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At least 1,423 records · Page 79Linked to original sources

Re-examining the growing degree day minimum for grass carp spawning initiation in Lake Erie: Have we missed the mark?

Understanding the timing of life history processes of invasive fish species, such as adult aggregations during spawning, allows natural resource managers to optimize targeted population control efforts. Temperature-based estimates of the timing of spawning initiation for grass carp ( Ctenopharyngodon idella ) exist from its native range, but have not previously been developed for grass carp reproduction in its invaded range in the Laurentian Great Lakes of North America. We accounted for differences among methods across studies and calculated cumulative growing degree days (GDD) for the dates of grass carp egg capture in Lake Erie tributaries (Sandusky, Maumee, and Huron rivers) during 2015–2024 and compared these values to the existing GDD base 15°C requirement estimate from the native range (633 GDD–15°C). The earliest egg detection in Lake Erie (Sandusky River) was 19 GDD–15°C or 361 GDD–5°C (latest egg detection was 2285 GDD–5°C from the Sandusky River), indicating that spawning was initiated up to 25 days earlier than would be predicted by the native range GDD. Moreover, spawning in Lake Erie tributaries occurred earlier than predicted for 58% of spawning events examined based on the native range GDD. The GDD values for spawning initiation in Lake Erie tributaries can be used to refine the timing of control efforts targeting pre-spawn and spawning adult fish, inform the timing of egg sampling, and provide linkages to existing early life stage models to infer the length of the growing season available for age-0 fish to reassess tributary suitability.

Ohio↗

Diamondoid hydrocarbons as a molecular proxy for thermal maturity and oil cracking: Geochemical models from hydrous pyrolysis

A series of isothermal hydrous pyrolysis experiments was performed on immature sedimentary rocks and peats of different lithology and organic source input to explore the generation of diamondoids during the thermal maturation of sediments. Oil generation curves indicate that peak oil yields occur between 340 and 360 ??C, followed by intense oil cracking in different samples. The biomarker maturity parameters appear to be insensitive to thermal maturation as most of the isomerization ratios of molecular biomarkers in the pyrolysates have reached their equilibrium values. Diamondoids are absent from immature peat extracts, but exist in immature sedimentary rocks in various amounts. This implies that they are not products of biosynthesis and that they may be generated during diagenesis, not just catagenesis and cracking. Most importantly, the concentrations of diamondoids are observed to increase with thermal stress, suggesting that they can be used as a molecular proxy for thermal maturity of source rocks and crude oils. Their abundance is most sensitive to thermal exposure above temperatures of 360-370 ??C (R0 = 1.3-1.5%) for the studied samples, which corresponds to the onset of intense cracking of other less stable components. Below these temperatures, diamondoids increase gradually due to competing processes of generation and dilution. Calibrations were developed between their concentrations and measured vitrinite reflectance through hydrous pyrolysis maturation of different types of rocks and peats. The geochemical models obtained from these methods may provide an alterative approach for determining thermal maturity of source rocks and crude oils, particularly in mature to highly mature Paleozoic carbonates. In addition, the extent of oil cracking was quantified using the concentrations of diamondoids in hydrous pyrolysates of rocks and peats, verifying that these hydrocarbons are valuable indicators of oil cracking in nature. ?? 2006 Elsevier Ltd. All rights reserved.

Organic Geochemistry↗

Prospects for mineral resource assessments on public lands: Proceedings of the Leesburg workshop

Modern geological surveys pursue a wide spectrum of research activities in the earth sciences. From the beginning, however, one of the core tasks of any national geological survey has been the assessment and evaluation of its nation's mineral and fuel resources. The methods by which such assessments are carried out have become more sophisticated over time, in keeping with advancing geoscientific knowledge and the development and application of new concepts and technologies. However, the basic objectives of such work have changed little, and the fundamental goal remains the construction of the best possible base of information on the nature, distribution and economic potential of the resources within a nation's landmass and its offshore jurisdictions.

Circular↗

Groundwater-quality data in the Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts study unit, 2008-2010--Results from the California GAMA Program

Groundwater quality in the 12,103-square-mile Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts (CLUB) study unit was investigated by the U.S. Geological Survey (USGS) from December 2008 to March 2010, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program's Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The CLUB study unit was the twenty-eighth study unit to be sampled as part of the GAMA-PBP. The GAMA CLUB study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer systems, and to facilitate statistically consistent comparisons of untreated-groundwater quality throughout California. The primary aquifer systems (hereinafter referred to as primary aquifers) are defined as parts of aquifers corresponding to the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the CLUB study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from the quality of groundwater in the primary aquifers; shallow groundwater may be more vulnerable to surficial contamination. In the CLUB study unit, groundwater samples were collected from 52 wells in 3 study areas (Borrego Valley, Central Desert, and Low-Use Basins of the Mojave and Sonoran Deserts) in San Bernardino, Riverside, Kern, San Diego, and Imperial Counties. Forty-nine of the wells were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and three wells were selected to aid in evaluation of water-quality issues (understanding wells). The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, and pharmaceutical compounds), constituents of special interest (perchlorate and N -nitrosodimethylamine [NDMA]), naturally-occurring inorganic constituents (trace elements, nutrients, major and minor ions, silica, total dissolved solids [TDS], alkalinity, and species of inorganic chromium), and radioactive constituents (radon-222, radium isotopes, and gross alpha and gross beta radioactivity). Naturally-occurring isotopes (stable isotopes of hydrogen, oxygen, boron, and strontium in water, stable isotopes of carbon in dissolved inorganic carbon, activities of tritium, and carbon-14 abundance) and dissolved noble gases also were measured to help identify the sources and ages of sampled groundwater. In total, 223 constituents and 12 water-quality indicators were investigated. Three types of quality-control samples (blanks, replicates, and matrix spikes) were collected at up to 10 percent of the wells in the CLUB study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Field blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Replicate samples generally were within the limits of acceptable analytical reproducibility. Median matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 85 percent of the compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is delivered to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH, and to non-regulatory benchmarks established for aesthetic concerns by CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. Most inorganic constituents detected in groundwater samples from the 49 grid wells were detected at concentrations less than drinking-water benchmarks. In addition, all detections of organic constituents from the CLUB study-unit grid-well samples were less than health-based benchmarks. In total, VOCs were detected in 17 of the 49 grid wells sampled (approximately 35 percent), pesticides and pesticide degradates were detected in 5 of the 47 grid wells sampled (approximately 11 percent), and perchlorate was detected in 41 of 49 grid wells sampled (approximately 84 percent). Trace elements, major and minor ions, and nutrients were sampled for at 39 grid wells, and radioactive constituents were sampled for at 23 grid wells; most detected concentrations were less than health-based benchmarks. Exceptions in the grid-well samples include seven detections of arsenic greater than the USEPA maximum contaminant level (MCL-US) of 10 micrograms per liter (μg/L); four detections of boron greater than the CDPH notification level (NL-CA) of 1,000 μg/L; six detections of molybdenum greater than the USEPA lifetime health advisory level (HAL-US) of 40 μg/L; two detections of uranium greater than the MCL-US of 30 μg/L; nine detections of fluoride greater than the CDPH maximum contaminant level (MCL-CA) of 2 milligrams per liter (mg/L); one detection of nitrite plus nitrate (NO 2- +NO 3- ), as nitrogen, greater than the MCL-US of 10 mg/L; and four detections of gross alpha radioactivity (72-hour count), and one detection of gross alpha radioactivity (30-day count), greater than the MCL-US of 15 picocuries per liter. Results for constituents with non-regulatory benchmarks set for aesthetic concerns showed that a manganese concentration greater than the CDPH secondary maximum contaminant level (SMCL-CA) of 50 μg/L was detected in one grid well. Chloride concentrations greater than the recommended SMCL-CA benchmark of 250 mg/L were detected in three grid wells, and one of these wells also had a concentration that was greater than the upper SMCL-CA benchmark of 500 mg/L. Sulfate concentrations greater than the recommended SMCL-CA benchmark of 250 mg/L were measured in six grid wells. TDS concentrations greater than the SMCL-CA recommended benchmark of 500 mg/L were measured in 20 grid wells, and concentrations in 2 of these wells also were greater than the SMCL-CA upper benchmark of 1,000 mg/L.

California↗

Groundwater-quality data in the Santa Barbara study unit, 2011: Results from the California GAMA Program

Groundwater quality in the 48-square-mile Santa Barbara study unit was investigated by the U.S. Geological Survey (USGS) from January to February 2011, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program’s Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The Santa Barbara study unit was the thirty-fourth study unit to be sampled as part of the GAMA-PBP. The GAMA Santa Barbara study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer system, and to facilitate statistically consistent comparisons of untreated-groundwater quality throughout California. The primary aquifer system is defined as those parts of the aquifers corresponding to the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the Santa Barbara study unit. Groundwater quality in the primary aquifer system may differ from the quality in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. In the Santa Barbara study unit located in Santa Barbara and Ventura Counties, groundwater samples were collected from 24 wells. Eighteen of the wells were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and six wells were selected to aid in evaluation of water-quality issues (understanding wells). The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, and pharmaceutical compounds); constituents of special interest (perchlorate and N-nitrosodimethylamine [NDMA]); naturally occurring inorganic constituents (trace elements, nutrients, major and minor ions, silica, total dissolved solids [TDS], alkalinity, and arsenic, chromium, and iron species); and radioactive constituents (radon-222 and gross alpha and gross beta radioactivity). Naturally occurring isotopes (stable isotopes of hydrogen and oxygen in water, stables isotopes of inorganic carbon and boron dissolved in water, isotope ratios of dissolved strontium, tritium activities, and carbon-14 abundances) and dissolved noble gases also were measured to help identify the sources and ages of the sampled groundwater. In total, 281 constituents and water-quality indicators were measured. Three types of quality-control samples (blanks, replicates, and matrix spikes) were collected at up to 12 percent of the wells in the Santa Barbara study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Replicate samples generally were within the limits of acceptable analytical reproducibility. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 82 percent of the compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and CDPH and to non-regulatory benchmarks established for aesthetic concerns by CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. All organic constituents and most inorganic constituents that were detected in groundwater samples from the 18 grid wells in the Santa Barbara study unit were detected at concentrations less than drinking-water benchmarks. Of the 220 organic and special-interest constituents sampled for at the 18 grid wells, 13 were detected in groundwater samples; concentrations of all detected constituents were less than regulatory and non-regulatory health-based benchmarks. In total, VOCs were detected in 61 percent of the 18 grid wells sampled, pesticides and pesticide degradates were detected in 11 percent, and perchlorate was detected in 67 percent. Polar pesticides and their degradates, pharmaceutical compounds, and NDMA were not detected in any of the grid wells sampled in the Santa Barbara study unit. Eighteen grid wells were sampled for trace elements, major and minor ions, nutrients, and radioactive constituents; most detected concentrations were less than health-based benchmarks. Exceptions are one detection of boron greater than the CDPH notification level (NL-CA) of 1,000 micrograms per liter (μg/L) and one detection of fluoride greater than the CDPH maximum contaminant level (MCL-CA) of 2 milligrams per liter (mg/L). Results for constituents with non-regulatory benchmarks set for aesthetic concerns from the grid wells showed that iron concentrations greater than the CDPH secondary maximum contaminant level (SMCL-CA) of 300 μg/L were detected in three grid wells. Manganese concentrations greater than the SMCL-CA of 50 μg/L were detected in seven grid wells. Chloride was detected at a concentration greater than the SMCL-CA recommended benchmark of 250 mg/L in four grid wells. Sulfate concentrations greater than the SMCL-CA recommended benchmark of 250 mg/L were measured in eight grid wells, and the concentration in one of these wells was also greater than the SMCL-CA upper benchmark of 500 mg/L. TDS concentrations greater than the SMCL-CA recommended benchmark of 500 mg/L were measured in 17 grid wells, and concentrations in six of these wells were also greater than the SMCL-CA upper benchmark of 1,000 mg/L.

California↗

Hydrostratigraphic interpretation of test-hole and geophysical data, Upper Loup River Basin, Nebraska, 2008-10

Nebraska's Upper Loup Natural Resources District is currently (2011) participating in the Elkhorn-Loup Model to understand the effect of various groundwater-management scenarios on surface-water resources. During Phase 1 of the Elkhorn-Loup Model, a lack of subsurface geological information in the Upper Loup Natural Resources District, hereafter referred to as the upper Loup study area, was identified as a gap in current knowledge that needed to be addressed. To improve the understanding of the hydrogeology of the upper Loup study area, the U.S. Geological Survey, in cooperation with the Upper Loup Natural Resources District and the University of Nebraska Conservation and Survey Division, collected and described the lithology of drill cuttings from nine test holes, and concurrently collected borehole geophysical data to identify the base of the High Plains aquifer. Surface geophysical data also were collected using time-domain electromagnetic (TDEM) and audio-magnetotelluric (AMT) methods at test-hole locations and between test holes, as a quick, non-invasive means of identifying the base of the High Plains aquifer. Test-hole drilling has indicated greater variation in the base-of-aquifer elevation in the western part of the upper Loup study area than in the eastern part reflecting a number of deep paleovalleys incised into the Brule Formation of the White River Group. TDEM measurements within the upper Loup study area were shown to be effective as virtual boreholes in mapping out the base of the aquifer. TDEM estimates of the base of aquifer were in good accordance with existing test-hole data and were able to improve the interpreted elevation and topology of the base of the aquifer. In 2010, AMT data were collected along a profile, approximately 12 miles (19 kilometers) in length, along Whitman Road, in Grant and Cherry Counties. The AMT results along Whitman Road indicated substantial variability in the elevation of the base of the High Plains aquifer and in the distribution of highly permeable zones within the aquifer.

Open-File Report↗

Geochemical investigations and interim recommendations for priority abandoned mine sites on U.S.D.A. Forest Service lands, Mineral Creek watershed, San Juan County, Colorado

Field observations, sampling of mine dumps and mine drainage waters, and laboratory studies of dump materials have been made at mining areas deemed to be on public lands administered by the USDA Forest Service in the Mineral Creek watershed. Results of chemical analyses of dump materials, leachates of those materials, and of surface waters draining mines or dumps provide indications of where acid is generated or consumed, and what metals are mobilized below mines or dumps. Information on 25 sites is reviewed and reclamation priorities are ranked into four classes (high, medium, low priority, or no work required). The western side of the upper Animas watershed (the Mineral Creek watershed) has a history of mining and prospecting for about 130 years. The intensity of miningrelated disturbance is higher than in most parts of the San Juan Mountains region, but actually is much less than the eastern half of the watershed (US BLM lands) and none of the mines moved millions of tons of rock and ore as in some of the eastern mines. The majority of the roughly one thousand mining sites on the USFS lands are very small (less than 100 tons or 70 cubic yards of dump material), are more than 2 miles from a major stream, or are so inaccessible as to prohibit reclamation. Twenty five sites have been considered by others to have significant size and potential for significant environmental degradation. These most significant mining areas were evaluated by multiple criteria, including tendency to generate acid or liberate toxic metals, observed acidic pH or dead vegetation (?kill zones?) below dumps or adits, potential mobility of metals, and likelihood of transport into streams of the watershed. In the author?s opinion, no single measurable parameter, such as metal concentration, is reliable for ranking significance or feasibility of reclamation. Rather, subjective estimates are required to evaluate combinations of, or interactions among, several parameters. The most subjective estimate in ranking feasibility of reclamation is the amount of natural and mine-related contamination at each mining area. Mitigation of natural contributions at mines or unmined areas is beyond the scope of these Abandoned Mine Lands (AML) investigations, but must be considered when planning reclamation. Available information for the 25 problem sites is adequate for ranking, but at some sites additional information on groundwater conditions is needed for a more reliable ranking and evaluation of reclamation methods.

Colorado↗

Geographic Information Systems Methods for Determining Drainage-Basin Areas, Stream-Buffered Areas, Stream Length, and Land Uses for the Neosho and Spring Rivers in Northeastern Oklahoma

Geographic Information Systems have many uses, one of which includes the reproducible computation of environmental characteristics that can be used to categorize hydrologic features. The Oklahoma Department of Wildlife Conservation and the Oklahoma Department of Environmental Quality are investigating Geographic Information Systems techniques to determine partial drainage-basin areas, stream-buffer areas, stream length, and land uses (drainage basin and stream characteristics) in northeastern Oklahoma. The U.S Geological Survey, in cooperation with Oklahoma Department of Wildlife Conservation and the Oklahoma Department of Environmental Quality, documented the methods used to determine drainage-basin and stream characteristics for the Neosho and Spring Rivers above Grand Lake Of the Cherokees in northeastern Oklahoma and calculated the characteristics. The drainage basin and stream characteristics can be used by the Oklahoma Department of Wildlife Conservation and the Oklahoma Department of Environmental Quality to aid in natural-resource assessments.

Scientific Investigations Report↗

Regeneration alternatives for upland white spruce after burning and logging in interior Alaska

Site-preparation and regeneration methods for white spruce (Picea glauca (Moench) Voss) were tested near Fairbanks, Alaska, on two upland sites which had been burned in a wildfire and salvage logged. After 5 and 10 years, white spruce regeneration did not differ among the four scarification methods but tended to be lower without scarification. Survival of container-grown planted seedlings stabilized after 3 years at 93% with scarification and at 76% without scarification. Broadcast seeding was also successful, with one or more seedlings on 80% of the scarified 6-m2 subplots and on 60% of the unscarified subplots after 12 years. Natural regeneration after 12 years exceeded expectations, with seedlings on 50% of the 6-m2 subplots 150 m from a seed source and on 28% of the subplots 230 m from a seed source. After 5 years, 37% of the scarified unsheltered seed spots and 52% of the scarified seed spots with cone shelters had one or more seedlings, but only 16% of the unscarified seed spots had seedlings, with and without funnel shelters. Growth rates for all seedlings were higher than on similar unburned sites. The results show positive effects of burning in interior Alaska, and suggest planting seedlings, broadcast seeding, and natural seedfall, alone or in combination, as viable options for similar sites.

Canadian Journal of Forest Research↗

Fate and identification of oil-brine contamination in different hydrogeologic settings

Past disposal of oil-field brine at the surface has caused substantial contamination of water resources in Kansas. Natural saline water occurs in and discharges from Permian bedrock in parts of the state, and other anthropogenic sources of saline water exist, requiring clear identification of different sources. Time-series analysis of Cl- concentration and streamflow relative to pre-contamination contents, and end-member mixing plots, especially for Br- and Cl-, are practical methods for source differentiation and quantification. Although regulations preventing escape of saltwater from oil wells were first passed in Kansas in 1935, much oil and gas brine was disposed on the surface through the 1940s. Hydrogeologic characteristics of the areas with past surface disposal of oil brine differ appreciably and result in large differences in the ratio of saltwater transported in streams or ground water. Much of the brine disposed during the 1910s to 1940s in an area of silty clay soils overlying shale and limestone bedrock in south-central Kansas soon ran off or was flushed from the surface by rain into streams. Chloride concentration in the rivers draining this area often exceeded 1000 mg/L after the start of oil production up to the 1950s. Chloride content in the rivers then generally declined to about 100 mg/L or less in recent low flows. Oil brine was also disposed in surface ponds overlying the unconsolidated High Plains aquifer in south-central Kansas from the latter 1920s into the 1940s. Most of the surface-disposed brine infiltrated to the underlying aquifer. Where the High Plains aquifer is thin, saltwater has migrated along the top of clay layers or the underlying shaly bedrock and either discharged into small streams or flowed into thicker parts of the aquifer. Where the aquifer is thick, surface-disposed oil brine moved downward until reaching clay lenses, migrated latterly to the edge of the clay, and again moved downward if still dense enough. Water-level declines from pumping have increased the lateral migration rate of the saltwater contamination in the aquifer towards water-supply wells. The period of flushing most of the surface-disposed saltwater from the area of shale and limestone bedrock is on the order of many decades but is at least many centuries for the deeper parts of the High Plains aquifer. ?? 2007 Elsevier Ltd. All rights reserved.

Applied Geochemistry↗

Modeling drivers of phosphorus loads in Chesapeake Bay tributaries and inferences about long-term change

Causal attribution of changes in water quality often consists of correlation, qualitative reasoning, listing references to the work of others, or speculation. To better support statements of attribution for water-quality trends, structural equation modeling was used to model the causal factors of total phosphorus loads in the Chesapeake Bay watershed. By transforming, scaling, and standardizing variables, grouping similar sites, grouping some causal factors into latent variable models, and using methods that correct for assumption violations, we developed a structural equation model to show how causal factors interact to produce total phosphorus loads. Climate (in the form of annual total precipitation and the Palmer Hydrologic Drought Index) and anthropogenic inputs are the major drivers of total phosphorus load in the Chesapeake Bay watershed. Increasing runoff due to natural climate variability is offsetting purposeful management actions that are otherwise decreasing phosphorus loading; consequently, management actions may need to be reexamined to achieve target reductions in the face of climate variability.

Chesapeake Bay↗

Beryllium geochemistry in soils: Evaluation of 10Be/9Be ratios in authigenic minerals as a basis for age models

Soils contain a diverse and complex set of chemicals and minerals. Being an 'open system', both in the chemical and nuclear sense, soils have defied quantitative nuclear dating. However, based on the published studies of the cosmogenic atmospheric 10Be in soils, its relatively long half-life (1.5 Ma), and the fact that 10Be gets quickly incorporated in most soil minerals, this radionuclide appears to be potentially the most useful for soil dating. We therefore studied the natural variations in the specific activities of 10Be with respect to the isotope 9Be in mineral phases in eight profiles of diverse soils from temperate to tropical climatic regimes and evaluated the implications of the data for determining the time of formation of soil minerals, following an earlier suggestion [Lal et al., 1991. Development of cosmogenic nuclear methods for the study of soil erosion and formation rates. Current Sci. 61, 636-639.]. We find that the 10Be/9Be ratios in both bulk soils and in the authigenic mineral phases are confined within a narrower range than in 10Be concentrations. Also, the highest 10Be/9Be ratios in authigenic minerals are observed at the soil-rock interface as predicted by the model. We present model 10Be/9Be ages of the B-horizon and the corresponding soil formation rates for several soil profiles. The present study demonstrates that the 10Be/9Be ratios in the authigenic phases, e.g. clay and Fe-hydroxides, can indeed be used for obtaining useful model ages for soils younger than 10-15 Ma. However, the present work has to be pushed considerably further, to take into account more realistic age models in which, for instance, downward transport of 10Be and clays, and in-situ dissolution of clay minerals at depths, altering the 10Be/9Be ratios of the acidic solutions, are included. We show that in the case of younger soils (< 1 Ma) studied here, their 10Be inventories and 10Be/9Be ratios have been significantly disturbed possibly by mixing with transported soils. ?? 1997 Elsevier Science B.V.

Chemical Geology↗

New insights into the nation's carbon storage potential

Carbon sequestration is a method of securing carbon dioxide (CO 2 ) to prevent its release into the atmosphere, where it contributes to global warming as a greenhouse gas. Geologic storage of CO 2 in porous and permeable rocks involves injecting high-pressure CO 2 into a subsurface rock unit that has available pore space. Biologic carbon sequestration refers to both natural and anthropogenic processes by which CO 2 is removed from the atmosphere and stored as carbon in vegetation, soils, and sediments.

Eos, Transactions, American Geophysical Union↗

Overestimation of marsh vulnerability to sea level rise

Coastal marshes are considered to be among the most valuable and vulnerable ecosystems on Earth, where the imminent loss of ecosystem services is a feared consequence of sea level rise. However, we show with a meta-analysis that global measurements of marsh elevation change indicate that marshes are generally building at rates similar to or exceeding historical sea level rise, and that process-based models predict survival under a wide range of future sea level scenarios. We argue that marsh vulnerability tends to be overstated because assessment methods often fail to consider biophysical feedback processes known to accelerate soil building with sea level rise, and the potential for marshes to migrate inland.

Nature Climate Change↗

Lake eutrophication— A natural process

Lake eutrophication is an economic, recreational, and aesthetic problem that affects every lake of the world. Eutrophication is the natural process of lake aging, and progresses irrespective of man's activities. Pollution, however, can hasten the natural rate of aging and shorten the life expectancy of a body of water. The eutrophication of a lake consists of the gradual progression from one life stage to another based on the degree of nourishment or productivity. The extinction of a lake is attributed to enrichment by nutritive materials, biological productivity, decay, and sedimentation. Presently used methods for retarding eutrophication are the abatement of cultural enrichment, treatment of eutrophic symptoms, and control of fundamental causes.

Journal of the American Water Resources Associatio↗

Individual heterogeneity influences the effects of translocation on urban dispersal of an invasive reptile

Background Invasive reptiles pose a serious threat to global biodiversity, but early detection of individuals in an incipient population is often hindered by their cryptic nature, sporadic movements, and variation among individuals. Little is known about the mechanisms that affect the movement of these species, which limits our understanding of their dispersal. Our aim was to determine whether translocation or small-scale landscape features affect movement patterns of brown treesnakes ( Boiga irregularis ), a destructive invasive predator on the island of Guam. Methods We conducted a field experiment to compare the movements of resident (control) snakes to those of snakes translocated from forests and urban areas into new urban habitats. We developed a Bayesian hierarchical model to analyze snake movement mechanisms and account for attributes unique to invasive reptiles by incorporating multiple behavioral states and individual heterogeneity in movement parameters. Results We did not observe strong differences in mechanistic movement parameters (turning angle or step length) among experimental treatment groups. We found some evidence that translocated snakes from both forests and urban areas made longer movements than resident snakes, but variation among individuals within treatment groups weakened this effect. Snakes translocated from forests moved more frequently from pavement than those translocated from urban areas. Snakes translocated from urban areas moved less frequently from buildings than resident snakes. Resident snakes had high individual heterogeneity in movement probability. Conclusions Our approach to modeling movement improved our understanding of invasive reptile dispersal by allowing us to examine the mechanisms that influence their movement. We also demonstrated the importance of accounting for individual heterogeneity in population-level analyses, especially when management goals involve eradication of an invasive species.

Movement Ecology↗

Developing version 2 of satellite-estimated precipitation monthly reports for selected locations in the Republic of the Marshall Islands

The Republic of the Marshall Islands (RMI; also known as the Marshall Islands) is a nation of more than 30 low-lying atolls and islands, most of which are inhabited, dispersed across an Exclusive Economic Zone over 770,000 square miles in the tropical central north Pacific Ocean. The study objectives and methods were originally presented in U.S. Geological Survey Data Report 1181 and are summarized herein. Monitoring environmental conditions for potential drought risk is challenging in such a dispersed island nation, and current drought hazard products provide generalities regarding conditions on a broad geographic scale. In 2022–23, a team of U.S. Geological Survey scientists, and managers of natural resources and natural hazards in the RMI, used Integrated Multi-satellitE Retrievals for Global Precipitation Measurement satellite estimates of precipitation to develop content and a template for timely monthly reporting of precipitation for 23 inhabited atolls and islands. After a year of report production and user feedback, the team incorporated lessons learned and revised user priorities to update the content and layout of the template. This data report describes the collaboration process and results of revising the report content and layout into version 2 of the monthly satellite-estimated precipitation report.

Data Report↗

Groundwater-quality data in the North San Francisco Bay Shallow Aquifer study unit, 2012: results from the California GAMA Program

Groundwater quality in the 1,850-square-mile North San Francisco Bay Shallow Aquifer (NSF-SA) study unit was investigated by the U.S. Geological Survey (USGS) from April to August 2012, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program&rsquo;s Priority Basin Project (PBP). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The NSF-SA study unit was the first study unit to be sampled as part of the second phase of the GAMA-PBP, which focuses on the shallow aquifer system. The GAMA NSF-SA study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the shallow aquifer systems and to facilitate statistically consistent comparisons of untreated-groundwater quality throughout California. The shallow aquifer system in the NSF-SA study unit was defined as the part of the aquifer system that is used by many private domestic wells and is shallower than the primary aquifer system used by many public-supply wells. In the NSF-SA study unit located in Marin, Mendocino, Napa, Solano, and Sonoma Counties, groundwater samples were collected from 71 wells. Seventy of the wells were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and one well was selected to aid in evaluation of water-quality issues (understanding well). The groundwater samples were analyzed for organic constituents (volatile organic compounds [VOCs], pesticides, and pesticide degradates); constituents of special interest (perchlorate and 1,2,3-trichloropropane [1,2,3-TCP]); naturally occurring inorganic constituents (trace elements, nutrients, major and minor ions, silica, and total dissolved solids [TDS]); and radioactive constituents (radon-222 and gross alpha and gross beta radioactivity). Naturally occurring isotopes (stable isotopes of hydrogen, oxygen, boron, strontium, and inorganic carbon in water, tritium activities, and carbon-14 abundances) were measured to help identify the sources and ages of the sampled groundwater. In total, 207 constituents and water-quality indicators were measured. Three types of quality-control samples (blanks, replicates, and matrix spikes) were collected at up to 13 percent of the wells in the NSF-SA study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample-collection procedures was not a significant source of bias in the data for the groundwater samples. Replicate samples generally were within the limits of acceptable analytical reproducibility. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 91 percent of the compounds. Most of the wells sampled for this study were private domestic wells. Private domestic wells are not regulated in California, and groundwater from these wells is rarely analyzed for water-quality constituents. Although regulatory benchmarks for drinking-water quality do not apply to private domestic wells, to provide some context for the results, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory health-based benchmarks established by the U.S. Environmental Protection Agency (USEPA) and California Department of Public Health (CDPH), to non-regulatory health-based benchmarks established by the USGS in cooperation with the USEPA, and to non-regulatory benchmarks established for aesthetic concerns by the CDPH. Comparisons between data collected for this study and benchmarks for drinking water are for illustrative purposes only and are not indicative of compliance or non-compliance with those benchmarks. Most of the organic and inorganic constituents that were detected in groundwater samples from the 70 grid wells in the NSF-SA study unit were detected at concentrations less than drinking-water benchmarks. Of the 149 organic and special-interest constituents analyzed for in groundwater samples, 31 were detected; concentrations of most detected constituents were less than regulatory and non-regulatory health-based benchmarks. One VOC, benzene, and one insecticide, dieldrin, were detected at concentrations above their respective health-based benchmarks. In total, VOCs were detected in 40 percent of the grid wells sampled, pesticides and pesticide degradates were detected in 13 percent, and perchlorate was detected in 27 percent of the 70 grid wells sampled. Groundwater samples from 70 grid wells were analyzed for trace elements, major and minor ions, nutrients, and radioactive constituents; most detected concentrations were less than health-based benchmarks. Exceptions are 12 detections of manganese greater than the USGS Health-Based Screening Level (HBSL), 7 detections of arsenic greater than the USEPA maximum contaminant level (MCL-US) of 10 micrograms per liter (&mu;g/L), 2 detections of boron greater than the HBSL of 6,000 &mu;g/L, 2 detections of fluoride greater than the CDPH maximum contaminant level (MCL-CA) of 2 milligrams per liter (mg/L), 2 detections of nitrate greater than the MCL-US of 10 mg/L, and two detections of radon-222 greater than the proposed MCL-US of 4,000 picocuries per liter. Results for constituents with non-regulatory benchmarks set for aesthetic concerns from the grid wells showed that iron concentrations greater than the CDPH secondary maximum contaminant level (SMCL-CA) of 300 &mu;g/L were detected in 13 grid wells. Chloride was detected at a concentration greater than the SMCL-CA recommended benchmark of 250 mg/L in two grid wells. Sulfate concentrations greater than the SMCL-CA recommended benchmark of 250 mg/L were measured in two grid wells, and the concentration in one of these wells was also greater than the SMCL-CA upper benchmark of 500 mg/L. TDS concentrations greater than the SMCL-CA recommended benchmark of 500 mg/L were measured in 15 grid wells, and concentrations in 4 of these wells were also greater than the SMCL-CA upper benchmark of 1,000 mg/L.

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