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At least 1,495 records · Page 83Linked to original sources
USGS2022

Comparison of the results of enzyme-linked immunosorbent assay (ELISA) to mass-spectrometry based analytical methods for six unregulated contaminants in source water and finished drinking-water samples

Regulatory entities, such as the Minnesota Department of Health, monitor public water systems for conformance with Federal and State monitoring requirements and water-quality standards. Although some contaminants have Federal and (or) State regulations and guidance values, many contaminants, such as pesticides and pharmaceuticals, are unregulated in that only non-enforceable health-based guidance values have been assigned to them. Furthermore, because these contaminants are not regulated, commonly only limited resources are available to public water systems or regulatory entities to monitor them in drinking water. Focused screening efforts on contaminants that are frequently detected in the environment can provide information to help monitoring entities prioritize their sampling efforts. Here we assess the use of enzyme-linked immunosorbent assay (ELISA) method, a rapid, inexpensive screening method, as an alternative to more expensive methods to analyze source and finished drinking-water samples collected from public water systems throughout Minnesota for three commonly detected pesticides (atrazine, imidacloprid, and pyrethroids) and three commonly detected pharmaceuticals (caffeine, carbamazepine, and sulfamethoxazole). The ELISA results were compared to results provided by more advanced mass-spectrometry analytical methods at the U.S. Geological Survey National Water Quality Laboratory (NWQL) and SGS AXYS Analytical Services Ltd. (AXYS). Overall, these datasets are highly censored (>80 percent) and contain multiple reporting limits within and between laboratories. To discern agreement between paired contaminant group results (target contaminant plus immunologically similar contaminants) by ELISA and the advanced analytical methods at NWQL and AXYS, presence-absence agreement analysis was coupled with false negative and false positive analysis. Analysis of presence-absence agreement shows that ELISA has generally good agreement (77.9 to 100 percent) with both NWQL and AXYS for all unregulated contaminant groups. Imidicloprid, pyrethroids, and caffeine contaminant groups have relatively low false positivity rates (16, 6, and 5 percent, respectively) when analyzed by ELISA, which indicates the ELISA method, for these contaminant groups, could be experiencing low-level interference attributed to the detection of immunologically similar contaminants. Similarly, sulfamethoxazole has a low false positivity rate (0.8 percent), which indicates ELISA is likely not overestimating results for this contaminant group. Analyses for carbamazepine and sulfamethoxazole by ELISA resulted in low false negativity rates (1.6 and 0.8 percent, respectively), which indicates the ELISA method is likely not underestimating the results for this contaminant group. Conversely, the atrazine contaminant group has a high false negativity rate (84 percent), which indicates the method has a strong negative bias and that ELISA underestimates results for this contaminant. These qualitative results indicate that the ELISA method could potentially serve as a reliable and cost-effective screening method to help drinking water monitoring entities prioritize sampling efforts for analyzing carbamazepine and sulfamethoxazole in source and finished drinking-water samples collected from public water systems. At the same time, although ELISA did not prove to be a good screening method for atrazine, evaluation of ELISA results indicated that its use for screening imidacloprid, pyrethroids, and caffeine could be beneficial for water testing.

Minnesota↗
USGS2022

Element concentrations and grain size of sediment from the Similkameen River above Enloe Dam (Enloe Reservoir) near Oroville, Washington, 2019

In 2019, the U.S. Geological Survey conducted a reconnaissance survey of concentrations of 41 trace elements present in bed sediment in the reservoir on the Similkameen River upstream from Enloe Dam, near Oroville, Washington. The Similkameen River drains a watershed containing highly mineralized geologic deposits with current (2019) and historical mining activity. Results of this survey indicated that surface and subsurface sediment are substantially enriched in element concentrations of silver (Ag), arsenic (As), gold (Au), bismuth (Bi), cadmium (Cd), copper (Cu), manganese (Mn), antimony (Sb), selenium (Se), tin (Sn), and tellurium (Te) relative to average concentrations found in upper continental-crustal material. Conversely, concentrations of mercury (Hg) and lead (Pb) in sediment above Enloe Dam (Enloe Reservoir) were generally less than average concentrations in upper continental-crustal material (Hg = 0.05 milligrams per kilogram [mg/kg]; Pb =17 mg/kg). Concentrations of most trace elements were higher in the less than 63-micrometer fraction (silt) and tended to be higher in subsurface than in surface sediment. The concentrations of trace elements were compared to consensus-based aquatic toxicity reference concentrations, Washington State Department of Ecology sediment management standards, and average concentrations of upper continental-crustal material. Arsenic concentrations were consistently elevated above these criteria among samples and often exceeded sediment management standards and aquatic toxicity reference values (both threshold effects and probable effects concentrations). High concentrations of As were measured in sediment with proportionally more material in the less than 63-micrometer size fraction; this result may be related to the presence of ore-processing waste material that has entered the aquatic system from approximately 125 years of mining operations in the basin. Elevated concentrations of chromium and copper that exceed the same criteria as arsenic (As) were measured less consistently and predominantly in the fine-grain size fraction.

Washington↗
USGS2023

Modeling flow and water quality in reservoir and river reaches of the Mahoning River Basin, Ohio

Executive Summary The U.S. Army Corps of Engineers (USACE) is considering changes to the management of water surface elevation in four lakes in the Mahoning River Basin. These changes would affect the timing and amounts of water released to the Mahoning River and could affect the water quality of those releases. To provide information on possible water-quality effects from these operational changes, flow and water-quality models were constructed for Berlin Lake, Lake Milton, Michael J Kirwan Reservoir, Mosquito Creek Lake, Mosquito Creek, and the Mahoning River from the dams downstream to Lowellville, Ohio. The models were calibrated for two calendar years each, with model years selected depending on the availability of water-quality data. Models were developed with CE-QUAL-W2 version 4.2 (Wells, S.A., 2020, CE-QUAL-W2—A two-dimensional, laterally averaged, hydrodynamic and water quality model [version 4.2]: Portland State University, variously paged), a two-dimensional, laterally averaged hydrodynamic and water-quality model. Modeled constituents included flow, velocity, ice cover, water temperature, total dissolved solids (TDS), sulfate, chloride, inorganic suspended sediment, nitrate, ammonia, total Kjeldahl nitrogen, orthophosphate, total phosphorus, dissolved and particulate organic matter, algae, and dissolved oxygen. Iron was included for the lake models, but not the river. A whole-basin model, with the four lake models and river model, was used to run model scenarios to examine the effects of altered lake water surface elevations on flow and water quality in the lakes, the lake outflows, and the Mahoning River. The initial whole-basin model, with calendar year 2013 hydrology and measured or typical water quality, was designated as scenario 0. Mahoning River flows for calendar year 2013 were close to a 20-year median flow. Four additional scenarios were constructed based on reservoir operations model (RES-SIM) model water surface elevations for the four lakes as provided by USACE. Scenario 1 was the RES-SIM base case, scenario 2 kept Berlin Lake water surface elevations higher in summer, scenario 3 allowed 25 percent of summer flood storage to extend the guide curve, and scenario 4 allowed more flexibility in lake management by removing any downstream Mahoning River minimum flow requirements. The Mahoning River model was not changed in any scenarios but received altered flows from the lakes. Significant findings from this study include the following: In two of the four lakes (Berlin and Mosquito Creek Lakes), development of lake model grids using recent bathymetric surveys suggests that sedimentation in these lakes has occurred since they were constructed, altering volume-elevation curves. Tests of model parameter sensitivity showed that modeled water temperature, TDS, and dissolved oxygen were relatively insensitive to model parameter values. Modeled chlorophyll a , a measure of algal concentration, was most sensitive to parameter values; nitrate and total phosphorus concentrations were affected by a few of the parameters tested. As a group, the lake model results were more sensitive to model parameter values compared to the Mahoning River model. Data gaps were identified for inflows, both for water quantity and water quality, that could be filled through future sampling programs. Ample data were available from within the waterbodies for model calibration. The model simulated the general spatial and temporal patterns of water temperature, TDS, chloride, sulfate, nutrients, suspended sediment, organic matter, chlorophyll a , and dissolved oxygen in the lakes and Mahoning River. From late spring to autumn in the years modeled (2006, 2013, 2017–19 depending on the lake), all lakes developed thermal stratification and periods of anoxia in bottom waters. Stratification was most stable in Michael J Kirwan Reservoir and least stable in Mosquito Creek Lake. The stratification and anoxia in Berlin Lake, Lake Milton, and Mosquito Creek Lake could be interrupted by high-flow inputs moving through those lakes. The model predicted the release of ammonia and iron during anoxic periods in the lake hypolimnions. Concentrations of TDS, nitrate, orthophosphate, and total phosphorus increased in the Mahoning River down to Lowellville, the end of the river model, in the years modeled. These concentrations were greater than those in upstream lake releases. Chloride and sulfate concentrations were underpredicted in the Mahoning River, suggesting the presence of unreported chloride and sulfate inputs to the river, at least in the years modeled. Model scenario 4 kept water surface elevations the highest in all lakes in the April to mid-December period, compared to scenarios 1–3. Model scenario 2 kept water surface elevations in Berlin Lake higher in summer and late autumn, compared to scenarios 1 and 3, but to satisfy downstream minimum flow requirements, water surface elevations in the other lakes had periods of lower water surface elevation. As a group, scenarios 1–3 had largely similar effects on flow and water surface elevation in the Mahoning River because the lake releases in those scenarios still met downstream Mahoning River flow targets. Modeling the removal of downstream flow targets, scenario 4 had periods of lower flow in the Mahoning River from April to mid-September as water was held in the lakes, and periods of higher Mahoning River flow from mid-September through November as the lakes were drawn down to prepare for winter flood-risk management. In the four scenarios, all the lakes and lake outflows had generally similar seasonal cycles of water quality, though some differences were predicted. For instance, higher concentrations of iron and ammonia in the Lake Milton hypolimnion were modeled during a period of both low inflows from Berlin Lake and low outflows at Lake Milton dam. It is possible that those changes could be minimized by maintaining more flow or pulses of higher flow through the lake. Compared to the scenario 1 base case, changes to Mahoning River water quality were relatively minor for scenarios 2 and 3, which maintained downstream flows but shifted the flow source among the upstream lakes. The largest changes in Mahoning River water quality were predicted between Leavittsburg and Lowellville for scenario 4. The periods of lower lake outflows between April and mid-September led to correspondingly higher concentrations of TDS, orthophosphate, total phosphorus, and nitrate in the river, compared to the base case scenario 1. Conversely, the overall greater lake outflows from mid-September through November in scenario 4 led to periods of lower concentrations of TDS and nutrients in that portion of the river, at that time of year.

Ohio↗
USGS2023

Assessing potential effects of changes in water use in the middle Carson River Basin with a numerical groundwater-flow model, Eagle, Dayton, and Churchill Valleys, west-central Nevada

During the economic boom of the mid part of the first decade of the 2000s in northwestern Nevada, municipal and housing growth increased use of the water resources of this semi-arid region. In 2008, when the economy slowed, new housing development stopped, and immediate pressure on groundwater resources abated. The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, began a hydrogeologic study of the middle Carson River Basin. The first half of the study reviewed and synthesized previous geologic studies and contributed new datasets that served as a foundation for a three-dimensional, transient numerical model of groundwater and surface-water flow for the middle Carson River Basin extending from Eagle Valley to Churchill Valley. The model can be used to evaluate the effects of proposed alternative management strategies on groundwater sustainability, flows in the Carson River, and routine operation of Lahontan Reservoir and can also provide a basis for basin-wide investigations seeking to quantitatively evaluate the effects of climate change or yet-to-be-determined alternative management strategies. The middle Carson model was constructed using the U.S. Geological Survey groundwater modeling software MODFLOW-NWT. MODFLOW is widely used groundwater modeling software and is well-suited for evaluating groundwater and surface-water interactions. The model uses 550-feet square grid cells that align with the previously published model for Carson Valley (adjacent upstream valley). Six grid layers with more finely resolved vertical resolution near the perimeter of the active model domain and near surface-water features, compared to other areas of the active model domain, hone the simulated groundwater and surface-water exchanges. In addition to simulating groundwater and surface-water interaction, crop and phreatophyte evapotranspiration, lake evaporation, mountain-front recharge, recharge from irrigation return flows, and groundwater pumping are also simulated. Surface-water flow entering the model domain, including the Carson River, tributary inflow from perennial streams in Eagle Valley, and trans-basin imports through the Truckee Canal (surface water diverted from the Truckee River) are specified according to U.S. Geological Survey streamgage records. Groundwater pumpage and surface-water diversions to 10 agricultural ditches and the managed release from Lahontan Reservoir, at the end of the middle Carson River Basin, are specified according to water-manager records. The model simulation period extended from 2000 through 2010 (January 1, 2000, to December 31, 2010) using 574 weekly stress periods, with a single steady-state stress period at the beginning of the simulation that establishes initial conditions by approximating average conditions during the transient simulation period. All available observations for this period were used during the model calibration process, performed using automated parameter-estimation software. Calibration targets included observations of groundwater elevations in wells, streamflow, differences in observed streamflow between successive streamgages and actual evapotranspiration from irrigated lands. Among all 5,296 simulated and observed groundwater level pairs, the mean error was 1.42 feet; the mean absolute error, 7.71 feet; and the percent bias was −0.1 percent. Three alternative management scenarios, run using the entire period of analysis (2000–10), were simulated to improve understanding of the potential effects of (1) loss of irrigated agricultural lands following conversion of water-rights to municipal groundwater rights; (2) reclaiming treated wastewater with induction wells; and (3) exercising permitted but under-utilized groundwater rights. Scenarios 2 and 3 were further explored using two and four subscenarios, respectively. Simulated scenario results ranged from having little effect on the groundwater system relative to a baseline simulation to having spatially extensive and large groundwater-level declines (10 to 20 feet) compared to the baseline simulation. None of the simulated scenarios increased delivery of river flows to Lahontan Reservoir. On the contrary, one of the subscenarios under alternative management scenario 3 led to surface-water delivery shortfalls of more than 10,000 acre-feet per year. Future model improvements may include an extension of the model simulation period backward and forward in time and directly linking it to the upstream Carson Valley groundwater model. Furthermore, converting this MODFLOW model to a GSFLOW model, which fully integrates groundwater and surface-water flows including precipitation runoff and infiltration, may provide an improved tool for comprehensive management of water-resources in the middle Carson River Basin.

Nevada↗
USGS2023

Investigation of potential factors controlling benthic algae in the upper White River Basin, Colorado, 2018–21

Nuisance levels of benthic filamentous green algae are becoming increasingly common in surface waters of Colorado and the western United States. In 2018 the U.S. Geological Survey began a study in cooperation with the White River and Douglas Creek Conservation Districts, Colorado River Basin Salinity Control Forum, and the Colorado River Water Conservation District to collect and analyze physical, chemical, and biological information for the upper White River Basin in Colorado and investigate causes of benthic algal blooms in the basin. This report (1) presents site-specific data including water temperature, riparian canopy cover, streambed particle size, and algal biomass and community composition; (2) describes the potential for streambed movement during spring runoff using physical channel characteristics and peak streamflow velocities; and (3) explains the results of a linear mixed-effects model used to test hypotheses about the influence of physical and chemical factors in explaining the occurrence of algal blooms across the basin. Benthic algal biomass ranged from 0.7 to 309 milligrams per square meter during the summer (July–August) from 2018 through 2021 and exceeded the Colorado Department of Public Health and Environment criteria of 150 milligrams per square meter on four occasions, in 2018. Four genera of filamentous green algae were identified in the upper White River Basin, including Cladophora , Stigeoclonium , Ulothrix , and Spirogyra . Many genera of cyanobacteria were present, including some capable of producing toxins and taste and odor compounds. The nuisance diatom Didymosphenia geminata , commonly referred to as didymo, was found at two sites on the South Fork White River and along the main stem White River. Hypotheses pertaining to the influence of measured variables on algal biomass were tested with a linear mixed-effects model. Median rock size and mean August water temperature had significant positive effects, meaning that greater bed stability and higher mean August water temperatures result in greater algal biomass. Total nitrogen to total phosphorus ratios had a significant negative effect on algal biomass, meaning that more nitrogen-limiting conditions, or greater phosphorus availability, corresponded to greater algal biomass. Streamflow and water temperature data at White River above Coal Creek near Meeker, Colo., were used to assess possible causes of bloom conditions across years, including when algal blooms were first studied in the basin during 2016 and 2017. Early or low-magnitude peak streamflow conditions were not prerequisites for algal bloom occurrence. Conversely, relatively large, late, and long-lasting peak streamflows, such as those measured in 2019, may limit algal blooms during the same year and into subsequent years, as evidenced by extremely low algal biomass in 2019 and 2020. The broad spatial extent of bloom conditions indicates that the factors contributing to the occurrence of algal blooms are likely basinwide. Findings from this multiyear study indicate that the effects caused by larger peak streamflow, including movement of the streambed, may be the dominant control on the occurrence of an algal bloom. The findings also indicate that in the absence of disturbance other resources, including substrate size, water temperature, and nutrient availability, moderate algal biomass.

Colorado↗
USGS2023

Updates to the regional groundwater-flow model of the New Jersey Coastal Plain, 1980–2013

A 21-layer three-dimensional transient groundwater-flow model of the New Jersey Coastal Plain was developed and calibrated by the U.S. Geological Survey (USGS) in cooperation with the New Jersey Department of Environmental Protection to simulate groundwater-flow conditions during 1980–2013, incorporating average annual groundwater withdrawals and average annual groundwater recharge. This model is the third version of the New Jersey Coastal Plain regional groundwater-flow model that was initially developed as part of the USGS Regional Aquifer System Analysis (RASA) program. The model simulates groundwater flow in 11 aquifers and 10 intervening confining units of the New Jersey Coastal Plain to provide a regional overview of groundwater conditions. Averaged groundwater withdrawal data for 1980 to 2013 were used in the model. The 11 aquifers in New Jersey are, from shallowest to deepest, the Holly Beach water-bearing zone and the confined Cohansey aquifer in Cape May County; the Rio Grande water-bearing zone; the Atlantic City 800-foot sand; the Piney Point, Vincentown, and Wenonah-Mount Laurel aquifers; the Englishtown aquifer system; and the upper, middle, and lower aquifers of the Potomac-Raritan-Magothy (PRM) aquifer system. The model was developed with the MODFLOW–2005 numerical code and the UCODE parameter estimation technique and calibrated using water-level and base-flow observations. A total of 3,453 water-level observations from 392 wells in New Jersey and 48 wells in Delaware from 1983 to 2013 were used in model calibration, which includes historical water-level trends for 29 wells in New Jersey during 1980–2013 presented in time-series hydrographs. In addition, derived observations also were included by calculating the vertical gradient at 33 pairs of nested observation wells in New Jersey, for a total of 210 observations. Changes in water levels over time were calculated for 134 wells in New Jersey and four wells in Delaware where water levels had varied substantially (approximately 10 ft) over the 30-year span of synoptic water-level measurements, for a total of 767 observations. A total of 1,485 base-flow observations in 47 surface-water basins in New Jersey from 1980 to 2013 were used in model calibration. Updates to the groundwater-flow model include the conversion to a fully three-dimensional model from the previous quasi-three-dimensional model. The new model will allow for potential future uses such as particle tracking or simulation of variable-density groundwater flow that could not be accomplished with earlier versions of the model. Spatially and temporally variable recharge estimated by using a soil-water balance model resulted in a spatially and temporally finer discretization. The Rio Grande water-bearing zone was added to the model as an aquifer layer to refine estimates of simulated flow in Atlantic and Cape May Counties, New Jersey. Hydrogeologic parameters were updated to include the confining units in New Jersey and corresponding hydrogeologic units in Delaware and eastern Maryland. The simulated water levels for the New Jersey Coastal Plain aquifers were compared to water-level measurements made during 1980–2013. The average residual for 4,243 water-level observations for New Jersey (simulated water levels minus measured water levels) is 1.5 feet. The simulated water-level contours for the confined aquifers for 2013 were compared to potentiometric surfaces produced from water levels measured during 2013. Simulated water levels generally matched the 2013 potentiometric surfaces of the confined aquifers in the areas of large withdrawals. Hydrographs of wells in the confined Coastal Plain aquifers of New Jersey show that simulated water levels generally match the magnitude and seasonal variation of the observed water levels. Hydrographs of base flow for the 47 streamgaging stations in New Jersey indicate that most of the simulated and estimated data match reasonably well. Groundwater withdrawals are an important resource for water supply, agricultural, industrial, and commercial needs in the New Jersey Coastal Plain. Groundwater withdrawals from the New Jersey Coastal Plain aquifers have resulted in persistent, regionally extensive cones of depression in the Englishtown aquifer system and Wenonah-Mount Laurel aquifer in Ocean and Monmouth Counties; Wenonah-Mount Laurel and upper, middle, and lower PRM aquifers in Camden County; and Atlantic City 800-foot sand in Atlantic County. Because hydrologic stresses and water-management needs change with time, periodic updates to the groundwater-flow model are required to provide current information about hydrologic conditions in the New Jersey Coastal Plain and to maintain its usefulness as a tool to manage water resources and develop water-resource strategies. The current updates will support the continued application of this model as a tool for evaluating the regional effects of changes in groundwater withdrawals and of current and potential future water-management strategies on groundwater levels in the New Jersey Coastal Plain.

New Jersey Coastal Plain↗
USGS2024

Introduction to recommended capabilities and instrumentation for volcano monitoring in the United States

Introduction The National Volcano Early Warning System (NVEWS) was authorized and partially funded by the U.S. Government in 2019. In response, the U.S. Geological Survey (USGS) Volcano Hazards Program asked its scientists to reflect on and summarize their views of best practices for volcano monitoring. The goal was to review and update the recommendations of a previous report (Moran and others, 2008) and to provide a more detailed analysis of capabilities and instrumentation for monitoring networks for U.S. volcanoes. This Scientific Investigations Report and its chapters reflect those USGS scientists’ views and summaries and will serve as a guide for future network upgrades funded through NVEWS. Given the well-documented hazards posed by volcanoes to population centers and aviation (for example, Blong, 1984; Scott, 1989; Neal and others, 1997, 2019; Guffanti and others, 2010; Shroder and Papale, 2014; Prata and Rose, 2015; Palmer, 2020), volcano monitoring is critical for ensuring public safety and for mitigating the impacts of volcanic activity. Accurate and timely forecasts are facilitated by well-designed monitoring networks that are in place long enough to allow for background behavior to be recognized and understood. Because precursory signals may be limited and unrest may progress rapidly to an eruption, our goal is to deploy monitoring systems that enable detection of the reactivation of dormant volcanoes as early as possible, allowing for public safety and risk mitigation. NVEWS planning is also informed by the results of Ewert and others (2005, 2018), whereby 161 U.S. volcanoes are currently categorized and ranked commensurate with their relative threat. In each chapter, author(s) considered the need for some redundancy of instrumentation and telemetry, given the likelihood of occasional equipment failure, particularly in extreme and remote environments. Establishing digital telemetry networks requires advanced planning, sighting, radio-shot testing, and, inevitably, troubleshooting in the field. This is harder to achieve rapidly during a crisis; thus, an important goal for monitoring U.S. volcanoes is to establish digital telemetry backbones with redundancy and extra capacity to absorb additional instruments should a volcano begin to exhibit signs of unrest (fig. A1). The National Telecommunications and Information Administration (NTIA) imposed new regulations in the United States, eliminating the use of older analog radios for many purposes, which had been one previous means for redundant data delivery. However, the resulting conversion from analog to digital systems usefully enables stations to accommodate new and multivariate real-time data streams (for example, Global Navigation Satellite System [GNSS] receivers, infrasound arrays, gas spectrometers, visible and infrared cameras, and broadband seismometers). We note that other USGS and broader national and international hazard programs can leverage NVEWS instrumentation plans. Examples of this include the following: Improved seismic coverage of volcanoes will increase the capability of the USGS Earthquake Hazards Program to detect and locate earthquakes, estimate ground shaking, and provide timely early warnings through the ShakeAlert Earthquake Early Warning System (Given and others, 2018). The National Oceanic and Atmospheric Administration’s Tsunami Program will benefit from additional seismic stations, particularly within the sparsely instrumented Aleutian Islands, Northern Mariana Islands, and American Samoa. Infrasound stations can detect signals from landslides, debris flows and lahars, floods, and weather events, providing benefits to the National Weather Service and the USGS Landslide Hazards Program.

Scientific Investigations Report↗
USGS2025

Simulated hydrologic responses to proposed wastewater-returnflow scenarios in Falmouth, Massachusetts

The Cape Cod aquifer is the sole source of drinking water for communities on Cape Cod, Massachusetts, including the Town of Falmouth, where the aquifer is currently threatened by contamination from septic-system-derived nitrogen. To address this problem, the Town is proposing to sewer areas of Falmouth, treat the wastewater at the Town’s Main Wastewater Treatment Facility (a nitrogen removing/tertiary treatment facility), and discharge the treated wastewater to an ocean outfall pipe in Nantucket Sound. The U.S. Geological Survey, in cooperation with the Town of Falmouth, updated a three-dimensional steady-state groundwater flow model to represent current (defined as 2019–23) average hydrologic conditions and to simulate the long-term average freshwater hydrologic response to two wastewater-return-flow scenarios. Scenario 1 involves the sewering of all properties south of Route 28 in Falmouth, which approximates the Town’s possible sewer expansion over the next 20–30 years. Scenario 2 involves sewering of all properties in Falmouth to demonstrate the maximum potential effect of sewering on the aquifer. Overall, the simulated hydrologic response of water-table altitudes and streamflow in both scenarios was relatively small compared to fluctuations from natural recharge. In scenario 1, the water-table altitude decreased by about 0.1 feet south of Route 28, where the conversion to municipal sewers removed wastewater-return flow from onsite septic systems. The water-table altitude decreased by about 0.1–0.2 feet over a larger area in Falmouth under town-wide sewering in scenario 2. The greatest decrease in water-table altitude in both scenarios occurred near the Main Wastewater Treatment Facility, with a decrease of about 1.1 feet in scenario 1 and about 1.3 feet in scenario 2. Simulated decreases in streamflow also were estimated for six selected streams in Falmouth and Mashpee. In both scenarios, the largest simulated decreases in streamflow were at the Coonamessett River, which is the closest stream to the Main Wastewater Treatment Facility. In scenario 1, the average annual decrease in flow at the Coonamessett River was 0.1 cubic feet per second, a 1.1 percent decrease from current (2019–23) conditions. In scenario 2, streamflow at the Coonamessett River decreased by 0.6 cubic feet per second, a 5.4 percent decrease from current (2019–23) conditions.

Massachusetts↗
USGS2026

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–23, California Groundwater Ambient Monitoring and Assessment Program, Priority Basin Project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–23. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban-and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert -butyl ether showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in total dissolved solids by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and methyl tert -butyl ether are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

California↗
USGS2026

Modeled groundwater and surface-water interactions surrounding Mobile Bay, Alabama, 2008–15

The U.S. Geological Survey, in cooperation with the Gulf Coast Ecosystem Restoration Council, has used MODFLOW 6 to develop a groundwater-flow model to simulate groundwater and surface-water interactions in the Mobile Bay, Alabama, area. The model results indicated that, on average, groundwater discharge near the coastline is equal to 2.5 percent of the surface water that flows into the bay. The model was also used to determine how changes in recharge, sea level, and groundwater pumping affect groundwater levels and discharge rates. The results indicate that more groundwater discharge occurred in the winter and spring when recharge was higher, sea level was lower, and groundwater pumping was lower than during the summer and fall. Additionally, the amount of emergent groundwater was closely related to sea level; when sea level was higher, there was more area with emergent groundwater. Furthermore, the depth of nonemergent groundwater was related to trends in recharge and pumping. During periods of increased recharge and reduced pumping, a significant portion of the model area exhibited a depth to the water table of less than 1 meter below the land surface. Conversely, during periods of decreased recharge and heightened pumping, much of the model area showed a depth to the water table ranging from 1 to 5 meters.

Alabama, Mississippi↗
USGS2023

White-Nose Syndrome Diagnostic Laboratory Network handbook

When responding to a wildlife disease outbreak, managers depend on consistent and clear data to make decisions. However, diagnostic methods for detecting pathogens of wildlife often lack the level of procedural and interpretational standardization that occurs in the investigation of human and domestic animal diseases. This lack of standardization can hamper diagnostic reliability in two ways. First is the inappropriate application of tests to new species or in situations that are outside of the original (in other words, validated) purpose. Second is the use of laboratory-specific modifications or analytical parameters without thorough investigation of how those changes affect result comparisons across institutions or the ability to make broader conclusions about pathogen or disease. White-nose syndrome (WNS) is a disease caused by the fungal pathogen Pseudogymnoascus destructans ( Pd ), which has spread rapidly and is causing population-level declines in some species of North American bats. During the last decade, quantitative polymerase chain reaction (qPCR) has become the most common method of testing for Pd because of qPCR’s speed, accuracy, and simplicity across a wide range of invasive and noninvasive sample types. Its widespread use by many State, Federal, Provincial, and academic institutions has inevitably led to variations in methodology and interpretation among laboratories. The progressive geographic spread of fungus and disease has also led to sampling contexts and strategies that differ from those for which the qPCR assay was originally developed and validated. These factors have resulted in inconsistencies among results tested in different laboratories and, subsequently, confusion for managers and decision makers. To address these challenges, the WNS National Response Team Diagnostic Working Group launched a project congruent with increased calls for the harmonization of wildlife disease diagnostic results, and reporting standards across disparate methodologies and laboratories. Beginning in 2019, interlaboratory testing was done to better understand how variations to Pd qPCR methodology affect diagnostic consistency and to reassess the assay’s fit for purpose in new testing contexts. This information led to expanded conversations within the Diagnostic Working Group related to best practices in Pd qPCR diagnostic testing, the development of common interpretation language for classifying test results, and the incorporation of that language into an updated WNS case definition. This handbook is the resulting product and is intended to help further harmonize Pd qPCR diagnostic testing by establishing recommendations related to voluntary participation in a WNS Diagnostic Laboratory Network, documenting the currently (2022) practiced Pd qPCR methodologies, discussing general best practices for molecular diagnostics and laboratory networks, and elaborating on the epidemiologic and diagnostic basis of the agreed-upon classification language for Pd qPCR results. Through this voluntary, consensus-based approach to diagnostic harmonization, this work aims to improve the confidence of management agencies in reported Pd qPCR results and can serve as an example of national diagnostic coordination for other unregulated wildlife diseases.

Techniques and Methods↗
USGS2015

U.S. Geological Survey Noble Gas Laboratory’s standard operating procedures for the measurement of dissolved gas in water samples

This report addresses the standard operating procedures used by the U.S. Geological Survey’s Noble Gas Laboratory in Denver, Colorado, U.S.A., for the measurement of dissolved gases (methane, nitrogen, oxygen, and carbon dioxide) and noble gas isotopes (helium-3, helium-4, neon-20, neon-21, neon-22, argon-36, argon-38, argon-40, kryton-84, krypton-86, xenon-103, and xenon-132) dissolved in water. A synopsis of the instrumentation used, procedures followed, calibration practices, standards used, and a quality assurance and quality control program is presented. The report outlines the day-to-day operation of the Residual Gas Analyzer Model 200, Mass Analyzer Products Model 215–50, and ultralow vacuum extraction line along with the sample handling procedures, noble gas extraction and purification, instrument measurement procedures, instrumental data acquisition, and calculations for the conversion of raw data from the mass spectrometer into noble gas concentrations per unit mass of water analyzed. Techniques for the preparation of artificial dissolved gas standards are detailed and coupled to a quality assurance and quality control program to present the accuracy of the procedures used in the laboratory.

Techniques and Methods↗
USGS2008

Guide to the Revised Ground-Water Flow and Heat Transport Simulator: HYDROTHERM - Version 3

The HYDROTHERM computer program simulates multi-phase ground-water flow and associated thermal energy transport in three dimensions. It can handle high fluid pressures, up to 1 ? 109 pascals (104 atmospheres), and high temperatures, up to 1,200 degrees Celsius. This report documents the release of Version 3, which includes various additions, modifications, and corrections that have been made to the original simulator. Primary changes to the simulator include: (1) the ability to simulate unconfined ground-water flow, (2) a precipitation-recharge boundary condition, (3) a seepage-surface boundary condition at the land surface, (4) the removal of the limitation that a specified-pressure boundary also have a specified temperature, (5) a new iterative solver for the linear equations based on a generalized minimum-residual method, (6) the ability to use time- or depth-dependent functions for permeability, (7) the conversion of the program code to Fortran 90 to employ dynamic allocation of arrays, and (8) the incorporation of a graphical user interface (GUI) for input and output. The graphical user interface has been developed for defining a simulation, running the HYDROTHERM simulator interactively, and displaying the results. The combination of the graphical user interface and the HYDROTHERM simulator forms the HYDROTHERM INTERACTIVE (HTI) program. HTI can be used for two-dimensional simulations only. New features in Version 3 of the HYDROTHERM simulator have been verified using four test problems. Three problems come from the published literature and one problem was simulated by another partially saturated flow and thermal transport simulator. The test problems include: transient partially saturated vertical infiltration, transient one-dimensional horizontal infiltration, two-dimensional steady-state drainage with a seepage surface, and two-dimensional drainage with coupled heat transport. An example application to a hypothetical stratovolcano system with unconfined ground-water flow is presented in detail. It illustrates the use of HTI with the combination precipitation-recharge and seepage-surface boundary condition, and functions as a tutorial example problem for the new user.

Techniques and Methods↗
USGS2008

User Guide and Documentation for Five MODFLOW Ground-Water Modeling Utility Programs

This report documents five utility programs designed for use in conjunction with ground-water flow models developed with the U.S. Geological Survey's MODFLOW ground-water modeling program. One program extracts calculated flow values from one model for use as input to another model. The other four programs extract model input or output arrays from one model and make them available in a form that can be used to generate an ArcGIS raster data set. The resulting raster data sets may be useful for visual display of the data or for further geographic data processing. The utility program GRID2GRIDFLOW reads a MODFLOW binary output file of cell-by-cell flow terms for one (source) model grid and converts the flow values to input flow values for a different (target) model grid. The spatial and temporal discretization of the two models may differ. The four other utilities extract selected 2-dimensional data arrays in MODFLOW input and output files and write them to text files that can be imported into an ArcGIS geographic information system raster format. These four utilities require that the model cells be square and aligned with the projected coordinate system in which the model grid is defined. The four raster-conversion utilities are * CBC2RASTER, which extracts selected stress-package flow data from a MODFLOW binary output file of cell-by-cell flows; * DIS2RASTER, which extracts cell-elevation data from a MODFLOW Discretization file; * MFBIN2RASTER, which extracts array data from a MODFLOW binary output file of head or drawdown; and * MULT2RASTER, which extracts array data from a MODFLOW Multiplier file.

Techniques and Methods↗
USGS2000

Design, revision, and application of ground-water flow models for simulation of selected water-management scenarios in the coastal area of Georgia and adjacent parts of South Carolina and Florida

Ground-water flow models of the Floridan aquifer system in the coastal area of Georgia and adjacent parts of South Carolina and Florida, were revised and updated to ensure consistency among the various models used, and to facilitate evaluation of the effects of pumping on the ground-water level near areas of saltwater contamination. The revised models, developed as part of regional and areal assessments of ground-water resources in coastal Georgia, are--the Regional Aquifer-System Analysis (RASA) model, the Glynn County area (Glynn) model, and the Savannah area (Savannah) model. Changes were made to hydraulic-property arrays of the RASA and Glynn models to ensure consistency among all of the models; results of theses changes are evidenced in revised water budgets and calibration statistics. Following revision, the three models were used to simulate 32 scenarios of hypothetical changes in pumpage that ranged from about 82 million gallons per day (Mgal/d) lower to about 438 Mgal/d higher, than the May 1985 pumping rate of 308 Mgal/d. The scenarios were developed by the Georgia Department of Natural Resources, Environmental Protection Division and the Chatham County-Savannah Metropolitan Planning Commission to evaluate water-management alternatives in coastal Georgia. Maps showing simulated ground-water-level decline and diagrams presenting changes in simulated flow rates are presented for each scenario. Scenarios were grouped on the basis of pumping location--entire 24-county area, central subarea, Glynn-Wayne-Camden County subarea, and Savannah-Hilton Head Island subarea. For those scenarios that simulated decreased pumpage, the water level at both Brunswick and Hilton Head Island rose, decreasing the hydraulic gradient and reducing the potential for saltwater contamination. Conversely, in response to scenarios of increased pumpage, the water level at both locations declined, increasing the hydraulic gradient and increasing the potential for saltwater contamination. Pumpage effects on ground-water levels and related saltwater contamination at Brunswick and Hilton Head Island generally diminish with increased distance from these areas. Additional development of the Upper Floridan aquifer may be possible in parts of the coastal area without affecting saltwater contamination at Brunswick or Hilton Head Island, due to the presence of two hydrologic boundaries--the Gulf Trough, separating the northern and central subareas; and the hypothesized Satilla Line, separating the central and southern subareas. These boundaries diminish pumpage effects across them; and may enable greater ground-water withdrawal in areas north of the Gulf Trough and south of the Satilla Line without producing appreciable drawdown at Brunswick or Hilton Head Island.

Florida, Georgia, South Carolina↗
USGS2001

Diurnal variations in metal concentrations in the Alamosa River and Wightman Fork, southwestern Colorado, 1995-97

A comprehensive sampling network was implemented in the Alamosa River Basin from 1995 to 1997 to address data gaps identified as part of the ecological risk assessment of the Summitville Superfund site. Aluminum, copper, iron, and zinc were identified as the constituents of concern for the risk assessment. Water-quality samples were collected at six sites on the Alamosa River and Wightman Fork by automatic samplers. Several discrete (instantaneous) samples were collected over 24 hours at each site during periods of high diurnal variations in streamflow (May through September). The discrete samples were analyzed individually and duplicate samples were composited to produce a single sample that represented the daily-mean concentration. The diurnal variations in concentration with respect to the theoretical daily-mean concentration (maximum minus minimum divided by daily mean) are presented. Diurnal metal concentrations were highly variable in the Alamosa River and Wightman Fork. The concentration of a metal at a single site could change by several hundred percent during one diurnal cycle. The largest percent change in metal concentrations was observed for aluminum and iron. Zinc concentrations varied the least of the four metals. No discernible or predictable pattern was indicated in the timing of the daily mean, maximum, or minimum concentrations. The percentage of discrete sample concentrations that varied from the daily-mean concentration by thresholds of plus or minus 10, 25, and 50 percent was evaluated. Between 50 and 75 percent of discrete-sample concentrations varied from the daily-mean concentration by more than plus or minus 10 percent. The percentage of samples exceeding given thresholds generally was smaller during the summer period than the snowmelt period. Sampling strategies are critical to accurately define variability in constituent concentration, and conversely, understanding constituent variability is important in determining appropriate sampling strategies. During nonsteady-state periods, considerable errors in estimates of daily-mean concentration are possible if based on one discrete sample. Flow-weighting multiple discrete samples collected over a diurnal cycle provides a better estimate of daily-mean concentrations during nonsteady-state periods.

Colorado↗
USGS2000

Documentation of a computer program to simulate lake-aquifer interaction using the MODFLOW ground water flow model and the MOC3D solute-transport model

Heads and flow patterns in surficial aquifers can be strongly influenced by the presence of stationary surface-water bodies (lakes) that are in direct contact, vertically and laterally, with the aquifer. Conversely, lake stages can be significantly affected by the volume of water that seeps through the lakebed that separates the lake from the aquifer. For these reasons, a set of computer subroutines called the Lake Package (LAK3) was developed to represent lake/aquifer interaction in numerical simulations using the U.S. Geological Survey three-dimensional, finite-difference, modular ground-water flow model MODFLOW and the U.S. Geological Survey three-dimensional method-of-characteristics solute-transport model MOC3D. In the Lake Package described in this report, a lake is represented as a volume of space within the model grid which consists of inactive cells extending downward from the upper surface of the grid. Active model grid cells bordering this space, representing the adjacent aquifer, exchange water with the lake at a rate determined by the relative heads and by conductances that are based on grid cell dimensions, hydraulic conductivities of the aquifer material, and user-specified leakance distributions that represent the resistance to flow through the material of the lakebed. Parts of the lake may become "dry" as upper layers of the model are dewatered, with a concomitant reduction in lake surface area, and may subsequently rewet when aquifer heads rise. An empirical approximation has been encoded to simulate the rewetting of a lake that becomes completely dry. The variations of lake stages are determined by independent water budgets computed for each lake in the model grid. This lake budget process makes the package a simulator of the response of lake stage to hydraulic stresses applied to the aquifer. Implementation of a lake water budget requires input of parameters including those representing the rate of lake atmospheric recharge and evaporation, overland runoff, and the rate of any direct withdrawal from, or augmentation of, the lake volume. The lake/aquifer interaction may be simulated in both transient and steady-state flow conditions, and the user may specify that lake stages be computed explicitly, semi-implicitly, or fully-implicitly in transient simulations. The lakes, and all sources of water entering the lakes, may have solute concentrations associated with them for use in solute-transport simulations using MOC3D. The Stream Package of MODFLOW-2000 and MOC3D represents stream connections to lakes, either as inflows or outflows. Because lakes with irregular bathymetry can exist as separate pools of water at lower stages, that coalesce to become a single body of water at higher stages, logic was added to the Lake Package to allow the representation of this process as a user option. If this option is selected, a system of linked pools (sublakes) is identified in each time step and stages are equalized based on current relative sublake surface areas.

Water-Resources Investigations Report↗
USGS2000

Reconnaissance of the hydrology, water quality, and sources of bacterial and nutrient contamination in the Ozark Plateaus aquifer system and Cave Springs Branch of Honey Creek, Delaware County, Oklahoma, March 1999-March 2000

A reconnaissance investigation of hydrology and water quality was conducted to evaluate possible sources of bacteria and nutrient contamination in the Cave Springs Branch basin and the underlying karstic Ozark Plateau aquifer system. Objectives were to: (1) determine the directions of ground-water flow in the basin and determine whether Cave Springs Branch interacts with ground water, (2) compare water quality in Cave Springs Branch with water quality in nearby wells to determine whether the stream is contaminating nearby wells, and (3) determine sources of fecal coliform bacteria and nitrate contamination in Cave Springs Branch and ground water. Potential sources of bacteria and nitrate in the area include cultivated agriculture, cow and horse on pasture, poultry production, households, and wildlife. Presence of fecal coliform and fecal streptococcal bacteria directly indicate fecal contamination and the potential for the presence of other pathogenic organisms in a water supply. Nitrate in drinking water poses health risks and may indicate the presence of additional contaminants. Fecal coliform bacteria colony counts were least in wells, intermediate in the poultry-processing plant wastewater outfall and Honey Creek above the confluence with Cave Springs Branch, and greatest in Cave Springs Branch. Bacteria strains and resistance to antibiotics by some bacteria indicate that livestock may have been sources of some bacteria in the water samples. Multiple antibiotic resistances were not present in the isolates from the water samples, indicating that the bacteria may not be from human or poultry sources. Ribotyping indicates that Escherichia coli bacteria in water samples from the basin were from bird, cow, horse, dog, deer, and human sources. The presence of multiple ribotypes from each type of animal source except bird indicates that most of the bacteria are from multiple populations of source animals. Identifiable sources of bacteria in Cave Springs Branch at the state line were dominantly cow and horse with one ribotype from bird. Escherichia coli was detected in only one well sample. Bacterial ribotypes in water from that upgradient well indicated human and dog feces as sources for bacteria, and that on site wastewater treatment may not always be adequate in these highly permeable soils. Greater concentrations of nitrate in Cave Springs Branch and O'Brien Spring relative to the poultry-processing plant wastewater outfall may be due, in part, to conversion of ammonia from poultry processing plant wastewater. The poultry-processing plant wastewater outfall sample collected in March 2000 contained greater concentrations of ammonia and total organic nitrogen plus ammonia than the spring, stream, and well samples collected during August 1999. Cave Springs Branch and Honey Creek contributed approximately equal loads of nitrogen to Honey Creek below the confluence and the greatest loads of nitrogen were introduced to Cave Springs Branch by the poultry processing plant wastewater outfall and O'Brien Spring. Nitrate concentrations in upgradient well samples ranged from 0.38 to 4.60 milligrams per liter, indicating that there are sources of ground-water nitrogen other than Cave Springs Branch, such as animal waste, fertilizer, or human waste. Nitrogen compounds in water from wells downgradient of Cave Springs Branch may be from Cave Springs Branch, fertilizers, animal waste, or human waste.

Oklahoma↗