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At least 1,423 records · Page 79Linked to original sources

Postwildfire soil‐hydraulic recovery and the persistence of debris flow hazards

Deadly and destructive debris flows often follow wildfire, but understanding of changes in the hazard potential with time since fire is poor. We develop a simulation‐based framework to quantify changes in the hydrologic triggering conditions for debris flows as postwildfire infiltration properties evolve through time. Our approach produces time‐varying rainfall intensity‐duration thresholds for runoff‐ and infiltration‐generated debris flows with physics‐based hydrologic simulations that are parameterized with widely available hydroclimatic, vegetation reflectance, and soil texture data. When we apply our thresholding protocol to a test case in the San Gabriel Mountains (California, USA), the results are consistent with existing regional empirical thresholds and rainstorms that caused runoff‐ and infiltration‐generated debris flows soon after and three years following a wildfire, respectively. We find that the hydrologic triggering mechanisms for the two observed debris flow types are coupled with the effects of fire on the soil saturated hydraulic conductivity. Specifically, the rainfall intensity needed to generate debris flows via runoff increases with time following wildfire while the rainfall duration needed to produce debris flows via subsurface pore‐water pressures decreases. We also find that variations in soil moisture, rainfall climatology, median grain size, and root reinforcement could impact the median annual probability of postwildfire debris flows. We conclude that a simulation‐based method for calculating rainfall thresholds is a tractable approach to improve situational awareness of debris flow hazard in the years following wildfire. Further development of our framework will be important to quantify postwildfire hazard levels in variable climates, vegetation types, and fire regimes.

Journal of Geophysical Research: Earth Surface↗

An examination of soil crusts on the floor of Jezero crater, Mars

Martian soils are critically important for understanding the history of Mars, past potentially habitable environments, returned samples, and future human exploration. This paper examines soil crusts on the floor of Jezero crater encountered during initial phases of the Mars 2020 mission. Soil surface crusts have been observed on Mars at other locations, starting with the two Viking Lander missions. Rover observations show that soil crusts are also common across the floor of Jezero crater, revealed in 45 of 101 locations where rover wheels disturbed the soil surface, 2 out of 7 helicopter flights that crossed the wheel tracks, and 4 of 8 abrasion/drilling sites. Most soils measured by the SuperCam laser-induced breakdown spectroscopy (LIBS) instrument show high hydrogen content at the surface, and fine-grained soils also show a visible/near infrared (VISIR) 1.9 µm H 2 O absorption feature. The Planetary Instrument for X-ray Lithochemistry (PIXL) and SuperCam observations suggest the presence of salts at the surface of rocks and soils. The correlation of S and Cl contents with H contents in SuperCam LIBS measurements suggests that the salts present are likely hydrated. On the “Naltsos” target, magnesium and sulfur are correlated in PIXL measurements, and Mg is tightly correlated with H at the SuperCam points, suggesting hydrated Mg-sulfates. Mars Environmental Dynamics Analyzer (MEDA) observations indicate possible frost events and potential changes in the hydration of Mg-sulfate salts. Jezero crater soil crusts may therefore form by salts that are hydrated by changes in relative humidity and frost events, cementing the soil surface together.

Journal of Geophysical Research: Planets↗

Measuring erosional and depositional patterns across Comet 67P's imhotep region

Comet 67P/Churyumov-Gerasimenko displays a pronounced hemispherical dichotomy in surface morphology, where the southern hemisphere exhibits more erosional features than the northern hemisphere due to receiving much greater solar radiation. Consequently, it is generally assumed that particles are ejected from the southern hemisphere through sublimation and a significant fraction eventually descends as airfall, covering the northern terrains. To investigate this south-to-north material transfer during the comet's perihelion passage, we used photoclinometry to measure material redistribution within its most extensive smooth terrain deposit around the Imhotep region. However, our findings do not align with this expected trend. Instead, we show that local-scale processes substantially impact the erosion and accumulation of material, with one area experiencing net erosion while another nearby region, just a few dozen meters away, sees sediment buildup. Our analysis underscores the complex interplay of processes shaping Comet 67P's surface and likely comets more generally.

Journal of Geophysical Research↗

Pockmarks offshore Big Sur, California provide evidence for recurrent, regional, and unconfined sediment gravity flows

Recent surface ship multibeam surveys of the Sur Pockmark Field, offshore Central California, reveal >5,000 pockmarks in an area that is slated to host a wind farm, between 500- and 1,500-m water depth. Extensive fieldwork was conducted to characterize the seafloor environment and its recent geologic history, including visual observations with remotely operated vehicles, sediment core sampling, and high-resolution, near-bottom Chirp and multibeam surveys collected with autonomous underwater vehicles to capture the morphology and stratigraphy of the pockmarks. No evidence of high methane concentrations in sediments, chemosynthetic biological communities, or methane-derived diagenetic byproducts was found. Chirp data and sediment cores showed alternating layers of slowly accumulating hemipelagic drapes interrupted by more reflective turbidite horizons that extend throughout the pockmark field and beyond. Chirp data showed multiple episodes of lateral migration over time in some of the pockmarks in association with erosion and infilling events. Laterally continuous turbidite horizons that overlay erosional surfaces indicated that pockmark migration occurred synchronously in multiple pockmarks separated by tens of kilometers. These shifts are presumed to be the result of asymmetrical erosion of the pockmark flanks caused by passing sediment gravity flows. While some pockmarks occur in chains, most are not clustered or randomly spaced but are regularly dispersed within the pockmark field. We hypothesize that intermittent, unconfined sediment gravity flows occurring over at least the last 280,000 years are the source of the regionally continuous turbidite deposits and the mechanism that maintained the regularly dispersed pockmarks.

California↗

Controls on stable methane isotope signatures in northern peatlands and potential shifts in signatures under permafrost thaw scenarios

Northern peatlands are a globally significant source of methane (CH 4 ), and emissions are projected to increase due to warming and permafrost loss. Understanding the microbial mechanisms behind patterns in CH 4 production in these systems will be key to predicting annual emissions changes, with stable carbon isotopes (δ 13 C-CH 4 ) being a powerful tool for characterizing these drivers. Given that δ 13 C signatures of CH 4 are used in top-down atmospheric inversion models to partition sources, our ability to model CH 4 production pathways and associated δ 13 C-CH 4 signatures in peatland types impacted by a changing climate is critical. We sought to characterize the role of environmental conditions, including both hydrologic and vegetation patterns associated with permafrost thaw, on δ 13 C-CH 4 signatures from a diverse set of high-latitude peatlands. We measured porewater and emitted CH 4 stable isotopes, pH, and vegetation composition from five boreal-Arctic peatlands. Porewater δ 13 C-CH 4 was strongly associated with peatland type, with δ 13 C enriched values obtained from more minerotrophic fens (-61.2 ± 9.1‰) compared to permafrost-free bogs (-74.1 ± 9.4‰) and raised permafrost bogs (-81.6 ± 11.5‰). Variation in porewater δ 13 C-CH 4 was best explained by sedge cover, CH 4 concentration, and the interactive effect of peatland type and pH ( r 2 = 0.50, p < 0.001). Emitted δ 13 C-CH 4 varied greatly but was positively correlated with porewater δ 13 C-CH 4 , suggesting that porewater data can be used to predict changing emissions signatures from these systems. We calculated a weighted mean mixed atmospheric CH 4 signature for northern peatlands of -65.3 ± 7‰ and show that this signature is more sensitive to landscape drying (4 to 10 % depletion in δ 13 C) than wetting (1.5 to 5% enrichment in δ 13 C) under permafrost thaw scenarios. Our results suggest northern peatland δ 13 C-CH 4 signatures are likely to shift in the future which has important implications for source partitioning in atmospheric inversion models.

Journal of Geophysical Research: Biogeosciences↗

Evolution of the Precambrian lithosphere: Seismological and geochemical constraints

Several recent models of crustal evolution are based on the belief that the thickness of the continental crust is proportional to its age, with ancient crust being the thickest. A worldwide review of seismic structure contradicts this belief and falsifies these models, at least for the Archean. Proterozoic crust has a thickness of 40–55 km and a substantial high‐velocity (>7 km/s) layer at its base, while Archean crust is only 27–40 km thick (except at the site of younger rifts and collisional boundaries) and lacks the basal high‐velocity layer. Seismology also provides evidence that the lithosphere is thickest beneath Archean cratons, while diamond ages show that this lithospheric keel must have already existed in the Archean. Geochemical data also indicate significant differences between Archean and Proterozoic lithosphere. Major and trace element studies of sediments show a change in upper crustal composition between the Archean and Proterozoic. Archean rocks are depleted in Si and K and enriched in Na, Ca, and Mg. There is also a marked change in the Eu/Eu * ratio. Mantle xenoliths and continental flood basalts show that the mantle lithosphere beneath Archean crust is ultradepleted in FeO compared to that beneath post‐Archean crust. The secular change in the crust‐forming process is attributed to a decline in mantle temperature, leading to a change in the composition of the lithospheric mantle. The higher temperature of the Archean mantle led to the eruption of komatiitic lavas, producing a refractory lithospheric mantle which is ultradepleted in FeO and volatiles. The resultant lithospheric keel is intrinsically less dense than the surrounding mantle and thus not susceptible to delamination. It was sufficiently thick and cool for diamonds to form during the Archean. In contrast, Proterozoic crust developed above fertile mantle. The eruption of continental flood basalts and underplating of basaltic sills is attributed to subsequent heating and partial melting of the lithospheric mantle. Consequently, Proterozoic crust is thickened and has a high‐velocity basal layer.

Journal of Geophysical Research B: Solid Earth↗

Quantitative investigations of the Missouri gravity low: A possible expression of a large, Late Precambrian batholith intersecting the New Madrid seismic zone

Analysis of gravity and magnetic anomaly data helps characterize the geometry and physical properties of the source of the Missouri gravity low, an important cratonic feature of substantial width (about 125 km) and length (> 600 km). Filtered anomaly maps show that this prominent feature extends NW from the Reelfoot rift to the Midcontinent Rift System. Geologic reasoning and the simultaneous inversion of the gravity and magnetic data lead to an interpretation that the gravity anomaly reflects an upper crustal, 11-km-thick batholith with either near vertical or outward dipping boundaries. Considering the modeled characteristics of the batholith, structural fabric of Missouri, and relations of the batholith with plutons and regions of alteration, a tectonic model for the formation of the batholith is proposed. The model includes a mantle plume that heated the crust during Late Precambrian and melted portions of lower and middle crust, from which the low-density granitic rocks forming the batholith were partly derived. The batholith, called the Missouri batholith, may be currently related to the release of seismic energy in the New Madrid seismic zone (earthquake concentrations occur at the intersection of the Missouri batholith and the New Madrid seismic zone). Three qualitative mechanical models are suggested to explain this relationship with seismicity. Copyright 1996 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

Lunar theory and processes

Despite the fact that the Surveyor 3 landed in a crater, the general appearance of the terrain is remarkably similar to that revealed by Surveyor 1. Evidence of the transport of material down the crater wall was observed. Some picture degradation occurred, apparently as a result of fine particulate lunar surface material being deposited on the TV system mirror during the unusual landing.

Journal of Geophysical Research↗

Late Cenozoic volcanism, geochronology, and structure of the Coso Range, Inyo County, California

The Coso Range lies at the west edge of the Great Basin, adjacent to the southern part of the Sierra Nevada. A basement complex of pre‐Cenozoic plutonic and metamorphic rocks is partly buried by ∼35 km 3 of late Cenozoic volcanic rocks that were erupted during two periods, as defined by K‐Ar dating: (1) 4.0–2.5 m.y., ∼31 km 3 of basalt, rhyodacite, dacite, andesite, and rhyolite, in descending order of abundance, and (2) ≤1.1 m.y., nearly equal amounts of basalt and rhyolite, most of the rhyolite being ≤0.3 m.y. old. Vents for the volcanic rocks of the younger period are localized on and near a horst of basement rocks within a concavity defined by the distribution of vents of the older period. The alignment of many vents and the presence of a considerable number of roughly north‐trending normal faults of late Cenozoic age reflect basin and range tectonics dominated by roughly east‐west lithospheric extension. Fumaroles, intermittently active thermal springs, and associated altered rocks occur within and immediately east of the central part of the field of Quaternary rhyolite, in an area characterized by various geophysical anomalies that are evidently related to an active hot‐water geothermal system. This system apparently is heated by a reservoir of silicic magma at ≥8‐km depth, itself produced and sustained through partial melting of crustal rocks by thermal energy contained in mantle‐derived basaltic magma that intrudes the crust in response to lithospheric extension.

California↗

Distribution of Quaternary rhyolite domes of the Coso Range, California: implications for extent of the geothermal anomaly.

38 separate domes and flows of phenocryst-poor, high-silica rhyolite of similar major element chemical composition were erupted over the past 1My from vents arranged in a crudely S-shaped array atop a granitic horst in the Coso Range, California. Most of the extrusions are probably less than about 0.3My old. The central part of the rhyolite field is characterized by high heat flow, low apparent resistivity, and substantial fumarolic activity indicative of an active geothermal system.

California↗

Sr isotopic tracer study of the Samail ophiolite, Oman

We have measured Rb and Sr concentrations and Sr isotopic compositions in 41 whole-rock samples and 12 mineral separates from units of the Samail ophiolite, including peridotite, gabbro, plagiogranite, diabase dikes, and gabbro and websterite dikes within the metamorphic peridotite. Ten samples of cumulate gabbro from the Wadir Kadir section and nine samples from the Wadi Khafifah section have mean 87 Sr/ 86 Sr ratios and standard deviations of 0.70314 ± 0.00030 and 0.70306 ± 0.00034, respectively. The dispersion in Sr isotopic composition may reflect real heterogeneities in the magma source region. The average Sr isotopic composition of cumulate gabbro falls in the range of isotopic compositions of modern midocean ridge basalt. The 87 Sr/ 86 Sr ratios of noncumulate gabbro, plagiogranite, and diabase dikes range from 0.7034 to 0.7047, 0.7038 to 0.7046, and 0.7037 to 0.7061, respectively. These higher 87 Sr/ 86 Sr ratios are due to alteration of initial magmatic compositions by hydrothermal exchange with seawater. Mineral separates from dikes that cut harzburgite tectonite have Sr isotopic compositions which agree with that of cumulate gabbro. These data indicate that the cumulate gabbro and the different dikes were derived from partial melting of source regions that had similar long-term histories and chemical compositions.

Journal of Geophysical Research Solid Earth↗

Petrology and geochronology of metamorphosed volcanic rocks and a middle Cretaceous volcanic neck in the east-central Sierra Nevada, California

Metamorphosed Mesozoic volcanic rocks from the east-central Sierra Nevada range in composition from basalt to rhyolite and have ages, based on whole rock Rb-Sr and U-Pb zircon dating, of about 237–224, 185, 163, 134, and 100 m.y. The major plutons of the batholith in this area are of Triassic (215–200 m.y.) and Cretaceous (94–80 m.y.) ages. Initial 87 Sr/ 86 Sr values for the metamorphosed volcanic rocks of the area are in the range from 0.7042 to 0.7058 and are generally different from the values for the surrounding batholithic rocks (0.7056–0.7066). A circular, zoned granitic pluton, with an outcrop area of 2.5 km 2 , similar in appearance to a ring dike complex, was apparently a conduit for some or possibly all of the middle-Cretaceous metamorphosed volcanic rocks exposed about 5 km to the south in the western part of the Ritter Range. Samples from the metamorphosed volcanic rocks and the pluton yield a Rb-Sr whole rock isochron age of 99.9 ± 2.2 m.y. with an initial 87 Sr/ 86 Sr of 0.7048 ± 0.0001. Major element variation diagrams of the pluton and volcanic rocks define coincident compositional trends. The pluton, intruded into Early Jurassic metamorphosed volcanic rocks (Rb-Sr whole rock isochron age of 185 ± 6 m.y., initial 87 / 86 Sr = 0.70474 ± 0.00009), is composed of a central body of granite that is intruded into and almost completely surrounded by a crescent-shaped outer rim of quartz monzodiorite. Contact relations between the granitic rocks, intrusive in some places and completely gradational at other places, indicate that the quartz monzodiorite was not completely crystallized prior to the intrusion of the granite. Modal minerology within the pluton is also consistent with this inferred crystallization history. The granitic rock textures are cataclastic, characterized by a groundmass of feldspar and quartz that surrounds larger grains of feldspar, hornblende, and biotite. Widely spaced aplite dikes from the granite intrude the quartz monzodiorite along the contact between the granitic rocks. The aplite dikes and interstitial alkali feldspar associated with myrmekite in the pluton, being undeformed, indicate crystallization of a small amount of silicate liquid after cataclasis. Aplite compositions suggest a minimum crystallization pressure of 0.5 kb (1–2 km); this depth is consistent with crystallization near the base of a large stratovolcano. The pluton is characterized by steep, linear features, defined by mineral clots and inclusions, that probably formed during the upward movement of the nearly crystallized magma in the volcanic conduit. The ages of volcanic events relative to the ages of the major intrusive epochs and the major element and isotopic compositions of the volcanic rocks relative to the major plutons indicate that the volcanic rocks are not simply or directly related to the major plutons in the Sierra Nevada.

Journal of Geophysical Research Solid Earth↗

Active tectonic and magmatic processes beneath Long Valley Caldera, eastern California: An overview

Geological, chronological, and structural studies of the Long Valley-Mono/Inyo Craters area document a long history of related volcanic eruptions and earthquakes controlled by regional extensional tectonics of the Basin and Range province. This activity has persisted for hundreds of thousands of years and is likely to continue. The Long Valley magma chamber had a volume approaching 3000 km 3 prior to its climatic caldera-forming eruption 0.7 m.y. ago but has been reduced to less than a third of this volume by cooling, eruption, and crystallization. Seismic evidence indicates that the main mass of the present Long Valley magma chamber is about 10 km in diameter and that its roof is 8–10 km deep with smaller cupolas as shallow as 4–5 km. Although a chamber of this size is probably capable of producing an eruption approaching 30 km 3 of lava, the record over the past 0.5 m.y. suggests that eruptions of 1 km 3 or less are far more likely. Models proposed for the current ground uplift and seismicity within the caldera require inflation of 0.1–0.2 km 3 by additional magma since mid-1979, and some models suggest that inflation was accompanied by injection of a thin dike or dikes (probably of silicic magma) into the ring fracture zone beneath the south moat. Several of the M 5.8–6.2 earthquakes that occurred in the region beginning in 1978 had non-double-couple focal mechanisms. Whether these unusual mechanisms indicate injection of mafic (low-viscosity) magma at midcrustal depths in the Sierra Nevada block south of the caldera remains debatable. Studies of calderas of various ages throughout the world indicate that episodes of unrest are relatively common and do not invariably culminate in eruptions. Although current unrest is concentrated in the south moat of Long Valley caldera, the Inyo/Mono Craters probably hold a greater potential for producing an eruption in the foreseeable future. The Inyo/Mono Craters have erupted at 500-year intervals over the past 2000–3000 years, whereas the Long Valley magma chamber has erupted at about 200,000-year intervals over the past 700,000 years. In either case, a major earthquake near the caldera could strongly influence the course of volcanic activity.

Journal of Geophysical Research Solid Earth↗

Structure of the southern Juan de Fuca Ridge from seismic reflection records

Twenty-four-channel seismic reflection records were obtained from the axial region of the southern Juan de Fuca Ridge. Two profiles are normal to the strike of the spreading center and intersect the ridge at latitude 44°40′N and 45°05′N; a third profile extends south along the ridge axis from latitude 45°20′N and crosses the Blanco Fracture Zone. Processing of the axial portions of the cross-strike lines resolved a weak reflection centered beneath the axis. The reflector is at a depth similar to seismically detected magma chambers on the East Pacific Rise and a Lau Basin spreading center; we suggest that the reflector represents the top of an axial magma chamber. In the migrated sections the top of the probable magma chamber is relatively flat and 1–2 km wide, and the subbottom depth of the chamber is greater where the depth to the ridge axis is greater.

Journal of Geophysical Research B: Solid Earth↗

Synfolding magnetization in the Jurassic Preuss Sandstone, Wyoming- Idaho-Utah thrust belt

The Jurassic Preuss Sandstone, exposed in five thrust plates of the Wyoming-Idaho-Utah thrust belt, carries directions of remanent magnetization that group most tightly after only partial unfolding. Field, petrographic, and rock magnetic evidence indicates that the carrier of this magnetization is detrital, low-Ti titanomagnetite. The detrital titanomagnetite was remagnetized at low temperatures (75°–150°C) probably completely during folding. Anisotropy of magnetic susceptibility and petrographic observations indicate that the detrital titanomagnetite has been affected by tectonic strain. We suggest that low-temperature remagnetization of the detrital titanomagnetite was either a viscous partial thermoremanent magnetization, the acquisition of which was enhanced by stress, or a piezoremanent magnetization that involved stress-induced movement of domain walls during intracrystalline strain, or was a combination of the two mechanisms. Stress may promote remagnetization at temperatures much lower than predicted by current theoretical models. Other mechanisms, such as acquisition of chemical remanent magnetization during folding, deflection of a prefolding magnetization by internal strain, or combination of components of magnetization with different direction cannot account for the geometry of magnetization in the Preuss. The locus of acquisition of synfolding magnetization in the Preuss migrated in conjunction with deformation in the thrust belt. A model is presented in which synfolding magnetization was acquired during cooling and folding as strata moved up thrust ramps. A lack of reverse-polarity directions remains a puzzling feature of the remanence. The remanent direction is tentatively interpreted to reflect the predominant polarity state during its acquisition over an extended rather than a discrete time period during folding in Late Cretaceous and early Tertiary (?) periods of predominantly normal polarity.

Journal of Geophysical Research Solid Earth↗

Prodigious submarine landslides on the Hawaiian Ridge

The extensive area covered by major submarine mass wasting deposits on or near the Hawaiian Ridge has been delimited by systematic mapping of the Hawaiian exclusive economic zone using the side‐looking sonar system GLORIA. These surveys show that slumps and debris avalanche deposits are exposed over about 100,000 km 2 of the ridge and adjacent seafloor from Kauai to Hawaii, covering an area more than 5 times the land area of the islands. Some of the individual debris avalanches are more than 200 km long and about 5000 km 3 in volume, ranking them among the largest on Earth. The slope failures that produce these deposits begin early in the history of individual volcanoes when they are small submarine seamounts, culminate near the end of subaerial shield building, and apparently continue long after dormancy. Consequently, landslide debris is an important element in the internal structure of the volcanoes. The dynamic behavior of the volcanoes can be modulated by slope failure, and the structural features of the landslides are related to elements of the volcanoes including rift zones and fault systems. The landslides are of two general types, slumps and debris avalanches. The slumps are slow moving, wide (up to 110 km), and thick (about 10 km) with transverse blocky ridges and steep toes. The debris avalanches are fast moving, long (up to 230 km) compared to width, and thinner (0.05–2 km); they commonly have a well‐defined amphitheater at their head and hummocky terrain in the lower part. Oceanic disturbance caused by rapid emplacement of debris avalanches may have produced high‐level wave deposits (such as the 365‐m elevation Hulopoe Gravel on Lanai) that are found on several islands. Most present‐day submarine canyons were originally carved subaerially in the upper parts of debris avalanches. Subaerial canyon cutting was apparently promoted by the recently steepened and stripped slopes of the landslide amphitheaters.

Journal of Geophysical Research B: Solid Earth↗

Quaternary extrusion rates of the Cascade Range, northwestern United States and southern British Columbia

Quaternary (2–0 Ma) extrusion rates change significantly along the Cascade Range volcanic arc. The extrusion rate north of Mount Rainier is about 0.21 km 3 km −1 m.y. −1 ; the rate in southern Washington and northern Oregon south to Mount Hood is about 1.6 km 3 km −1 m.y. −1 ; in central Oregon the rate is 3–6 km 3 km −1 m.y. −1 ; and in northern California, the rate is 3.2 km 3 km −1 m.y. −1 . Eruption style also changes along the arc but at latitudes different from rate changes. At the ends of the arc, volcanism is focused at isolated intermediate to silicic composite volcanoes. The composite volcanoes represent ∼30% of the total volume of the arc. Mafic volcanic fields partly ring some composite volcanoes, especially in the south. In contrast, volcanism is diffused in the middle of the arc, where numerous overlapping mafic shields and a few composite volcanoes have built a broad ridge. Contrasting eruption style may signify diffuse versus focused heat sources or may reflect changes in permeability to ascending magma along the arc.

Journal of Geophysical Research Solid Earth↗

Relations between and among contaminant concentrations and biomarkers in black bass (Micropterus spp.) and common carp (Cyprinus carpio) from large U.S. rivers, 1995-2004

Environmental contaminant and biomarker monitoring data from major U.S. river basins were summarized for black bass (Micropterus spp.) and common carp (Cyprinus carpio) sampled over a nine year period. Cumulative frequency distributions revealed taxon differences for many organochlorine residue concentrations, elemental contaminant concentrations, and biomarkers, but few gender differences were evident for chemical concentrations. Concentrations of dacthal, pentachloroanisole, p,p???-DDE, endosulfan sulfate, barium, cadmium, copper, manganese, lead, selenium, vanadium, and zinc were greater in carp than bass, but concentrations of mercury and magnesium were greater in bass. Gender differences were evident in bass for mercury and in carp for zinc, but the differences were small compared to taxon differences. Greater vitellogenin concentrations, 17??-estradiol concentrations, 17??-estradiol/11-ketotestosterone ratios, and percent oocyte atresia in female carp compared to female bass may be related to the sequential spawning of carp. Regression analyses indicated that as much as 78% of biomarker variation was explained by chemical contaminant concentrations. Sites grouped consistently by river basin in the chemical contaminant principal components analysis (PCA) models and were driven by mercury, magnesium, barium, mirex, and oxychlordane. PCA models for the biomarkers did not group the sites by basin for either bass or carp. Statistical analyses and data interpretation were limited by the study design. The implications of these limitations are discussed. Recommendations to be considered during the planning of future monitoring studies include the exclusion of gender- and species-specific sampling for certain chemical contaminants considering analytical methods with appropriate sensitivities; and allowing for the addition of new chemical and biological variables as methods and information needs evolve. ?? The Royal Society of Chemistry.

Journal of Environmental Monitoring↗