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Physical and Vegetative Characteristics of a Newly Constructed Wetland and Modified Stream Reach, Tredyffrin Township, Chester County, Pennsylvania, 2000-2006

To compensate for authorized disturbance of naturally occurring wetlands and streams during roadway improvements to U.S. Highway 202 in Chester and Montgomery Counties, Pa., the Pennsylvania Department of Transportation (PennDOT) constructed 0.42 acre of emergent wetland and 0.94 acre of scrub-shrub/forested wetland and modified sections of a 1,600-foot reach of Valley Creek with woody riparian plantings and streambank-stabilization structures (including rock deflectors). In accordance with project permits and additional guidance issued by the U.S. Army Corps of Engineers, the U.S. Geological Survey (USGS), in cooperation with PennDOT, collected data from 2000 through 2006 to quantify changes in 1) the vegetation, soils, and extent of emergent and scrub-shrub/forested parts of the constructed wetland, 2) the profile, dimension, and substrate in the vicinity of rock deflectors placed at two locations within the modified stream reach, and 3) the woody vegetation within the planted riparian buffer. The data for this investigation were collected using an approach adapted from previous investigations so that technology and findings may be more easily transferred among projects with similar objectives. Areal cover by planted and non-planted vegetation growing within the emergent and scrub-shrub/forested parts of the constructed wetland exceeded 85 percent at the end of each growing season, a criterion in special condition 25c in the U.S. Army Corps of Engineers project permit. Areal cover of vegetation in emergent and scrub-shrub/forested parts of the constructed wetland exceeded 100 percent in all but one growing season. Frequent and long-lasting soil saturation favored obligate-wetland species like Typha latifolia (broadleaf cattail) and Scirpus validus (great bulrush), both of which maintained dominance in the emergent wetland throughout the study (percent cover was 20 and 78 percent, respectively, in 2006). Echinocloa crusgalli (barnyard grass), an annual invasive from Eurasia, initially established in the newly disturbed soils of the scrub-shrub/forested wetland (areal cover was 56 percent in 2000), but by 2002, E. crusgalli was not growing in any sample plots and other species including Agrostis stolonifera (creeping bent grass), Festuca rubra (red fescue), Cornus spp. (dogwood species), and Salix nigra (black willow) were becoming more common. Sal. nigra contributed 30-percent cover in the scrub-shrub/forested wetland part by fall 2003. Rapid colonization of this species in subsequent years increased annual cover through 2006, when 15- to 25-foot tall Sal. nigra trees dominated the tree/shrub stratum (48 percent of the areal cover in 2006). The understory of the scrub-shrub/forested wetland was mostly shaded because of the canopy of Sal. nigra trees. Herbaceous species growing under and near the margins of the canopy included Ag. stolonifera and Ty. latifolia (29- and 23-percent areal cover, respectively). Flows in Valley Creek are responsible for transporting sediment and shaping the channel. Annual mean streamflow during the period the modified stream reach was monitored ranged from 15.2 cubic feet per second (ft3/s) in the 2002 water year to 53.0 ft3/s in the 2004 water year. This is a range of about 55 percent lower to 58 percent higher than the annual mean streamflow for the period of record. Despite the variability in streamflow, longitudinal profiles surveyed near rock deflectors in two short (100-foot) reaches within the modified stream reach maintained a constant slope throughout the monitoring period, most likely because of the presence of bedrock control. Cross-section geometry in the upstream reach was virtually unchanged during the monitoring period but 10 feet of bank migration was measured downstream, leaving the rock deflectors in mid-stream. As indicated by the change in channel morphology at the downstream reach, it is apparent that the rock deflectors were ineffective at adequately protecting the bank

Scientific Investigations Report↗

Exploratory water-well drilling in the Houston District, Texas

In the spring and summer of 1939 a program of exploratory drilling wad undertaken in the Houston district, Tx., in conjunction with a general initiation of the water resources of the district. The main purposes of the program were to determine the thickness and character of water-bearing sands down to a maximum depth of 2,000 feet, the chemical character of the water at different depths, and the artesian pressure and to provide additional observation wells for studying fluctuations in artesian pressure and possibilities of intrusion of salt water from the direction of the Gulf. Thirteen deep test wells, 5? inches in diameter and ranging in depth from 360 to 2,000 feet, were put down with a hydraulic rotary drill by the city of Houston. The combined drilling footage of all of the wells amounted to 17,460 feet, and their averse depth was 1,246 feet. All were electrically logged. Samples of cuttings were collected from the drilling mud after every 20 feet of drilling. In 6 of the wells sand samples were obtained by core drilling in beds at selected horizons, about 230 feet being recovered. A total of 15 samples of sand and water were obtained in 8 wells by the drill-stem method. Side-wall sampling was attempted. Six of the test holes were cased with 3? casing (inside diameter) and equipped with screens so that water-level measurements could be made and samples of water collected for chemical analyses , Selected sand samples were analyzed and tested in a field laboratory for mechanical composition, permeability, and porosity. The field and laboratory data were studied with special reference to the significance of the electrical logs. A comparison of the electrical logs of the test wells with the driller's logs shows that, on the whole, they agree remarkably well in fixing the upper and lower limits of the thicker beds of sand and clay, but that the agreement is not so close where the beds are thin. Variable results were obtained from attempts to correlate the second curve of the electrical log with the permeability and mechanical composition of the sand samples obtained by core drilling and drill-stem sampling. In the case of the core samples there was no apparent relationship between any of the three characteristics in well 3, but in well 5 a slight but distinct increase in the resistivity was accompanied by a large increase in permeability. In well 6 the resistivity in nearly every case varied with the permeability and coarseness of the samples. In well 6 the drilling mud was local clay enriched with Aquagel, whereas in wells 3 and 5 only local clay was used; the data obtained, however, are too meager to be used on a basis for even a tentative conclusion as to the effect of artificial mud on the correlations. In the 15 drill-stem sand samples the data show that, in general, the resistivity of sands having fluid content varies with but is not proportional to the permeability, but there seems to be little or no relationship between the coarseness of the sands and either the resistivity or the permeability. Studies of the relationship of the electrical logs to the salinity of the water indicate that increasing chloride is accompanied by decreasing resistivity. They suggest .that changes in the chloride content are accompanied by large changes in resistivity when the water contains less than 100 parts per million of chloride and by relatively small changes when the chloride content is over 100 parts per million. On the whole, the results of the test drilling from Houston tend to show that, although electrical logs give much information that is useful in the development of water wells, for the present at least these logs should be used in conjunction with driller's logs and drill-stem sampling of both sand and water in all the more promising sand horizons. The tests indicate that an average of 600 feet of .water-bearing sands occurs between the surface and a depth of 1,500 feet along the line of test wells we

Water Supply Paper↗

Remote sensing for environmental site screening and watershed evaluation in Utah Mine lands: East Tintic mountains, Oquirrh mountains, and Tushar mountains

Imaging spectroscopy-a powerful remote-sensing tool for mapping subtle variations in the composition of minerals, vegetation, and man-made materials on the Earth's surface-was applied in support of environmental assessments and watershed evaluations in several mining districts in the State of Utah. Three areas were studied through the use of Landsat 7 ETM+ and Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data: (1) the Tintic mining district in the East Tintic Mountains southwest of Provo, (2) the Camp Floyd mining district (including the Mercur mine) and the Stockton (or Rush Valley) mining district in the Oquirrh Mountains south of the Great Salt Lake, and (3) the Tushar Mountains and Antelope Range near Marysvale. The Landsat 7 ETM+ data were used for initial site screening and the planning of AVIRIS surveys. The AVIRIS data were analyzed to create spectrally defined maps of surface minerals with special emphasis on locating and characterizing rocks and soils with acid-producing potential (APP) and acid-neutralizing potential (ANP). These maps were used by the United States Environmental Protection Agency (USEPA) for three primary purposes: (1) to identify unmined and anthropogenic sources of acid generation in the form of iron sulfide and (or) ferric iron sulfate-bearing minerals such as jarosite and copiapite; (2) to seek evidence for downstream or downwind movement of minerals associated with acid generation, mine waste, and (or) tailings from mines, mill sites, and zones of unmined hydrothermally altered rocks; and (3) to identify carbonate and other acid-buffering minerals that neutralize acidic, potentially metal bearing, solutions and thus mitigate potential environmental effects of acid generation. Calibrated AVIRIS surface-reflectance data were spectrally analyzed to identify and map selected surface materials. Two maps were produced from each flightline of AVIRIS data: a map of iron-bearing minerals and water having absorption features in the spectral region from 0.35 µ m to 1.35 µ m and a map of minerals (including clays, sulfates, micas, and carbonates) having absorptions in the spectral region from 1.45 µ m to 2.51 µ m. Several methods were used to verify the AVIRIS mapping results, including field checking of selected locations with a portable spectrometer, visual inspection of the AVIRIS reflectance spectra, and X-ray diffraction (XRD) analysis of field samples. The maps of iron-bearing minerals derived from analysis of the visible (VIS) and near-infrared (NIR) regions of the electromagnetic spectrum were shown to be more consistently reliable in indicating the presence of jarosite than were the maps generated from analysis of the short-wave infrared (SWIR) region. When present in abundance, phyllosilicate minerals tend to dominate the SWIR and mask the spectral features of jarosite in that wavelength region. The crystal field absorptions of jarosite in the VIS and NIR spectral regions will commonly be present regardless of whether the Fe-OH absorption feature near 2.27 µ m can be detected. For this reason, the VIS and NIR were preferable to the SWIR for the remote spectroscopic identification of jarosite (and other iron-bearing minerals). Large exposures of unmined hydrothermally altered rocks occur throughout the three study areas. These rocks commonly contain sulfide or sulfate minerals that produce sulfuric acid upon subaerial oxidation. The acid may be introduced into local surface and ground water and thus lower the baseline (that is, the premining) pH for a watershed.

Utah↗

Status and understanding of groundwater quality in the North San Francisco Bay groundwater basins, 2004: California GAMA Priority Basin Project

Groundwater quality in the approximately 1,000-square-mile (2,590-square-kilometer) North San Francisco Bay study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in northern California in Marin, Napa, and Sonoma Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA North San Francisco Bay study was designed to provide a spatially unbiased assessment of untreated groundwater quality in the primary aquifer systems. The assessment is based on water-quality and ancillary data collected by the USGS from 89 wells in 2004 and water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer systems (hereinafter referred to as primary aquifers) were defined by the depth interval of the wells listed in the CDPH database for the North San Francisco Bay study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifers; shallower groundwater may be more vulnerable to surficial contamination. The first component of this study, the status of the current quality of the groundwater resource, was assessed by using data from samples analyzed for volatile organic compounds (VOC), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources within the primary aquifers of the North San Francisco Bay study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal and (or) California benchmarks. A relative-concentration greater than (>) 1.0 indicates a concentration above a benchmark, and less than or equal to (≤) 1.0 indicates a concentration equal to or below a benchmark. Relative-concentrations of organic and special interest constituents were classified as “high” (relative-concentration > 1.0), “moderate” (0.1 < relative-concentration ≤ 1.0), or “low” (relative-concentration ≤ 0.1). Inorganic constituent relative-concentrations were classified as “high” (relative-concentration > 1.0), “moderate” (0.5 < relative-concentration ≤ 1.0), or “low” (relative-concentration ≤ 0.5). Aquifer-scale proportion was used as a metric for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the primary aquifers that have a relative-concentration greater than 1.0; proportion is calculated on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifers that have moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based and spatially-weighted—were used to evaluate aquifer-scale proportion for individual constituents and classes of constituents. Grid-based and spatially-weighted estimates were comparable in the North San Francisco Bay study unit (90-percent confidence intervals). For inorganic constituents with human-health benchmarks, relative-concentrations were high in 14.0 percent of the primary aquifers, moderate in 35.8 percent, and low in 50.2 percent. The high aquifer-scale proportion of inorganic constituents primarily reflected high aquifer-scale proportions of arsenic (10.0 percent), boron (4.1 percent), and lead (1.6 percent). In contrast, relative-concentrations of organic constituents (one or more) were high in 1.4 percent, moderate in 4.9 percent, and low in 93.7 percent (not detected in 64.8 percent) of the primary aquifers. The high aquifer-scale proportion of organic constituents primarily reflected high aquifer-scale proportions of PCE (1.3 percent), TCE (0.1 percent), and 1,1-dichloroethene (0.1 percent). The inorganic constituents with secondary maximum contaminant levels (SMCL), manganese and iron, had relative-concentrations that were high in 40.8 percent and 24.4 percent of the primary aquifers, respectively. Of the 255 organic and special-interest constituents analyzed for, 26 constituents were detected. Two organic constituents were frequently detected (in 10 percent or more of samples), the trihalomethane chloroform and the herbicide simazine, but both were detected at low relative-concentrations. The second component of this study, the understanding assessment, identified the natural and human factors that affect groundwater quality by evaluating land use, physical characteristics of the wells, geochemical conditions of the aquifer, and water temperature. Results from these evaluations were used to explain the occurrence and distribution of constituents in the study unit. The understanding assessment indicated that a majority of the wells that contained nitrate also had an urban or agricultural land-use classification, had a modern or mixed age classification, and had depths to their top perforations <100 ft (30 m). Geochemical data are consistent with partial denitrification of nitrate in some reducing groundwaters in the terminal and deeper parts of the flow system. High and moderate relative-concentrations of arsenic may be attributed to reductive dissolution of manganese or iron oxides, or to desorption or inhibition of arsenic sorption under alkaline conditions. Arsenic concentrations increased with increasing depth and groundwater age in the North San Francisco Bay study unit. High to moderate relative-concentrations of boron were primarily associated with hydrothermal activity or high-salinity waters in the Napa Sonoma lowlands. Simazine was detected in groundwater classified as modern and mixed age more often than in groundwater classified as pre-modern age, while chloroform was detected most often in groundwater classified as mixed age. Simazine and chloroform also were observed in wells that had surrounding land use classified as agricultural or land use classified as urban, and top of perforation depths less than 100 ft (30 m). Together, the occurrence of chloroform and simazine in shallow wells with modern or mixed groundwater located in urban or agricultural areas suggests that these constituents result from anthropogenic activities during the last 50 years. Tritium, helium-isotope, and carbon-14 data were used to classify the predominant age of groundwater samples into three categories: modern (water that has entered the aquifer in the last 50 years), pre-modern (water that entered the aquifer more than 50 years to tens of thousands of years ago), and mixed (mixtures of modern- and pre-modern-age waters). Arsenic, iron, and total dissolved solids (TDS) concentrations were significantly greater in groundwater having pre-modern-age classification than modern, suggesting that these constituents accumulate with groundwater residence time.

California↗

Investigations needed to stimulate the development of Jordan's mineral resources

The level of living that any society can attain is a direct function of the use it makes of all kinds of raw materials (soil, water, metals, nonmetals, etc.), all kinds of energy (both animate and inanimate), and all kinds of human ingenuity; and is an inverse function of the size of the population that must share the collective product. The relation between raw materials, energy and ingenuity is such that use of a large amount of one may offset the need for large amounts of others. The most vital raw materials are water, soil, and construction materials, for these are needed in large quantities and are hard to import. Metals, chemicals, and inanimate energy are necessary for industrialization. The more of these minerals a nation possess, the better, but not nation can hope to be self-sufficient in all of the m and therefore must trade for some essential materials. Jordan’s natural resources have been little explored. The grantitc-metamorphic terrane in the southeastern part of the Kingdom could contain deposits of tungsten, rare earths, feldspar, mica, fluorite etc. and the sedimentary terrane over much of the rest of the county is favorable for the occurrence of oil. Even if none of these minerals is found, however, Jordan’s other mineral resource, if fully explored and developed in the light of modern technology, will support a far higher level of living than her people now enjoy. Very likely she can increase her rainfall by about 10 percent by cloud seeding, and she undeveloped supplies in both surface and ground water that are sufficient to nearly double her usable water supply. Even if she does not have oil or have it in large quantities, she can buy it cheaply from neighboring counties, and in addition has undeveloped sources of hydroelectric power, large reserves of bituminous limestone, large reserves of nuclear power as uranium in phosphate rock, and can use solar and wind power for special purposes. Her large supplies of construction, fertilizer, and other chemical raw materials will not only satisfy her own needs, but will yield both raw materials and some manufactured products for export. And she has valuable resource of touristic interest in the form of incomparable scenery, antiquities, and holy places, which, if properly advertised, could well become her largest single source of foreign currency. Revenues obtained from this source and from the export of agricultural products, nonmetallic minerals, and mineral products should support foreign oil purchase of oil, machinery, and other products not mined or produced internally. Full development of Jordan’s economic potential will take years to achieve and involves many complex activities. One of the most essential is one that can be pressed in the early years, namely the gathering of facts and basic data concerning the character, extent, and distribution of her resources, and the uses that can be made of them. Without each fundamental data or the understanding of their meaning or the ways to use and apply them, costly developmental projects and similar efforts to raise the level of living are likely to have limited success at best. Basic data and mineral resources are best gathered and published by permanent government agencies, for private organizations and individual cannot afford to take the risks involved in gathering data that may not have an immediate economic return; and even if private parties do collect such data they are not likely to make them general available. Of the activities needed in the field of mineral resources, some are already underway as the established function of government agencies. No bureau however, seems to have responsibility for making geologic maps and for gathering data on such things as steam flow, composition and properties of minerals and rocks, or for investigating the uses to which Jordan’s minerals might be put. To satisfy these needs, a Geological Survey and a Bureau of Mineral Industries should be formed and placed in operation as quickly as possible. The task of collecting and interpreting basic data or mineral resources must be done largely by Jordanians, for only in this way will Jordan acquire the technical competence needed to use the information. Few Jordanians have enough training or experience to work independently in these fields now, however, so help from outside technicians would be necessary over an initial training period of several years. But the number of outside technicians should never exceed the number of Jordanian technicians, and for this reason, neither organization could have a staff of more than a few people during the early years of operation.

Open-File Report↗

A framework for assessing the sustainability of monitored natural attenuation

The sustainability of monitored natural attenuation (MNA) over time depends upon (1) the presence of chemical/biochemical processes that transform wastes to innocuous byproducts, and (2) the availability of energy to drive these processes to completion. The presence or absence of contaminant-transforming chemical/biochemical processes can be determined by observing contaminant mass loss over time and space (mass balance). The energy available to drive these processes to completion can be assessed by measuring the pool of metabolizable organic carbon available in a system, and by tracing the flow of this energy to available electron acceptors (energy balance). For the special case of chlorinated ethenes in ground-water systems, for which a variety of contaminant-transforming biochemical processes exist, natural attenuation is sustainable when the pool of bioavailable organic carbon is large relative to the carbon flux needed to drive biodegradation to completion. These principles are illustrated by assessing the sustainability of MNA at a chlorinated ethene-contaminated site in Kings Bay, Georgia. Approximately 1,000 kilograms of perchloroethene (PCE) was released to a municipal landfill in the 1978-1980 timeframe, and the resulting plume of chlorinated ethenes migrated toward a nearby housing development. A numerical model, built using the sequential electron acceptor model code (SEAM3D), was used to quantify mass and energy balance in this system. The model considered the dissolution of non-aqueous phase liquid (NAPL) as the source of the PCE, and was designed to trace energy flow from dissolved organic carbon to available electron acceptors in the sequence oxygen > chlorinated ethenes > ferric iron > sulfate > carbon dioxide. The model was constrained by (1) comparing simulated and measured rates of ground-water flow, (2) reproducing the observed distribution of electron-accepting processes in the aquifer, (3) comparing observed and measured concentrations of chlorinated ethenes, and (4) reproducing the observed production and subsequent dilution of dissolved chloride, a final degradation product of chloroethene biodegradation. Simulations using the constrained model indicated that an average flux of 5 milligrams per liter per day of organic carbon (CH2O) per model cell (25 square meters) is required to support the short-term sustainability of MNA. Because this flux is small relative to the pool of renewable organic carbon (about 4.7 x 107 milligrams [mg] per model cell) present in the soil zone and non-renewable carbon (about 6.9 x 108 mg per model cell) in an organic-rich sediment layer overlying the aquifer, the long-term sustainability of MNA is similarly large. This study illustrates that the short- and long-term sustainability of MNA can be assessed by: 1. Estimating the time required for contaminants to dissolve/disperse/degrade under ambient hydrologic conditions (time of remediation). 2. Quantifying the organic carbon flux to the system needed to consume competing electron acceptors (oxygen) and direct electron flow toward chloroethene degradation (short-term sustainability). 3. Comparing the required flux of organic carbon to the pool of renewable and non-renewable organic carbon given the estimated time of remediation (long-term sustainability). These are general principles that can be used to assess the sustainability of MNA in any hydrologic system.

Circular↗

Ground-water quality data in the San Fernando-San Gabriel study unit, 2005— Results from the California GAMA program

Ground-water quality in the approximately 460 square mile San Fernando-San Gabriel study unit (SFSG) was investigated between May and July 2005 as part of the Priority Basin Assessment Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin Assessment Project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The San Fernando-San Gabriel study was designed to provide a spatially unbiased assessment of raw ground-water quality within SFSG, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 52 wells in Los Angeles County. Thirty-five of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and seventeen wells were selected to aid in the evaluation of specific water-quality issues or changes in water chemistry along a historic ground-water flow path (understanding wells). The ground-water samples were analyzed for a large number of synthetic organic constituents [volatile organic compounds (VOCs), pesticides and pesticide degradates], constituents of special interest [perchlorate, N-nitrosodimethylamine (NDMA), 1,2,3-trichloropropane (1,2,3-TCP), and 1,4-dioxane], naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, and carbon-14, and stable isotopes of hydrogen, oxygen, and carbon), and dissolved noble gases also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blanks, replicates, samples for matrix spikes) were collected at approximately one-fifth (11 of 52) of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control results showed that the data had very little bias or variability and resulted in censoring of less than 0.7 percent (32 of 4,484 measurements) of the data collected for ground-water samples. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, or blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. VOCs were detected in more than 90 percent (33 of 35) of grid wells. For all wells sampled for SFSG, nearly all VOC detections were below health-based thresholds, and most were less than one-tenth of the threshold values. Samples from seven wells had at least one detection of PCE, TCE, tetrachloromethane, NDMA, or 1,2,3-TCP at or above a health-based threshold. Pesticides were detected in about 90 percent (31 of 35) grid wells and all detections in samples from SFSG wells were below health-based thresholds. Major ions, trace elements, and nutrients in samples from 17 SFSG wells were all below health-based thresholds, with the exception of one detection of nitrate that was above the USEPA maximum contaminant level (MCL-US). With the exception of 14 samples having radon-222 above the proposed MCL-US, radioactive constituents were below health-based thresholds for 16 of the SFSG wells sampled. Total dissolved solids in 6 of the 24 SFSG wells that were sampled ha

California↗

Grain-size distribution and selected major and trace element concentrations in bed-sediment cores from the Lower Granite Reservoir and Snake and Clearwater Rivers, eastern Washington and northern Idaho, 2010

Lower Granite Dam impounds the Snake and Clearwater Rivers in eastern Washington and northern Idaho, forming Lower Granite Reservoir. Since 1975, the U.S. Army Corps of Engineers has dredged sediment from the Lower Granite Reservoir and the Snake and Clearwater Rivers in eastern Washington and northern Idaho to keep navigation channels clear and to maintain the flow capacity. In recent years, other Federal agencies, Native American governments, and special interest groups have questioned the negative effects that dredging might have on threatened or endangered species. To help address these concerns, the U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers, collected and analyzed bed-sediment core samples (hereinafter cores) in Lower Granite Reservoir and impounded or backwater affected parts of the Snake and Clearwater Rivers. Cores were collected during the spring and fall of 2010 from submerged sampling locations in the Lower Granite Reservoir, and Snake and Clearwater Rivers. A total of 69 cores were collected by using one or more of the following corers: piston, gravity, vibrating, or box. From these 69 cores, 185 subsamples were removed and submitted for grain size analyses, 50 of which were surficial-sediment subsamples. Fifty subsamples were also submitted for major and trace elemental analyses. Surficial-sediment subsamples from cores collected from sites at the lower end of the reservoir near the dam, where stream velocities are lower, generally had the largest percentages of silt and clay (more than 80 percent). Conversely, all of the surficial-sediment subsamples collected from sites in the Snake River had less than 20 percent silt and clay. Most of the surficial-sediment subsamples collected from sites in the Clearwater River contained less than 40 percent silt and clay. Surficial-sediment subsamples collected near midchannel at the confluence generally had more silt and clay than most surficial-sediment subsamples collected from sites on the Snake and Clearwater Rivers or even sites further downstream in Lower Granite Reservoir. Two cores collected at the confluence and all three cores collected on the Clearwater River immediately upstream from the confluence were extracted from a thick sediment deposit as shown by the cross section generated from the bathymetric surveys. The thick sediment deposits at the confluence and on the Clearwater River may be associated with floods in 1996 and 1997 on the Clearwater River. Fifty subsamples from 15 cores were analyzed for major and trace elements. Concentrations of trace elements were low, with respect to sediment quality guidelines, in most cores. Typically, major and trace element concentrations were lower in the subsamples collected from the Snake River compared to those collected from the Clearwater River, the confluence of the Snake and Clearwater Rivers, and Lower Granite Reservoir. Generally, lower concentrations of major and trace elements were associated with coarser sediments (larger than 0.0625 millimeter) and higher concentrations of major and trace elements were associated with finer sediments (smaller than 0.0625 millimeter).

Idaho, Washington↗

Department of the Interior metadata implementation guide—Framework for developing the metadata component for data resource management

The Department of the Interior (DOI) is a Federal agency with over 90,000 employees across 10 bureaus and 8 agency offices. Its primary mission is to protect and manage the Nation’s natural resources and cultural heritage; provide scientific and other information about those resources; and honor its trust responsibilities or special commitments to American Indians, Alaska Natives, and affiliated island communities. Data and information are critical in day-to-day operational decision making and scientific research. DOI is committed to creating, documenting, managing, and sharing high-quality data and metadata in and across its various programs that support its mission. Documenting data through metadata is essential in realizing the value of data as an enterprise asset. The completeness, consistency, and timeliness of metadata affect users’ ability to search for and discover the most relevant data for the intended purpose; and facilitates the interoperability and usability of these data among DOI bureaus and offices. Fully documented metadata describe data usability, quality, accuracy, provenance, and meaning. Across DOI, there are different maturity levels and phases of information and metadata management implementations. The Department has organized a committee consisting of bureau-level points-of-contacts to collaborate on the development of more consistent, standardized, and more effective metadata management practices and guidance to support this shared mission and the information needs of the Department. DOI’s metadata implementation plans establish key roles and responsibilities associated with metadata management processes, procedures, and a series of actions defined in three major metadata implementation phases including: (1) Getting started—Planning Phase, (2) Implementing and Maintaining Operational Metadata Management Phase, and (3) the Next Steps towards Improving Metadata Management Phase. DOI’s phased approach for metadata management addresses some of the major data and metadata management challenges that exist across the diverse missions of the bureaus and offices. All employees who create, modify, or use data are involved with data and metadata management. Identifying, establishing, and formalizing the roles and responsibilities associated with metadata management are key to institutionalizing a framework of best practices, methodologies, processes, and common approaches throughout all levels of the organization; these are the foundation for effective data resource management. For executives and managers, metadata management strengthens their overarching views of data assets, holdings, and data interoperability; and clarifies how metadata management can help accelerate the compliance of multiple policy mandates. For employees, data stewards, and data professionals, formalized metadata management will help with the consistency of definitions, and approaches addressing data discoverability, data quality, and data lineage. In addition to data professionals and others associated with information technology; data stewards and program subject matter experts take on important metadata management roles and responsibilities as data flow through their respective business and science-related workflows. The responsibilities of establishing, practicing, and governing the actions associated with their specific metadata management roles are critical to successful metadata implementation.

Techniques and Methods↗

Ground-water quality data in the southeast San Joaquin Valley, 2005–2006— Results from the California GAMA program

Ground-water quality in the approximately 3,800 square-mile Southeast San Joaquin Valley study unit (SESJ) was investigated from October 2005 through February 2006 as part of the Priority Basin Assessment Project of Ground-Water Ambient Monitoring and Assessment (GAMA) Program. The GAMA Statewide Basin Assessment project was developed in response to the Ground-Water Quality Monitoring Act of 2001 and is being conducted by the California State Water Resources Control Board (SWRCB) in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory (LLNL). The SESJ study was designed to provide a spatially unbiased assessment of raw ground-water quality within SESJ, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 99 wells in Fresno, Tulare, and Kings Counties, 83 of which were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study area (grid wells), and 16 of which were sampled to evaluate changes in water chemistry along ground-water flow paths or across alluvial fans (understanding wells). The ground-water samples were analyzed for a large number of synthetic organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, and pharmaceutical compounds), constituents of special interest (perchlorate, N-nitrosodimethylamine, and 1,2,3-trichloropropane), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, and carbon-14, and stable isotopes of hydrogen, oxygen, nitrogen, and carbon), and dissolved noble gases also were measured to help identify the source and age of the sampled ground water. Quality-control samples (blanks, replicates, samples for matrix spikes) were collected at approximately 10 percent of the wells, and the results for these samples were used to evaluate the quality of the data for the ground-water samples. Assessment of the quality-control data resulted in censoring of less than 1 percent of the detections of constituents measured in ground-water samples. This study did not attempt to evaluate the quality of drinking water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable drinking-water quality. Regulatory thresholds apply to the treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and other health-based thresholds established by the U.S. Environmental Protection Agency and California Department of Public Health (CDPH) and thresholds established for aesthetic concerns by CDPH. Two VOCs were detected above health-based thresholds: 1,2-dibromo-3-chloropropane (DBCP), and benzene. DBCP was detected above the U.S. Environmental Protections Agency’s maximum contaminant level (MCL-US) in three grid wells and five understanding wells. Benzene was detected above the CDPH’s maximum contaminant level (MCL-CA) in one grid well. All pesticide detections were below health-based thresholds. Perchlorate was detected above its maximum contaminate level for California in one grid well. Nitrate was detected above the MCL-US in six samples from understanding wells, of which one was a public supply well. Two trace elements were detected above MCLs-US: arsenic and uranium. Arsenic was detected above the MCL-US in four grid wells and two understanding wells; uranium was detected above the MCL-US in one grid well and one understanding well. Gross alpha radiation was detected above MCLs-US in five samples; four of them understanding wells, and uranium isotope activity was greater than the MCL-US for one understanding well. Radon-222 was detected above the proposed MCL-US in all wells sampled. Total coliforms were detected in two wells and somatic coliphage was detected in one well.

California↗

Methods for determining magnitude and frequency of floods in California, based on data through water year 2006

Methods for estimating the magnitude and frequency of floods in California that are not substantially affected by regulation or diversions have been updated. Annual peak-flow data through water year 2006 were analyzed for 771 streamflow-gaging stations (streamgages) in California having 10 or more years of data. Flood-frequency estimates were computed for the streamgages by using the expected moments algorithm to fit a Pearson Type III distribution to logarithms of annual peak flows for each streamgage. Low-outlier and historic information were incorporated into the flood-frequency analysis, and a generalized Grubbs-Beck test was used to detect multiple potentially influential low outliers. Special methods for fitting the distribution were developed for streamgages in the desert region in southeastern California. Additionally, basin characteristics for the streamgages were computed by using a geographical information system. Regional regression analysis, using generalized least squares regression, was used to develop a set of equations for estimating flows with 50-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent annual exceedance probabilities for ungaged basins in California that are outside of the southeastern desert region. Flood-frequency estimates and basin characteristics for 630 streamgages were combined to form the final database used in the regional regression analysis. Five hydrologic regions were developed for the area of California outside of the desert region. The final regional regression equations are functions of drainage area and mean annual precipitation for four of the five regions. In one region, the Sierra Nevada region, the final equations are functions of drainage area, mean basin elevation, and mean annual precipitation. Average standard errors of prediction for the regression equations in all five regions range from 42.7 to 161.9 percent. For the desert region of California, an analysis of 33 streamgages was used to develop regional estimates of all three parameters (mean, standard deviation, and skew) of the log-Pearson Type III distribution. The regional estimates were then used to develop a set of equations for estimating flows with 50-, 20-, 10-, 4-, 2-, 1-, 0.5-, and 0.2-percent annual exceedance probabilities for ungaged basins. The final regional regression equations are functions of drainage area. Average standard errors of prediction for these regression equations range from 214.2 to 856.2 percent. Annual peak-flow data through water year 2006 were analyzed for eight streamgages in California having 10 or more years of data considered to be affected by urbanization. Flood-frequency estimates were computed for the urban streamgages by fitting a Pearson Type III distribution to logarithms of annual peak flows for each streamgage. Regression analysis could not be used to develop flood-frequency estimation equations for urban streams because of the limited number of sites. Flood-frequency estimates for the eight urban sites were graphically compared to flood-frequency estimates for 630 non-urban sites. The regression equations developed from this study will be incorporated into the U.S. Geological Survey (USGS) StreamStats program. The StreamStats program is a Web-based application that provides streamflow statistics and basin characteristics for USGS streamgages and ungaged sites of interest. StreamStats can also compute basin characteristics and provide estimates of streamflow statistics for ungaged sites when users select the location of a site along any stream in California.

California↗

Results of a workshop concerning assessment of the functions of bottomland hardwoods

The U.S. Environmental Protection Agency (EPA) is authorized under Section 404 of the Clean Water Act (33 U.S.C. 1344) to participate in the regulation of the discharge of dredged or fill material into waters of the United States. This regulatory authority is exercised in partnership with the U.S. Army Corps of Engineers, which has responsibility for permit issuance, and in consultation with the U.S. Fish and Wildlife Service and the National Marine Fisheries Service. Through amendments to the original statute, a series of legal actions and court decisions, and the development of operating guidance among the responsible agencies, Section 404 has evolved into the primary mechanism afforded Federal authorities for the protection of wetlands. EPA recognizes the importance of wetlands in achieving the goals of the Clean Water Act, which are to protect and maintain the chemical, physical, and biological integrity of the Nation’s waters. EPA Administrator Lee Thomas has identified wetlands protection as among the highest of Agency priorities. EPA recognizes that bottomland hardwood (BLH) wetlands have vital and unique attributes that, if lost, would severely impact the physical, chemical, and biological integrity of the Nation's waters. As part of a broad program to better protect the Nation's wetlands, EPA has therefore identified bottomland hardwood wetlands as a priority resource requiring special attention on a national basis. Recognizing the importance of implementing an effective, nationally consistent, and scientifically defensible regulatory program, EPA, in October 1984, issued Interim Operating Guidance to its field personnel for implementing the Section 404 regulatory program in bottomland hardwood wetlands. With the goal of improving and finalizing that guidance, EPA is sponsoring a series of workshops designed to answer key questions concerning BLH wetlands, based on the best scientific and technical information currently available. The first two workshops were directed toward summarizing existing scientific and technical knowledge concerning the functions of BLH ecosystems, the characteristics that are important to each function, and the impact of various development activities on those characteristics. The first workshop, which was held in St. Francisville, Louisiana, in December, 1984, examined a wetland zonation concept as a framework for gaining a greater understanding of BLH structure and function. The workshop set out to determine whether characterization of BLH resources as a series of relatively distinct zones, defined by concomitant variation in hydrologic regime, soils, and vegetation, might provide the basis for a useful and scientifically sound regulatory framework. For examp1e, if certain zones are of particular importance to one or more wetland functions that the Clean Water Act was intended to protect, then the zonation concept might be useful from the perspective of how various activities should be regulated. Discussions during the first workshop, however, indicated that the zonation concept provides, at best, only an incomplete picture of the structure and function of BLH ecosystems. In many cases, BLH functions are not limited to or closely correlated with particular zones and, furthermore, many factors other than zone are important determinants of BLH functions. With these responses in mind, the second workshop, held at Lake Lanier, Georgia, in July, 1985, was designed to elicit information on two questions. First, if zones are not an adequate framework for understanding the functions of BLH systems, what characteristics (predictors) can be used to assess the extent to which a particular site performs these functions? And second, what are the impacts of various development activities that often occur in BLH ecosystems on those characteristics and thus on the functions themselves? At the second workshop, individual workgroups dealing with particular subject areas (e.g., hydrology, water quality, fisheries, wildlife, ecosystem processes, and cultural/recreational/economic resources) were able to identify site characteristics that are important determinants of the performance of various functions. For example, the Hydrology Workgroup identified flood storage as one of three major hydrologic functions that BLH ecosystems perform. The workgroup then identified the most important characteristic (e.g., surface area of the site, soil saturation, and others) that determine flood storage and the likely impact of several common activities (e.g., conversion to soybean production and levee construction) on these characteristics. Some of the workgroups also provided estimates of the aggregate impact of activities, acting through all of the characteristics, on certain functions. The workgroups also identified key characteristics that could be used to identify high-value wetlands for various functions. In addition, the workgroups pointed out a number of topics needing further examination and discussion. First, all of the workgroups identified the need to develop the technical basis and information sources to address the problem of cumulative impacts in the regulatory process. Second, most of the workgroups noted the important of contextual variables in assessing the function of a particular site. For example, the location of a BLH site in relationship to other tracts of habitat is an important variable for many wildlife species. Similarly, the extent to which a site retains or transforms contaminants is depended not only on the characteristics of the site, but also on its position in a watershed relative to contaminant inputs. And finally, several of the workgroups pointed out that assessing the impact of an activity on a function is not as simple as "adding up" the impact on individual characteristics, but may depend instead on complex interactions among characteristics. Addressing these questions, as summarized in the objectives and discussions that follow, was the focus of the third workshop, the results of which are described in this report.

Report↗

Status of groundwater quality in the Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts study unit, 2008-2010: California GAMA Priority Basin Project

Groundwater quality in the approximately 963-square-mile Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in southern California in San Bernardino, Riverside, San Diego, and Imperial Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The GAMA Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts study was designed to provide a spatially unbiased assessment of the quality of untreated (raw) groundwater in the primary aquifer system. The assessment is based on water-quality and ancillary data collected by the U.S. Geological Survey from 52 wells (49 grid wells and 3 understanding wells) and on water-quality data from the California Department of Public Health database. The primary aquifer system was defined by the depth intervals of the wells listed in the California Department of Public Health database for the Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts study unit. The quality of groundwater in the primary aquifer system may be different from that in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. This study assesses the status of the current quality of the groundwater resource by using data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources in the primary aquifer system of the Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal or California regulatory or non-regulatory benchmarks for drinking-water quality. A relative-concentration greater than 1.0 indicates a concentration greater than a benchmark, and a relative-concentration less than or equal to 1.0 indicates a concentration equal to or less than a benchmark. Relative-concentrations of organic constituents and special-interest constituents [perchlorate and N-nitrosodimethylamine (NDMA)] were classified as high (relative-concentration greater than 1.0), moderate (relative-concentration greater than 0.1 and less than or equal to 1.0), or low (relative-concentration less than or equal to 0.1). Relative-concentrations of inorganic constituents were classified as high (relative-concentration greater than 1.0), moderate (relative-concentration greater than 0.5 and less than or equal to 1.0), or low (relative-concentration less than or equal to 0.5). Aquifer-scale proportion was used as the primary metric in the status assessment for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the area of the primary aquifer system with a high relative-concentration for a particular constituent or class of constituents; this percentage is based on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentages of the primary aquifer system with moderate and low relative-concentrations, respectively, of a constituent or class of constituents. Two statistical approaches—grid-based and spatially weighted—were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. Grid-based and spatially weighted estimates were comparable to each other (within 90-percent confidence intervals) in the study unit. Inorganic constituents (one or more) with health-based benchmarks were detected at high relative-concentrations in 48 percent of the primary aquifer system and at moderate relative-concentrations in 26 percent of the primary aquifer system. The high aquifer-scale proportion of inorganic constituents primarily reflected high aquifer-scale proportions of fluoride (27 percent), arsenic (18 percent), molybdenum (16 percent), boron (10 percent), uranium (5.6 percent), gross alpha radioactivity (9.7 percent), and nitrate (2.7 percent). The inorganic constituents with secondary maximum contaminant levels (SMCLs) were detected at high relative-concentrations in 13 percent of the primary aquifer system and at moderate relative-concentrations in 39 percent. The high aquifer-scale proportion for SMCL constituents reflected high aquifer-scale proportions of total dissolved solids (TDS, 11 percent), manganese (2.8 percent), and chloride (2.8 percent). Organic constituents were not detected at high relative-concentrations in the primary aquifer system, and were present at moderate relative-concentrations in 5.0 percent, and at low relative-concentrations or were not detected in 95 percent of the primary aquifer system. Of the 148 organic constituents analyzed, 12 constituents were detected. Two organic constituents, chloroform and tetrachloroethene (PCE), were detected in more than 10 percent of samples, but were detected mostly at low relative-concentrations.

California↗

Geochemical Exploration Techniques Applicable in the Search for Copper Deposits

Geochemical exploration is an important part of copper-resource evaluation. A large number of geochemical exploration techniques, both proved and untried, are available to the geochemist to use in the search for new copper deposits. Analyses of whole-rock samples have been used in both regional and local geochemical exploration surveys in the search for copper. Analyses of mineral separates, such as biotite, magnetite, and sulfides, have also been used. Analyses of soil samples are widely used in geochemical exploration, especially for localized surveys. It is important to distinguish between residual and transported soil types. Orientation studies should always be conducted prior to a geochemical investigation in a given area in order to determine the best soil horizon and the best size of soil material for sampling in that area. Silty frost boils, caliche, and desert varnish are specialized types of soil samples that might be useful sampling media. Soil gas is a new and potentially valuable geochemical sampling medium, especially in exploring for buried mineral deposits in arid regions. Gaseous products in samples of soil may be related to base-metal deposits and include mercury vapor, sulfur dioxide, hydrogen sulfide, carbon oxysulfide, carbon dioxide, hydrogen, oxygen, nitrogen, the noble gases, the halogens, and many hydrocarbon compounds. Transported materials that have been used in geochemical sampling programs include glacial float boulders, glacial till, esker gravels, stream sediments, stream-sediment concentrates, and lake sediments. Stream-sediment sampling is probably the most widely used and most successful geochemical exploration technique. Hydrogeochemical exploration programs have utilized hot- and cold-spring waters and their precipitates as well as waters from lakes, streams, and wells. Organic gel found in lakes and at stream mouths is an unproved sampling medium. Suspended material and dissolved gases in any type of water may also be useful media. Samples of ice and snow have been used for limited geochemical surveys. Both geobotanical and biogeochemical surveys have been successful in locating copper deposits in many parts of the world. Micro-organisms, including bacteria and algae, are other unproved media that should be studied. Animals can be used in geochemical-prospecting programs. Dogs have been used quite successfully to sniff out hidden and exposed sulfide minerals. Tennite mounds are commonly composed of subsurface material, but have not as yet proved to be useful in locating buried mineral deposits. Animal tissue and waste products are essentially unproved but potentially valuable sampling media. Knowledge of the location of areas where trace-element-associated diseases in animals and man are endemic as well as a better understanding of these diseases, may aid in identifying regions that are enriched in or depleted of various elements, including copper. Results of analyses of gases in the atmosphere are proving valuable in mineral-exploration surveys. Studies involving metallic compounds exhaled by plants into the atmosphere, and of particulate matter suspended in the atmosphere are reviewed these methods may become important in the future. Remote-sensing techniques are useful for making indirect measurements of geochemical responses. Two techniques applicable to geochemical exploration are neutron-activation analysis and gamma-ray spectrometry. Aerial photography is especially useful in vegetation surveys. Radar imagery is an unproved but potentially valuable method for use in studies of vegetation in perpetually clouded regions. With the advent of modern computers, many new techniques, such as correlation analysis, regression analysis, discriminant analysis, factor analysis, cluster analysis, trend-surface analysis, and moving-average analysis can be applied to geochemical data sets. Selective use of these techniques can provide new insights into the interpretatio

Professional Paper↗

Monitoring lahars

Introduction Lahars, or debris flows that originate from a volcano (Pierson and Scott, 1985; Pierson, 1995), are among the most destructive, far-reaching, and persistent hazards on stratovolcanoes. Lahars may be triggered by syneruptive rapid melting of snow and ice, lake breakouts, or heavy rains in conjunction with large eruptive columns. Alternatively, lahars can follow eruptions, when clastic deposits are mobilized by heavy rainfall or lake breakouts, occurring sporadically for years to decades after large eruptions. Some lahars can travel many tens of kilometers in river drainages stemming from volcanoes, as during the 1980 eruption of Mount St. Helens (Washington) (for example, Janda and others, 1981), recent eruptions of Redoubt Volcano (Alaska) (fig. H1; Dorava and Meyer, 1994; Waythomas and others, 2013), and the 1991 eruption of Mount Pinatubo (Philippines) (Major and others, 1996; Pierson and others, 1996). Large lahars are less likely in the absence of eruptive activity, but still possible. The Electron Mudflow at Mount Rainier (approximately A.D. 1500), Wash., is an example of a potential noneruptive lahar, likely initiated by a spontaneous collapse of weak rock, that reached the Puget Lowland after it flowed dozens of kilometers without a recognized eruptive trigger (Sisson and Vallance, 2009). The extreme hazard posed by lahars was demonstrated tragically by the 1985 Nevado del Ruiz (Colombia) catastrophe that claimed the lives of more than 20,000 people (Naranjo and others, 1986). The potential to provide warnings of minutes to hours in advance of lahar arrival in a populated area (for example, Voight, 1990) is a strong reason to provide special monitoring attention to the hazard. Populated river valleys are located downstream from many very high threat and high threat volcanoes, and these areas could be affected by lahars (for example, Hoblitt and others, 1998). The volume and mobility of lahars are two characteristics that can influence the extent of downstream effects (for example, George and others, 2022). The flows that reach the farthest downstream are mobile and voluminous. Additionally, entrainment of material as a lahar travels downstream may increase the volume, and a lahar that starts small may grow to a destructive size under certain conditions. Increasingly, stratovolcanoes host recreational enthusiasts who could be affected by relatively localized geologic hazards, such as rainfall-induced debris flows, glacial outburst floods, rockfalls, and avalanches. These types of events can be common on many volcanoes, occurring seasonally in the case of debris flows and several times per year in the case of avalanches and rockfalls (for example, Allstadt and others, 2018). Many very high threat stratovolcanoes, especially within the contiguous United States, have low eruption frequencies (less than once per century), such that monitoring networks could be used more often for detection and characterization of small surface flows than for identification of volcanic unrest. Such information can be used to validate avalanche forecasts, inform rescue efforts, or notify other agencies of potentially damaged infrastructure (for example, roads, powerlines, or trails). Note that although many of these smaller surface flows create seismic and infrasound waves, the signals are typically highly distorted by the complex volcanic topography and geology. In general, the smaller the flow, the weaker the geophysical signals that it generates, and thus a denser geophysical network is required to study smaller flows (for example, Allstadt and others, 2018). Lahar detection may not be an appropriate or necessary monitoring capability for all volcanoes. Some very high threat volcanoes, like Kīlauea and Mauna Loa, have no lahar hazards currently, and thus no detection, tracking, and characterization capabilities for lahars are needed. At other very high threat volcanoes, such as Pavlof Volcano, Alaska, lahars might be common but pose minimal threat because the volcano is so remote. Ideally, the local observatory would understand the combination of hazard and risk associated with surface flows and assign monitoring and detection capabilities appropriately. Several volcano monitoring techniques (for example, Real-Time Seismic Amplitude Measurement [RSAM], amplitude-based locations, and infrasound array processing) can be adapted to also detect, characterize, and track debris flows, lahars, and other surface flows, so instrumentation installed for detecting volcanic unrest and eruptions can have multiple purposes. The utility of instrumentation for the purpose of monitoring unrest and lahars further justifies the importance and utility of a dense network of monitoring stations, even if the volcano remains quiescent.

Scientific Investigations Report↗

Status of groundwater quality in the Southern, Middle, and Northern Sacramento Valley study units, 2005-08: California GAMA Priority Basin Project

Groundwater quality in the Southern, Middle, and Northern Sacramento Valley study units was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study units are located in California’s Central Valley and include parts of Butte, Colusa, Glenn, Placer, Sacramento, Shasta, Solano, Sutter, Tehama, Yolo, and Yuba Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The three study units were designated to provide spatially-unbiased assessments of the quality of untreated groundwater in three parts of the Central Valley hydrogeologic province, as well as to provide a statistically consistent basis for comparing water quality regionally and statewide. Samples were collected in 2005 (Southern Sacramento Valley), 2006 (Middle Sacramento Valley), and 2007–08 (Northern Sacramento Valley). The GAMA studies in the Southern, Middle, and Northern Sacramento Valley were designed to provide statistically robust assessments of the quality of untreated groundwater in the primary aquifer systems that are used for drinking-water supply. The assessments are based on water-quality data collected by the USGS from 235 wells in the three study units in 2005–08, and water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer systems (hereinafter, referred to as primary aquifers) assessed in this study are defined by the depth intervals of the wells in the CDPH database for each study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from quality of groundwater in the primary aquifers; shallow groundwater may be more vulnerable to contamination from the surface. The status of the current quality of the groundwater resource was assessed by using data from samples analyzed for volatile organic compounds (VOC), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources within the primary aquifers of the three Sacramento Valley study units, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentrations divided by benchmark concentrations) were used for evaluating groundwater quality for those constituents that have Federal or California regulatory or non-regulatory benchmarks for drinking-water quality. A relative-concentration greater than 1.0 indicates a concentration greater than a benchmark. For organic (volatile organic compounds and pesticides) and special-interest (perchlorate) constituents, relative-concentrations were classified as high (greater than 1.0); moderate (equal to or less than 1.0 and greater than 0.1); or low (equal to or less than 0.1). For inorganic (major ion, trace element, nutrient, and radioactive) constituents, the boundary between low and moderate relative-concentrations was set at 0.5. Aquifer-scale proportions were used in the status assessment for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the area of the primary aquifers that have a relative-concentration greater than 1.0 for a particular constituent or class of constituents; percentage is based on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifers that have moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based, which used one value per grid cell, and spatially-weighted, which used the full dataset—were used to calculate aquifer-scale proportions for individual constituents and classes of constituents. High and moderate aquifer-scale proportions were significantly greater for inorganic constituents than organic constituents in all three study units. In the Southern Sacramento Valley study unit, relative-concentrations for one or more inorganic constituents with health-based benchmarks (HBBs) were high in 30 percent (%), moderate in 30%, and low in 40% of the primary aquifer. In the Middle Sacramento Valley study unit, aquifer-scale proportions for inorganic constituents with HBBs were high in 24%, moderate in 38%, and low in 38% of the primary aquifer. Arsenic, boron, and nitrate were detected at high relative-concentrations in the Southern and Middle Sacramento Valley study units. In the Northern Sacramento Valley study unit, high, moderate, and low relative-concentrations of inorganic constituents relative to HBBs were 2.1, 12, and 86% of the primary aquifer, respectively. Arsenic was the only constituent detected at high relative-concentrations. The high aquifer-scale proportions for inorganic constituents with non-health-based benchmarks were 32, 27, and 4.6% of the primary aquifer for the Southern, Middle, and Northern Sacramento Valley study units, respectively. The high aquifer-scale proportions for organic constituents with HBBs were less than 1% in the Southern, Middle, and Northern Sacramento Valley study units. Organic constituents were detected at moderate relative-concentrations in about 3% of the Southern and Middle Sacramento Valley study units and in 1% of the Northern Sacramento Valley study unit. Of the 227 organic constituents analyzed for, 86 were detected, and of those detected, 56 have HBBs. Six organic constituents (atrazine, bentazon, chloroform, simazine, tetrachloroethene, and trichloroethene) were detected in 10% or more of the sampled wells in one or more of the three Sacramento Valley study units.

California↗

The geologic story of the Great Plains

The Great Plains! The words alone create a sense of space and a feeling of destiny a challenge. But what exactly is this special part of Western America that contains so much of our history? How did it come to be? Why is it different? Geographically, the Great Plains is an immense sweep of country; it reaches from Mexico far north into Canada and spreads out east of the Rocky Mountains like a huge welcome mat. So often maligned as a drab, featureless area, the Great Plains is in fact a land of marked contrasts and limitless variety: canyons carved into solid rock of an arid land by the waters of the Pecos and the Rio Grande; the seemingly endless grainfields of Kansas; the desolation of the Badlands; the beauty of the Black Hills. Before it was broken by the plow, most of the Great Plains from the Texas panhandle northward was treeless grassland. Trees grew only along the floodplains of streams and on the few mountain masses of the northern Great Plains. These lush prairies once were the grazing ground for immense herds of bison, and the land provided a bountiful life for those Indians who followed the herds. South of the grasslands, in Texas, shrubs mixed with the grasses: creosote bush along the valley of the Pecos River; mesquite, oak, and juniper to the east. The general lack of trees suggests that this is a land of little moisture, as indeed it is. Nearly all of the Great Plains receives less than 24 inches of rainfall a year, and most of it receives less than 16 inches. This dryness and the strength of sunshine in this area, which lies mostly between 2,000 and 6,000 feet above sea level, create the semiarid environment that typifies the Great Plains. But it was not always so. When the last continental glacier stood near its maximum extent, some 12,000-14,000 years ago, spruce forest reached southward as far as Kansas, and the Great Plains farther south was covered by deciduous forest. The trees retreated northward as the ice front receded, and the Great Plains has been a treeless grassland for the last 8,000-10,000 years. For more than half a century after Lewis and Clark crossed the country in 1805-6, the Great Plains was the testing ground of frontier America here America grew to maturity (fig. 1). In 1805-7, explorer Zebulon Pike crossed the southcentral Great Plains, following the Arkansas River from near Great Bend, Kans., to the Rocky Mountains. In later years, Santa Fe traders, lured by the wealth of New Mexican trade, followed Pike's path as far as Bents Fort, Colo., where they turned southwestward away from the river route. Those pioneers who later crossed the plains on the Oregon Trail reached the Platte River near the place that would become Kearney, Nebr., by a nearly direct route from Independence, Mo., and followed the Platte across the central part of the Great Plains.

Bulletin↗

Molt and aging criteria for four North American grassland passerines

Prairie and grassland habitats in central and western North America have declined substantially since settlement by Europeans (Knopf 1994) and many of the birds and other organisms that inhabit North American grasslands have experienced steep declines (Peterjohn and Sauer 1999; Johnson and Igl 1997; Sauer, Hines, and Fallon 2007). The species addressed here, Sprague’s Pipit (Anthus spragueii), Grasshopper (Ammodramus savannarum) and Baird’s (A. bairdii) sparrows, and Chestnut-collared Longspurs (Calcarius ornatus), are grassland birds that are of special conservation concern throughout their ranges due to declining populations and the loss of the specific grassland habitats required on both their breeding and wintering ranges (Knopf 1994, Davis and Sealy 1998, Davis 2003, Davis 2004, Jones and Dieni 2007). Population-trend data on grassland birds, while clearly showing declines, provides no information on the causes of population declines. Without demographic information (i.e., productivity and survivorship), there are no means to determine when in their life cycle the problems that are creating these declines are occurring, or to determine to what extent population trends are driven by factors that affect birth rates, death rates, or both (DeSante 1995). For migratory birds, population declines may be driven by factors on breeding grounds, during migration, and/or on wintering grounds. Lack of data on productivity and survivorship thus impedes the formulation of effective management and conservation strategies to reverse population declines (DeSante 1992). Furthermore, if deficiencies in survivorship are revealed, management strategies may need to address habitats on both breeding and non-breeding grounds, as well as along migratory pathways. One technique that helps inform management strategies is the biochemical analysis of isotopes and genetic markers, from the sampling of individual feathers from live birds (Smith et al. 2003, Pérez and Hobson 2006; Appendix). Determining demographic parameters and effectively sampling feathers to reveal connectivity between breeding and wintering grounds requires detailed knowledge of molt patterns and age determination criteria for the target species, in the hand. For example, productivity, survivorship, and territory acquisition may all be age-dependent, with first-year birds showing different patterns and responses than older birds. In many cases it may be possible to sample both a feather grown on the breeding grounds and one grown on the wintering grounds from a single individual, but knowledge of age-specific molt patterns, as well as an ability to recognize different feather generations, is needed to accomplish such a task. While some information on molt and aging criteria exists for grassland passerine species (Pyle 1997a), these species have been rarely captured during mark-recapture studies (Jones et al. 2007) and this information thus needs refining. There is a need for additional resources to assist field workers in determining molt patterns and age in captured individuals. Our objective is to describe molt and aging criteria for four grassland passerine species with the aid of digital photographs taken in the field. We hope that this document will be useful for researchers studying grassland species through capture and banding of live individuals on either the breeding or the wintering grounds. We present a general section on molt and aging techniques, followed by specific accounts for the four species treated: Sprague’s Pipits, Grasshopper and Baird sparrows, and Chestnut-collared Longspur. We also provide a brief protocol on collecting feather samples (Appendix).

Biological Technical Publication↗