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Three-dimensional hydrogeologic framework model of the Rio Grande transboundary region of New Mexico and Texas, USA, and northern Chihuahua, Mexico

As part of a U.S. Geological Survey study in cooperation with the Bureau of Reclamation, a digital three-dimensional hydrogeologic framework model was constructed for the Rio Grande transboundary region of New Mexico and Texas, USA, and northern Chihuahua, Mexico. This model was constructed to define the aquifer system geometry and subsurface lithologic characteristics and distribution for use in a regional numerical hydrologic model. The model includes five hydrostratigraphic units: river channel alluvium, three informal subdivisions of Santa Fe Group basin fill, and an undivided pre-Santa Fe Group bedrock unit. Model input data were compiled from published cross sections, well data, structure contour maps, selected geophysical data, and contiguous compilations of surficial geology and structural features in the study area. These data were used to construct faulted surfaces that represent the upper and lower subsurface hydrostratigraphic unit boundaries. The digital three-dimensional hydrogeologic framework model is constructed through combining faults, the elevation of the tops of each hydrostratigraphic unit, and boundary lines depicting the subsurface extent of each hydrostratigraphic unit. The framework also compiles a digital representation of the distribution of sedimentary facies within each hydrostratigraphic unit. The digital three-dimensional hydrogeologic model reproduces with reasonable accuracy the previously published subsurface hydrogeologic conceptualization of the aquifer system and represents the large-scale geometry of the subsurface aquifers. The model is at a scale and resolution appropriate for use as the foundation for a numerical hydrologic model of the study area.

Chihuahua, New Mexico, Texas↗

Geology and K-Ar geochronology of the Paradise Peak Mine and the relationship of pre-Basin and Range extension to Early Miocene precious metal mineralization in west-central Nevada

The Paradise Peak mine is a major gold-silver-mercury deposit located in the southwestern part of the Paradise Range near the eastern edge of the Walker Lane in the western Great Basin, Nevada. The Tertiary volcanic rocks of the area can be divided into a sequence of 26- to 24-Ma intermediate lavas, a sequence of 24- to 22-Ma silicic ash-flow tuffs, and a sequence of 20- to 15-Ma intermediate lavas. We classify these rocks as the older, middle, and younger sequences. Sedimentary rocks, and latites and basalts 12 Ma old or younger, locally overlie the younger intermediate lavas south of the mine. Silicified rhyolite tuff in the lower part of the middle tuff sequence is the principal host of the precious metal ore. Most ore occurs under an acid-leached zone of alunitic alteration and is contained in hydrothermal breccias that crosscut early quartz-pyrite and alunite alteration.Field relations and K-Ar ages of hypogene alunite indicate that precious metal mineralization and alunitic and silicic alteration formed at about 19 to 18 Ma, several million years after eruption of the main host rock. Mineralization formed during high-angle faulting related to crustal extension. Low-angle normal faults are present 5 km northeast of the Paradise Peak mine, but they formed more than 2 Ma after formation of the Paradise Peak deposit. Silicic and alunitic alteration and precious metal mineralization are generally absent in areas of low-angle faulting.Regional stratigraphic relations and K-Ar ages indicate that volcanism changed from silicic ash-flow tuffs to intermediate lavas at about 20 to 19 Ma. Regionally extensive angular unconformities indicate that a period of "pre-Basin and Range" crustal extension occurred between about 22 to 19 Ma. This extension was penecontemporaneous with the shift in the style of volcanism and with gold-silver mineralization in the Paradise Peak mine and in the Goldfield and Tonopah districts of western Nevada. The close temporal and spatial relationships of precious metal mineralization with pre-Basin and Range extension suggest that extension was a major factor in the genesis of early Miocene precious metal deposits in the western Great Basin.

Economic Geology↗

Active metamorphism of upper Cenozoic sediments in the Salton Sea geothermal field and the Salton Trough, southeastern California

The Salton Sea geothermal system is entirely within Pliocene and Quaternary sediments of the Colorado River delta at the north end of the Gulf of California. At the time of deposition, these sediments consisted of sands, silts, and clays of uniform original mineralogic composition, but under the elevated temperatures and pressures of the geothermal system they are being transformed to low-grade metamorphic rocks of the greenschist facies. We have studied these transformations by X-ray, petrographic, and chemical analyses of cuttings and core from deep wells that penetrate the sedimentary section. Temperatures within the explored geothermal system range up to 360° C at 7100 feet. The wells produce a brine containing over 250,000 ppm dissolved solids, primarily Cl, Na, Ca, K, and Fe, plus a host of minor constituents.

California↗

Possible evidence for subducted sedimentary materials beneath central California

Seismic reflection and refraction data from the Coast Ranges of central California west of the San Andreas fault suggest the presence of a low-velocity (4.5–5.0 km/s) wedge at a depth of about 15–22 km that dips east beneath rocks of both the Franciscan assemblage and the Salinian block. We propose that the wedge represents sedimentary materials that were subducted in an offshore trench within the past 23 m.y. The refraction data also suggest the presence of a second low-velocity zone that extends at least to mid-crustal depths beneath the San Andreas fault zone.

Geology↗

Meteoroid mayhem in Ole Virginny: Source of the North American tektite strewn field

New seismic reflection data from Chesapeake Bay reveal a buried, 85-km-wide, 1.5-2.0-km-deep, peak-ring impact crater, carved through upper Eocene to Lower Cretaceous sedimentary strata and into underlying pre-Mesozoic crystalline basement rocks. A polymictic, late Eocene impact breccia, composed mainly of locally derived sedimentary debris (determined from four continuous cores), surrounds and partly fills the crater. Structural and sedimentary characteristics of the Chesapeake Bay crater closely resemble those of the Miocene Ries peakring crater in southern Germany. We speculate that the Chesapeake Bay crater is the source of the North American tektite strewn field.

Geology↗

Hydrothermal, biogenic, and seawater components in metalliferous black shales of the Brooks Range, Alaska: Synsedimentary metal enrichment in a carbonate ramp setting

Trace element and Os isotope data for Lisburne Group metalliferous black shales of Middle Mississippian (early Chesterian) age in the Brooks Range of northern Alaska suggest that metals were sourced chiefly from local seawater (including biogenic detritus) but also from externally derived hydrothermal fluids. These black shales are interbedded with phosphorites and limestones in sequences 3 to 35 m thick; deposition occurred mainly on a carbonate ramp during intermittent upwelling under varying redox conditions, from suboxic to anoxic to sulfidic. Deposition of the black shales at ~335 Ma was broadly contemporaneous with sulfide mineralization in the Red Dog and Drenchwater Zn-Pb-Ag deposits, which formed in a distal marginal basin. Relative to the composition of average black shale, the metalliferous black shales ( n = 29) display large average enrichment factors (>10) for Zn (10.1), Cd (11.0), and Ag (20.1). Small enrichments (>2–<10) are shown by V, Cr, Ni, Cu, Mo, Pd, Pt, U, Se, Y, and all rare earth elements except Ce, Nd, and Sm. A detailed stratigraphic profile over 23 m in the Skimo Creek area (central Brooks Range) indicates that samples from at and near the top of the section, which accumulated during a period of major upwelling and is broadly correlative with the stratigraphic levels of the Red Dog and Drenchwater Zn-Pb-Ag deposits, have the highest Zn/TOC (total organic carbon), Cu/TOC, and Tl/TOC ratios for calculated marine fractions (no detrital component) of these three metals. Average authigenic (detrital-free) contents of Mo, V, U, Ni, Cu, Cd, Pb, Ge, Re, Se, As, Sb, Tl, Pd, and Au show enrichment factors of 4.3 × 10 3 to 1.2 × 10 6 relative to modern seawater. Such moderate enrichments, which are common in other metalliferous black shales, suggest wholly marine sources (seawater and biogenic material) for these metals, given similar trends for enrichment factors in organic-rich sediments of modern upwelling zones on the Namibian, Peruvian, and Chilean shelves. The largest enrichment factors for Zn and Ag are much higher (1.4 × 10 7 and 2.9 × 10 7 , respectively), consistent with an appreciable hydrothermal component. Other metals such as Cu, Pb, and Tl that are concentrated in several black shale samples, and are locally abundant in the Red Dog and Drenchwater Zn-Pb-Ag deposits, may have a partly hydrothermal origin but this cannot be fully established with the available data. Enrichments in Cr (up to 7.8 × 10 6 ) are attributed to marine and not hydrothermal processes. The presence in some samples of large enrichments in Eu (up to 6.1 × 10 7 ) relative to modern seawater and of small positive Eu anomalies (Eu/Eu* up to 1.12) are considered unrelated to hydrothermal activity, instead being linked to early diagenetic processes within sulfidic pore fluids. Initial Os isotope ratios ( 187 Os/ 188 Os) calculated for a paleontologically based depositional age of 335 Ma reveal moderately unradiogenic values of 0.24 to 0.88 for four samples of metalliferous black shale. A proxy for the ratio of coeval early Chesterian seawater is provided by initial ( 187 Os/ 188 Os) 335 Ma ratios of four unaltered black shales of the coeval Kuna Formation that average 1.08, nearly identical to the initial ratio of 1.06 for modern seawater. Evaluation of possible sources of unradiogenic Os in the metalliferous black shales suggests that the most likely source was mafic igneous rocks that were leached by externally derived hydrothermal fluids. This unradiogenic Os is interpreted to have been leached by deeply circulating hydrothermal fluids in the Kuna basin, followed by venting of the fluids into overlying seawater. We propose that metal-bearing hydrothermal fluids that formed Zn-Pb-Ag deposits such as Red Dog or Drenchwater vented into seawater in a marginal basin, were carried by upwelling currents onto the margins of a shallow-water carbonate platform, and were then deposited in organic-rich muds, together with seawater- and biogenically derived components, by syngenetic sedimentary processes. Metal concentration in the black shales was promoted by high biologic productivity, sorption onto organic matter, diffusion across redox boundaries, a low sedimentation rate, and availability of H 2 S in bottom waters and pore fluids.

Alaska↗

Uranium in secondary silica: A possible exploration guide

Study of uraniferous silica precipitates in the Shirley Basin, Wyoming, identified areas where ancient uraniferous ground water once ponded. Chalcedony collected from and directly beneath thick accumulations of rhyolite ash contain as much as 250 ppm uranium in a pre-ash topographic low and lesser concentrations (10 to 160 ppm) elsewhere. Differences in the U concentration of chalcedony collected from approximately the same stratigraphic horizon reflect the enrichment of uranium in ground water as it percolated downward and basinward through the overlying rhyolite ash. Uranium is homogeneously distributed as a uranyl species within the chalcedony and reflects coprecipitation of dissolved uranium and colloidal silica in a uraniferous silica-gel. Laboratory measurements of the partitioning of uranium between various solutions and silica-gel precipitates indicate that, for ranges of pH and dissolved carbonate typical of ground water, dried silica-gel contains about 400 to 1,000 times the uranium concentration of the solution from which it forms. Uranium is postulated to be incorporated as an adsorbed uranyl-silica-hydroxyl complex. A 20-m.y.-minimum apparent age for uraniferous chalcedony was obtained by U-Pb isotope dating. Reported minimum ages for nearby sedimentary uranium deposits generally lie between this age and the age of rhyolite which hosts the silica (32.4 + or - 2.6 m.y.). Leaching of uranium from ash during the period 20 to 32 m.y. is therefore compatible with a volcanic source-rock hypothesis.

Wyoming↗

Sulfur and lead isotope studies of stratiform Zn-Pb-Ag deposits, Anvil Range, Yukon: Basinal brine exhalation and anoxic bottom-water mixing (Canada)

Five stratiform Zn-Pb-Ag deposits are known in Early Cambrian metapelitic rocks along a curvilinear trend in the Anvil Range, central Yukon. The Anvil Range deposits occur along the southwestern boundary of the Selwyn basin in the stratigraphic transition zone between metapelites of the Mt. Mye unit and calcareous phyllites of the overlying Vangorda unit. The massive sulfides are associated closely with anomalously thick graphitic phyllites, apparently related to a second-order basin. A typical Anvil cycle of mineralization begins with a ribbon-banded graphitic-quartzitic-pyritic unit. This grades upward into sulfide-bearing quartzite, quartzitic massive sulfide, massive sulfide, and finally a baritic massive sulfide horizon. Sericitic alteration envelopes irregularly encompass each deposit and locally are developed best in footwall rocks. Detailed sulfur isotope studies have been carried out on the DY and Grum deposits and on one representative drill hole from the Faro deposit. The delta 34 S values of sulfide minerals generally range from 10 to 22 per mil and are similar in all three deposits. The delta 34 S values of pyrite in unmineralized samples from the district exhibit a wider range, from 6 to 34 per mil, and show distinct upward stratigraphic increase due to a stagnation cycle in the basin. The delta 34 S values of barite samples are strongly dependent on bottom-water conditions and mode of mixing during brine exhalation. They range from 22 to 26 per mil in the Faro deposit to 36 to 42 per mil in the DY deposit. These variations are due to mixing of isotopically light sulfate (18-20ppm) in Ba-bearing ore fluid and isotopically heavy residual sulfate (30-60ppm) in anoxic seawater. Thirty-eight samples of galena from the DY, Grum, Faro, SB, and Swim deposits have been analyzed for lead isotope ratios. In general, the lead isotope ratio data indicate an upper crustal lead source, with the Proterozoic Grit unit which is inferred to underlie the district being the most likely source rock. A small component of mantle leads from mafic igneous rocks or due to source rock inhomogeneity is also indicated. Graphitic host lithologies, lack of stratiform iron oxides, delta 34 S values of sedimentary pyrite, and sulfide sulfur-organic carbon variations in unmineralized cores indicate formation of the Anvil deposits in strongly reduced bottom water related to a previously unknown Early Cambrian anoxic event.

Economic Geology↗

Geology of Devils Tower National Monument, Wyoming

Devils Tower is a steep-sided mass of igneous rock that rises above the surrounding hills and the valley of the Belle Fourche River in Crook County, Wyo. It is composed of a crystalline rock, classified as phonolite porphyry, that when fresh is gray but which weathers to green or brown. Vertical joints divide the rock mass into polygonal columns that extend from just above the base to the top of the Tower. The hills in the vicinity and at the base of the Tower are composed of red, yellow, green, or gray sedimentary rocks that consist of sandstone, shale, or gypsum. These rocks, in aggregate about 400 feet thick, include, from oldest to youngest, the upper part of the Spearfish formation, of Triassic age, the Gypsum Spring formation, of Middle Jurassic age, and the Sundance formation, of Late Jurassic age. The Sundance formation consists of the Stockade Beaver shale member, the Hulett sandstone member, the Lak member, and the Redwater shale member. The formations have been only slightly deformed by faulting and folding. Within 2,000 to 3.000 feet of the Tower, the strata for the most part dip at 3 deg - 5 deg towards the Tower. Beyond this distance, they dip at 2 deg - 5 deg from the Tower. The Tower is believed to have been formed by the intrusion of magma into the sedimentary rocks, and the shape of the igneous mass formed by the cooled magma is believed to have been essentially the same as the Tower today. Devils Tower owes its impressiveness to its resistance to erosion as compared with the surrounding sedimentary rocks, and to the contrast of the somber color of the igneous column to the brightly colored bands of sedimentary rocks.

Bulletin↗

Results of diamond drilling and geologic investigation of the Shirley May (Garo) uranium deposit, Park County, Colorado

The Shirley May (Garo) uranium deposit near Garo, Park County, Colo., consists of tyuyamunite and carnotite that occur as disseminations and as fracture fillings in three beds of medium- to coarse-grained sandstone. The sandstones are in the Maroon formation of Permian age. This deposit was explored by means of 12 core-drill holes, totalling 2,003 feet. The deposit is on the northeast flank of the Garo anticline, a local structure that probably is related to Tertiary tectonic movement. In the vicinity of the deposit the sedimentary rocks strike northwest and dip steeply. They are cut by numerous northerly-trending faults that have horizontal displacements of as much as 1,000 feet. The ore minerals tyuyamunite, carnotite, volborthite, calciovolborthite, malachite, azurite, chalcocite(?) , and an unidentified yellow to dark-red vanadium oxide are restricted to a complexly faulted area. The ore body that has yielded most of the uranium ore is in the uppermost ore-bearing sandstone (bed no. 1) and is stratigraphically 50 and 150 feet above the ore horizons in sandstones nos. 2 and 3, respectively. The uranium content of samples from the mine workings ranges from 0. 001 to 0. 48 percent uranium; dump samples contain as much as 2.39 percent uranium. A total of 40 tons of uranium ore, averaging 1.0 percent uranium, was produced in 1919.

Colorado↗

Petroleum geology and resources of the North Caspian Basin, Kazakhstan and Russia

The North Caspian basin is a petroleum-rich but lightly explored basin located in Kazakhstan and Russia. It occupies the shallow northern portion of the Caspian Sea and a large plain to the north of the sea between the Volga and Ural Rivers and farther east to the Mugodzhary Highland, which is the southern continuation of the Ural foldbelt. The basin is bounded by the Paleozoic carbonate platform of the Volga-Ural province to the north and west and by the Ural, South Emba, and Karpinsky Hercynian foldbelts to the east and south. The basin was originated by pre-Late Devonian rifting and subsequent spreading that opened the oceanic crust, but the precise time of these tectonic events is not known. The sedimentary succession of the basin is more than 20 km thick in the central areas. The drilled Upper Devonian to Tertiary part of this succession includes a prominent thick Kungurian (uppermost Lower Permian) salt formation that separates strata into the subsalt and suprasalt sequences and played an important role in the formation of oil and gas fields. Shallow-shelf carbonate formations that contain various reefs and alternate with clastic wedges compose the subsalt sequence on the 1 basin margins. Basinward, these rocks grade into deep-water anoxic black shales and turbidites. The Kungurian salt formation is strongly deformed into domes and intervening depressions. The most active halokinesis occurred during Late Permian?Triassic time, but growth of salt domes continued later and some of them are exposed on the present-day surface. The suprasalt sequence is mostly composed of clastic rocks that are several kilometers thick in depressions between salt domes. A single total petroleum system is defined in the North Caspian basin. Discovered reserves are about 19.7 billion barrels of oil and natural gas liquids and 157 trillion cubic feet of gas. Much of the reserves are concentrated in the supergiant Tengiz, Karachaganak, and Astrakhan fields. A recent new oil discovery on the Kashagan structure offshore in the Caspian Sea is probably also of the supergiant status. Major oil and gas reserves are located in carbonate reservoirs in reefs and structural traps of the subsalt sequence. Substantially smaller reserves are located in numerous fields in the suprasalt sequence. These suprasalt fields are largely in shallow Jurassic and Cretaceous clastic reservoirs in salt dome-related traps. Petroleum source rocks are poorly identified by geochemical methods. However, geologic data indicate that the principal source rocks are Upper Devonian to Lower Permian deep-water black-shale facies stratigraphically correlative to shallow-shelf carbonate platforms on the basin margins. The main stage of hydrocarbon generation was probably in Late Permian and Triassic time, during deposition of thick orogenic clastics. Generated hydrocarbons migrated laterally into adjacent subsalt reservoirs and vertically, through depressions between Kungurian salt domes where the salt is thin or absent, into suprasalt clastic reservoirs. Six assessment units have been identified in the North Caspian basin. Four of them include Paleozoic subsalt rocks of the basin margins, and a fifth unit, which encompasses the entire total petroleum system area, includes the suprasalt sequence. All five of these assessment units are underexplored and have significant potential for new discoveries. Most undiscovered petroleum resources are expected in Paleozoic subsalt carbonate rocks. The assessment unit in subsalt rocks with the greatest undiscovered potential occupies the south basin margin. Petroleum potential of suprasalt rocks is lower; however, discoveries of many small to medium size fields are expected. The sixth identified assessment unit embraces subsalt rocks of the central basin areas. The top of subsalt rocks in these areas occurs at depths ranging from 7 to 10 kilometers and has not been reached by wells. Undiscovered resources of this unit did not rec

Bulletin↗

Map showing mineral resource potential of the Paiute Instant (Primitive) Study Area, Mohave County, Arizona

A geologic and geochemical investigation and a survey of the existing mines and prospects have been conducted to determine the mineral resource potential of the Paiute Instant (Primitive) Study Area, Mohave County, Ariz. The study area encompasses part of the Virgin Mountains and the Sullivans Canyon area. Precambrian metamorphic and igneous rocks are exposed in the core and are overlain by folded and faulted Paleozoic and Mesozoic quartzose and carbonate rocks. Mesozoic sedimentary rocks are overlain by Cenozoic volcanic and sedimentary units. The geochemical and mines and prospects survey indicates that the study area contains some mineral deposits that presently are not economically significant. Oil and gas has not been discovered in the area, and the resource potential is apparently nil or at best very low; any future oil and gas exploration would most likely be conducted outside the study area where favorable exploration localities exist. Other combustibles such as coal and oil shale are not known to occur in the study area. There is no evidence of geothermal activity or surficial radioactive mineralization. Several areas in the Paiute Instant Study Area are judged to have at best a low mineral potential. These include areas of copper, lead, manganese, molybdenum, nickel, silver, tungsten, and zinc mineralization, as well as occurrences of dumortierite, beryllium, arsenic, barium, gypsum, gem minerals, sand, gravel, and limestone. The metallic deposits and dumortieri te, beryllium, and arsenic occur over small surface areas. Significant production has not resulted from mining activity in mineralized areas. Sand, gravel, limestone, gem minerals, gypsum, and barium occurrences are far from major markets. Currently, there are no active mining operations in the study area.

Arizona↗

Active geologic processes in Barrow Canyon, northeast Chukchi Sea

Circulation patterns on the shelf and at the shelf break appear to dominate the Barrow Canyon system. The canyon's shelf portion underlies and is maintained by the Alaska Coastal Current (A.C.C.), which flows northeastward along the coast toward the northeast corner of the broad Chukchi Sea. Offshelf and onshelf advective processes are indicated by oceanographic measurements of other workers. These advective processes may play an important role in the production of bedforms that are found near the canyon head as well as in processes of erosion or non-deposition in the deeper canyon itself. Coarse sediments recovered from the canyon axis at 400 to 570 m indicate that there is presently significant flow along the canyon. The canyon hooks left at a point north of Point Barrow where the A.C.C. loses its coastal constriction. The left hook, as well as preferential west-wall erosion, continues down to the abyssal plain of the Canada Basin at 3800 m. A possible explanation for the preferential west-wall erosion along the canyon, at least for the upper few hundred meters, is that the occasional upwelling events, which cause nutrient-rich water to flow along the west wall would in turn cause larger populations of burrowing organisms to live there than on the east wall, and that these organisms cause high rates of bioerosion. This hypothesis assumes that the dominant factor in the canyon's erosion is biological activity, not current velocity. Sedimentary bedforms consisting of waves and furrows are formed in soft mud in a region on the shelf west of the canyon head; their presence there perhaps reflects: (a) the supply of fine suspended sediments delivered by the A.C.C. from sources to the south, probably the Yukon and other rivers draining northwestern Alaska; and (b) the westward transport of these suspended sediments by the prevailing Beaufort Gyre which flows along the outer shelf.

Alaska↗

Origin of high-grade gold ore, source of ore fluid components, and genesis of the Meikle and neighboring Carlin-type deposits, Northern Carlin Trend, Nevada

The Meikle mine exploits one of the world's highest grade Carlin-type gold deposits with reserves of ca. 220 t gold at an average grade of 24.7 g/t. Locally, gold grades exceed 400 g/t. Several geologic events converged at Meikle to create these spectacular gold grades. Prior to mineralization, a Devonian hydrothermal system altered the Bootstrap limestone to Fe-rich dolomite. Subsequently the rocks were brecciated by faulting and Late Jurassic intrusive activity. The resulting permeability focused flow of late Eocene Carlin-type ore fluids and allowed them to react with the Fe-rich dolomite. Fluid inclusion data and mineral assemblages indicate that these fluids were hot (ca. 220??C),of moderate salinity (<6 wt % NaCl equiv), acidic, and H2S rich. Gold-rich pyrite formed by dissolution of dolomite and sulfidation of its contained Fe. Where dissolution and replacement were complete, ore-stage pyrite and other insoluble minerals were all that remained. Locally, these minerals accumulated as internal sediments in dissolution cavities to form ore with gold grades >400 g/t. Petrographic observations, geochemical data, and stable isotope results from the Meikle mine and other deposits at the Goldstrike mine place important constraints on genetic models for Meikle and other Carlin-type gold deposits on the northern Carlin trend. The ore fluids were meteoric water (??D = -135???, ??18O = -5???) that interacted with sedimentary rocks at a water/rock ratio of ca. 1 and temperatures of ca. 220??C. The absence of significant silicification suggests that there was little cooling of the ore fluids during mineralization. These two observations strongly suggest that ore fluids were not derived from deep sources but instead flowed parallel to isotherms. The gold was transported by H2S (??34S = 9???), which was derived from Paleozoic sedimentary rocks. The presence of auriferous sedimentary exhalative mineralization in the local stratigraphic sequence raises the possibility that preexisting concentrations of gold contributed to the Carlin-type deposits. Taken together our observations suggest that meteoric water evolved to become an ore fluid by shallow circulation through previously gold- and sulfur-enriched rocks. Carlin-type gold deposits formed where these fluids encountered permeable, reactive Fe-rich rocks.

Economic Geology↗

Applied geochemistry, geology and mineralogy of the northernmost Carlin trend, Nevada

Investigations in the northernmost Carlin trend were undertaken to advance understanding of the geochemical signatures and genesis of precious metal deposits in the trend . Two fundamental geologic relationships near the trend significantly affect regional geochemical distributions: a remarkably intact lower Paleozoic stratigraphic sequence of siliceous rocks in the upper plate of the middle Paleozoic Roberts Mountains thrust, and the widespread repetition of rocks high in the upper plate during late Paleozoic thrusting that thickens the cover above mineralized rock in the lower plate. A compilation of previously published chemical analyses of 440 stream sediment samples and 115 rocks from two 7 1/2-minute quadrangles, as well as new chemical analyses of approximately 1,000 drill core samples in a 1,514 m (4,970 ft) hole through the Rodeo Creek deposit were used to construct three-dimensional element distribution models that highlight metal zonation in the mineralized systems. The Rodeo Creek deposit comprises deep Ag base-metal ± Au-mineralized rock below the Roberts Mountains thrust and contains an unusually high Ag/Au ratio greater than 30. Stacked geochemical halos related to the deposit are confined to the lower plate of the Roberts Mountains thrust and include two horizons of Hg, Cu, and Zn anomalies-as much as 180 m above the deposit-that mostly result from mercurian sphalerite. Extremely subtle indications of mineralization in the upper plate of the Roberts Mountains thrust above the deposit include arsenopyrite overgrowths on small pyrite crystals in 50- to 75-μm-wide clay-carbonate veinlets that lack alteration halos, arsenical rims on small disseminated crystal of recrystallized diagenetic pyrite, and partial replacement of diagenetic pyrite by tennantite. Some of these minerals contain anomalously high Au. However, these As-(Au)-bearing rocks most likely represent another locus of largely untested mineralized rock rather than distal halos related to either the Rodeo Creek or the nearby Dee and Storm gold deposits. Application of micromineralogic techniques helped to identify mineral assemblages that are specific to mineralization and provided an empirical foundation for interpretations of geochemical halos in the Carlin trend . District-scale geochemical patterns of several elements in stream sediments and surface rocks coincide with the northernmost Carlin trend and can be used to explore for Carlin -type deposits. Concentrations of elevated As and Sb in stream sediments (as much as 54 ppm As) have northwest-elongate lobate patterns that clearly outline the trend across a width of approximately 4 km. Arsenic contents of exposed rocks (as much as 90 ppm As) strongly correlate with As contents of derivative stream sediments, and rock contents of Sb show a somewhat lesser but nonetheless strong and similar correspondence. Factor analysis of stream-sediment data shows that those factor scores that are correlated with As, Sb, Au, and Pb also are high along the trend and suggest that mineralized rocks may be present. Although As was not detected by scanning electron microscope-energy dispersive spectrometer (SEM-EDS) studies in heavy mineral concentrates of high-As stream sediments in the Carlin trend , X-ray absorption near-edge spectra (XANES) of selected light fractions of stream sediment samples indicate that Al-bearing phases, such as gibbsite, amorphous Al oxyhydroxides, or aluminosilicate clay minerals host most of the As(V). The best fit, visually and in terms of the lowest residual, was obtained by a model compound of As(V) sorbed to gibbsite. Thus, most As in stream sediments derived from altered rock within the Carlin trend apparently is contained in light fractions. The geochemical character of young, unconsolidated, postmineral deposits that cover mineralized rocks on the Carlin trend partly results from mineralized sources along the trend . Concentration of As in the Miocene Carlin Formation shows an exceptionally well developed progressive increase to about 30 ppm As as altered rock surrounding the trend is approached. Mineralized and/or altered rock fragments probably have been shed directly into the sedimentary basin of the Carlin Formation, and migration of As, now fixed as As(V), also may have occurred in the supergene environment after material was recycled out of the Carlin Formation and into present-day gulleys.

Nevada↗

Structural evidence for northeastward movement on the Chocolate Mountains Thrust, southeasternmost California

The Late Cretaceous Chocolate Mountains thrust of southeastern California and southwestern Arizona places a block of Proterozoic and Mesozoic continental crust over the late Mesozoic continental margin oceanic sedimentary and volcanic rocks of the regionally distinctive Orocopia Schist. The Chocolate Mountains thrust is interpreted as a thrust (burial, subduction) fault rather than a low-angle normal (exhumation, unroofing, uplift) fault. An important parameter required to understand the tectonic significance of the Chocolate Mountains and related thrusts is their sense of movement. The Chocolate Mountains thrust zone contains sparse to locally abundant mesoscopic asymmetric folds. Fabric relations, supported by regional geologic evidence, indicate that these folds are an integral part of and coeval with the thrust zone. On a lower hemisphere equal-area plot representing the orientation and sense of asymmetry of 80 thrust zone folds from 36 localities, spread over an area 60 by 10 km, Z folds plot northwest of and S folds plot southeast of a northeast-southwest striking vertical plane of overall monoclinic symmetry. The only sense of movement consistent with the collective asymmetry of the thrust zone folds is top to the northeast. Asymmetric microstructures studied at several localities also indicate top to the northeast movement. Paleomagnetic data suggest that the original sense of thrusting, prior to Neogene vertical axis tectonic rotation related to the San Andreas fault system, was northward. The essential point is that movement of the upper plate of the Chocolate Mountains thrust evidently was continentward. Continentward thrusting suggests a tectonic scenario in which an insular or peninsular microcontinental fragment collided with mainland southern California. The suture predicted by this model is elusive; but the Chocolate Mountains thrust and underlying Orocopia Schist themselves may represent the suture, at the present level of exposure. Alternative tectonic models involving subduction of the Orocopia Schist eastward beneath continental southern California circumvent the suture problem but are presently not supported by any direct structural evidence.

Journal of Geophysical Research↗

Isostatic residual gravity and crustal geology of the United States

A new isostatic residual gravity map of the conterminous United States presents continent-wide gravity data in a form that can be readily used, with geologic information and other geophysical data, in studies of the composition and structure of the continental crust. This map was produced from the gridded gravity data on which the recently released Gravity Anomaly Map of the United States is based. About 1 million onland and 0.8 million offshore gravity observations interpolated to a 4- by 4-km grid serve as the basis for both maps. The Airy-Heiskanen model of isostatic compensation of topography applied to topographic and bathymetric data averaged over 5- by 5-min compartments was used to remove, to first order, the large, long-wavelength Bouguer gravity anomalies caused by deep density distributions that support topographic loads. The parameters used in the Airy-Heiskanen model were topographic density, 2.67 g/cm 3 ; sea-level crustal thickness, 30 km; and density contrast across the base of the model crust, 0.35 g/cm 3 . Many of the conspicuous short-wavelength anomalies (widths less than several hundred kilometers) on the isostatic residual gravity map correlate with mapped or near-surface geologic features, and primarily reflect shallow-density distributions rather than any departures from isostatic equilibrium. In general, gravity highs occur over (1) mafic igneous bodies emplaced in rift or magmatic arc settings or as isolated intrusions controlled by structures; (2) accreted slices of mafic oceanic, island-arc, or transitional crust; and (3) uplifted crystalline basement. Gravity lows are found over (1) thick bodies of felsic intrusive or extrusive rocks; (2) sedimentary deposits in extensional, convergent, or transform settings; and (3) depressed crystalline basement. Anomalies with widths as much as 1,000 km or more also appear to reflect crustal properties in many cases—several broad gravity highs are associated with crust having a high average seismic wave velocity, and comparable broad gravity lows occur over areas of low average seismic velocity. Alternative ways of viewing the isostatic residual gravity data provide additional information about density distributions in the crust. The first-vertical derivative map accentuates gravity anomalies over shallow, abrupt density changes at the expense of those resulting from deeper or more gradual density transitions. The maximum horizontal gradient map contains information about the locations of pronounced density boundaries. Two-dimensional spectral analysis of the gravity data provides a quantitative means for identifying dominant fabrics in the gravity field and for distinguishing various terranes from each other. Neither Bouguer nor isostatic residual gravity anomalies are particularly well suited for practical modeling of deep structure in conjunction with deep seismic information. However, a scheme in which the entire Earth outside the area of interest is approximated by laterally homogeneous layers and isostatically compensated topography, and in which the area of interest is modeled using the seismic constraints applied in a two-and-one-half-dimensional geometry, holds promise for exploiting useful features of both the Bouguer and isostatic residual gravity anomalies.

conterminous United States↗

Integrated geophysical analysis provides an alternate interpretation of the northern margin of the North American Midcontinent Rift System, Central Lake Superior

The Midcontinent Rift System (MRS) is a 1.1 Ga sequence of voluminous basaltic eruptions and multiple intrusions followed by widespread sedimentation that extends across the Midcontinent and northern Great Lakes region of North America. Previous workers have commonly used seismic-reflection data (Great Lakes International Multidisciplinary Program on Crustal Evolution [GLIMPCE] line A) to demonstrate that the northern rift margin in central Lake Superior developed as a normal growth fault that was structurally inverted to a reverse fault during a compressional event after rifting had ended. A prominent, curvilinear aeromagnetic anomaly that extends from Isle Royale, Michigan, to Superior Shoal in central Lake Superior, Ontario (the IR-SS anomaly), is commonly presented as a manifestation of this reverse fault. We have integrated multidisciplinary geophysical analyses (seismic-reflection, seismic-refraction, aeromagnetic, and gravity), physical-property information (density, magnetic susceptibility and remanence, and compressional-wave velocity), and geologic concepts to develop an alternate interpretation of the rift margin along GLIMPCE line A, where it intersects the IR-SS anomaly. Our new model indicates that a normal fault is the dominant structure at the northern rift margin along line A, contrary to the original rift-margin paradigm, which asserts that compressional structures are the dominant features preserved today. Integral to this alternate model is a newly interpreted, prerift sedimentary basin intruded by sills in northern Lake Superior. Our alternate model of the northern rift margin has implications for interpreting the style, scale, and timing of extension, rift-related intrusion, and compression during development of the MRS.

Lake Superior↗