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Fluvial sediment and chemical quality of water in the Little Blue River basin, Nebraska and Kansas
The Little Blue River drains about 3,37)0 square miles in south-central Nebraska and north-central Kansas. The uppermost bedrock in the basin is limestone and shale of Permian age and sandstone, shale, and limestone of Cretaceous age. Bedrock is exposed in many places in the lower one-third of the basin but elsewhere is buried beneath a thin to thick mantle of younger sediments, mostly of Quaternary age. These younger sediments are largely fluvial and eolian deposits but also include some glacial till. Consisting in large part of sand and gravel, the fluvial deposits are an important source of ground-water supplies throughout much of the upper two-thirds of the basin. Loess, an eolian deposit of clayey silt, is by far the most widespread surficial deposit. The climate is continental. Temperatures ranging from -38 ? F to 118 ? F have been recorded in the basin. Average annual precipitation as low as 10.31 and as high as 49.32 inches has been recorded. During most years in the period 1956-62, when nearly all the water-quality data were obtained, annual precipitation and annual runoff were greater than normal. Flow-duration data indicate, however, that the flow distribution for the period was near normal. The Little Blue River has the same suspended-sediment characteristics as nearly all unregulated streams in the Great Plains--a wide range in concentrations, low concentrations during low-flow periods, and high concentrations during almost all periods of significant overland runoff. The maximum instantaneous concentration normally occurs many hours before maximum water discharge during any given rise in stage; the maximum daily mean concentration during any given year normally occurs at a moderate stream stage, not during a major flood. Suspended-sediment data for Little Blue River near Deweese, Nebr., which receives drainage from the upstream third of the basin, approximately, show that during the 1!}57-61 water years concentrations of 100 ppm (parts per million) or less prevailed about 42 percent of the time and concentrations of 1,000 ppm or less prevailed about 85 percent of the time. Observed concentrations ranged from 2 to 21,000 ppm: daily mean concentrations ranged from 2 to 13,800 ppm. The discharge-weighted suspended-sediment concentration was computed as about 2,800 ppm at Little Blue River near Deweese, about 3,300 ppm near Fairbury (Endicott), and about 3,000 ppm at Waterville. These stations receive drainage from about one-third, two-thirds, and nearly all the basin, respectively. Water-utilization problems resulting from high concentrations are not significant in the basin ; use of water from the Little Blue River is quantitatively negligible. Concentrations and, consequently, discharges of sediment are greater at a given water discharge on a rising stage than at the same discharge on the falling stage of the same runoff event. Also, a wide range in sediment discharge occurs at similar water discharges during different runoff events. Daily sediment discharges at Little Blue River near Deweese ranged from about 1,400 to 16,000 tons at daily mean water discharges of about 500 cfs (cubic feet per second) and from almost 7,500 to 28,000 tons at water discharges of about 1,000 cfs. The estimated long-term sediment discharge at Little Blue River near Deweese is about 400,000 tons per year: near Fairbury, about 1,200,000 tons per year: and at Waterville, about 1.900,000 tons per year. The high sediment discharge from the downstream part of the basin is due to greater precipitation and runoff--not to higher concentrations of suspended sediment--in the downstream parts of the basin. Nearly all the suspended sediment is silt and clay. The streambed material is mainly medium sand to gravel. The median particle size of bed material observed was about 0.73 mm near Deweese and about 0.77 mm near Fairbury. A few computations of total sediment discharge of Little Blue River near Deweese indicate that suspended-sedim
Ground-water development in the high plains of Colorado, with a section on chemical quality of the ground water
The High Plains of Colorado includes all or part of 11 counties and has an area of about 9,500 square miles. The land surface slopes eastward and in most areas is gently rolling owing to erosion by ephemeral streams. The Ogallala Formation, of Pliocene age, is the principal aquifer. In pierces it is overlain by dune sand, alluvium, or loess. The Ogallala is semiconsolidated and consists of sand, gravel, silt, clay, and caliche. The Ogallala Formation is recharged by precipitation at a rate of about 0.85 inch per year. The water table slopes generally eastward. The major use of ground water is for irrigation. About 72,500 acre-feet of water was pumped from 428 wells to irrigate about 56,600 acres in 1962. Estimates of consumptive use made by the Blaney-Criddle method show that the optimum amount of water is being used to irrigate parts of the High Plains. At the end of the 1963 irrigation season, 525 irrigation wells each pumped more than 300 gallons per minute. Water levels decline as much as 10 feet in some places during the irrigation season but return almost to normal at the completion of pumping. By prorating transmissibility on the basis of lithologic descriptions from well logs, the average permeability of the Ogallala Formation in various places can be estimated. Most water from the Ogallala Formation in the High Plains is a calcium bicarbonate solution having a dissolved-solids content ranging from 100 to 600 parts per million. The water is generally hard; its calcium carbonate hardness ranges from 100 to 350 parts per million. Except for some ground water in the area south of the Cheyenne-Kiowa County line, the ground water analyzed was suitable for all uses.
Special sediment investigations Mississippi River at St. Louis, Missouri, 1961-63
Four sets of comprehensive hydraulic and sediment data were obtained during 1961-63 for the Mississippi River at St. Louis at ranges of mean velocity from 3.3 to 5.6 feet per second, of mean depth from 22 to 37 feet, of width from 1,570 to 1,670 feet, of mean water-surface slope from 0.000054 to 0.000109, and of suspended-sediment concentration from 314 to 928 parts per million. The suspended sediment consisted of 9-46 percent sand, 30-46 percent silt, and 20-56 percent clay. The median size of bed material was about 0.42 millimeter for three sets of measurements and about 0.18 millimeter for the other set. A dune bed form was present during all four data-collection periods. Data obtained on consecutive days indicate that the turbulence constant can be computed from either streamflow-measurement notes or from vertical-velocity profiles. Constants computed from streamflow-measurement notes averaged 0.34, and those from vertical-velocity profiles averaged 0.35. The coefficients of vertical distribution of concentration for selected size ranges of suspended sands (expressed as z1, the slope, of the line relating the logarithms of concentration and a depth parameter) plotted against corresponding fall velocities indicate that on the average, the z1's are proportional to about the 0.7 power of the fall velocity. The data also indicate that the relation of z1 to fall velocity may vary with the mean velocity of flow.
Correlation and analysis of water-temperature data for Oregon streams
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Summary of floods in the United States during 1962
This report describes the most outstanding floods in the United Spates during 1962. The most damaging floods during the year occurred in February in southern Idaho and northern Nevada and Utah, and during the latter part of February and the early part of March in Kentucky and in the Cumberland River basin in Tennessee. The floods in Idaho and adjacent areas of Nevada and Utah resulted from a combination of prolonged low-intensity rainfall, moderate amounts of snow on low-altitude areas, a period of high temperatures, and a glaze of ice over deeply frozen ground. The floods affected some of the most valuable agricultural land in the region and some of the most heavily populated areas in Idaho. Damage in Idaho was estimated at more than \$7 million. The floods in Kentucky and Tennessee were caused by two storms; precipitation exceeded 7 inches at places during the second storm. Damage in Kentucky totaled about \$7 million. Recordbreaking snowmelt floods occurred in March and April in southeastern South Dakota and adjacent areas. Many peak discharges were much greater than those that can be expected to occur on an average of once in 25 years. Peak discharges on the Floyd River and the Big Sioux River were the greatest snowmelt floods since 1881. Damage in South Dakota was estimated at \$4 million. Heavy rains during May and intense rains in early June caused flooding in Minnesota on tributaries of the Red River of the North. Peak discharges exceeded previous maximums at some areas in the basins of the Buffalo, Clearwater, and Wild Rice Rivers. Damage from the floods of May and June in Minnesota was about \$5 million. The greatest flood since 1920 in Rapid City, S. Dak., caused at out $600,000 damage in July. The great runoff of 3,300 cubic feet per second, from a relatively small area downstream from Pactola Reservoir, resulted from rainfall having an intensity greater than that for a 100-year recurrence interval. Floods caused almost \$3 million damage in three river basins' in western Florida in September. The greatest damage was in Sarasota where from 3 to 7 feet of water flooded homes and stores. About 70,000 acres of farmland and woodland was inundated. Unusual floods of September in southern Arizona flooded areas up to 10 miles wide. Damage, which totaled about \$3 million, was almost entirely to farms, as the flood area is sparsely populated. In addition to the floods just mentioned, 15 others of lesser magnitude are considered outstanding enough to be included in this annual summary.
Availability of ground water upper Pawcatuck River basin Rhode Island
The upper Pawcatuck River basin is a 70-square-mile area in southcentral Rhode Island consisting of broad, rolling hills and narrow valleys in the north and fiat-floored plains in the south. It is drained by the Pawcatuck River and its two major tributaries, the Usquepaug-Queen River and the Chipuxet River. Analysis of the water budget for the basin shows that approximately 94 mgd (million gallons per day) or about 63 percent of the precipitation flows out of the basin as streamflow. Of this amount, about 66 mgd is from ground-water seepage. Two ground-water reservoirs composed of glacial deposits of sand and gravel and capable of substantial yields are in the basin. The larger reservoir underlies the central part of the Usquepaug-Queen River valley. This reservoir ranges in width from 3,000 to 4,000 feet and is 32,000 feet long. A large part of the reservoir contains sand and gravel more than 100 feet thick, having a permeability of more than 1,000 gallons per day per square foot. The yield of this reservoir is estimated to be about 17 mgd. The smaller ground-water reservoir is in the Chipuxet River valley. It is about 4,000 feet wide and 16,000 feet long. A large part of this reservoir contains sand and gravel more than 150 feet thick having a permeability of more than 1,000 gallons per day per square foot. The yield of the Chipuxet reservoir is estimated to be about 8.6 mgd. Mineral content of water from both of the reservoirs is generally less than 200 parts per million of dissolved solids. However, in the Chipuxet groundwater reservoir the dissolved solids are somewhat higher, and the iron content is a problem. Only about 1.5 mgd of water is used in the basin. Most of it is used for public supplies and is obtained from wells not tapping the Usquepaug-Queen or Chipuxet ground-water reservoirs. Estimates of the 25 mgd of ground water potentially available are believed to be conservative, and substantially larger quantities may actually be available when development takes place.
Sedimentation and chemical quality of surface water in the Heart River drainage basin, North Dakota
The Heart River drainage basin of southwestern North Dakota comprises an area of 3,365 square miles and lies within the Missouri Plateau of the Great Plains province. Streamflow of the Heart River and its tributaries during 1949-58 was directly proportional to .the drainage area. After the construction of Heart Butte Dam in 1949 and Dickinson Dam in 1950, the mean annual streamflow near Mandan was decreased an estimated 10 percent by irrigation, evaporation from the two reservoirs, and municipal use. Processes that contribute sediment to the Heart River are mass wasting, advancement of valley heads, and sheet, lateral stream, and gully erosion. In general, glacial deposits, terraces, and bars of Quaternary age are sources of sand and larger sediment, and the rocks of Tertiary age are sources of clay, silt. and sand. The average annual suspended-sediment discharges near Mandan were estimated to be 1,300,000 tons for 1945-49 and 710,000 tons for 1970-58. The percentage composition of ions in water of the Heart River, based on average concentrations in equivalents per million for selected ranges of streamflow, changes with flow and from station to station. During extremely low flows the water contains a large percentage of sodium and about equal percentages of bicarbonate and .sulfate, and during extremely high flows the water contains a large percentage of calcium plus magnesium and bicarbonate. The concentrations, in parts per million, of most of the ions vary inversely with flow. The water in the reservoirs--Edward Arthur Patterson Lake and Lake Tschida--during normal or above-normal runoff is of suitable quality for public use. Generally, because of medium or high salinity hazards, the successful long-term use of Heart River water for irrigation will depend on a moderate amount of leaching, adequate drainage, ,and the growing of crops that have moderate or good salt tolerance.
Ground-water levels in the United States, 1960-64, south-central states
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Geology and hydrology of northeastern Nassau County, Long Island, New York
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Water resources of the Ipswich River basin, Massachusetts
Water resources of the Ipswich River basin are at resent {1960) used principally for municipal supply to about 379,000 person's in 16 towns and cities in or near the river basin. By the year 2000 municipal use of water in this region will probably be more than twice the current use, and subsidiary uses of water, especially for recreation, also will have increased greatly. To meet the projected needs, annual pumpage of water from the Ipswich River could be increased from current maximums of about 12 mgd (million galleons a day) to about 45 mgd without reducing average base flows in the river, provided that the increased withdrawals would be restricted to periods of high streamflow. In addition, considerably more pumpage could be derived from streamflow by utilizing base-flow discharge; however, the magnitude of such use could be determined only in relation to factors such as concurrent ground-water use, the disposal of waste water, and the amount of streamflow required to dilute the pollution load to acceptable levels. Under present conditions, little or no increase in diversion of streamflow would be warranted in the upstream rafts of the basin during the summer and early fall of each year, and only a moderate increase could be made in the lower reaches of the stream during the same period. Annual rainfall in the basin averages about 42.5 inches, and represents the water initially available for use. Of this amount, an average of about 20.5 inches is returned to the a.tmosphere by evapotranspiration. The remainder, about 22 inches, runs off as streamflow in the Ipswich River or is diverted from the basin by pumpage. The average annual stream runoff, amounting to about 47 billion gallons, is a measure of the water actually available for man's use. The amounts of water used by municipalities in recent years are less than 10 percent of the available supply. Large supplies of ground water may be obtained under water-table conditions from the stratified glacial drift that forms .the principal ground-water reservoir of the basin. Stratified drift deposits fill valleys in about 31 percent of the basin. Thicknesses of the deposits are generally less than 50 feet, but at places may be as great as 200 feet. Between 1931 and 1960 recoverable annual recharge to stratified drift aquifers averaged about 10 inches, equal to 42 mgd. The least possible recharge during any of these years was probably more than 41inches, or 25 mgd. Therefore, ground-water withdrawals from the basin could be sustained at a rate at least five times greater than the 1960 rate of 4.9 mgd. In the lower Ipswich basin. withdrawal of ground water could be sustained at a rate eight or nine times greater than the 1960 rate of 1.86 mgd. There are 1 or more favorable sites for further exploration for ground water in each of the 10 communities that occupy the major part of the river ,basin. Small but reliable supplies of ground water for domestic use may be withdrawn from bedrock almost anywhere it. the basin. Ground-water levels show no long-term trend since 1939, and although large fluctuations in water levels occur during each year, the ground-water reservoir at most places in the Ipswich River basin is replenished annually to its full capacity. During parts of most years potential recharge is unable to enter the already-saturated ground-water reservoirs, and most of this 'rejected recharge' enters streams as surface runoff. The chemical quality of both ground and surface water is generally satisfactory for most uses, although excessive concentrations of iron and manganese occur locally, and at places the hardness of the water is objectionable. The surface- and ground-water resources of the basin are closely related. Because most areas favorable for further development of ground water are adjacent to stream channels, large increases in the withdrawal of ground water during low-flow periods will result in reductions of streamflow. The magnitude of t
Form and stability of aluminum hydroxide complexes in dilute solution
Laboratory studies of solutions 4.53 x 10 -4 to 4.5 x 10 -5 molal (12.2-1.2 ppm) in aluminum, in 0.01 molal sodium perchlorate, were conducted to obtain information as to the probable behavior of aluminum in natural water. When the solutions were brought to pH 7.5-9.5 and allowed to stand for 24 hours, a precipitate was obtained which was virtually amorphous as shown by X-rays, and which had a solubility equivalent to that of boehmite. This precipitate had a hydrolysis constant (*Ks4) of 1.93 x 10 -13a. When solutions were allowed to stead at this pH range for 10 days, their precipitates gave the X-ray pattern of bayerite (*Ks4 = 1.11 > (10- 4). These hydrolysis constants were obtained at 25?C. and corrected to zero ionic strength and are in close agreement with other published values. The predominant dissolved form in this pH range is Al(OH) -4. Below neutral pH (7.0) the dissolved aluminum species consist of octahedral units in which each aluminum ion is surrounded by six water molecules or hydroxide ions. Single units such as Al(OH2)6 + 3 and AlOH(OH2)5+2 are most abundant below pH 5.0, and where the molar ratio (r) of combined hydroxide to total dissolved aluminum is low. When r is greater than 1.0, polymerization of the octahedral units occurs. When r is between 2.0 and 3.0, solutions aged for 10 days or more contained colloidal particles between 0.10 and 0.45 ? in diameter. Particles whose diameters were greater than 0.10 ? were identified by X-ray diffraction as gibbsite. Particles smaller than 0.10 ? were also present and were shown by means of the electron microscope to have a hexagonal crystal pattern. Structured material consisting of sheets of coalesced six-membered rings of aluminum ions held together by double OH bridges has a distinctive kinetic behavior. This property was used to determine amounts of polymerized material in solutions having r between 1.0 and 3.0 after aging times ranging from a few hours to more than 4 months. Aging increased the size and orderliness of the polymeric aggregates and was accompanied by a decrease in the pH of the solution. The kinetic experiments and stoichiometric data for solutions aged for long periods provided a means of determining activities of polymerized aluminum. From these values the solubility product for microcrystalline gibbsite was determined to be 2.24 x 10 -3, and its free energy of formation, -? 272.3 0.4 kcal per mole. Where polymerization was observed, the process did not stop with small polynuclear complexes containing a few aluminum ions, but proceeded with aging until macromolecules or colloidal-sized particles were formed.
Graphical methods for studies of aqueous aluminum hydroxide, fluoride, and sulfate complexes
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Solubility of aluminum in the presence of hydroxide, fluoride, and sulfate
The total concentration of aqueous dissolved species of aluminum that will be present in equilibrium with microcrystalline gibbsite at various levels of complexing ligand concentration are shown graphically. The graphs can be used to estimate aluminum solubility, at 25?C and 1 atmosphere total pressure, when the pH of the solution, its ionic strength, and the total sulfate and fluoride concentrations are known. The standard free energy of formation of cryolite calculated from solubility experiments is --745.4 ? 1.0 kcal per mole at 25?C. Diagrams are included showing the solubility of cryolite in terms of aluminum, fluoride, and sodium concentrations. The stability fields of cryolite and microcrystalline gibbsite and their solubilities also are shown on pH-[F] diagrams.
Effect of aging on aluminum hydroxide complexes in dilute aqueous solutions
Aqueous aluminum solutions containing 4?10 -5 mole/liter aluminum and a constant total ionic strength of 10 -2, but with varying ratios of hydroxide to aluminum (OH:Al), were prepared. Progress of these solutions toward equilibrium conditions over aging periods of as much as 2 years was studied by determining the composition and pH of the solutions at various time intervals. The solutions, after mixing, were supersaturated with respect to both crystalline and amorphous forms of aluminum oxides and aluminum hydroxides. The compositions of the solutions were determined by use of a timed colorimetric analytical procedure which allowed the estimation of three separate forms of aluminum that have been designated Al a, Al b, and Al c. Form Al a appeared to be composed of monomeric species such as Al(H20)6+3, Al(OH)(H20)5+2, Al(OH)2(H20)4 +I and Al(OH)4-. Form Al b was polynuclear material containing perhaps 20-400 aluminum atoms per structure. It appeared to be a metastable material. Form Al c was composed of relatively large, microcrystalline, clearly solid AI(OH)3 particles. For each OH :Al ratio, the concentration of Al a remained constant with aging time, Al b decreased, and Al c increased. It appeared that Al b particles were increasing in size and ultimately were converted to Al c particles. After a few weeks' aging, Al c particles had the structure of gibbsite. In all solutions, equilibrium was only very slowly achieved, and the time required depended on the OH:Al ratio and how rapidly the solution was initially prepared (mixing time). Lower ratios caused a slower approach to equilibrium; sometimes equilibrium was not achieved even after several years' aging. The more slowly base was initially added (to obtain the proper OH:Al ratio), the more slowly was equilibrium approached. Ultimate equilibrium values of dissolved aluminum concentration and pH were consistent with known thermodynamic data on monomeric aluminum species. From data determined during the aging study and by considering Al b material to consist of extremely small solid gibbsite particles, it was possible to estimate the Gibbs free energy of the (001) crystal face (?F, the gibbsite 'face') and the. Gibbs free energy of the (110) and (100) crystal faces (?E, the gibbsite 'edge') of gibbsite in equilibrium with its saturated solution. These values were: ?F=1404 ? 24 ergs/cm 2, and ?E = 483 ?-84 ergs/cm 2.
Chemical interactions of aluminum with aqueous silica at 25 degrees Celsius
Solutions containing from 10 -5 to 10 -2 moles per liter of aluminum and dissolved silica in various ratios were aged at pH levels between 4 and 10 at 25?C. A colloidal amorphous product having the composition of halloysite was produced in most solutions. It had a consistent and reversible equilibrium solubility equivalent to a standard free energy of formation of -8974 ? 1.0 kcal per mole for the formula A12Si2O5(OH)4. Some aging times were longer than 4 years, but most solutions gave consistent solubilities after only a few months of aging. Where silica concentrations were below about 10 -4 molar, microcrystalline gibbsite was formed below pH 6.0 and crystalline bayerite above pH 7.0, but only after much longer aging than was required for crystallization in silica-free solutions. Electron micrographs and diffraction patterns of the synthesized material indicate some crystallinity in the aluminosilicate, but no X-ray diffraction patterns could be obtained even in the material aged 4 years. Solubility relationships for solutions containing fluoride as well as silica and aluminum are explainable by using cryolite stabilities determined in previous work. Aluminum contents of 51 samples of water analyzed for other purposes are in reasonable agreement with the assumption of equilibrium with amorphous clay mineral species similar to the material synthesized in this work. Solubility calculations are summarized graphically for solutions of ionic strength of 0.01 and 0.10.
Reactions of aqueous aluminum species at mineral surfaces
Aqueous aluminum solutions containing 4.5 ? 10 4 molar aluminum in 0.01 molar NaC104 were partly neutralized with NaOH to give OH:A1 mole ratios from 1.40 to 2.76. Measured amounts of montmorillonite, kaolinite, volcanic ash, or feldspathic sand were added to provide an area of inert surface. Reactions that occurred during 100 days of aging were compared with those in similar solutions without added surfaces, studied in earlier work. Adsorption of monomeric species Al(H20)6+3, AlOH(H2O)5+2, and Al(OH)2(H2O 4? on the added surfaces follows a cation exchange mass law equilibrium model, and adsorption is essentially complete in 1 hour. Only minor changes in monomeric aluminum species occurred after that. Rapid adsorption of polynuclear aluminum hydroxide species also occurs and follows the pattern of the Langmuir adsorption isotherm. In the absence of surfaces, the polynuclear ions slowly increase in size and become microcrystalline gibbsite during aging. Electron micrographs showed microcrystalline gibbsite was present or surfaces after aging only 2 days. However, the analytical data suggest this material must have been adsorbed after it had already attained a near-crystalline state. Adsorbed polynuclear aluminum hydroxide species were not extensively converted to microcrystalline gibbsite during 100 days of aging.
Effects of organic solutes on chemical reactions of aluminum
Concentrations of organic matter in the general range of 1-10 milligrams per litre organic carbon are common in natural water, and many naturally occurrin7 organic compounds form aluminum complexes. The aluminum concentrations in near-neutral pH solutions may be 10-100 times higher than the values predicted from solubility data if formation of such organic complexes is ignored. The processes of polymerization of aluminum hydroxide and precipitation of gibbsite are inhibited by the presence of the organic flavone compound quercetin in concentrations as low as 10 x -5.3 mole per litre. Quercetin forms a complex, with a probable molar ratio of 1:2 aluminum to quercetin, that has a formation constant (f12) of about 10 12. A complex with a higher aluminum-quercetin ratio also was observed, but this material tends to evolve into a compound of low solubility that removes aluminum from solution. In the presence of both dissolved aluminum and aqueous silica, low concentrations of quercetin improved the yield of crystallized kaolinite and halloysite. Small amounts of well-shaped kaolinite and halloysite crystals were identified by electron microscopy in solutions with pH's in the range 6.5-8.5 after 155 days aging in one experimer t and 481 days aging in a repeated experiment. The bulk of the precipitated material was amorphous to X-rays, and crystalline material was too small a proportion of the total to give identifiable X-ray diffraction peaks. The precipitates had aluminum-silicon ratios near 1, and their solubility corresponded to that found by Hem, Roberson, Lind, and Polzer (1973) for similar aluminosilicate precipitated in the absence of organic solutes. The improved yield of crystalline material obtained in the presence of quercetin probably is the result of the influence of the organic compound on the aluminum hydroxide polymerization process. Natural water containing color imparted by organic material tends to be higher in aluminum than would be predicted by pH, silica concentrations, and solubility data for inorganic aluminum species.