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Iron photoreduction and oxidation in an acidic mountain stream

In a small mountain stream in Colorado that receives acidic mine drainage, photoreduction of ferric iron results in a well-defined increase in dissolved ferrous iron during the day. To quantify this process, an instream injection of a conservative tracer was used to measure discharge at the time that each sample was collected. Daytime production of ferrous iron by photoreduction was almost four times as great as nighttime oxidation of ferrous iron. The photoreduction process probably involves dissolved or colloidal ferric iron species and limited interaction with organic species because concentrations of organic carbon are low in this stream.

Science↗

40Ar/39Ar age of the Lathrop Wells volcanic center, Yucca Mountain, Nevada

Paleomagnetic and 40 Ar/ 39 Ar analyses from the Lathrop Wells volcanic center, Nevada, indicate that two eruptive events have occurred there. The ages (136 ± 8 and 141 ± 9 thousand years ago) for these two events are analytically indistinguishable. The small angular difference (4.7°) between the paleomagnetic directions from these two events suggests they differ in age by only about 100 years. These ages are consistent with the chronology of the surficial geological units in the Yucca Mountain area. These results contradict earlier interpretations of the cinder-cone geomorphology and soil-profile data that suggest that at least five temporally discrete eruptive events occurred at Lathrop Wells approximately 20,000 years ago.

Nevada↗

Hercynian I-type and S-type granitoids from the Slavonian mountains (southern Pannonian Basin, northern Croatia)

Two genetically different groups of Hercynian granitoids occur in the Slavonian Mountains which are included in the southern Pannonian Basin. I-type granitoids occur in Barrovian-type progressive metamorphic sequences which originated during the Hercynian orogeny from the Late Silurian to Lower Carboniferous magmatic-sedimentary complex. S-type granitoids, enriched in incompatible trace elements, are accompanied by penecontemporaneous migmatites which originated from rocks of the same progressive metamorphic sequences and lower continental crust. I-type granitoids are represented mostly by granodiorite and monzogranite impoverished in incompatible trace elements, with rare diorite and monzodiorite and basic to intermediate rocks. Hercynian age of the crystalline rocks is supported by numerous K-Ar, 40Ar-39Ar and Rb-Sr measurements carried out mostly on monomineralic concentrates. About 20 representative samples of S-type and I-type granites and associated rocks were selected from over 1000 samples and analyzed in detail for major and trace elements, including REE, Sr and O isotopic compositions; microprobe chemical composition of the main rock-forming minerals was determined. Although most major and trace element diagrams do not provide the best genetic discrimination between the Slavonian granitoids, Sr and O isotope composition, REE data and some other data for the S-type granitoids are indicative of their sedimentary and continental crust source, whereas the I-type granitoids were derived by partial melting of the upper mantle with slight crustal contamination.

Slavonian mountains, southern Pannonian Basin↗

Diatom floras in lakes in the Ruby Mountains and East Humboldt Range, Nevada, USA: A tool for assessing high-elevation climatic variability

Local conditions, including lake size, depth, bathymetric profile, watershed characteristics, and timing and extent of ice cover determine the characteristics of diatom floras, and how those assemblages respond to short and long-term changes in climate. The diatom assemblages from fourteen sediment samples collected from marginal and profundal zones of seven lakes in the Ruby Mountains and East Humboldt Range of northeastern Nevada are characterized in order to identify the factors affecting controlling species diversity, equitability, and assemblage structure. Principle component analysis delineates three depth-controlled diatom assemblages: shallow (~1), medium (~11 m), and deep (>12 m). The shallowest samples are characterized by a diverse benthic assemblage, the medium depth sample is dominated by small fragilarioid taxa, and, the deepest samples, while not dominated by planktonic species, show an increase in their abundance. In general, diatom assemblages in shallower samples exhibit higher diversity and greater equitability.

Nevada↗

Age and evolution of the Precambrian crust of the Tobacco Root Mountains, Montana

U-Pb analyses of zircons from gneisses, anatectic leucosome, metasedimentary rocks, and a younger (metamorphosed) mafic dike from the Tobacco Root Mountains of southwestern Montana document a Precambrian history that extends from at least 3.90–1.77 Ga. The oldest U-Pb age reported here (3.8 Ga) is from a detrital zircon from a quartzite within the Spuhler Peak Metamorphic Suite, although younger ages of clearly detrital grains suggest the protolith was deposited subsequent to 3.2 Ga. Alternatively, a Pb-Pb age of ca. 2.45 Ga from a single subhedral zircon from this quartzite suggests the quartzite, and perhaps other Spuhler Peak Metamorphic Suite lithologies, may have formed in the Proterozoic. An Archean age, however, seems most compatible with the Archean Sm-Nd model ages of mafic and metasedimentary components of the Spuhler Peak Metamorphic Suite and the age distribution of zircons from the quartzite, which is very similar to the age distribution present in Archean quartzites in the region. The Spuhler Peak Metamorphic Suite lies in tectonic contact with volumetrically dominant, Archean, quartzofeldspathic gneisses and intercalated metasedimentary rocks. The protoliths of these gneisses were apparently emplaced 3.2–3.4 Ga, and are interpreted to be the basement upon which the intercalated (meta)sedimentary rocks were deposited. U-Pb analyses of zircons from anatectic leucosome near the boundary between the gneisses and the Spuhler Peak Metamorphic Suite, however, yield a significant population of 1.77 Ga grains, which are interpreted to have crystallized from the leucosome. All other grains are Archean (to 3.48 Ga) and interpreted to derive from the metasedimentary source of the leucosome. In addition, U-Pb analyses of zircons extracted from a granulite facies mafic dike that cuts across Archean gneissic banding indicate the dike was intruded at 2.06 Ga, but reached granulite facies at 1.76 Ga. Structural, petrologic, and geochronologic data suggest all lithologies experienced granulite facies metamorphism at ca. 1.77 Ga and that the Spuhler Peak Metamorphic Suite was tectonically emplaced after 2.06 Ga, but before 1.77 Ga. This Paleoproterozoic tectonic activity is most likely a result of burial during terrane collision (e.g., the juxtaposition of the Wyoming and Hearne provinces) and/or to postcollisional mafic underplating.

Montana↗

Middle Jurassic Topawa group, Baboquivari Mountains, south-central Arizona: Volcanic and sedimentary record of deep basins within the Jurassic magmatic arc

Among supracrustal sequences of the Jurassic magmatic arc of the southwestern Cordillera, the Middle Jurassic Topawa Group, Baboquivari Mountains, south-central Arizona, is remarkable for its lithologic diversity and substantial stratigraphic thickness, ???8 km. The Topawa Group comprises four units (in order of decreasing age): (1) Ali Molina Formation-largely pyroclastic rhyolite with interlayered eolian and fluvial arenite, and overlying conglomerate and sandstone; (2) Pitoikam Formation-conglomerate, sedimentary breccia, and sandstone overlain by interbedded silt- stone and sandstone; (3) Mulberry Wash Formation-rhyolite lava flows, flow breccias, and mass-flow breccias, with intercalated intraformational conglomerate, sedimentary breccia, and sandstone, plus sparse within-plate alkali basalt and comendite in the upper part; and (4) Tinaja Spring Porphyry-intrusive rhyolite. The Mulberry Wash alkali basalt and comendite are genetically unrelated to the dominant calcalkaline rhyolite. U-Pb isotopic analyses of zircon from volcanic and intrusive rocks indicate the Topawa Group, despite its considerable thickness, represents only several million years of Middle Jurassic time, between approximately 170 and 165 Ma. Sedimentary rocks of the Topawa Group record mixing of detritus from a minimum of three sources: a dominant local source of porphyritic silicic volcanic and subvolcanic rocks, identical or similar to those of the Topawa Group itself; Meso- proterozoic or Cambrian conglomerates in central or southeast Arizona, which contributed well-rounded, highly durable, polycyclic quartzite pebbles; and eolian sand fields, related to Middle Jurassic ergs that lay to the north of the magmatic arc and are now preserved on the Colorado Plateau. As the Topawa Group evidently represents only a relatively short interval of time, it does not record long-term evolution of the Jurassic magmatic arc, but rather represents a Middle Jurassic "stratigraphic snapshot" of the arc. This particular view of the arc has been preserved primarily because the Topawa Group accumulated in deep intra-arc basins. These nonmarine basins were fundamentally tectonic and extensional, rather than volcano-tectonic, in origin. Evidence from the Topawa Group supports two previous paleogeographic inferences: the Middle Jurassic magmatic arc in southern Arizona was relatively low standing, and externally derived sediment was introduced into the arc from the continent (northeast) side, without appreciable travel along the arc. We speculate that because the Topawa Group intra-arc basins were deep and rapidly subsiding, they became the locus of a major (though probably intermittent) fluvial system, which flowed into the low-standing magmatic arc from its northeast flank. ?? 2005 Geological Society of America.

Special Paper of the Geological Society of America↗

Hornblendes formed during progressive metamorphism of amphibolites, northwest Adirondack Mountains, New York

Hornblendes in amphibolite interlayers in the paragneiss of the northwest Adirondack Mountains undergo systematic changes in color, composition, and density during progressive metamorphism from almandine- amphibolite to hornblende -granulite facies. In contrast, indices of refraction of the hornblendes remain about constant. In the almandine- amphibolite facies the amphibolite layers have the bulk composition of a saturated basalt and consist of bluish-green hornblende , andesine, and quartz. As these layers are traced into the hornblende -granulite facies, their composition undergoes a progressive change to that of an olivine basalt with brownish-green hornblende , clinopyroxene and orthopyroxene, and calcic andesine as major constituents. Compositional changes in the hornblendes with increasing grade of metamorphism include increases in Ti, Na, K, Cr, V, and Sc. Decreases occur in the amounts of Mn, Zn, OH + F + Cl, and in the ratios Fe 2 O 3 /FeO and Fe/Mg. Density of the hornblendes increases from 3.260 to 3.278 with the increasing grade of metamorphism . These changes in the hornblendes with increasing T and P, although well denned, are less pronounced than those measured in biotites and garnets of the enclosing paragneiss. Large variations in the physical and chemical properties of hornblendes in metamafic rocks reconstituted above the epidote- amphibolite facies appear to be induced principally by critical changes in the bulk composition of the total rock, and not by the regional gradients in T, P, or by changes in kind, or composition, of the coexisting minerals.

New York↗

Isotopic ages of minerals from granitic rocks of the central Sierra Nevada and Inyo Mountains, California

Potassium-argon ages of biotite and hornblende from specimens of 17 granitic plutons in the central Sierra Nevada and the western Inyo Mountains, California, range from 69 to 183 m. y. The Mount Givens, Lamarck. and Round Valley Peak Granodiorites and related younger and more felsic quartz monzonites represent a pulse of magma emplaced in the general time interval of 80-90 million years ago, during Cretaceous time. Mineral ages of granitic rocks that flank these plutons on both the east and the west have been reduced during the emplacement of the Cretaceous intrusive rocks and are minimum ages for the time of crystallization. The ages of hornblende from the Tinemaha Granodiorite (150 to 180 m. y.) may approach crystallization dates. In conjunction with ages for other intrusive rocks in the Sierra Nevada and adjacent desert ranges they strongly suggest a magmatic episode during the Early Jurassic.

California↗

Stratigraphy and heavy minerals of the bays formation, Bays Mountain synclinorium, northeast Tennessee

The Bays Mountain synclinorium is in the Valley and Ridge province in northeast Tennessee , southwest of Kingsport and west of Greeneville. The more clastic part of the Bays formation lies in the east section of the synclinorium . The thickness of the Bays decreases from about 870 feet on the east to about 600 feet on the west. Presumably, the red beds and primary features of the Bays formation formed under deltaic conditions. A Camarocladia Zone near its base indicates a time-transgression of the Bays . The Bays is older at the base to the east than at its base to the west. The heavy minerals of the Bays were compared with those of the Cambrian and Precambrian(?) sediments, volcanic rocks, and accessory minerals of the crystalline complex which now comprise the Blue Ridge. The minerals identified include nearly all those in the Cambrian and Precambrian(?) sediments as well as additional minerals not found in these older sediments but that are in the crystalline complex. Such minerals indicate that at least a part of the crystalline complex was above sea level during the Middle Ordovician.

Tennessee↗

Structure, metamorphism, and plutonism in the south-central Klamath Mountains, California

In the south-central Klamath Mountains 50 miles of the the north-trending central metamorphic belt and adjacent parts of the eastern Paleozoic and western Paleozoic and Triassic belts have been mapped and studied in detail. Within the central metamorphic belt a sequence of three lithologically distinctive metamorphic units has been recognized (from bottom to top): (1) siliceous metasedimentary rocks and greenstones of the Stuart Fork Formation; (2) the Salmon Hornblende Schist; and (3) siliceous, calcareous, and amphibolitic rocks, predominantly metasedimentary, of the Grouse Ridge Formation. The age of these metamorphic rocks is uncertain; they are known only to predate intrusion of Late Jurassic (Nevadan) granitic rocks. Ultramafic rocks, mainly alpine-type peridotites, were emplaced before the granitic rocks and occur primarily in a single large sheetlike body which separates the central metamorphic belt from the eastern Paleozoic belt. Granitic plutons, including quartz diorites, trondhjemites, granodiorites, diorites, and gabbros, in decreasing order of abundance, range in size from less than 1 to about 80 square miles in area. Two orogenic phases in the central metamorphic belt have been distinguished by structural and textural features. A late deformation uniformly affected the metamorphic terrane and the ultramafic rocks but predated granitic rocks. It was accompanied by some metamorphism in the lower to middle greenchist facies and produced upright folds that trend south and plunge gently. An earlier phase affected the various rock units differentially; it produced widespread recumbent folding and upper greenschist- to amphibolite-facies metamorphism in Salmon and Grouse Ridge rocks, but involved the underlying Stuart Fork Formation less severely, producing at least local recumbent folding and lower greenschist-facies metamorphism. The preferred interpretation of this upward increase in structural complexity and metamorphic grade is that the Salmon-Grouse Ridge sequence is a thrust sheet which overrode the Stuart Fork rocks concurrently with emplacement of the ultramafic rocks during the culmination of early recumbent folding and metamorphism. Thrusting was then followed by upright folding during the waning stages of regional metamorphism. The first deformational phase, and possibly the second, occurred during late Paleozoic time as indicated by recent isotopic ages of Salmon Hornblende Schist.

California↗

Carbon isotopes in pelites of the Precambrian Uncompahgre Formation, Needle Mountains, Colorado

Carbon isotopic ratios and weight percentages of carbon were measured in 15 samples of slate, phyllite, and schist of the approximately 1500- to 1600-m.y.-old Uncompahgre Formation of the Needle Mountains, southwestern Colorado. Rocks with less than 1 percent total carbon, all of which is reduced, have δC 13 values of −23 to −28 per mil, whereas those with 1 to 6.4 percent carbon have δC 13 from −29 to −31 per mil. In general, the slates and phyllites contain more carbon and isotopically lighter carbon than do the schists of higher metamorphic rank. Increasing loss of C 12 -enriched methane with increasing intensity of metamorphism is suggested to account for these differences.

Colroado↗

Faulting in the Burro Mountain area, California Coast Ranges, and its relation to the Nacimiento fault

The northwest-striking Nacimiento fault, in the southern Coast Ranges of California, has generally been regarded as the boundary between two major structural blocks: the Nacimiento block to the southwest, in which the basement rocks belong to the Franciscan Formation (Upper Jurassic to Upper Cretaceous), and the Salinian block to the northeast, in which the basement rocks are granitic and high-grade metamorphic. It has been found, however, that in the Burro Mountain area of the southern Santa Lucia Range, the “Nacimiento” fault of Jennings (1959) is nearly vertical and is within the Nacimiento block. In this area, the Franciscan Formation crops out northeast of the “Nacimiento” fault through windows in an older, low-angle thrust fault that brings the Asuncion Group of Taliaferro (1943) (Upper Cretaceous) over the Franciscan Formation. The fault boundary between the Nacimiento and the Salinian blocks must therefore lie farther to the northeast, where it may be buried beneath the Asuncion Group and younger strata. This conclusion is supported by Hanna's recent aeromagnetic work (1969).

California↗

Thermal infrared investigations, Arbuckle Mountains, Oklahoma

Thermal-infrared images obtained on flights over the Tishomingo anticline and South Flank areas near Mill Creek in the Arbuckle Mountains, Oklahoma, were used to study the possibility of identifying some common rock types from their diagnostic reflection and emission characteristics, and to evaluate the usefulness of infrared images in structural geologic investigations. The areas flown are underlain by folded and faulted Paleozoic dolomite, limestone, sandstone, shale, and Precambrian granite. Images were obtained at 6:00 a.m., 11:00 a.m., and 2:00 p.m. The predawn (6:00 a.m.) image is the most useful in distinguishing rock types. Of particular interest is a thermal contrast of dolomite (warm) and limestone (cool), sufficient to distinguish those rock types and to reveal facies changes between them. Theoretical considerations indicate that this thermal contrast arises from a combination of albedo and thermal-inertia characteristics distinctive of dolomites and limestones in many areas. The daytime images display much stratigraphic and structural detail. Small-scale bedding detail is enhanced in the morning images of low-relief areas, and contrasts of alternating formations that form hogbacks and valleys are enhanced in the afternoon images of higher relief areas. The difference in features displayed in morning and afternoon images appears to be a function of the insolation on sunward and shadowed slopes of differing scale. Fault or fracture zones are best displayed in the predawn image; they appear cooler than surrounding ground, because of greater water content and concomitant evaporation. The abundance and throughgoing nature of lineaments (which coincide for the most part with joint systems) are more obvious in the infrared images than in aerial photographs. Lineaments striking northwest are preferentially enhanced in the morning images, and lineaments striking northeast are preferentially shown in the afternoon images. This enhancement cannot be ascribed to the effects of topography, insolation, or wind; it may relate to a combination of ground-water and vegetation effects.

Oklahoma↗

Relations of folded dikes and Precambrian polyphase deformation, Gardner Lake area, Beartooth Mountains, Wyoming

Two cross-cutting mafic dikes in the headwall of Gardner Lake in the eastern Beartooth Mountains, Wyoming, have structural relations with Archean migmatite and gneiss that suggest intrusion between deformational phases recognized in the eastern part of the range. Fabric data show that the older dike, an orthoamphibolite, was emplaced subsequent to the F 1 deformational event, but prior to the main episode of metamorphism, metasomatism, and folding, F 2 . The younger dike, a metanorite, was intruded after F 2 , but is folded by west-trending, open F 3 folds. The style and general trend of these F 3 folds are consistent with those observed elsewhere in the eastern part of the range. The data available and absolute age relations in other parts of the range indicate that F 2 occurred 2750 m.y. ago and F 3 1600 to 1800 m.y. ago.

Wyoming↗

Paleozoic metasediments in the northern Ruby Mountains, Nevada

New evidence indicates that high-grade regionally metamorphosed marble and quartzite in the northern Ruby Mountains are Paleozoic strata. Correlation is based on a match of the lithologic sequence to strata of Cambrian to Devonian age in nearby areas; particularly diagnostic is a brown dolomite at the base of the Cambrian carbonate sequence. The metamorphic complex contrasts with unmetamorphosed terranes exposed in nearby areas, and apparently formed in the Mesozoic as part of a metamorphic infrastructure.

Nevada↗

Thrust and strike-slip faulting in the Plomosa Mountains, southwestern Arizona

Thrust and strike-slip faulting are recognized in the Plomosa Mountains, southwestern Arizona. The distribution of rock types and the geometry of the thrust faults necessitate that the upper plate moved from east to west. The amount of displacement is not known, but is considered to be large. Apparent separations along the strike-slip faults are in a right-lateral sense and are greater than 19,000 ft. Rhyodacite flows, dated by K-Ar methods at 19 to 20 m.y., unconformably overlie the thrust faults and are cut by the strike-slip faults.

Arizona↗

Radiometric ages of intrusive rocks in the Little Belt Mountains, Montana

Radiometric ages indicate that most, if not all, of the major intrusions in the Little Belt Mountains, central Montana, were emplaced during the Eocene epoch, between 48 and 54 m.y. ago. In the Hughesville area, igneous activity continued, or was episodic until 42 m.y. ago. As a result of the continued igneous activity, radiometric ages in the Hughesville area can be interpreted either as primary ages or as reset ages.

Montana↗

Lead isotope systematics and uranium depletion in the Granite Mountains, Wyoming

Isotopic composition and concentration of lead in whole rock and microcline and concentration of uranium and thorium in whole-rock samples of granite from the Granite Mountains, Wyoming, have been determined. The lead isotopic composition in the whole rocks was found to be highly radiogenic with a range in Pb 206 /Pb 204 of 19.58 to 42.27; the corresponding range in microclines is 15.39 to 22.44. A Pb 206 /Pb 204 versus Pb 207 /Pb 204 plot of the whole-rock data yields an apparent isochron age of 2,790 ± 80 m.y. as the time of crystallization of the granite. Chemically determined values of U 238 /Pb 204 in the whole rocks lie between 3.3 and 18.4 and are too low to account for the amount of radiogenic lead observed. A material balance of lead, thorium, and uranium components indicates that an average of approximately 75 percent of the amount of uranium required to produce the radiogenic lead was removed from the rocks, whereas, on the average, there was no apparent loss of thorium. Loss of uranium from the granite is demonstrated to extend at least to a depth of 165 ft in a drill core. The average uranium loss from the samples analyzed represents about 20 g uranium per 1,000 kg of rock that apparently was removed during the Cenozoic and that probably constitutes the major source of uranium now in ore deposits in central Wyoming basins. The lead isotopic composition of the microclines indicates that lead was mobilized within the granite and was isolated in the feldspar during a thermal event about 1,640 + 120 m.y. ago. However, there is no evidence that the whole rocks themselves became open systems at that time. Whole-rock and microcline isochrons intersect at Pb 206 /Pb 204 and Pb 207 /Pb 204 of 13.77 and 14.86, respectively, indicating a characteristic U 238 /Pb 204 of 8.96 in the source region of the granite magma.

Wyoming↗