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At least 1,405 records · Page 78Linked to original sources

USGS2024

Geologic constraints on the formation and evolution of Saturn’s mid-sized moons

Saturn’s mid-sized icy moons have complex relationships with Saturn’s interior, the rings, and with each other, which can be expressed in their shapes, interiors, and geology. Observations of their physical states can, thus, provide important constraints on the ages and formation mechanism(s) of the moons, which in turn informs our understanding of the formation and evolution of Saturn and its rings. Here, we describe the cratering records of the mid-sized moons and the value and limitations of their use for constraining the histories of the moons. We also discuss observational constraints on the interior structures of the moons and geologically-derived inferences on their thermal budgets through time. Overall, the geologic records of the moons (with the exception of Mimas) include evidence of epochs of high heat flows, short- and long-lived subsurface oceans, extensional tectonics, and considerable cratering. Curiously, Mimas presents no clear evidence of an ocean within its surface geology, but its rotation and orbit indicate a present-day ocean. While the moons need not be primordial to produce the observed levels of interior evolution and geologic activity, there is likely a minimum age associated with their development that has yet to be determined. Uncertainties in the populations impacting the moons makes it challenging to further constrain their formation timeframes using craters, whereas the characteristics of their cores and other geologic inferences of their thermal evolutions may help narrow down their potential histories. Disruptive collisions may have also played an important role in the formation and evolution of Saturn’s mid-sized moons, and even the rings of Saturn, although more sophisticated modeling is needed to determine the collision conditions that produce rings and moons that fit the observational constraints. Overall, the existence and physical characteristics of Saturn’s mid-sized moons provide critical benchmarks for the development of formation theories.

Space Science Reviews↗

USGS2017

Regional acidification trends in Florida shellfish estuaries: A 20+ year look at pH, oxygen, temperature, and salinity

Increasing global CO 2 and local land use changes coupled with increased nutrient pollution are threatening estuaries worldwide. Local changes of estuarine chemistry have been documented, but regional associations and trends comparing multiple estuaries latitudinally have not been evaluated. Rapid climate change has impacted the annual and decadal chemical trends in estuaries, with local ecosystem processes enhancing or mitigating the responses. Here, we compare pH, dissolved oxygen, temperature, and salinity data from 10 Florida shellfish estuaries and hundreds of shellfish bed stations. Over 80,000 measurements, spanning from 1980 to 2008, taken on Atlantic Ocean and West Florida coast showed significant regional trends of consistent pH decreases in 8 out of the 10 estuaries, with an average rate of decrease on the Gulf of Mexico side estuaries of Florida of 7.3 × 10 −4 pH units year −1 , and average decrease on the Atlantic Coast estuaries of 5.0 × 10 −4 pH units year −1 . The rates are approximately 2–3.4 times slower than observed in pH decreases associated with ocean acidification in the Atlantic and Pacific. Other significant trends observed include decreasing dissolved oxygen in 9 out of the 10 estuaries, increasing salinity in 6 out of the 10, and temperature increases in 3 out of the 10 estuaries. The data provide a synoptic regional view of Florida estuary trends which reflect the complexity of changing climate and coastal ocean acidification superimposed on local conditions. These data provide context for understanding, and interpreting the past and predicting future of regional water quality health of shellfish and other organisms of commercial and ecological significance along Florida’s coasts.

Estuaries and Coasts↗

USGS1987

Thermal evolution of a differentiated Ganymede and implications for surface features

Thermal evolution models are presented for Ganymede, assuming a mostly differentiated initial state of a water ocean overlying a rock layer. The only heat sources are assumed to be primordial heat (provided by accretion) and the long-lived radiogenic heat sources in the rock component. As Ganymede cools, the ocean thins, and two ice layers develop, one above composed of ice I, and the other below composed of high-pressure polymorphs of ice. Subsolidus convection proceeds separately in each ice layer, its transport of heat calculated using a simple parameterized convection scheme and the most recent data on ice rheology. The model requires that the average entropy of the deep ice layer exceeds that of the ice I layer. If the residual ocean separating these layers becomes thin enough, then a Rayleigh-Taylor-like (“diapiric”) instability may ensue, driven by the greater entropy of the deeper ice and merging the two ice mantles into a single convective layer. This instability is not predicted by linear analysis but occurs for plausible finite amplitude perturbations associated with large Rayleigh number convection. The resulting warm ice diapirs may lead to a dramatic “heat pulse” at the surface and to fracturing of the lithosphere, and may be directly or indirectly responsible for resurfacing and grooved terrain formation on Ganymede. The timing of this event depends rather sensitively on poorly known rheological parameters, but could be consistent with chronologies deduced from estimated cratering rates. Irrespective of the occurrence or importance of the heat pulse, we find that lithospheric fracturing requires rapid stress loading (on a time scale ⪅10 4 years). Such a time scale can be realized by warm ice diapirism, but not directly by gradual global expansion. In the absence of any quantitative and self-consistent model for the resurfacing of Ganymede by liquid water, we favor resurfacing by warm ice flows, which we demonstrate to be physically possible, a plausible consequence of our models, compatible with existing observations, and a hypothesis testable by Galileo. We discuss core formation as an alternative driver for resurfacing, and conclude that it is less attractive. We also consider anew the puzzle of why Callisto differs so greatly from Ganymede, offering several possible explanations. The models presented do not provide a compelling explanation for all aspects of Ganymedean geological evolution, since we have identified several potential problems, most notably the apparently extended period of grooved terrain formation (several hundred million years), which is difficult to reconcile with the heat pulse phenomenon.

Icarus↗

USGS1990

Sediment thickness in the southern Canada Basin

Multichannel seismic reflection data are used, in conjunction with deep crustal seismic refraction data, to estimate the thickness of sediments in the southern Canada Basin of the Arctic Ocean north of Alaska. The sediments are interpreted to be of Hauterivian (mid-Early Cretaceous) to Holocene age. Comparison of the seismic reflection character of seismic reflections in the study area with that in other basins indicates that a base-of-sediment—top of oceanic layer 2 reflection is not present above the depth at which the water-bottom multiple obscures all deeper arrivals, which is in conflict with the conclusions drawn from aeromagnetic, refraction, and other reflection studies. Seismic velocity structure, determined from the reflection data, indicates that the reflections above the multiple are from sedimentary strata. In the absence of seismic reflection evidence for the top of layer 2 above the multiple, we estimate total sediment thickness by using the layer 3 refractions and subtracting an average assumed layer 2 thickness from the top of layer 3. Assuming that an average thickness of oceanic layer 2 (1.4 km) overlies layer 3 in the southern Canada Basin, sediment thickness in the study area is estimated to range between 6.5 km where water depth is 3.8 km to greater than 11 km where the water depth is 2 km. This is nearly double that of any previous estimates and should have a significant effect on calculations such as the age of Canada Basin, regional heat flow, and long-term sedimentation rates.

Marine Geology↗

USGS2017

New evidence for the age of the Gubik Formation Alaskan North Slope

At several Alaskan North Slope localities south of the shore of the Arctic Ocean the Gubik Formation, herein regarded as latest Pliocene and Pleistocene in age, contains a marine unit at its base. Near Ocean Point and near Teshekpuk Lake this basal unit, or the lowest exposed marine unit, of the Gubik contains unusual, relatively warm-water marine mammals. Although these mammals have poorly known fossil histories, consideration of what is known suggests that the basal marine unit near Ocean Point is of latest Pliocene age, between 2.2 and 1.7 my old, and that the marine unit near Teshekpuk Lake is probably late Pleistocene, most likely correlating with the Sangamon Interglaciation and about 120,000 yr old. ?? 1983.

Quaternary Research↗

USGS1979

CDP seismic sections of the western Beaufort continental margin

The continental rise, slope, and shelf in the Beaufort Sea off northern Alaska were surveyed with 5600 km of common-depth-point (CDP) seismic data by the U.S. Geological Survey in 1977. The lower continental rise consists of a wedge of at least 4.5 km of low-velocity, generally flat-lying, parallel-bedded sediments. Slump-related diapiric folds, probably cored by shale, occur on the upper rise and lower slope. The observed minimum depth to oceanic basement in the Canada Basin requires an age for this basin of at least 120 m.y., assuming it to be floored by oceanic crust with a subsidence history similar to that of the Atlantic and Pacific oceans.

Alaska↗

USGS1990

Continental extension, magmatism and elevation; formal relations and rules of thumb

To investigate simplified relations between elevation and the extensional, magmatic and thermal processes that influence lithosphere buoyancy, we assume that the lithosphere floats on an asthenosphere of uniform density and has no flexural strength. A simple graph relating elevation to lithosphere density and thickness provides an overview of expectable conditions around the earth and a simple test for consistency of continental and oceanic lithosphere models. The mass-balance relations yield simple general rules for estimating elevation changes caused by various tectonic, magmatic and thermal processes without referring to detailed models. The rules are general because they depend principally on buoyancy, which under our assumptions is specified by elevation, a known quantity; they do not generally require a knowledge of lithosphere thickness and density. The elevation of an extended terrain contains important information on its tectonic and magmatic history. In the Great Basin where Cenozoic extension is estimated to be 100%, the present high mean elevation ( ~ 1.75 km) probably requires substantial low-density magmatic contributions to the extending lithosphere. The elevation cannot be reasonably explained solely as the buoyant residue of a very high initial terrane, or of a lithosphere that was initially very thick and subsequently delaminated and heated. Even models with a high initial elevation typically call for 10 km or so of accumulated magmatic material of near-crustal density. To understand the evolution of the Great Basin, it is important to determine whether such intruded material is present; some could replenish the stretching crust by underplating and crustal intrusion and some might reside in the upper mantle. The elevation maintained or approached by an intruded extending lithosphere depends on the ratio B of how fast magma is supplied from the asthenosphere ( b km/Ma) to how fast the lithosphere spreads the magma out by extension (γ Ma −1 ). For a surface maintained 212km below sea level (e.g., an ocean ridge) B is about 5 km; for continental extension the ratio may be much greater. The frequent association of volcanism with continental extension, the high elevation (and buoyancy) of some appreciably extended terrains, and the oceanic spreading analog all suggest that magmatism may play an important role in continental extension. Better estimates of total extension and elevation change in extended regions can help to identify that role.

Tectonophysics↗

USGS1994

Comparison of 14C ages of hydrothermal petroleums

In order to set limits on the time frame of formation of hydrothermal petroleum, we have obtained 14 C ages on samples from three diverse regions; Gulf of California (Guaymas Basin), Northeast Pacific Ocean (Escanaba Trough and Middle Valley), and the East African Rift (Tanganyika Trough). The results date the source of carbon and therefore provide maximum ages for the formation and emplacement of the hydrothermal petroleums. The youngest petroleum occurs iin the Souther Trough of Guaymas Basin (3200–6600 yr, mean 4692 yr); in the Northern Trough the petroleum is slightly older (7400 yr). Significantly older hydrothermal petroleum occurs in Escanaba Trough (17,000 yr) and Middle Valley (29,000 yr). A continental example from the East African Rift has an age of 25,000 yr, comparable to the ages observed in the oceanic samples from the Northeast Pacific Ocean. These ages affirm that hydrothermal petroleum formation is a very rapid process and took place some time between the latest Pleistocene and the present in these active hydrothermal systems.

Organic Geochemistry↗

USGS1986

Pb-, Sr- and Nd-Isotopic systematics and chemical characteristics of cenozoic basalts, Eastern China

Forty-eight Paleogene, Neogene and Quaternary basaltic rocks from northeastern and east-central China have been analyzed for major-element composition, selected trace-element contents, and Pb, Sr and Nd isotopic systematics. The study area lies entirely within the marginal Pacific tectonic domain. Proceeding east to west from the continental margin to the interior, the basalts reveal an isotopic transition in mantle source material and/or degree of crustal interaction. In the east, many of the rocks are found to merge both chemically and isotopically with those previously reported from the Japanese and Taiwan island-arc terrains. In the west, clear evidence exists for component(s) of Late Archean continental lithosphere to be present in some samples. A major crustal structure, the Tan-Lu fault, marks the approximate boundary between continental margin and interior isotopic behaviors. Although the isotopic signature of the western basalts has characteristics of lower-crustal contamination, a subcrustal lithosphere, i.e. an attached mantle keel, is probably more likely to be the major contributor of their continental “flavor”. The transition from continental margin to interior is very pronounced for Pb isotopes, although Sr and Nd isotopes also combine to yield correlated patterns that deviate strikingly from the mid-ocean ridge basalt (MORB) and oceanic-island trends. The most distinctive chemical attribute of this continental lithosphere component is its diminished U/Pb as reflected in the Pb isotopic composition when compared to sources of MORB, oceanic-island and island-arc volcanic rocks. Somewhat diminished Sm/Nd and elevated Rb/Sr, especially in comparison to the depleted asthenospheric mantle, are also apparent from the Nd- and Sr-isotopic ratios.

Chemical Geology↗

USGS1983

Biochronology and paleoclimatic implications of Middle Eocene to Oligocene planktic foraminiferal faunas

Planktic foraminiferal assemblages have been analyzed quantitatively in six DSDP sites in the Atlantic (Site 363), Pacific (Sites 292, 77B, 277), and Indian Ocean (Sites 219, 253) in order to determine the nature of the faunal turnover during Middle Eocene to Oligocene time. Biostratigraphic ranges of taxa and abundance distributions of dominant species are presented and illustrate striking similarities in faunal assemblages of low latitude regions in the Atlantic, Pacific and Indian oceans. A high resolution biochronology, based on dominant faunal characteristics and 55 datum events, permits correlation between all three oceans with a high degree of precision. Population studies provide a view of the global impact of the paleoclimatic and paleoceanographic changes occurring during Middle Eocene to Oligocene time. Planktic foraminiferal assemblage changes indicate a general cooling trend between Middle Eocene to Oligocene time, consistent with previously published oxygen isotope data. Major faunal changes, indicating cooling episodes, occur, however, at discrete intervals: in the Middle Eocene 44-43 Ma (P13), the Middle/Late Eocene boundary 41-40 Ma (P14/P15), the Late Eocene 39-38 Ma (P15/P16), the Eocene/Oligocene boundary 37-36 Ma (P18), and the Late Oligocene 31-29 Ma (P20/P21). With the exception of the E/0 boundary, faunal changes occur abruptly during short stratigraphic intervals, and are characterized by major species extinctions and first appearances. The Eocene/Oligocene boundary cooling is marked primarily by increasing abundances of cool water species. This suggests that the E/0 boundary cooling, which marks a major event in the oxygen isotope record affected planktic faunas less than during other cooling episodes. Planktic foraminiferal faunas indicate that the E/0 boundary event is part of a continued cooling trend which began during the Middle Eocene. Two hiatus intervals are recognized in low and high latitude sections at the Middle/Late Eocene boundary and in the Late Eocene (P15/P16). These hiatuses suggest that vigorous bottom water circulation began developing in the Middle Eocene, consistent with the onset of the faunal cooling trend, and well before the development of the psychrosphere at the E/0 boundary.

Marine Micropaleontology↗

USGS2021

Foraging in marine habitats increases mercury concentrations in a generalist seabird

Methylmercury concentrations vary widely across geographic space and among habitat types, with marine and aquatic-feeding organisms typically exhibiting higher mercury concentrations than terrestrial-feeding organisms. However, there are few model organisms to directly compare mercury concentrations as a result of foraging in marine, estuarine, or terrestrial food webs. The ecological impacts of differential foraging may be especially important for generalist species that exhibit high plasticity in foraging habitats, locations, or diet. Here, we investigate whether foraging habitat, sex, or fidelity to a foraging area impact blood mercury concentrations in western gulls ( Larus occidentalis ) from three colonies on the US west coast. Cluster analyses showed that nearly 70% of western gulls foraged primarily in ocean or coastal habitats, whereas the remaining gulls foraged in terrestrial and freshwater habitats. Gulls that foraged in ocean or coastal habitats for half or more of their foraging locations had 55% higher mercury concentrations than gulls that forage in freshwater and terrestrial habitats. Ocean-foraging gulls also had lower fidelity to a specific foraging area than freshwater and terrestrial-foraging gulls, but fidelity and sex were unrelated to gull blood mercury concentrations in all models. These findings support existing research that has described elevated mercury levels in species using aquatic habitats. Our analyses also demonstrate that gulls can be used to detect differences in contaminant exposure over broad geographic scales and across coarse habitat types, a factor that may influence gull health and persistence of other populations that forage across the land-sea gradient.

California, Oregon↗

USGS2011

Characterization of winter foraging locations of Adélie penguins along the Western Antarctic Peninsula, 2001–2002

In accord with the hypotheses driving the Southern Ocean Global Ocean Ecosystems Dynamics (SO GLOBEC) program, we tested the hypothesis that the winter foraging ecology of a major top predator in waters off the Western Antarctic Peninsula (WAP), the Adélie penguin ( Pygoscelis adeliae ), is constrained by oceanographic features related to the physiography of the region. This hypothesis grew from the supposition that breeding colonies in the WAP during summer are located adjacent to areas of complex bathymetry where circulation and upwelling processes appear to ensure predictable food resources. Therefore, we tested the additional hypothesis that these areas continue to contribute to the foraging strategy of this species throughout the non-breeding winter season. We used satellite telemetry data collected as part of the SO GLOBEC program during the austral winters of 2001 and 2002 to characterize individual penguin foraging locations in relation to bathymetry, sea ice variability within the pack ice, and wind velocity and divergence (as a proxy for potential areas with cracks and leads). We also explored differences between males and females in core foraging area overlap. Ocean depth was the most influential variable in the determination of foraging location, with most birds focusing their effort on shallow (<200 m) waters near land and on mixed-layer (200–500 m) waters near the edge of deep troughs. Within-ice variability and wind (as a proxy for potential areas with cracks and leads) were not found to be influential variables, which is likely because of the low resolution satellite imagery and model outputs that were available. Throughout the study period, all individuals maintained a core foraging area separated from other individuals with very little overlap. However, from a year with light sea ice to one with heavy ice cover (2001–2002), we observed an increase in the overlap of individual female foraging areas with those of other birds, likely due to restricted access to the water column, reduced prey abundance, or higher prey concentration. Male birds maintained separate core foraging areas with the same small amount of overlap, showing no difference in overlap between the years. While complex bathymetry was an important physical variable influencing the Adélie penguin's foraging, the analysis of sea ice data of a higher resolution than was available for this study may help elucidate the role of sea ice in affecting Adélie penguin winter foraging behavior within the pack ice.

Deep-Sea Research Part II: Topical Studies in Ocea↗

USGS2016

Trace elements at the intersection of marine biological and geochemical evolution

Life requires a wide variety of bioessential trace elements to act as structural components and reactive centers in metalloenzymes. These requirements differ between organisms and have evolved over geological time, likely guided in some part by environmental conditions. Until recently, most of what was understood regarding trace element concentrations in the Precambrian oceans was inferred by extrapolation, geochemical modeling, and/or genomic studies. However, in the past decade, the increasing availability of trace element and isotopic data for sedimentary rocks of all ages has yielded new, and potentially more direct, insights into secular changes in seawater composition – and ultimately the evolution of the marine biosphere. Compiled records of many bioessential trace elements (including Ni, Mo, P, Zn, Co, Cr, Se, and I) provide new insight into how trace element abundance in Earth's ancient oceans may have been linked to biological evolution. Several of these trace elements display redox-sensitive behavior, while others are redox-sensitive but not bioessential (e.g., Cr, U). Their temporal trends in sedimentary archives provide useful constraints on changes in atmosphere-ocean redox conditions that are linked to biological evolution, for example, the activity of oxygen-producing, photosynthetic cyanobacteria. In this review, we summarize available Precambrian trace element proxy data, and discuss how temporal trends in the seawater concentrations of specific trace elements may be linked to the evolution of both simple and complex life. We also examine several biologically relevant and/or redox-sensitive trace elements that have yet to be fully examined in the sedimentary rock record (e.g., Cu, Cd, W) and suggest several directions for future studies.

Earth-Science Reviews↗

USGS2005

Seasonal variations of alkenones and UK37 in the Chesapeake Bay water column

Alkenone unsaturation indices (UK37 and U K???37) have long been used as proxies for surface water temperature in the open ocean. Recent studies have suggested that in other marine environments, variables other than temperature may affect both the production of alkenones and the values of the indices. Here, we present the results of a reconnaissance field study in which alkenones were extracted from particulate matter filtered from the water column in Chesapeake Bay during 2000 and 2001. A multivariate analysis shows a strong positive correlation between UK37 (and UK???37) values and temperature, and a significant negative correlation between UK37 (and UK???37) values and nitrate concentrations. However, temperature and nitrate concentrations also co-vary significantly. The temperature vs. UK37 relationships (UK37=0.018 (T)-0.162, R2=0.84, UK???37=0.013 (T)-0.04, R2=0.80) have lower slopes than the open-ocean equations of Prahl et al. [1988. Further evaluation of long-chain alkenones as indicators of paleoceanographic conditions. Geochimica et Cosmochimica Acta 52, 2303-2310] and Mu??ller et al. [1998. Calibration of the alkenone paleotemperature index UK???37 based on core-tops from the eastern South Atlantic and the global ocean (60??N-60??S). Geochimica et Cosmochimica Acta 62, 1757-1772], but are similar to the relationships found in controlled studies with elevated nutrient levels and higher nitrate:phosphate (N:P) ratios. This implies that high nutrient levels in Chesapeake Bay have either lowered the UK37 vs. temperature slope, or nutrient levels are the main controller of the U K37 index. In addition, particularly high abundances (>5% of total C37 alkenones) of the tetra-unsaturated ketone, C37:4, were found when water temperatures reached 25??C or higher, thus posing further questions about the controls on alkenone production as well as the biochemical roles of alkenones. ?? 2005 Elsevier Ltd. All rights reserved.

Estuarine, Coastal and Shelf Science↗

USGS2013

The significance of ultra-refracted surface gravity waves on sheltered coasts, with application to San Francisco Bay

Ocean surface gravity waves propagating over shallow bathymetry undergo spatial modification of propagation direction and energy density, commonly due to refraction and shoaling. If the bathymetric variations are significant the waves can undergo changes in their direction of propagation (relative to deepwater) greater than 90° over relatively short spatial scales. We refer to this phenomenon as ultra-refraction. Ultra-refracted swell waves can have a powerful influence on coastal areas that otherwise appear to be sheltered from ocean waves. Through a numerical modeling investigation it is shown that San Francisco Bay, one of the earth's largest and most protected natural harbors, is vulnerable to ultra-refracted ocean waves, particularly southwest incident swell. The flux of wave energy into San Francisco Bay results from wave transformation due to the bathymetry and orientation of the large ebb tidal delta, and deep, narrow channel through the Golden Gate. For example, ultra-refracted swell waves play a critical role in the intermittent closure of the entrance to Crissy Field Marsh, a small restored tidal wetland located on the sheltered north-facing coast approximately 1.5 km east of the Golden Gate Bridge.

California↗

USGS2023

Organohalogenated contaminants in multiple life stages of the Pacific lamprey (Entosphenus tridentatus), Oregon, USA

Pacific lamprey (Entosphenus tridentatus) are ecologically and culturally important anadromous animals native to the West Coast of the United States. Pacific lamprey populations are in decline, and contaminants may be a contributing factor. Between 2017 and 2021, three life stages of Pacific lamprey and collocated sediment samples were collected in Oregon (larval lamprey, sediment, and returning adult lamprey) and off the coast of Oregon and Washington (ocean juvenile lamprey). Tissue and sediment samples were analyzed for 56 organohalogenated compounds that included legacy pesticides, current use pesticides, polybrominated diphenyl ether congeners, and polychlorinated biphenyl congeners. Organohalogenated compounds were detected in all three Pacific lamprey life stages. The organohalogenated compounds detected in collocated sediment and larval lamprey samples were generally dissimilar, and compounds detected in larval lamprey indicate potential point sources along the rivers. Ocean-caught juvenile lamprey had significantly higher lipid contents than returning adult lamprey, but lipid content and concentrations of select compounds were not strongly correlated. Concentrations of select compounds detected in both ocean juvenile and returning adult lamprey were either not significantly different or were higher in returning adult lamprey. Concentrations of some compounds in returning adult lamprey—which are consumed by Indigenous peoples—exceeded state and national human health consumption thresholds. Collaboration among Tribes and public-sector agencies helped make this study successful.

Oregon↗

USGS2008

Using the Model Coupling Toolkit to couple earth system models

Continued advances in computational resources are providing the opportunity to operate more sophisticated numerical models. Additionally, there is an increasing demand for multidisciplinary studies that include interactions between different physical processes. Therefore there is a strong desire to develop coupled modeling systems that utilize existing models and allow efficient data exchange and model control. The basic system would entail model "1" running on "M" processors and model "2" running on "N" processors, with efficient exchange of model fields at predetermined synchronization intervals. Here we demonstrate two coupled systems: the coupling of the ocean circulation model Regional Ocean Modeling System (ROMS) to the surface wave model Simulating WAves Nearshore (SWAN), and the coupling of ROMS to the atmospheric model Coupled Ocean Atmosphere Prediction System (COAMPS). Both coupled systems use the Model Coupling Toolkit (MCT) as a mechanism for operation control and inter-model distributed memory transfer of model variables. In this paper we describe requirements and other options for model coupling, explain the MCT library, ROMS, SWAN and COAMPS models, methods for grid decomposition and sparse matrix interpolation, and provide an example from each coupled system. Methods presented in this paper are clearly applicable for coupling of other types of models. ?? 2008 Elsevier Ltd. All rights reserved.

Environmental Modelling and Software↗

USGS2004

The global variation in the iron isotope composition of marine hydrogenetic ferromanganese deposits: Implications for seawater chemistry?

The iron (Fe) isotope compositions of 37 hydrogenetic ferromanganese deposits from various oceans have been analysed by MC-ICPMS; they permit the construction of a global map of Fe isotopic values. The isotopic compositions range between -1.2 and -0.1??? in ??57FeIRMM14. Averages for the Atlantic and the Pacific are -0.41 and -0.88???, but their standard deviations are identical (0.27, 1 ??) and the data very largely overlap. No correlation is found with Pb or Nd isotope compositions and there is no evidence that the observed oceanic Fe isotopic heterogeneity is directly controlled by variations in continental sources. The small quantities of Fe that can be introduced from hydrothermal sources render as unlikely the possibility that the isotopic variations reflect variable proportions of continental and hydrothermal Fe, as recently proposed. The more likely explanation is that the variations are induced locally within the ocean. The exact sources of fractionation remain unclear. Likely possibilities are the dissolution and reprecipitation processes that liberate Fe from sediments during anoxic events, dissolution in surface waters or processes occurring during growth of the crusts. ?? 2004 Elsevier B.V. All rights reserved.

Earth and Planetary Science Letters↗