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Geologic, geochemical, and isotopic studies of a carbonate- and siliciclastic-hosted Pb-Zn deposit at Lion Hill, Vermont

Zn-, Pb-, Cu-, and Fe-bearing rocks of the Lion Hill area in western Vermont formed during the Early Cambrian by syngenetic sedimentary-exhalative and diagenetic replacement processes. Sphalerite, galena, chalcopyrite, pyrite, and, locally, magnetite form stratabound and broadly stratiform lenticular zones, -300 meters long and 25-50 meters thick, which are uneconomic at the present time. The lenses are structurally disrupted and metamorphosed to greenschist facies, probably due to the Taconic orogeny. Textural evidence suggests that mineralizing fluids permeated the sediments prior to lithification and that a dilatant fracture zone, possibly a feeder zone, contains some of the discordant veins at Lion Hill. The veins may have formed when the sediments were in a plastic, semiconsolidated state. The association of layered iron formation containing base-metal sulfide minerals provides possible lithologic evidence for syngenetic mineralization by submarine exhalative activity. Sand bars and tidal channels present in the sedimentary section could have acted as permeable pathways for movement of mineralizing fluids. The complex interlayering in the sedimentary sequence of carbonate and siliciclastic rock types having widely varying permeabilities created numerous fluid traps. Homogenization temperatures of primary and secondary inclusions in vein sphalerite range from 152°C to 196°C; salinities range from 11.5 to 14.0 equivalent weight percent NaCl. δ 34 S values of sulfides from Lion Hill vary from -25.9 to +10.0 per mil, and fall within the expected range for sulfide produced from bacteriogenic reduction of sulfate with δ 34 S values of 25 to 30 per mil. In addition, some pyrite probably formed from sulfate in trapped pore fluid that resulted in heavier isotopic values characteristic of more closed-system behavior. Three sphalerite samples that have heavier sulfur isotopic values may reflect a change in the source of sulfur during a later episode of mineralization, perhaps a change to a deep-seated source. Lead isotopic compositions of galenas from mineralized zones at Lion Hill range from 18.351 to 18.632 for 206 Pb/ 204 Pb, from 15.546 to 15.618 for 207 Pb/ 204 Pb, and from 38.126 to 38.496 for 208 Pb/ 204 Pb. The lead isotopic compositions of galena from Lion Hill and fluid inclusion and sulfur isotopic values for the Lion Hill sulfides are more like those of Pb-Zn-Ag deposits of Ireland than those of MVT or Appalachian-type Zn deposits. The prospect of an Irish-type sedimentary-exhalative origin for stratabound Pb-Zn deposits of the Paleozoic shelf of North America is of considerable importance to understanding the timing of mineralization relative to platform evolution and for evaluating the mineral resource potential of the region. Our study of the Lion Hill deposit indicates a potential for Irish-type Pb-Zn deposits in platform rocks of western Vermont; however, at Lion Hill they contain enrichments of Pb, Zn, and Cu rather than a Pb, Zn, and Ag association.

Vermont↗

Distribution and abundance of Least Bell’s Vireos ( Vireo bellii pusillus ), Southwestern Willow Flycatchers ( Empidonax traillii extimus ), and Coastal California Gnatcatchers ( Polioptila californica californica ) at the Carbon Canyon Dam, Orange County, California—2025 data summary

Executive Summary We surveyed for Least Bell’s Vireos ( Vireo bellii pusillus ; vireo), Southwestern Willow Flycatchers ( Empidonax traillii extimus ; flycatcher), and Coastal California Gnatcatchers ( Polioptila californica californica ; gnatcatcher) at the Carbon Canyon Dam study area near Brea, California, in 2025. Four gnatcatcher and vireo surveys were completed between April 22 and June 25, 2025, and three flycatcher surveys were completed between May 15 and June 25, 2025. We detected 14 territorial male vireos, 12 of which were paired. We also detected a transient vireo. Juvenile vireos were observed in two territories during surveys. Of the five vireo nests incidentally located during surveys, three were parasitized by Brown-headed Cowbirds ( Molothrus ater ). Vireos were reported in four habitat types: (1) mixed willow riparian, (2) riparian scrub, (3) upland, and (4) non-native vegetation. The dominant tree species in vireo territories was Goodding’s black willow ( Salix gooddingii ). Most vireo territories (12) were in habitat with greater than 50-percent native vegetation. The most common exotic species in vireo territories was poison hemlock ( Conium maculatum ). No flycatchers or gnatcatchers were observed during surveys.

California↗

Spring Database for the Basin and Range Carbonate-Rock Aquifer System, White Pine County, Nevada, and Adjacent Areas in Nevada and Utah

A database containing nearly 3,400 springs was developed for the Basin and Range carbonate-rock aquifer system study area in White Pine County, Nevada, and adjacent areas in Nevada and Utah. The spring database provides a foundation for field verification of springs in the study area. Attributes in the database include location, geographic and general geologic settings, and available discharge and temperature data for each spring.

Data Series↗

Irrigated Acreage Within the Basin and Range Carbonate-Rock Aquifer System, White Pine County, Nevada, and Adjacent Areas in Nevada and Utah

Accurate delineations of irrigated acreage are needed for the development of water-use estimates and in determining water-budget calculations for the Basin and Range carbonate-rock aquifer system (BARCAS) study. Irrigated acreage is estimated routinely for only a few basins in the study area. Satellite imagery from the Landsat Thematic Mapper and Enhanced Thematic Mapper platforms were used to delineate irrigated acreage on a field-by-field basis for the entire study area. Six hundred and forty-three fields were delineated. The water source, irrigation system, crop type, and field activity for 2005 were identified and verified through field reconnaissance. These data were integrated in a geodatabase and analyzed to develop estimates of irrigated acreage for the 2000, 2002, and 2005 growing seasons by hydrographic area and subbasin. Estimated average annual potential evapotranspiration and average annual precipitation also were estimated for each field.The geodatabase was analyzed to determine the spatial distribution of field locations, the total amount of irrigated acreage by potential irrigation water source, by irrigation system, and by crop type. Irrigated acreage in 2005 totaled nearly 32,000 acres ranging from less than 200 acres in Butte, Cave, Jakes, Long, and Tippett Valleys to 9,300 acres in Snake Valley. Irrigated acreage increased about 20 percent between 2000 and 2005 and increased the most in Snake and White River Valleys. Ground-water supplies as much as 80 percent of irrigation water during dry years. Almost 90 percent of the irrigated acreage was planted with alfalfa.

Data Series↗

Total Mercury, Methylmercury, and Carbon and Nitrogen Stable Isotope Data for Biota from Selected Streams in Oregon, Wisconsin, and Florida, 2002-04

The U.S. Geological Survey National Water-Quality Assessment Program conducted a multidisciplinary study to investigate the bioaccumulation of mercury from 2002 to 2004. Study areas were located in Oregon, Wisconsin, and Florida. Each study area included one urban site, and one or two nonurban sites that had the following attributes: high-percent wetland or low-percent wetland. Periphyton, macroinvertebrates, and forage fish were collected twice per year (during 2003 and 2004) to capture seasonality. Top predators, specifically largemouth bass (Micropterus salmoides), brown trout (Salmo trutta), and cutthroat trout (Oncorhynchus clarkii), were collected once per year (Oregon, Wisconsin, and Florida in 2003; Florida only in 2004). All biota were identified to the lowest possible taxonomic category and were analyzed for mercury and stable carbon and nitrogen isotopes. Periphyton and invertebrates were analyzed for total mercury and methylmercury; fish were analyzed for total mercury only. This report presents (1) methodology and data on mercury, methylmercury, stable isotopes, and (2) other ecologically relevant measurements in biological tissues of periphyton, invertebrates, forage fish, and predator fish.

Data Series↗

Subsidence and carbon fluxes in the Sacramento/San Joaquin Delta, California

The Sacramento/San Joaquin Delta was once tidal marshland and was formed by the confluence of the Sacramento and the San Joaquin Rivers. The delta covers more than 1,000 square miles and is bordered by the major population centers of the San Francisco Bay area, Sacramento, and Stockton (fig. 1). The delta took its current form by the 1930's when drainage of 100 islands and tracts and construction of 2,250 miles of levees were completed. The land surface on the delta islands has progressively subsided below sea level since the early 20th century. The integrity of the levee network is threatened because subsidence increases the differences in water levels maintained by the levees, which can cause levee failure and consequent flooding of the delta islands. Levee failure affects the quality and beneficial use of water in the delta, which is the major source of California's water supply to millions of residents and acres of agricultural land. This Fact Sheet briefly summarizes the research done by the U.S. Geological Survey, in cooperation with the California Department of Water Resources to assess the causes of subsidence, processes that affect subsidence, and carbon fluxes in the delta.

California↗

Inventario mundial de la calidad del carbon mineral (WoCQI) [The world coal quality inventory (WoCQI)]

Los oficiales encargados de la politica comercial de cada pais requieren informacion clara y precisa sobre el recurso del carbon mineral, particularmente sobre sus propiedades y caracteristicas, para tomar decisiones bien fundamentadas con respecto al mejor uso de los recursos naturales, necesidades de importacion y oportunidades de exportacion, objetivos de politica interna y externa, oportunidades de transferencia tecnologica, posibilidades de inversion externa, estudios ambientales y de salud, y asuntos relacionados con el uso de productos secundarios y su disposicion.

Fact Sheet↗

Magnitude and Significance of Carbon Burial in Lakes, Reservoirs, and Northern Peatlands

It is estimated that freshwater lakes in the world have a total area of about 1.5x1012 m2 (Shiklomanov, 1993; table 1). Including saline inland seas in this total would add another 1x1012 m2. The 28 largest (area of each > 5,000 km2) freshwater lakes in the world have a total area of 1.18x1012 m2 or about 79 percent of the total area of all freshwater lakes. If the 28 large lakes bury organic carbon (OC), on average, at the same rate as Lake Michigan (5 g/m2/yr), then the annual rate of OC burial in these 28 lakes is about 6 Tg/yr (6 terragrams per year or 6x1012 g/yr; table 1). If the smaller lakes bury OC, on average, at the same rate as an average Minnesota lake (72 g/m2/yr), then the annual rate of OC accumulation in these smaller lakes is about 23 Tg/yr (23x1012 g/yr; table 1). If saline inland seas bury OC at the Lake Michigan rate, this would be an additional 5 Tg/yr, for a total of 34 Tg/yr for all freshwater lakes and saline inland seas (table 1). Mulholland and Elwood (1982) estimated the OC burial in all lakes and inland seas (excluding the Black Sea) to be 60 Tg/yr today (table 1) and an average of 20 Tg/yr for the last 10,000 years. Stallard (1998) modeled terrestrial sedimentation as a series of 864 scenarios. For lake area, he used 1.54x1012 m2, the area of the 250 largest lakes in the world. This is close to the total of large and small lakes given in table 1. Again, including inland seas to this total would add an additional 1x1012 m2. Results of scenarios for lakes and reservoirs were divided into two components, those with clastic sediments and those with organic sediments. The results of OC burial in the most likely of Stallard's scenarios for lakes range from 48 to 72 Tg/yr (table 1), the average of which is close to the 60 Tg/yr estimated by Mulholland and Elwood (1982). We will use an average of 54 Tg/yr (table 1). The closeness of these estimates, calculated by different methods, suggests that this value is not in error by more than a factor of two.

Fact Sheet↗

Potential effects of elevated atmospheric carbon dioxide (CO 2 ) on coastal wetlands

Carbon dioxide (CO 2 ) concentration in the atmosphere has steadily increased from 280 parts per million (ppm) in preindustrial times to 381 ppm today and is predicted by some models to double within the next century. Some of the important pathways whereby changes in atmospheric CO 2 may impact coastal wetlands include changes in temperature, rainfall, and hurricane intensity ( fig. 1 ). Increases in CO 2 can contribute to global warming, which may (1) accelerate sea-level rise through melting of polar ice fields and steric expansion of oceans, (2) alter rainfall patterns and salinity regimes, and (3) change the intensity and frequency of tropical storms and hurricanes. Sea-level rise combined with changes in storm activity may affect erosion and sedimentation rates and patterns in coastal wetlands and maintenance of soil elevations. Feedback loops between plant growth and hydroedaphic conditions also contribute to maintenance of marsh elevations through accumulation of organic matter. Although increasing CO 2 concentration may contribute to global warming and climate changes, it may also have a direct impact on plant growth and development by stimulating photosynthesis or improving water use efficiency. Scientists with the U.S. Geological Survey are examining responses of wetland plants to elevated CO 2 concentration and other factors. This research will lead to a better understanding of future changes in marsh species composition, successional rates and patterns, ecological functioning, and vulnerability to sea-level rise and other global change factors.

Fact Sheet↗

Monitoring for methane gas in Carbon and Emery Counties, Utah, 1995-2003

The release of methane gas from coal beds creates the potential for it to move into near-surface environments through natural and human-made pathways. To help ensure the safety of communities and determine the potential effects of development of coal-bed resources, methane gas concentrations in soils and ground water in Carbon and Emery Counties, Utah, were monitored from 1995 to 2003. A total of 420 samples were collected, which contained an average methane concentration of 2,740 parts per million by volume (ppmv) and a median concentration of less than 10 ppmv. On the basis of spatial and temporal methane concentration data collected during the monitoring period, there does not appear to be an obvious, widespread, or consistent migration of methane gas to the near-surface environment.

Utah↗

Carbon sequestration to mitigate climate change

Human activities, especially the burning of fossil fuels such as coal, oil, and gas, have caused a substantial increase in the concentration of carbon dioxide (CO2) in the atmosphere. This increase in atmospheric CO2 - from about 280 to more than 380 parts per million (ppm) over the last 250 years - is causing measurable global warming. Potential adverse impacts include sea-level rise; increased frequency and intensity of wildfires, floods, droughts, and tropical storms; changes in the amount, timing, and distribution of rain, snow, and runoff; and disturbance of coastal marine and other ecosystems. Rising atmospheric CO2 is also increasing the absorption of CO2 by seawater, causing the ocean to become more acidic, with potentially disruptive effects on marine plankton and coral reefs. Technically and economically feasible strategies are needed to mitigate the consequences of increased atmospheric CO2. The United States needs scientific information to develop ways to reduce human-caused CO2 emissions and to remove CO2 from the atmosphere.

Fact Sheet↗

Biochar for soil fertility and natural carbon sequestration

Biochar is charcoal (similar to chars generated by forest fires) that is made for incorporation into soils to increase soil fertility while providing natural carbon sequestration. The incorporation of biochar into soils can preserve and enrich soils and also slow the rate at which climate change is affecting our planet. Studies on biochar, such as those cited by this report, are applicable to both fire science and soil science.

Fact Sheet↗

Groundwater quality in the Valley and Ridge and Piedmont and Blue Ridge carbonate-rock aquifers, eastern United States

Groundwater provides nearly 50 percent of the Nation’s drinking water. To help protect this vital resource, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Project assesses groundwater quality in aquifers that are important sources of drinking water. The Valley and Ridge and Piedmont and Blue Ridge carbonate-rock aquifers constitute two of the important areas being evaluated. One or more inorganic constituents with human-health benchmarks were detected at high concentrations in about 15 percent of the study area and at moderate concentrations in about 17 percent. Organic constituents were not detected at high concentrations in the study area. One or more organic constituents with human-health benchmarks were detected at moderate concentrations in about 2 percent of the study area.

Fact Sheet↗

Environmental quality and preservation; reefs, corals, and carbonate sands; guides to reef-ecosystem health and environment

Introduction In recent years, the health of the entire coral reef ecosystem that lines the outer shelf off the Florida Keys has declined markedly. In particular, loss of those coral species that are the building blocks of solid reef framework has significant negative implications for economic vitality of the region. What are the reasons for this decline? Is it due to natural change, or are human activities (recreational diving, ship groundings, farmland runoff, nutrient influx, air-borne contaminants, groundwater pollutants) a contributing factor and if so, to what extent? At risk of loss are biologic resources of the reefs, including habitats for endangered species in shoreline mangroves, productive marine and wetland nurseries, and economic fisheries. A healthy reef ecosystem builds a protective offshore barrier to catastrophic wave action and storm surges generated by tropical storms and hurricanes. In turn, a healthy reef protects the homes, marinas, and infrastructure on the Florida Keys that have been designed to capture a lucrative tourism industry. A healthy reef ecosystem also protects inland agricultural and livestock areas of South Florida whose produce and meat feed much of the United States and other parts of the world. In cooperation with the National Oceanic and Atmospheric Administration's (NOAA) National Marine Sanctuary Program, the U.S. Geological Survey (USGS) continues longterm investigations of factors that may affect Florida's reefs. One of the first steps in distinguishing between natural change and the effects of human activities, however, is to determine how coral reefs have responded to past environmental change, before the advent of man. By so doing, accurate scientific information becomes available for Marine Sanctuary management to understand natural change and thus to assess and regulate potential human impact better. The USGS studies described here evaluate the distribution (location) and historic vitality (thickness) of Holocene reefs in South Florida, relative to type of underlying bedrock morphology, and their varied natural response to rising sea level. These studies also assess movement and accumulation of sands, relative to direction of prevailing energy, and origin of the component sand grains. Geophysical data collected with highresolution sound-wave instruments that provide pictures of the sediment and bedrock are used to interpret sediment thickness. Reef thickness is determined by collecting limestone rock cores by drilling. Drill cores through reefs are used to identify the coral species that built them and to determine how reefs reacted to rising sea level. These data are supplemented by using isotope-dating techniques to derive the carbon-14 (C14) age of the corals and mangrove peat in the cores. Mangrove peat forms in very shallow water and at the shoreline but is found today buried beneath offshore reefs.

Open-File Report↗

Texture, Carbonate Content, and Preliminary Maps of Surficial Sediments of the Flower Garden Banks Area, Northwestern Gulf of Mexico Outer Shelf

The purpose of this report is to release texture and carbonate content analyses of 107 seafloor sediments collected within and near the East and West Flower Garden Banks areas of the Sanctuary and to show relationships between these data and existing bathymetric data. The sediment data, in conjunction with previously collected geological, geophysical and biological data were used to construct a reconnaissance-scale map of the distribution of seafloor sediment types. This map will be useful for resource managers and can be used, with additional data, as a basis for future habitat mapping.

Open-File Report↗

Data report: geology of reef-front carbonate sediment deposits around Oahu, Hawaii

This Open-File Report presents data and derivative products from an investigation of carbonate sediment deposits on the reef front in four areas around the island of Oahu, Hawaii - in Kailua Bay off Oahu's windward (east) side, off the leeward (west) coast from Makua to Kahe Point, off the north coast from Waimea to Camp Erdman, and off the south coast around Waikiki (Figure 1). The primary purpose of the investigation was to assess the resource potential of the deposits, particularly as a source of sand for beach nourishment. This work builds on previous studies by researchers from the University of Hawaii (Moberly et al., 1975; Coulbourn et al., 1988; Barry, 1995). The field program included collection of high-resolution acoustic-reflection profiles and vibracore sediment samples in Kailua Bay and off the leeward and north coasts. In a related project, in collaboration with the Hawaii State Department of Land and Natural Resources and the University of Hawaii, sidescan images and vibracores were collected in the Halekulani channel and on the adjacent Makua Terrace off Waikiki along the south coast.

Hawai'i↗

Role of rock/fluid characteristics in carbon (CO 2 ) storage and modeling

The presentation ? Role of Rock/Fluid Characteristics in Carbon (CO2) Storage and Modeling ? was prepared for the meeting of the Environmental Protection Agency (EPA) in Houston, Tex., on April 6?7, 2005. It provides an overview of greenhouse gases, particularly CO2, and a summary of their effects on the Earth?s atmosphere. It presents methods of mitigating the effects of greenhouse gases, and the role of rock and fluid properties on CO2 storage mechanisms. It also lists factors that must be considered to adequately model CO2 storage.

Open-File Report↗

Water Resources of the Basin and Range Carbonate-Rock Aquifer System, White Pine County, Nevada, and Adjacent Areas in Nevada and Utah - Draft Report

Summary of Major Findings This report summarizes results of a water-resources study for White Pine County, Nevada, and adjacent areas in east-central Nevada and western Utah. The Basin and Range carbonate-rock aquifer system (BARCAS) study was initiated in December 2004 through Federal legislation (Section 131 of the Lincoln County Conservation, Recreation, and Development Act of 2004) directing the Secretary of the Interior to complete a water-resources study through the U.S. Geological Survey, Desert Research Institute, and State of Utah. The study was designed as a regional water-resource assessment, with particular emphasis on summarizing the hydrogeologic framework and hydrologic processes that influence ground-water resources. The study area includes 13 hydrographic areas that cover most of White Pine County; in this report however, results for the northern and central parts of Little Smoky Valley were combined and presented as one hydrographic area. Hydrographic areas are the basic geographic units used by the State of Nevada and Utah and local agencies for water-resource planning and management, and are commonly defined on the basis of surface-water drainage areas. Hydrographic areas were further divided into subbasins that are separated by areas where bedrock is at or near the land surface. Subbasins represent subdivisions used in this study for estimating recharge, discharge, and water budget. Hydrographic areas represent the subdivision used for reporting summed and tabulated subbasin estimates.

Open-File Report↗