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Geochemical constraints on adakites of different origins and copper mineralization

The petrogenesis of adakites holds important clues to the formation of the continental crust and copper ± gold porphyry mineralization. However, it remains highly debated as to whether adakites form by slab melting, by partial melting of the lower continental crust, or by fractional crystallization of normal arc magmas. Here, we show that to form adakitic signature, partial melting of a subducting oceanic slab would require high pressure at depths of >50 km, whereas partial melting of the lower continental crust would require the presence of plagioclase and thus shallower depths and additional water. These two types of adakites can be discriminated using geochemical indexes. Compiled data show that adakites from circum-Pacific regions, which have close affinity to subduction of young hot oceanic plate, can be clearly discriminated from adakites from the Dabie Mountains and the Tibetan Plateau, which have been attributed to partial melting of continental crust, in Sr/Y-versus-La/Yb diagram. Given that oceanic crust has copper concentrations about two times higher than those in the continental crust, whereas the high oxygen fugacity in the subduction environment promotes the release of copper during partial melting, slab melting provides the most efficient mechanism to concentrate copper and gold; slab melts would be more than two times greater in copper (and also gold) concentrations than lower continental crust melts and normal arc magmas. Thus, identification of slab melt adakites is important for predicting exploration targets for copper- and gold-porphyry ore deposits. This explains the close association of ridge subduction with large porphyry copper deposits because ridge subduction is the most favorable place for slab melting.

Dabie Mountains and the Tibetan Plateau↗

Characterization of clouds in Titan's tropical atmosphere

Images of Titan's clouds, possible over the past 10 years, indicate primarily discrete convective methane clouds near the south and north poles and an immense stratiform cloud, likely composed of ethane, around the north pole. Here we present spectral images from Cassini's Visual Mapping Infrared Spectrometer that reveal the increasing presence of clouds in Titan's tropical atmosphere. Radiative transfer analyses indicate similarities between summer polar and tropical methane clouds. Like their southern counterparts, tropical clouds consist of particles exceeding 5 ??m. They display discrete structures suggestive of convective cumuli. They prevail at a specific latitude band between 8??-20?? S, indicative of a circulation origin and the beginning of a circulation turnover. Yet, unlike the high latitude clouds that often reach 45 km altitude, these discrete tropical clouds, so far, remain capped to altitudes below 26 km. Such low convective clouds are consistent with the highly stable atmospheric conditions measured at the Huygens landing site. Their characteristics suggest that Titan's tropical atmosphere has a dry climate unlike the south polar atmosphere, and despite the numerous washes that carve the tropical landscape. ?? 2009. The American Astronomical Society.

Astrophysical Journal↗

The global seismographic network reveals atmospherically coupled normal modes excited by the 2022 Hunga Tonga eruption

The eruption of the submarine Hunga Tonga-Hunga Haʻapai (Hunga Tonga) volcano on 15 January 2022, was one of the largest volcanic explosions recorded by modern geophysical instrumentation. The eruption was notable for the broad range of atmospheric wave phenomena it generated and for their unusual coupling with the oceans and solid Earth. The event was recorded worldwide across the Global Seismographic Network (GSN) by seismometers, microbarographs and infrasound sensors. The broad-band instrumentation in the GSN allows us to make high fidelity observations of spheroidal solid Earth normal modes from this event at frequencies near 3.7 and 4.4 mHz. Similar normal mode excitations were reported following the 1991 Pinatubo (Volcanic Explosivity Index of 6) eruption and were predicted, by theory, to arise from the excitation of mesosphere-scale acoustic modes of the atmosphere coupling with the solid Earth. Here, we compare observations for the Hunga Tonga and Pinatubo eruptions and find that both strongly excited the solid Earth normal mode 0 S 29 (3.72 mHz). However, the mean modal amplitude was roughly 11 times larger for the 2022 Hunga Tonga eruption. Estimates of attenuation ( Q ) for 0 S 29 across the GSN from temporal modal decay give Q = 332 ± 101, which is higher than estimates of Q for this mode using earthquake data ( Q = 186.9 ± 5). Two microbarographs located at regional distances (<1000 km) to the volcano provide direct observations of the fundamental acoustic mode of the atmosphere. These pressure oscillations, first observed approximately 40 min after the onset of the eruption, are in phase with the seismic Rayleigh wave excitation and are recorded only by microbarographs in proximity (<1500 km) to the eruption. We infer that excitation of fundamental atmospheric modes occurs within a limited area close to the site of the eruption, where they excite select solid Earth fundamental spheroidal modes of similar frequencies that are globally recorded and have a higher apparent Q due to the extended duration of atmospheric oscillations.

Geophysical Journal International↗

KG²B, a collaborative benchmarking exercise for estimating the permeability of the Grimsel granodiorite - Part 2: modeling, microstructures and complementary data

Measuring and modelling the permeability of tight rocks remains a challenging task. In addition to the traditional sources of errors that affect more permeable formations (e.g. sample selection, non-representative specimens, disturbance introduced during sample acquisition and preparation), tight rocks can be particularly prone to solid–fluid interactions and thus more sensitive to the methods, procedures and techniques used to measure permeability. To address this problem, it is desirable to collect, for a single material, measurements obtained by different methods and pore fluids. For that purpose, a benchmarking exercise involving 24 laboratories was organized for measuring and modelling the permeability of a single low-permeability material, the Grimsel granodiorite. The objectives of the benchmark were: (i) to compare the results for a given method, (ii) to compare the results between different methods, (iii) to analyse the accuracy of each method, (iv) to study the influence of experimental conditions (especially the nature of pore fluid), (v) to discuss the relevance of indirect methods and models and finally (vi) to suggest good practice for low-permeability measurements. To complement the data set of permeability measurements presented in a companion paper, we focus here on (i) quantitative analysis of microstructures and pore size distribution, (ii) permeability modelling and (iii) complementary measurements of permeability anisotropy and poroelastic parameters. Broad ion beam—scanning electron microscopy, micro-computerized tomography, mercury injection capillary pressure (MICP) and nuclear magnetic resonance (NMR) methods were used to characterize the microstructures and provided the input parameters for permeability modelling. Several models were used: (i) basic statistical models, (ii) 3-D pore network and effective medium models, (iii) percolation model using MICP data and (iv) free-fluid model using NMR data. The models were generally successful in predicting the actual range of measured permeability. Statistical models overestimate the permeability because they do not adequately account for the heterogeneity of the crack network. Pore network and effective medium models provide additional constraints on crack parameters such as aspect ratio, aperture, density and connectivity. MICP and advanced microscopy techniques are very useful tools providing important input data for permeability estimation. Permeability measured—orthogonal to foliation is lower that—parallel to foliation. Combining the experimental and modelling results provide a unique and rich data set.

Geophysical Journal International↗

Non-lethal detection of Renibacterium salmoninarum in Greenback Cutthroat Trout Oncorhynchus clarkii stomias comparing mucus, blood, and ovarian fluid samples to kidney tissues

Objective Renibacterium salmoninarum , the causative agent of bacterial kidney disease, poses a major threat to both wild and aquaculture salmonid populations. Traditional detection methods typically involve lethal sampling to collect kidney tissues but are often impractical for species of conservation concern. This study evaluates nonlethal sampling techniques for detecting R. salmoninarum in Greenback Cutthroat Trout Oncorhynchus clarkii stomias by comparing mucus, blood, and ovarian fluid samples to conventional kidney tissue. Methods During the 2019 spawning season, we collected samples from 781 adult fish and tested for R. salmoninarum via direct fluorescent antibody test (DFAT) and quantitative polymerase chain reaction (qPCR). Results A total of 25 and 256 kidney tissues were positive by DFAT and qPCR, respectively. Of the three nonlethal samples tested, mucus swabs showed the highest percent correlation for detection with positive kidney tissues (DFAT = 47.6%, qPCR = 41.7%). Blood and ovarian fluid samples showed a lower percent correlation with positive kidney tissues (blood: DFAT = 12.0%, qPCR = 1.2%; ovarian fluid: DFAT = 12.5%, qPCR = 21.4%). Conclusions Our results suggest that nonlethal mucus swabbing could serve as a practical alternative for monitoring R. salmoninarum, especially in conservation efforts where minimizing fish mortality is critical.

Colorado↗

Determination of benzocaine in rainbow trout plasma

A liquid chromatographic method is described for analysis of benzocaine (BZ), a proposed fish anesthetic, in rainbow trout plasma. Mean recoveries of BZ from plasma samples fortified at 44–10 100 ng/mL were 96–100%. The method detection limit is 10 ng/mL, and the limit of quantitation is 37 ng/mL. Acetylation of BZ occurs in whole blood after storage at room temperature (i.e., 21 °C) for 10 min. However, no acetylation of BZ was detected in plasma samples held at room temperature for 4 h. Mean method precision for plasma samples with incurred BZ residue is similar to that for fortified samples in the same concentration range (relative standard deviations of 0.9 and 1.2%, respectively).

Journal of AOAC International↗

Variation in migratory behavior influences regional genetic diversity and structure among American kestrel populations (Falco sparverius) in North America

Birds employ numerous strategies to cope with seasonal fluctuations in high-quality habitat availability. Long distance migration is a common tactic; however, partial migration is especially common among broadly distributed species. Under partial migration systems, a portion of a species migrates, whereas the remainder inhabits breeding grounds year round. In this study, we identified effects of migratory behavior variation on genetic structure and diversity of American Kestrels (Falco sparverius), a widespread partial migrant in North America. American Kestrels generally migrate; however, a resident group inhabits the southeastern United States year round. The southeastern group is designated as a separate subspecies (F. s. paulus) from the migratory group (F. s. sparverius). Using mitochondrial DNA and microsatellites from 183 and 211 individuals, respectively, we illustrate that genetic structure is stronger among nonmigratory populations, with differentiation measures ranging from 0.060 to 0.189 depending on genetic marker and analysis approach. In contrast, measures from western North American populations ranged from 0 to 0.032. These findings suggest that seasonal migratory behavior is also associated with natal and breeding dispersal tendencies. We likewise detected significantly lower genetic diversity within nonmigratory populations, reflecting the greater influence of genetic drift in small populations. We identified the signal of population expansion among nonmigratory populations, consistent with the recent establishment of higher latitude breeding locations following Pleistocene glacial retreat. Differentiation of F. s. paulus and F. s. sparverius reflected subtle differences in allele frequencies. Because migratory behavior can evolve quickly, our analyses suggest recent origins of migratory American Kestrel populations in North America.

Journal of Heredity↗

Hibernation behavior of a federally-threatened ground squirrel: Climate change and habitat selection implications

Hibernation is an adaptation to survive periods of stress, from food limitation or harsh thermal conditions. A key question in contemporary ecology is whether rare, range-restricted species can change their behavior in response to climate change (i.e., through behavioral plasticity). The northern Idaho ground squirrel, Urocitellus brunneus (A. H. Howell, 1928), is a federally threatened species that hibernates for approximately 8 months per year within the bounds of its small range in central Idaho, USA. Changes in temperature, snow accumulation, and summer precipitation, all brought about as a result of climate change, may reduce survival or fecundity of northern Idaho ground squirrels if they cannot adapt to these climate changes. Hibernating species can respond to climate-change-induced thermal challenges in two ways: change their hibernation physiology and behavior (i.e., emergence date or number of torpor bouts) or alter their environment (i.e., change hibernacula depth or location). We explored a suite of intrinsic and extrinsic factors to document the extent to which they influenced hibernation behavior of northern Idaho ground squirrels. Emergence date was positively associated with snowpack and negatively associated with mean winter temperature. Mean minimum skin temperature was negatively associated with canopy closure and slope of a squirrel’s hibernaculum. Duration of the heterothermal period, number of euthermic bouts, and total time spent euthermic were positively associated with body mass. Immergence date and duration of the longest torpor bout were negatively associated with body mass. Warmer temperatures and less snow accumulation in the winter—caused by climate change—likely will cause altered emergence dates. Our results suggest that any future climate-induced changes in snowfall, ambient temperature, food availability, or habitat likely will impact survival of this rare ground squirrel, because such changes will cause changes in hibernation behavior, percent mass loss during hibernation, and duration of the active season when small mammals are more susceptible to predation.

Idaho↗

Population density influences dispersal in female white-tailed deer

Dispersal behavior in white-tailed deer ( Odocoileus virginianus ) predominantly occurs in 1-year-old males; however, females of the same age also disperse. The timing of female dispersal during fawning season and low dispersal rates suggest that competition for mates and reduced inbreeding are not ultimate causes of female dispersal, as suggested for males. We proposed that female dispersal is the result of competition for space when pregnant females seek to isolate themselves before and after parturition. To test this hypothesis, we conducted a meta-analysis of female dispersal rates from 12 populations of white-tailed deer and predicted dispersal rate and distance were positively related to deer density. We found a positive relationship between dispersal rate and deer per forested km 2 and between dispersal distance and deer per forested km 2 . These results are consistent with the hypothesis that female dispersal is density-dependent and caused by the exclusion of subordinate 1-year-olds as adult females seek isolation before and after parturition.

Journal of Mammalogy↗

Calcium and phosphorus requirements of breeding bobwhite quail

In the course of studies designed to determine the calcium and phosphorus requirements of breeding bobwhite quail, it was found that best results were obtained when the Ca/P ratio in the diet was approximately 2.3:1. Variations in the Ca/P ratio produced significant differences in results when the level of phosphorus in the diet was 0.75%, but the differences were less marked when the level of phosphorus was increased to 1.00%. Although diets containing 0.75% phosphorus and 1.8% calcium appeared adequate for reproduction, as judged by the criteria of the maintenance of satisfactory condition in the breeders, egg production, fertility, hatchability and survival of offspring during the first 5 days after hatching, it was found that the winter mortality of the offspring of birds fed such a diet was much greater than that occurring in the offspring of birds fed on diets containing 1.00 or 1.25% phosphorus. It is concluded that breeding bobwhite quail require diets furnishing approximately 1.00% phosphorus and 2.3% calcium.

Journal of Nutrition↗

Attitudes and intentions of off-highway vehicle riders toward trail use: Implications for forest managers

Management of off-highway vehicles (OHV) in public forest areas requires up-to-date information about the attitudes and intentions of OHV riders toward trail use. A survey of 811 members of the New England Trail Riders Association was conducted in fall 2007; 380 questionnaires were completed and returned. Descriptive statistics and regressions were used to identify relationships between OHV rider attitudes, management preferences, and intentions toward two trail use–related behaviors (i.e., illegal use of trails by OHVs and the creation and/or use of unauthorized trails by OHV riders). Results reveal that the average responding association member has a negative attitude toward the two depreciative behaviors, intends to ride OHVs legally, and slightly prefers indirect over direct forms of management. Significant relationships between intentions and both attitudes and management preferences are identified. Policy and management implications and strategies are discussed.

Journal of Forestry↗

Patterns of genetic differentiation and conservation of the slabside pearlymussel, Lexingtonia dolabelloides (Lea, 1840) in the Tennessee River drainage

The restoration and recovery of imperiled mussel species will require the re-establishment of populations into historically occupied habitats. The possible existence of genetic differentiation among populations should be considered before inter-basin transfers are made. Eighty individuals of the federal candidate species Lexingtonia dolabelloides were sampled from populations in the North Fork Holston, Middle Fork Holston, Clinch, Paint Rock and Duck rivers of the Tennessee River basin in the southeastern United States. We sequenced 603 base-pairs of a mitochondrial DNA gene (ND-1) and 512 base-pairs of a nuclear DNA gene (ITS-1). Analyses of molecular variation (AMOVA) values for both genes indicated that the majority of variation in L. dolabelloides resided within populations (82.9-88.3%), with 11.7-17.1% of variation among populations. Haplotype frequencies differed significantly among populations for both genes sequenced. Clustering of haplotypes in minimum-spanning networks did not conform stringently to population boundaries, reflecting high within-population and low between-population variability. Maximum parsimony analysis did not identify any population as a monophyletic lineage. A Mantel test showed no significant correlation between geographical stream distance and genetic distance, thus not supporting a pattern of isolation-by-distance. Overall, results provided support to manage fragmented populations of L. dolabelloides in the Tennessee River drainage as two management units (MUs), but did not provide evidence for the existence of ESUs following published molecular criteria. ?? The Author 2005. Published by Oxford University Studies on behalf of The Malacological Society of London, all rights reserved.

Journal of Molluscan Studies↗

Coexisting amphiboles from blueschist facies metamorphic rocks

Four pairs of associated calcic and sodic amphiboles from blueschist facies metamorphic rocks were analyzed with the electron microprobe and studied by single-crystal X-ray diffraction techniques. Except for ranges in the ratios Mg/(Mg+Fe) and Fe 3+ /(Fe 3+ +Al+Ti), the sodic amphiboles are similar in chemical composition. The amount of calcium in the M(4)-site ranges only from 0·18 to 0·21 ion per formula unit. The calcic amphiboles, in addition to a range in Mg/(Mg+Fe), vary in Na/(Na+Ca) ratio (0·29–0·48). Three of the calcic amphiboles contain less than 1·5 calcium ions per formula unit, indicating a significant solid solution of sodic amphibole components in the calcic amphibole phase. The a and b unit-cell parameters of the calcic amphiboles decrease with increased content of the sodic component.

Journal of Petrology↗

Petrogenetic evolution of the torfajökull volcanic complex, Iceland I. relationship between the magma types

The Torfajökull volcano, Iceland's largest silicic centre, is situated close to the junction of the active, southerly propagating Eastern Rift Zone and the South Eastern Zone, an older crustal segment. This paper provides major, trace, and some Sr isotope data on postglacial (<10000 y) rocks, i.e., tholeiitic magmas of the Eastern Rift Zone and transitional basalts, icelandites, and rhyolites of the Torfajökull centre, and assesses the relationships between the magma types in terms of the development of the Icelandic crust.Tholeiitic magmas from the Eastern Rift Zone are LILE-enriched relative to MORB. They have undergone extensive olivine-plagioclase-clinopyroxene fractionation at low pressures. Compared with the tholeiites, Torfajökull transitional basalts show LILE/HFS enrichment and higher ( 87 Sr/ 86 Sr) 1 ratios. They define several magmatic lineages and have equilibrated over a wide range of pressures. Both basalt types were derived by very small degrees of partial melting of compositionally similar mantle sources, the main difference being that the tholeiites were generated in the spinel Iherzolite, and the transitional basalts in the garnet lherzolite, stability fields, a conclusion previously reached by Meyer et al. (1985). The mantle sources may have contained LILE-enriched streaks.Low-pressure differentiation of Torfajökull transitional basalt produced an iceiandite to sub-alkaline rhyolite sequence by crystal fractionation, the rhyolites representing >90% crystallization of parental basalts. The rhyolites were emplaced as nine separate lava fields, formed during 11 eruptive episodes. The compositional range within each field is limited, and, although similar, the ranges define several magmatic lineages. Continued fractionation of plagioclase-alkali feldspar-clinopyroxene-magnetite-apatite-zircon assemblages generated peralkaline rhyolites in certain post-glacial eruptions. Chemical variations in the deposits from the Hrafntinnusker peralkaline eruption were related predominantly to alkali feldspar fractionation, and the melts were erupted from a zoned magma chamber. All postglacial volcanic rocks at Torfajokull have been mantle derived and thus represent new additions to the Icelandic crust. © 1990 Oxford University Press.

Journal of Petrology↗

Properties of synthetic triclinic KFeSi3O8, iron-microcline, with some observations on the iron-microcline⇌iron-sanidine transition

Triclinic KFeSi 3 O 8 , iron-microcline, has been synthesized from oxide mixes and by complete conversion of monoclinic KFeSi 3 O 8 , iron-sanidine. Iron-microcline is triclinic, C ī, a =8·68±0·01 Å, b =13·10±0·01, c =7·34±0·01, α =90° 45′±10′, β =116° 03′±10′, γ=86°14′±10′. The optical properties (Na light) are: α =1·585±0·002, β =1·596±0·002, γ=1·605±0·002, 2 V α =85° (calc.), X≈ b , Z ∧ c =20°±5°. A reversible phase transition between triclinic and monoclinic KFeSi 3 O 8 occurs at 704°±6° C at 2000 bars total pressure. Iron-microcline is the low-temperature polymorph; no intermediate polymorphs were observed in either hydrothermal or dry heating experiments.

Journal of Petrology↗

Garnet granulite xenoliths from the Northern Baltic shield: The underplated lower crust of a palaeoproterozoic large igneous province

Garnet granulite facies xenoliths hosted in Devonian lamprophyres from the Kola Peninsula are interpreted to represent the high-grade metamorphic equivalents of continental flood tholeiites, emplaced into the Baltic Shield Archaean lower crust in early Proterozoic time. Geochronological data and similarities in major and trace element geochemistry suggest that the xenoliths formed during the same plume-related magmatic event that created a widespread Palaeoproterozoic large igneous province (LIP) at 2·4–2·5 Ga. They are, thus, the first samples of the lower crust of a Palaeoproterozoic LIP to be studied in petrological detail. The suite includes mafic granulites (gar + cpx + rutile ± plag ± opx ± phlog ± amph), felsic granulites (plag + gar + cpx + rutile ± qtz ± Kspar ± phlog ± amph) and pyroxenites (± phlog ± amph), but mafic garnet granulites predominate. Although some samples are restites, there is no evidence for a predominance of magmatic cumulates, as is common for Phanerozoic lower-crustal xenolith suites. Metasediments are also absent. Phlogopite and/or amphibole occur in xenoliths of all types and are interpreted to be metasomatic in origin. The K-rich metasomatic event occurred at ∼2·0 Ga, and led to substantial enrichment in Rb, K, LREE/HREE, Th/U, Th/Pb and, to a lesser extent, Nb and Ti. The fluids responsible for this metasomatism were probably derived from a second plume that arrived beneath the region at this time. Evidence for partial melting of mafic crust exists in the presence of migmatitic granulites. The timing of migmatization overlaps that of metasomatism, and it is suggested that migmatization was facilitated by the metasomatism. The metamorphism, metasomatism and migmatization recorded in the Kola granulite xenoliths may be representative of the processes responsible for converting Archaean LIP-generated proto-continents into continental crust.

Elovy Island, Kandalaksha Gulf, Kola Peninsula, Wh↗

Evaluation of a Mysis bioenergetics model

Direct approaches for estimating the feeding rate of the opossum shrimp Mysis relicta can be hampered by variable gut residence time (evacuation rate models) and non-linear functional responses (clearance rate models). Bioenergetics modeling provides an alternative method, but the reliability of this approach needs to be evaluated using independent measures of growth and food consumption. In this study, we measured growth and food consumption for M. relicta and compared experimental results with those predicted from a Mysis bioenergetics model. For Mysis reared at 10°C, model predictions were not significantly different from observed values. Moreover, decomposition of mean square error indicated that 70% of the variation between model predictions and observed values was attributable to random error. On average, model predictions were within 12% of observed values. A sensitivity analysis revealed that Mysis respiration and prey energy density were the most sensitive parameters affecting model output. By accounting for uncertainty (95% CLs) in Mysis respiration, we observed a significant improvement in the accuracy of model output (within 5% of observed values), illustrating the importance of sensitive input parameters for model performance. These findings help corroborate the Mysis bioenergetics model and demonstrate the usefulness of this approach for estimating Mysis feeding rate.

Journal of Plankton Research↗

Sulfurospirillum barnesii sp. nov. and Sulfurospirillum arsenophilum sp. nov., new members of the Sulfurospirillum clade of the ε-Proteobacteria

Two strains of dissimilatory arsenate-reducing vibrio-shaped bacteria are assigned to the genus Sulfurospirillum. These two new species, Sulfurospirillum barnesii strain SES-3(T) and Sulfurospirillum arsenophilum strain MIT-13(T), in addition to Sulfurospirillum sp. SM-5, two strains of Sulfurospirillum deleyianum, and Sulfurospirillum arcachonense, form a distinct clade within the ?? subclass of the Proteobacteria based on 16S rRNA analysis.

International Journal of Systematic Bacteriology↗