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USGS1989

Depositional aspects and a guide to Paleocene coal-bearing sequences, Powder River Basin

The Paleocene coal-bearing sequences in the northern Powder River Basin are contained in the Tongue River Member of the Fort Union Formation and include anomalously thick (54 m) subbituminous coals. These thick coals have been the target of exploration and development for the past few decades. For the past decade, these coals have also been the object of depositional modeling studies [Law, 1976; Galloway, 1979; Flores, 1981, 1983, 1986; Ethridge and others, 1981; Ayers and Kaiser, 1984; Warwick, 1985; Ayers, 1986; Moore, 1986; Warwick and Stanton, 1988]. Intensive modeling of these coals has resulted in two major schools of thought. Firstly, Galloway [1979], Flores [1981, 1983, 1986], Ethridge and others [1981], Warwick [1985], Moore [1986], and Warwick and Stanton [1988] believe that the coals formed from peat that accumulated in swamps of fluvial systems. The fluvial systems are interpreted as a basin axis trunktributary complex that drained to the north-northeast into the Williston Basin. Secondly, Ayers and Kaiser [1984] and Ayers [1986] believe that the coals formed from peat swamps of deltaic systems. These deltas are envisioned to have prograded east to west from the Black Hills and infilled Lebo lake that was centrally located along the basin axis. In order to explain the low ash content of the thick coals, Flores [1981] proposed that they are formed as domed peats, similar in geomorphology to swamps associated with the modern fluvial systems in Borneo as described by Anderson [1964]. Ethridge and others [1981] suggested that these fluvial-related swamps are platforms well above drainage systems and are fed by ground water that is recharged from surrounding highlands. Warwick [1985], Warwick and Stanton [1988], Satchell [1984], and Pocknall and Flores [1987] confirmed the domed peat hypothesis by investigating the petrology and palynology of the thick coals. The purpose of this paper is to provide a guide to the depositional aspects of the thick coals in the Tongue River Member of the Fort Union Formation and, because of the biases of the field trip leaders, it elaborates on the fluvial origin of the swamps in which the thick coals formed. Case histories of these thick coals and associated sediments in the Gillette, Powder River, and Kaycee-Linch areas of Wyoming and in the Decker-Tongue River area of Montana (fig. 1) are highlighted on this field trip.

Montana, Wyoming↗

USGS1992

Ages, rare-earth element enrichment, and petrogenesis of tholeiitic and alkalic basalts from Kahoolawe Island, Hawaii

Kahoolawe Island, Hawaii (18×11 km), is a basaltic shield volcano with caldera-filling lavas, seven identified postshield vents, and at least two occurrences of apparent rejuvenated-stage eruptive. We examined 42 samples that represent all stages of Kahoolawe volcano stratigraphy for their petrography, whole-rock major-and trace-element contents, mineral compositions, and K−Ar ages. The two oldest shield samples have an average age of 1.34±0.08 Ma, and four postshield samples (3 are alkalic) average 1.15±0.03 Ma; ages of 1.08 and 0.99 Ma for two additional tholeiitic samples probably are minimum ages. Whole-rock major- and trace-element and mineral compositions of Kahoolawe shield and caldera-fill laves are generally similar to the lavas forming Kilauea and Mauna Loa tholeiitic shields, but in detail, Kahoolawe shield lavas have distinctive compositions. An unusual aspect of many postshield Ka-hoolawe lavas is anomalously high REE and Y abundances (up to 200 ppm La and 175 ppm Y) and negative Ce anomalies. These enrichments reflect surficial processes, where weathering and soil development promoted REE-Y transport at the weathering front. Major element abundances (MgO, 10–6 wt.%) for shield and caldera-fill basalts are consistent with fractionation of ol+px+pl in frequently replenished magma reservoirs. In general, tholeiitic basalts erupted from late vents are higher in SiO 2 than the shield lavas, and temporal differences in parental magma compositions are the likely explanation. Alkalic basalts that erupted from vents are comparable in composition to those at other Hawaiian volcanoes. Trace-element abundance ratios indicate that alkalic basalts represent either relatively lower degrees of melting of the shield source or a distinct source. Apparent rejuvenated-stage basalts (i.e., emplaced after substantial Kahoolawe erosion) are tholeiitic, unlike the rejuvenated-stages at other Hawaiian volcanoes (alkalic). Kahoolawe, like several other Hawaiian volcanoes, has intercalated tholeiitic and alkalic basalts in the postshield stage, but it is the only volcano that appears to have produced tholeiitic rejuvenated-stage lavas.

Hawaii↗

USGS2002

Geologic map of the Frisco quadrangle, Summit County, Colorado

New 1:24,000-scale geologic mapping along the Interstate-70 urban corridor in western Colorado, in support of the USGS Central Region State/USGS Cooperative Geologic Mapping Project, is contributing to a more complete understanding of the stratigraphy, structure, tectonic evolution, and hazard potential of this rapidly developing region. The 1:24,000-scale Frisco quadrangle is near the headwaters of the Blue River and straddles features of the Blue River graben (Kellogg, K.S., 1999, Neogene basins of the northern Rio Grande rift?partitioning and asymmetry inherited from Laramide and older uplifts: Tectonophysics, v. 305, p. 141-152.), part of the northernmost reaches of the Rio Grande rift, a major late Oligocene to recent zone of extension that extends from Colorado to Mexico. The Williams Range thrust fault, the western structural margin of the Colorado Front Range, cuts the northeastern corner of the quadrangle. The oldest rocks in the quadrangle underlie the Tenmile Range and include biotite-sillimanite schist and gneiss, amphibolite, and migmatite that are intruded by granite inferred to be part of the 1,667-1,750 Ma Routt Plutonic Suite (Tweto, Ogden, 1987, Rock units of the Precambrian- basement in Colorado: U.S. Geological Survey Professional Paper 1321-A, 54 p.). The oldest sedimentary unit is the Pennsylvanian Maroon Formation, a sequence of red sandstone, conglomerate, and interbedded shale. The thickest sequence of sedimentary rocks is Cretaceous in age and includes at least 500 m of the Upper Cretaceous Pierre Shale. The sedimentary rocks are intruded by sills and dikes of dacite porphyry sills of Swan Mountain, dated at 44 Ma (Marvin, R.F., Mehnert, H.H., Naeser, C.W., and Zartman, R.E., 1989, U.S. Geological Survey radiometric ages, compilation ?C??Part five?Colorado, Montana, Utah, and Wyoming: Isochron/West, no. 53, p. 14-19. Simmons, E.C., and Hedge, C.E., 1978, Minor-element and Sr-isotope geochemistry of Tertiary stocks, Colorado mineral belt: Contributions to Mineralogy and Petrology, v. 67, p. 379-396.). Surficial deposits include (1) an old, deeply dissected landslide deposit, possibly as old as Tertiary, on the south flank of Tenderfoot Mountain, (2) deeply weathered, very coarse gravel deposits, mostly along Gold Run and underlying Mesa Cortina; the gravels are gold bearing and were mined by hydraulic methods in the 1800's, (3) glacial deposits of both Bull Lake (middle Pleistocene) and Pinedale (late Pleistocene) that were derived from large valley glaciers that flowed down Tenmile and North Tenmile Creeks; the town of Frisco is underlain mostly by Pinedale-age glacial outwash, (4) recent landslide deposits, including one large (about 1 square kilometer) area just downslope from Lilly Pad Lake, west of I-70, and (5)extensive colluvial and alluvial deposits. The latest seismic events appear to be middle Pliestocene in age and are associated with small scarps that cut Bull Lake till but do not cut Pinedale till.

Miscellaneous Field Studies Map↗

USGS1996

Petrology and U-PB geochronology of the Robertson River Igneous Suite, Blue Ridge province, Virginia - Evidence for multistage magmatism associated witn an early episode of Laurentian rifting

The Late Neoproterozoic (735-702 Ma) Robertson River Igneous Suite includes at least eight plutons ranging in composition from syenogranite to alkali feldspar granite to alkali feldspar syenite. These plutons intruded Mesoproterozoic (1.2-1.0 Ga) gneissic basement of the Blue Ridge anticlinorium in northern and central Virginia during an early episode of Laurentian rifting. Robertson River plutons range in composition from metaluminous to peralkaline and, relative to other granite types, exhibit compositional characteristics of A-type granitoids including (1) marked enrichment in Nb, Zr, Y, REE (except Eu), and Ga, (2) high Ga/Al and FeO (total) /MgO, and (3) depletion of Ba and Sr. High Ga/Al ratios are particularly diagnostic of the suite and serve as an effective discriminant between originally metaluminous and peralkaline bulk compositions, providing a useful proxy for widely used indicators based on major elements that are prone to remobilization. U-Pb isotopic analyses of zircons indicate that the suite was emplaced in two pulses, occurring at 735 to 722 and 706 to 702 Ma. Metaluminous magmas were emplaced during both pulses, formed most of the main batholith, and fractionated as independent, time-correlative groups. Peralkaline magmas were emplaced only during the final pulse, formed a volcanic center that erupted unknown quantities of rhyolite, and experienced a style of fractionation similar to the metaluminous types. Differences in Ce/Nb, Y/Nb, and Yb/Ta ratios suggest that the metaluminous and peralkaline magmas were derived from different sources. The Robertson River Igneous Suite is part of a regional group of Late Neoproterozoic (760-700 Ma) plutons including at least 20 other A-type granitoid bodies exposed throughout the Laurentian terrane of Virginia and northwestern North Carolina. Like the Robertson River, most of the other granitoids are metaluminous in composition, typically form multi-intrusive, elongate plutons, and are not geographically constrained to the vicinity of major Neoproterozoic volcanic centers. The Late Neoproterozoic plutons of the Laurentian Appalachians are similar in lithology, composition, and style of emplacement to Miocene granitoids that occur on the southern flanks of the present Red Sea rift and that are considered a younger analog of the Appalachian plutons. However, the Red Sea granitoids were emplaced within a few million years of the initial development of oceanic crust whereas the Appalachian plutons appear largely to have pre-dated development of the Iapetus Ocean by about 130 my.

Virginia↗

USGS2007

A three-dimensional geophysical model of the crust in the Barents Sea region: Model construction and basement characterization

BARENTS50, a new 3-D geophysical model of the crust in the Barents Sea Region has been developed by the University of Oslo, NORSAR and the U.S. Geological Survey. The target region comprises northern Norway and Finland, parts of the Kola Peninsula and the East European lowlands. Novaya Zemlya, the Kara Sea and Franz-Josef Land terminate the region to the east, while the Norwegian-Greenland Sea marks the western boundary. In total, 680 1-D seismic velocity profiles were compiled, mostly by sampling 2-D seismic velocity transects, from seismic refraction profiles. Seismic reflection data in the western Barents Sea were further used for density modelling and subsequent density-to-velocity conversion. Velocities from these profiles were binned into two sedimentary and three crystalline crustal layers. The first step of the compilation comprised the layer-wise interpolation of the velocities and thicknesses. Within the different geological provinces of the study region, linear relationships between the thickness of the sedimentary rocks and the thickness of the remaining crystalline crust are observed. We therefore, used the separately compiled (area-wide) sediment thickness data to adjust the total crystalline crustal thickness according to the total sedimentary thickness where no constraints from 1-D velocity profiles existed. The BARENTS50 model is based on an equidistant hexagonal grid with a node spacing of 50 km. The P -wave velocity model was used for gravity modelling to obtain 3-D density structure. A better fit to the observed gravity was achieved using a grid search algorithm which focussed on the density contrast of the sediment-basement interface. An improvement compared to older geophysical models is the high resolution of 50 km. Velocity transects through the 3-D model illustrate geological features of the European Arctic. The possible petrology of the crystalline basement in western and eastern Barents Sea is discussed on the basis of the observed seismic velocity structure. The BARENTS50 model is available at http://www.norsar.no/seismology/barents3d/ .

Geophysical Journal International↗

USGS1977

The origin of garnet in the anorthosite-charnockite suite of the Adirondacks

Detailed analysis of textural and chemical criteria in rocks of the anorthosite-charnockite suite of the Adirondack Highlands suggests that development of garnet in silica-saturated rocks of the suite occurs according to the reaction: {Mathematical expression}, where ?? is a function of the distribution of Fe and Mg between the several coexisting ferromagnesian phases. Depending upon the relative amounts of Fe and Mg present, quartz may be either a reactant or a product. Using an aluminum-fixed reference frame, this reaction can be restated in terms of a set of balanced partial reactions describing the processes occurring in spatially separated domains within the rock. The fact that garnet invariably replaces plagioclase as opposed to the other reactant phases indicates that the aluminum-fixed model is valid as a first approximation. This reaction is univariant and produces unzoned garnet. It differs from a similar equation proposed by de Waard (1965) for the origin of garnet in Adirondack metabasic rocks, i.e. 6 Orthopyroxene+2 Anorthite = Clinopyroxene+Garnet+2 Quartz, the principle difference being that iron oxides (ilmenite and/or magnetite) are essential reactant phases in the present reactions. The product assemblage (garnet+clinopyroxene+plagioclase ?? orthopyroxene ?? quartz) is characteristic of the clinopyroxene-almandine subfacies of the granulite facies. ?? 1977 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

USGS2000

Magma mixing, recharge and eruption histories recorded in plagioclase phenocrysts from El Chichón Volcano, Mexico

Consistent core-to-rim decreases of 87 Sr/ 86 Sr ratios and coincident increases in Sr concentrations in plagioclase phenocrysts of varying size (∼1 cm to 2 mm) are reported from samples of the 1982 and pre-1982 (∼200 ka) eruptions of El Chichón Volcano. Maximum 87 Sr/ 86 Sr ratios of ∼0·7054, significantly higher than the whole-rock isotopic ratios (∼0·7040–0·7045), are found in the cores of plagioclase phenocrysts, and minimum 87 Sr/ 86 Sr ratios of ∼0·7039 are found near some of the rims. Plagioclase phenocrysts commonly display abrupt fluctuations in An content (up to 25 mol %) that correspond to well-developed dissolution surfaces. The isotopic, textural and compositional characteristics suggest that these plagioclase phenocrysts grew in a system that was periodically recharged by higher-temperature magma with a lower 87 Sr/ 86 Sr ratio and a higher Sr concentration. Rim 87 Sr/ 86 Sr ratios in plagioclase phenocrysts of rocks from the 200 ka eruption indicate that, at that time, the magma had already attained the lowest recorded 87 Sr/ 86 Sr value of the system (∼0·7039). In contrast, cores from plagioclase phenocrysts of the 1982 eruption, inferred to have grown in the past few thousand years, have the highest recorded 87 Sr/ 86 Sr ratios of the system. Collectively, the Sr isotopic data (for plagioclase and whole rock), disequilibrium textural features of the phenocrysts, known eruption frequencies, and inferred crystal-residence times of the plagioclases are best interpreted in terms of an intermittent magma chamber model. Similar processes, including crustal contamination, magma mixing, periodic recharge by addition of more mafic magma to induce plagioclase disequilibrium (possibly triggering eruption) and subsequent re-equilibration, apparently were operative throughout the 200 ky history of the El Chichón magma system.

Chiapas↗

USGS1996

Thermal and mass implications of magmatic evolution in the Lassen volcanic region, California, and minimum constraints on basalt influx to the lower crust

We have analyzed the heat and mass demands of a petrologic model of basalt-driven magmatic evolution in which variously fractionated mafic magmas mix with silicic partial melts of the lower crust. We have formulated steady state heat budgets for two volcanically distinct areas in the Lassen region: the large, late Quaternary, intermediate to silicic Lassen volcanic center and the nearby, coeval, less evolved Caribou volcanic field. At Caribou volcanic field, heat provided by cooling and fractional crystallization of 52 km 3 of basalt is more than sufficient to produce 10 km of rhyolitic melt by partial melting of lower crust. Net heat added by basalt intrusion at Caribou volcanic field is equivalent to an increase in lower crustal heat flow of ∼7 mW m −2 , indicating that the field is not a major crustal thermal anomaly. Addition of cumulates from fractionation is offset by removal of erupted partial melts. A minimum basalt influx of 0.3 km 3 (km 2 Ma) −1 is needed to supply Caribou volcanic field. Our methodology does not fully account for an influx of basalt that remains in the crust as derivative intrusives. On the basis of comparison to deep heat flow, the input of basalt could be ∼3 to 7 times the amount we calculate. At Lassen volcanic center, at least 203 km 3 of mantle-derived basalt is needed to produce 141 km 3 of partial melt and drive the volcanic system. Partial melting mobilizes lower crustal material, augmenting the magmatic volume available for eruption at Lassen volcanic center; thus the erupted volume of 215 km 3 exceeds the calculated basalt input of 203 km 3 . The minimum basalt input of 1.6 km 3 (km 2 Ma) −1 is >5 times the minimum influx to the Caribou volcanic field. Basalt influx high enough to sustain considerable partial melting, coupled with locally high extension rate, is a crucial factor in development of Lassen volcanic center; in contrast, Caribou volcanic field has failed to develop into a large silicic center primarily because basalt supply there has been insufficient.

Journal of Geophysical Research B: Solid Earth↗

USGS2010

Global significance of a sub-Moho boundary layer (SMBL) deduced from high-resolution seismic observations

We infer the fine structure of a sub-Moho boundary layer (SMBL) at the top of the lithospheric mantle from high-resolution seismic observations of Peaceful Nuclear Explosions (PNE) on superlong-range profiles in Russia. Densely recorded seismograms permit recognition of previously unknown features of teleseismic propagation of the well known Pn and Sn phases, such as a band of incoherent, scattered, high-frequency seismic energy, developing consistently from station to station, apparent velocities of sub-Moho material, and high-frequency energy to distances of more than 3000 km with a coda band, incoherent at 10 km spacing and yet consistently observed to the end of the profiles. Estimates of the other key elements of the SMBL were obtained by finite difference calculations of wave propagation in elastic 2D models from a systematic grid search through parameter space. The SMBL consists of randomly distributed, mild velocity fluctuations of 2% or schlieren of high aspect ratios (???40) with long horizontal extent (???20 km) and therefore as thin as 0.5 km only; SMBL thickness is 60-100 km. It is suggested that the SMBL is of global significance as the physical base of the platewide observed high-frequency phases Pn and Sn. It is shown that wave propagation in the SMBL waveguide is insensitive to the background velocity distribution on which its schlieren are superimposed. This explains why the Pn and Sn phases traverse geological provinces of various age, heat flow, crustal thickness, and tectonic regimes. Their propagation appears to be independent of age. temperature, pressure, and stress. Dynamic stretching of mantle material during subduction or flow, possibly combined with chemical differentiation have to be considered as scale-forming processes in the upper mantle. However, it is difficult to distinguish with the present sets of Pn/Sn array data whether (and also where) the boundary layer is a frozen-in feature of paleo-processes or whether it is a response to an on-going processes; nevertheless, the derived quantitative estimates of the SMBL properties provide important constraints for any hypothesis on scale-forming processes. Models to be tested by future numerical and field experiments are, for example, repeated subduction-convection stretching of oceanic lithosphere (marble-cake model) and schlieren formation at mid-ocean ridges. It is also proposed that the modeling of the observed blocking of Sn and Pn propagation at active plate margins offers a new tool to study the depth range of tectonics below the crust-mantle boundary. Finally, the deduced schlieren structure of the SMBL closes an important scale gap of three to four orders of magnitude between structural dimensions studied in petrological analysis of mantle samples (xenoliths or outcrop of oceanic lithosphere) and those imaged in classical seismological studies of the lithosphere.

International Geology Review↗

USGS1990

Petrogenetic evolution of the torfajökull volcanic complex, Iceland I. relationship between the magma types

The Torfajökull volcano, Iceland's largest silicic centre, is situated close to the junction of the active, southerly propagating Eastern Rift Zone and the South Eastern Zone, an older crustal segment. This paper provides major, trace, and some Sr isotope data on postglacial (<10000 y) rocks, i.e., tholeiitic magmas of the Eastern Rift Zone and transitional basalts, icelandites, and rhyolites of the Torfajökull centre, and assesses the relationships between the magma types in terms of the development of the Icelandic crust.Tholeiitic magmas from the Eastern Rift Zone are LILE-enriched relative to MORB. They have undergone extensive olivine-plagioclase-clinopyroxene fractionation at low pressures. Compared with the tholeiites, Torfajökull transitional basalts show LILE/HFS enrichment and higher ( 87 Sr/ 86 Sr) 1 ratios. They define several magmatic lineages and have equilibrated over a wide range of pressures. Both basalt types were derived by very small degrees of partial melting of compositionally similar mantle sources, the main difference being that the tholeiites were generated in the spinel Iherzolite, and the transitional basalts in the garnet lherzolite, stability fields, a conclusion previously reached by Meyer et al. (1985). The mantle sources may have contained LILE-enriched streaks.Low-pressure differentiation of Torfajökull transitional basalt produced an iceiandite to sub-alkaline rhyolite sequence by crystal fractionation, the rhyolites representing >90% crystallization of parental basalts. The rhyolites were emplaced as nine separate lava fields, formed during 11 eruptive episodes. The compositional range within each field is limited, and, although similar, the ranges define several magmatic lineages. Continued fractionation of plagioclase-alkali feldspar-clinopyroxene-magnetite-apatite-zircon assemblages generated peralkaline rhyolites in certain post-glacial eruptions. Chemical variations in the deposits from the Hrafntinnusker peralkaline eruption were related predominantly to alkali feldspar fractionation, and the melts were erupted from a zoned magma chamber. All postglacial volcanic rocks at Torfajokull have been mantle derived and thus represent new additions to the Icelandic crust. © 1990 Oxford University Press.

Journal of Petrology↗

USGS2007

Organic petrology of Paleocene Marcelina Formation coals, Paso Diablo mine, western Venezuela: Tectonic controls on coal type

About 7??Mt of high volatile bituminous coal are produced annually from the four coal zones of the Upper Paleocene Marcelina Formation at the Paso Diablo open-pit mine of western Venezuela. As part of an ongoing coal quality study, we have characterized twenty-two coal channel samples from the mine using organic petrology techniques. Samples also were analyzed for proximate-ultimate parameters, forms of sulfur, free swelling index, ash fusion temperatures, and calorific value. Six of the samples represent incremental benches across the 12-13??m thick No. 4 bed, the stratigraphically lowest mined coal, which is also mined at the 10??km distant Mina Norte open-pit. Organic content of the No. 4 bed indicates an upward increase of woody vegetation and/or greater preservation of organic material throughout the life of the original mire(s). An upward increase in telovitrinite and corresponding decrease in detrovitrinite and inertinite illustrate this trend. In contrast, stratigraphically higher coal groups generally exhibit a 'dulling upward' trend. The generally high inertinite content, and low ash yield and sulfur content, suggest that the Paso Diablo coals were deposited in rain-fed raised mires, protected from clastic input and subjected to frequent oxidation and/or moisture stress. However, the two thinnest coal beds (both 0.7??m thick) are each characterized by lower inertinite and higher telovitrinite content relative to the rest of Paso Diablo coal beds, indicative of less well-established raised mire environments prior to drowning. Foreland basin Paleocene coals of western Venezuela, including the Paso Diablo deposit and time-correlative coal deposits of the Ta??chira and Me??rida Andes, are characterized by high inertinite and consistently lower ash and sulfur relative to Eocene and younger coals of the area. We interpret these age-delimited coal quality characteristics to be due to water availability as a function of the tectonic control of subsidence rate. It is postulated that slower subsidence rates dominated during the Paleocene while greater foreland basin subsidence rates during the Eocene-Miocene resulted from the loading of nappe thrust sheets as part of the main construction phases of the Andean orogen. South-southeastward advance and emplacement of the Lara nappes during the oblique transpressive collision of the Caribbean and South American tectonic plates in the Paleocene was further removed from the sites of peat deposition, resulting in slower subsidence rates. Slower subsidence in the Paleocene may have favored the growth of raised mires, generating higher inertinite concentrations through more frequent moisture stress. Consistently low ash yield and sulfur content would be due to the protection from clastic input in raised mires, in addition to the leaching of mineral matter by rainfall and the development of acidic conditions preventing fixation of sulfur. In contrast, peat mires of Eocene-Miocene age encountered rapid subsidence due to the proximity of nappe emplacement, resulting in lower inertinite content, higher and more variable sulfur content, and higher ash yield.

International Journal of Coal Geology↗

USGS2018

Caldera life-cycles of the Yellowstone hotspot track: Death and rebirth of the Heise Caldera

As one of the most geochemically unique drill cores recovered within the Yellowstone–Snake River Plain (YSRP) province, the Sugar City geothermal test well was drilled into intra-caldera rhyolite lavas and tuffs erupted during the middle to late Pliocene and the resurgent basaltic volcanism erupted during the Pleistocene. This sequence parallels the two main stages proposed for YSRP hotspot calderas: i.e. the eruption of several large-volume, ash-flow tuff sheets followed by caldera collapse, then cessation of major rhyolitic activity and gradual subsidence accompanied by filling and eventual burial of the caldera by basalt lava flows. We employ stratigraphic relationships, paleomagnetism, and major, trace element, and Sr–Nd isotope geochemistry to develop models for the origin of the basaltic and rhyolitic magmas within a geographical and temporal context. The basalts are characterized by distinct groupings based on depth and geochemistry and reflect the dominant compositions observed on the surface, e.g. Snake River olivine tholeiite (SROT) and evolved type (e.g. Craters of the Moon). We also observe contaminated basalts that interacted with rhyolite/granite. The basaltic magma formed by shallow partial melting in the plume channel carved into the lithosphere. The older rhyolites preserve the classical characteristics of A-type granites and display major element and trace element concentrations typical for Eastern SRP caldera centres and minimal stratigraphic variation. Multiple lines of evidence document extensive magmatic differentiation and coupled basalt–rhyolite interactions. We find that the most plausible origin for the rhyolites is via partial melting of a hybrid source, comprising Archean crustal components and younger juvenile mafic intrusions. Assimilation of hydrothermally altered material is also required for some eruptive units. The rhyolites did not evolve from residual magma left over from the climactic Kilgore eruption (4·0 Ma), but instead represent discrete magma generation events in the course of a few hundred thousand years between 4·0 to 3·8 Ma. Beginning at approximately 3.3 Ma, basalts were able to erupt through the solidified composite pluton that formed below the caldera. The transition from rhyolite to basalt is tied to the declining flux of basaltic magma as North America moved away from the Yellowstone hotspot core.

Journal of Petrology↗

USGS2012

Sixty thousand years of magmatic volatile history before the caldera-forming eruption of Mount Mazama, Crater Lake, Oregon

The well-documented eruptive history of Mount Mazama, Oregon, provides an excellent opportunity to use pre-eruptive volatile concentrations to study the growth of an explosive silicic magmatic system. Melt inclusions (MI) hosted in pyroxene and plagioclase crystals from eight dacitic–rhyodacitic eruptive deposits (71–7.7 ka) were analyzed to determine variations in volatile-element concentrations and changes in magma storage conditions leading up to and including the climactic eruption of Crater Lake caldera. Temperatures (Fe–Ti oxides) increased through the series of dacites, then decreased, and increased again through the rhyodacites (918–968 to ~950 to 845–895 °C). Oxygen fugacity began at nickel–nickel-oxide buffer (NNO) +0.8 (71 ka), dropped slightly to NNO +0.3, and then climbed to its highest value with the climactic eruption (7.7 ka) at NNO +1.1 log units. In parallel with oxidation state, maximum MI sulfur concentrations were high early in the eruptive sequence (~500 ppm), decreased (to ~200 ppm), and then increased again with the climactic eruption (~500 ppm). Maximum MI sulfur correlates with the Sr content (as a proxy for LREE, Ba, Rb, P 2 O 5 ) of recharge magmas, represented by basaltic andesitic to andesitic enclaves and similar-aged lavas. These results suggest that oxidized Sr-rich recharge magmas dominated early and late in the development of the pre-climactic dacite–rhyodacite system. Dissolved H 2 O concentrations in MI do not, however, correlate with these changes in dominant recharge magma, instead recording vapor solubility relations in the developing shallow magma storage and conduit region. Dissolved H 2 O concentrations form two populations through time: the first at 3–4.6 wt% (with a few extreme values up to 6.1 wt%) and the second at ≤2.4 wt%. CO 2 concentrations measured in a subset of these inclusions reach up to 240 ppm in early-erupted deposits (71 ka) and are below detection in climactic deposits (7.7 ka). Combined H 2 O and CO 2 concentrations and solubility models indicate a dominant storage region at 4–7 km (up to 12 km), with drier inclusions that diffusively re-equilibrated and/or were trapped at shallower depths. Boron and Cl (except in the climactic deposit) largely remained in the melt, suggesting vapor–melt partition coefficients and gas fractions were low. Modeled Li, F, and S vapor–melt partition coefficients are higher than those of B and Cl. The decrease in maximum MI CO 2 concentration following the earliest dacitic eruptions is interpreted to result from a broadening of the shallow storage region to greater than the diameter of subjacent feeders, so that greater proportions of reservoir magma were to the side of CO 2 -bearing vapor bubbles ascending vertically from the locus of recharge magma injection, thereby escaping recarbonation by streaming vapor bubbles. The Mazama melt inclusions provide a picture of a growing magma storage region, where chemical variations in melt and magma occur due to changes in the nature and supply rate of magma recharge, the timing of degassing, and the possible degree of equilibration with gases from below.

Oregon↗

USGS1983

Oxygen and strontium isotopic studies of basaltic lavas from the Snake River plain, Idaho

The Snake Creek-Williams Canyon pluton of the southern Snake Range crops out over an area of about 30 km2, about 60 km southeast of Ely, Nev. This Jurassic intrusion displays large and systematic chemical and mineralogical zonation over a horizontal distance of 5 km. Major-element variations compare closely with Dalyls average andesite-dacite-rhyolite over an SiO2 range of 63 to 76 percent. For various reasons it was originally thought that assimilation played a dominant role in development of the Snake Creek-Williams Canyon pluton. However, based on modeling of more recently obtained trace element and isotopic data, we have concluded that the zonation is the result of in-situ fractional crystallization, with little assimilation at the level of crystallization. This report summarizes data available for each of the mineral species present in the zoned intrusion. Special attention has been paid to trends We present oxygen and strontium isotopic data for olivine tholeiites, evolved (that is, differentiated and (or) contaminated) lavas, rhyolites, and crustal- derived xenoliths from the Snake River Plain. These data show that the olivine tholeiites are fairly uniform in d80 (5.1 to 6.2) and 87Sr/86Sr (0.7056 to 0.7076) and reveal no correlation between these ratios. The tholeiites are considered representative of mantle-derived magmas that have not interacted significantly with crustal material or meteoric water. The evolved lavas display a wider range in d 80 (5.6 to 7.6) and 87Sr/86Sr (0.708 to 0.717) with positive correlations between these ratios in some suites but not in others. Crustal xenoliths have high and variable 8?Sr/86Sr (0.715 to 0.830) and d80 values that vary widely (6.7 to 9.2) and are a few permil greater than d80 values of the Snake River basalts. Thus, isotopic data for the evolved lavas are permissive of small degrees of contamination by crustal rocks similar to the most d80-depleted xenoliths. The d80 enrichments in some evolved lavas also are consistent with crystal fractionation processes and do not necessarily require bulk interaction with crustal rocks. Enrichment in d80 but not in 87Sr/86Sr in one suite of evolved lavas suggests that crustal contamination may not be essential to the petrogenesis of those lavas. Other suites of evolved lavas display large variations in 87Sr/86Sr that reflect at least some selective contamination with 87St. Bulk solid/liquid oxygen-isotope fractionation factors (a's) calculated for the evolved lavas from Craters of the Moon National Monument are comparatively large. These a's are dependent upon the nature and proportions of phases removed by crystal fractionation; basaltic lava a's differ from latitic lava a?s in accordance with different phenocryst assemblages in these rocks. Snake River Plain rhyolites are isotopically distinct from both the analyzed crustal xenoliths and olivine tholeiites. Their origin remains poorly understood, but crustal or sub-crustal sources may be viable. In the first case, they must be derived by anatexis of material distinct from the analyzed crustal xenoliths. In the second case, they must be derived from material unlike the source for tholeiites. No cogenetic relation with the tholeiites seems likely on the basis of available data. that might relate to the variation in the chemical petrology of the pluton.

Open-File Report↗

USGS1962

Lower temperature terminations of the three-phase region plagioclase-alkali feldspar-liquid

Geological and experimental evidence indicate that the three-phase field, plagioclase-alkalifeldspar-liquid, may terminate in several different ways. The possible terminations have been developed from Schreinemakers' rules governing the disappearance of three-phase fields. In igncous rocks, these different terminations may arise from variations in the relative amounts of additional components in magmas, or from changes of total pressure, or from structural changes that effect the extent of solid solution in feldspar.The three-phase region originates from the intersection of the solidus and the feldspar solvus. The available evidence regarding this intersection is reviewed, as is the evidence for the existence and form of the boundary curve on the feldspar liquidus. The data are used to project a series of isobaric polythermal and isobaric isothermal diagrams for each possible termination . Subsequent discussions relate the theoretical arguments to the natural evidence, suggest the more probable geological environments of some of the terminations , and indicate characteristic features of each termination .It may be possible to identify the type of termination involved in the crystallization of some rocks. The necessary data are the amounts and compositions of both kinds of coexisting feldspars and of the feldspar components of the coexisting liquid at one or more stages of the crystallization process. Volcanic rocks are most suitable for such studies.The terminations explain many of the compositional relationships possible between feldspar crystals and silicate melt under geological and experimental conditions. These compositional relationships are fundamental to understanding the crystallization of igneous rocks and the formation of melts by partial fusion. Other geological applications include a simple explanation for some resorbed feldspars, the separation, correlation, and comparison of porphyritic rock units, interpretation of compositional changes of successive zones of zoned feldspars, and mantling of one feldspar by another. With all types of termination , extensive fractionation yields a liquid rich in Or and Ab that may crystallize to alkali feldspar or feldspars.

Journal of Petrology↗

USGS2010

The role of water in generating the calc-alkaline trend: New volatile data for aleutian magmas and a new tholeiitic index

The origin of tholeiitic (TH) versus calc-alkaline (CA) magmatic trends has long been debated. Part of the problem stems from the lack of a quantitative measure for the way in which a magma evolves. Recognizing that the salient feature in many TH–CA discrimination diagrams is enrichment in Fe during magma evolution, we have developed a quantitative index of Fe enrichment, the Tholeiitic Index (THI): THI = Fe 4 ·0 /Fe 8 ·0 , where Fe 4 ·0 is the average FeO* concentration of samples with 4 ± 1 wt % MgO, and Fe 8 ·0 is the average FeO* at 8 ± 1 wt % MgO. Magmas with THI > 1 have enriched in FeO* during differentiation from basalts to andesites and are tholeiitic; magmas with THI < 1 are calc-alkaline. Most subduction zone volcanism is CA, but to varying extents; the THI expresses the continuum of Fe enrichment observed in magmatic suites in all tectonic settings. To test various controls on the development of CA trends, we present new magmatic water measurements in melt inclusions from eight volcanoes from the Aleutian volcanic arc (Augustine, Emmons, Shishaldin, Akutan, Unalaska, Okmok, Seguam, and Korovin). Least degassed H 2 O contents vary from ∼2 wt % (Shishaldin) to >7 wt % (Augustine), spanning the global range in arc mafic magmas. Within the Aleutian data, H 2 O correlates negatively with THI, from strongly calc-alkaline (Augustine, THI = 0·65) to moderately tholeiitic (Shishaldin, THI = 1·16). The relationship between THI and magmatic water is maintained when data are included from additional arc volcanoes, back-arc basins, ocean islands, and mid-ocean ridge basalts (MORBs), supporting a dominant role of magmatic water in generating CA trends. An effective break between TH and CA trends occurs at ∼2 wt % H 2 O. Both pMELTs calculations and laboratory experiments demonstrate that the observed co-variation of H 2 O and THI in arcs can be generated by the effect of H 2 O on the suppression of plagioclase and the relative enhancement of Fe-oxides on the liquid line of descent. The full THI–H 2 O array requires an increase in fO 2 with H 2 O, from ≤FMQ (where FMQ is the fayalite–magnetite–quartz buffer) in MORB to ∼ΔFMQ +0·5 to +2 in arcs, consistent with inferences from measured Fe and S species in glasses and melt inclusions. A curve fit to the data, H 2 O (wt % ± 1·2) = exp[(1·26 – THI)/0·32], may provide a useful tool for estimating the H 2 O content of magmas that are inaccessible to melt inclusion study.

Journal of Petrology↗

USGS2005

Contrasting Proterozoic basement complexes near the truncated margin of Laurentia, northwestern Sonora–Arizona international border region

We utilize new geological mapping, conventional isotope dilution–thermal ionization mass spectrometry (ID-TIMS) and sensitive high-resolution ion microprobe (SHRIMP) U-Pb zircon analyses, and whole-rock radiogenic isotope characteristics to distinguish two contrasting Proterozoic basement complexes in the international border region southeast of Yuma, Arizona. Strategically located near the truncated southwest margin of Laurentia, these Proterozoic exposures are separated by a northwest-striking Late Cretaceous batholith. Although both complexes contain strongly deformed Paleoproterozoic granitoids (augen gneisses) intruded into fine-grained host rocks, our work demonstrates marked differences in age, host rock composition, and structure between the two areas. The Western Complex reveals a >5-km-thick tilted section of finely banded felsic, intermediate, and mafic orthogneiss interspersed with tabular intrusive bodies of medium-grained leucocratic biotite granite (1696 ± 11 Ma; deepest level), medium-grained hornblende-biotite granodiorite (1722 ± 12 Ma), and coarse-grained porphyritic biotite granite (1725 ± 19 Ma; shallowest level). Penetrative ductile deformation has converted the granites to augen gneisses and caused isoclinal folding and transposition of primary contacts. Exposed in a belt of northwest-trending folds, these rocks preserve southwest-vergent shear fabric annealed during amphibolite facies metamorphism, when crystalloblastic textures developed. Deformation and regional metamorphism occurred before emplacement of 1.1 Ga(?) mafic dikes. Throughout the Eastern Complex, meta-arkose, quartzite, biotite schist, and possible felsic metavolcanic rocks comprise the country rocks of strongly foliated medium- and coarse-grained biotite granite augen gneisses that yield mean 207 Pb/ 206 Pb ages of 1646 ± 10 Ma, 1642 ± 19 Ma, and 1639 ± 15 Ma. Detrital zircons from four samples of host sandstone are isotopically disturbed; nevertheless, the data indicate a restricted provenance (ca. 1665 Ma to 1650 Ma), with two older grains (1697 and 1681 Ma). The pervasively recrystallized Paleoproterozoic map units strike parallel to foliation and are repeated in south-trending folds that are locally refolded about easterly hinges. Southeasterly lineation developed in augen gneiss and host strata becomes penetrative in local domains of L-tectonite. Regional metamorphism associated with this tectonism persisted until ca. 1590 Ma, as recorded by metamorphic growths within some zircon grains. Mesoproterozoic intrusions that crosscut the Paleoproterozoic metasediments and augen gneisses include coarsely porphyritic biotite granite (1432 ± 6 Ma) and diabase dikes (1.1 Ga?). Emplacement of the granite was accompanied by secondary high-U overgrowths, dated at 1433 ± 8 Ma, on some of the Paleoproterozoic detrital zircons, and apparently was also responsible for resetting the whole-rock Pb isotopic systematics (1441 ± 39 Ma) within these Eastern Complex augen gneisses. Younger plutons emplaced into both Proterozoic basement complexes include medium-grained quartz diorite (73.4 ± 3.3 Ma and 72.8 ± 1.7 Ma), Late Cretaceous hornblende-biotite granodiorite, and Paleogene leucocratic biotite granite. Neogene sedimentary and volcanic strata overlie basement along unconformities that are tilted to the northeast, southeast, or southwest. A brittle normal fault, dipping gently northeast, juxtaposes Tertiary andesite with Paleoproterozoic metasandstone. These relationships suggest that the area shares a common history of mid-Tertiary extension with southwestern Arizona. Later influence of the southern San Andreas fault system is implied by multiple dextral offsets of pre-Tertiary units across northwest-trending valleys. Our structural, geochronologic, and isotopic data provide new information to constrain pre–750 Ma Rodinia reconstructions involving southwestern Laurentia. Whole-rock U-Th-Pb and Rb-Sr isotopic systematics in both Paleoproterozoic gneiss complexes are disturbed, however, well-behaved Sm-Nd analyses preserve depleted initial ε Nd values (+2 to +4) that are distinct from the Mojave crustal province, but overlapping with the Yavapai and Mazatzal Provinces of Arizona. The Eastern Complex has the appropriate age and Nd isotopic signature to be part of the Mazatzal Province, but records major tectonism and metamorphism at ca. 1.6 Ga that postdates the Mazatzal orogeny. Deformed granitoids of the Western Complex have “Yavapai-type” ages and ε Nd but display structures discordant to the southwesterly Yavapai trend in central Arizona. The Western Complex lies along-strike with similar-age rocks (1.77 Ga to 1.69 Ga) of the “Caborca block” that have only been studied in detail near Quitovac and south of Caborca. Collectively, these rocks form a northwest-trending strip of basement situated at the truncated edge of Laurentia. The present-day basement geography may reflect an original oroclinal bend in the Yavapai orogenic belt. Alternatively, the western Proterozoic belt of Sonora may represent displaced fragments of basement juxtaposed against the Yavapai-Mazatzal Provinces along a younger sinistral transform fault (e.g., the Late Jurassic Mojave-Sonora megashear or the Permian Coahuila transform). Crustal blocks with these specific petrologic, geochronologic, and isotopic characteristics can be found in south-central and northeastern portions of the Australian Proterozoic basement, further supporting a connection between the two continents prior to breakup of the Rodinian supercontinent.

Arizona, California, Nevada, Sonora↗

USGS2004

Magma generation at a large, hyperactive silicic volcano (Taupo, New Zealand) revealed by U-Th and U-Pb systematics in zircons

Young (<∼65 ka) explosive silicic volcanism at Taupo volcano, New Zealand, has involved the development and evacuation of several crustal magmatic systems. Up to and including the 26·5 ka 530 km 3 Oruanui eruption, magmatic systems were contemporaneous but geographically separated. Subsequently they have been separated in time and have vented from geographically overlapping areas. Single-crystal (secondary ionization mass spectrometry) and multiple-crystal (thermal ionization mass spectrometry) zircon model-age data are presented from nine representative eruption deposits from ∼45 to ∼3·5 ka. Zircon yields vary by three orders of magnitude, correlating with the degrees of zircon saturation in the magmas, and influencing the spectra of model ages. Two adjacent magma systems active up to 26·5 ka show wholly contrasting model-age spectra. The smaller system shows a simple unimodal distribution. The larger system, using data from three eruptions, shows bimodal model-age spectra. An older ∼100 ka peak is interpreted to represent zircons (antecrysts) derived from older silicic mush or plutonic rocks, and a younger peak to represent zircons (phenocrysts) that grew in the magma body immediately prior to eruption. Post-26·5 ka magma batches show contrasting age spectra, consistent with a mixture of antecrysts, phenocrysts and, in two examples, xenocrysts from Quaternary plutonic and Mesozoic–Palaeozoic metasedimentary rocks. The model-age spectra, coupled with zircon-dissolution modelling, highlight contrasts between short-term silicic magma generation at Taupo, by bulk remobilization of crystal mush and assimilation of metasediment and/or silicic plutonic basement rocks, and the longer-term processes of fractionation from crustally contaminated mafic melts. Contrasts between adjacent or successive magma systems are attributed to differences in positions of the source and root zones within contrasting domains in the quartzo-feldspathic (<15 km deep) crust below the volcano.

Taupo volcano↗