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At least 1,459 records · Page 81Linked to original sources
USGS2000

Forces dictating colloidal interactions between viruses and soil

The fate and transport of viruses in soil and aquatic environments were studied with respect to the different forces involved in the process of sorption of these viruses on soil particles. In accordance with the classical DLVO theory, we have calculated the repulsive electrostatic forces and the attractive van der Waals forces. Bacteriophages have been used as model sorbates, while different clays have been used as model sorbents. The equations used for the determination of the change in free energy for the process (Δ G ) takes into consideration the roughness of the sorbent surfaces. Results indicate that attractive van der Waals forces predominate the process of sorption of the selected bacteriophages on clays.

Chemosphere↗
USGS2003

Modeling radium and radon transport through soil and vegetation

A one-dimensional flow and transport model was developed to describe the movement of two fluid phases, gas and water, within a porous medium and the transport of 226Ra and 222Rn within and between these two phases. Included in this model is the vegetative uptake of water and aqueous 226Ra and 222Rn that can be extracted from the soil via the transpiration stream. The mathematical model is formulated through a set of phase balance equations and a set of species balance equations. Mass exchange, sink terms and the dependence of physical properties upon phase composition couple the two sets of equations. Numerical solution of each set, with iteration between the sets, is carried out leading to a set-iterative compositional model. The Petrov-Galerkin finite element approach is used to allow for upstream weighting if required for a given simulation. Mass lumping improves solution convergence and stability behavior. The resulting numerical model was applied to four problems and was found to produce accurate, mass conservative solutions when compared to published experimental and numerical results and theoretical column experiments. Preliminary results suggest that the model can be used as an investigative tool to determine the feasibility of phytoremediating radium and radon-contaminated soil. ?? 2003 Elsevier Science B.V. All rights reserved.

Journal of Contaminant Hydrology↗
USGS2026

Rethinking seed selection based on climate matching during restoration: Geography, soils and climate explain species-specific mortality

Implicit in the construction of seed transfer zones (STZs) are the assumptions that plant populations are adapted to their home climates and that transferring native seed across climate gradients risks maladaptation and poor performance. However, plants are adapted to multiple aspects of their environments that are often excluded from STZ development. Here, we used models integrating geographic distance, climate distance and soil metrics to predict plant mortality in an experimental garden for three restoration-relevant species in the southwestern United States: Bouteloua curtipendula , Heterotheca villosa and Sporobolus cryptandrus . Overall, climate distance explained mortality better than geographic distance, but increasing climate distance was not consistently associated with higher mortality. In contrast, mortality always increased with geographic distance. Species responded idiosyncratically to environmental gradients such as soil texture and pH, indicating that incorporating site-specific variables beyond climate can improve predictions of survival. Finally, seed sources of H. villosa from hotter, drier climates exhibited improved survival during abnormally hot, dry conditions at the experimental site, whereas no consistent pattern emerged for the two grass species. Collectively, our results suggest that seeding strategies extending beyond climate matching alone may better support restoration outcomes when species-specific guidance is unavailable.

Arizona, Colorado, New Mexico, Utah↗
USGS2017

Late Quaternary loess and soils on uplands in the Canyonlands and Mesa Verde areas, Utah and Colorado

Thin loess deposits on the uplands of the southeastern Colorado Plateau have previously not been well studied. We sampled deposits and soils from trenches on Hatch Point (HP) mesa near Canyonlands National Park, Utah, and from two outcrops in Mesa Verde National Park, Colorado. At HP, the oldest buried unit yielded 2 optically stimulated luminescence (OSL) ages of 10,370 and 7555 yr; the middle unit yielded 10 OSL ages from 6220 to 1385 yr; and the youngest unit had a single age of 1740 yr. At Mesa Verde (MV), three loess units are preserved in the two outcrops we examined; 6 OSL ages range from 51 to 17 ka. At least one buried soil is present between two units with ages of about 50 and 40 ka. The ages of the loess units in both study areas correspond well with OSL-dated dune sands in Canyonlands National Park and with dune sands on Black Mesa, Arizona. Particle-size distribution combined with chemical and magnetic data indicate that HP loess was derived mostly from nearby sandstone sources with a small component of far-traveled atmospheric dust, whereas MV loess was sourced both from the nearby sandstone and the San Juan River and its tributaries.

Colorado, Utah↗
USGS2021

Exposure and transport of alkaloids and phytoestrogens from soybeans to agricultural soils and streams in the Midwestern United States

Phytotoxins are naturally produced toxins with potencies similar/higher than many anthropogenic micropollutants. Nevertheless, little is known regarding their environmental fate and off-field transport to streams. To fill this research gap, a network of six basins in the Midwestern United States with substantial soybean production was selected for the study. Stream water ( n = 110), soybean plant tissues ( n = 8), and soil samples ( n = 16) were analyzed for 12 phytotoxins (5 alkaloids and 7 phytoestrogens) and 2 widely used herbicides (atrazine and metolachlor). Overall, at least 1 phytotoxin was detected in 82% of the samples, with as many as 11 phytotoxins detected in a single sample (median = 5), with a concentration range from below detection to 37 and 68 ng/L for alkaloids and phytoestrogens, respectively. In contrast, the herbicides were ubiquitously detected at substantially higher concentrations (atrazine: 99% and metolachlor: 83%; the concentrations range from below detection to 150 and 410 ng/L, respectively). There was an apparent seasonal pattern for phytotoxins, where occurrence prior to and during harvest season (September to November) and during the snow melt season (March) was higher than that in December–January. Runoff events increased phytotoxin and herbicide concentrations compared to those in base-flow conditions. Phytotoxin plant concentrations were orders of magnitude higher compared to those measured in soil and streams. These results demonstrate the potential exposure of aquatic and terrestrial organisms to soybean-derived phytotoxins.

Illinois, Indiana, Iowa, Minnesota, Missouri, Sout↗
USGS2007

Chemical quality of depositional sediments and associated soils in New Orleans and the Louisiana peninsula following Hurricane Katrina

Hurricane Katrina made landfall on the Louisiana peninsula south of New Orleans on Aug 29, 2005. The resulting storm surge caused numerous levy breaches in the parishes of New Orleans as well as on the Louisiana peninsula. This study was conducted to determine the concentrations of inorganic and organic constituents in sediments and associated soils in New Orleans parishes and the Louisiana peninsula after the floodwaters had been removed and/or receded following Hurricane Katrina. A total of 46 sediment and soil samples were analyzed that were collected throughout New Orleans and the Louisiana peninsula. Approximately 20% of the sediment samples were analyzed, including shallow sediment samples from locations that included the top and beneath automobiles, in residential and commercial areas, and near refineries. Gasoline constituents, pesticides, and leachable heavy metals were analyzed using headspace gas chromatography/mass spectrometry (GC/MS), organic extraction GC/MS, and inductively coupled plasma/mass spectrometry, respectively. A significant number of samples had leachable As and Pb concentrations in excess of drinking water standards. The remaining metals analyzed (i.e., Cd, Cr, Cu, Hg, and V) generally had much lower leachable levels. Of the gasoline constituents, only benzene was observed above the limit of detection (of 5 ??g/kg), with no samples observed as being above the method detection limits of 10 ??g/kg. For the 18 pesticides analyzed, most were in the nondetectable range and all were in trace amounts that were orders of magnitude below regulatory guidelines. ?? 2007 American Chemical Society.

Environmental Science & Technology↗
USGS2002

Presence of organoarsenicals used in cotton production in agricultural water and soil of the Southern United States

Arsenicals have been used extensively in agriculture in the United States as insecticides and herbicides. Mono- and disodium methylarsonate and dimethylarsinic acid are organoarsenicals used to control weeds in cotton fields and as defoliation agents applied prior to cotton harvesting. Because the toxicity of most organoarsenicals is less than that of inorganic arsenic species, the introduction of these compounds into the environment might seem benign. However, biotic and abiotic degradation reactions can produce more problematic inorganic forms of arsenic, such as arsenite [As(III)] and arsenate [As(V)]. This study investigates the occurrences of these compounds in samples of soil and associated surface and groundwaters. Preliminary results show that surface water samples from cotton-producing areas have elevated concentrations of methylarsenic species (>10 ??g of As/L) compared to background areas (<1 ??g of As/L). Species transformations also occur between surface waters and adjacent soils and groundwaters, which also contain elevated arsenic. The data indicate that point sources of arsenic related to agriculture might be responsible for increased arsenic concentrations in local irrigation wells, although the elevated concentrations did not exceed the new (2002) arsenic maximum contaminant level of 10 ??g/L in any of the wells sampled thus far.

Journal of Agricultural and Food Chemistry↗
USGS2003

Global carbon sequestration in tidal, saline wetland soils

Wetlands represent the largest component of the terrestrial biological carbon pool and thus play an important role in global carbon cycles. Most global carbon budgets, however, have focused on dry land ecosystems that extend over large areas and have not accounted for the many small, scattered carbon -storing ecosystems such as tidal saline wetlands. We compiled data for 154 sites in mangroves and salt marshes from the western and eastern Atlantic and Pacific coasts, as well as the Indian Ocean, Mediterranean Ocean, and Gulf of Mexico. The set of sites spans a latitudinal range from 22.4°S in the Indian Ocean to 55.5°N in the northeastern Atlantic. The average soil carbon density of mangrove swamps (0.055 ± 0.004 g cm -3 ) is significantly higher than the salt marsh average (0.039 ± 0.003 g cm -3 ). Soil carbon density in mangrove swamps and Spartina patens marshes declines with increasing average annual temperature, probably due to increased decay rates at higher temperatures. In contrast, carbon sequestration rates were not significantly different between mangrove swamps and salt marshes. Variability in sediment accumulation rates within marshes is a major control of carbon sequestration rates masking any relationship with climatic parameters. Globally, these combined wetlands store at least 44.6 Tg C yr -1 and probably more, as detailed areal inventories are not available for salt marshes in China and South America. Much attention has been given to the role of freshwater wetlands, particularly northern peatlands, as carbon sinks. In contrast to peatlands, salt marshes and mangroves release negligible amounts of greenhouse gases and store more carbon per unit area.

Global Biogeochemical Cycles↗
USGS2005

Soil organic carbon dynamics as related to land use history in the northwestern Great Plains

Strategies for mitigating the global greenhouse effect must account for soil organic carbon (SOC) dynamics at both spatial and temporal scales, which is usually challenging owing to limitations in data and approach. This study was conducted to characterize the SOC dynamics associated with land use change history in the northwestern Great Plains ecoregion. A sampling framework (40 sample blocks of 10 × 10 km 2 randomly located in the ecoregion) and the General Ensemble Biogeochemical Modeling System (GEMS) were used to quantify the spatial and temporal variability in the SOC stock from 1972 to 2001. Results indicate that C source and sink areas coexisted within the ecoregion, and the SOC stock in the upper 20-cm depth increased by 3.93 Mg ha −1 over the 29 years. About 17.5% of the area was evaluated as a C source at 122 kg C ha −1 yr −1 . The spatial variability of SOC stock was attributed to the dynamics of both slow and passive fractions, while the temporal variation depended on the slow fraction only. The SOC change at the block scale was positively related to either grassland proportion or negatively related to cropland proportion. We concluded that the slow C pool determined whether soils behaved as sources or sinks of atmospheric CO 2 , but the strength depended on antecedent SOC contents, land cover type, and land use change history in the ecoregion.

Global Biogeochemical Cycles↗
USGS2010

Regional and grain size influences on the geochemistry of soil at Gusev Crater

Congruous with earlier work, Martian soil along the Spirit Rover's traverse at Gusev crater can be divided into three broad groups by size: fines (<150 μ m), sand, and a mix of various grain sizes. The key chemical observation is greater homogeneity in fines relative to the other two, consistent with regional‐ and global‐scale sampling of chemical compositions by finer particle sizes. The mix class is generally more heterogeneous as are samples from the Columbia Hills within each class. Variation in the trace element Ni is consistent with a CI contribution not exceeding 3%, while that of Ti is compatible with Fe‐Ti oxide enrichment not exceeding 3%. Physical mixing models are poorly supported. Among many potential binary and three‐component mixing models, only two show some consistency with the soil data: typical fines with the opaline Si end‐member identified at Home Plate and typical fines with sulfates (bearing a variable mix of Ca, Fe, and Mg cations). We also infer that binary mixing transcends classes, contrasting strongly with terrestrial sediments, and that mixing trends are consistent with significant nonmixing contributions, perhaps including localized chemical alteration. The decoupling between chemistry and grain size classes also suggests that processes linking composition with grain size, such as heavy mineral sorting, may have been minimal or absent entirely. The primary exception to this is the correlation between Cl and Si, Cl‐S, and Al‐Si, which is strongest in the fines class.

Journal of Geophysical Research E: Planets↗
USGS2011

Sources and physical processes responsible for OH/H2O in the lunarsoil as revealed by the Moon Mineralogy Mapper (M3)

Analysis of two absorption features near 3 μ m in the lunar reflectance spectrum, observed by the orbiting M 3 spectrometer and interpreted as being due to OH and H 2 O, is presented, and the results are used to discuss the processes producing these molecules. This analysis focuses on the dependence of the absorptions on lunar physical properties, including composition, illumination, latitude, and temperature. Solar wind proton-induced hydroxylation is proposed as the creation process, and its products could be a source for other reported types of hydrogen-rich material and water. The irregular and damaged fine-grained lunar soil seems especially adapted for trapping solar wind protons and forming OH owing to abundant dangling oxygen bonds. The M 3 data reveal that the strengths of the two absorptions are correlated and widespread, and both are correlated with lunar composition but in different ways. Feldspathic material seems richer in OH. These results seem to rule out water from the lunar interior and cometary infall as major sources. There appear to be correlations of apparent band strengths with time of day and lighting conditions. However, thermal emission from the Moon reduces the apparent strengths of the M 3 absorptions, and its removal is not yet completely successful. Further, many of the lunar physical properties are themselves intercorrelated, and so separating these dependencies on the absorptions is difficult, due to the incomplete M 3 data set. This process should also operate on other airless silicate surfaces, such as Mercury and Vesta, which will be visited by the Dawn spacecraft in mid-2011.

Journal of Geophysical Research E: Planets↗
USGS2011

In situ measurements of post-fire debris flows in southern California: Comparisons of the timing and magnitude of 24 debris-flow events with rainfall and soil moisture conditions

Debris flows often occur in burned steeplands of southern California, sometimes causing property damage and loss of life. In an effort to better understand the hydrologic controls on post-fire debris-flow initiation, timing and magnitude, we measured the flow stage, rainfall, channel bed pore fluid pressure and hillslope soil-moisture accompanying 24 debris flows recorded in five different watersheds burned in the 2009 Station and Jesusita Fires (San Gabriel and Santa Ynez Mountains). The measurements show substantial differences in debris-flow dynamics between sites and between sequential events at the same site. Despite these differences, the timing and magnitude of all events were consistently associated with local peaks in short duration (< = 30 min) rainfall intensity. Overall, debris-flow stage was best cross-correlated with time series of 5-min rainfall intensity, and lagged the rainfall by an average of just 5 min. An index of debris-flow volume was also best correlated with short-duration rainfall intensity, but found to be poorly correlated with storm cumulative rainfall and hillslope soil water content. Post-event observations of erosion and slope stability modeling suggest that the debris flows initiated primarily by processes related to surface water runoff, rather than shallow landslides. By identifying the storm characteristics most closely associated with post-fire debris flows, these measurements provide valuable guidance for warning operations and important constraints for developing and testing models of post-fire debris flows. copyright. 2011 by the American Geophysical Union.

Journal of Geophysical Research F: Earth Surface↗
USGS2025

Quantifying the effect of petrogenic carbon on SOC turnover for two Rocky Mountain soils: When are petrogenic carbon corrections required?

Petrogenic organic carbon (OC petro ), derived from sedimentary rocks, is an often overlooked and poorly quantified source of soil organic carbon (SOC), which may influence measured or modeled SOC composition, age, and stability. In this study, we exploited differences in thermochemical stability between OC petro and biogenic SOC (OC bio ) using stepped elemental analysis to quantify the fractional contribution of OC petro to total SOC (f petro ), and we conducted a sensitivity analysis to estimate the effects of OC petro on modeled SOC transit times and system ages. Specifically, we compared the effects of accounting for OC petro inputs in SOC turnover modeling (using SoilR) for two montane meadow soils that are underlain by Cretaceous Mancos Shale. At these sites, we estimate that OC petro comprises 7%–9% of the total SOC stock (f petro = 0.07–0.09). However, accounting for OC petro as a mixture of inert and passive C or as completely inert C had negligible effects on SOC transit times and system ages, suggesting that there is a threshold of OC petro content under which there is minimal effect on calculated SOC turnover. Based on our sensitivity analysis, we estimate this threshold to be f petro = 0.125, further supporting that the accurate calculation of OC petro remains an important factor in estimating SOC turnover.

Colorado↗
USGS2024

Stream nitrate dynamics driven primarily by discharge and watershed physical and soil characteristics at intensively monitored sites: Insights from deep learning

We developed a suite of models using deep learning to make hindcast predictions of the 7‐day average backward‐looking nitrate concentration at 46 predominantly agricultural sites across the midwestern and eastern United States. The models used daily observations of discharge and meteorological variables and watershed attributes describing anthropogenic modification to hydrology, nitrogen application, climate, groundwater, land use, watershed physiographic attributes, and soils. Across all sites, discharge and watershed soil and physiographic attributes showed a strong influence on model performance. Analysis of drivers across sites revealed considerable regional differences related to controlling processes such as groundwater contributions. We tested several ways to pool data across sites to develop accurate models and make the most effective use of available data. Single‐site models, in which models are trained and tested at a single location, showed generally strong predictive performance (median Kling‐Gupta Efficiency = 0.66), and accuracy at poorly performing sites could be improved by grouping sites with similar characteristics. Developing a single model for all sites reduced performance at several locations with distinct characteristics, suggesting that there is a threshold of dissimilarity beyond which more data does not improve the model. While many deep learning studies have shown that national or even global models can outperform local models, it is not clear that this is true for water quality constituents. This study demonstrates how data can be combined effectively, using deep learning to develop accurate and interpretable models of instream nitrate at sites where varying processes are responsible for changes in nitrate concentration.

Water Resources Research↗
USGS2025

Organic matter composition versus microbial source: Controls on carbon loss from fen wetland and permafrost soils

Wetland and permafrost soils contain some of Earth's largest reservoirs of organic carbon, and these stores are threatened by rapid warming across the Arctic. Nearly half of northern wetlands are affected by permafrost. As these ecosystems warm, the cycling of dissolved organic matter (DOM) and the opportunities for microbial degradation are changing. This is particularly evident as the relationship between wetland and permafrost DOM dynamics evolves, especially with the introduction of permafrost-derived DOM into wetland environments. Thus, understanding the interplay of DOM composition and microbial communities from wetlands and permafrost is critical to predicting the impact of released carbon on global carbon cycling. As little is understood about the interactions between wetland active layer and permafrost-derived sources as they intermingle, we conducted experimental bioincubations of mixtures of DOM and microbial communities from two fen wetland depths (shallow: 0–15 cm, and deep: 15–30 cm) and two ages of permafrost soil (Holocene and Pleistocene). We found that the source of microbial inoculum was not a significant driver of dissolved organic carbon (DOC) degradation across treatments; rather, DOM source and specifically, DOM molecular composition, controlled the rate of DOC loss over 100 days of bioincubations. DOC loss across all treatments was negatively correlated with modified aromaticity index, O/C, and the relative abundance of condensed aromatic and polyphenolic formula, and positively correlated with H/C and the relative abundance of aliphatic and peptide-like formula. Pleistocene permafrost-derived DOC exhibited ∼70% loss during the bioincubation driven by its initial molecular-level composition, highlighting its high bioavailability irrespective of microbial source.

Alaska↗
USGS1998

Three-year decline of magmatic CO2 emissions from soils of a Mammoth Mountain tree kill: Horseshoe Lake, CA, 1995-1997

We used the closed chamber method to measure soil CO 2 efflux over a three-year period at the Horseshoe Lake tree kill (HLTK)—the largest tree kill on Mammoth Mountain in central eastern California. Efflux contour maps show a significant decline in the areas and rates of CO 2 emission from 1995 to 1997. The emission rate fell from 350 t d −1 (metric tons per day) in 1995 to 130 t d −1 in 1997. The trend suggests a return to background soil CO 2 efflux levels by early to mid 1999 and may reflect exhaustion of CO 2 in a deep reservoir of accumulated gas and/or mechanical closure or sealing of fault conduits transmitting gas to the surface. However, emissions rose to 220 t d −1 on 23 September 1997 at the onset of a degassing event that lasted until 5 December 1997. Recent reservoir recharge and/or extension-enhanced gas flow may have caused the degassing event.

Geophysical Research Letters↗
USGS2014

The displacement of calibration curves for electrical soil‐moisture units

Electrical‐resistance blocks were calibrated for use in soil‐moisture studies at Seabrook, N.J. Curves from successive laboratory calibrations are positioned differently because of the effects of chemical quality of the water used, drying techniques and other factors. Furthermore, the laboratory curves are displaced from the field calibration curves because of the difficulty of establishing moisture equilibrium in laboratory samples. It is believed that the results demonstrate the general unreliability of laboratory calibrations when compared with field calibrations of soil‐moisture blocks

Eos, Transactions, American Geophysical Union↗
USGS2017

Climate change reduces extent of temperate drylands and intensifies drought in deep soils

Drylands cover 40% of the global terrestrial surface and provide important ecosystem services. While drylands as a whole are expected to increase in extent and aridity in coming decades, temperature and precipitation forecasts vary by latitude and geographic region suggesting different trajectories for tropical, subtropical, and temperate drylands. Uncertainty in the future of tropical and subtropical drylands is well constrained, whereas soil moisture and ecological droughts, which drive vegetation productivity and composition, remain poorly understood in temperate drylands. Here we show that, over the twenty first century, temperate drylands may contract by a third, primarily converting to subtropical drylands, and that deep soil layers could be increasingly dry during the growing season. These changes imply major shifts in vegetation and ecosystem service delivery. Our results illustrate the importance of appropriate drought measures and, as a global study that focuses on temperate drylands, highlight a distinct fate for these highly populated areas.

Nature Communications↗