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At least 1,405 records · Page 78Linked to original sources
USGS2003

Quality of water in domestic wells in the Chicot and Chicot equivalent aquifer systems, southern Louisiana and southwestern Mississippi, 2000-2001

In 2000-2001, water-quality data were collected from 60 randomly selected domestic wells in the Acadian-Pontchartrain Study Unit, as part of the National Water-Quality Assessment Program. The data were collected from wells screened in shallow sands (less than 350 feet below land surface) in two major aquifer systems--the Chicot aquifer system in southwestern Louisiana and the Chicot equivalent aquifer system in southeastern Louisiana and southwestern Mississippi. The Chicot equivalent aquifer system is part of the Southern Hills regional aquifer system, and both the Chicot aquifer system and the Southern Hills regional aquifer systems are designated as sole-source aquifers by the U.S. Environmental Protection Agency (USEPA). The well depths ranged from 40 to 340 feet below land surface with a median depth of 120 feet. The ground-water-quality data included 5 physiochemical properties, dissolved solids, 9 major inorganic ions, 24 trace elements, 6 nutrients, dissolved organic carbon, 109 pesticides and degradation products, and 85 volatile organic compounds (VOC's); and a subset of the wells were sampled for radon, chlorofluorocarbons, and stable isotopes. Water from 35 of the 60 domestic wells sampled had pH values less than the USEPA Seconday Maximum Contaminant Level (SMCL) range of 6.5 to 8.5 standard units. Specific conductance ranged from 17 to 1,420 microsiemens per centimeter at 25 degrees Celsius. Dissolved-solids concentrations in water from two wells exceeded the SMCL of 500 mg/L (milligrams per liter); the maximum concentration was 858 mg/L. Sodium and calcium were the dominant cations, and bicarbonate and chloride were the dominant anions. One chloride concentration (264 mg/L) exceeded the SMCL of 250 mg/L. One arsenic concentration (55.3 micrograms per liter) exceeded the USEPA Maximum Contaminant Level (MCL) of 10 micrograms per liter. Iron concentrations in water from 22 wells exceeded the SMCL of 300 micrograms per liter; the maximum concentration was 8,670 micrograms per liter. Manganese concentrations in water from 26 wells exceeded the SMCL of 50 micrograms per liter; the maximum concentration was 481 micrograms per liter. Health Advisories have been established for six of the trace elements analyzed; no concentrations were greater than these nonenforceable standards. Radon concentrations in water from 9 of 50 wells sampled were greater thanthe proposed USEPA MCL of 300 picocuries per liter. Concentrations of ammonia, ammonia plus organic nitrogen, and nitrite plus nitrate in water from four wells were greater than 2 mg/L, a level that might indicate anthropogenic influences. The median dissolved organic carbon concentration was an estimated 0.30 mg/L, which indicated naturally occurring dissolved organic carbon conditions in the study area. Eight pesticides and two degradation products were detected in water from five wells. Twenty-four VOC's were detected in water from 44 wells. All concentrations of pesticides and VOC's were less than USEPA drinking-water standards. Quality-control samples, which included field-blank samples, replicates, and field and laboratory spikes, indicated no bias in ground-water data from collection procedures or analyses. VAriance between the environmental sampls and he corresponding replicate samples was typically less than 5 percent, indicating and acceptable degree of laboratory precision and data collection reproducibility. The Mann-Whitney rank-sum test was used to compare depth to top of screen and selected physicochemical properties and chemical constituents between six groups of wells. Values for selected physicochemical and chemical constituents were typically greater in wells located in the Chicot aquifer system than in the Chicot equivalent aquifer system. Values for specific conductance, pH, calcium, sodium, bicarbonate, chloride, dis

Water-Resources Investigations Report↗
USGS2003

A summary report of sediment processes in Chesapeake Bay and watershed

The Chesapeake Bay, the Nation's largest estuary, has been degraded because of diminished water quality, loss of habitat, and over-harvesting of living resources. Consequently, the bay was listed as an impaired water body due to excess nutrients and sediment. The Chesapeake Bay Program (CBP), a multi-jurisdictional partnership, completed an agreement called "Chesapeake 2000" that revises and establishes new restoration goals through 2010 in the bay and its watershed. The goal of this commitment is the removal of the bay from the list of impaired waterbodies by the year 2010. The CBP is committed to developing sediment and nutrient allocations for major basins within the bay watershed and to the process of examining new and innovative management plans in the estuary itself and along the coastal zones of the bay. However, additional information is required on the sources, transport, and deposition of sediment that affect water clarity. Because the information and data on sediment processes in the bay were not readily accessible to the CBP or to state, and local managers, a Sediment Workgroup (SWGP) was created in 2001. The primary objective of this report, therefore, is to provide a review of the literature on the sources, transport, and delivery of sediment in Chesapeake Bay and its watershed with discussion of potential implications for various management alternatives. The authors of the report have extracted, discussed, and summarized the important aspects of sediment and sedimentation that are most relevant to the CBP and other sediment related-issues with which resources managers are involved. This report summarizes the most relevant studies concerning sediment sources, transport and deposition in the watershed and estuary, sediments and relation to water clarity, and provides an extensive list of references for those wanting more information.

Water-Resources Investigations Report↗
USGS2005

Borehole-geophysical and hydraulic investigation of the fractured-rock aquifer near the University of Connecticut Landfill, Storrs, Connecticut, 2000 to 2001

An integrated borehole-geophysical and hydraulic investigation was conducted at the former landfill area near the University of Connecticut in Storrs, Connecticut, where solvents and landfill leachate have contaminated a fractured-bedrock aquifer. Borehole-geophysical techniques and hydraulic methods were used to characterize the site bedrock lithology and structure, fractures, and hydraulic properties. The geophysical and hydraulic methods included conventional logs, borehole imaging, borehole radar, flowmeter under ambient- and stressed hydraulic conditions, and discrete-zone hydraulic testing, sampling, and monitoring. The conventional geophysical-logging methods included caliper, deviation, electromagnetic induction, gamma, specific conductance, and fluid temperature. The advanced methods included optical and acoustic imaging of the borehole wall, heat-pulse flowmeter, and directional radar reflection. Borehole-geophysical methods were used to further define conductive features identified with surface-geophysical methods in the first phase of the investigation. The results of the surface- and borehole-geophysical logging were evaluated in an iterative and integrated manner to develop a conceptual model of ground-water flow at the site. The rock type, foliation, and fractures at the site were characterized from high-resolution optical televiewer (OTV) images of rocks penetrated by the boreholes and were compared to drilling logs and conventional geophysical logs. The rocks are interpreted as fine- to mediumgrained quartz-feldspar-biotite-garnet gneiss and schist with local intrusions of quartz diorite and pegmatite and minor concentrations of sulfide mineralization similar to rocks described as the Bigelow Brook Formation on regional geologic maps. Layers containing high concentrations of sulfide minerals appear as high electrical conductivity zones on electromagnetic-induction and borehole-radar logs. Foliation in the rocks generally strikes to the southwest and northeast, and dips to the northwest and southeast consistent with previous investigations in this area. The orientation of foliation, however, varies locally and with depth in some of the boreholes. These results are consistent with geologic mapping that has identified small-scale folding. The orientations of the transmissive fractures identified in the six boreholes logged for this investigation are similar to the fracture orientations mapped in a previous investigation. Many of these fractures are oriented with a north-northwest strike and have a shallow dip to the west. Other transmissive fractures have a southwest strike and dip at shallow angles to the northwest, and some strike roughly east-west and dip to the north and south. Flowmeter logging was used to identify transmissive fractures and to estimate the hydraulic properties in the boreholes. Ambient down flow was measured in one borehole, and ambient up flow and down flow were measured in another borehole. The other four bedrock boreholes did not have measurable vertical flow. Under low-rate pumping conditions (0.25 to 0.5 gallons per minute), one to three inflow zones were identified in each well. Commonly, fractures that are active under ambient conditions contribute to the well under pumping conditions. The ambient conditions were incorporated into the determination of the relative proportions of transmissivity. Specific capacity and transmissivity were determined for these open-hole low-rate pumping tests. Quasi-steady-state water levels were reached in four of the boreholes, including MW201R, MW204R, MW302R, and W202-NE. When pumped at low-rate conditions for 0.5 to 4 hours, the specific capacity ranged from 0.03 to 0.18 gallons per minute per foot. The open-hole transmissivity estimates ranged from 4.9 to 30 feet squared per day (ft2/d). Open-hole transmissivity was determined for boreholes that did not reach quasi-steady-state conditions under low-rate pumping conditions. Transmissivity was estimated for MW201R, MW202R, and MW203R using non-equilibrium methods, pumping rate, and the transient drawdown data to estimate the open-hole transmissivity. Transmissivity in these boreholes ranged from 0.98 to 3.2 ft 2 /d. The transmissivity and head of individual fractures or zones of fractures were estimated from heat-pulse flowmeter data acquired under ambient and stressed conditions. In the absence of ambient flow, data from two profiles of heat-pulse flowmeter data under two different stressed conditions were used to estimate the transmissivity and head of individual fracture zones. Only two boreholes, MW302R and W202-NE, had sufficient data for these analyses. The estimated transmissivity of individual transmissive zones ranged from 1.2 to 9.2 ft 2 /d. The transmissivity values determined by this numerical simulation method were less than the open-hole estimations, which were 15 and 30 ft 2 /d. Transmissivity also was measured directly over discrete intervals of the borehole using a straddle-packer apparatus and constant-rate pumping tests. Pumping rates were less than or equal to 0.25 gallons per minute. These discretezone single-hole pumping tests were conducted over a short period of time, usually about 30 minutes to 1 hour in duration. Pumping continued until the test zone reached a steady-state water level or until it was determined that the zone could not yield water at the pumped rate. The estimated transmissivity of individual transmissive zones ranged from about 0.21 to 11 ft 2 /d. The zone at a depth of 197 feet in W202-NE was the only zone that had discrete-interval testing with a straddle packer and sufficient heat-pulse flowmeter data for modeling the flow and estimating transmissivity and head. The two methods produced similar results. The straddle-packer method estimated a transmissivity of 4.7 ft 2 /d, and the heat-pulse flowmeter modeling results estimated a transmissivity of 6.9 ft 2 /d. A comparison of the transmissivity estimates indicate estimates typically are within an order of magnitude. The heat-pulse flowmeter methods used in this investigation to determine transmissivity of the boreholes and the individual fractures measure only the upper two or three orders of magnitude of transmissivity. Hence, other fractures in these boreholes permit the movement of water; their transmissivities, however, are lower than the detection limits of the methods that were used for this investigation and very small compared to the transmissive fractures that were studied. The data collected in this investigation were used to design discrete-zone monitoring systems for four of the boreholes used for monitoring. The results of the investigation are useful for refining the conceptual site model of ground-water flow, and for providing critical information for interpreting the results of water-quality sampling.

Connecticut↗
USGS2004

Sources and Transport of Nutrients, Organic Carbon, and Chlorophyll-a in the San Joaquin River Upstream of Vernalis, California, during Summer and Fall, 2000 and 2001

Oxidizable materials from the San Joaquin River upstream of Vernalis can contribute to low dissolved oxygen episodes in the Stockton Deep Water Ship Channel that can inhibit salmon migration in the fall. The U.S. Geological Survey collected and analyzed samples at four San Joaquin River sites in July through October 2000 and June through November 2001, and at eight tributary sites in 2001. The data from these sites were supplemented with data from samples collected and analyzed by the University of California at Davis at three San Joaquin River sites and eight tributary sites as part of a separate study. Streamflows in the San Joaquin River were slightly above the long-term average in 2000 and slightly below average in 2001. Nitrate loads at Vernalis in 2000 were above the long-term average, whereas loads in 2001 were close to average. Total nitrogen loads in 2000 were slightly above average, whereas loads in 2001 were slightly below average. Total phosphorus loads in 2000 and 2001 were well below average. These nutrient loads correspond with the flow-adjusted concentration trends--nitrate concentrations significantly increased since 1972 (p < 0.01), whereas total nitrogen and total phosphorus concentrations did not (p > 0.05). Loading rates of nutrients and dissolved organic carbon increased in the San Joaquin River in the fall with the release of wetland drainage into Mud Slough and with increased reservoir releases on the Merced River. During August 2000 and September 2001, the chlorophyll-a loading rates and concentrations in the San Joaquin River declined and remained low during the rest of the sampling period. The most significant tributary sources of nutrients were the Tuolumne River, Harding Drain, and Mud Slough. The most significant tributary sources of dissolved organic carbon were Salt Slough, Mud Slough, and the Tuolumne and Stanislaus Rivers. Compared with nutrients and dissolved organic carbon, the tributaries were minor sources of chlorophyll-a, suggesting that most of the chlorophyll-a was produced in the San Joaquin River rather than its tributaries. On the basis of the carbon-to-nitrogen ratios and the d13C of particulate organic matter in the San Joaquin River and tributaries, the particulate organic matter in the river was mostly phytoplankton. On the basis of the d15N values of the particulate organic matter, and of total dissolved nitrogen and nitrate, the nitrate in the San Joaquin River probably was a significant nutrient source for the phytoplankton. The range of d15N and d18O values of nitrate in the San Joaquin River and tributaries suggest that animal waste or sewage was a significant source of nitrate in the river at the time the samples were collected.

Water-Resources Investigations Report↗
USGS2003

Water Resources of the Ground-Water System in the Unconsolidated Deposits of the Colville River Watershed, Stevens County, Washington

A study of the water resources of the ground-water system in the unconsolidated deposits of the Colville River Watershed provided the Colville River Watershed Planning Team with an assessment of the hydrogeologic framework, preliminary determinations of how the shallow and deeper parts of the ground-water system interact with each other and the surface-water system, descriptions of water-quantity characteristics including water-use estimates and an estimated water budget for the watershed, and an assessment of further data needs. The 1,007-square-mile watershed, located in Stevens County in northeastern Washington, is closed to further surface-water appropriations throughout most of the basin during most seasons. The information provided by this study will assist local watershed planners in assessing the status of water resources within the Colville River Watershed (Water Resources Inventory Area 59). The hydrogeologic framework consists of glacial and alluvial deposits that overlie bedrock and are more than 700 feet thick in places. Twenty-six hydrogeologic sections were constructed, using a map of the surficial geology and drillers' logs for more than 350 wells. Seven hydrogeologic units were delineated: the Upper outwash aquifer, the Till confining unit, the Older outwash aquifer, the Colville Valley confining unit, the Lower aquifer, the Lower confining unit, and Bedrock. Synoptic stream discharge measurements made in September 2001 identified gaining and losing reaches over the unconsolidated valley deposits. During the September measurement period, the Colville River gained flow from the shallow ground-water system near its headwaters to the town of Valley and lost flow to the shallow ground-water system from Valley to Chewelah. Downstream from Chewelah, the river generally lost flow, but the amounts lost were small and within measurement error. Ground-water levels indicate that the Lower aquifer and the shallow ground-water system may act as fairly independent systems. The presence of flowing wells completed in the Lower aquifer indicates upward head gradients along much of the Colville Valley floor. Total surface- and ground-water withdrawals during 2001 were estimated to be 9,340 million gallons. Water use for 2001, as a percentage of the total, was 75.3 percent for irrigation, 16.3 percent for public supply, 6.5 percent for private wells, and about 1 percent each for industrial and livestock use. An approximate water budget for a typical year in the Colville River Watershed shows that 27 inches of precipitation are balanced by 4.2 inches of streamflow discharge from the basin, 0.3 inch of ground-water discharge from the basin, and 22.5 inches of evapotranspiration.

Water-Resources Investigations Report↗
USGS2003

Simulation of ground-water flow and rainfall runoff with emphasis on the effects of land cover, Whittlesey Creek, Bayfield County, Wisconsin, 1999-2001

The effects of land cover on flooding and base-flow characteristics of Whittlesey Creek, Bayfield County, Wis., were examined in a study that involved ground-water-flow and rainfall-runoff modeling. Field data were collected during 1999-2001 for synoptic base flow, streambed head and temperature, precipitation, continuous streamflow and stream stage, and other physical characteristics. Well logs provided data for potentiometric-surface altitudes and stratigraphic descriptions. Geologic, soil, hydrography, altitude, and historical land-cover data were compiled into a geographic information system and used in two ground-water-flow models (GFLOW and MODFLOW) and a rainfall-runoff model (SWAT). A deep ground-water system intersects Whittlesey Creek near the confluence with the North Fork, producing a steady base flow of 17?18 cubic feet per second. Upstream from the confluence, the creek has little or no base flow; flow is from surface runoff and a small amount of perched ground water. Most of the base flow to Whittlesey Creek originates as recharge through the permeable sands in the center of the Bayfield Peninsula to the northwest of the surface-water-contributing basin. Based on simulations, model-wide changes in recharge caused a proportional change in simulated base flow for Whittlesey Creek. Changing the simulated amount of recharge by 25 to 50 percent in only the ground-water-contributing area results in relatively small changes in base flow to Whittlesey Creek (about 2?11 percent). Simulated changes in land cover within the Whittlesey Creek surface-water-contributing basin would have minimal effects on base flow and average annual runoff, but flood peaks (based on daily mean flows on peak-flow days) could be affected. Based on the simulations, changing the basin land cover to a reforested condition results in a reduction in flood peaks of about 12 to 14 percent for up to a 100-yr flood. Changing the basin land cover to 25 percent urban land or returning basin land cover to the intensive row-crop agriculture of the 1920s results in flood peaks increasing by as much as 18 percent. The SWAT model is limited to a daily time step, which is adequate for describing the surface-water/ground-water interaction and percentage changes. It may not, however, be adequate in describing peak flow because the instantaneous peak flow in Whittlesey Creek during a flood can be more than twice the magnitude of the daily mean flow during that same flood. In addition, the storage and infiltration capacities of wetlands in the basin are not fully understood and need further study.

Wisconsin↗
USGS2004

Geochemical characterization of ground-water flow in the Santa Fe Group aquifer system, Middle Rio Grande Basin, New Mexico

Chemical and isotopic data were obtained from ground water and surface water throughout the Middle Rio Grande Basin (MRGB), New Mexico, and supplemented with selected data from the U.S. Geological Survey (USGS) National Water Information System (NWIS) and City of Albuquerque water-quality database in an effort to refine the conceptual model of ground-water flow in the basin. The ground-water data collected as part of this study include major- and minor-element chemistry (30 elements), oxygen-18 and deuterium content of water, carbon-13 content and carbon-14 activity of dissolved inorganic carbon, sulfur-34 content of dissolved sulfate, tritium, and dissolved atmospheric gases including nitrogen, argon, helium, chlorofluorocarbons, and sulfur hexafluoride from 288 wells and springs in parts of the Santa Fe Group aquifer system. The surface-water data collected as part of this study include monthly measurements of major- and minor-element chemistry (30 elements), oxygen-18 and deuterium content of water, chlorofluorocarbons, and tritium content at 14 locations throughout the basin. Additional data include stable isotope analyses of precipitation and of ground water from City of Albuquerque production wells collected and archived from the early 1980?s, and other data on the chemical and isotopic composition of air, unsaturated zone air, plants, and carbonate minerals from throughout the basin. The data were used to identify 12 sources of water to the basin, map spatial and vertical extents of ground-water flow, map water chemistry in relation to hydrogeologic, stratigraphic, and structural properties of the basin, determine radiocarbon ages of ground water, and reconstruct paleo-environmental conditions in the basin over the past 30,000 years. The data indicate that concentrations of most elements and isotopes generally parallel the predominant north to south direction of ground-water flow. The radiocarbon ages of dissolved inorganic carbon in ground water range from modern (post-1950) to more than 30,000 years before present, and appear to be particularly well defined in the predominantly siliciclastic aquifer system. Major sources of water to the basin include (1) recharge from mountains along the north, east and southwest margins (median age 5,000-9,000 years); (2) seepage from the Rio Grande and Rio Puerco (median age 4,000-8,000 years), and from Abo and Tijeras Arroyos (median age 3,000-9,000 years); (3) inflow of saline water along the southwestern basin margin (median age 20,000 years); and (4) inflow along the northern basin margin that probably represents recharge from the Jemez Mountains during the last glacial period (median age 20,000 years). Water recharged from the Jemez Mountains during the last glacial period occurs at the water table in the central part of the basin and beneath younger recharge along the Rio Grande and the northern mountain front. In some parts of the basin, boundaries between hydrochemical zones appear to be near major faults that may affect ground-water flow. However, in other parts of the basin, such as along the east side of Albuquerque near the Sandia Fault zone, ground-water flow appears to be unaffected by major faults. Upward leakage of saline water occurs along some faults and can be a source of salinity and elevated arsenic concentrations in some ground water. A trough in the modern and predevelopment water table west of Albuquerque is centered along a zone of predominantly late Pleistocene age water through the center of the basin and is flanked and overlain along the trough boundary by water that infiltrated from the Rio Puerco on the west and the Rio Grande to the east. It is suggested that the groundwater trough is a relatively recent transient feature of the Santa Fe Group aquifer system. At Albuquerque, a distinct north-south boundary in deuterium content of ground water marks the division between recharge from the eastern mountain front and that from the Rio Grande.

New Mexico↗
USGS2003

Development and calibration of a ground-water flow model for the Sparta Aquifer of southeastern Arkansas and north-central Louisiana and simulated response to withdrawals, 1998-2027

The Sparta aquifer, which consists of the Sparta Sand, in southeastern Arkansas and north-central Louisiana is a major water resource and provides water for municipal, industrial, and agricultural uses. In recent years, the demand in some areas has resulted in withdrawals from the Sparta aquifer that substantially exceed replenishment of the aquifer. Considerable drawdown has occurred in the potentiometric surface forming regional cones of depression as water is removed from storage by withdrawals. These cones of depression are centered beneath the Grand Prairie area and the cities of Pine Bluff and El Dorado in Arkansas, and Monroe in Louisiana. The rate of decline for hydraulic heads in the aquifer has been greater than 1 foot per year for more than a decade in much of southern Arkansas and northern Louisiana where hydraulic heads are now below the top of the Sparta Sand. Continued hydraulic-head declines have caused water users and managers alike to question the ability of the aquifer to supply water for the long term. Concern over protecting the Sparta aquifer as a sustainable resource has resulted in a continued, cooperative effort by the Arkansas Soil and Water Conservation Commission, U.S. Army Corps of Engineers, and the U.S. Geological Survey to develop, maintain, and utilize numerical ground-water flow models to manage and further analyze the ground-water system. The work presented in this report describes the development and calibration of a ground-water flow model representing the Sparta aquifer to simulate observed hydraulic heads, documents major differences in the current Sparta model compared to the previous Sparta model calibrated in the mid-1980's, and presents the results of three hypothetical future withdrawal scenarios. The current Sparta model-a regional scale, three-dimensional numerical ground-water flow model-was constructed and calibrated using available hydrogeologic, hydraulic, and water-use data from 1898 to 1997. Significant changes from the previous model include grid rediscretization of the aquifer, extension of the active model area northward beyond the Cane River Formation facies change, and representation of model boundaries. The current model was calibrated with the aid of parameter estimation, a nonlinear regression technique, combined with trial and error parameter adjustment using a total of 795 observations from 316 wells over 4 different years-1970, 1985, 1990, and 1997. The calibration data set provides broad spatial and temporal coverage of aquifer conditions. Analysis of the residual statistics, spatial distribution of residuals, simulated compared to observed hydrographs, and simulated compared to observed potentiometric surfaces were used to analyze the ability of the calibrated model to simulate aquifer conditions within acceptable error. The calibrated model has a root mean square error of 18 feet for all observations, an improvement of more than 12 feet from the previous model. The current Sparta model was used to predict the effects of three hypothetical withdrawal scenarios on hydraulic heads over the period 1998-2027 with one of those extended indefinitely until equilibrium conditions were attained, or steady state. In scenario 1a, withdrawals representing the time period from 1990 to 1997 was held constant for 30 years from 1998 to 2027. Hydraulic heads in the middle of the cone of depression centered on El Dorado decreased by 10 feet from the 1997 simulation to 222 feet below NGVD of 1929 in 2027. Hydraulic heads in the Pine Bluff cone of depression showed a greater decline from 61 feet below NGVD of 1929 to 78 feet below NGVD of 1929 in the center of the cone. With these same withdrawals extended to steady state (scenario 1b), hydraulic heads in the Pine Bluff cone of depression center declined an 2 Development and Calibration of a Ground-Water Flow Model for the Sparta Aquifer of Southeastern Arkansas and North-Central Louisiana and Simulated Response to Withdrawa

Water-Resources Investigations Report↗
USGS2003

Diffusion and drive-point sampling to detect ordnance-related compounds in shallow ground water beneath Snake Pond, Cape Cod, Massachusetts, 2001-02

Diffusion samplers and temporary drive points were used to test for ordnance-related compounds in ground water discharging to Snake Pond near Camp Edwards at the Massachusetts Military Reservation, Cape Cod, MA. The contamination resulted from artillery use and weapons testing at various ranges upgradient of the pond.The diffusion samplers were constructed with a high-grade cellulose membrane that allowed diffusion of explosive compounds, such as RDX (Hexahydro-1,3,5-trinitro-1,3,5-triazine) and HMX (Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine), into deionized water inside the samplers. Laboratory tests confirmed that the cellulose membrane was permeable to RDX and HMX. One transect of 22 diffusion samplers was installed and retrieved in August-September 2001, and 12 transects with a total of 108 samplers were installed and retrieved in September-October 2001. The diffusion samplers were buried about 0.5 feet into the pond-bottom sediments by scuba divers and allowed to equilibrate with the ground water beneath the pond bottom for 13 to 27 days before retrieval. Water samples were collected from temporary well points driven about 2-4 feet into the pond bottom at 21 sites in December 2001 and March 2002 for analysis of explosives and perchlorate to confirm the diffusion-sampling results. The water samples from the diffusion samplers exhibited numerous chromatographic peaks, but evaluation of the photo-diode-array spectra indicated that most of the peaks did not represent the target compounds. The peaks probably are associated with natural organic compounds present in the soft, organically enriched pond-bottom sediments. The presence of four explosive compounds at five widely spaced sites was confirmed by the photo-diode-array analysis, but the compounds are not generally found in contaminated ground water near the ranges. No explosives were detected in water samples obtained from the drive points. Perchlorate was detected at less than 1 microgram per liter in two drive-point samples collected at the same site on two dates about 3 months apart. The source of the perchlorate in the samples could not be related directly to other contamination from Camp Edwards with the available information. The results from the diffusion and drive-point sampling do not indicate an area of ground-water discharge with concentrations of the ordnance-related compounds that are sufficiently elevated to be detected by these sampling methods. The diffusion and drive-point sampling data cannot be interpreted further without additional information concerning the pattern of ground-water flow at Snake Pond and the distributions of RDX, HMX, and perchlorate in ground water in the aquifer near the pond.

Massachusetts↗
USGS2004

Water-quality and bottom-material characteristics of Cross Lake, Caddo Parish, Louisiana, 1997-99

Cross Lake is a shallow, monomictic lake that was formed in 1926 by the impoundment of Cross Bayou. The lake is the primary drinking-water supply for the City of Shreveport, Louisiana. In recent years, the lakeshore has become increasinginly urbanized. In addition, the land use of the watershed contributing runoff to Cross Lake has changed. Changes in land use and urbanization could affect the water chemistry and biology of the Lake. Water-quality data were collected at 10 sites on Cross Lake from February 1997 to February 1999. Water-column and bottom-material samples were collected. The water-column samples were collected at least four times per year. These samples included physical and chemical-related properties such as water temperature, dissolved oxygen, pH, and specific conductance; selected major inorganic ions; nutrients; minor elements; organic chemical constituents; and bacteria. Suspended-sediment samples were collected seven times during the sampling period. The bottom-material samples, which were collected once during the sampling period, were analyzed for selected minor elements and inorganic carbon. Aside from the nutrient-enriched condition of Cross Lake, the overall water-quality of Cross Lake is good. No primary Federal or State water-quality criteria were exceeded by any of the water-quality constituents analyzed for this report. Concentrations of major inorganic constituents, except iron and manganese, were low. Water from the lake is a sodium-bicarbonate type and is soft. Minor elements and organic compounds were present in low concentrations, many below detection limits. Nitrogen and phosphorus were the nutrients occurring in the highest concentrations. Nutrients were evenly distributed across the lake with no particular water-quality site indicating consistently higher or lower nutrient concentrations. No water samples analyzed for nitrate exceeded the U.S. Environmental Protection Agency's Maximum Contaminant Level of 10 milligrams per liter. Based on nitrogen to phosphorus ratios calculated for Cross Lake, median values for all water-quality sites were within the nitrogen-limited range (less than or equal to 5). Historical Trophic State Indexes for Cross Lake classified the lake as eutrophic. Recent (1998-99) Trophic State Indexes classify Cross Lake as mesotrophic-eutrophic, which might indicate a recution in eutrophication. Sedimentation traps indicate that Cross Lake is filling at an average rate of 0.41 inches per year. Concentrations of fecal-coliform and streptococci bacteria generally were low. Fecal coliform was detected in higher concentrations than fecal streptococci. High bacterial concentrations were measured shortly after rainfall-runoff events, possibly washing bacteria from surrounding areas into the lake.

Louisiana↗
USGS2003

Environmental effects of the Big Rapids dam remnant removal, Big Rapids, Michigan, 2000-02

The U.S. Geological Survey (USGS), in cooperation with the city of Big Rapids, investigated the environmental effects of removal of a dam-foundation remnant and downstream cofferdam from the Muskegon River in Big Rapids, Mich. The USGS applied a multidiscipline approach, which determined the water quality, sediment character, and stream habitat before and after dam removal. Continuous water-quality data and discrete water-quality samples were collected, the movement of suspended and bed sediment were measured, changes in stream habitat were assessed, and streambed elevations were surveyed. Analyses of water upstream and downstream from the dam showed that the dam-foundation remnant did not affect water quality. Dissolved-oxygen concentrations downstream from the dam remnant were depressed for a short period (days) during the beginning of the dam removal, in part because of that removal effort. Sediment transport from July 2000 through March 2002 was 13,800 cubic yards more at the downstream site than the upstream site. This increase in sediment represents the remobilized sediment upstream from the dam, bank erosion when the impoundment was lowered, and contributions from small tributaries between the sites. Five habitat reaches were monitored before and after dam-remnant removal. The reaches consisted of a reference reach (A), upstream from the effects of the impoundment; the impoundment (B); and three sites below the impoundment where habitat changes were expected (C, D, and E, in downstream order). Stream-habitat assessment reaches varied in their responses to the dam-remnant removal. Reference reach A was not affected. In impoundment reach B, Great Lakes and Environmental Assessment Section (GLEAS) Procedure 51 ratings went from fair to excellent. For the three downstream reaches, reach C underwent slight habitat degradation, but ratings remained good; reach D underwent slight habitat degradation with ratings changing from excellent to good; and, in an area affected by a 1966 sediment release, reach E habitat rated fair in April 2000 and remained fair in September 2001. The most noticeable habitat change in the three reaches downstream from the dam site was a measurable increase in siltation and embeddedness. Bed-elevation profiles show that bed material upstream from the dam site was remobilized as suspended sediment and bedload, and was redeposited in the reaches below the cofferdam. Deposition was greater in the deep, slow-moving pools than the shallow, fast-moving riffles. For the most part, where deposition took place, deposits were less than 1 foot in thickness. In the year following the removal of the cofferdam, much of the sediment deposited below the dam was moved out of the study reach.

Michigan↗
USGS2004

Hydrogeology and water quality of the Pepacton Reservoir Watershed in southeastern New York. Part 1. Concentrations of pesticides and their degradates in stream baseflow, 2000-2001

Baseflow samples were collected from 20 small streams in the Pepacton Reservoir watershed in Delaware County, N.Y., from December 2000 through November 2001 as part of an investigation to define the occurrence of pesticides in shallow ground water in watersheds containing either a recent (2001) corn crop, a previous (1993-94) corn crop, or no history of row-crop cultivation. Baseflow water quality was assumed to represent the chemical quality of shallow ground water within the drainage area above each sampling site. Baseflow samples were analyzed for 57 pesticides and pesticide degradates. Three herbicides (atrazine, metolachlor and simazine) and three herbicide degradates (alachlor ESA [ethanesulfonic acid], deethylatrazine, and metolachlor ESA) were detected, but no concentrations exceeded any Federal or State water-quality criteria, and the maximum concentrations of all compounds except metolachlor ESA were less than 0.10 microgram per liter. The most frequently detected compounds (atrazine, metolachlor, deethylatrazine and metolachlor ESA) are either those typically used on corn crops, or those whose parent compounds are commonly used on corn crops and have been detected in streams that drain row-crop settings elsewhere in New York State. The pesticide and pesticide-degradate concentrations in baseflow samples collected in December 2000 and July 2001 samples generally corresponded to the amount of cornfield acreage in each watershed in 2001. The types of pesticides detected, and their median concentrations, were similar to those noted in two previous ground-water studies in row-crop areas elsewhere in upstate New York. Also the SAM ratios (ratio of metolachlor ESA concentration to metolachlor concentration) for the Pepacton samples were similar to those for ground-water samples from other agricultural settings in upstate New York, but were significantly higher than that for stormflow and baseflow samples collected in 1997-98 from Canajoharie Creek, an upstate stream that drains row-crop farmland. These comparisons confirm that the baseflow samples were derived from, and were representative of, ground water in their respective watersheds. Late-summer decreases in atrazine and deethylatrazine concentrations at a site where corn was grown in 2001 may have resulted from the seasonally dry conditions and the accompanying decrease in ground-water discharge from the upper-most part of the surficial aquifer system to streams. The lack of a similar decrease in metolachlor ESA concentrations during this period may reflect the transport of metolachlor ESA to deeper parts of the surficial aquifer that continued to discharge to streams during the dry period.

New York↗
USGS2003

Simulation of streamflow and water quality in the Red Clay Creek subbasin of the Christina River Basin, Pennsylvania and Delaware, 1994-98

The Christina River Basin drains 565 square miles (mi 2 ) in Pennsylvania and Delaware and includes the major subbasins of Red Clay Creek, White Clay Creek, Brandywine Creek, and Christina River. The Red Clay Creek is the smallest of the subbasins and drains an area of 54 mi 2 . Streams in the Christina River Basin are used for recreation, drinking-water supply, and to support aquatic life. Water quality in some parts of the Christina River Basin is impaired and does not support designated uses of the stream. A multi-agency, waterquality management strategy included a modeling component to evaluate the effects of point and nonpointsource contributions of nutrients and suspended sediment on stream water quality. To assist in nonpointsource evaluation, four independent models, one for each of the four main subbasins of the Christina River Basin, were developed and calibrated using the model code Hydrological Simulation Program?Fortran (HSPF). Water-quality data for model calibration were collected in each of the four main subbasins and in smaller subbasins predominantly covered by one land use following a nonpoint-source monitoring plan. Under this plan, stormflow and base-flow samples were collected during 1998 at 1 site in the Red Clay Creek subbasin and at 10 sites elsewhere in the Christina River Basin. The HSPF model for the Red Clay Creek subbasin simulates streamflow, suspended sediment, and the nutrients, nitrogen and phosphorus. In addition, the model simulates water temperature, dissolved oxygen, biochemical oxygen demand, and plankton as secondary objectives needed to support the sediment and nutrient simulations. For the model, the basin was subdivided into nine reaches draining areas that ranged from 1.7 to 10 mi 2 . One of the reaches contains a regulated reservoir. Ten different pervious land uses and two impervious land uses were selected for simulation. Land-use areas were determined from 1995 land-use data. The predominant land uses in the Red Clay Creek subbasin are agricultural, forested, residential, and urban. The hydrologic component of the model was run at an hourly time step and calibrated using streamflow data from three U.S. Geological Survey (USGS) streamflow-measurement stations for the period of October 1, 1994, through October 29, 1998. Daily precipitation data from one National Oceanic and Atmospheric Administration (NOAA) gage and hourly data from one NOAA gage were used for model input. The difference between observed and simulated stream- flow volume ranged from -0.8 to 2.1 percent for the 4-year period at the three calibration sites. Annual differences between observed and simulated streamflow generally were greater than the overall error for the 4-year period. For example, at a site near Stanton, Del., near the bottom of the basin (drainage area of 50.2 mi 2 ), annual differences between observed and simulated streamflow ranged from -5.8 to 6.0 percent and the overall error for the 4-year period was -0.8 percent. Calibration errors for 36 storm periods at the three calibration sites for total volume, low-flow-recession rate, 50-percent lowest flows, 10-percent highest flows, and storm peaks were 20 percent or less. Much of the error in simulating storm events on an hourly time step can be attributed to uncertainty in the rainfall data. The water-quality component of the model was calibrated using nonpoint-source monitoring data collected in 1998 at one USGS streamflowmeasurement station and other water-quality monitoring data collected at three USGS streamflowmeasurement stations. The period of record for waterquality monitoring was variable at the stations, with an end date of October 1998 but the start date ranging from October 1994 to January 1998. Because of availability, monitoring data for suspended-solids concentrations were used as surrogates for suspendedsediment concentrations, although suspended solids may underestimate suspended sediment and affect apparent accuracy of the suspended-sediment simulation. Comparison of observed to simulated loads for five storms in 1998 at the one nonpoint-source monitoring site at Wooddale, Del., indicates that simulation error commonly is as large as an order of magnitude for suspended sediment and nutrients. The simulation error tends to be smaller for dissolved utrients than particulate nutrients. Errors of 40 percent or less for monthly or annual values indicate a fair to good water-quality calibration according to recommended criteria, with much larger errors possible for individual storm events. Assessment of the accuracy of the water-quality calibration under stormflow conditions is limited by the sparsity of available water-quality data in the basin. Users of the Red Clay Creek HSPF model should be aware of model limitations and consider the following when predictive scenarios are desired: streamflow-duration curves indicate the model simulates stream-flow reasonably well when evaluated over a broad range of conditions and time, although streamflow and the corresponding water quality for individual storm events may not be well simulated; streamflow-duration curves for the simulation period compare well with duration curves for the 57.5-year period ending in 2001 at Wooddale, Del., and include all but the extreme high-flow and low-flow events; calibration for water quality was based on sparse data, with the result of increasing uncertainty in the water-quality simulation.

Water-Resources Investigations Report↗
USGS2003

Spatial variability of sedimentary interbed properties near the Idaho Nuclear Technology and Engineering Center at the Idaho National Engineering and Environmental Laboratory, Idaho

The subsurface at the Idaho National Engineering and Environmental Laboratory (INEEL) is complex, comprised primarily of thick, fractured basalt flows interbedded with thinner sedimentary intervals. The unsaturated zone can be as thick as 200 m in the southwestern part of the INEEL. The Vadose Zone Research Park (VZRP), located approximately 10 km southwest of the Idaho Nuclear Technology and Engineering Center (INTEC), was established in 2001 to study the subsurface of a relatively undisturbed part of the INEEL. Waste percolation ponds for the INTEC were relocated to the VZRP due to concerns that perched water within the vadose zone under the original infiltration ponds (located immediately south of the INTEC) could contribute to migration of contaminants to the Snake River Plain aquifer. Knowledge of the spatial distribution of texture and hydraulic properties is important for developing a better understanding of subsurface flow processes within the interbeds, for example, by identifying low permeability layers that could lead to the formation of perched ground-water zones. Because particle-size distributions are easier to measure than hydraulic properties, particle size serves as an analog for determining how the unsaturated hydraulic properties vary both vertically within particular interbeds and laterally within the VZRP. As part of the characterization program for the subsurface at the VZRP, unsaturated and saturated hydraulic properties were measured on 10 core samples from six boreholes. Bulk properties, including particle size, bulk density, particle density, and specific surface area, were determined on material from the same depth intervals as the core samples, with an additional 66 particle- size distributions measured on bulk samples from the same boreholes. From lithologic logs of the 32 boreholes at the VZRP, three relatively thick interbeds (in places up to 10 m thick) were identified at depths of 35, 45, and 55 m below land surface. The 35-m interbed extends laterally over a distance of at least 900 m from the Big Lost River to the new percolation pond area of the VZRP. Most wells within the VZRP were drilled to depths less than 50 m, making it difficult to infer the lateral extent of the 45-m and 55-m interbeds. The 35-m interbed is uniform in texture both vertically and laterally; the 45-m interbed coarsens upward; and the 55-m interbed contains alternating coarse and fine layers. Seventy-one out of 90 samples were silt loams and 9 out of 90 samples were classified as either sandy loams, loamy sands, or sands. The coarsest samples were located within the 45-m and 55-m interbeds of borehole ICPP-SCI-V-215, located near the southeast corner of the new percolation pond area. At the tops of some interbeds, baked-zone intervals were identified by their oxidized color (yellowish red to red) compared to the color of the underlying non-baked material (pale yellow to brown). The average geometric mean particle diameter of baked-zone intervals was only slightly coarser, in some cases, than the underlying non-baked sediment. This is likely due to both depositional differences between the top and bottom of the interbeds and the presence of small basalt clasts in the sediment. Core sample hydraulic properties from baked zones within the different interbeds did not show effects from alteration caused during basalt deposition, but differed mainly by texture. Saturated hydraulic conductivities (Ksat) for the 10 core samples ranged from 10-7 to 10-4 cm/s. Low permeability layers, with Ksat values less than 10-7 cm/s, within the 35-m and 45-m interbeds may cause perched ground-water zones to form beneath the new percolation pond area, leading to the possible lateral movement of water away from the VZRP.

Idaho↗