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Prediction of the probability of elevated nitrate concentrations at groundwater depths used for drinking-water supply in the Puget Sound basin, Washington, 2004–19

The Puget Sound basin encompasses the 13,700-square-mile area that drains to the Puget Sound and the adjacent marine waters of Washington State. Well more than 4 million people live within the basin, with numbers continuing to increase, who rely on the basin’s natural resources including groundwater. The Puget Sound Partnership was created by a Washington State statute to implement a science-based recovery of the Puget Sound to help address impacts to these resources. As part of the recovery, the partnership developed the Puget Sound Vital Signs as measures of ecosystem health that guide the assessment of progress toward Puget Sound recovery goals. The Puget Sound Partnership Leadership Council adopted a Drinking Water Vital Sign associated with human health and quality of life, recognizing certain indicators as integral to the sustainability of Puget Sound recovery efforts. One such Vital Sign indicator was the vulnerability of groundwater throughout the aquifers of the Puget Sound basin to elevated nitrate concentrations as defined by the probability of exceeding 2 milligrams/liter (mg/L) at a specific location and well depth. The U.S. Geological Survey (USGS) led the effort to characterize groundwater vulnerability. For this study, groundwater vulnerability refers to a probability with which a contaminant applied at or near the land surface can migrate to the aquifer of interest for a given set of land-use practices. Nitrate concentration data were selected for evaluation because elevated nitrate concentrations are typically caused by anthropogenic activities and have been associated with deleterious impacts on human health. To identify groundwater vulnerability to elevated nitrate concentrations, logistic regression was used to relate anthropogenic (human associated) and natural variables to the occurrence of elevated nitrate concentrations in untreated groundwater from large public water supply system wells found within the Washington State Department of Health Sentry database. Variables that were analyzed included well depth, soil hydraulic conductivity, precipitation, population density, fertilizer application amounts, and land-use types. Statistically significant models that predicted the probabilities of groundwater nitrate concentrations greater than 2 mg/L based on the predictor variables were created for the time periods 2000–04, 2005–09, 2010–14, and 2015–19. For all time periods, well depth and a measure of the abundance of urban and agricultural land over or near the well consistently helped explain the vulnerability of the well to elevated nitrate concentrations defined as a probability of exceeding 2 mg/L of nitrate. Precipitation and (or) soil hydraulic conductivity were also important predictor variables in the models. The models for each time period were used to create maps of groundwater vulnerability at 150- and 300-foot depths throughout the Puget Sound basin. As expected, the most vulnerable locations were associated with shallower well depths and increased agriculture and urban land cover. Across all four time periods, groundwater vulnerability throughout the Puget Sound was low, with probabilities of exceeding 2 mg/L concentrations of nitrate at depths at 150 and 300 feet typically less than 50 percent. Results also found a slight decrease in probabilities of elevated nitrate concentrations throughout the basin over time. More specifically, additional statistical tests found that groundwater with probabilities of less than about 60 percent declined from 2000 to 2019 and represented more than 75 percent of the modeled Puget Sound basin aquifer. Wells with greater than 60 percent probability increased over the same time period but represented only about 25 percent of the aquifer. The maps and statistical analysis presented in the study provide valuable and informative evaluation of the vulnerability of groundwater in the Puget Sound basin to elevated nitrate concentrations. The probability maps do not represent measured nitrate concentrations in groundwater, but rather they present the probability that nitrate concentrations exceed 2 mg/L. The models and predictions from this study are a viable indicator for the Puget Sound Partnership’s Healthy Human Population—Drinking Water Vital Sign. The logistic regression modeling approach presented here benefits water managers by allowing them to assess temporal trends in a range of probabilities, explore vulnerability changes as new regional land cover and anthropogenic data are generated, and distinguish vulnerabilities at different depths within the aquifer.

Washington

Insights and strategic opportunities from the USGS 2024 Per- and Polyfluoroalkyl Substances (PFAS) Interagency Workshop

Introduction In 2021, the U.S. Geological Survey (USGS) published Circular 1490 titled, “Integrated Science for the Study of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS) in the Environment: A Strategic Science Vision for the U.S. Geological Survey” (Tokranov and others, 2021). Circular 1490 was created to be a resource for USGS scientists prioritizing and planning research related to per- and polyfluoroalkyl substances (PFAS) and to be a guide for developing partnerships with other scientists, State and Federal agencies, and stakeholders engaged in PFAS research and management and mitigation of the environmental and human-health effects of PFAS. This USGS PFAS Strategic Science Vision document was intended to be the foundation for a “living strategic vision,” periodically providing updates on the state of USGS PFAS research, emerging PFAS data gaps and needs, and progress on interagency and stakeholder PFAS partnerships and priorities. To meet this objective, the USGS planned to host an Interagency and Stakeholder PFAS Workshop every 2–3 years. During September 10–12, 2024, the USGS hosted the first Interagency and Stakeholder PFAS Workshop in Reston, Virginia. The Workshop brought together experts from other Federal agencies (U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Food and Drug Administration, Department of Defense [Air Force, Army]), State agencies (Washington Fish and Wildlife, Virginia Department of Transportation), and academia (Harvard University, University of Maryland) to address key challenges relating to the measurement and modeling of PFAS and the implications for environmental health. Participants engaged in in-depth discussions centered around six pivotal topics related to PFAS: (1) sampling protocols, methods and interpretation; (2) environmental sources, source apportionment, and occurrence; (3) environmental fate and transport; (4) human and wildlife exposure routes and risk; (5) bioconcentration, bioaccumulation, and biomagnification; and (6) ecotoxicology and effects. Each topic had three breakout sessions. A recurrent theme of workshop discussions was how data on a nationwide scale for PFAS occurrence in various environmental matrices, including air, water, food crops, biota, soil, and streambed sediment could help to advance scientific understanding. Participants noted significant geospatial data gaps, particularly in the midwestern and southern United States and the Pacific Northwest. PFAS data collection tends to be more robust along the eastern seaboard and in California. Participants stressed how enhancing the integration of large and small datasets across various agencies could help to support national scale understanding of PFAS. To address these gaps, attendees suggested leveraging datasets from Federal entities like the USGS and the U.S. Department of Defense, State agencies, and municipal utility services to develop predictive contaminant detection and transport models. Improved coordination between water quality programs and USGS research could help to facilitate access to valuable data, leading to comprehensive databases that inform PFAS point (wastewater treatment plants and landfills) and nonpoint (runoff from land, atmospheric deposition, food packaging) sources, environmental transport mechanisms, environmental detection and concentrations, potential exposure routes, and health effects on different biota, including humans. A specific request was made to develop a map demarking the depth of modern (1953 or later) groundwater, which is susceptible to surface-derived anthropogenic (that is, human-made) contamination, based on tritium-age dating. Emphasis was placed on incorporation of hydrology, groundwater flow paths, groundwater–surface water interactions, and landscape factors in predictive statistical models as a step to improve contaminant source identification and tracking. Molecular fingerprinting approaches garnered attention as techniques to link specific PFAS mixtures detected in a sample to environmental sources and levels in biota (Dávila-Santiago and others, 2022). Integrating data from abiotic (that is, water, soil, and air) and biotic (that is, living organisms) systems identified as a research opportunity. For example, understanding the composition of soils and sediments, which include a mixture of mineral, plant, and animal components, could advance understanding of exposure pathways. The discussions highlighted opportunities to explore and understand the potential redistribution and biotic exposures of PFAS from biosolid and wastewater treatment plant effluent land application practices, in addition to atmospheric releases and discharges from landfill and wastewater treatment plants. Participants identified research gaps surrounding how these sources may contribute to contamination and may affect surrounding ecosystems, including a better definition of anthropogenic background concentrations. Moving forward, the collection of co-occurrence data was noted as a means to improve understanding of complex mixtures and to leverage companion modeling efforts focused on areas with high and low contamination levels to identify areas of concern and unaffected resources. Participants emphasized how centralized USGS databases and the establishment of sample-metadata archives can help to ensure that samples are preserved and accessible for future research. In conclusion, the workshop participants identified opportunities to bridge data gaps and improve measurement techniques, modeling frameworks, databases, and communication, to enhance the understanding of PFAS and their effects on environmental and human health. Upon completion of the workshop, participants indicated an interest in developing strategic data collection, modeling, and analytical approaches to address these challenges.

Open-File Report

Deformed submarine terraces in Puget Sound, Pacific Northwest, indicate only one M >~7.5 earthquake on the Seattle fault zone in the past 11,000 yr

Submerged marine terraces in Puget Sound, deformed across the Seattle fault zone (SFZ), indicate that only one earthquake as large as M~7.5 has occurred in at least the past 11 kyr. Previous paleoseismic studies document a M~7.5 earthquake between 923–4 CE, which uplifted coastal marine terraces by as much as 8 m. We demonstrate that this earthquake was the only such event since ~11 ka by mapping and quantifying deformation of older marine terraces, now submerged in Puget Sound. The submerged terraces, attributed to a late-glacial sea-level lowstand, record both glacial isostatic rebound and tectonic deformation. Vertical offset of the ~11 ka terraces within the SFZ is comparable to that of the marine terraces uplifted in 923 CE, implying no additional large (M>~7.5) earthquake on the SFZ since ~11 ka. This result implies a longer recurrence interval than current hazard estimates, which assumes recurrence of M>7.1 events every 5 kyr. Our mapping of SFZ deformation since ~11 ka also supports fault segmentation and contiguous block uplift between the Seattle and Tacoma fault zones.

Washington

Techniques for estimating magnitude and frequency of floods on streams in Indiana

Equations are presented for estimating the magnitude and frequency of floods at ungaged sites on unregulated and nonurban streams in Indiana. The equations were developed by multiple-regression, analysis of basin characteristics and peak-flow statistical data from 242 gaged locations in Indiana, Ohio, and Illinois. The State of Indiana was divided into seven areas on the basis of the regression analysis. A set of equations for estimating peak discharges with recurrence intervals of 2, IO, 25, 50, and 100 years was developed for each area. Significant basin characteristics in the equations are drainage area, channel length, channel slope, mean annual precipitation, storage, precipitation intensity, and a runoff coefficient. Standard errors of estimate for the equations range from 24 to 45 percent. Methods are also presented for estimating flood magnitude and frequency at sites on gaged streams. Flood-frequency data based on observed peaks are given for 270 gaged locations. Twenty of these are on regulated streams, and six are on urban streams. Basin characteristics are also included car 245 of the gaged locations on unregulated and nonurban streams. No techniques are given for estimating flood magnitude and frequency at ungaged sites on regulated or urban streams. A rainfall-runoff model was tlsed to synthesize long-term peak data at 11 gaged locations on small streams. Flood-frequency curves developed from the long-term synthetic data were combined with curves based on short-term observed data to provide weighted estimates of flood magnitude and frequency at the rainfall-runoff stations.

Indiana

2023 Earthquake Ground-Motion Workshop for the Central and Eastern United States, with a focus on the Gulf and Atlantic Coastal Plains—Agenda and abstracts

The U.S. Geological Survey held a virtual workshop December 7–8, 2023, to share research and ideas about earthquake ground motions in the Central and Eastern United States, with a focus on the Atlantic and Gulf Coastal Plains. The workshop was organized to learn about potential regionalization of ground-motion characteristics (source, path, and site), consider new explanatory variables for site response, and hear and discuss updates on ground-motion research on the Atlantic and Gulf Coastal Plains. The workshop was organized into a series of contributed presentations and three panel discussions held during 2 days. This report documents the agenda, contributed abstracts, and panel summaries.

Scientific Investigations Report

Velocity-independent dry friction on mica: A realization of ideal Amontons-Coulomb friction

The Amontons-Coulomb friction law assumes that the frictional force between materials is independent of sliding velocity. However, as Coulomb noted, this is a rough approximation, and a second-order dependence of friction on the logarithm of sliding velocity is incorporated in a commonly used ‘rate- and state-dependent’ friction representation. Here we conduct shear experiments on mica, a layer-structured mineral, at temperatures ranging from 25 to 200ºC and under normal stress of 100 MPa. The friction coefficient clearly depends on the logarithmic sliding velocity at 25ºC, but rate sensitivity decreases with increasing temperature until at 200ºC, the friction coefficient is independent of sliding velocity. Our findings could initiate the development of velocity-independent frictional materials, realizing the ideal Amontons-Coulomb friction.

Physical Review Letters

Observations of tear-drinking by lepidopterans on moose ( Alces alces americana ) in northeastern North America

Lepidoptera have long been known to feed on the tears of vertebrates as a presumed source of minerals or nutrients. While this unusual behavior has been observed in a variety of species, only a single previous record has been documented outside of the tropics. Here, we present the first documentation of moths visiting the eyes of a bull moose ( Alces americanus americanus ), captured via trail camera in Green Mountain National Forest, Vermont, United States. We discuss the biogeography of this behavior, how it may differ between tropical and temperate climates, and its potential impact on moose health.

Vermont

The effect of temperature, flow, density and disease on smallmouth bass (Micropterus dolomieu) early life growth rate

Individual growth rates of fish are influenced by gradually changing environmental conditions and rapid-onset events. However, there is a paucity of information on drivers of spatiotemporal variability in growth rates of fishes across large spatial extents. Using a 36-year dataset of smallmouth bass ( Micropterus dolomieu ) length-at-age data across 10 river reaches in Pennsylvania, USA ( n = 54,068 individuals), we estimated annual early life growth rates (mm year −1 ) and assessed the effects of relative abundance, summer temperature, summer streamflow rate and a disease outbreak on growth rate. We found that temperature had a positive effect on growth rate, varied spatially, and had a stronger effect in diseased reaches. There was also evidence for an impact of disease on early life growth through density-dependent mechanisms, with growth rates increasing from ∼85 to 101 mm·year −1 following disease-related decreases in abundance. This study adds to our understanding of the factors that shape early life growth, including rapid-onset events like disease which can have immediate and lasting effects on growth rate trajectory.

Pennsylvania

Simulated ground motion dataset in the Azores Plateau, Portugal, on rock and soil sites

Building on a previously developed bedrock dataset, this study extends the Azores Plateau ground motion simulations to include soil-amplified records and introduces a comprehensive validation framework. Soil amplification is modeled using one-dimensional soil profiles. A stochastic source-based approach is employed to generate the dataset, incorporating randomization of input-model parameters to account for the aleatory uncertainty in seismic activity. The accuracy of the dataset is verified through a comprehensive validation framework, showing that the randomization effectively captures variance and inter-period correlation observed in records. This work provides a robust dataset for advancing seismic hazard and risk assessment in the Azores Plateau.

central and eastern Azores islands