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A cross-site comparison of ecosystem- and plot-scale methane fluxes across multiple sites

Wetland and upland ecosystems play significant but opposing roles in the global methane (CH 4 ) budget, acting as natural sources and sinks, respectively. Two of the most common approaches for measuring CH 4 fluxes (FCH 4 ) are chambers, which measure fluxes at fine spatial scales (ca. 1 m 2 ), and eddy covariance (EC) towers, which integrate fluxes across larger footprints (ca. 100–10 000 m 2 ). Although chamber and EC observations have been combined in various syntheses and databases to estimate CH 4 budgets, a unified cross-site evaluation of FCH 4 estimates at plot and ecosystem scales is lacking. As a first step toward a systematic spatiotemporal scaling of EC tower and chamber footprints, we quantified differences in site-level aggregate FCH 4 between EC and chamber measurements ( Δ FCH 4 ) across ten wetland and upland sites at half-hourly, hourly, daily, weekly, monthly, and annual timescales. We found that ecosystem-scale median FCH 4 was consistently higher than plot-scale FCH 4 at all temporal scales, with the smallest difference at the daily timescale (multi-site median Δ FCH 4 : 1.36 nmol m −2 s −1 ; median ecosystem-scale FCH 4 = 1.56 nmol m −2 s −1 , median plot-scale FCH 4 = 0.06 nmol m −2 s −1 ) and the largest at annual scales (2.58 nmol m −2 s −1 ; median ecosystem-scale FCH 4 = 25.91 nmol m −2 s −1 , median plot-scale FCH 4 = 6.55 nmol m −2 s −1 ). In general, the agreement between ecosystem- and plot-scale FCH 4 decreased with finer temporal resolution (from Spearman ρ = 0.95 at the annual scale to ρ = 0.65 at the half-hourly scale), while Δ FCH 4 variation was greatest at daily-to-annual scales. Key environmental predictors of Δ FCH 4 across the ten sites included plot-scale spatial heterogeneity, dominant vegetation type, vapor pressure deficit, atmospheric pressure, and friction velocity at the daily and monthly scales. Wind direction was a significant predictor only at the monthly scale, suggesting EC footprint effects at these sites. These findings suggest that accounting for variability in EC footprint extent, chamber measurement placement, and measurement artifacts is key to reconciling multi-scale FCH 4 observations across diverse ecosystems and refining CH 4 budgets.

Biogeosciences

Birds, breakpoints, and baselines: How citizen science data can reveal ecological boundaries in Kenya’s Upper Tana watershed

Tropical watersheds are increasingly threatened by climate change, land-use conversion, and resource extraction, yet conventional biodiversity monitoring in these systems is often spatially and temporally limited. Citizen science offers a complementary approach, enabling biodiversity data collection over large areas that can supplement professional scientific surveys. We analyzed 10 years (2012–2022) of Upper Tana Watershed bird data from the Kenya Bird Map project, covering 114 pentads (9 × 9 km) within a 17,000 km 2 watershed to assess patterns of bird community composition and distribution across this watershed and to also evaluate the effects of environmental variables, seasonality, and sampling effort to help inform improvements in future citizen science projects. Citizen (or community) scientists recorded 575 species (>50% of Kenya’s total avifauna) in 74 families. Asymptotic species accumulation indicates that most probable species present in the watershed were detected. Threshold indicator taxa analysis revealed distinct ecological boundaries along elevation (∼1,500 m), precipitation (∼1,100 mm), and mean temperature (∼19°C) gradients, corresponding to a turnover from xeric savanna to mesic montane forest assemblages. Notably, bird communities showed little seasonal differentiation between wet and dry periods, consistent with dominance by resident year-round species. Data limitations including uneven survey distribution and frequency, absence of abundance metrics, and coarse representation of local environmental conditions that likely reduced our ability to detect fine-scale species–habitat relationships. Addressing these gaps through spatially balanced sampling at greater resolution, greater survey frequency in underrepresented areas, and improved capture of habitat metrics could strengthen the use of citizen-science bird data for watershed bioassessment. Our findings demonstrate that structured citizen-science initiatives can identify ecological boundaries and inform adaptive management of tropical socio-ecological systems under rapid environmental change.

Upper Tana watershed

On connecting hydro-social parameters to vegetation greenness differences in an evolving groundwater-dependent ecosystem

Understanding groundwater-dependent ecosystems (i.e., areas with a relatively shallow water table that plays a major role in supporting vegetation health) is key to sustaining water resources in the western United States. Groundwater-dependent ecosystems (GDEs) in Colorado have non-pristine temporal and spatial patterns, compared to agro-ecosystems, which make it difficult to quantify how these ecosystems are impacted by changes in water availability. The goal of this study is to examine how key hydrosocial parameters perturb GDE water use in time and in space. The temporal approach tests for the additive impacts of precipitation, surface water discharge, surface water mass balance as a surrogate for surface–groundwater exchange, and groundwater depth on the monthly Landsat normalized difference vegetation index (NDVI). The spatial approach tests for the additive impacts of river confluences, canal augmentation, development, perennial tributary confluences, and farmland modification on temporally integrated NDVI. Model results show a temporal trend (monthly, 1984–2019) is identifiable along segments of the Arkansas River at resolutions finer than 10 km. The temporal impacts of river discharge correlate with riparian water use sooner in time compared to precipitation, but this result is spatially variable and dependent on the covariates tested. Spatially, areal segments of the Arkansas River that have confluences with perennial streams have increased cumulative vegetation density. Quantifying temporal and spatial dependencies between the sources and effects of GDEs could aid in preventing the loss of a vulnerable ecosystem to increased water demand, changing climate, and evolving irrigation methodologies.

Colorado

Deep subsurface organic-rich shale supports abundant, diverse, and novel fungi

As Earth’s principal reservoir of organic carbon and microbial biomass, the deep subsurface hosts microorganisms capable of mobilizing this once-sequestered carbon. Contrary to standard assumptions of eukaryotic scarcity, this study documents abundant fungal communities, ranging from 4.2 × 10 3 to 6.8 × 10 3 fungal cells mL −1 , across a methane-producing organic-rich shale 247–556 meters below the surface. Although fungal:bacterial cell ratios ranged from 1:7028 to 1:713, application of biomass conversion factors developed for oceanic systems yielded a median fungal:bacterial biomass ratio of 1:4.7. 16S rRNA gene amplicons revealed bacterial and archaeal communities mirroring those found in well-characterized extremophilic, carbon-degrading environments, while sequencing of 18S rRNA gene and ITS rRNA spacer amplicons collectively identified a eukaryotic hotspot with 689 fungal OTUs across six phyla. The dominant fungal classes, Agaricomycetes and Dothideomycetes, are well-established degraders of recalcitrant carbon compounds at the surface, suggesting they may similarly contribute to organic matter degradation and ecosystem maintenance in the subsurface. Cultivation and isolation efforts yielded 205 fungal strains, including 13 candidate novel taxa, underscoring the deep subsurface as an underexplored eukaryotic habitat. Stable carbon isotopes indicate methane is predominantly generated via microbial conversion of the fossil carbon, while water isotopes suggest in situ geochemical conditions have been relatively stable since the Late Pleistocene, with subglacial recharge as a plausible mechanism for microbial introduction. Collectively, these findings suggest that fungi are underrecognized contributors to organic matter transformation and functional diversity in the deep biosphere, revealing a critical gap in our understanding of deep subsurface ecosystem processes.

Indiana, Michigan, Ohio

Forecasting water levels using the ConvLSTM algorithm in the Everglades, USA

Forecasting water levels in complex ecosystems like wetlands can support effective water resource management, ecological conservation, and understanding surface and groundwater hydrology. Predictive models can be used to simulate the complex interactions among natural processes, hydrometeorological factors, and human activities. The Greater Everglades in the USA is a well-known example of an ecosystem where complexity has motivated adoption of machine learning algorithms in water level prediction studies. This paper aims to contribute to extending existing machine learning algorithms by integrating spatiotemporal data with deep-learning algorithms in the forecasting process. In this study, a deep-learning model is developed to predict water levels on a regional scale, covering a large area of approximately 9,138 square kilometers in the Everglades ecosystem. This model has the architecture of Convolutional Long Short-Term Memory which can deal with spatiotemporal data by capturing both spatial and temporal dependencies in the training data. The forecasting capabilities of this model (referred to as the global model) are assessed by comparing the global model to two Artificial Neural Networks developed at two different gaging stations, referred to here as local models. One local model is developed at a gaging station directly influenced by nearby water control structures, whereas the other is developed at a gaging station located farther away from these structures. By leveraging data from the Everglades Depth Estimation Network spanning from January 2002 to May 2023, the global and local models were trained to forecast water levels with a two-day lead time. Our findings suggest that both the global and local models perform with approximately the same level of accuracy, with Mean Absolute Relative Error values ranging from 0.38% to 1.4% at the selected stations. The developed global model has demonstrated strong potential as a standalone forecasting tool for the entire study area in the Everglades and could eliminate the need for developing multiple local models. This finding also highlights how machine learning can capture complex spatial and temporal relationships to generate accurate water level predictions on a regional scale.

Florida

Modeling legacy nitrogen transport under instantaneous, steady-state, and transient groundwater flow conditions

In hydrologic settings where groundwater discharge contributes substantially to surface waters, legacy nitrogen in groundwater can confound surface water nitrogen loads estimated exclusively from current terrestrial sources. Additionally, legacy nitrogen in groundwater can contribute to lagged responses to nitrogen management efforts. Some methods of estimating groundwater contributions to surface water nitrogen loads account for legacy nitrogen, while others do not. The resulting differences are rarely quantified. We used a numerical modeling framework to compare three methods of estimating time-varying annual groundwater nitrogen loads to surface water receptors on eastern Long Island, New York. The instantaneous load method used steady-state contributing areas and includes no temporal groundwater lag. The second method used numerical simulations of nitrogen loads under steady-state flow, which captures groundwater transport lags but omits the annual variability in transient hydrologic stresses. The third method numerically simulated both transient groundwater flow and nitrogen transport to explicitly capture the effects of legacy nitrogen in groundwater. Depending on antecedent nitrogen and hydrologic conditions, historical nitrogen loads estimated from the numerical simulations were sometimes similar (<10% difference) and other times substantially different (±100%) from the instantaneous load estimates. Additionally, simulated future surface water nitrogen loads responded asymptotically over several decades following reductions in terrestrial nitrogen sources, further highlighting the effect of groundwater transport lag times. The comparison of the three methods, quantification of historical interannual variability, and prediction of lagged responses to nitrogen source reductions provide important context for decision makers using estimated groundwater nitrogen loads to help evaluate nitrogen management efficacy.

New York

Microplastics undergo fragmentation during pressurized membrane filtration

Low-micrometer microplastics (<10 μm) have been detected in drinking water, driving growing interest in using pressure-driven membrane filtration to remove these particles and ensure drinking water safety. However, little attention is paid to the fate of microplastics concentrated in the filtration byproduct. In this study, using well-defined polystyrene (PS) and poly(methyl methacrylate) microspheres as model particles, we observed microplastic fragmentation during nanofiltration and the subsequent release of smaller fragments. After operating for 3 h at 20 bar, 67.9 ± 8.0% of the PS spheres in the concentrate, based on particles counted in selected fields of view, were transformed into fractured particles. The characteristic Raman band signals of microplastics were significantly weakened after fragmentation, leading to detection challenges. To address this, a data processing algorithm was developed to identify PS fragments as small as 1 μm. Preliminary statistical analysis reveals that within the tested pressure range, operation time has a stronger influence on fragmentation than pressure magnitude alone and that fragmentation is further governed by the intrinsic mechanical properties of the tested model polymers. This work provides direct evidence that pressure-driven membrane processes induce microplastic fragmentation and highlights the environmental risks associated with the discharge of fragmented microplastics into the concentrate.

Environmental Science & Technology Letters

A global database of soil microbial phospholipid fatty acids and enzyme activities

Soil microbes drive ecosystem function and play a critical role in how ecosystems respond to global change. Research surrounding soil microbial communities has rapidly increased in recent decades, and substantial data relating to phospholipid fatty acids (PLFAs) and potential enzyme activity have been collected and analysed. However, studies have mostly been restricted to local and regional scales, and their accuracy and usefulness are limited by the extent of accessible data. Here we aim to improve data availability by collating a global database of soil PLFA and potential enzyme activity measurements from 12,258 georeferenced samples located across all continents, 5.1% of which have not previously been published. The database contains data relating to 113 PLFAs and 26 enzyme activities, and includes metadata such as sampling date, sample depth, and soil pH, total carbon, and total nitrogen. This database will help researchers in conducting both global- and local-scale studies to better understand soil microbial biomass and function.

Scientific Data

A robust quantitative method to distinguish runoff-generated debris flows from floods

Debris flows and floods generated by rainfall runoff occur in rocky mountainous landscapes and burned steeplands. Flow type is commonly identified post-event through interpretation of depositional structures, but these may be poorly preserved or misinterpreted. Prior research indicates that discharge magnitude is commonly amplified in debris flows relative to floods due to volumetric bulking and increased frictional resistance. Here, we use this flow amplification to develop a metric ( Q* ) to separate debris flows from floods based on the ratio of observed peak discharge to the theoretical maximum water discharge from rainfall runoff. We compile 642 observations of floods and debris flows and demonstrate that Q* distinguishes flow type to ∼92% accuracy. Q* allows for accurate identification of debris flows through simple channel cross-section surveys rather than through qualitative interpretation of deposits, and therefore should increase the performance of models and engineered structures that require accurate flow-type observations.

Geophysical Research Letters

Peak-discharge frequency and potential extreme peak discharge for natural streams in the Brazos River basin, Texas

The 2-, 5-, 10-, 25-, 50-, and 100-year peak discharges were estimated for 186 streamflow-gaging stations with at least 8 years of data for natural streams in and near the Brazos River Basin, Texas. Multiple regression equations were developed to estimate peak-discharge frequency for the 2-, 5-, 10-, 25-, 50-, and 100-year recurrence intervals for each of three hydrologic regions that compose the Brazos River Basin. The equations for each region are a function of significant basin characteristics (explanatory variables). The significant explanatory variables among six that were tested are the contributing drainage area and stream slope for regions 1 and 2 and the contributing drainage area for region 3. For the three sets of equations, the coefficient of determination ranges from 0.59 to 0.93, and the standard error ranges from 0.184 to 0.391 log units. A larger coefficient of determination and a lower standard error generally are associated with the equations for hydrologic regions 2 and 3. Statistics from the regression analysis allow computation of the prediction interval associated with a given significance level for a peak-discharge frequency estimate. The regression equations can be used to estimate peak discharges for sites at, near, or away from sites with streamflow-gaging stations. The potential extreme peak-discharge curves as related to contributing drainage area were estimated for each of the three hydrologic regions from measured extreme peaks of record at 186 sites with streamflow-gaging stations and from measured extreme peaks at 37 sites without streamflow-gaging stations in and near the Brazos River Basin. The potential extreme peak-discharge curves generally are similar for hydrologic regions 1 and 2, and the curve for region 3 consistently is below the curves for regions 1 and 2, which indicates smaller peak discharges.

Texas

Land-use interactions, Oil-Field infrastructure, and natural processes control hydrocarbon and arsenic concentrations in groundwater, Poso Creek Oil Field, California, USA

Like many hydrocarbon production areas in the U.S., the Poso Creek Oil Field in California includes and is adjacent to other land uses (agricultural and other developed lands) that affect the hydrology and geochemistry of the aquifer overlying and adjacent to oil development. We hypothesize that the distributions of hydrocarbons and arsenic in groundwater in such areas will be controlled by complex interactions between mixed land uses, oil-field infrastructure, and natural processes. In 2020–2021, samples of groundwater and surface water were collected and analyzed for a large suite of inorganic and organic chemicals and isotope and gas tracers to test this hypothesis. Those data are supplemented with ancillary data on historical geochemistry, hydrology, geology, and oil-field infrastructure. Hydrocarbons in groundwater (e.g., methane through pentane gases and benzene) are associated with natural processes (e.g., fault offsets or transition in sediment depositional environment) and oil-field infrastructure (e.g., fluid-migration pathways associated with uncemented annulus in oil wells or unlined pits). Arsenic concentrations >10 μg per liter (μg/L; maximum concentration 12.9 μg/L) are associated with natural processes in old, high-pH groundwater, and more recent recharge of water from natural and/or engineered recharge processes. Along the southwest margin of the oil field, pumping for drinking-water and irrigation supplies in combination with engineered groundwater recharge produce a depression in groundwater elevations where groundwater with elevated sulfate concentrations from agricultural areas and groundwater with hydrocarbons from the oil field mix to produce a zone of sulfate reduction that removes hydrocarbons and arsenic from groundwater but produces elevated sulfide (S 2- ) concentrations (maximum concentration 29 mg per liter, mg/L). In this study, multiple approaches were required to resolve the overlapping effects of land uses, oil-field infrastructure, and natural processes on the distributions of hydrocarbons and arsenic in groundwater. The combined use of geographic, historical, physical, chemical, isotopic, and other information to constrain processes could be a useful approach for studies in other hydrocarbon-production areas. This is particularly important where land uses affect aquifer hydrology to an extent that causes mixing of groundwaters with different chemical compositions.

California

Earthquake cycle mechanics during caldera collapse: Simulating the 2018 Kīlauea eruption

In multiple observed caldera-forming eruptions, the rock overlying a draining magma reservoir dropped downward along ring faults in sequences of discrete collapse earthquakes. These sequences are analogous to tectonic earthquake cycles and provide opportunities to examine fault mechanics and collapse eruption dynamics over multiple events. Collapse earthquake cycles have been studied with zero-dimensional slider-block models, but these do not account for the complicated interplay between fluid and elastic dynamics or for factors such as the heterogeneous fault properties and non-vertical ring fault geometries often inferred at volcanoes. We present two-dimensional axisymmetric mafic piston-like collapse earthquake cycle models that include rate-and-state friction, fully-dynamic elasticity, and compressible viscous fluid magma flow. We demonstrate that collapse earthquake intervals and magnitudes are highly sensitive to inertial effects, evolving stress fields, fault geometry, and depth-varying fault friction. Given the consistent earthquake cycles observed in most eruptions, this suggests that ring faults can quickly stabilize and often become nearly vertical at depth. We use the well-monitored 2018 collapse sequence at Kı̄lauea as a case study. Our model can produce many features of Kı̄lauea seismic and geodetic observations, except for a significant amount of interseismic slip, which cannot be readily explained with simple rate-and-state friction parameterizations.

Hawaii

Potential warming-induced changes in stream water sources between proglacial and non-glacial streams, south-central Alaska

Snow and ice-melt are essential for global water resources. Rising air temperatures are causing vegetation encroachment and shrubification of previously snow- and ice-covered landscapes, and precipitation regimes are changing. Collectively, these changes will likely affect the hydrology of mountain environments, although the exact ways in which the hydrology will change are poorly understood. Changing source waters (i.e., the proportion of ice-melt, snowmelt, rain and groundwater) affect the timing and magnitude of streamflow and affect stream temperature, sediment, solute and nutrient fluxes. We investigate spatial and seasonal source water contributions across sub-watersheds of the Nellie Juan River watershed on Alaska's Kenai Peninsula, which differ in glacier cover, elevation and land cover, using a space-for-time approach. To do so, we use a three-endmember mixing model to quantify the contribution of rain, snow/ice-melt and deep groundwater. We show that snow/ice-melt peak later in proglacial streams compared to non-glacial streams. Endmember contributions in non-glacial streams generally vary with elevation and season. We also found that groundwater is a major contributor to streamflow across the study area, contributing between 12% and 47% seasonally, and may become increasingly important as snowpack and ice-melt decrease. This research characterises the shift from a glacierised to a deglaciating landscape through the lens of source water contribution. Broadly, these findings could help improve understanding of how water resources in glacierised watersheds are affected by warming air temperatures.

Alaska

SURF: An automated method for building nonplanar 3D fault models from earthquake hypocenters

Accurately characterizing 3D fault geometry is vital for improving our understanding of earthquake behavior and informing the development of seismic hazard models. Despite their importance, subsurface fault structures tend to be poorly constrained because of limitations in observational data. Improvements to the seismic networks and earthquake detection algorithms have increased the precision and volume of earthquake catalogs, which help illuminate detailed subsurface fault structure and provide the most direct information available about fault geometries at depth. We present a Python package to automate generating 3D fault geometries directly from hypocentral seismicity patterns. This method begins with clustering events based on their spatial density, identifying coherent patterns. Nearby clusters are then merged based on the similarity of their orientations. We fit nonplanar surfaces using support vector regression to balance surface accuracy with minimal deviations from planarity. The fault models are output as quadrilateral meshes at user‐defined resolution. In the process of generating the 3D fault surfaces, we compute the spatial density of seismicity around the surface and the planarity as quantitative metrics of the model outputs. As a proof of concept, we apply this approach to the San Andreas–Calaveras fault junction region and the 2019 Ridgecrest earthquake sequence, both in California, which contain complex subparallel faults well defined at the Earth’s surface and abundant microseismicity. These case studies demonstrate the method’s ability to model complex fault structures, including long continuous fault surfaces, crossing faults, variably dipping segments, and subparallel faults. We test the method on both standard network catalogs and double‐difference relocated catalogs. We find that our seismicity‐based fault model results align with published 3D models that incorporate additional constraints and interpretations ( Plesch et al. , 2020 ; Aagaard and Hirakawa, 2021 ). This workflow provides a low‐user‐input solution for estimating fault geometries at depth from earthquake catalogs.

California

Long-term trends in microseismicity during operational shut-ins at the Coso Geothermal Field, California

Pausing injection and production can lead to induced seismicity in a variety of settings, with some of the largest events occurring during these so-called shut-ins. In geothermal fields, shut-ins are periodically conducted for maintenance on wells and surface infrastructure, thereby offering recurring means of estimating stress changes in the subsurface that lead to increased seismicity rates. Here, we examine daily production and microseismicity data from the Coso Geothermal Field (CGF) in California between 1996 and 2010 to investigate the repetitive trends of operational shut-in microseismicity. Using 24 local seismic stations, we first analyze spatial and temporal trends of over 60,000 earthquakes with magnitudes between -0.4 to 3.8. We find that the northern region exhibits no significant seismicity changes during shut-ins, whereas the rest of the field experiences induced seismicity during almost every shut-in with an increasing intensity towards the southern and eastern portions of the field, highlighting local differences in stress within the CGF. Additionally, we cluster the seismicity using waveform cross-correlation, revealing several earthquake clusters primarily occurring during shut-in periods. These observations suggest that certain fracture and fault sections respond quicker to changes in pore pressure and poroelastic stresses within the geothermal system, possibly highlighting main fluid pathways.

California

Characterizing sedimentary organic carbon in a hydrothermal spreading center, the Escanaba Trough

Sediments in critical marine mineral environments are of wide importance due to their preservation of both marine minerals and organic carbon (OC) stocks. However, OC storage and cycling is often overlooked in mineral system studies. This work characterizes sedimentary OC within the Escanaba Trough, a hydrothermal sulfide system off the coast of northern California. By utilizing ROV-based push coring, we collected sediments near and far from high temperature, low temperature, and inactive vents. We applied a multipronged organic geochemical approach, measuring bulk sediment, OC fractions of varying labilities, and biomarkers to tease apart the storage, source, and cycling of OC within this complex system. In contrast to past work indicating a primarily terrestrial source to deeper, Pleistocene sediments, our results suggest a primarily marine source in surface sediments at least 50 m away from active venting. Near active venting, we see evidence of locally produced chemosynthetic OC in addition to the background marine source. This chemosynthetic OC appears to be rapidly remineralized and supports more complex deep-sea food webs compared to hemipelagic sites. Still, the greatest contribution of labile OC was observed at inactive vent sites, which we suggest is due to hydrothermal fluid alteration of more labile OC at actively venting sites. Depending on fluid temperature, hydrothermally altered OC is either preserved in the sediments as petroleum or migrated with fluid flow. Considering inactive sites are those most likely to be targeted by potential mining, we suggest additional studies could verify if these results apply at other sedimented seafloor massive sulfide systems.

California

Hydrologic and water-quality conditions in the Horse Creek basin, west-central Florida, October 1992-February 1995

A baseline study of the 241-square-mile Horse Creek basin was undertaken from October 1992 to February 1995 to assess the hydrologic and water-quality conditions of one of the last remaining undeveloped basins in west-central Florida. During the period of the study, much of the basin remained in a natural state, except for limited areas of cattle and citrus production and phosphate mining. Rainfall in 1993 and 1994 in the Horse Creek basin was 8 and 31 percent, respectively, above the 30-year long-term average. The lowest and highest maximum instantaneous peak discharge of the six daily discharge stations occurred at the Buzzard Roost Branch and the Horse Creek near Arcadia stations with 185 to 4,180 cubic feet per second, respectively. The Horse Creek near Arcadia station had the lowest number of no-flow days with zero days and the Brushy Creek station had the highest number with 113 days. During the study, the West Fork Horse Creek subbasin had the highest daily mean discharge per square mile with 30.6 cubic feet per second per square mile, and the largest runoff coefficient of 43.7 percent. The Buzzard Roost Branch subbasin had the lowest daily mean discharge per square mile with 5.05 cubic feet per second per square mile, and Brushy Creek and Brandy Branch shared the lowest runoff coefficient of 0.6 percent. Brandy Branch had the highest monthly mean runoff in both 1993 and 1994 with 11.48 and 19.28 inches, respectively. During the high-baseflow seepage run, seepage gains were 8.87 cubic feet per second along the 43-mile Horse Creek channel. However, during the low-baseflow seepage run, seepage losses were 0.88 cubic foot per second. Three methods were used to estimate average annual ground-water recharge in the Horse Creek basin: (1) well hydrograph, (2) chloride mass balance, and (3) streamflow hydrograph. Estimated average annual recharge using these three methods ranged from 3.6 to 8.7 inches. The high percentage of carbonate plus bicarbonate analyzed at the Carlton surficial aquifer well could indicate an upward ground-water flow from the underlying intermediate aquifer system. Based on constituent concentrations in water samples from the six daily discharge stations, concentrations generally are lower in the upper three subbasins, West Fork Horse Creek, Upper Horse Creek, and Brushy Creek than in the lower three subbasins. Typically, concentrations were highest for major ions at Buzzard Roost Branch and nutrients at Brushy Creek.

Florida

Geochemical processes related to mined, milled, or natural metal deposits in a rapidly changing global environment

The demand for metals and raw materials, such as nickel and copper, has been projected to expand in the coming decades, driven by the global energy transition, the need for green technologies, and expanding infrastructure. Consequently, the increasing extraction and production of mining waste can have adverse impacts on surrounding environments and human health. The aim of this thematic collection is to fill critical knowledge gaps in the present-day cycles of metal(loid)s from source to larger sinks, and the effect of environmental management, anthropogenic development, and climate change. Altogether, the studies have been conducted in different natural settings around the world and comprise investigations in laterites, a soil-medicinal plant system, watersheds, and banded iron formations, among others. The geochemical applications in tracing mineralization, its secondary products, and/or potential impact on the immediate environment are highly diverse with applied tools ranging from isotope tracers to major and trace element systematics. Particularly the use of rare earth elements, their patterns and anomalies are methods employed by several studies in this collection. We summarize the findings to offer a potential future direction for the use of geochemical tracing techniques in resource exploration in the context of climate change and environmental challenges.

Geochemistry: Exploration, Environment, Analysis