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Accumulation of fossil fuels and metallic minerals in active and ancient rift lakes

A study of active and ancient rift systems around the world suggests that accumulations of fossil fuels and metallic minerals are related to the interactions of processes that form rift valleys with those that take place in and around rift lakes. The deposition of the precursors of petroleum, gas, oil shale, coal, phosphate, barite, Cu-Pb-Zn sulfides, and uranium begins with erosion of uplifted areas, and the consequent input of abundant nutrients and solute loads into swamps and tectonic lakes. Hot springs and volcanism add other nutrients and solutes. The resulting high biological productivity creates oxidized/reduced interfaces, and anoxic and H 2 S-rich bottom waters which preserves metal-bearing organic tissues and horizons. In the depositional phases, the fine-grained lake deposits are in contact with coarse-grained beach, delta, river, talus, and alluvial fan deposits. Earthquake-induced turbidites also are common coarse-grained deposits of rift lakes. Postdepositional processes in rifts include high heat flow and a resulting concentration of the organic and metallic components that were dispersed throughout the lakebeds. Postdepositional faulting brings organic- and metal-rich sourcebeds in contact with coarse-grained host and reservoir rocks. A suite of potentially economic deposits is therefore a characteristic of rift valleys.

Tectonophysics↗

A review of crust and upper mantle structure studies of the Snake River Plain-Yellowstone volcanic system: A major lithospheric anomaly in the western U.S.A.

The Snake River Plain-Yellowstone volcanic system is one of the largest, basaltic, volcanic field in the world. Here, there is clear evidence for northeasterly progression of rhyolitic volcanism with its present position in Yellowstone. Many theories have been advanced for the origin of the Snake River Plain-Yellowstone system. Yellowstone and Eastern Snake River Plain have been studied intensively using various geophysical techniques. Some sparse geophysical data are available for the Western Snake River Plain as well. Teleseismic data show the presence of a large anomalous body with low P- and S-wave velocities in the crust and upper mantle under the Yellowstone caldera. A similar body in which compressional wave velocity is lower than in the surrounding rock is present under the Eastern Snake River Plain. No data on upper mantle anomalies are available for the Western Snake River Plain. Detailed seismic refraction data for the Eastern Snake River Plain show strong lateral heterogeneities and suggest thinning of the granitic crust from below by mafic intrusion. Available data for the Western Snake River Plain also show similar thinning of the upper crust and its replacement by mafic material. The seismic refraction results in Yellowstone show no evidence of the low-velocity anomalies in the lower crust suggested by teleseismic P-delay data and interpreted as due to extensive partial melting. However, the seismic refraction models indicate lower-than-normal velocities and strong lateral inhomogeneities in the upper crust. Particularly obvious in the refraction data are two regions of very low seismic velocities near the Mallard Eake and Sour Creek resurgent domes in the Yellowstone caldera. The low-velocity body near the Sour Creek resurgent dome is interpreted as partially molten rock. Together with other geophysical and thermal data, the seismic results indicate that a sub-lithospheric thermal anomaly is responsible for the time-progressive volcanism along the Eastern Snake River Plain. However, the exact mechanism responsible for the volcanism and details of magma storage and migration are not yet fully understood.

California, Idaho, Montana, Nevada, Oregon, Washin↗

The Richter scale: its development and use for determining earthquake source parameters

The M L scale, introduced by Richter in 1935, is the antecedent of every magnitude scale in use today. The scale is defined such that a magnitude-3 earthquake recorded on a Wood-Anderson torsion seismometer at a distance of 100 km would write a record with a peak excursion of 1 mm. To be useful, some means are needed to correct recordings to the standard distance of 100 km. Richter provides a table of correction values, which he terms -log A o , the latest of which is contained in his 1958 textbook. A new analysis of over 9000 readings from almost 1000 earthquakes in the southern California region was recently completed to redetermine the -log A o values. Although some systematic differences were found between this analysis and Richter's values (such that using Richter's values would lead to under and overestimates of M L at distances less than 40 km and greater than 200 km, respectively), the accuracy of his values is remarkable in view of the small number of data used in their determination. Richter's corrections for the distance attenuation of the peak amplitudes on Wood-Anderson seismographs apply only to the southern California region, of course, and should not be used in other areas without first checking to make sure that they are applicable. Often in the past this has not been done, but recently a number of papers have been published determining the corrections for other areas. If there are significant differences in the attenuation within 100 km between regions, then the definition of the magnitude at 100 km could lead to difficulty in comparing the sizes of earthquakes in various parts of the world. To alleviate this, it is proposed that the scale be defined such that a magnitude 3 corresponds to 10 mm of motion at 17 km. This is consistent both with Richter's definition of M L at 100 km and with the newly determined distance corrections in the southern California region. Aside from the obvious (and original) use as a means of cataloguing earthquakes according to size, ML has been used in predictions of ground shaking as a function of distance and magnitude; it has also been used in estimating energy and seismic moment. There is a good correlation of peak ground velocity and the peak motion on a Wood-Anderson instrument at the same location, as well as an observationally defined (and theoretically predicted) nonlinear relation between M L and seismic moment. An important byproduct of the establishment of the M L scale is the continuous operation of the network of Wood-Anderson seismographs on which the scale is based. The records from these instruments can be used to make relative comparisons of amplitudes and waveforms of recent and historic earthquakes; furthermore, because of the moderate gain, the instruments can write onscale records from great earthquakes at teleseismic distances and thus can provide important information about the energy radiated from such earthquakes at frequencies where many instruments have saturated.

California↗

Dikes, joints, and faults in the upper mantle

Three different types of macroscopic fractures are recognized in upper-mantle and lower-crustal xenoliths in volcanic rocks from around the world: 1. (1) joints that are tensile fractures not occupied by crystallized magma products 2. (2) dikes that are tensile fractures occupied by mafic magmas crystallized to pyroxenites, gabbros or hydrous-mineral-rich rocks, 3. (3) faults that are unfilled shear fractures with surface markings indicative of shear displacement. In addition to intra-xenolith fractures, xenoliths commonly have polygonal or faceted shapes that represent fractures exploited during incorporation of the xenoliths into the host magma that brought them to the surface. The various types of fractures are considered to have formed in response to the pressures associated with magmatic fluids and to the ambient tectonic stress field. The presence of fracture sets and crosscutting relations indicate that both magma-filled and unfilled fractures can be contemporaneous and that the local stress field can change with time, leading to repeated episodes of fracture. These observations give insight into the nature of deep fracture processes and the importance of fluid-peridotite interactions in the mantle. We suggest that unfilled fractures were opened by volatile fluids exsolved from ascending magmas to the tops of growing dikes. These volatile fluids are important because they are of low viscosity and can rapidly transmit fluid pressure to dike and fault tips and because they lower the energy and tectonic stresses required to extend macroscopic cracks and to allow sliding on pre-existing fractures. Mantle seismicity at depths of 20-65 km beneath active volcanic centers in Hawaii corresponds to the depth interval where CO2-rich fluids are expected to be liberated from ascending basaltic magmas, suggesting that such fluids play an important role in facilitating earthquake instabilities in the presence of tectonic stresses. Other phenomena related to the fractures include permeation of peridotite by fluid inclusions derived by degassing of magmas, partial melting of peridotite and dike rocks, and metasomatic alteration of peridotite host rock by magmas emplaced in fractures. These effects of magmatism generally reduce the bulk density of peridotite and might also reduce seismic velocities. The velocity contrasts between fractured and unfractured peridotite might be detected by seismic-velocity profiling techniques.

Tectonophysics↗

Third-order Middle Miocene-Early Pliocene depositional sequences in the prograding delta complex of the Pannonian Basin

Few studies exist in the geologic literature that show the distribution of seismic facies and depositional sequences within a lacustrine basin. The Pannonian Basin of Central Europe offers a unique opportunity to evaluate the influence of the eustatic signal on lacustrine deposition. Seismic stratigraphie and sedimentological studies indicate that the Middle Miocene-Early Pliocene infill of the transtensional Pannonian Basin was formed by large delta systems. Systematic sequence stratigraphie analysis of 6000 km of reflection seismic data and more than 100 hydrocarbon exploration wells in Hungary allowed the identification of twelve third-order sequence boundaries in the late Neogene sedimentary fill. This number of depositional sequences corresponds to that of the published global eustatic curve for this time period. Furthermore, based on magnetostratigraphic and radiometric data, the ages of these depositional sequences can be tentatively correlated with the global eustatic curve. The Pannonian Basin became isolated from the world sea at the Sarmatian/Pannonian (11.5 Ma) boundary and formed a large lake. The stratal patterns and sedimentary facies of individual systems tracts within the lacustrine sequences display the same characteristics as marine depositional sequences. The relatively low rate of thermal subsidence and the high rate of sediment supply resulted in a good sequence resolution. Within the third-order sequences higher-order sequences can be recognized with an average duration of about 0.1-0.5 Ma.

Tectonophysics↗

Natural occurrence and significance of fluids indicating high pressure and temperature

Most natural minerals have formed from a fluid phase such as a silicate melt or a saline aqueous solution. Fluid inclusions are tiny volumes of such fluids that were trapped within the growing crystals. These inclusions can provide valuable but sometimes ambiguous data on the temperature, pressure, and composition of these fluids, many of which are not available from any other source. They also provide “visual autoclaves” in which it is possible to watch, through the microscope, the actual phase changes take place as the inclusions are heated. This paper reviews the methods of study and the results obtained, mainly on inclusions formed from highly concentrated solutions, at temperatures ≥500°C. Many such fluids have formed as a result of immiscibility with silicate melt in igneous or high-temperature metamorphic rocks. These include fluids consisting of CO 2 , H 2 O, or hydrosaline melts that were <50% H 2 O. From the fluid inclusion evidence it is clear that a boiling, very hot, very saline fluid was present during the formation of most of the porphyry copper deposits in the world. Similarly, from the inclusion evidence it is clear that early (common) pegmatites formed from essentially silicate melts and that the late, rare-element-bearing and chamber-type pegmatites formed from a hydrosaline melt or a more dilute water solution. The evidence on whether this change in composition from early to late solutions was generally continuous or involved immiscibility is not as clear.

Physics and Chemistry of the Earth↗

Indicators of sewage contamination in sediments beneath a deep-ocean dump site off New York

The world's largest discharge of municipal sewage sludge to surface waters of the deep sea has caused measurable changes in the concentration of sludge indicators in sea-floor sediments, in a spatial pattern which agrees with the predictions of a recent sludge deposition model. Silver, linear alkylbenzenes, coprostanol, and spores of the bacterium Clostridium perfringens, in bottom sediments and in near-bottom suspended sediment, provide evidence for rapid settling of a portion of discharged solids, accumulation on the sea floor, and biological mixing beneath the water sediment interface. Biological effects include an increase in 1989 of two species of benthic polychaete worm not abundant at the dump site before sludge dumping began in 1986. These changes in benthic ecology are attributed to the increased deposition of utilizable food in the form of sludge-derived organic matter.

New Jersey, New York↗

Accumulation of organic matter in Cretaceous oxygen-deficient depositional environments in the central Pacific Ocean

Complete records of organic-carbon-rich Cretaceous strata were continuouslycored on the flanks of the Mid-Pacific Mountains and southern Hess Rise in the central North Pacific Ocean during DSDP Leg 62. Organic-carbon-rich laminated silicified limestones were deposited in the western Mid-Pacific Mountains during the early Aptian, a time when that region was south of the equator and considerably shallower than at present. Organic-carbon-rich, laminated limestone on southern Hess Rise overlies volcanic basement and includes 136 m of stratigraphic section of late Albian to early Cenomanian age. This limestone unit was deposited rapidly as Hess Rise was passing under the equatorial high-productivity zone and was subsiding from shallow to intermediate depths. The association of volcanogenic components with organic-carbon-rich strata on Hess Rise in the Mid-Pacific Mountains is striking and suggests that there was a coincidence of mid-plate volcanic activity and the production and accumulation of organic matter at intermediate water depths in the tropical Pacific Ocean during the middle Cretaceous. Pyrolysis assays and analyses of extractable hydrocarbons indicate that the organic matter in the limestone on Hess Rise is composed mainly of lipid-rich kerogen derived from aquatic marine organisms and bacteria. Limestones from the Mid-Pacific Mountains generally contain low ratios of pyrolytic hydrocarbons to organic carbon and low hydrogen indices, suggesting that the organic matter may contain a significant proportion of land-derived material, possibly derived from numerous volcanic islands that must have existed before the area subsided. The organic carbon in all samples analyzed is isotopically light ( δ 13 C − 24 to − 29 per mil) relative to most modern rine organic carbon, and the lightest carbon is also the most lipid-rich. There is a positive linear correlation between sulfur and organic carbon in samples from Hess Rise and from the Mid-Pacific Mountains. The slopes and intercepts of C-S regression lines however, are different for each site and all are different from regression lines for samples from modern anoxic marine sediments and from Black Sea cores. The organic-carbon-rich limestones on Hess Rise, the Mid-Pacific Mountains, and other plateaus and seamounts in the Pacific Ocean are not synchronous but do occur within the same general middle Cretaceous time period as organic-carbon-rich lithofacies elsewhere in the world ocean, particularly in the Atlantic Ocean. Strata of equivalent age in the deep basins of the Pacific Ocean are not rich in organic carbon, and were deposited in oxygenated environments. This observation, together with the evidence that the plateau sites were considerably shallower and closse to the equator during the middle Creataceous suggests that local tectonic and hydrographic conditions may have resulted in high surface-water productivity and the preservation of organic matter in an oxygen-deficient environment where an expanded mid-water oxygen minimum developed and impinged on elevated platforms and seamounts.

Organic Geochemistry↗

A review of the geochemistry of methane in natural gas hydrate

The largest accumulations on Earth of natural gas are in the form of gas hydrate, found mainly offshore in outer continental margin sediment and, to a lesser extent, in polar regions commonly associated with permafrost. Measurements of hydrocarbon gas compositions and of carbon-isotopic compositions of methane from natural gas hydrate samples, collected in subaquatic settings from around the world, suggest that methane guest molecules in the water clathrate structures are mainly derived by the microbial reduction of CO 2 from sedimentary organic matter. Typically, these hydrocarbon gases are composed of > 99% methane, with carbon-isotopic compositions (δ 13 C PDB ) ranging from − 57 to − 73‰. In only two regions, the Gulf of Mexico and the Caspian Sea, has mainly thermogenic methane been found in gas hydrate. There, hydrocarbon gases have methane contents ranging from 21 to 97%, with δ 13 C values ranging from − 29 to − 57‰. At a few locations, where the gas hydrate contains a mixture of microbial and thermal methane, microbial methane is always dominant. Continental gas hydrate, identified in Alaska and Russia, also has hydrocarbon gases composed of > 99% methane, with carbon-isotopic compositions ranging from − 41 to − 49‰. These gas hydrate deposits also contain a mixture of microbial and thermal methane, with thermal methane likely to be dominant.

Organic Geochemistry↗

Ocean eddy structure by satellite radar altimetry required for iceberg towing

Models for the towing of large tabular icebergs give towing speeds of 0.5 knots to 1.0 knots relative to the ambient near surface current. Recent oceanographic research indicates that the world oceans are not principally composed of large steady-state current systems, like the Gulf Stream, but that most of the ocean momentum is probably involved in intense rings, formed by meanders of the large streams, and in mid-ocean eddies. These rings and eddies have typical dimensions on the order of 200 km with dynamic height anomalies across them of tens-of-centimeters to a meter. They migrate at speeds on the order of a few cm/sec. Current velocities as great as 3 knots have been observed in rings, and currents of 1 knot are common. Thus, the successful towing of icebergs is dependent on the ability to locate, measure, and track ocean rings and eddies. To accomplish this systematically on synoptic scales appears to be possible only by using satelliteborne radar altimeters. Ocean current and eddy structures as observed by the radar altimeters on the GEOS-3 and Seasat-1 satellites are presented and compared. Several satellite programs presently being planned call for flying radar altimeters in polar or near-polar orbits in the mid-1980 time frame. Thus, by the time tows of large icebergs will probably be attempted, it is possible synoptic observations of ocean rings and eddies which can be used to ascertain their location, size, intensity, and translation velocity will be a reality.

Cold Regions Science and Technology↗

The geology of selected peat-forming environments in temperate and tropical latitudes

We studied peat in several geologic and climatic settings: (1) a glaciated terrain in cold-temperate Maine and Minnesota, U.S.A.; (2) an island in a temperate maritime climate in the Atlantic Ocean off the coast of Maine, U.S.A., where sea level is rising rapidly and changing the environment of peat accumulation; (3) swamps along the warm-temperate U.S. Atlantic and Gulf Coastal Plains, where sea level has changed often, thus creating sites for accumulation; and (4) in a tropical climate along the coast of Sarawak, Malaysia, and the delta of the Batang Hari River, Sumatra, Indonesia (Figs. 1 and 2). With the exception of the deposits on the Atlantic and Gulf Coastal Plains, most of the deposits described are domed bogs in which peat accumulation continued above the surface of the surrounding soil. The bogs of the U.S. Atlantic and Gulf Coastal Plains have almost level surfaces. All domed bogs are not entirely ombrotrophic (watered only from precipitation); multidomed bogs that rise from irregular or hilly surfaces may be crossed by streams that supply water to the bogs. The geologic processes or organic sedimentation, namely terrestrialization and paludification, are similar in all peat deposits considered here. Differences in geomorphology affecting the quantity and that quality of peat that has ash contents of less than 25%, which are desirable for commercial purposes, depend chiefly on: (1) high humidity, which is favorable to luxuriant growth of peat-forming vegetation; (2) a depositional setting that permits extensive accumulation relatively free from inorganic contamination from sea water and streams and from dust and volcanic ash; and (3) a stable regional water table that controls the rate of decomposition under aerobic conditions and protects the deposit against the ravages of fire. Differences in peat textures are due to the type of vegetation and to the degree of decomposition. The rate of decomposition is largely the result of the amount of oxidation and aerobic microbial activity. Stratigraphic distribution of various textures and amounts of inorganic components within a peat deposit is largely determined by the vertical positions occupied by peat-forming environments, such as pond, marsh, swamp and heath where vegetation accumulated, and the depth to zones of unoxygenated water. Peat also differs in the rate of accumulation. On the basis of carbon-14 dating, an estimated 8 m of peat in the tropical Batang Hari River deposit in Sumatra has been accumulating at the rate of about 1.5 m/1,000 yr, whereas peat in the cold-temperate deposit in Maine has been accumulating at the rate of 0.66 m/1,000 yr. Accumulation rates in domed deposits such as these are affected not only by factors controlling volume of biomass and aerobic decay but also by stream erosion and fires that remove peat. Such disconformities (see Fig. 2) within the deposit may be recognized by sudden vertical changes in degree of decomposition and/or the presence of charcoal. The trace-element content of peat deposits is affected by the environments of their settings. Samples of peat that have an ash content of less than 25% dry weight and that are from small, almost level swamp deposits along the Atlantic Coastal Plain of North Carolina were compared with similar samples from small domed bogs in Maine, a glaciated area. Samples from Nort Carolina, which are from deposits in thick fluvial and nearshore marine sediments far from the bedrock source, are generally higher in Ti, Cr and Pb. The Maine samples from deposits in glacial drift close to the bedrock source contain more Zn, Mn, P, Ca, Na and Fe. The kind and amount of trace elements within the deposits appear to relate largely to depositional setting, to kinds of bedrock source, and to the modes of transportation from source to peat swamp. Trace-element concentrations in the extensive Sumatra peat deposit, which represents a potentially commercial coal bed, are similar to those found in Appalachian coals except for As and Au, which are higher in the former. This similarity most likely implies that geochemical controls on mineral matter controlled the concentrations in both. Most peat deposits found in the world today are not precursors of economic coal beds because they are too local in extent, lack beds of commercial-quality peat greater than 6 m thick, and/or are too far from sea level to be rapidly by marine or marginal marine sediments before destruction by erosion and decomposition. However, the two domed deposits in Sarawak and Sumatra described above are parts of extensive, thick, low-sulfur, fuel-quality peat deposits, which have bases below the levels of rivers on coastal deltas. These are likely to be preserved in their lower part and to become precursors of tropical coal seams of potential economic importance. The lenticular and tabular peat deposits of the Atlantic and Gulf Coastal Plains, which have little chance of survival, have features resembling those in Tertiary peat deposits in alluvial settings of western North America. The quality, shape, and extent of modern and ancient peat deposits are controlled by the same factors - humidity, vegetation type, ground- and surface-water regimes, and physiographic and geologic setting. Thus, a study of modern peat deposits may help in studies of the areal distribution and the thickness and quality of ancient coal beds.

International Journal of Coal Geology↗

Geologic research in support of sustainable agriculture

The importance and role of the geosciences in studies of sustainable agriculture include such traditional research areas as, agromineral resource assessments, the mapping and classification of soils and soil amendments, and the evaluation of landscapes for their vulnerability to physical and chemical degradation. Less traditional areas of study, that are increasing in societal importance because of environmental concerns and research into sustainable systems in general, include regional geochemical studies of plant and animal trace element deficiencies and toxicities, broad-scale water quality investigations, agricultural chemicals and the hydrogeologic interface, and minimally processed and ion-exchange agrominerals. We discuss the importance and future of phosphate in the US and world based on human population growth, projected agromineral demands in general, and the unavailability of new, high-quality agricultural lands. We also present examples of studies that relate geochemistry and the hydrogeologic characteristics of a region to the bioavailability and cycling of trace elements important to sustainable agricultural systems.

Agriculture, Ecosystems and Environment↗

Chemistry and palynology of carbon seams and associated rocks from the Witwatersrand goldfields, South Africa

Carbon seams in the Witwatersrand System of South Africa host some of the richest gold concentrations in the world. A study of the microscopic characteristics in thin sections and acid residues, and of the chemical and physical nature of the carbon-bearing phases, was undertaken to gain some understanding of the biological precursors and thermal changes that have occurred since the seams were buried. The HCl HF acid-resistant organic tissues in this Early Proterozoic coal are filamentous and spherical, which are typical morphologies for microorganisms. The tissues are carbonized black as would be expected for metamorphic rocks, so usual palynological techniques were of limited use. Therefore, the chemical and physical nature of the organic remains was studied by H C "> HC ratios, X-ray diffraction (XRD), 13 C nuclear magnetic resonance (NMR), reductive chemistry, crosspolarization/magic angle spinning NMR (CP/MAS), and electron spin resonance (ESR). The H C "> HC ratios of the samples examined are similar to those of semi-anthracite and petroleum cokes from delayed cokers. XRD shows graphite is not present and that the gold is in elemental form, not chemically bound or intercalated between carbon planes. NMR shows that both aromatic and paraffinic carbons are present. Integration of the carbon NMR spectra suggests that 80% of the carbon is sp 2 -hybridized and 20% is sp 3 -hybridized. Reductive chemistry shows that the benzenoid entities are larger than common polynuclear aromatic hydrocarbons such as perylene and decacyclene. Dipolar dephasing CP/MAS NMR suggests the presence of two types of paraffinic carbons, a rigid methylene group and a rotating methyl group. The narrowing of the ESR linewidth between room temperature and 300°C shows that the materials examined have not previously been subjected to temperatures as high as 300°C.

Witwatersrand goldfields↗

Origin of the late quaternary dune fields of northeastern Colorado

Stabilized eolian deposits, mostly parabolic dunes and sand sheets, cover much of the landscape of northeastern Colorado and adjacent parts of southwestern Nebraska in four geographically distinct dune fields. Stratigraphic and soil-geomorphic relations and accelerator radiocarbon dating indicate that at least three episodes of eolian sand movement occurred between 27 ka and 11 ka, possibly between 11 ka and 4 ka, and within the past 1.5 ka. Thus, eolian sand deposition took place under both glacial and interglacial climatic conditions. In the youngest episodes of eolian sand movement, Holocene parabolic dunes partially buried Pleistocene sand sheet deposits. Late Holocene sands in the Fort Morgan and Wray dune fields, to the south of the South Platte River, have trace element ratios that are indistinguishable from modern South Platte River sands, but different from Ogallala Formation bedrock, which has previously been cited as the main source of dune sand on the Great Plains. Sands in the Greeley dune field, to the north of the South Platte River, have trace element concentrations that indicate a probable Laramie Formation source. Measurements of parabolic dunes indicate paleowinds from the northwest in all dune fields, in good agreement with resultant drift directions calculated for nearby weather stations. Thus, paleowinds were probably not significantly different from present-day winds, and are consistent with a South Platte River source for the Fort Morgan and Wray dune fields, and a Laramie Formation source for the Greeley dune field. Sand accumulated downwind of the South Platte River to form the Fort Morgan duen field. In addition, sand was also transported farther downwind over the upland formed by the calcrete caprock of the Ogallala Formation, and deposited in the lee of the upland on the southeast side. Because of high wind energy, the upland itself served as a zone of sand transport, but little or no sand accumulation took place on this surface. These studies, which demonstrate the importance of fluvial-source sediments for dune fields in Colorado, may be applicable to other dune fields in North America. Because modern drift potentials in northeastern Colorado are among the highest in the world, the present stability of dunes in the region may be in part a function of the dunes being supply-limited rather than solely transport-limited. Extensive (∼ 7700 km 2 ) late Holocene dunes document that eolian sand in northeastern Colorado is very sensitive to small changes in climate or fluvial source conditions.

Geomorphology↗

Significant results from using earth observation satellites for mineral and energy resource exploration

A large number of Earth-observation satellites orbit our world several times each day, providing new information about the land and sea surfaces and the overlying thin layer of atmosphere that makes our planet unique. Meteorological satellites have had the longest history of experimental use and most are now considered operational. The geologic information collected by the Landsat, Polar Orbiting Geophysical Observatory (POGO), Magsat, Heat Capacity Mapping Mission (HCMM) and Seasat land and ocean observation systems is being thoroughly tested, and some of these systems are now approaching operational use. Landsat multispectral images provide views of large areas of the Earth under uniform lighting conditions and can be obtained at a variety of scales and formats. Not only do the Landsat data provide highly useful images showing surficial materials and structures such as folds and faults, but also measurements and computer-derived ratios of the brightness of different rock types, alteration zones, and mineral associations. These data have led to the finding of a variety of new ore deposits. In addition, the combination of Landsat digital data and aeromagnetic data has extended the use of Landsat as an exploration tool which can be used to readily relate surface features to subsurface anomalies. Magsat data, now being collected, are helping refine information on major crustal anomalies that were first recognized during the analysis of POGO data. The more nearly circular orbit, lower altitude, and increased sophistication of its vector magnetometer enable Magsat to provide more precise information than POGO. Information of this type is required to develop crustal models. Although Magsat is designed to operate for only 4&ndash;8 months, the number of orbits that it should be able to make will be sufficient to accomplish its mission and to record a major magnetic storm expected in 1980. HCMM is a two-band visible to near-IR (0.55&ndash;1.1 &mu;m) and thermal infrared (10.2&ndash;12.5 &mu;m) system designed to measure reflected solar energy, determine the heat capacity of rocks and to monitor soil moisture, thermal effluents, plant canopy temperatures and snow cover. Launched in April 1978, it is in sun-synchronous, circular orbit at an altitude of 620 km. It is a relatively low-resolution system with an instantaneous field of view (IFOV) of 500&ndash;600 m and a swath width of 716 km. However, the system is designed to detect objects in the range of 260&deg;&ndash;340&deg; K with a sensitivity (NE&delta;T) of 0.4&deg;K at 280&deg;. Recording the thermal radiation of urban heat islands and high thermal inertia of quartzite strata in the Appalachian region are two examples of its land applications. Launched in June 1978, Seasat operated for only 100 days, but successfully acquired much information over both sea and land. The collection of synthetic aperture radar (SAR) imagery and radar altimetry was particularly important to geologists. Although there are difficulties in processing and distributing these data in a timely manner, initial evaluations indicate that the radar imagery supplements Landsat data by increasing the spectral range and offering a different look angle. The radar altimeter provides accurate profiles over narrow strips of land (1 km wide) and has demonstrated usefulness in measuring icecap surfaces (Greenland, Iceland, and Antarctica). The Salar of Uyuni in southern Bolivia served as a calibration site for the altimeter and has enabled investigators to develop a land-based smoothing algorithm that is believed to increase the accuracy of the system to 10 cm. Data from the altimeter are currently being used to measure subsidence resulting from ground water withdrawal in the Phoenix-Tucson area.

Advances in Space Research↗

Bimodal tholeiitic-dacitic magmatism and the Early Precambrian crust

Interlayered plagioclase-quartz gneisses and amphibolites from 2.7 to more than 3.6 b.y. old form much of the basement underlying Precambrian greenstone belts of the world; they are especially well-developed and preserved in the Transvaal and Rhodesian cratons. We postulate that these basement rocks are largely a metamorphosed, volcanic, bimodal suite of tholeiite and high-silica low-potash dacite—compositionally similar to the 1.8-b.y.-old Twilight Gneiss — and partly intrusive equivalents injected into the lower parts of such volcanic piles. We speculate that magmatism in the Early Precambrian involved higher heat flow and more hydrous conditions than in the Phanerozoic. Specifically, we suggest that the early degassing of the Earth produced a basaltic crust and pyrolitic upper mantle that contained much amphibole, serpentine, and other hydrous minerals. Dehydration of the lower parts of a downgoing slab of such hydrous crust and upper mantle would release sufficient water to prohibit formation of andesitic liquid in the upper part of the slab. Instead, a dacitic liquid and a residuum of amphibole and other silica-poor phases would form, according to Green and Ringwood's experimental results. Higher temperatures farther down the slab would cause total melting of basalt and generation of the tholeiitic member of the suite. This type of magma generation and volcanism persisted until the early hydrous lithosphere was consumed. An implication of this hypothesis is that about half the present volume of the oceans formed before about 2.6 b.y. ago.

Precambrian Research↗

Crystalline gold in soil and the problem of supergene nugget formation: Freezing and exclusion as genetic mechanisms

Many of the world's richest gold placer deposits now occur in cold regions despite differences in their climatic history. It therefore seems possible that there may be some fundamental connection between freezing climates and the local chemical behavior of gold in the weathering cycle. This hypothesis, along with the problematical occurrence of gold as euhedral crystals in arctic gravel and soil placers, has led me to review low temperature phenomena that may bear on the geochemistry of gold. Several effects which may influence the weathering of natural gold-bearing rocks, the chemical complexation of gold, and its subsequent mobility and deposition appear to be strongly connected with freeze action. The exclusion of dissolved solutes, solute gases, and particles from ice, subjects rock and soil minerals to increased corrosion from thin, unfrozen, adsorbed water films which remain at particle surfaces throughout the freezing of rocks and soils. The preferential exclusion of cations (over anions) from growing ice crystals creates charge separations and measurable current flow across waterice phase boundaries in freezing soil — a phenomenon which leads to troublesome seasonal electrolytic corrosion of pipelines buried in soil; this phenomenon may also favor the dissolution of normally insoluble metals such as gold during geologic time periods. The ice-induced accumulation of clays, organic acids, bacteria, and other organic matter at mineral surfaces may also speed chemical attack by providing a nearby sink of alternate cation-binding sites and hence rapid removal of liberated cations from solution. The latter mechanism may be operative in both the dissolution and redeposition of gold. These physical, chemical, and electrical effects are favorable to the dissolution of rocks (in addition to frost shattering) and to the dissolution, mobilization, and redeposition of gold and other noble metals and must therefore contribute significantly to the behavior of gold at low temperatures. The occurrence of large numbers of gold placer deposits in northern Canada, Alaska, and Siberia may thus be due in part to the low temperatures common to these regions.

Precambrian Research↗

Metallogeny of the midcontinent rift system of North America

The 1.1 Ga Midcontinent rift system of North America is one of the world's major continental rifts and hosts a variety of mineral deposits. The rocks and mineral deposits of this 2000 km long rift are exposed only in the Lake Superior region. In the Lake Superior region, the rift cuts across Precambrian basement terranes ranging in age from ∼ 1850 Ma to more than 3500 Ma. Where exposed, the rift consists of widespread tholeiitic basalt flows with local interlayered rhyolite and clastic sedimentary rocks. Beneath the center of Lake Superior the volcanic and sedimentary rocks are more than 30 km deep as shown by recent seismic reflection profiles. This region hosts two major classes of mineral deposits, magmatic and hydrothermal. All important mineral production in this region has come from hydrothermal deposits. Rift-related hydrothermal deposits include four main types: (1) native copper deposits in basalts and interflow sediments; (2) sediment-hosted copper sulfide and native copper; (3) copper sulfide veins and lodes hosted by rift-related volcanic and sedimentary rocks; and (4) polymetallic (five-element) veins in the surrounding Archean country rocks. The scarcity of sulfur within the rift rocks resulted in the formation of very large deposits of native metals. Where hydrothermal sulfides occur (i.e., shale-hosted copper sulfides), the source of sulfur was local sedimentary rocks. Magmatic deposits have locally supported exploration and minor production, but most are subeconomic presently. These deposits occur in intrusions exposed near the margins of the rift and include CuNiPGE and TiFe (V) in the Duluth Complex, U-REE-Nb in small carbonatites, and breccia pipes resulting from local hydrothermal activity around small felsic intrusions. Mineralization associated with some magmatic bodies resulted from the concentration of incompatible elements during fractional crystallization. Most of the sulfide deposits in intrusions, however, contain sulfur derived from country rocks; the interaction between magma and country rocks was important in generation of the magmatic CuNi sulfide deposits. A mantle plume origin has been proposed for the formation of the Midcontinent rift. More than 1 million km 3 of mafic magma was erupted in the rift and a comparable volume of mafic intrusions are inferred beneath the rift, providing a ready and structurally confined supply of mafic source rocks that were available for leaching of metals by basinal brines. These brines were heated by a steep geothermal gradient that resulted from the melting and underplating of magma derived from the plume. Hydrothermal deposits were emplaced for at least 30–40 m.y. after rift magmatism and extension ceased. This time lag may reflect either the time required to heat deeply buried rocks and fluids within the rift, or may be due to the timing of post-rift compression that may have provided the driving mechanism for expulsion of hydrothermal fluids from deep portions of the rift.

Precambrian Research↗