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USGS2003

Multiple oxygen and sulfur isotopic analyses on water-soluble sulfate in bulk atmospheric deposition from the southwestern United States

Sulfate is a major component of bulk atmospheric deposition (including dust, aerosol, fog, and rain). We analyzed sulfur and oxygen isotopic compositions of water-soluble sulfate from 40 sites where year-round dust traps collect bulk atmospheric deposition in the southwestern United States. Average sulfur and oxygen isotopic compositions (δ 34 S and δ 18 O) are 5.8 ± 1.4 (CDT) and 11.2 ± 1.9 (SMOW) (n = 47), respectively. Samples have an oxygen 17 anomaly (Δ 17 O), with an average value of 1.0 ± 0.6‰. Except for a weak positive correlation between δ 18 O and Δ 17 O values (r 2 ≈ 0.4), no correlation exists for δ 18 O versus δ 34 S, Δ 17 O versus δ 34 S, or any of the three isotopic compositions versus elevation of the sample site. Exceptional positive Δ 17 O values (up to 4.23‰) are found in samples from sites in the vicinity of large cities or major highways, and near-zero Δ 17 O values are found in samples close to dry lakes. Comparison of isotopic values of dust trap sulfate and desert varnish sulfate from the region reveals that varnish sulfate has average isotopic values that are ∼4.8‰ lower for δ 18 O, ∼2.1‰ higher for δ 34 S, and ∼0.3‰ lower for Δ 17 O than those of the present-day bulk deposition sulfate. Although other factors could cause the disparity, this observation suggests a possibility that varnish sulfate may have recorded a long-term atmospheric sulfate deposition during the Holocene or Pleistocene, as well as the differences between sulfur and oxygen isotopic compositions of the preindustrial bulk deposition sulfate and those of the industrial era.

Journal of Geophysical Research D: Atmospheres↗

USGS2006

Atmospheric mercury emissions from substrates and fumaroles associated with three hydrothermal systems in the western United States

This paper quantifies atmospheric mercury (Hg) emissions from substrates and fumaroles associated with three hydrothermal systems: Lassen Volcanic Center, California (LVC); Yellowstone Caldera, Wyoming (YC); and Dixie Valley, Nevada (DV). Substrate Hg fluxes were measured using field chamber methods at thermal and nonthermal sites. The highest Hg fluxes (up to 541 ng m −2 h −1 ) were measured at thermal active areas. Fluxes from altered and unaltered nonthermal sites were <10 ng m −2 h −1 and were comparable to those measured in natural low-Hg background regions for YC and DV, and at LVC they were slightly elevated. Similarly, reactive gaseous mercury concentrations were higher in thermal active areas. Using a Geographic Information System framework for scaling, estimated area-average Hg emissions from substrates were 0.9–3.8 ng m −2 h −1 at LVC, 0.8–2.8 ng m −2 h −1 at YC, and 0.4–0.5 ng m −2 h −1 at DV. At LVC, nonthermal areas were the primary substrate source of atmospheric Hg (>98%). At YC, substrate Hg emissions were dominated (50 to 90%) by acidically altered thermal areas. Substrate emissions at DV were low and primarily from nonthermal areas (66% to 75%). Fumarole emissions at LVC (91–146 kg yr −1 ) and YC (0.18–1.6 kg yr −1 for Mud Volcano) were estimated by applying Hg:H 2 O and Hg:CO 2 ratios in hydrothermal gas samples to H 2 O and CO 2 emissions. Applying total area-average emissions from substrates and thermal features at LVC, YC, and DV to similar systems across the conterminous United States, yearly atmospheric Hg emissions from active hydrothermal systems are projected to be 1.3–2.1 Mg.

Journal of Geophysical Research D: Atmospheres↗

USGS2024

Microplastic and associated black particles from road-tire wear: Implications for radiative effects across the cryosphere and in the atmosphere

The environmental effects of airborne micro- and nano-size plastic particles are poorly understood. Microscopy and chemical analyses of atmospherically deposited particles on snow surfaces at high elevation (2,865–3,690 m) in the Upper Colorado River basin (UCRB; Colorado Rocky Mountains) revealed the presence of black substances intimately associated with microplastic fibers, particles interpreted to have originated as tire matter. Identical and similar particles occur in shredded tires and road-surface samples. The substance responsible for the black color of all tires is carbon black, a graphitic light-absorbing tire additive produced by hydrocarbon combustion that homogeneously permeates the mixture of tire polymers and other additives. Such black tire matter may thus exert radiative effects closely similar to those of black carbon. The presence in snow of many organic compound types common to tires, measured by two-dimensional gas chromatography, suggests that atmospherically deposited black road-tire-wear matter is among the light-absorbing particulates that advance the onset and rate of snow melt in the UCRB. The mass of road-tire-wear particles shed from vehicles may be estimated by multiplying measured amounts of eroded tire-per-distance traveled by vehicular distances. Under a combination of measurements and assumptions about the amounts and radiative properties of atmospheric tire-wear particles, the radiative effects of these particles might add about 10%–30% to those effects from black carbon, an estimate ripe for revision. On regional and global scales, the amounts and effects of emitted and deposited tire-wear matter likely vary by factors of geographic source, transport pathway, and depositional setting.

JGR - Atmospheres↗

USGS2003

Arctic transitions in the Land - Atmosphere System (ATLAS): Background, objectives, results, and future directions

This paper briefly reviews the background, objectives, and results of the Arctic Transitions in the Land-Atmosphere System (ATLAS) Project to date and provides thoughts on future directions. The key goal of the ATLAS Project is to improve understanding of controls over spatial and temporal variability of terrestrial processes in the Arctic that have potential consequences for the climate system, i.e., processes that affect the exchange of water and energy with the atmosphere, the exchange of radiatively active gases with the atmosphere, and the delivery of freshwater to the Arctic Ocean. Three important conclusions have emerged from research associated with the ATLAS Project. First, associated with the observation that the Alaskan Arctic has warmed significantly in the last 30 years, permafrost is warming, shrubs are expanding, and there has been a temporary release of carbon dioxide from tundra soils. Second, the winter is a more important period of biological activity than previously appreciated. Biotic processes, including shrub expansion and decomposition, affect snow structure and accumulation and affect the annual carbon budget of tundra ecosystems. Third, observed vegetation changes can have a significant positive feedback to regional warming. These vegetation effects are, however, less strong than those exerted by land-ocean heating contrasts and the topographic constraints on air mass movements. The papers of this special section provide additional insights related to these conclusions and to the overall goal of ATLAS.

Journal of Geophysical Research D: Atmospheres↗

USGS2007

Relations between winter precipitation and atmospheric circulation simulated by the Geophysical Fluid Dynamics Laboratory general circulation model

General circulation model (GCM) simulations of atmospheric circulation are more reliable than GCM simulations of temperature and precipitation. In this study, temporal correlations between 700 hPa height anomalies simulated winter precipitation at eight locations in the conterminous United States are compared with corresponding correlations in observations. The objectives are to 1) characterize the relations between atmospheric circulation and winter precipitation simulated by the GFDL, GCM for selected locations in the conterminous USA, ii) determine whether these relations are similar to those found in observations of the actual climate system, and iii) determine if GFDL-simulated precipitation is forced by the same circulation patterns as in the real atmosphere. -from Authors

International Journal of Climatology↗

USGS2020

Evaluation of a roughness length parametrization accounting for wind–wave alignment in a coupled atmosphere–wave model

The importance of wind energy as an alternative energy source has increased over the latest years with more focus on offshore winds. A good estimation of the offshore winds is thus of major importance for this industry. Up to now the effect of the wind–wave (mis)alignment has not yet been taken into account in coupled atmosphere–wave models to study the vertical wind profile and power production estimations of offshore wind farms. In this study the roughness length parametrization of Drennan et al . in 2003, and its extension addressing the wind–wave (mis)alignment proposed by Porchetta et al . in 2019, are investigated in the Coupled Ocean–Atmosphere–Wave–Sediment Transport (COAWST) model. This study shows that the yearly mean wind estimation at hub height (100 m) is improved by the roughness length parametrization of Porchetta et al . compared to Drennan. This is mainly due to the increased roughness of the former parametrization compare to the latter, even in aligned wind–wave conditions. This difference in roughness is caused by the dataset used to obtain the constants, deep‐water conditions versus mixed offshore conditions. Moreover, the roughness length parametrization of Porchetta et al . performs better in two of three alignment categories. Furthermore, similar model performances are obtained if we exclude the wind directions from the wind shadow zone of the measurement mast or the wind directions from the recently built Alpha Ventus wind farm, which is in close vicinity of the measurement mast. Investigating different wind conditions shows that the new roughness length parametrization of Porchetta et al . performs best for both offshore and onshore winds. Additionally, we show that the coupled model estimations of the vertical wind are only slightly affected by significant wave height estimations. Similar model performances for different accuracies of significant wave height estimations are presented. One exception is the perpendicular alignment category where the new roughness length of Porchetta et al . outperforms the roughness length of Drennan when investigating the wind estimations related to significant wave heights with a higher accuracy. The roughness length parametrization of Porchetta et al . reduced the power production overestimation of the coupled model from 5.7 to 2.8%. We also show that the standalone atmospheric model including the roughness length of Charnock in 1955 has a degraded performance compared to the coupled model including the roughness length parametrization of Porchetta et al . for yearly average wind profiles.

Quarterly Journal of the Royal Meteorological Soci↗

USGS1991

Atmospheric deposition and solute export in giant sequoia: Mixed conifer watersheds in the Sierra Nevada, California

Atmospheric depostion and stream discharge and solutes were measured for three years (September 1984 — August 1987) in two mixed conifer watersheds in Sequoia National Park, in the southern Sierra Nevada of California. The Log Creek watershed (50 ha, 2067–2397 m elev.) is drained by a perennial stream, while Tharp's Creek watershed (13 ha, 2067–2255 m elev.) contains an intermittent stream. Dominant trees in the area include Abies concolor (white fir), Sequoiadendron giganteum (giant sequoia), A. magnifica (red fir), and Pinus lambertiana (sugar pine). Bedrock is predominantly granite and granodiorite, and the soils are mostly Pachic Xerumbrepts. Over the three year period, sulfate (SO 4 2− ), nitrate (NO 3 − ), and chloride (Cl −1 ) were the major anions in bulk precipitation with volume-weighted average concentrations of 12.6, 12.3 and 10.0 μeq/1, respectively. Annual inputs of NO 3 -N, NH 4 -N and SO 4 -S from wet deposition were about 60 to 75% of those reported from bulk deposition collectors. Discharge from the two watersheds occurs primarily during spring snowmelt. Solute exports from Log and Tharp's Creeks were dominated by HCO 3 − , Ca 2+ and Na + , while H + , NO 3 − , NH 4 + and PO 4 3− outputs were relatively small. Solute concentrations were weakly correlated with instantaneous stream flow for all solutes (r 2 <0.2) except HCO 3 − (Log Cr. r 2 = 0.72; Tharp's Cr. r 2 = 0.38), Na + (Log Cr. r 2 = 0.56; Tharp's Cr. r 2 = 0.47), and silicate (Log Cr. r 2 = 0.71; Tharp's Cr. r 2 = 0.49). Mean annual atmospheric contributions of NO 3 -N (1.6 kg ha −1 ), NH 4 -N (1.7 kg ha −1 ), and SO 4 -S (1.8 kg ha −1 ), which are associated with acidic deposition, greatly exceed hydrologic losses. Annual watershed yields (expressed as eq ha −1 ) of HCO 3 − exceeded by factors of 2.5 to 37 the annual atmospheric deposition of H + .

California↗

USGS1989

Recent increases in atmospheric deposition of mercury to North-Central Wisconsin lakes inferred from sediment analyses

Profiles of total mercury (Hg) concentrations in sediments were examined in 11 lakes in north-central Wisconsin having a broad range of pH (5.1 to 7.8) and alkalinity (-12 to 769 μeq/L). Mercury concentrations were greatest in the top 15 cm of the cores and were much lower in the deeper strata. The Hg content in the most enriched stratum of individual cores ranged from 0.09 to 0.24 μg/g dry weight, whereas concentrations in deep, precolonial strata ranged from 0.04 to 0.07 μg/g. Sediment enrichment factors varied from 0.8 to 2.8 and were not correlated with lake pH. The increase in the Hg content of recent sediments was attributed to increased atmospheric deposition of the metal. Eight of the 11 systems studied were low-alkalinity lakes that presumably received most (≥90%) of their hydrologic input from precipitation falling directly onto the lake surface. Thus, the sedimentary Hg in these lakes seems more likely linked to direct atmospheric deposition onto the lake surfaces than to influxes from the watershed. The data imply that a potentially significant fraction of the high Hg burdens measured in game fish in certain lakes in north-central Wisconsin originated from atmospheric sources.

Wisconsin↗

USGS2002

Annual emissions of mercury to the atmosphere from natural sources in Nevada and California

The impact of natural source emissions on atmospheric mercury concentrations and the biogeochemical cycle of mercury is not known. To begin to assess this impact, mercury emissions to the atmosphere were scaled up for three areas naturally enriched in mercury: the Steamboat Springs geothermal area, Nevada, the New Idria mercury mining district, California, and the Medicine Lake volcano, California. Data used to scale up area emissions included mercury fluxes, measured in-situ using field flux chambers, from undisturbed and disturbed geologic substrates, and relationships between mercury emissions and geologic rock types, soil mercury concentrations, and surface heat flux. At select locations mercury fluxes were measured for 24 h and the data were used to adjust fluxes measured at different times of the day to give an average daily flux. This adjustment minimized daily temporal variability, which is observed for mercury flux because of light and temperature effects. Area emissions were scaled spatially and temporally with GIS software. Measured fluxes ranged from 0.3 to approximately 50 ng m-2 h-1 at undisturbed sites devoid of mercury mineralization, and to greater than 10,000 ng m-2 h-1 from substrates that were in areas of mercury mining. Area-averaged fluxes calculated for bare soil at Steamboat Springs, New Idria, and Medicine Lake of 181, 9.2, and 2 ng m-2 h-1, respectively, are greater than fluxes previously ascribed to natural non-point sources, indicating that these sources may be more significant contributors of mercury to the atmosphere than previously realized.

Environmental Geology↗

USGS2016

Climate-change signals in national atmospheric deposition program precipitation data

National Atmospheric Deposition Program (NADP)/National Trends Network precipitation type, snow-season duration, and annual timing of selected chemical wet-deposition maxima vary with latitude and longitude within a 35-year (1979–2013) data record for the contiguous United States and Alaska. From the NADP data collected within the region bounded by 35.6645°–48.782° north latitude and 124°–68° west longitude, similarities in latitudinal and longitudinal patterns of changing snow-season duration, fraction of annual precipitation recorded as snow, and the timing of chemical wet-deposition maxima, suggest that the chemical climate of the atmosphere is linked to physical changes in climate. Total annual precipitation depth has increased 4–6 % while snow season duration has decreased from approximately 7 to 21 days across most of the USA, except in higher elevation regions where it has increased by as much as 21 days. Snow-season precipitation is increasingly comprised of snow, but annually total precipitation is increasingly comprised of liquid precipitation. Meanwhile, maximum ammonium deposition occurs as much as 27 days earlier, and the maximum nitrate: sulfate concentration ratio in wet-deposition occurs approximately 10–21 days earlier in the year. The maximum crustal (calcium + magnesium + potassium) cation deposition occurs 2–35 days earlier in the year. The data suggest that these shifts in the timing of atmospheric wet deposition are linked to a warming climate, but the ecological consequences are uncertain.

Climate Dynamics↗

USGS1998

Modeled responses of terrestrial ecosystems to elevated atmospheric CO2: A comparison of simulations by the biogeochemistry models of the Vegetation/Ecosystem Modeling and Analysis Project (VEMAP)

Although there is a great deal of information concerning responses to increases in atmospheric CO 2 at the tissue and plant levels, there are substantially fewer studies that have investigated ecosystem-level responses in the context of integrated carbon, water, and nutrient cycles. Because our understanding of ecosystem responses to elevated CO 2 is incomplete, modeling is a tool that can be used to investigate the role of plant and soil interactions in the response of terrestrial ecosystems to elevated CO 2 . In this study, we analyze the responses of net primary production (NPP) to doubled CO 2 from 355 to 710 ppmv among three biogeochemistry models in the Vegetation/Ecosystem Modeling and Analysis Project (VEMAP): BIOME-BGC (BioGeochemical Cycles), Century, and the Terrestrial Ecosystem Model (TEM). For the conterminous United States, doubled atmospheric CO 2 causes NPP to increase by 5% in Century, 8% in TEM, and 11% in BIOME-BGC. Multiple regression analyses between the NPP response to doubled CO 2 and the mean annual temperature and annual precipitation of biomes or grid cells indicate that there are negative relationships between precipitation and the response of NPP to doubled CO 2 for all three models. In contrast, there are different relationships between temperature and the response of NPP to doubled CO 2 for the three models: there is a negative relationship in the responses of BIOME-BGC, no relationship in the responses of Century, and a positive relationship in the responses of TEM. In BIOME-BGC, the NPP response to doubled CO 2 is controlled by the change in transpiration associated with reduced leaf conductance to water vapor. This change affects soil water, then leaf area development and, finally, NPP. In Century, the response of NPP to doubled CO 2 is controlled by changes in decomposition rates associated with increased soil moisture that results from reduced evapotranspiration. This change affects nitrogen availability for plants, which influences NPP. In TEM, the NPP response to doubled CO 2 is controlled by increased carboxylation which is modified by canopy conductance and the degree to which nitrogen constraints cause down-regulation of photosynthesis. The implementation of these different mechanisms has consequences for the spatial pattern of NPP responses, and represents, in part, conceptual uncertainty about controls over NPP responses. Progress in reducing these uncertainties requires research focused at the ecosystem level to understand how interactions between the carbon, nitrogen, and water cycles influence the response of NPP to elevated atmospheric CO 2 .

Oecologia↗

USGS2020

Evolving infrasound detections from Bogoslof volcano, Alaska: Insights from atmospheric propagation modeling

Bogoslof volcano, a back-arc volcano in Alaska’s Aleutian arc, began an eruptive sequence in mid-December 2016 that ended in late August 2017, with 70 individual eruptive episodes. Because there were no local seismic or infrasound stations on the island, the Alaska Volcano Observatory (AVO) relied on distant geophysical networks and remote sensing techniques to assess activity during the eruption. AVO maintains six infrasound arrays to monitor activity along the Aleutian arc: Adak, the Island of Four Mountains, Okmok, Akutan, Sand Point, and Dillingham. Eruption detection at infrasound arrays is subject to local as well as mesoscale meteorological conditions that vary greatly over both short and long timescales. Infrasound detections from the array nearest to Bogoslof (Okmok), with a latency of about 3 min, played a crucial role in monitoring activity during the eruption. Despite the relative proximity of the Okmok array to Bogoslof (60 km), infrasound detections were not uniformly observed with only about two-thirds of the events successfully detected. The farthest array at Dillingham (816 km) detected approximately half of the explosive events, with all other arrays detecting less than half of the events. We compare observations with infrasound propagation model predictions, using both normal mode and parabolic equation forward models, to interpret the variation in detections of the 70 explosive events across the AVO infrasound network. The forward models utilize the newly created, publicly available AVO-G2S atmospheric reconstruction using numerical weather predictions data for the lower atmosphere, coupled with upper atmosphere empirical models of wind speeds and temperature. We find that long-range detections (> 100 km) of Bogoslof events are largely aligned with seasonal variability in favorable propagation conditions, while regional detections (< 100 km) are less consistent with propagation modeling. Understanding the output of numerical models in comparison to past observations will facilitate their use in future operational settings for AVO and other observatories.

Alaska↗

USGS2013

Climate, not atmospheric deposition, drives the biogeochemical mass-balance of a mountain watershed

Watershed mass-balance methods are valuable tools for demonstrating impacts to water quality from atmospheric deposition and chemical weathering. Owen Bricker, a pioneer of the mass-balance method, began applying mass-balance modeling to small watersheds in the late 1960s and dedicated his career to expanding the literature and knowledge of complex watershed processes. We evaluated long-term trends in surface-water chemistry in the Loch Vale watershed, a 660-ha. alpine/subalpine catchment located in Rocky Mountain National Park, CO, USA. Many changes in surface-water chemistry correlated with multiple drivers, including summer or monthly temperature, snow water equivalent, and the runoff-to-precipitation ratio. Atmospheric deposition was not a significant causal agent for surface-water chemistry trends. We observed statistically significant increases in both concentrations and fluxes of weathering products including cations, SiO 2 , SO 4 2− , and ANC, and in inorganic N, with inorganic N being primarily of atmospheric origin. These changes are evident in the individual months June, July, and August, and also in the combined June, July, and August summer season. Increasingly warm summer temperatures are melting what was once permanent ice and this may release elements entrained in the ice, stimulate chemical weathering with enhanced moisture availability, and stimulate microbial nitrification. Weathering rates may also be enhanced by sustained water availability in high snowpack years. Rapid change in the flux of weathering products and inorganic N is the direct and indirect result of a changing climate from warming temperatures and thawing cryosphere.

Loch Vale Watershed, Rock Mountain National Park↗

USGS2010

Response of lake chemistry to changes in atmospheric deposition and climate in three high-elevation wilderness areas of Colorado

Trends in precipitation chemistry and hydrologic and climatic data were examined as drivers of long-term changes in the chemical composition of high-elevation lakes in three wilderness areas in Colorado during 1985–2008. Sulfate concentrations in precipitation decreased at a rate of −0.15 to −0.55 μeq/l/year at 10 high-elevation National Atmospheric Deposition Program stations in the state during 1987–2008 reflecting regional reductions in SO 2 emissions. In lakes where sulfate is primarily derived from atmospheric inputs, sulfate concentrations also decreased although the rates generally were less, ranging from −0.12 to −0.27 μeq/l/year. The similarity in timing and sulfur isotopic data support the hypothesis that decreases in atmospheric deposition are driving the response of high-elevation lakes in some areas of the state. By contrast, in lakes where sulfate is derived primarily from watershed weathering sources, sulfate concentrations showed sharp increases during 1985–2008. Analysis of long-term climate records indicates that annual air temperatures have increased between 0.45 and 0.93°C per decade throughout most mountainous areas of Colorado, suggesting climate as a factor. Isotopic data reveal that sulfate in these lakes is largely derived from pyrite, which may indicate climate warming is preferentially affecting the rate of pyrite weathering.

Colorado↗

USGS2023

Atmospheric mercury and its deposition during the phasing out of an amalgam electrolysis plant: Temporal, seasonal, and spatial patterns

Large amounts of mercury (Hg) were consumed and emitted into the atmosphere during the process of amalgam electrolysis used to produce chlorine and caustic soda since the nineteenth century. In Europe, amalgam electrolysis has been gradually replaced by advanced Hg-free technologies. In this work, we describe changes in atmospheric Hg and bulk Hg wet deposition during the phasing out of an amalgam electrolytic production line of a chlor-alkali plant in Neratovice, Czech Republic, central Europe. Bulk wet deposition Hg near the chlor-alkali plant was low at 3.6 ± 0.8 μg m −2 year −1 due in part to low annual precipitation amounts (486 ± 97 mm) in the period 2015–2021. Nevertheless, Hg deposition was elevated relative to a nearby reference site both before and after decommissioning of the electrolytic line. Switching off the amalgam electrolytic line did not notably affect bulk wet deposition Hg near the chlor-alkali plant. Levels of gaseous elemental Hg (GEM) and particle-bound Hg (PBM) monitored seasonally four times per year over 24-h time periods indicated rapid declines in four nearby settlements set in cardinal directions from the Hg emission source. Mean atmospheric GEM and PBM concentrations decreased rapidly from 9.0 ± 2.1 ng m −3 and 243 ± 255 pg m −3 in the period 2013–2017 when amalgam electrolysis was operating to 3.3 ± 0.4 ng m −3 and 32 ± 6 pg m −3 in the period 2018–2021 after its decommissioning in November 2017. Seasonal changes of GEM coincided with changes in temperature with the highest concentrations in summer, while PBM air levels were lowest in summer due to the highest seasonal precipitation amount. GEM concentrations at the four monitored settlements at Neratovice remained elevated at 2.8 ng m −3 with respect to regional background, but PBM levels decreased to background levels.

Neratovice↗

USGS1982

Phase relations in the system NaCl-KCl-H2O. Part I: Differential thermal analysis of the NaCl-KCl liquidas at 1 atmosphere and 500, 1000, 1500, and 2000 bars

A simple differential thermal analysis (DTA) technique has been developed to study phase relations of various chemical systems at elevated pressures and temperatures. The DTA system has been calibrated against known melting temperatures in the system NaCl-KCl. Isobaric sections of the liquidus in the system NaCl-KCl have been determined at pressures of 1 atmosphere and 500, 1000, 1500, and 2000 bars. Using the least-squares method, the following equation was used to fit the experimental data: T(°C)= ∑ i=0 6 a i X i KCl "> T(°C)=∑i=06a i X i KCl where T is the liquidus temperature, X KCl is mole fraction of KCl, and a i (listed below) are the derived empirical constants. P (bars) a o "> ao a 1 "> a1 a 2 "> a2 a 3 "> a3 a 4 "> a4 a 5 "> a5 a 6 "> a6 1 atm. 800.1 −334.2 781.6 −6490.3 17553.1 −17638.4 6098.3 500 813.5 −354.9 743.3 −6011.7 16406.4 −16516.3 5702.8 1000 824.5 −406.7 1446.8 −8818.4 21253.5 −20343.7 6839.4 1500 838.6 −418.7 1434.7 −8819.0 21557.9 −20908.4 7123.1 2000 848.5 −381.5 1246.9 −8605.0 21785.8 −21449.1 7375.8 The liquidus temperatures estimated from these equations are within ±3°C of experimental values. The measured liquidus temperatures at 1 atmosphere agree with the best available data to within 5°C. The melting temperatures for pure end members at higher pressures agree with the values calculated from the Simon equation (Clark, 1959) to within 3°C. No previous melting data are available for the intermediate compositions at elevated pressures. Using the data in both heating and cooling scans, the minimum melting temperature at 1 atmosphere in the system was located at 658° ± 3° C where the sample has an equimolar composition.

Geochimica et Cosmochimica Acta↗

USGS1967

On the chemistry of Jupiter's upper atmosphere

We conduct a first investigation into the ion-molecule chemistry of the upper Jovian atmosphere. Experimental results show that intense ultraviolet radiation reacts with the constituents of the Jovian atmosphere to produce C 2 H 4 , C 2 H 6 , C 3 H 8 , and higher polymers. The general procedure for calculating both equilibrium and nonequilibrium abundances of these products is formulated and applied to the case of the surface passage of a satellite shadow. A specific example is made of ethylene, for which an analytical approximation gives 10 10 molecules in an atmospheric column of 1 cm 2 cross section after a very rapid rise to equilibrium. Such a concentration of ethylene does not substantially affect the infrared radiation in the shadow.

Icarus↗

USGS1972

The martian atmosphere: Mariner 9 television experiment progress report

Atmospheric phenomena appearing in the Mariner 9 television pictures are discussed in detail. The surface of the planet was heavily obscured by a global dust storm during the first month in orbit. Brightness data during this period can be fitted by a semi-infinite scattering and absorbing atmosphere model with a single-scattering albedo in the range 0.70–0.85. This low value suggests that the mean radius of the particles responsible for the obscuration was at least 10 μm. By the end of the second month, this dust storm had largely dissipated, leaving a residual optical depth ∼0.1. Much of the region north of 45°N was covered by variable clouds comprising the north polar hood. The cloud structures revealed extensive systems of lee waves generated by west-to-east flow over irregular terrain. Extensive cloud systems in this region resembled baroclinic wave cyclones. Clouds were also observed over several of the large calderas; these clouds are believed to contain water ice. Several localized dust storms were seen after the global dust storm cleared. These dust clouds appeared to be intensely convective. The convective nature of these storms and the stirring of large dust particles to great heights can be explained by vertical velocities generated by the absorption of solar radiation by the dusty atmosphere.

Icarus↗