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Do bighorn sheep use desert tortoise burrow spoil piles as mineral licks in southern California?

In a previous study, bighorn sheep ( Ovis canadensis ) were periodically photographed by trail cameras when they visited desert tortoise ( Gopherus agassizii ) burrows in the San Bernardino Mountains near Palm Springs, California, USA. The authors suggested that bighorn sheep may utilize the excavated spoil material from burrows as a mineral lick. To test that supposition, we collected soil samples from the spoil piles and undisturbed surface soil up to 1 m away at two desert tortoise study sites with bighorn sheep at the aforementioned site and another nearby site. We hypothesized that sodium concentrations would be greater in spoil than in nearby surface soil samples. Common major cations were quantified in soil samples using inductively coupled plasma-mass spectrometry following microwave-assisted digestion to solubilize the fraction of elements that could become biologically or environmentally available. Mean sodium concentrations were greater in burrow spoil samples than in undisturbed soil samples at both sites, likely due to aqueous leaching of sodium from surface to subsurface soil horizons. Although we did not collect evidence of geophagy by bighorn sheep, the behavior is well known. However, trail camera photographs of bighorn sheep with their head next to the entrance of tortoise burrows suggests that they may periodically utilize sodium and other elements brought to the surface by desert tortoises that are otherwise unavailable to bighorn sheep on the surface.

California

Temporal, spatial, and chemical evolution of Quaternary high-silica rhyolites in the Mineral Mountains, Utah

The Mineral Mountains in southwestern Utah are a structurally controlled core complex at the confluence of the Colorado Plateau and the Basin and Range physiographic provinces. Aside from hosting Utah’s largest batholith, the Mineral Mountains host some of the State’s youngest high-silica rhyolites, which have been linked to a magma source that is presently being utilized as an enhanced geothermal system. The high-silica rhyolites take the form of effusive lavas and domes, and explosive products are rare. Previous K-Ar dating of these Pleistocene rhyolites placed eruptions between about 790 and 500 kilo-annum (ka) with contemporaneous basalts erupting in the valley to the east of the Mineral Mountains. Large uncertainties on these ages obscured the tempo of eruptions and thus hindered attempts to constrain the timescales of the petrogenetic processes that produced the rhyolites. In this study, we build on previous studies conducted in the 1970s and 1980s by using new geochronologic and geochemical data to investigate the temporal and spatial evolution of the youngest phase of volcanism in the Mineral Mountains. We identify two major eruptive periods, from approximately 850 to 750 ka and from approximately 590 to 480 ka. The older phase is characterized by the eruption of several basaltic lavas, two obsidian flows, and a series of coalescing porphyritic rhyolite domes. The younger phase included the eruption of six evolved high-silica rhyolite domes and one pyroclastic deposit, followed by the eruption of trachyandesite in the adjacent valley to the east. Whole-rock geochemical data indicate that the rhyolites can be divided into three chemical groups, with more evolved compositions erupting through time. The youngest rhyolites along the range crest have the lowest total iron and TiO 2 concentrations and the highest incompatible element concentrations, indicative of increasing differentiation with time and elevation. Improved precision on the eruption ages indicates a recurrence interval of approximately 20 thousand years. The eruptive flux for both periods of rhyolitic volcanism is about 0.01 cubic kilometers per thousand years, which is less than the magma resurgence flux rates for syn-caldera and post-caldera eruptions of the Valles Caldera and Yellowstone Caldera volcanic systems. Collectively, these geochemical, geochronological, and volumetric data may facilitate a better understanding of heat flux and the longevity of magmatic sources related to geothermal resources in similar small-volume, silicic systems.

Utah

Wangyanite, PdNi8S8, a new Pd end-member mineral of the pentlandite group from the J-M reef, Stillwater Complex, Montana, USA

Wangyanite (IMA2024-008a), ideally PdNi 8 S 8 , is a Pd end-member mineral of the pentlandite group that was discovered in the J-M reef of the Stillwater Complex, Montana, USA. Wangyanite occurs as anhedral-subhedral granular crystals 200–400 µm in size, associated with isoferroplatinum, braggite, pentlandite, and chalcopyrite interstitial to plagioclase grains within anorthosite. Wangyanite exhibits a yellowish brown color with a black streak and a metallic luster. It is brittle with uneven fractures, and has a calculated density of 5.14 g/cm 3 . The mineral does not show discernible pleochroism, bireflectance, or anisotropy. It has an average composition of 9.95 wt.% Pd, 31.95 wt.% Ni, 25.02 wt.% Fe, 0.57 wt.% Co, 31.74 wt.% S, totaling 99.23 wt.%. The empirical formula, based on eight sulfur atoms per formula unit, is (Pd 0.76 Co 0.08 ) Σ0.84 (Ni 4.39 Fe 3.60 ) Σ7.99 S 8 . Wangyanite has a cubic cell with a space group of Fm -3 m (#225), having lattice parameters of a = 10.1167(12) Å, V = 1035.4(4) Å 3 , and Z = 4. Its crystal structure has been solved by single-crystal three-dimensional electron diffraction study. The strongest X-ray diffraction lines of wangyanite are claculated at [ d in Å ( I %)( hkl )]: 5.841(14.03)(111), 3.050(100)(311), 1.947(29.16)(115,333), 1.264(11.66)(800), 3.577(8.79)(220), 2.920(20.82)(222), and 2.321(9.34)(331). Wangyanite shares the same crystal structure as pentlandite, but the octahedrally coordinated site is mainly occupied by Pd in wangyanite. Based on the textural features and previous experimental Pd-Fe-Ni-S phase system, wangyanite could form by peritectic reaction between braggite, pentlandite and sulfide liquid. These mineral associations are stable in a Ni-Pd-rich sulfide melt system at about 550 °C or even lower temperature. Therefore, wangyanite can potentially serve as an indicator of the presence of Pd-rich residual melts. The mineral is named in honor of Prof. Christina Yan Wang, a well-known researcher on platinum-group element (PGE) occurrences and enrichment mechanisms in mafic-ultramafic intrusions, notably those deposits related to the Emeishan large igneous province in China.

Montana

Quantitative mineral resource assessment of lithium pegmatite deposits in the southern Appalachian orogen

The first quantitative mineral resource assessment for undiscovered lithium pegmatite deposits in the southern Appalachian region of the United States was conducted. Permissive tracts for lithium pegmatite deposits were delineated by integrating lithological, tectonic, geochemical, geophysical and mineral occurrence data. Lithium pegmatite prospectivity of the tracts was ranked with simplified mappable criteria, including proximity to Paleozoic felsic intrusions and major lithotectonic structures, stream sediment geochemical anomalies, and pegmatite occurrence data. The geospatial data and permissive tracts were used to estimate the number of undiscovered lithium pegmatite deposits. These estimates were integrated into probabilistic simulations along with a new global lithium pegmatite grade and tonnage dataset to quantify potential contained undiscovered lithium resources. An economic filter was applied to convert the probabilistic estimates of contained lithium into recoverable material. The identified lithium pegmatite resources for the Carolina Lithium and Kings Mountain deposits, North Carolina, contain 1589 thousand tons (kt) of Li 2 O. The median contained undiscovered resource for the southern Appalachian orogen was estimated to be 2240 kt Li 2 O. At 90% confidence, the region contains at least 130 kt Li 2 O, and 10,700 kt at 10% confidence. After applying economic filters, the median recoverable contained resource was 1430 kt Li 2 O, corresponding to approximately 201 years of current lithium imports for consumption in the United States. North and South Carolina are likely to contain most of these resources. Coarse data resolution and intra-state variations in the geological data contribute to uncertainty of undiscovered lithium pegmatite resources. Continued efforts to harmonize disparate geospatial datasets with updated or new information can improve the accuracy and precision of estimated undiscovered lithium pegmatite resources in the study area and at broader scales.

Alabama, Georgia, Maryland, North Carolina, South

Rare earth element-mineralized carbonatite in the Bear Lodge Alkaline Complex, USA—Ore genesis implications from fluid inclusion characterization

Rare earth element (REE) resources of the Bear Lodge Alkaline Complex, Wyoming, are hosted in variably leached carbonatite spatially related to diatreme breccia pipes. We investigated the genesis of REE and lesser-known gold resources through fluid inclusion analysis of carbonatite, fluorite breccia, and smoky quartz vein samples. Physicochemical characteristics of inclusion-trapped fluids were evaluated using petrography, microthermometry, Raman spectroscopy, decrepitate mound analysis, energy-dispersive spectroscopy, laser ablation inductively coupled plasma mass spectrometry, and noble gas isotope analysis. Microthermometry results reveal three fluid types that affected carbonatite dikes within deeper zones that escaped near-surface, ore-grade REE enrichment: (1) high-temperature (330–432°C) magmatic fluid captured in fine-grained calcite; (2) REE-enriched alkali bicarbonate-sulfate brine; and (3) low-temperature (117–182°C) diluted magmatic or meteoric water. Multiphase brine-like inclusions contain burbankite, nahcolite, strontianite, celestine and alkali sulfate daughter crystals, linking them to early burbankite mineralization. Peripheral smoky quartz and fluorite occurrences at Smith Ridge, 1.5 km from the central carbonatite dike swarm, contain primary inclusions that are Cl-poor and rich in Na-HCO 3 -SO 4 , similar to secondary and pseudosecondary inclusions in carbonatites. Helium isotopes reveal a MORB-like source for carbonatite samples and an older crust signature at Smith Ridge, consistent with the proximal ridge-top exposures of Archean granite. Results from this fluid inclusion study coupled with previous studies of carbonatite mineral paragenesis, show that light REEs (LREEs) were not mobilized great distances. Instead, burbankite crystallized within carbonatite from alkali bicarbonate fluids. With sodium retained in early burbankite, outward-emanating fluids enriched in potassium relative to sodium (higher K:Na) resulted in potassium–ferric iron metasomatism of silicate host rocks. This alkali fractionation was accompanied by fractionation of LREEs and heavy REEs (HREEs), with LREEs dominating the central carbonatite resources. In contrast, areas of peripheral REE mineralization at Bear Lodge are commonly characterized by higher HREE:LREE ratios. The K:Na ratio of associated fenites or alteration assemblages could be indicative of early crystallized burbankite in carbonatites and REE fractionation processes potentially leading to areas of concentrated HREEs with greater supply vulnerabilities.

South Dakota, Wyoming

Factors regulating the potential for freshwater mineral soil wetlands to function as natural climate solutions

There are increasing global efforts and initiatives aiming to tackle climate change and mitigate its impacts via natural climate solutions (NCS). Wetlands have been considered effective NCS given their capacity to sequester and retain atmospheric carbon dioxide (CO 2 ) while also providing a myriad of other ecosystem functions that can assist in mitigating the impacts of climate change. However, wetlands have a dual impact on climate, influencing the atmospheric concentrations of both CO 2 and methane (CH 4 ). The cooling effect associated with wetland CO 2 sequestration can be counterbalanced by the warming effect caused by CH 4 emissions from wetlands. The relative ability of wetlands to sequester CO 2 versus emit CH 4 is dependent on a suite of interacting physical, chemical, and biological factors, making it difficult to determine if/which wetlands are considered important NCS. The fact that wetlands are embedded in landscapes with surface and subsurface hydrological connections to other wetlands (i.e., wetlandscapes) that flow over and through geochemically active soils and sediments adds a new layer of complexity and poses further challenges to understanding wetland carbon sequestration and greenhouse gas fluxes at large spatial scales. Our review demonstrates how additional scientific advances are required to understand the driving mechanisms associated with wetland carbon cycling under different environmental conditions. It is vital to understand wetland functionality at both wetland and wetlandscape scales to effectively implement wetlands as NCS to maximize ecological, social, and economic benefits.

Wetlands

A global assessment of SAOCOM-1 L-band stripmap data for InSAR characterization of volcanic, tectonic, cryospheric, and anthropogenic deformation

SAOCOM-1 is an L-band (23.5 cm) synthetic aperture radar (SAR) constellation made up of two satellites launched in 2018 and 2020 by Comisión Nacional de Actividades Espaciales (CONAE, Argentina). In this contribution, we present a global summary of interferometric SAR (InSAR) observations of ground deformation with SAOCOM-1 stripmap data for tracking volcanic, tectonic, glacier, and anthropogenic deformation. These examples include: 1) episodes of unrest at volcanoes in the Aleutian Islands, Southern Andes, and Italy, with line-of-sight (LOS) deformation from 4 cm/yr in InSAR time series to ~70 cm in interferograms; 2) dike intrusions in Hawai’i; 3) earthquakes in the Andean fold and thrust belt and the East Anatolian fault; 4) ice flow of the Southern Patagonia icefield; and 5) subsidence due to lithium brine extraction in the Salar de Atacama basin (northern Chile). Comparisons between SAOCOM-1, ALOS-2 SM3, Sentinel-1, and TerraSAR-X/ TanDEM-X/PAZ (TSX/TDX/PAZ) mean velocities from InSAR time series show a 1:1 ± 3% correlation in the LOS velocity, which highlights the high accuracy of SAOCOM-1 data. The minimum deformation that we measured in individual interferograms is 4 ± 0.6 cm. One limitation of SAOCOM-1 is the lack of a global acquisition program, which reduces its global and broader applications. Considering the repeat periods, background observation program, and lack of a controlled orbital tube, the best suited targets for SAOCOM-1 InSAR are two. First, volcanoes that deform with secular rates located in vegetated regions in mid- and high-latitudes, and/or that undergo transient episodes of fast deformation in which C-band coherence is lost quickly. Second, glaciers where coherence can be sustained during the repeat period of eight days.

IEEE Transactions on Geoscience and Remote Sensing

Comparing magmatism and hydrothermal alteration using magnetic modelling and stable isotopes at the Clementine porphyry copper prospect, Montana, USA

Recent mapping of the underexplored Clementine prospect in southwestern Montana has revealed evidence of hydrothermal alteration and mineralized breccia vein gossan interpreted to represent the upper expression of a Cretaceous, sediment-hosted copper porphyry system. The prospect is at the nexus of several Cretaceous granites, including the pre-mineralization Butte Granite and Big Hole Canyon plutons and local pre- to post-mineralization granite intrusions. Here, 3D magnetic inversions and stable isotope data are used to evaluate the spatial and genetic relationship of mineralization and Cretaceous magmatism. Magnetic inversions reveal a zone of high magnetic susceptibility beneath the prospect that is related to an exposure of unaltered, likely post-mineralization granite. The granite appears to connect to the Big Hole Canyon pluton at depth, suggesting it is a late-stage differentiate of the cooling, pre-mineralization pluton that may have been one of several potential heat sources for the mineral system at Clementine. This is supported by carbon isotope values of graphite that indicate organic material in shale of the Cretaceous Kootenai Formation was subject to metamorphism. Preliminary light hydrogen isotope values of actinolite hydrothermal orbs suggest formation following magmatic outgassing during thermal advection from an underlying intrusion.

Montana

Widespread occurrence of former anhydrite phenocrysts in Laramide-age magmas related to porphyry-skarn Cu mineralization at Santa Rita and Hanover-Fierro, New Mexico, USA

Reports of magmatic anhydrite are relatively rare, with only ~30 occurrences documented worldwide so far. However, magmatic anhydrite saturation is difficult to recognize because anhydrite decomposes rapidly in near-surface environments. In most cases, only anhydrite inclusions shielded within other phenocryst phases were able to survive. Alternatively, since anhydrite phenocrysts preserved in fresh volcanic rocks are characteristically intergrown with apatite phenocrysts, the former presence of anhydrite phenocrysts can be recognized based on the occurrence of lath-shaped cavities that show a strong spatial association with apatite phenocrysts. These cavities can be either empty or filled with low-temperature, secondary minerals such as zeolites, carbonates, or microcrystalline silica. A systematic search for the occurrence of such cavities, combined with optical and Raman-spectroscopic identification of anhydrite inclusions preserved within apatite, hornblende and quartz phenocrysts, demonstrates that most of the Laramide-age magmas associated with the Santa Rita and Hanover-Fierro porphyry-skarn Cu (Zn, Mo, Au, Pb) deposits were saturated in magmatic anhydrite. The anhydrite typically coexisted with monosulfide solid solution (MSS), suggesting oxygen fugacities of ~2.0±0.5 log units above the fayalite-magnetite-quartz buffer. The magmas range from andesitic to rhyodacitic in composition, and from shortly pre-mineralization (~61 Ma) to shortly post-mineralization (~57 Ma) in age. In three samples with particularly well-recognizable former anhydrite phenocrysts, their modal abundance could be quantified based on high-resolution scans of polished hand specimens. The observed modal anhydrite abundances of 0.63–1.8 vol% translate into minimum magma sulfur contents of 0.20–0.56 wt% S. The highest sulfur content of 0.56 wt% S is difficult to reconcile with available anhydrite solubility models, but it could be reproduced in an anhydrite solubility experiment performed at 950 °C and 1.15 GPa on a natural latite containing 13.1 wt% dissolved H2O. The sample with the second-highest sulfur content of 0.26 wt% S requires ~10 wt% H2O in the silicate melt, and, consequently, a minimum pressure of ~0.5 GPa. Taken together, the results suggest that the magmas of the Central Mining District were extremely hydrous and thus originated from great depth. Indeed, their major element compositions and reconstructed H2O and S contents agree well with experimentally observed and numerically predicted compositions of residual silicate melts after 50–70 wt% crystallization of ordinary arc basalts at high pressure and high oxygen fugacities.

New Mexico

Solution-collapse breccia pipe uranium deposits of the southern Colorado Plateau, northwestern Arizona, USA

Some of the highest-grade uranium deposits in the United States occur in breccia pipes that formed by solution and collapse of sedimentary strata, which occur in the southern portion of the Colorado Plateau in northwestern Arizona. The host breccia pipes are up to 1200 m in vertical extent, average about 90 m in diameter, and can cross-cut strata from their base in the Mississippian Redwall Limestone to as stratigraphically high on some plateaus as the Triassic Chinle Formation. These uranium-base metal deposits are up to 600 m thick and formed within the breccia pipes where they transect the Permian Coconino Sandstone, Hermit Formation, and the Esplanade Sandstone. Of the hundreds of breccia pipes identified across this region, only a small percentage are known to contain mineralization. The main uranium ore mineral is uraninite that is intergrown with at least 20 base-metal sulfide minerals, which contribute Fe, Cu, Co, As, Pb, Zn, Ni, and Ag to the deposits. This study considered regional stratigraphy, sulfur isotope systematics, mineralogy, in situ dating, and compilation and analysis of previous work on the deposits. A comprehensive deposit model has not been published for these deposits. This analysis identified new additions to update the deposit model for these unusual, possibly unique deposits. Proposed modifications to the model include: (1) the source, mechanisms, timing of the base-metal sulfide mineral assemblages, and (2) the source, mechanism, and timing of the uranium mineralization. Sulfide and uranium deposition are shown to be separate mineralization events. The study proposes the possible role of gypsum as a source of sulfur for the sulfide minerals in the deposits. Groundwaters carrying uranium encountered the preexisting sulfides in breccia pipes, reducing the uranyl ions, and precipitating U oxide (as uraninite). Analysis of the regional stratigraphy recognized that numerous beds of gypsum are in the strata that lie only tens of meters above the breccia pipe deposits. In the breccia pipe region, if these stratigraphic units (Toroweap and Kaibab Formations) do not contain gypsum layers then the underlying pipes are not mineralized; where these Permian gypsum layers do occur, breccia pipes can host mineralization. This new understanding should be useful in identifying the prospective region for mineralized pipes.

Arizona

In-situ geochronology using LA-ICP-MS/MS: Application of the Lu-Hf system in carbonate, apatite and fluorite

Geochronology is a fundamental tool for reconstructing earth history and constraining the timing of ore deposit formation. Traditionally, U-rich minerals like zircon, titanite, monazite and apatite have been analysed to determine the timing of mineralization and alteration events. However, not all deposits or alteration assemblages contain these minerals, and the U-Pb system can be disturbed due to open system behaviour. We present a methodology for obtaining in-situ Lu-Hf dates from various minerals to demonstrate the potential for dating ore deposits that lack U-rich minerals. Carbonate, apatite and fluorite minerals from different tectonic settings and geological environments were analysed. We acquired Lu-Hf and REE (rare earth element) data from carbonate minerals from a carbonatite orebody and dike samples from the Mountain Pass REE carbonatite deposit in California, USA. We also tested a ‘double-dating’ method, where U-Th-Pb dates and Lu-Hf dates were obtained from the same analysis of apatite from rocks in the Michigan’s Great Lakes Tectonic Zone. Preliminary results for Lu-Hf dating of fluorite from carbonatite rocks in the Lemitar Mountains of New Mexico are also included. The analytical methodology shows promising results in each of these cases where there is sufficient parent Lu and U and measurable daughter Hf and Pb respectively.

Conference Paper

Mafic alkaline magmatism and rare earth element mineralization in the Mojave Desert, California: The Bobcat Hills connection to Mountain Pass

Occurrences of alkaline and carbonatite rocks with high concentrations of rare earth elements (REE) are a defining feature of Precambrian geology in the Mojave Desert of southeastern California. The most economically important occurrence is the carbonatite stock at Mountain Pass, which constitutes the largest REE deposit in the United States. A central scientific goal is to understand the genesis of the carbonatite ore body in the context of widespread REE-rich igneous activity. A swarm of mafic alkaline (shonkinite) dikes has been mapped and sampled at Bobcat Hills, 65 km southeast of the Mountain Pass mine. Whole-rock geochemistry and zircon geochronology demonstrate a clear affinity to the ca. 1.4 Ga Mountain Pass intrusive system. Bobcat Hills dikes have comparably high REE concentrations (La ∼1,000× chondritic) and an error-weighted mean 207 Pb/ 206 Pb zircon crystallization age of 1,426 ± 2 Ma (2 σ ). Unlike the alkaline intrusions at Mountain Pass, which have abundant inherited zircon from Paleoproterozoic basement rocks and crustally influenced oxygen isotope compositions (δ 18 O zircon = 6.5–7.5‰), the Bobcat Hills dikes lack any evidence of crustal assimilation and have oxygen isotope values that overlap a mantle range (Bobcat Hills average δ 18 O zircon = 5.6 ± 0.3‰). The dikes were a high-temperature, early center of mafic alkaline magmatism in the Mojave Desert that serve as a snapshot of melt generation from a spatially extensive, metasomatized mantle source. We propose that modification of the crust over many tens of Myr at Mountain Pass created an environment that favored crustal assimilation and enabled ascent of late-stage, REE-rich carbonatite magmas.

California

A review of abrupt permafrost thaw: Definitions, usage, and a proposed conceptual framework

Purpose of Review We review how ‘abrupt thaw’ has been used in published studies, compare these definitions to abrupt processes in other Earth science disciplines, and provide a definitive framework for how abrupt thaw should be used in the context of permafrost science. Recent Findings We address several aspects of permafrost systems necessary for abrupt thaw to occur and propose a framework for classifying permafrost processes as abrupt thaw in the future. Based on a literature review and our collective expertise, we propose that abrupt thaw refers to thaw processes that lead to a substantial persistent environmental change within a few decades. Abrupt thaw typically occurs in ice-rich permafrost but may be initiated in ice-poor permafrost by external factors such as hydrologic change (i.e., increased streamflow, soil moisture fluctuations, altered groundwater recharge) or wildfire. Summary Permafrost thaw alters greenhouse gas emissions, soil and vegetation properties, and hydrologic flow, threatening infrastructure and the cultures and livelihoods of northern communities. The term ‘abrupt thaw’ has emerged in scientific discourse over the past two decades to differentiate processes that rapidly impact large depths of permafrost, such as thermokarst, from more gradual, top-down thaw processes that impact centimeters of near-surface permafrost over years to decades. However, there has been no formal definition for abrupt thaw and its use in the scientific literature has varied considerably. Our standardized definition of abrupt thaw offers a path forward to better understand drivers and patterns of abrupt thaw and its consequences for global greenhouse gas budgets, impacts to infrastructure and land-use, and Arctic policy- and decision-making.

Current Climate Change Reports

Geochemical, mineralogical, and isotopic evidence for multi-stage genesis of the Hicks Dome REE + Y-HFSE-fluorite deposit, Illinois, USA

Hicks Dome hosts breccias enriched in rare earth elements (REE), Y, Th, F, Ba, Ti, Nb, and Be, alongside spatially associated lamprophyre dikes (ca. 271 Ma). Hicks Dome is located within the Illinois–Kentucky Fluorspar District, which hosts fluorite, Pb–Zn, and barite resources. This study investigates the genetic relationships between Hicks Dome mineralization in breccias, alkaline magmatism, and Illinois–Kentucky Fluorspar District mineralization. Lamprophyre dikes are light REE–enriched with chondrite-normalized abundances decreasing from La to Lu. The Host Breccia exhibits middle and heavy REE–enriched patterns that mirror those of the principal REE–Th host minerals, including fluorapatite, xenotime, and thorite. Textural evidence suggests recrystallization of phosphates, sulfates, and Ti–Nb oxides in the Host Breccia. U–Pb geochronology constrains multiple mineralizing events, with ages of 277 ± 18 Ma from low-Th apatite interpreted as main-stage mineralization, and 121.6 ± 9.7 Ma from high-Th apatite indicating later overprinting. O–H–C stable isotope data provide evidence for multiple stages of fluid-rock interaction and fluid mixing: (1) early magmatic fluids dissolved limestone country rock, (2) mixing between magmatic fluids and basinal brines led to main-stage mineralization in the Host Breccia, and (3) late-stage mineralization occurred following mixing of meteoric water and basinal brine. These results indicate that heavy REEs, high field strength elements, and fluorine precipitated proximal to its alkaline magmatic source because of fluid–rock interactions and fluid mixing. Subsequent fluid mixing drove late-stage recrystallization and additional fluorite formation, a process that may be similar to mineralization in the Illinois-Kentucky Fluorspar District.

Illinois

Regional characterization of coal resources in the Gulf Coast Coal Region—In support of coal as a potential source for critical minerals and rare earth elements

There is increasing interest in extracting critical minerals (CM), including rare earth elements (REE), from coals in the United States to address the overreliance on imported REE. The Gulf Coast and the Fort Union regions are the two major lignite-bearing regions within the United States. Recent REE and CM studies of the lignite in these regions have indicated that the coals may be a viable source material for REE and CM extraction. To evaluate in-place coal as a potential source of REE and CM, the coal resources need to be quantified. This study presents the results of a regional analysis of Gulf Coast Coal Region lignite and bituminous coal resources that might be available as potential sources of REE and CM. The resource analysis used kriging methods to develop isopleth maps of cumulative coal thickness throughout the region using data from drill holes and measured mine and outcrop sections for a total of 31,181 data points. The estimated total remaining coal resource in the Gulf Coast Coal Region is about 83 billion metric tons in the upper 90 meters (approximately 300 feet) of the subsurface. The current estimate of remaining coal resources includes approximately 1.88 billion metric tons of coal that have been extracted in the region since 1983. Texas accounted for 39 percent (32 billion metric tons) of the remaining total resource, followed by Mississippi (24 percent, 20 billion metric tons ), Louisiana (14 percent, 12 billion metric tons), Tennessee (10 percent, 8.5 billion metric tons), and Arkansas (6 percent, 5.1 billion metric tons). Alabama, Georgia, Kentucky, and Missouri each accounted for less than 5 percent of the total resource; Georgia had the smallest resource estimated at 7 million metric tons. Here we report the first known statewide lignite resource estimates for Georgia, Kentucky (820 million metric tons), and Missouri (1,800 million metric tons). A comparison of the results of this study with those of previous Gulf Coast Coal Region and Fort Union Coal Region resource studies is difficult because each study used different data sources, assessment methodologies, overburden depths, and qualifying coal thicknesses.

Alabama, Arkansas, Florida, Georgia, Illinois, Lou

Coastal Science Navigator companion guide—Discover the U.S. Geological Survey coastal science products you need

The Coastal Science Navigator is an online gateway to a wide variety of U.S. Geological Survey (USGS) coastal change hazards-related information, data, and tools relevant to stakeholders’ scientific and decision-making needs. The products within the Coastal Science Navigator provide data related to past, present, and future threats to our coastlines. The filter search allows users to see all available products and identify relevant options by time scale, geographic scope, coastal hazard theme, and other filters. The guided search suggests products based on users’ answers to a short series of questions. A comprehensive summary is available for each product. The idea for the Coastal Science Navigator arose in 2020 in response to stakeholder feedback identifying the need for a central source for USGS coastal science information. It was published in July 2023 and initially included 55 products. Regular updates are planned to integrate other existing and new products. This guide introduces some of the many coastal change hazards-related products available through the USGS. In it, we showcase the products included in the Coastal Science Navigator’s initial publication in July 2023. While it is not representative of all the information, tools, and data available, we hope it serves as a compelling snapshot of what the USGS has to offer and encourages you to explore the Coastal Science Navigator to discover more of the products you need. To navigate this guide, the products have been organized by the time scale they are best suited for—past, present, or future—although many products cover multiple time scales. An additional section features software, one of the many product types available as filters within the Coastal Science Navigator. Other products include downloadable data, websites, and geonarratives (web pages that combine text, images, and interactive maps into narratives you can scroll through). Featured geographic scopes are also highlighted within this guide, detailing some of the many regions in which the USGS conducts research and illustrating another way to filter products within the Coastal Science Navigator.

Circular

Formation of the Mount Weld rare earth element deposit, Western Australia: A carbonatite-derived laterite

Carbonatite-hosted rare earth element (REE) deposits are the primary source of the world’s light REEs. The Mount Weld REE deposit in Western Australia is hosted in a lateritic sequence that reflects supergene enrichment of the underlying carbonatite. Water-rock interaction is a key to the formation of this world-class deposit. REE enrichment in the laterite is controlled by the breakdown of primary minerals, the release and transport of REEs, and the formation of secondary minerals. Secondary REE-bearing phosphate minerals are the primary REE-host phases in the laterite ore with monazite as the dominant phase; other REE-bearing phases include rhabdophane, cerianite, churchite, florencite, and crandallite subgroup minerals. Profiles through the laterite show that in the REE-rich zone, apatite and primary calcite and dolomite have broken down such that the loss of Ca and Mg, as well as Si and K, leads to a relative increase in the REEs. Sequestering of REEs in secondary mineral phases formed by groundwater further enhances the REE concentration.

Mount Weld Mine