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USGS2006

Modeling physical and biogeochemical controls over carbon accumulation in a boreal forest soil

Boreal soils are important to the global C cycle owing to large C stocks, repeated disturbance from fire, and the potential for permafrost thaw to expose previously stable, buried C. To evaluate the primary mechanisms responsible for both short- and long-term C accumulation in boreal soils, we developed a multi-isotope (12,14C) Soil C model with dynamic soil layers that develop through time as soil organic matter burns and reaccumulates. We then evaluated the mechanisms that control organic matter turnover in boreal regions including carbon input rates, substrate recalcitrance, soil moisture and temperature, and the presence of historical permafrost to assess the importance of these factors in boreal C accumulation. Results indicate that total C accumulation is controlled by the rate of carbon input, decomposition rates, and the presence of historical permafrost. However, unlike more temperate ecosystems, one of the key mechanisms involved in C preservation in boreal soils examined here is the cooling of subsurface soil layers as soil depth increases rather than increasing recalcitrance in subsurface soils. The propagation of the 14C bomb spike into soils also illustrates the importance of historical permafrost and twentieth century warming in contemporary boreal soil respiration fluxes. Both 14C and total C simulation data also strongly suggest that boreal SOM need not be recalcitrant to accumulate; the strong role of soil temperature controls on boreal C accumulation at our modeling test site in Manitoba, Canada, indicates that carbon in the deep organic soil horizons is probably relatively labile and thus subject to perturbations that result from changing climatic conditions in the future. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗

USGS2005

Geochemistry of the Amazon Estuary

The Amazon River supplies more freshwater to the ocean than any other river in the world. This enormous volume of freshwater forces the estuarine mixing out of the river channel and onto the continental shelf. On the continental shelf, the estuarine mixing occurs in a very dynamic environment unlike that of a typical estuary. The tides, the wind, and the boundary current that sweeps the continental shelf have a pronounced influence on the chemical and biological processes occurring within the estuary. The dynamic environment, along with the enormous supply of water, solutes and particles makes the Amazon estuary unique. This chapter describes the unique features of the Amazon estuary and how these features influence the processes occurring within the estuary. Examined are the supply and cycling of major and minor elements, and the use of naturally occurring radionuclides to trace processes including water movement, scavenging, sediment-water interaction, and sediment accumulation rates. The biogeochemical cycling of carbon, nitrogen, and phosphorus, and the significances of the Amazon estuary in the global mass balance of these elements are examined.

Amazon River↗

USGS1995

Geochemistry of sediments from coastal marshes of Louisiana

As a part of the U.S. Geological Survey Global Change and Climate History Program we have been studying the biogeochemistry of coastal marshes in Terrebonne Basin, Louisiana. Louisiana has about 40 percent of the coastal wetlands in the conterminous U.S. and it is losing wetlands at one of the highest rates in the U.S. with the conversion of about 65 km2/yr of marsh to open water (Britsch and Dunbar, 1993). The losses have been attributed to human and natural causes including saltwater intrusion through man-made canals, reduced sediment input, and regional subsidence. The net effect of these influences is to change the salinity of interior marshes in a fashion similar to a eustatic sea level rise. We are studying the cycling of carbon, sulfur, and other elements in sediments, waters, and marsh macrophytes in fresh, intermediate/brackish, and saltwater marshes in order to better understand how sea level rise, one aspect of global change, will influence and in turn be influenced by cycling of these elements. By characterizing the critical biogeochemical processes and the recent past environments in these rapidly changing marshes, we can improve predictions of future changes and interpretations of the historic geologic record in similar environments. In this report we describe our coastal marsh study sites in Louisiana, the types of samples collected, the collection methods, the chemical analysis methods, and selected chemical analysis results. Also included are summaries of the project quality control results. The raw chemical analysis results are provided in this report without interpretation. Interpretations will be provided in subsequent reports.

Louisiana↗

USGS2020

Soil biogeochemical responses of a tropical forest to warming and hurricane disturbance

Tropical forests represent <15% of Earths terrestrial surface yet support >50% of the planets species and play a disproportionately large role in determining climate due to the vast amounts of carbon they store and exchange with the atmosphere. Currently, disturbance patterns in tropical ecosystems are changing due to factors such as increased land use pressure and an occurrence of hurricanes. At the same time, these regions are expected to experience unprecedented warming before 2100. Despite the importance of these ecosystems for forecasting the global consequences of multiple stressors, our understanding of how projected changes in climate and disturbance will affect the biogeochemical cycling of tropical forests remains in its infancy. Until now, no studies to our knowledge have evaluated forest recovery following hurricane disturbance within the context of concurrent climatic change. Here, we present soil biogeochemical results from a tropical forest field warming experiment in Puerto Rico where, a year after experimental warming began, Hurricanes Irma and Mara greatly altered the forest, allowing a unique opportunity to explore the interacting effects of hurricane disturbance and warming. We tracked post-hurricane forest recovery for a year without warming to assess legacy effects of prior warming on the disturbance response, and then reinitiated warming treatments to further evaluate interactions between forest recovery and warmer temperatures. The data showed that warming affected multiple aspects of soil biogeochemical cycling even in the first year of treatment, with particularly large positive effects on soil microbial biomass pools (e.g., increases of 54, 43, and 46% relative to the control plots were observed for microbial biomass carbon, nitrogen, and phosphorus, respectively after 6 months of warming). We also observed significant effects of the hurricanes on soil biogeochemical cycling, as well as interactive controls of warming and disturbance. Taken together, our results showed dynamic soil responses that suggest the future of biogeochemical cycling in this tropical wet forest will be strongly shaped by the directional effects of warming and the episodic effects of hurricanes.

Puerto Rico↗

USGS2011

Land cover change, biogeochemical modelling of carbon stocks, and climate change in West Africa

The carbon in ecosystems exists in dynamic soil and vegetation pools which vary in amounts and cycle with the global atmosphere at varying rates. These stocks and fluxes play important roles in global carbon regulation and in the maintenance of goods and services. Changes in land cover or ecosystems result in increased or decreased fluxes to the atmosphere and play a major role in climate regulation. Carbon in soil is closely coupled to soil nitrogen and the continued mining of soil for crops or fuel without replenishment of nutrients results in decreased productivity and impacts food security. The assessment of these processes across large areas, although difficult, is aided by the integration of simulation modelling (biogeochemical and ecosystem) and remote sensing. We acquired satellite imagery for four periods from the 1960s to 2000s, trained environmental scientists from 14 countries on image analysis and interpretation, and now report systematic analyses of land cover changes in select countries of West Africa and quantify potential impacts of climate change and management at specific sites. Statistical changes and maps of land cover are documented for most countries. Senegal, for example, illustrates a 57 percent loss in dense forests between 1975 and 2000 with an even greater loss rate in the preceding 10 years. Bare soil increased 16.6 percent, often related to unproductive “badland” formation. Settlements increased 45.6 percent, and reforestation replaced bare sandy areas for sand dune stabilization. In some countries (Senegal and Ghana), the impact of these conversions and changes in land management and future projections has been incorporated into biogeochemical models to quantify carbon changes and project future carbon and crop scenarios. We present current assessments of carbon fluxes and the availability of data for these West African countries.

Conference Paper↗

USGS2020

Making ‘chemical cocktails’ – Evolution of urban geochemical processes across the periodic table of elements

Urbanization contributes to the formation of novel elemental combinations and signatures in terrestrial and aquatic watersheds, also known as ‘chemical cocktails.’ The composition of chemical cocktails evolves across space and time due to: (1) elevated concentrations from anthropogenic sources, (2) accelerated weathering and corrosion of the built environment, (3) increased drainage density and intensification of urban water conveyance systems, and (4) enhanced rates of geochemical transformations due to changes in temperature, ionic strength, pH, and redox potentials. Characterizing chemical cocktails and underlying geochemical processes is necessary for: (1) tracking pollution sources using complex chemical mixtures instead of individual elements or compounds; (2) developing new strategies for co-managing groups of contaminants; (3) identifying proxies for predicting transport of chemical mixtures using continuous sensor data; and (4) determining whether interactive effects of chemical cocktails produce ecosystem-scale impacts greater than the sum of individual chemical stressors. First, we discuss some unique urban geochemical processes which form chemical cocktails, such as urban soil formation, human-accelerated weathering, urban acidification-alkalinization, and Freshwater Salinization Syndrome. Second, we review and synthesize global patterns in concentrations of major ions, carbon and nutrients, and trace elements in urban streams across different world regions and make comparisons with reference conditions. In addition to our global analysis, we highlight examples from watersheds in the Baltimore-Washington DC area, USA, which show increased transport of major ions, trace metals, and nutrients across streams draining a well-defined land-use gradient. Urbanization increased the concentrations of multiple major and trace elements in streams draining human-dominated watersheds compared to reference conditions. Chemical cocktails of major and trace elements were formed over diurnal cycles coinciding with changes in streamflow, dissolved oxygen, pH, and other variables measured by high-frequency sensors. Some chemical cocktails of major and trace elements were also significantly related to specific conductance (p < 0.05), which can be measured by sensors. Concentrations of major and trace elements increased, peaked, or decreased longitudinally along streams as watershed urbanization increased, which is consistent with distinct shifts in chemical mixtures upstream and downstream of other major cities in the world. Our global analysis of urban streams shows that concentrations of multiple elements along the periodic table significantly increase when compared with reference conditions. Furthermore, similar biogeochemical patterns and processes can be grouped among distinct mixtures of elements of major ions, dissolved organic matter, nutrients, and trace elements as chemical cocktails. Chemical cocktails form in urban waters over diurnal cycles, decades, and throughout drainage basins. We conclude our global review and synthesis by proposing strategies for monitoring and managing chemical cocktails using source control, ecosystem restoration, and green infrastructure. We discuss future research directions applying the watershed chemical cocktail approach to diagnose and manage environmental problems. Ultimately, a chemical cocktail approach targeting sources, transport, and transformations of different and distinct elemental combinations is beneficial to more holistically monitor and manage the emerging impacts of chemical mixtures in the world's fresh waters.

Applied Geochemistry↗

USGS2018

Beyond clay: Towards an improved set of variables for predicting soil organic matter content

Improved quantification of the factors controlling soil organic matter (SOM) stabilization at continental to global scales is needed to inform projections of the largest actively cycling terrestrial carbon pool on Earth, and its response to environmental change. Biogeochemical models rely almost exclusively on clay content to modify rates of SOM turnover and fluxes of climate-active CO 2 to the atmosphere. Emerging conceptual understanding, however, suggests other soil physicochemical properties may predict SOM stabilization better than clay content. We addressed this discrepancy by synthesizing data from over 5,500 soil profiles spanning continental scale environmental gradients. Here, we demonstrate that other physicochemical parameters are much stronger predictors of SOM content, with clay content having relatively little explanatory power. We show that exchangeable calcium strongly predicted SOM content in water-limited, alkaline soils, whereas with increasing moisture availability and acidity, iron- and aluminum-oxyhydroxides emerged as better predictors, demonstrating that the relative importance of SOM stabilization mechanisms scales with climate and acidity. These results highlight the urgent need to modify biogeochemical models to better reflect the role of soil physicochemical properties in SOM cycling.

Biogeochemistry↗

USGS1993

Integration of environmental simulation models with satellite remote sensing and geographic information systems technologies: case studies

Environmental modelers are testing and evaluating a prototype land cover characteristics database for the conterminous United States developed by the EROS Data Center of the U.S. Geological Survey and the University of Nebraska Center for Advanced Land Management Information Technologies. This database was developed from multi temporal, 1-kilometer advanced very high resolution radiometer (AVHRR) data for 1990 and various ancillary data sets such as elevation, ecological regions, and selected climatic normals. Several case studies using this database were analyzed to illustrate the integration of satellite remote sensing and geographic information systems technologies with land-atmosphere interactions models at a variety of spatial and temporal scales. The case studies are representative of contemporary environmental simulation modeling at local to regional levels in global change research, land and water resource management, and environmental simulation modeling at local to regional levels in global change research, land and water resource management and environmental risk assessment. The case studies feature land surface parameterizations for atmospheric mesoscale and global climate models; biogenic-hydrocarbons emissions models; distributed parameter watershed and other hydrological models; and various ecological models such as ecosystem, dynamics, biogeochemical cycles, ecotone variability, and equilibrium vegetation models. The case studies demonstrate the important of multi temporal AVHRR data to develop to develop and maintain a flexible, near-realtime land cover characteristics database. Moreover, such a flexible database is needed to derive various vegetation classification schemes, to aggregate data for nested models, to develop remote sensing algorithms, and to provide data on dynamic landscape characteristics. The case studies illustrate how such a database supports research on spatial heterogeneity, land use, sensitivity analysis, and scaling issues involving regional extrapolations and parameterizations of dynamic land processes within simulation models.

Pecora 12 Symposium↗

USGS2017

Grand challenges in understanding the interplay of climate and land changes

Half of Earth’s land surface has been altered by human activities, creating various consequences on the climate and weather systems at local to global scales, which in turn affect a myriad of land surface processes and the adaptation behaviors. This study reviews the status and major knowledge gaps in the interactions of land and atmospheric changes and present 11 grand challenge areas for the scientific research and adaptation community in the coming decade. These land-cover and land-use change (LCLUC)-related areas include 1) impacts on weather and climate, 2) carbon and other biogeochemical cycles, 3) biospheric emissions, 4) the water cycle, 5) agriculture, 6) urbanization, 7) acclimation of biogeochemical processes to climate change, 8) plant migration, 9) land-use projections, 10) model and data uncertainties, and, finally, 11) adaptation strategies. Numerous studies have demonstrated the effects of LCLUC on local to global climate and weather systems, but these putative effects vary greatly in magnitude and even sign across space, time, and scale and thus remain highly uncertain. At the same time, many challenges exist toward improved understanding of the consequences of atmospheric and climate change on land process dynamics and services. Future effort must improve the understanding of the scale-dependent, multifaceted perturbations and feedbacks between land and climate changes in both reality and models. To this end, one critical cross-disciplinary need is to systematically quantify and better understand measurement and model uncertainties. Finally, LCLUC mitigation and adaptation assessments must be strengthened to identify implementation barriers, evaluate and prioritize opportunities, and examine how decision-making processes work in specific contexts.

Earth Interactions↗

USGS2009

The changing global carbon cycle: Linking plant-soil carbon dynamics to global consequences

Most current climate-carbon cycle models that include the terrestrial carbon (C) cycle are based on a model developed 40 years ago by Woodwell & Whittaker (1968) and omit advances in biogeochemical understanding since that time. Their model treats net C emissions from ecosystems as the balance between net primary production (NPP) and heterotrophic respiration (HR, i.e. primarily decomposition). Under conditions near steady state, geographic patterns of decomposition closely match those of NPP, and net C emissions are adequately described as a simple balance of NPP and HR (the Woodwell-Whittaker model). This close coupling between NPP and HR occurs largely because of tight coupling between C and N (nitrogen) cycles and because NPP constrains the food available to heterotrophs. Processes in addition to NPP and HR become important to understanding net C emissions from ecosystems under conditions of rapid changes in climate, hydrology, atmospheric CO 2 , land cover, species composition and/or N deposition. Inclusion of these processes in climate-C cycle models would improve their capacity to simulate recent and future climatic change. Processes that appear critical to soil C dynamics but warrant further research before incorporation into ecosystem models include below-ground C flux and its partitioning among roots, mycorrhizas and exudates; microbial community effects on C sequestration; and the effects of temperature and labile C on decomposition. The controls over and consequences of these processes are still unclear at the ecosystem scale. Carbon fluxes in addition to NPP and HR exert strong influences over the climate system under conditions of rapid change. These fluxes include methane release, wildfire, and lateral transfers of food and fibre among ecosystems. Water and energy exchanges are important complements to C cycle feedbacks to the climate system, particularly under non-steady-state conditions. An integrated understanding of multiple ecosystem-climate feedbacks provides a strong foundation for policies to mitigate climate change. Synthesis . Current climate systems models that include only NPP and HR are inadequate under conditions of rapid change. Many of the recent advances in biogeochemical understanding are sufficiently mature to substantially improve representation of ecosystem C dynamics in these models.

Journal of Ecology↗

USGS2011

Dust: Small-scale processes with global consequences

Desert dust, both modern and ancient, is a critical component of the Earth system. Atmospheric dust has important effects on climate by changing the atmospheric radiation budget, while deposited dust influences biogeochemical cycles in the oceans and on land. Dust deposited on snow and ice decreases its albedo, allowing more light to be trapped at the surface, thus increasing the rate of melt and influencing energy budgets and river discharge. In the human realm, dust contributes to the transport of allergens and pathogens and when inhaled can cause or aggravate respiratory diseases. Dust storms also represent a significant hazard to road and air travel. Because it affects so many Earth processes, dust is studied from a variety of perspectives and at multiple scales, with various disciplines examining emissions for different purposes using disparate strategies. Thus, the range of objectives in studying dust, as well as experimental approaches and results, has not yet been systematically integrated. Key research questions surrounding the production and sources of dust could benefit from improved collaboration among different research communities. These questions involve the origins of dust, factors that influence dust production and emission, and methods through which dust can be monitored.

Eos, Transactions, American Geophysical Union↗

USGS2023

Droughting a megadrought: Ecological consequences of a decade of experimental drought atop aridification on the Colorado Plateau

Global dryland vegetation communities will likely change as ongoing drought conditions shift regional climates towards a more arid future. Additional aridification of drylands can impact plant and ground cover, biogeochemical cycles, and plant-soil feedbacks, yet how and when these crucial ecosystem components will respond to drought intensification requires further investigation. Using a long-term precipitation reduction experiment (35% reduction) conducted across the Colorado Plateau and spanning ten years into a 20+ year regional megadrought, we explored how vegetation cover, soil conditions, and growing season nitrogen (N) availability are impacted by drying climate conditions. We observed large declines for all dominant plant functional types (C 3 and C 4 grasses and C 3 and C 4 shrubs) across measurement period, both in the drought treatment and control plots, likely due to ongoing regional megadrought conditions. In experimental drought plots, we observed less plant cover, less biological soil crust cover, warmer and drier soil conditions, and more soil resin-extractable N compared to the control plots. Observed increases in soil N availability were best explained by a negative correlation with plant cover regardless of treatment, suggesting that declines in vegetation N uptake may be driving increases in available soil N. However, in ecosystems experiencing long-term aridification, increased N availability may ultimately result in N losses if soil moisture is consistently too dry to support plant and microbial N immobilization and ecosystem recovery. These results show dramatic, worrisome declines in plant cover with long-term drought. Additionally, this study highlights that more plant cover losses are possible with further drought intensification, and underscore that, in addition to large drought effects on aboveground communities, drying trends drive significant changes to critical soil resources such as N availability, all of which could have long-term ecosystem impacts for drylands.

Global Change Biology↗

USGS2017

The concurrent use of novel soil surface microclimate measurements to evaluate CO2 pulses in biocrusted interspaces in a cool desert ecosystem

Carbon cycling associated with biological soil crusts, which occupy interspaces between vascular plants in drylands globally, may be an important part of the coupled climate-carbon cycle of the Earth system. A major challenge to understanding CO 2 fluxes in these systems is that much of the biotic and biogeochemical activity occurs in the upper few mm of the soil surface layer (i.e., the ‘mantle of fertility’), which exhibits highly dynamic and difficult to measure temperature and moisture fluctuations. Here, we report a multi-sensor approach to simultaneously measuring temperature and moisture of this biocrust surface layer (0–2 mm), and the deeper soil profile, concurrent with automated measurement of surface soil CO 2 effluxes. Our results illuminate robust relationships between biocrust water content and field CO 2 pulses that have previously been difficult to detect and explain. All observed CO 2 pulses over the measurement period corresponded to surface wetting events, including when the wetting events did not penetrate into the soil below the biocrust layer (0–2 mm). The variability of temperature and moisture of the biocrust surface layer was much greater than even in the 0–5 cm layer of the soil beneath the biocrust, or deeper in the soil profile. We therefore suggest that coupling surface measurements of biocrust moisture and temperature to automated CO 2 flux measurements may greatly improve our understanding of the climatic sensitivity of carbon cycling in biocrusted interspaces in our study region, and that this method may be globally relevant and applicable.

Biogeochemistry↗

USGS1998

Mississippi Basin Carbon Project science plan

Understanding the carbon cycle is one of the most difficult challenges facing scientists who study the global environment. Lack of understanding of global carbon cycling is perhaps best illustrated by our inability to balance the present-day global CO 2 budget. The amount of CO 2 produced by burning fossil fuels and by deforestation appears to exceed the amount accumulating in the atmosphere and oceans. The carbon needed to balance the CO 2 budget (the so-called "missing" carbon) is probably absorbed by land plants and ultimately deposited in soils and sediments. Increasing evidence points toward the importance of these terrestrial processes in northern temperate latitudes. Thus, efforts to balance the global CO 2 budget focus particular attention on terrestrial carbon uptake in our own North American "backyard." The USGS Mississippi Basin Carbon Project conducts research on the carbon budget in soils and sediments of the Mississippi River basin. The project focuses on the effects of land-use change on carbon storage and transport, nutrient cycles, and erosion and sedimentation throughout the Mississippi River Basin. Particular emphasis is placed on understanding the interactions among changes in erosion, sedimentation, and soil dynamics. The project includes spatial analysis of a wide variety of geographic data sets, estimation of whole-basin and sub-basin carbon and sediment budgets, development and implementation of terrestrial carbon-cycle models, and site-specific field studies of relevant processes. The USGS views this project as a "flagship" effort to demonstrate its capabilities to address the importance of the land surface to biogeochemical problems such as the global carbon budget.

Open-File Report↗

USGS2024

Tropical forests and global change: Biogeochemical responses and opportunities for cross-site comparisons, an organized INSPIRE session at the 108th Annual Meeting, Ecological Society of America, Portland, Oregon, USA, August 2023

Tropical forests play a critical role in the global carbon (C) cycle. These ecosystems maintain the highest rates of net primary production (NPP) on Earth (Hengl et al ., 2017 ), contain c . 30% of terrestrial C stocks (Jobbagy & Jackson, 2000 ), and have some of the largest stores of fine-root biomass globally (Jackson et al ., 1996 ), as well as higher fine-root production and turnover rates compared with other biomes (Cusack et al ., 2021 ). Tropical forest responses to projected warming, altered rainfall regimes, and elevated CO 2 concentrations (IPCC, 2021 ) are likely to be different from other ecosystems because of their unique characteristics (Box 1 ), making targeted research and model development important for understanding tropical forest–climate feedbacks. There is now a critical mass of long-term global change field experiments and modeling efforts in tropical forests, yet thus far there has been little synthesis, cross-site comparison, or multi-site standardized experimentation among tropical forests to help us understand how these biomes are changing. An organized INSPIRE session at the 108 th Annual Meeting of the Ecological Society of America set out to tackle just this. Speakers covered large-scale tropical forest field experiments and modeling efforts, with an emphasis on changes in ecosystem biogeochemistry under warming, drying, elevated atmospheric CO 2 , and changing nutrient status. In this Meeting report, we provide an overview of the large-scale global change experiments presented and highlight the main objectives and opportunities for tropical forest research that emerged, including cross-site comparisons and integration with ecosystem-scale models (Fig. 1 ).

New Phytologist↗

USGS2024

Arsenic and other geogenic contaminants in global groundwater

Geogenic groundwater contaminants (GGCs) affect drinking-water availability and safety, with up to 60% of groundwater sources in some regions contaminated by more than recommended concentrations. As a result, an estimated 300–500 million people are at risk of severe health impacts and premature mortality. In this Review, we discuss the sources, occurrences and cycling of arsenic, fluoride, selenium and uranium, which are GGCs with widespread distribution and/or high toxicity. The global distribution of GGCs is controlled by basin geology and tectonics, with GGC enrichment in both orogenic systems and cratonic basement rocks. This regional distribution is broadly influenced by climate, geomorphology and hydrogeochemical evolution along groundwater flow paths. GGC distribution is locally heterogeneous and affected by in situ lithology, groundwater flow and water–rock interactions. Local biogeochemical cycling also determines GGC concentrations, as arsenic, selenium and uranium mobilizations are strongly redox-dependent. Increasing groundwater extraction and land-use changes are likely to modify GGC distribution and extent, potentially exacerbating human exposure to GGCs, but the net impact of these activities is unknown. Integration of science, policy, community involvement programmes and technological interventions is needed to manage GGC-enriched groundwater and ensure equitable access to clean water.

Nature Reviews Earth & Environment↗

USGS2008

Increasing eolian dust deposition in the western United States linked to human activity

Mineral aerosols from dust are an important influence on climate and on marine and terrestrial biogeochemical cycles. These aerosols are generated from wind erosion of surface soils. The amount of dust emission can therefore be affected by human activities that alter surface sediments. However, changes in regional- and global-scale dust fluxes following the rapid expansion of human populations and settlements over the past two centuries are not well understood. Here we determine the accumulation rates and geochemical properties of alpine lake sediments from the western interior United States for the past 5,000 years. We find that dust load levels increased by 500% above the late Holocene average following the increased western settlement of the United States during the nineteenth century. We suggest that the increased dust deposition is caused by the expansion of livestock grazing in the early twentieth century. The larger dust flux, which persists into the early twenty-first century, results in a more than fivefold increase in inputs of K, Mg, Ca, N and P to the alpine ecosystems, with implications for surface-water alkalinity, aquatic productivity and terrestrial nutrient cycling.

Colorado↗

USGS2014

Mercury in fishes from 21 national parks in the Western United States: inter- and intra-park variation in concentrations and ecological risk

Mercury (Hg) is a global contaminant and human activities have increased atmospheric Hg concentrations 3- to 5-fold during the past 150 years. This increased release into the atmosphere has resulted in elevated loadings to aquatic habitats where biogeochemical processes promote the microbial conversion of inorganic Hg to methylmercury, the bioavailable form of Hg. The physicochemical properties of Hg and its complex environmental cycle have resulted in some of the most remote and protected areas of the world becoming contaminated with Hg concentrations that threaten ecosystem and human health. The national park network in the United States is comprised of some of the most pristine and sensitive wilderness in North America. There is concern that via global distribution, Hg contamination could threaten the ecological integrity of aquatic communities in the parks and the wildlife that depends on them. In this study, we examined Hg concentrations in non-migratory freshwater fish in 86 sites across 21 national parks in the Western United States. We report Hg concentrations of more than 1,400 fish collected in waters extending over a 4,000 kilometer distance, from Alaska to the arid Southwest. Across all parks, sites, and species, fish total Hg (THg) concentrations ranged from 9.9 to 1,109 nanograms per gram wet weight (ng/g ww) with a mean of 77.7 ng/g ww. We found substantial variation in fish THg concentrations among and within parks, suggesting that patterns of Hg risk are driven by processes occurring at a combination of scales. Additionally, variation (up to 20-fold) in site-specific fish THg concentrations within individual parks suggests that more intensive sampling in some parks will be required to effectively characterize Hg contamination in western national parks. Across all fish sampled, only 5 percent had THg concentrations exceeding a benchmark (200 ng/g ww) associated with toxic responses within the fish themselves. However, Hg concentrations in 35 percent of fish sampled were above a benchmark for risk to highly sensitive avian consumers (90 ng/g ww), and THg concentrations in 68 percent of fish sampled were above exposure levels recommended by the Great Lakes Advisory Group (50 ng/g ww) for unlimited consumption by humans. Of the fish assessed for risk to human consumers (that is, species that are large enough to be consumed by recreational or subsistence anglers), only one individual fish from Yosemite National Park had a muscle Hg concentration exceeding the benchmark (950 ng/g ww) at which no human consumption is advised. Zion, Capital Reef, Wrangell-St. Elias, and Lake Clark National Parks all contained sites in which most fish exceeded benchmarks for the protection of human and wildlife health. This finding is particularly concerning in Zion and Capitol Reef National Parks because the fish from these parks were speckled dace, a small, invertebrate-feeding species, yet their Hg concentrations were as high or higher than those in the largest, long-lived predatory species, such as lake trout. Future targeted research and monitoring across park habitats would help identify patterns of Hg distribution across the landscape and facilitate management decisions aimed at reducing the ecological risk posed by Hg contamination in sensitive ecosystems protected by the National Park Service.

Alaska;Arizona;California;Colorado;Idaho;Montana;N↗