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USGS2025

Exploring the news media and scientific conversations around water quality in a water-rich basin of the United States

Community concerns about water availability vary depending on local economic, regulatory, environmental, and ecological considerations. In water-rich basins, water quality is often the focus of community concerns. As such, understanding community priorities in the context of water quality is crucial for informing scientists working in water-rich basins. In this work, we compiled over 6,500 local news articles (public discourse) and 190 scientific abstracts (scientific discourse) related to water-quality issues in the water-rich Illinois River Basin (ILRB) published between 2018 and 2022. We applied a Structural Topic Model (STM) to identify key water-quality topics within both datasets and explore the variability of newspaper topics geographically across the basin. Prevalent topics in both the public (local news articles) and scientific (abstracts) discourses were agriculture, drinking water quality, PFAS (per- and polyfluoroalkyl substances), and river ecosystem/fish. Topics exclusive to public discourse included water infrastructure, community development, and public water supply, while the scientific discourse focused more heavily on a wider range of agricultural issues. Furthermore, the public discourse varied geographically across the basin. Some topics are correlated with land use or urban/rural divides within the basin, and the frequency of many topics clearly varied across state (political) boundaries. Understanding and quantifying public and scientific discourses related to water-quality are important for scientists and water managers working in the basin to improve communication of critical science to the public.

Illinois, Indiana, Michigan, Wisconsin↗
USGS2022

Science mission requirements for a globally ranging, riserless drilling vessel for U.S. Scientific Ocean Drilling

Through the collection and analysis of shallow and deep subseafloor sediments, rocks, fluids, and life, scientific ocean drilling has enriched our understanding of the complex Earth system. Among other achievements, scientific ocean drilling has documented the history of Earth’s climate, the waxing and waning of polar ice sheets, the past changes in ocean and atmospheric circulation, the existence and function of microbial life in the subseafloor, the compositional variations in Earth’s crust and underlying mantle, and the physical and chemical processes acting at subduction zones, including those associated with tsunamigenic earthquakes. Over the decades, more than 12,000 articles that depend on analyses of scientific ocean drilling samples and geophysical data have been published, many detailing breakthrough contributions to global knowledge about the Earth system. Approximately 45% of these publications were led by U.S.-affiliated authors (International Ocean Discovery Program Publication Services, 2021). Since the mid-1980s, the workhorse of this multidisciplinary, international research effort has been the riserless D/V JOIDES Resolution, operated by Texas A&M University with funding from the U.S. National Science Foundation (NSF). D/V JOIDES Resolution has conducted the vast majority of scientific ocean drilling expeditions and collected most of the scientific cores over that period, including 82% of the expeditions and 93% of the cores in the last decade alone, despite being one of three platforms that is operated within the International Ocean Discovery Program. However, D/V JOIDES Resolution is approaching the end of its useful life. With a strong commitment to continue scientific ocean drilling beyond the end of the current phase, the community developed a document outlining the research frontiers that should be pursued. Exploring Earth by Scientific Ocean Drilling: 2050 Science Framework (Koppers and Coggon, 2020) describes seven scientific strategic objectives that focus on understanding interconnections within the Earth system and five flagship initiatives that integrate these objectives into long-term research efforts that address issues facing society. Additional elements in the 2050 Science Framework, including STEM education, workforce development, technology development, and innovative applications of data analytics, will advance the goals of scientific ocean drilling. Addressing the 2050 Science Framework also requires building partnerships with allied U.S. and international science programs and strengthening existing ones. To implement a significant portion of the 2050 Science Framework, the U.S. scientific community seeks to lease or acquire a newly built, globally ranging, state-of-the art, riserless drilling vessel. The many and varied technical and human resources requirements for successful accomplishment of scientific and educational goals summarized in this document and described in detail in the 2050 Science Framework require broad community input and careful consideration. Following receipt of NSF’s formal Request for Assistance to the United States Science Support Program (USSSP), the U.S. scientific ocean drilling community conducted a one-year exercise to identify its national scientific needs and priorities in order to determine the Science Mission Requirements (SMRs) presented here. This community effort included: (1) a U.S. community-wide survey to identify the specific operational and technical capabilities critical to addressing science in the 2050 Science Framework; (2) a series of online workshops focusing on critical capabilities identified by the survey; and (3) a large in-person workshop to synthesize the results of the survey and the virtual workshops (Appendix 1). The approach was designed to reach as many participants as possible. Overall, 278 survey responses were received from U.S. community members, representing 104 unique institutions from 39 states and the District of Columbia, and 137 unique individuals participated in the workshops (Appendix 2). The results of this effort comprise two classes of SMRs: Foundational Science Mission Requirements and Primary Science Mission Requirements. Foundational SMRs define minimum criteria for a new riserless drilling vessel that can address significant portions of the 2050 Science Framework. Primary SMRs build upon the Foundational SMRs and will create more robust science opportunities and data collection capabilities, will increase progress in addressing the 2050 Science Framework objectives, and will provide more real-time ship-to-shore interaction to improve science productivity, engagement, and outreach. Modern safety and environmental standards, including meeting standards to access protected waters such as exclusive economic zones, extended continental shelves, or high latitudes, while being cognizant of the vessel’s environmental footprint. Safe and efficient operations in global locations and in water depths from 70 m to 6000+ m, with total drill string length of at least 7000 m. High-quality core and data collection from a range of key subseafloor environments. Advanced heave compensation, dynamic positioning, and drill pipe stability. Modern mud and cement/casing systems. Critical onboard measurements for safety, operational decision-making, documentation of ephemeral properties, mission-specific science, and long-term science goals that extend beyond a single expedition. Designated and appropriate space for sample and data preservation. Highly skilled onboard personnel, including technical staff for curation and core handling; support for safety, time-sensitive, and critical shipboard measurements; computer support; equipment and instrument repair; application support; and data assurance. Primary Science Mission Requirements include: Flexible shipboard space for laboratories and on deck to ensure safe, successful implementation of diverse science objectives and operations. Minimizing contamination of recovered samples. Over-the-side capabilities for science-supporting technology (e.g., remotely operated vehicles, water- column sampling, sediment-water interface sampling). Downhole logging and measurements. Expanded borehole observatory capabilities. Reliable and consistent ship-to-shore communications. NSF’s investment in a new globally ranging, riserless drilling vessel will have a powerful economic multiplier effect, including the infusion of additional science support funds in the United States for training and research, the development of new technologies and tools, and the associated scientific and technical workforce development. The skills and knowledge gained through scientific ocean drilling are translatable to careers in fields such as sustainable energy development (e.g., geothermal and offshore wind), carbon sequestration, data management and cyberinfrastructure, biotechnology, communications, science education, policy, hazard mitigation, and environmental management. The United States is a leader in a well-established and internationally collaborative scientific ocean drilling community. A modern, globally ranging, riserless drilling vessel will allow the United States to expand its leadership position, address broad scientific questions that current capabilities preclude, and cultivate equitable international, multidisciplinary collaborations that will ensure scientific ocean drilling’s future success.

Report↗
USGS2014

Reflections on a vision for integrated research and monitoring after 15 years

In May of 1998, Owen Bricker and his co-author Michael Ruggiero introduced a conceptual design for integrating the Nation’s environmental research and monitoring programs. The Framework for Integrated Monitoring and Related Research was an organizing strategy for relating data collected by various programs, at multiple spatial and temporal scales, and by multiple science disciplines to solve complex ecological issues that individual research or monitoring programs were not designed to address. The concept nested existing intensive monitoring and research stations within national and regional surveys, remotely sensed data, and inventories to produce a collaborative program for multi-scale, multi-network integrated environmental monitoring and research. Analyses of gaps in data needed for specific issues would drive decisions on network improvements or enhancements. Data contributions to the Framework from existing networks would help indicate critical research and monitoring programs to protect during budget reductions. Significant progress has been made since 1998 on refining the Framework strategy. Methods and models for projecting scientific information across spatial and temporal scales have been improved, and a few regional pilots of multi-scale data-integration concepts have been attempted. The links between science and decision-making are also slowly improving and being incorporated into science practice. Experiments with the Framework strategy since 1998 have revealed the foundational elements essential to its successful implementation, such as defining core measurements, establishing standards of data collection and management, integrating research and long-term monitoring, and describing baseline ecological conditions. They have also shown us the remaining challenges to establishing the Framework concept: protecting and enhancing critical long-term monitoring, filling gaps in measurement methods, improving science for decision support, and integrating the disparate integrated science efforts now underway. In the 15 years since the Bricker and Ruggiero (Ecol Appl 8(2):326–329, 1998) paper challenged us with a new paradigm for bringing sound and comprehensive science to environmental decisions, the scientific community can take pride in the progress that has been made, while also taking stock of the challenges ahead for completing the Framework vision.

Aquatic Geochemistry↗
USGS2022

Flow–recruitment relationships for Shoal Chub and implications for managing environmental flows

Objective Regulation of river flow regimes by dams and diversions impacts aquatic biota and ecosystems globally. However, our understanding of the ecological consequences of flow alteration and ecological benefits of flow restoration lags behind our ability to manipulate flows, and there is a need for broader development of flow–ecology relationships. Approaches for establishing flow–ecology relationships have recently shifted away from state-based methods that analyze snapshots of ecological conditions and towards rate-based methods focused on mechanisms that link hydrology with dynamics of important ecological components and processes. Methods We used a rate-based approach to validate environmental flow standards developed for the lower Brazos River, Texas, by analyzing the relationship between flow regime components and recruitment strength of imperiled Shoal Chub Macrhybopsis hyostoma , a fluvial specialist and pelagic-broadcast-spawning fish. We collected 254 age-0 Shoal Chub (9–40 mm total length), extracted their otoliths to estimate age in days, and used a generalized additive model to regress the number of captured recruits that hatched on a calendar date against flow regime metrics, such as pulse magnitude, flow rate of change, and pulse timing in relation to environmental flow standards proposed by a science advisory committee (Brazos Basin and Bay Area Expert Science Team). Result The model revealed that flow magnitude, rate of change, and timing were all significant predictors that collectively explained 60% of variation in the recruitment strength index. Hindcasting for 1919–2020 showed a general reduction in recruitment strength following commencement of flow regulation in the lower Brazos River and revealed that high recruitment correlated with years in which most or all proposed flow tiers were attained, whereas low recruitment correlated with years when less than half of the targeted tiers were attained. Conclusion Our work represents an effective validation method for environmental flow recommendations and reveals specific flow regimes that benefit an imperiled fish species.

New Mexico, Texas↗
USGS2011

Partnership of Environmental Education and Research-A compilation of student research, 1999-2008

The U.S. Geological Survey (USGS) Tennessee Water Science Center and the College of Engineering and Technology at Tennessee State University developed a Partnership in Environmental Education and Research (PEER) to support environmental research at TSU and to expand the environmental research capabilities of the USGS in Tennessee. The PEER program is driven by the research needs to better define the occurrence, fate, and transport of contaminants in groundwater and surface water. Research in the PEER program has primarily focused on the transport and remediation of organic contamination in karst settings. Research conducted through the program has also expanded to a variety of media and settings. Research areas include contaminant occurrence and transport, natural and enhanced bioremediation, geochemical conditions in karst aquifers, mathematical modeling for contaminant transport and degradation, new methods to evaluate groundwater contamination, the resuspension of bacteria from sediment in streams, the use of bioluminescence and chemiluminescence to identify the presence of contaminants, and contaminant remediation in wetlands. The PEER program has increased research and education opportunities for students in the College of Engineering, Technology, and Computer Science and has provided students with experience in presenting the results of their research. Students in the program have participated in state, regional, national and international conferences with more than 140 presentations since 1998 and more than 40 student awards. The PEER program also supports TSU outreach activities and efforts to increase minority participation in environmental and earth science programs at the undergraduate and graduate levels. TSU students and USGS staff participate in the TSU summer programs for elementary and high school students to promote earth sciences. The 2007 summer camps included more than 130 students from 20 different States and Washington DC.

Tennessee↗
USGS2022

The researcher's lament: Why do they ignore my science?

The researcher's lament is shared by many environmental and conservation scientists who complain about the little support they receive for their research proposals during the review and selection process. Understandably, any hopes of having their anticipated scientific findings applied toward the formulation of environmental management decisions or natural resource policy action are shattered. They attribute this lack of endorsement to shortcomings and limitations among decision makers and proposal selection officials when, in many cases, the rejection of project proposals is often a function of a handful of self-inflicted failures by applied scientists who anchor themselves stubbornly to doomed approaches. Familiar deficiencies in their research proposals perpetuate the disconnect between the enterprise of science and real-world resource management challenges. Researchers themselves can affect conditions that turn up the appetite for their scientific endeavors as a more meaningful component of the decision-making process, namely, to stage and deliver science that is more readily "actionable." Perhaps it is time for them to consider a course correction to improve the viability of their actionable science proposals. A few basic steps may help rejigger the science planning process in this direction and, consequently, help avoid the researcher's lament. The likelihood of gaining support during the proposal review and award adjudication process, and securing practical application of scientific products, increases when the products are (1) the result of active engagement of researchers with decision makers; (2) better connected to social and political priorities; (3) clearly designed to inform specific management decisions; and (4) tailored to fit the needs of targeted end users. These considerations and activities exist beyond the comfort zone of many environmental or conservation scientists. Yet, those who adopt them will spend less time lamenting rejection and become more influential in the production of actionable knowledge.

Ecosphere↗
USGS2023

Critical stakeholder engagement: The road to actionable science Is paved with scientists’ good intentions

To help stakeholders such as planners, resource managers, policymakers, and decision makers address environmental challenges in the Anthropocene, scientists are increasingly creating actionable science—science that is useful, usable, and used. Critical physical geography encourages the engagement of stakeholders in the creation of scientific knowledge to conduct actionable science and produce outputs that are directly relevant to stakeholder plans, decisions, or actions. Many scientists, however, lack formal training in how to partner with stakeholders using effective and ethical practices. In this article, we use the core principles for ethical research of respect for persons, beneficence, and justice from the Belmont Report (1979) as a suggested framework to examine the perspectives of stakeholders engaged in climate adaptation science projects. We argue that this framework aligns with the principles of critical physical geography and provides guidance for scientists to make their research more actionable while placing necessary emphasis on ethical considerations. We also challenge scientists to consider the broader ethical implications of engaging with these partners.

Annals of the American Association of Geographers↗
USGS2013

Challenge theme 7: Information support for management of border security and environmental protection: Chapter 9 in United States-Mexican Borderlands: Facing tomorrow's challenges through USGS science

Historically, international borders were located far from the major political and economic capitals of their countries and rarely received adequate planning or infrastructure development. Today, as a result of global economics and increased movement of goods between nations, border regions play a much greater role in commerce, tourism, and transportation. For example, Mexico is the second largest destination for United States exports (Woodrow Wilson Center Mexico Institute, 2009). The rapid population and economic growth along the United States–Mexican border, undocumented human border crossings, and the unique natural diversity of resources in the Borderlands present challenges for border security and environmental protection. Assessing risks and implementing sustainable growth policies to protect the environment and quality of life greatly increase in complexity when the issues cross an international border, where social services, environmental regulations, lifestyles, and cultural beliefs are unique for each country. Shared airsheds, water and biological resources, national security issues, and disaster management needs require an integrated binational approach to assess risks and develop binational management strategies.

United States-Mexico Borderlands↗
USGS2006

Airport geomagnetic surveys in the United States

The Federal Aviation Administration (FAA) and the United States military have requirements for design, location, and construction of compass calibration pads (compass roses), these having been developed through collaboration with US Geological Survey (USGS) personnel. These requirements are detailed in the FAA Advisory Circular AC 150/5300-13, Appendix 4, and in various military documents, such as Handbook 1021/1, but the major requirement is that the range of declination measured within 75 meters of the center of a compass rose be less than or equal to 30 minutes of arc. The USGS Geomagnetism Group has developed specific methods for conducting a magnetic survey so that existing compass roses can be judged in terms of the needed standards and also that new sites can be evaluated for their suitability as potentially new compass roses. First, a preliminary survey is performed with a total-field magnetometer, with differences over the site area of less than 75nT being sufficient to warrant additional, more detailed surveying. Next, a number of survey points are established over the compass rose area and nearby, where declination is to be measured with an instrument capable of measuring declination to within 1 minute of arc, such as a Gurley transit magnetometer, DI Flux theodolite magnetometer, or Wild T-0. The data are corrected for diurnal and irregular effects of the magnetic field and declination is determined for each survey point, as well as declination range and average of the entire compass rose site. Altogether, a typical survey takes about four days to complete. ?? 2006 Springer.

NATO Security through Science Series C: Environmen↗
USGS2008

Grazed riparian management and stream channel response in southeastern Minnesota (USA) streams

The U.S. Department of Agriculture-Natural Resources Conservation Service has recommended domestic cattle grazing exclusion from riparian corridors for decades. This recommendation was based on a belief that domestic cattle grazing would typically destroy stream bank vegetation and in-channel habitat. Continuous grazing (CG) has caused adverse environmental damage, but along cohesive-sediment stream banks of disturbed catchments in southeastern Minnesota, short-duration grazing (SDG), a rotational grazing system, may offer a better riparian management practice than CG. Over 30 physical and biological metrics were gathered at 26 sites to evaluate differences between SDG, CG, and nongrazed sites (NG). Ordinations produced with nonmetric multidimensional scaling (NMS) indicated a gradient with a benthic macroinvertebrate index of biotic integrity (IBI) and riparian site management; low IBI scores associated with CG sites and higher IBI scores associated with NG sites. Nongrazed sites were associated with reduced soil compaction and higher bank stability, as measured by the Pfankuch stability index; whereas CG sites were associated with increased soil compaction and lower bank stability, SDG sites were intermediate. Bedrock geology influenced NMS results: sites with carbonate derived cobble were associated with more stable channels and higher IBI scores. Though current riparian grazing practices in southeastern Minnesota present pollution problems, short duration grazing could reduce sediment pollution if managed in an environmentally sustainable fashion that considers stream channel response. ?? 2008 Springer Science+Business Media, LLC.

Environmental Management↗
USGS2007

Local and regional factors affecting atmospheric mercury speciation at a remote location

Atmospheric concentrations of elemental (Hg0), reactive gaseous (RGM), and particulate (PHg) mercury were measured at two remote sites in the midwestern United States. Concurrent measurements of Hg0, PHg, and RGM obtained at Devil's Lake and Mt. Horeb, located approximately 65 km apart, showed that Hg0 and PHg concentrations were affected by regional, as well as local sources, while RGM was mainly impacted by local sources. Plumes reaching the Devil's Lake site from a nearby coal-fired power plant significantly impacted SO2 and RGM concentrations at Devil's Lake, but had little impact on Hg0. Our findings suggest that traditional modeling approaches to assess sources of mercury deposited that utilize source emissions and large-scale grids may not be sufficient to predict mercury deposition at sensitive locations due to the importance of small-scale sources and processes. We suggest the use of a receptor-based monitoring to better understand mercury source-receptor relationships.

Wisconsin↗
USGS2024

Climate change

Amphibian ecology and distribution are strongly correlated with climate. Regional patterns of amphibian biodiversity are intimately linked to temperature, evapotranspiration rate, and clines in humidity. While amphibians are and will continue to be adversely affected by recent and projected changes in climate, research suggests that adaptation may happen more slowly than the expected rate of environmental shifts. Here, we review conservation-relevant aspects of both realised and potential impacts of climate change, and outline options for amphibian conservation planning and management. Recent advances in our understanding of climate change impacts on amphibians have primarily stemmed from ecological modelling and direct assessment of climatic tolerances and dispersal capacities through physiological assays, landscape genetics, and dispersal tracking. Anthropogenic climate change has already altered amphibian assemblages and their impacts on ecosystem functioning and services. Because of known and hypothesised ecological tolerances, many amphibians might have reached or exceeded most limits in their ability to adapt to or tolerate further climate change, however the uncertainties are substantial. Implementation of conservation planning and action can help to forestall severe impacts of environmental shifts. Scientific research and science-based decision-making and policy development have already lagged; the current pace of conservation planning and action may not allow for effective identification of threats and mitigation. An increased response rate could help to avert further loss of amphibian biodiversity and decay of ecosystem services. The lack of basic field research in natural habitats continues to be an underlying challenge. We suggest priority areas of research to include the development of biologically realistic predictive models of amphibian response to climate change, field verification of model estimates and key parameters, population monitoring across multiple sites and taxa, and a combination of efforts within and across ecosystems to understand how impacts of climate change can be better mitigated.

Book chapter↗
USGS2012

Environmental setting of Lake Mead National Recreation Area: Chapter 2 in A synthesis of aquatic science for management of Lakes Mead and Mohave

Lakes Mead and Mohave provide opportunities for millions of regional, national, and international visitors to enjoy a wide array of water-based recreation in a spectacular desert setting. The national significance of the site’s recreational opportunities and scientific values led to its designation as the nation’s first National Recreation Area in 1964. The stark contrast of the deep blue lakes with spacious open water basins against a backdrop of mountain and canyon scenery creates a diversity of landscapes inviting recreation from the active to the contemplative (Maxon, 2009). The quality of the setting as a backdrop for the recreational experience has resulted in designation of approximately 200,000 acres of lands surrounding the lakes as wilderness (National Park Service, 2005).

Circular↗
USGS1999

USGS Science for Restoration of South Florida: The South Florida Ecosystem Program

As land and resource managers see the value of their resources diminish, and the public watches the environments they knew as children become degraded, there are increasing calls to restore what has been lost, or to build productive ecosystems that will be healthy and sustainable under the conditions of human use. The U.S. Geological Survey's (USGS) Placed-Based Studies Program was established to provide sound science for resource managers in critical ecosystems such as South Florida (fig. 1). The program, which began in south Florida in 1995, provides relevant information, high-quality data, and models to support decisions for ecosystem restoration and management. The program applies multi- and interdisciplinary science to address regional and subregional environmental resources issues.

Florida↗
USGS2005

Health-Based Screening Levels and their Application to Water-Quality Data

To supplement existing Federal drinking-water standards and guidelines, thereby providing a basis for a more comprehensive evaluation of contaminant-occurrence data in a human-health context, USGS began a collaborative project in 1998 with USEPA, the New Jersey Department of Environmental Protection, and the Oregon Health & Science University to calculate non-enforceable health-based screening levels. Screening levels were calculated for contaminants that do not have Maximum Contaminant Level values using a consensus approach that entailed (1) standard USEPA Office of Water methodologies (equations) for establishing Lifetime Health Advisory (LHA) and Risk-Specific Dose (RSD) values for the protection of human health, and (2) existing USEPA human-health toxicity information.

Fact Sheet↗
USGS2014

Powder X-ray diffraction laboratory, Reston, Virginia

The powder x-ray diffraction (XRD) laboratory is managed jointly by the Eastern Mineral and Environmental Resources and Eastern Energy Resources Science Centers. Laboratory scientists collaborate on a wide variety of research problems involving other U.S. Geological Survey (USGS) science centers and government agencies, universities, and industry. Capabilities include identification and quantification of crystalline and amorphous phases, and crystallographic and atomic structure analysis for a wide variety of sample media. Customized laboratory procedures and analyses commonly are used to characterize non-routine samples including, but not limited to, organic and inorganic components in petroleum source rocks, ore and mine waste, clay minerals, and glassy phases. Procedures can be adapted to meet a variety of research objectives.

Virginia↗
USGS2025

Decision-support modeling and research priorities for establishing baseline conditions for outstandingly remarkable values, Obed Wild and Scenic River, Tennessee

The Obed River is the last undammed river in Tennessee. The Obed Wild and Scenic River is managed by the National Park Service and covers a protected area of the Obed River headwaters (including four contributing tributaries). The Obed Wild and Scenic River supports a unique ecosystem with eight federally listed species. The National Park Service is responsible for preserving the baseline free-flowing condition of the river and associated outstandingly remarkable values (ORVs). Previous studies have been mostly project-based with differing methods, thus complicating efforts to quantify long-term changes in environmental conditions. This report presents a science plan summarizing (1) ORV conditions, (2) recent results of a decision-support hydrologic model for OBRI, and (3) possible future research priorities. The decision-support model was created to model streamflow conditions and changes in the ORVs since park establishment in 1976 and during three additional time periods. Established baseline conditions could help with management of ORVs not dependent on streamflow.

Tennessee↗
USGS2019

Water-quality and geochemical variability in the Little Arkansas River and Equus aquifer, south-central Kansas, 2001–16

The city of Wichita’s water supply currently (2019) comes from two primary sources: Cheney Reservoir and the Equus Beds aquifer. The Equus Beds aquifer storage and recovery project was developed to help the city of Wichita meet increasing future water demands. Source water for artificial recharge comes from the Little Arkansas River during above-base-flow conditions, is treated using National Primary Drinking Water Regulations as a guideline, and is injected into the Equus Beds aquifer through recharge wells or surface spreading basins for later use. The Equus Beds aquifer storage and recovery project currently (2019) consists of two coexisting phases. Phase I began in 2007 and captures Little Arkansas River water and indirect streambank diversion well water for aquifer recharge using 4 wells and 2 recharge basins. Phase II began in 2013 and currently (2019) includes a surface-water treatment facility, a river intake facility, eight recharge injection wells, and a third recharge basin. The U.S. Geological Survey, in cooperation with the City of Wichita, completed this study to summarize water-quality and geochemical variability of the Equus Beds aquifer. Data in this report can be used to establish baseline conditions before implementing artificial aquifer recharge further, document groundwater quality, evaluate changing conditions, identify environmental factors affecting groundwater, provide science-based information for decision making, and help meet regulatory monitoring requirements. Physicochemical properties were measured and water-quality data were collected from 2 Little Arkansas River surface-water sites and 63 Equus Beds aquifer groundwater sites, including 38 areal assessment index wells (IWs) during 2001 through 2016. Data collection included discrete samples and additional continuous measurements at selected sites. Discretely collected samples were analyzed for physicochemical properties, dissolved solids, primary ions, nutrients (nitrogen and phosphorus species), organic carbon, indicator bacteria, trace elements, arsenic species, organic compounds, and radioactivity. This report focuses discussion on aquifer water quality. Federal drinking-water criteria were used to evaluate aquifer water quality. Primary drinking-water criteria are those that are enforceable for public drinking water. Secondary criteria are those that can cause aesthetics or tastes that are unpleasant. Continuously collected data at a subset of sites included streamflow, groundwater levels, water temperature, specific conductance, pH, oxidation-reduction potential (ORP), dissolved oxygen, turbidity, nitrate plus nitrite, and fluorescent dissolved organic matter. Continuous measurement of physicochemical properties in near-real time allowed characterization of Little Arkansas River surface water and Equus Beds aquifer groundwater during conditions and time scales that would not have been possible otherwise and served as a complement to discrete water-quality sampling. During 2001 through 2016, less than 1 percent of chloride and nitrate plus nitrite, 7 percent of dissolved iron, 48 percent of dissolved manganese, 12 percent of dissolved arsenic, and 39 percent of atrazine detections in surface-water samples exceeded their respective Federal primary or secondary drinking-water criteria. None of the surface-water samples collected exceeded the Federal sulfate criterion, and every sample had detections of total coliform bacteria during the study. Constituents of concern in the Equus Beds aquifer exceeded their respective Federal criteria throughout the study period and included chloride, sulfate, nitrate plus nitrite, Escherichia coli ( E. coli ), total coliforms, and dissolved iron and arsenic species. About 5 percent of shallow (less than 80 feet) and 7 percent of deep (greater than 80 feet) IW chloride sample concentrations exceeded the secondary Federal criterion of 250 milligrams per liter (mg/L). Chloride tended to exceed its criterion in shallow and deep wells along the Arkansas River and near Burrton, Kansas, an area with past oil and gas activities. Chloride concentrations near Burrton were larger in the deep parts of the aquifer. About 18 percent of shallow and 13 percent of deep IW sulfate sample concentrations exceeded the secondary Federal criterion of 250 mg/L. Mean sulfate concentrations tended to exceed the criterion in the central part of the study area. Shallow IW mean nitrate plus nitrite (hereafter referred to as “nitrate”) was substantially larger than mean deep IW nitrate. Geochemical conditions in the deeper aquifer reduced forms of nitrogen to species such as ammonia. About 15 percent of shallow and less than 1 percent of deep IW nitrate sample concentrations exceeded the Federal criterion of 10 mg/L. Mean shallow IW nitrate concentrations exceeded the criterion in the northeastern and southeastern parts of the study area; on average, deep IW nitrate concentrations did not exceed the criterion. E. coli and fecal coliform bacteria detections were usually at or near the detection limit. E. coli was detected in 3 percent of shallow and deep IWs, and fecal coliform bacteria were detected in 8 percent of shallow and 6 percent of deep IWs. Total coliforms were detected in 24 percent of shallow and 12 percent of deep IWs. E. coli coliphage was detected in two shallow IW samples (1 percent of samples) at the detection limit and was not detected in deep IW samples. Dissolved iron was detected in 51 percent of shallow and 62 percent of deep IW samples. Dissolved iron concentrations exceeded the secondary Federal criterion of 0.3 mg/L in 38 percent of shallow and 46 percent of deep IW samples. Mean dissolved iron concentrations were largest mostly in the central and northwest part of the study area corresponding to an area of the aquifer where aquifer material is more clay-rich. The distribution of large dissolved iron concentrations was similar to that of large sulfate concentrations. About 55 percent of shallow and 92 percent of deep IW dissolved manganese samples exceeded the secondary Federal criterion of 0.05 mg/L. Almost all samples from the central and northern parts of the study area had mean dissolved manganese concentrations that exceeded the Federal criterion in the shallow part of the aquifer. Mean dissolved manganese concentrations in the shallow part of the aquifer were substantially large (greater than 1,000 micrograms per liter [μg/L]) in wells near the Little Arkansas River and in the central part of the study area because of chemically reducing conditions in the aquifer that likely related to larger percentages of clay in the aquifer material. Concentrations of dissolved arsenic species generally were larger in the deep parts of the aquifer. Arsenite was the dominant form of arsenic on average in shallow (52 percent) and deep (55 percent) IWs. About 12 percent of shallow and 34 percent of deep IW dissolved arsenic sample concentrations exceeded the Federal primary drinking criterion of 10 μg/L. Shallow IW dissolved arsenic concentrations were larger near the Little Arkansas River and the center of the study area; large shallow IW dissolved arsenic concentrations (10–50 μg/L) in the center of the study area correspond to areas that have had the most water-level recovery since the historical low in 1993. Mean ORP in shallow IWs generally decreased with increasing water-level depths and were inversely related to mean dissolved arsenic concentrations because of more reducing conditions (smaller ORP) at larger depths below the land surface. Larger dissolved arsenic concentrations in the shallow parts of the aquifer were associated with decreases in water levels and a subsequent decrease in ORP and thus more reducing conditions. Atrazine was detected in about 58 percent of shallow and 28 percent of deep IWs and did not exceed the primary Federal criterion of 3 μg/L in any groundwater samples. Atrazine concentrations in shallow IWs generally were largest in the northwest part of the study area near the North Branch Kisiwa Creek, and atrazine concentrations in deep IWs generally were largest most often in the southern part of the study area. Gross α radioactivity concentrations exceeded the primary Federal criterion of 15 picocuries per liter in 4 percent of shallow IW samples. Gross α and gross β radioactivity concentrations generally were larger in the southern third of the aquifer. Most groundwater-sample-simulated minerals saturation indices (SIs) were consistently negative (undersaturated). Minerals that had SI values that were consistently or typically positive (oversaturated) included iron oxide, hydroxide, and quartz-group minerals. Several SI values for arsenic- and manganese-bearing minerals were consistently negative. Some manganese-bearing mineral SI values ranged from undersaturated to oversaturated in shallow and deep IWs during the study. Several carbonate minerals in shallow and deep IWs varied across their equilibrium state. Calcite SI values were larger more often in the deep parts of the aquifer and did not show a clear distributional pattern. Mean and median calcite SI values for shallow and deep IWs were negative (undersaturated) indicating the potential for calcite dissolution if calcite is present for a substantial part of the study period. However, some individual calcite SI values in this study indicated saturation and subsequent calcite precipitation may occur in the study area, potentially resulting in formation of calcite mineral deposits that may reduce efficiency of injection wells. SI values with respect to iron hydroxide varied across their equilibrium states. Mean and median SI values with respect to iron hydroxide were undersaturated in shallow and deep IWs; however, some samples had positive SI values indicating there is potential for iron hydroxide precipitation, possibly caused by leaching and oxidation of iron-containing minerals, like pyrite, in the aquifer material.

Kansas↗