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At least 1,459 records · Page 81Linked to original sources
USGS2025

Specific conductance and water type as a proxy model for salinity and total dissolved solids measurements in the Upper Colorado River Basin

Salinity levels in streams and tributaries of the Colorado River Basin have been a major concern for the United States and Mexico for over 50 years as the water is used by millions of people for domestic and industrial purposes. Recently, the United States Geological Survey expanded stream monitoring networks including the number of sites where continuous (15-min) specific conductance is measured in the Colorado River Headwaters and Gunnison River Basin located east of the Colorado-Utah state line (hereafter, UCOL). The purpose of this study is to apply a proxy method to determine salinity and total dissolved solids concentrations from specific conductance and major-ion water type that is applicable to monitoring sites in the UCOL. Within the UCOL, carbonate rich waters originate from high-elevation mountain regions in the eastern UCOL, calcium sulfate rich waters are mainly found in the western half of the UCOL including the Gunnison River Basin, and waters of variable composition are found along the lower reaches of the Colorado River and Eagle River. It was found that the chemistry of sites with variable composition changes seasonally and is impacted by both geogenic and anthropogenic processes, potentially including seasonal application of deicing road salt. The specific conductance – water type proxy can be used to reliably (±10 %) predict salinity and total dissolved solids at 66 monitoring sites in the UCOL. The method is rapid, can generate high-resolution measurements, is cost-effective, and greatly expands the utility of specific conductance measurements. Furthermore, the high-resolution estimates provide an accurate approach to determining long-term salinity loads as short-term events are accurately accounted for.

Colorado↗
USGS2000

Ground-water quality atlas of Oakland County, Michigan

The U.S. Geological Survey (USGS), in cooperation with Oakland County Health Division (OCHD), collected 140 water samples from 38 wells in Oakland County during 1998 to better understand ground-water quality. OCHD had observed temporal variations in concentrations of various constituents, so two additional sets of samples were collected to evaluate potential short-term variability related to sample collection procedures and long-term seasonal variability. Replicate samples from 28 wells were analyzed in the Michigan Department of Environmental Quality (MDEQ) Drinking Water Laboratory to compare MDEQ’s analytical results to those obtained from the USGS National Water Quality Laboratory. Several additional databases describing population, land use, water supply, soils, geology, and flows of ground water and surface water are presented in the first part of the report to assist in interpreting the water-quality data. Maps created from these databases are provided in the first portion of the report as an extension of the study-area description. The U.S. Environmental Protection Agency (USEPA) has established Maximum Contaminant Levels (MCL) and Secondary Maximum Contaminant Levels (SMCL) for which samples were analyzed in this study. Water from the 38 wells sampled by the USGS did not exceed the SMCL or MCL for sulfate, fluoride, or nitrite. However, water from 26 wells exceeded the SMCL for iron, water from 12 wells exceeded the SMCL for manganese, and water from 12 wells exceeded the SMCL for dissolved solids. Water from two wells exceeded the MCL for nitrate, although nitrate concentrations in water from most wells was below the detection limit. Water from seven wells exceeded the SMCL for chloride, and water from all wells contained detectable concentrations of chloride. Water from five wells exceeded the MCL for arsenic, and most of the wells sampled contained detectable concentrations of arsenic. These five wells were identified from previous MDEQ analyses to have elevated arsenic concentrations, and were sampled to obtain additional chemistry information. Replicate samples were collected from 26 of the 38 wells for analysis at the MDEQ Drinking-Water Laboratory to compare the results with the USGS National Water Quality Laboratory. The results of the replicate analyses indicate close agreement between the laboratories, with mean differences for nitrate, chloride, and arsenic of 0.10 milligrams per liter (mg/L) as nitrogen, 6.8 mg/L, and 0.0008 mg/L, respectively between the USGS and MDEQ analyses. Potential health effects associated with ingesting nitrate, chloride, and arsenic are provided with the water-quality data, along with references for further information.

Michigan↗
USGS2013

Geohydrology, geochemistry, and groundwater simulation (1992-2011) and analysis of potential water-supply management options, 2010-60, of the Langford Basin, California

Groundwater withdrawals began in 1992 from the Langford Basin within the Fort Irwin National Training Center (NTC), California. From April 1992 to December 2010, approximately 12,300 acre-feet of water (averaging about 650 acre-feet per year) has been withdrawn from the basin and transported to the adjacent Irwin Basin. Since withdrawals began, water levels in the basin have declined by as much as 40 feet, and the quality of the groundwater withdrawn from the basin has deteriorated. The U.S. Geological Survey collected geohydrologic data from Langford Basin during 1992–2011 to determine the quantity and quality of groundwater available in the basin. Geophysical surveys, including gravity, seismic refraction, and time-domain electromagnetic induction surveys, were conducted to determine the depth and shape of the basin, to delineate depths to the Quaternary-Tertiary interface, and to map the depth to the water table and changes in water quality. Data were collected from existing wells and test holes, as well as 11 monitor wells that were installed at 5 sites as part of this study. Water-quality samples collected from wells in the basin were used to determine the groundwater chemistry within the basin and to delineate potential sources of poor-quality groundwater. Analysis of stable isotopes of oxygen and hydrogen in groundwater indicates that present-day precipitation is not a major source of recharge to the basin. Tritium and carbon-14 data indicate that most of the basin was recharged prior to 1952, and the groundwater in the basin has an apparent age of 12,500 to 30,000 years. Recharge to the basin, estimated to be less than 50 acre-feet per year, has not been sufficient to replenish the water that is being withdrawn from the basin. A numerical groundwater-flow model was developed for the Langford Basin to better understand the aquifer system used by the Fort Irwin NTC as part of its water supply, and to provide a tool to help manage groundwater resources at the NTC. Measured groundwater-level declines since the initiation of withdrawals (1992–2011) were used to calibrate the groundwater-flow model. The simulated recharge was about 46 acre-feet per year, including approximately 6 acre-feet per year of natural recharge derived from precipitation runoff and as much as 40 acre-feet per year of underflow from the Irwin Basin. Between April 1992 and December 2010, an average of about 650 acre-feet per year of water was withdrawn from the Langford Basin. Groundwater withdrawals in excess of natural recharge resulted in a net loss of 11,670 acre-feet of groundwater storage within the basin for the simulation period. The Fort Irwin NTC is considering various groundwater-management options to address the limited water resources in the Langford Basin. The calibrated Langford Basin groundwater-flow model was used to evaluate the hydrologic effects of four groundwater-withdrawal scenarios being considered by the Fort Irwin NTC over the next 50 years (January 2011 through December 2060). Continuation of the 2010 withdrawal rate in the three existing production wells will result in 70 feet of additional drawdown in the central part of the basin. Redistributing the 2010 withdrawal rate equally to the three existing wells and two proposed new wells in the northern and southern parts of the basin would result in about 10 feet less drawdown in the central part of the basin but about 100 feet of additional drawdown in the new well in the northern part of the basin and about 50 feet of additional drawdown in the new well in the southern part of the basin. Reducing the withdrawals from the three existing production wells in the central part of the basin from about 45,000 acre-feet to about 32,720 acre-feet would result in about 40 feet of additional drawdown in the central basin near the pumping wells, about 25 feet less than if withdrawals were not reduced. The combination of reducing and redistributing the cumulative withdrawals to the three existing and two proposed new wells results in about 40 feet of additional drawdown in the central and southern parts of the basin and about 70 feet in the northern part of the basin. These results show that reducing and redistributing the groundwater withdrawals would maintain the upper aquifer at greater than 50 percent of its predevelopment saturated thickness throughout the groundwater basin. The scenarios simulated for this study demonstrate how the calibrated model can be utilized to evaluate the hydrologic effects of different water-management strategies.

California↗
USGS2025

Environmental persistence and toxicity of weathered wildland fire retardants to rainbow trout

Long-term fire retardants are employed to combat and control wildfires by altering the way fuels burn, and they continue to decrease fire intensity after water in the retardant solution has evaporated. After application, fire retardants may persist on dry stream beds or in riparian habitats before precipitation events flush the retardant into intermittent streams. We exposed juvenile (30–60 days post swim-up) rainbow trout ( Oncorhynchus mykiss ) to fire retardants weathered for 7–56 days on different substrates (duff, gravel, high organic content soil, and low organic content soil) under static conditions for 96 h to evaluate the potential toxicity of two current-use long-term fire-retardant (LC95A-R and MVP-Fx) products. Trout mortality was greater in LC95A-R treatments compared to MVP-Fx due to higher concentrations of LC95A-R in the applied product than MVP-Fx at the same application rate. Underlying substrate affected fire-retardant toxicity, with 31% higher average mortality for products applied to duff and gravel compared to soil. Differences in mortality across substrates and products after weathering may be attributed to differences in the mix ratio of applied product and interactions of product chemistries with underlying substrate. These interactions resulted in elevated ionic concentrations of the overlying water in duff and gravel treatments. Trout mortality decreased 15% for products weathered 56 days compared to 7 days. Our results suggest that long-term fire retardants may persist in the environment and that underlying substrate may alter the toxicity of these products upon entrance into an intermittent stream.

Archives of Environmental Contamination and Toxico↗
USGS2016

Intertidal salt marshes as an important source of inorganic carbon to the coastal ocean

Dynamic tidal export of dissolved inorganic carbon (DIC) to the coastal ocean from highly productive intertidal marshes and its effects on seawater carbonate chemistry are thoroughly evaluated. The study uses a comprehensive approach by combining tidal water sampling of CO 2 parameters across seasons, continuous in situ measurements of biogeochemically-relevant parameters and water fluxes, with high-resolution modeling in an intertidal salt marsh of the U.S. northeast region. Salt marshes can acidify and alkalize tidal water by injecting CO 2 (DIC) and total alkalinity (TA). DIC and TA generation may also be decoupled due to differential effects of marsh aerobic and anaerobic respiration on DIC and TA. As marsh DIC is added to tidal water, the buffering capacity first decreases to a minimum and then increases quickly. Large additions of marsh DIC can result in higher buffering capacity in ebbing tide than incoming tide. Alkalization of tidal water, which mostly occurs in the summer due to anaerobic respiration, can further modify buffering capacity. Marsh exports of DIC and alkalinity may have complex implications for the future, more acidified ocean. Marsh DIC export exhibits high variability over tidal and seasonal cycles, which is modulated by both marsh DIC generation and by water fluxes. The marsh DIC export of 414 g C m −2 yr −1 , based on high-resolution measurements and modeling, is more than twice the previous estimates. It is a major term in the marsh carbon budget and translates to one of the largest carbon fluxes along the U.S. East Coast.

Massachusetts↗
USGS1958

The solusphere - its inferences and study

Water is a fundamental geologic agent active in rock decomposition, erosion, and synthesis. Solutes in water are of particular interest to geochemists as sources of raw material for synthesis or as products of decomposition. When geochemical studies move from the laboratory into natural environment many variables relating to solute hydrology must be considered. As a focal point there has been designed a graphical representation of solute hydrology, the solusphere, which embodies the concepts of land-water occurrence and movement on which are superimposed geologic, biologic, physical, chemical, and cultural processes affecting solutes. The solusphere is demonstrated by passing an imaginary plane through the centre of the earth. This plane intercepts concentric zones designated as rock flowage, saturation, aeration, surface activity, and atmosphere. Transport processes carry solutes within and between zones without alteration or conversion. However, whether stationary or in motion, the water's solute character is constantly subject to (1) alteration processes that change concentration by addition or subtraction of solutes or solvent without loss of solute identities, and (2) conversion processes that change the chemical state and form of solutes. The geochemist is concerned with specific conversion processes, but he also must consider transport, alteration, and other conversion processes that are continually modifying the materials with which he is dealing in nature. The solusphere is an attempt to organize processes affecting the chemical quality of land waters into a unified field of science much like the field of marine chemistry.

Geochimica et Cosmochimica Acta↗
USGS1991

A review of the hydrogeologic-geochemical model for Cerro Prieto

With continued exploitation of the Cerro Prieto, Mexico, geothermal field, there is increasing evidence that the hydrogeologic model developed by Halfman and co-workers presents the basic features controlling the movement of geothermal fluids in the system. In mid–1987 the total installed capacity at Cerro Prieto reached 620 MW c , requiring a large rate of fluid production (more than 10,500 tonnes/hr of a brine-steam mixture; August 1988). This significant mass extraction has led to changes in reservoir thermodynamic conditions and in the chemistry of the produced fluids. Pressure drawdown has caused an increase in cold water recharge in the southern and western edges of the field, and local and general reservoir boiling in parts of the geothermal system. After reviewing the hydrogeologic and geochemical models of Cerro Prieto, the exploitation-induced cold water recharge and reservoir boiling (and plugging) observed in different areas of the field, are discussed and interpreted on the basis of these models and schematic flow models that describe the hydrogeology.

Geothermics↗
USGS2009

The stable carbon isotope biogeochemistry of acetate and other dissolved carbon species in deep subseafloor sediments at the northern Cascadia Margin

Ocean drilling has revealed the existence of vast microbial populations in the deep subseafloor, but to date little is known about their metabolic activities. To better understand the biogeochemical processes in the deep biosphere, we investigate the stable carbon isotope chemistry of acetate and other carbon-bearing metabolites in sediment pore-waters. Acetate is a key metabolite in the cycling of carbon in anoxic sediments. Its stable carbon isotopic composition provides information on the metabolic processes dominating acetate turnover in situ. This study reports our findings for a methane-rich site at the northern Cascadia Margin (NE Pacific) where Expedition 311 of the Integrated Ocean Drilling Program (IODP) sampled the upper 190 m of sediment. At Site U1329, δ 13 C values of acetate span a wide range from −46.0‰ to −11.0‰ vs. VPDB and change systematically with sediment depth. In contrast, δ 13 C values of both the bulk dissolved organic carbon (DOC) (−21.6 ± 1.3‰ vs. VPDB) and the low-molecular-weight compound lactate (−20.9 ± 1.8‰ vs. VPDB) show little variability. These species are interpreted to represent the carbon isotopic composition of fermentation products. Relative to DOC, acetate is up to 23.1‰ depleted and up to 9.1‰ enriched in 13 C. Broadly, 13 C-depletions of acetate relative to DOC indicate flux of carbon from acetogenesis into the acetate pool while 13 C-enrichments of pore-water acetate relative to DOC suggest consumption of acetate by acetoclastic methanogenesis. Isotopic relationships between acetate and lactate or DOC provide new information on the carbon flow and the presence and activity of specific functional microbial communities in distinct biogeochemical horizons of the sediment. In particular, they suggest that acetogenic CO 2 -reduction can coexist with methanogenic CO 2 -reduction, a notion contrary to the hypothesis that hydrogen levels are controlled by the thermodynamically most favorable electron-accepting process. Further, the isotopic relationship suggests a relative increase in acetate flow to acetoclastic methanogenesis with depth although its contribution to total methanogenesis is probably small. Our study demonstrates how the stable carbon isotope biogeochemistry of acetate can be used to identify pathways of microbial carbon turnover in subsurface environments. Our observations also raise new questions regarding the factors controlling acetate turnover in marine sediments.

Geochimica et Cosmochimica Acta↗
USGS2016

Effects of energy development on wetland plants and macroinvertebrate communities in Prairie Pothole Region wetlands

Energy production in the Williston Basin, USA, results in the coproduction of highly saline, sodium chloride-dominated water (brine). The Prairie Pothole Region (PPR) overlies the northeastern portion of the Williston Basin. Although PPR wetlands span a range of salinity, the dominant salt is sodium sulfate, and salinities are much lower than brine. Introduction of brine to wetlands can result in pronounced water-quality changes; however, the ecological effects of such contamination are poorly understood. We examined the effects of brine contamination on primary productivity, emergent macrophyte tissue chemistry, and invertebrate communities from 10 wetlands in the PPR. Based on a recognized Contamination Index (CI) used to identify brine contamination in the PPR, water-quality samples indicated that six wetlands were uncontaminated while four were contaminated. Across this gradient, we observed a significant decrease in above-ground biomass and a significant increase in tissue chloride concentrations of hardstem bulrush ( Schoenoplectus acutus ) with increased CI values. Additionally, a significant decrease in macroinvertebrate taxonomic richness with increased CI values was observed. These findings provide needed insight on the biological effects of brine contamination on PPR wetlands.

Journal of Freshwater Ecology↗
USGS2021

Evaluation and application of the Purge Analyzer Tool (PAT) to determine in-well flow and purge criteria for sampling monitoring wells at the Stringfellow Superfund site in Jurupa Valley, California, in 2017

The U.S. Geological Survey and U.S. Environmental Protection Agency are developing analytical tools to assess the representativeness of groundwater samples from fractured-rock aquifers. As part of this effort, monitoring wells from the Stringfellow Superfund site in Jurupa Valley in Riverside County, California, approximately 50 miles east of Los Angeles, were field tested to collect information to assist in the evaluation and application of in-well flow as computed by the analytical model called the Purge Analyzer Tool, which computes in-well groundwater travel times for simple piston transport of inflowing groundwater from open intervals of a monitoring well to the pump intake and can provide insight into optimal purging parameters (duration, rate, and pump position) needed for the collection of representative groundwater samples. Field testing of wells included hydraulic, chemistry, and dye tracer analysis to investigate travel times in wells under pumping conditions. The Purge Analyzer Tool was able to replicate dye velocities (travel times) for one of three wells that had appreciable inflow from the aquifer but not the other two wells, which are screened in low-permeability sediments and rock, where flow was dominated by borehole storage. A set of criteria was established to help assess the ability to collect representative groundwater chemistry from monitoring wells; criteria included understanding the height of the static well water column and relative exchange rate between the aquifer and the well.

California↗
USGS1953

Water

[No abstract available]

Analytical Chemistry↗
USGS2007

Water-Quality Characteristics for Sites in the Tongue, Powder, Cheyenne, and Belle Fourche River Drainage Basins, Wyoming and Montana, Water Years 2001-05, with Temporal Patterns of Selected Long-Term Water-Quality Data

Water-quality sampling was conducted regularly at stream sites within or near the Powder River structural basin in northeastern Wyoming and southeastern Montana during water years 2001-05 (October 1, 2000, to September 30, 2005) to characterize water quality in an area of coalbed natural gas development. The U.S. Geological Survey, in cooperation with the Wyoming Department of Environmental Quality, characterized the water quality at 22 sampling sites in the Tongue, Powder, Cheyenne, and Belle Fourche River drainage basins. Data for general hydrology, field measurements, major-ion chemistry, and selected trace elements were summarized, and specific conductance and sodium-adsorption ratios were evaluated for relations with streamflow and seasonal variability. Trend analysis for water years 1991-2005 was conducted for selected sites and constituents to assess change through time. Average annual runoff was highly variable among the stream sites. Generally, streams that have headwaters in the Bighorn Mountains had more runoff as a result of higher average annual precipitation than streams that have headwaters in the plains. The Powder River at Moorhead, Mont., had the largest average annual runoff (319,000 acre-feet) of all the sites; however, streams in the Tongue River drainage basin had the highest runoff per unit area of the four major drainage basins. Annual runoff in all major drainage basins was less than average during 2001-05 because of drought conditions. Consequently, water-quality samples collected during the study period may not represent long-term water-quality con-ditions for all sites. Water-quality characteristics were highly variable generally because of streamflow variability, geologic controls, and potential land-use effects. The range of median specific-conductance values among sites was smallest in the Tongue River drainage basin. Median values in that basin ranged from 643 microsiemens per centimeter at 25 degrees Celsius (?S/cm at 25?C) on the Tongue River to 1,460 ?S/cm at 25?C on Prairie Dog Creek. The Tongue River drainage basin has the largest percentage of area underlain by Mesozoic-age and older rocks and by more resistant rocks. In addition, the higher annual precipitation and a steeper gradient in this basin compared to basins in the plains produce relatively fast stream velocities, which result in a short contact time between stream waters and basin materials. The Powder River drainage basin, which has the largest drainage area and most diverse site conditions, had the largest range of median specific-conductance values among the four major drainage basins. Median values in that basin ranged from 680 ?S/cm at 25?C on Clear Creek to 5,950 ?S/cm at 25?C on Salt Creek. Median specific-conductance values among sites in the Cheyenne River drainage basin ranged from 1,850 ?S/cm at 25?C on Black Thunder Creek to 4,680 ?S/cm at 25?C on the Cheyenne River. The entire Cheyenne River drainage basin is in the plains, which have low precipitation, soluble geologic materials, and relatively low gradients that produce slow stream velocities and long contact times. Median specific-conductance values among sites in the Belle Fourche River drainage basin ranged from 1,740 ?S/cm at 25?C on Caballo Creek to 2,800 ?S/cm at 25?C on Donkey Creek. Water in the study area ranged from a magnesium-calcium-bicarbonate type for some sites in the Tongue River drainage basin to a sodium-sulfate type at many sites in the Powder, Cheyenne, and Belle Fourche River drainage basins. Little Goose Creek, Goose Creek, and the Tongue River in the Tongue River drainage basin, and Clear Creek in the Powder River drainage basin, which have headwaters in the Bighorn Mountains, consistently had the smallest median dissolved-sodium concentrations, sodium-adsorption ratios, dissolved-sulfate concentrations, and dissolved-solids concentrations. Salt Creek, Wild Horse Creek, Little Powder River, and the Cheyenne River, which have headwat

Scientific Investigations Report↗