek drainage basin, Carbon and Emery Counties, Utah, 2004-2005

In 2004 and 2005, the U.S. Geological Survey, in cooperation with the Bureau of Land Management, reassessed the hydrologic system in and around the drainage basin of the North Fork of the Right Fork (NFRF) of Miller Creek, in Carbon and Emery Counties, Utah. The reassessment occurred 13 years after cessation of underground coal mining that was performed beneath private land at shallow depths (30 to 880 feet) beneath the NFRF of Miller Creek. This study is a follow-up to a previous USGS study of the effects of underground coal mining on the hydrologic system in the area from 1988 to 1992. The previous study concluded that mining related subsidence had impacted the hydrologic system through the loss of streamflow over reaches of the perennial portion of the stream, and through a significant increase in dissolved solids in the stream. The previous study also reported that no substantial differences in spring-water quality resulted from longwall mining, and that no clear relationship between mining subsidence and spring discharge existed. During the summers of 2004 and 2005, the USGS measured discharge and collected water-quality samples from springs and surface water at various locations in the NFRF of Miller Creek drainage basin, and maintained a streamflow-gaging station in the NFRF of Miller Creek. This study also utilized data collected by Cyprus–Plateau Mining Corporation from 1992 through 2001. Of thirteen monitored springs, five have discharge levels that have not returned to those observed prior to August 1988, which is when longwall coal mining began beneath the NFRF of Miller Creek. Discharge at two of these five springs appears to fluctuate with wet and dry cycles and is currently low due to a drought that occurred from 1999–2004. Discharge at two other of the five springs did not increase with increased precipitation during the mid-1990s, as was observed at other monitored springs. This suggests that flowpaths to these springs may have been altered by land subsidence caused by underground coal mining. Analysis of possible impacts to the fifth spring were inconclusive due to a lack of data collected during the mid-1990s. Discharge at eight other monitored springs in the study area appears to be controlled mainly by climatic fluctuations and was generally near the value measured prior to 1988. Discharge at one of these eight springs is significantly greater than that measured during the longwall mining period. Concentrations of magnesium, calcium, sulfate, and dissolved solids at one undermined spring were elevated in relation to other springs in the study area. Dissolved solids concentration at this spring ranged from 539–709 milligrams per liter. Dissolved-solids concentration for all other springs in the study area ranged from 163 to 360 milligrams per liter and was near the median value measured prior to longwall mining beneath the NFRF of Miller Creek drainage basin. Baseflow measured at a streamflow-gaging station on the NFRF of Miller Creek located downstream of the mined area during the summer of 2004 was near 5 gallons per minute. Baseflow in 2005 increased to 7–8 gallons per minute, due to increased precipitation. This is slightly greater than the range of baseflow measured near the end of the longwall mining period which was approximately 3–5 gallons per minute. Seepage investigations carried out in the summer of 2004 and 2005 along the NFRF of Miller Creek showed a net loss of surface flow along the studied reach. Specific areas within the study reach had streamflow losses prior to longwall mining, however, the study reach as a whole was observed to gain in discharge when measured in 1986–1988, immediately before longwall mining began. The area where the greatest loss in discharge from the NFRF of Miller Creek occurred corresponds to an area where overburden (material overlying a deposit of useful geological materials or bedrock) is between 700 and 210 feet thick. Overburden thickness at the place where the streambed first dried up was approximately 600 feet thick. In 2004, approximately 1,600 ft of the streambed of the NFRF of Miller Creek was dry. Only 300 feet of the streambed was dry during the wetter year of 2005. Prior to longwall mining, no dry reaches were observed, though seepage loss was documented. Average discharge measured at a tributary to the NFRF of Miller Creek has increased from 1.6 gallons per minute measured during longwall mining to 7.2 gallons per minute measured in 2004–2005. During both years of this study, the lower reach of the stream regained flow from this tributary and from seepage gains. Water quality in the lower reach of the NFRF of Miller Creek downstream of the longwall-mined area, showed significantly higher concentrations of magnesium, calcium, sulfate, and strontium, in relation to water in the upper reach of the NFRF of Miller Creek and to the springs sampled in the area. Dissolved-solids concentration measured in the lower reach of the stream in 2004 and 2005 ranged from 1,880 to 2,220 milligrams per liter, while sulfate concentrations ranged from 1,090 to 1,320 mg/L. The maximum contaminant level for drinking water in the state of Utah for dissolved solids and sulfate is 2,000 and 1,000 mg/L respectively. Concentrations of these ions are slightly greater than those measured during and just following mining beneath the NFRF of Miller Creek drainage basin, but are significantly higher than those measured prior to mining. With the exception of strontium, dissolved metals concentrations in the NFRF of Miller Creek were similar to those measured in area springs. pH in the creek and at all spring sites was near neutral. Qualitative observations of the creek bottom suggest that mining-related activities have had little effect on vegetative growth.

Utah↗

Mapping Evapotranspiration Units in the Basin and Range Carbonate-Rock Aquifer System, White Pine County, Nevada, and Adjacent Areas in Nevada and Utah

Accurate estimates of ground-water discharge are crucial in the development of a water budget for the Basin and Range carbonate-rock aquifer system study area. One common method used throughout the southwestern United States is to estimate ground-water discharge from evapotranspiration (ET). ET is a process by which water from the Earth's surface is transferred to the atmosphere. The volume of water lost to the atmosphere by ET can be computed as the product of the ET rate and the acreage of vegetation, open water, and moist soil through which ET occurs. The procedure used in the study groups areas of similar vegetation, water, and soil conditions into different ET units, assigns an average annual ET rate to each unit, and computes annual ET from each ET unit within the outer extent of potential areas of ground-water discharge. Data sets and the procedures used to delineate the ET-unit map used to estimate ground-water discharge from the study area and a qualitative assessment of the accuracy of the map are described in this report.

Scientific Investigations Report↗

Application of the Basin Characterization Model to Estimate In-Place Recharge and Runoff Potential in the Basin and Range Carbonate-Rock Aquifer System, White Pine County, Nevada, and Adjacent Areas in Nevada and Utah

A regional-scale water-balance model was used to estimate recharge and runoff potential and support U.S. Geological Survey efforts to develop a better understanding of water availability for the Basin and Range carbonate-rock aquifer system (BARCAS) study in White Pine County, Nevada, and adjacent areas in Nevada and Utah. The water-balance model, or Basin Characterization Model (BCM), was used to estimate regional ground-water recharge for the 13 hydrographic areas in the study area. The BCM calculates recharge by using a distributed-parameter, water-balance method and monthly climatic boundary conditions. The BCM requires geographic information system coverages of soil, geology, and topographic information with monthly time-varying climatic conditions of air temperature and precipitation. Potential evapotranspiration, snow accumulation, and snowmelt are distributed spatially with process models. When combined with surface properties of soil-water storage and saturated hydraulic conductivity of bedrock and alluvium, the potential water available for in-place recharge and runoff is calculated using monthly time steps using a grid scale of 866 feet (270 meters). The BCM was used with monthly climatic inputs from 1970 to 2004, and results were averaged to provide an estimate of the average annual recharge for the BARCAS study area. The model estimates 526,000 acre-feet of potential in-place recharge and approximately 398,000 acre-feet of potential runoff. Assuming 15 percent of the runoff becomes recharge, the model estimates average annual ground-water recharge for the BARCAS area of about 586,000 acre-feet. When precipitation is extrapolated to the long-term climatic record (1895-2006), average annual recharge is estimated to be 530,000 acre-feet, or about 9 percent less than the recharge estimated for 1970-2004.

Scientific Investigations Report↗

Water Resources of the Basin and Range Carbonate-Rock Aquifer System, White Pine County, Nevada, and Adjacent Areas in Nevada and Utah

INTRODUCTION This report summarizes results of a water-resources study for White Pine County, Nevada, and adjacent areas in east-central Nevada and western Utah. The Basin and Range carbonate-rock aquifer system (BARCAS) study was initiated in December 2004 through Federal legislation (Section 301(e) of the Lincoln County Conservation, Recreation, and Development Act of 2004; PL108-424) directing the Secretary of the Interior to complete a water-resources study through the U.S. Geological Survey, Desert Research Institute, and State of Utah. The study was designed as a regional water-resource assessment, with particular emphasis on summarizing the hydrogeologic framework and hydrologic processes that influence ground-water resources. The study area includes 13 hydrographic areas that cover most of White Pine County; in this report however, results for the northern and central parts of Little Smoky Valley were combined and presented as one hydrographic area. Hydrographic areas are the basic geographic units used by the State of Nevada and Utah and local agencies for water-resource planning and management, and are commonly defined on the basis of surface-water drainage areas. Hydrographic areas were further divided into subbasins that are separated by areas where bedrock is at or near the land surface. Subbasins are the subdivisions used in this study for estimating recharge, discharge, and water budget. Hydrographic areas are the subdivision used for reporting summed and tabulated subbasin estimates.

Scientific Investigations Report↗

Use of stable isotopes of carbon and nitrogen to identify sources of organic matter to bed sediments of the Tualatin River, Oregon

The potential sources of organic matter to bed sediment of the Tualatin River in northwestern Oregon were investigated by comparing the isotopic fractionation of carbon and nitrogen and the carbon/nitrogen ratios of potential sources and bed sediments. Samples of bed sediment, suspended sediment, and seston, as well as potential source materials, such as soil, plant litter, duckweed, and wastewater treatment facility effluent particulate were collected in 1998-2000. Based on the isotopic data, terrestrial plants and soils were determined to be the most likely sources of organic material to Tualatin River bed sediments. The delta 13C fractionation matched well, and although the delta 15N and carbon/nitrogen ratio of fresh plant litter did not match those of bed sediments, the changes expected with decomposition would result in a good match. The fact that the isotopic composition of decomposed terrestrial plant material closely resembled that of soils and bed sediments supports this conclusion. Phytoplankton probably was not a major source of organic matter to bed sediments. Compared to the values for bed sediments, the delta 13C values and carbon/nitrogen ratios of phytoplankton were too low and the delta 15N values were too high. Decomposition would only exacerbate these differences. Although phytoplankton cannot be considered a major source of organic material to bed sediment, a few bed sediment samples in the lower reach of the river showed a small influence from phytoplankton as evidenced by lower delta 13C values than in other bed sediment samples. Isotopic data and carbon/nitrogen ratios for bed sediments generally were similar throughout the basin, supporting the idea of a widespread source such as terrestrial material. The delta 15N was slightly lower in tributaries and in the upper reaches of the river. Higher rates of sediment oxygen demand have been measured in the tributaries in previous studies and coupled with the isotopic data may indicate the presence of more labile organic matter in these areas. Results from this study indicate that strategies to improve oxygen conditions in the Tualatin River are likely to be more successful if they target sources of soil, leaf litter, and other terrestrially derived organic materials to the river rather than the instream growth of algae.

Scientific Investigations Report↗

Seasonal patterns in nutrients, carbon, and algal responses in wadeable streams within three geographically distinct areas of the United States, 2007-08

The U.S. Geological Survey determined seasonal variability in nutrients, carbon, and algal biomass in 22 wadeable streams over a 1-year period during 2007 or 2008 within three geographically distinct areas in the United States. The three areas are the Upper Mississippi River Basin (UMIS) in Minnesota, the Ozark Plateaus (ORZK) in southern Missouri and northern Arkansas, and the Upper Snake River Basin (USNK) in southern Idaho. Seasonal patterns in some constituent concentrations and algal responses were distinct. Nitrate concentrations were greatest during the winter in all study areas potentially because of a reduction in denitrification rates and algal uptake during the winter, along with reduced surface runoff. Decreases in nitrate concentrations during the spring and summer at most stream sites coincided with increased streamflow during the snowmelt runoff or spring storms indicating dilution. The continued decrease in nitrate concentrations during summer potentially is because of a reduction in nitrate inputs (from decreased surface runoff) or increases in biological uptake. In contrast to nitrate concentrations, ammonia concentrations varied among study areas. Ammonia concentration trends were similar at UMIS and USNK sampling sites with winter peak concentrations and rapid decreases in ammonia concentrations by spring or early summer. In contrast, ammonia concentrations at OZRK sampling sites were more variable with peak concentrations later in the year. Ammonia may accumulate in stream water in the winter under ice and snow cover at the UMIS and USNK sites because of limited algal metabolism and increased mineralization of decaying organic matter under reducing conditions within stream bottom sediments. Phosphorus concentration patterns and the type of phosphorus present changes with changing hydrologic conditions and seasons and varied among study areas. Orthophosphate concentrations tended to be greater in the summer at UMIS sites, whereas total phosphorus concentrations at most UMIS and USNK sites peaked in the spring during runoff and then decreased through the remainder of the sampling period. Total phosphorus and orthophosphate concentrations in OZRK streams peaked during summer indicating a runoff-based source of both nutrients. Orthophosphate concentrations may increase in streams in the late summer when surface runoff composes less of total streamflow, and when groundwater containing orthophosphate becomes a more dominant source in streams during lower flows. Seston chlorophyll a concentrations were greatest early in the growing season (spring), whereas the spring runoff events coincided with reductions in benthic algal chlorophyll a biomass likely because of scour of benthic algae from the channel bottom that are entrained in the water column during that period. Nitrate, ammonia, and orthophosphate concentrations also decreased during that same period, indicating dilution in the spring during runoff events. The data from this study indicate that the source of water (surface runoff or groundwater) to a stream and the intensity of major runoff events are important factors controlling instream concentrations. Biological processes appear to affect nutrient concentrations during more stable lower flow periods in later summer, fall, and winter when residence time of water in a channel is longer, which allows more time for biological uptake and transformations. Management of nutrient conditions in streams is challenging and requires an understanding of multiple factors that affect in-stream nutrient concentrations and biological uptake and growth.

Scientific Investigations Report↗

Steady-state numerical groundwater flow model of the Great Basin carbonate and alluvial aquifer system

This report describes the construction, calibration, evaluation, and results of a steady-state numerical groundwater flow model of the Great Basin carbonate and alluvial aquifer system that was developed as part of the U.S. Geological Survey National Water Census Initiative to evaluate the nation’s groundwater availability. The study area spans 110,000 square miles across five states. The numerical model uses MODFLOW-2005, and incorporates and tests complex hydrogeologic and hydrologic elements of a conceptual understanding of an interconnected groundwater system throughout the region, including mountains, basins, consolidated rocks, and basin fill. The level of discretization in this model has not been previously available throughout the study area. Observations used to calibrate the model are those of water levels and discharge to evapotranspiration, springs, rivers, and lakes. Composite scaled sensitivities indicate the simulated values of discharge to springs, rivers, and lakes provide as much information about model parameters as do simulated water-level values. The model has 176 parameters and little parameter correlation. The simulated equivalents to observations provide enough information to constrain most parameters to smaller ranges than the conceptual constraints, and most parameter values are within reasonable ranges. Model fit to observations, comparison of simulated to conceptual water-level contours, and comparison of simulated to conceptual water budgets indicate this model provides a reasonable representation of the regional groundwater system. Eighty-six percent of the simulated values of water levels in wells are within 119 feet (one standard deviation of the error) of the observed values. Ninety percent of the simulated discharges are within 30 percent of the observed values. Total simulated recharge in the study area is within 10 percent of the conceptual amount; total simulated discharge is the same as conceptual discharge. Comparison of simulated hydraulic heads with the conceptual potentiometric surface indicates that the model accurately depicts major features of the hydraulic-head distribution. The incorporation of new recharge estimates and of mountain springs and streams as model observations creates higher simulated recharge mounds under many mountain ranges and highlights that in many cases, the regional flow paths go around, not through (or under) mountain ranges. Results from the model show that much of the flow in the groundwater system occurs in deeper layers, even though about 86 percent of the discharge occurs in layer 1. Over 95 percent of the recharge moves down from layer 1, and about 25 percent moves down to layer 8. The model was used to delineate six simulated groundwater flow regions that connect recharge areas to discharge areas. The eastern Great Salt Lake and Great Salt Lake Desert model regions contain 75 percent of the groundwater budget, but only 42 percent of the study area. In contrast, the more southern Death Valley and Colorado model regions contain only 12 percent of the groundwater budget, but 37 percent of the study area. Examples of potential use of the model to investigate the groundwater system include (1) the effects of different recharge, (2) different interpretations of the extent or offset of long faults or fault zones, and (3) different conceptual models of the spatial variation of hydraulic properties. The model can also be used to examine the ultimate effects of groundwater withdrawals on a regional scale, to provide boundary conditions for local-scale models, and to guide data collection.

Great Basin↗

National assessment of geologic carbon dioxide storage resources: allocations of assessed areas to Federal lands

Following the geologic basin-scale assessment of technically accessible carbon dioxide storage resources in onshore areas and State waters of the United States, the U.S. Geological Survey estimated that an area of about 130 million acres (or about 200,000 square miles) of Federal lands overlies these storage resources. Consequently, about 18 percent of the assessed area associated with storage resources is allocated to Federal land management. Assessed areas are allocated to four other general land-ownership categories as follows: State lands about 4.5 percent, Tribal lands about 2.4 percent, private and other lands about 72 percent, and offshore areas about 2.6 percent.

Scientific Investigations Report↗

Nutrient, organic carbon, and chloride concentrations and loads in selected Long Island Sound tributaries—Four decades of change following the passage of the Federal Clean Water Act

Trends in long-term water-quality and streamflow data from 14 water-quality monitoring sites in Connecticut were evaluated for water years 1974–2013 and 2001–13, coinciding with implementation of the Clean Water Act of 1972 and the Connecticut Nitrogen Credit Exchange program, as part of an assessment of nutrient and chloride concentrations and loads discharged to Long Island Sound. In this study, conducted by the U.S. Geological Survey in cooperation with the Connecticut Department of Energy and Environmental Protection, data were evaluated using a recently developed methodology of weighted regressions with time, streamflow, and season. Trends in streamflow were evaluated using a locally weighted scatterplot smoothing method. Annual mean streamflow increased at 12 of the 14 sites averaging 8 percent during the entire study period, primarily in the summer months, and increased by an average of 9 percent in water years 2001–13, primarily during summer and fall months. Downward trends in flow-normalized nutrient concentrations and loads were observed during both periods for most sites for total nitrogen, total Kjeldahl nitrogen, nitrite plus nitrate nitrogen, total phosphorus, and total organic carbon. Average flow-normalized loads of total nitrogen decreased by 23.9 percent for the entire period and 10.9 percent for the period of water years 2001‒13. Major factors contributing to decreases in flow-normalized loads and concentrations of these nutrients include improvements in wastewater treatment practices, declining atmospheric wet deposition of nitrogen, and changes in land management and land use. Loads of dissolved silica (DSi; flow-normalized and non-flow-normalized) increased slightly at most stations during the study period and were positively correlated to urbanized land in the basin and negatively correlated to area of open water. Concentrations and loads of chloride increased at 12 of the 14 sites during both periods. Increases likely are the result of an increase in the use of salt for deicing, as well as other factors related to urbanization and population growth, such as increases in wastewater discharge and discharge from septic systems.

Connecticut↗

Using CO 2 Prophet to estimate recovery factors for carbon dioxide enhanced oil recovery

Introduction The Oil and Gas Journal’s enhanced oil recovery (EOR) survey for 2014 (Koottungal, 2014) showed that gas injection is the most frequently applied method of EOR in the United States and that carbon dioxide (CO 2 ) is the most commonly used injection fluid for miscible operations. The CO 2 -EOR process typically follows primary and secondary (waterflood) phases of oil reservoir development. The common objective of implementing a CO 2 -EOR program is to produce oil that remains after the economic limit of waterflood recovery is reached. Under conditions of miscibility or multicontact miscibility, the injected CO 2 partitions between the gas and liquid CO2 phases, swells the oil, and reduces the viscosity of the residual oil so that the lighter fractions of the oil vaporize and mix with the CO 2 gas phase (Teletzke and others, 2005). Miscibility occurs when the reservoir pressure is at least at the minimum miscibility pressure (MMP). The MMP depends, in turn, on oil composition, impurities of the CO 2 injection stream, and reservoir temperature. At pressures below the MMP, component partitioning, oil swelling, and viscosity reduction occur, but the efficiency is increasingly reduced as the pressure falls farther below the MMP. CO 2 -EOR processes are applied at the reservoir level, where a reservoir is defined as an underground formation containing an individual and separate pool of producible hydrocarbons that is confined by impermeable rock or water barriers and is characterized by a single natural pressure system. A field may consist of a single reservoir or multiple reservoirs that are not in communication but which may be associated with or related to a single structural or stratigraphic feature (U.S. Energy Information Administration [EIA], 2000). The purpose of modeling the CO 2 -EOR process is discussed along with the potential CO 2 -EOR predictive models. The data demands of models and the scope of the assessments require tradeoffs between reservoir-specific data that can be assembled and simplifying assumptions that allow assignment of default values for some reservoir parameters. These issues are discussed in the context of the CO 2 Prophet EOR model, and their resolution is demonstrated with the computation of recovery-factor estimates for CO 2 -EOR of 143 reservoirs in the Powder River Basin Province in southeastern Montana and northeastern Wyoming.

Scientific Investigations Report↗

Carbon dioxide enhanced oil recovery performance according to the literature

Introduction The need to increase the efficiency of oil recovery and environmental concerns are bringing to prominence the use of carbon dioxide (CO 2 ) as a tertiary recovery agent. Assessment of the impact of flooding with CO 2 all eligible reservoirs in the United States not yet undergoing enhanced oil recovery (EOR) requires making the best possible use of the experience gained in 40 years of applications. Review of the publicly available literature has located relevant CO 2 -EOR information for 53 units (fields, reservoirs, pilot areas) in the United States and 17 abroad. As the world simultaneously faces an increasing concentration of CO 2 in the atmosphere and a higher demand for fossil fuels, the CO 2 -EOR process continues to gain popularity for its efficiency as a tertiary recovery agent and for the potential for having some CO 2 trapped in the subsurface as an unintended consequence of the enhanced production (Advanced Resources International and Melzer Consulting, 2009). More extensive application of CO 2 -EOR worldwide, however, is not making it significantly easier to predict the exact outcome of the CO 2 flooding in new reservoirs. The standard approach to examine and manage risks is to analyze the intended target by conducting laboratory work, running simulation models, and, finally, gaining field experience with a pilot test. This approach, though, is not always possible. For example, assessment of the potential of CO 2 -EOR at the national level in a vast country such as the United States requires making forecasts based on information already available. Although many studies are proprietary, the published literature has provided reviews of CO 2 -EOR projects. Yet, there is always interest in updating reports and analyzing the information under new perspectives. Brock and Bryan (1989) described results obtained during the earlier days of CO 2 -EOR from 1972 to 1987. Most of the recovery predictions, however, were based on intended injections of 30 percent the size of the reservoir’s hydrocarbon pore volume (HCPV), and the predictions in most cases badly missed the actual recoveries because of the embryonic state of tertiary recovery in general and CO 2 flooding in particular at the time. Brock and Bryan (1989), for example, reported for the Weber Sandstone in the Rangely oil field in Colorado, an expected recovery of 7.5 percent of the original oil in place (OOIP) after injecting a volume of CO 2 equivalent to 30 percent of the HCPV, but Clark (2012) reported that after injecting a volume of CO 2 equivalent to 46 percent of the HCPV, the actual recovery was 4.8 percent of the OOIP. Decades later, the numbers by Brock and Bryan (1989) continue to be cited as part of expanded reviews, such as the one by Kuuskraa and Koperna (2006). Other comprehensive reviews including recovery factors are those of Christensen and others (2001) and Lake and Walsh (2008). The Oil and Gas Journal (O&GJ) periodically reports on active CO 2 -EOR operations worldwide, but those releases do not include recovery factors. The monograph by Jarrell and others (2002) remains the most technically comprehensive publication on CO 2 flooding, but it does not cover recovery factors either. This chapter is a review of the literature found in a search for information about CO 2 -EOR. It has been prepared as part of a project by the U.S. Geological Survey (USGS) to assess the incremental oil production that would be technically feasible by CO 2 flooding of all suitable oil reservoirs in the country not yet undergoing tertiary recovery.

Scientific Investigations Report↗