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Preferential groundwater discharges along stream corridors are disregarded sources of greenhouse gases

Groundwater delivery of greenhouse gases (GHGs) to stream banks and riparian areas, before mixing with surface waters, has not been well quantified. We measured preferential groundwater delivery of GHGs to stream banks within three stream reaches, and found that stream banks with discharging groundwater emitted more CO 2 and were sources of N 2 O compared to stream banks without actively discharging groundwater, which emitted less CO 2 and were N 2 O sinks. At one of our stream reaches, groundwater CO 2 and N 2 O concentrations were 1.4–19.2 and 1.1–40.6 times higher than those in surface water, respectively, and groundwater delivery rates of CO 2 and N 2 O were 1.5 and 1.6 times higher than surface water emissions per unit area. On average, 21% (range 0%–100%) of CO 2 and N 2 O were emitted at the stream bank before mixing with surface waters. Preferential groundwater GHG emissions may contribute substantially to stream corridor emissions and may be underestimated when using a channel-centric approach to estimate riverine GHG budgets.

JGR Biogeosciences

Estimating groundwater level records using MOVE.1 and computing monthly percentiles from estimated groundwater records in Massachusetts

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, performed record extensions on groundwater levels at select wells using the Maintenance of Variance Extension type 1 (MOVE.1) method. The groundwater levels estimated from these record extensions were used to compute monthly percentiles to improve future determinations of a groundwater index. In Massachusetts, 27 of 29 short-record study wells with continuous groundwater levels between 0.8 and 8.1 years were suitable for record extensions; 37 long-record index wells were used to extend the groundwater level records at the study wells. The index well selected to pair with a study well was chosen based on Pearson correlation coefficient values; cross-correlation between the two wells; geologic and topographic similarity; and smallest distance spanning the wells. Each study well and its corresponding index well have 1 or more years of concurrent, overlapping data; a Pearson correlation coefficient that exceeded a threshold value of 0.8; and a similar aquifer type and hydrologic characteristics. Of the 29 study wells, 2 showed poor correlations with all index wells and were not considered for record extensions. Performance metrics used to assess the accuracy of the MOVE.1 models indicated that most models provided reasonable estimates of groundwater levels. Root mean square error values ranged from 0.097 to 2.292 feet, with a median of 0.536 foot. Nash-Sutcliffe efficiency coefficient values ranged from 0.623 to 0.996, with a median value of 0.759. Generally, study wells in close geographical proximity to their index well resulted in stronger model performance. The average length of groundwater level records was extended by 14.1 years to a new average of 18.1 years. The estimated groundwater level records from the MOVE.1 models resulted in an increase in the range of highest and lowest groundwater levels at 23 of 27 wells. The increase in range of groundwater levels was between 0.08 to 7.95 feet. Monthly percentiles for State drought indices were computed from the estimated MOVE.1 records and observed records through December 31, 2021. Percentiles computed from estimated records show an average groundwater level about 1.0 foot lower than observed data at the 2d percentile and 0.1 foot lower at the 30th percentile.

Massachusetts

Hydrogeologic framework and conceptual model of the Red River alluvial aquifer east of Lake Texoma, southeastern Oklahoma, 1980–2022

The 1973 Oklahoma Groundwater Law (Oklahoma Statutes §82-1020.5) requires that the Oklahoma Water Resources Board conduct hydrologic investigations of the State’s groundwater basins to support a determination of the maximum annual yield for each groundwater basin. At present (2025), the Oklahoma Water Resources Board has not established a maximum annual yield for the Red River alluvial aquifer east of Lake Texoma. To support the evaluation and determination of a maximum annual yield, a hydrogeologic framework and conceptual groundwater-flow model were developed to assess groundwater availability in the Red River alluvial aquifer east of Lake Texoma. The scope of this hydrologic investigation is the alluvium and terrace containing the Red River alluvial aquifer in Oklahoma between Lake Texoma, the Texas State line, and the Arkansas State line, an extent referred to in this report as “the eastern part of the Red River alluvial aquifer.” Parts of the alluvium and terrace extent in Arkansas and Texas are included in some analyses to address hydrologic influences from outside the aquifer’s boundaries in Oklahoma. The eastern part of the Red River alluvial aquifer in southeastern Oklahoma consists of approximately 401,280 acres of Quaternary alluvium and terrace deposits associated with the Red River and its major tributaries. Mean annual recharge to the aquifer for the 1980–2022 study period was estimated to be 8.62 inches per year, or 17.98 percent of the mean annual precipitation over the same period (47.94 inches). This mean annual recharge rate is equivalent to an inflow of approximately 288,250 acre-feet per year for the eastern part of the Red River alluvial aquifer. Recharge estimated using the Soil-Water-Balance code accounts for 98.7 percent of the conceptual-model inflows to the eastern part of the Red River alluvial aquifer. Saturated-zone evapotranspiration accounts for 11.9 percent and net streambed seepage accounts for 87.4 percent of the outflows in the conceptual model.

Arkansas, Oklahoma, Texas

Biodegradation of chlorinated ethenes at a karst site in middle Tennessee

This report presents results of field and laboratory investigations examining the biodegradation of chlorinated ethenes in a karst aquifer contaminated with trichloroethylene (TCE). The study site, located in Middle Tennessee, was selected because of the presence of TCE degradation byproducts in the karst aquifer and available site hydrologic and chlorinated-ethene information. Additional chemical, biological, and hydrologic data were gathered to evaluate whether the occurrence of TCE degradation byproducts in the karst aquifer was the result of biodegradation within the aquifer or simply transport into the aquifer. Geochemical analysis established that sulfate-reducing conditions, essential for reductive dechlorination of chlorinated solvents, existed in parts of the contaminated karst aquifer. Other areas of the aquifer fluctuated between anaerobic and aerobic conditions and contained compounds associated with cometabolism, such as ethane, methane, ammonia, and dissolved oxygen. A large, diverse bacteria population inhabits the contaminated aquifer. Bacteria known to biodegrade TCE and other chlorinated solvents, such as sulfate-reducers, methanotrophs, and ammonia-oxidizers, were identified from karst-aquifer water using the RNA-hybridization technique. Results from microcosms using raw karst-aquifer water found that aerobic cometabolism and anaerobic reductive-dechlorination degradation processes were possible when appropriate conditions were established in the microcosms. These chemical and biological results provide circumstantial evidence that several biodegradation processes are active in the aquifer. Additional site hydrologic information was developed to determine if appropriate conditions persist long enough in the karst aquifer for these biodegradation processes to be significant. Continuous monitoring devices placed in four wells during the spring of 1998 indicated that pH, specific conductance, dissolved oxygen, and oxidation-reduction potentials changed very little in areas isolated from active ground-water flow paths. These stable areas in the karst aquifer had geochemical conditions and bacteria conducive to reductive dechlorination of chlorinated ethenes. Other areas of the karst aquifer were associated with active ground-water flow paths and fluctuated between anaerobic and aerobic conditions in response to rain events. Associated with this dynamic environment were bacteria and geochemical conditions conducive to cometabolism. In summary, multiple lines of evidence developed from chemical, biological, and hydrologic data demonstrate that a variety of biodegradation processes are active in this karst aquifer.

Tennessee

Evidence for fluid pressurization of fault zones and persistent sensitivity to injection rate beneath the Raton Basin

Subsurface wastewater injection has increased the seismicity rate within the Raton Basin over more than two decades, with the basin-wide injection rate peaked between 2009-2015. To understand the evolution of injection-induced earthquakes, we systematically analyzed 2016-2024 broadband recordings with a machine-learning-based phase picker and constructed a catalog with 95,993 earthquakes (-1≤ M L ≤4.3). We then inverted for full centroid moment tensors (CMT) for 90 M L ≥ 2 events, with a special interest in constraining the non-double-couple components via probabilistic metrics. Both relocations and CMT solutions support basement-rooted normal faults, including graben and half-graben structures. Furthermore, we observe the non-double-couple components that imply elevated pore pressure in the fault zones. An earthquake cluster emerged in the north-central basin in 2023, preceded by ~1-yr of increased injection volume from wells within 15km. Despite a basin-wide decrease in the injection volume, we highlights the persistence of seismicity that remains to sensitive to injection rates within the Raton Basin.

Colorado, New Mexico

Beyond optimality: Dryland ecosystems infrequently use water efficiently for carbon gain

Optimality theory assumes plants maximize carbon gain per unit water lost and is often implemented to scale leaf-level carbon gain and water use to regional and global scales. Optimality theory is often mathematically represented by assuming plant water-use efficiency (WUE) scales with VPD k , where k = ½ represents expected optimal behavior. It is unclear, however, if this relationship holds in arid and semi-arid ecosystems that are strongly impacted by soil and atmospheric moisture status. We used data from seven flux tower sites along an aridity gradient in New Mexico to answer: how does the relationship between WUE and VPD compare to expectations based on optimality theory? To address this question, we integrated the Dynamic Evapotranspiration Partitioning Approach for Rapid Timescales with a stochastic antecedent model to estimate ecosystem-level WUE (GPP/T) and the net sensitivity of WUE to VPD, or k Dynamic , which we compare to the theoretical optimal sensitivity of k = ½. Our results show that optimality theory is not always appropriate, and k Dynamic often deviates from ½, especially at some of the more arid sites or during periods of low soil moisture. At less arid, higher elevation sites, k Dynamic is most consistent with optimality theory at moderate VPD levels, but not at high VPD. In general, the sensitivity of WUE to VPD is highly variable such that k Dynamic exhibits notable daily and seasonal variability, suggesting highly dynamic stomatal behavior. These results emphasize that representing plant water-use strategies as dynamic in time and space is critical to improving large-scale estimates of plant water use.

New Mexico

Mine waste as a potential source of critical minerals and other commodities: Examples from the Four Corners states, USA

The growing demand for critical minerals and other mineral resources has raised concerns about possible supplies of these essential commodities. Mine waste is a potential source of these essential commodities. We compiled a geospatial database of publicly available data of the largest non-fuel mine waste features (>200,000 m 2 in areal extent) in the Four Corners states of the United States, where most of those features are from porphyry Cu deposits. The combined volume of those large porphyry Cu mine waste features is approximately 17 cubic kilometers, 60% of which is ore-related material such as tailings. Using publicly available data on density, grade, and previous recovery values, we estimate the contained endowments of Ag, As, Au, Bi, Cu, Mo, Re, S, Sb, Se, Te, and W. These estimates indicate endowments within ore-related mine wastes are collectively comparable to endowments of giant to supergiant deposits. If fully recovered, these commodities could meet current global demand from less than 1 year (Sb) to more than 200 years (Re), underscoring the enormous untapped resource potential of mine waste.

Arizona, Colorado, New Mexico, Utah

Hydrogeologic investigation, framework, and conceptual flow model of the Antlers aquifer, southeastern Oklahoma, 1980–2022

The 1973 Oklahoma Groundwater Law (Oklahoma Statute §82–1020.5) requires that the Oklahoma Water Resources Board conduct hydrologic investigations of the State’s groundwater basins to support a determination of the maximum annual yield for each groundwater basin. Every 20 years, the Oklahoma Water Resources Board is required to update the hydrologic investigation on which the maximum annual yield determinations were based. The maximum annual yield allocated per acre of land is used to set the equal-proportionate share pumping rate. The maximum annual yield of 5,913,600 acre-feet per year and equal-proportionate-share of 2.1 acre-feet per acre per year currently (2025) in place for the Antlers aquifer were issued by the Oklahoma Water Resources Board on February 14, 1995. Because more than 20 years have elapsed since the 1995 final order for the Antlers aquifer was issued, the U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, completed an in-depth hydrologic study that included a hydrogeologic framework and conceptual groundwater-flow model for the 1980–2022 study period. The results of an analysis of land use, long-term climate patterns, streamflow and base-flow patterns, historical groundwater use, as well as groundwater-level fluctuations across the Antlers aquifer are described. In addition, groundwater quality was analyzed for total dissolved solids concentrations and major ions for the Antlers aquifer. An updated hydrogeologic framework was developed that included refining the aquifer boundary in Oklahoma, the creation of new potentiometric surface and saturated thickness of fresh groundwater maps, one multiple-well aquifer test, slug tests, and an analysis of lithologic logs across the aquifer. A conceptual groundwater flow model and water budget were developed by incorporating estimates of recharge from precipitation, saturated-zone evapotranspiration, streambed seepage, lateral groundwater flows, vertical leakage, and withdrawals from groundwater wells.

Oklahoma, Texas

Introduction to the special section on improving measurements of earthquake source parameters

Earthquake source parameters such as magnitude, seismic moment, source dimension, stress drop, and radiated energy are fundamental to understanding earthquake physics, and are also key ingredients in earthquake ground‐motion modeling, rupture simulation, and statistical seismology. However, the uncertainties in these parameters estimated from the radiated seismic wavefield are large due to variability in approaches, including site and attenuation characterizations, and so estimates for an individual earthquake made by different studies can vary greatly. Estimating spectral source parameters remains a popular topic, due to a combination of their intrinsic importance and their apparent ease of measurement, but also a controversial one, due to many sources of variability and large uncertainty. The available methods coupled with necessary parameter choices and assumptions in the analysis make it challenging for researchers to apply methods or understand the reliability in results or reported source parameters. This Special Section on Improving Measurements of Earthquake Source Parameters showcasing comparisons between methods and studies seeks to alleviate some of these difficulties to help the community identify the important components and trade‐offs of decomposing recorded seismograms into their source, path, and site components.

Bulletin of the Seismological Society of America

Pesticides in surface waters of the Upper Colorado River Basin, Colorado, 1996-98

Forty-four river, stream, and drain sites in the Upper Colorado River Basin in Colorado were sampled during 1996-98 to determine the occurrence and distribution of pesticides in the basin. In a fixed-station study, 57 surface-water samples were collected from October 1996 through January 1998 at four sites. Each site was sampled approximately monthly for up to a year, with more frequent sampling during the spring and summer growing season. In a synoptic study, surface-water samples were collected at 43 sites in the agricultural areas of the Grand Valley and the Uncompahgre River Valley in May 1998. Each site was sampled once. Pesticide concentrations generally were low and varied seasonally and across land uses. Thirty-five pesticides were detected at least once in the two studies, and 11 pesticides accounted for almost 82 percent of the detections. Herbicides were more commonly detected than insecticides, and only the herbicides alachlor and atrazine were detected in more than 50 percent of the samples. Carbofuran was the most commonly detected insecticide and was detected in 19 percent of the samples. Pesticide detections increased and were measured at higher concentrations in the summer months and at the agriculture sites. All pesticide concentrations were less than drinking-water standards, and most complied with human-health advisories and criteria for the protection of freshwater aquatic life. Pesticides in the Upper Colorado River Basin in Colorado were detected slightly less frequently and generally at lower concentrations than in 20 National Water-Quality Assessment Program study-unit basins that collected water-quality data from 1992 through 1996. Results from surface-water sampling conducted during 1996?98 in the Upper Colorado River Basin in Colorado indicate that beneficial uses of water were not being impaired by the presence of pesticides in surface waters in the basin.

Colorado

Invasion of perennial sagebrush steppe by shallow-rooted exotic cheatgrass reduces stable forms of soil carbon in a warmer but not cooler ecoregion

Soil organic carbon ('SOC') in drylands comprises nearly a third of the global SOC pool and has relatively rapid turnover and thus is a key driver of variability in the global carbon cycle. SOC is also a sensitive indicator of longer-term directional change and disturbance-responses of ecosystem C storage. Biome-scale disruption of the dryland carbon cycle by exotic annual grass invasions (mainly Bromus tectorum, 'Cheatgrass') threatens carbon storage and corresponding benefits to soil hydrology and nutrient retention. Past studies on cheatgrass impacts mainly focused on total C, and of the few that evaluated SOC, none compared the very different fractions of SOC, such as relatively unstable particulate organic carbon (POC) or relatively stable, mineral-associated organic carbon (MAOC). We measured SOC and its POC and MAOC constituents in the surface soils of sites that had sagebrush canopies but differed in whether their understories had been invaded by cheatgrass or not, in both warm and relatively colder ecoregions of the western USA. MAOC stocks were 36.1% less in the 0–10 cm depth and 46.1% less in the 10–20 cm depth in the cheatgrass-invaded stands compared to the uninvaded stands of the warmer Colorado Plateau, but not in the cooler and more carbon-rich Wyoming Basin ecoregion. In plots where cheatgrass increased SOC, it was via unstable POC. These findings indicate that cheatgrass effects on the distribution of soil carbon among POC and MAOC fractions may vary among ecoregions, and that cheatgrass can reduce forms of carbon that are otherwise considered stable and 'secure', i.e. sequestered.

Environmental Research Communications

Nitrogen deposition weakens soil carbon control of nitrogen dynamics across the contiguous United States

Anthropogenic nitrogen (N) deposition is unequally distributed across space and time, with inputs to terrestrial ecosystems impacted by industry regulations and variations in human activity. Soil carbon (C) content normally controls the fraction of mineralized N that is nitrified ( ƒ nitrified ), affecting N bioavailability for plants and microbes. However, it is unknown whether N deposition has modified the relationships among soil C, net N mineralization, and net nitrification. To test whether N deposition alters the relationship between soil C and net N transformations, we collected soils from coniferous and deciduous forests, grasslands, and residential yards in 14 regions across the contiguous United States that vary in N deposition rates. We quantified rates of net nitrification and N mineralization, soil chemistry (soil C, N, and pH), and microbial biomass and function (as beta-glucosidase (BG) and N -acetylglucosaminidase (NAG) activity) across these regions. Following expectations, soil C was a driver of ƒ nitrified across regions, whereby increasing soil C resulted in a decline in net nitrification and ƒ nitrified . The ƒ nitrified value increased with lower microbial enzymatic investment in N acquisition (increasing BG:NAG ratio) and lower active microbial biomass, providing some evidence that heterotrophic microbial N demand controls the ammonium pool for nitrifiers. However, higher total N deposition increased ƒ nitrified , including for high soil C sites predicted to have low ƒ nitrified , which decreased the role of soil C as a predictor of ƒ nitrified . Notably, the drop in contemporary atmospheric N deposition rates during the 2020 COVID-19 pandemic did not weaken the effect of N deposition on relationships between soil C and ƒ nitrified . Our results suggest that N deposition can disrupt the relationship between soil C and net N transformations, with this change potentially explained by weaker microbial competition for N. Therefore, past N inputs and soil C should be used together to predict N dynamics across terrestrial ecosystems.

contiguous United States

Stream habitat characteristics at selected sites in the Georgia-Florida coastal plain

Habitat characterization is part of a multidisciplinary approach to water-quality assessment implemented by the National Water-Quality Assessment Program. Habitat data were collected in the Georgia-Florida Coastal Plain study unit at 24 sites during 1993-95. Data were collected for habitat characteristics at three spatial scales: basin, segment, and reach. Basin data include physiography, land resource provinces, and land use, providing a description of the environmental setting at each site. Segment data include length, gradient, and sinuosity. A Kendall correlation analysis performed on segment characteristics and the log-of-basin area showed a correlation between segment gradient and the log-of-basin area and a correlation between sinuosity and segment length. Reach data consist of field-collected measurements of both instream and riparian habitats. Sand and detritus were the most common channel-bed substrates among the sampled sites. Measurements of channel width, water depth, and bank width and height were used to create cross-sectional profiles of each sampled area. Elevations of selected durations plotted on cross sections illustrated the percentage of time that the banks were inundated at each site. Sites were divided into two groups based on duration of bank inundation (less than or equal to 1 percent and greater than 1 percent). Bank woody vegetation was also sampled and a clustering algorithm known as Two-Way INdicator SPecies ANalysis (TWINSPAN) was used to analyze these data. TWINSPAN divided the sites into two groups based on their vegetation composition. A statistical comparison of the two types of site groups (duration of bank inundation and vegetation) was performed. The significant association between these groups was consistent with the hypothesis that inundation frequency affected riparian vegetation.

Florida, Georgia

Characterization of change in tree cover state and condition over the conterminous United States

Variability in the effects of disturbances and extreme climate events can lead to changes in tree cover over time, including partial or complete loss, with diverse ecological consequences. It is therefore critical to identify in space and time the change processes that lead to tree cover change. Studies of change are often hampered by the lack of data capable of consistently detecting different types of change. Using the Landsat satellite record to create a long time-series of land cover and land cover change, the U.S. Geological Survey Land Change Monitoring Assessment and Projection (LCMAP) project has made an annual time series of land cover across the conterminous United States for the period 1985 to 2018. Multiple LCMAP products analyzed together with map validation reference plots provide a robust basis for understanding tree cover change. In LCMAP (Collection 1.2), annual change detection is based on harmonic model breaks calculated at each Landsat pixel from the Continuous Change Detection and Classification (CCDC) algorithm. The results showed that the majority of CCDC harmonic model breaks (signifying change) indicated partial tree cover loss (associated with management practices such as tree cover thinning) as compared to complete tree cover loss (associated with practices like clearcut harvest or fire disturbance). Substantially fewer occurrences of complete tree cover loss were associated with change in land cover state. The area of annual tree cover change increased after the late 1990s and stayed high for the rest of the study period. The reference data showed that tree harvest dominated across the conterminous United States. The majority of tree cover change occurred in evergreen forests. Large estimates of disturbance-related tree cover change indicated that tree cover loss may have previously been underreported due to omission of partial tree cover loss in prior studies. This has considerable implications for forest carbon accounting along with tracking ecosystem goods and services.

Forests

Water resources related to breccia pipe uranium mining in the Grand Canyon region

Introduction In the arid Grand Canyon region, water resources are limited to primarily the Colorado River and associated tributaries and to groundwater in the form of seeps and springs. Groundwater resources in the region supply water for human use and support diverse and rich ecosystems in the locations immediately surrounding the seeps and springs. Throughout the region, uranium resources occur and may interact with water resources in both mined and unmined uranium deposits. There is a need to better understand groundwater in the region and the effects from uranium mining in order to better manage the limited water resources in the area. This Fact Sheet summarizes results from U.S. Geological Survey studies that were conducted on this topic from 2012 to 2023.

Arizona

U-Pb scheelite ages of tungsten and antimony mineralization in the Stibnite-Yellow Pine district, central Idaho

The Stibnite-Yellow Pine district contains the largest antimony resource in the United States, as well as significant gold, and is a historic producer of tungsten. Application of in situ laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) direct dating of scheelite from two Au-Sb-W ore deposits, Yellow Pine and Hangar Flats, yielded an older group of U-Pb ages in the range of 60.0 ± 2.8 to 57.0 ± 1.1 Ma and a younger U-Pb age for scheelite intergrown with stibnite of 47.4 ± 1.1 Ma. These in situ analyses were calibrated by isotope dilution-thermal ionization mass spectrometry (ID-TIMS) U-Pb lower intercept ages of two coarsely crystalline scheelite samples that yielded ages of 57.52 ± 0.22 and 56.62 ± 0.16 Ma. Scheelite of the latter age is of sufficient quality to serve as a primary reference material for LA-ICP-MS scheelite U-Pb geochronology. The group of older U-Pb scheelite ages agrees with 40 Ar/ 39 Ar ages of 56.9 ± 1.2 to 56.38 ± 0.54 Ma on adularia from Yellow Pine and Hangar Flats, whereas the younger U-Pb scheelite age is similar to an 40 Ar/ 39 Ar age of 46.00 ± 0.40 Ma on adularia from an epithermal gold-silver deposit in the adjacent Thunder Mountain caldera. Our results indicate that the main stage of tungsten mineralization occurred at ca. 57 Ma, whereas the main stage of antimony mineralization occurred at ca. 47 Ma—thereby providing first-time age constraints for antimony and tungsten mineralization in the Stibnite-Yellow Pine district.

Idaho

Tephra from Kīlauea’s 2008–2018 lava lake eruption—Proximal deposits and dispersal characteristics

A network of ten buckets was established early in the 2008–2018 summit eruption at Kīlauea to collect proximal tephra ejected from the new, informally named the “Overlook crater”; the buckets were emptied on most days of the eruption thereafter. This report summarizes the results of more than 2,400 different sampling intervals (most 1–3 days long) during the eruption, focusing on the physical and dispersal characteristics of the tephra deposits. The network was within about 300 meters south of the vent to capture tephra dispersed by the dominant northeast trade wind. The juvenile tephra mainly reflected spattering at the southeast (SE) sink, a downwelling area in the southeastern part of the lava lake in the Overlook crater that remained in the same area throughout the eruption, with admixtures of solid rock and secondary minerals derived from the wall of the crater. The proportion of juvenile material to lithic material ranged widely early in the eruption but was generally greater than 90 percent for the last 6 years of the eruption as lake level rose and the crater walls decreased in height and became more stable. The accumulation rate of tephra at each bucket was strongly dependent on the location of the bucket and reflects the interplay between lava lake level and wind direction and speed. The mass per unit area (m/a) of collected tephra was a maximum of about 97 kilograms per square meter for the entire eruption, equivalent to a thickness of about 75 millimeters. Thirty-two explosive events with a volcanic explosivity index of −2 to −4 deposited much of the tephra in the network. Fifteen of these rock-fall-induced events occurred within 6 days of one another. Pele’s hair, a volcanic glass predominantly associated with quieter activity at the vent in the final half of the eruption, was dispersed more than 60 kilometers downwind from the lava lake and formed a nearly continuous deposit near the Overlook crater. This eruption was probably the most frequently sampled long-lasting eruption in history, but most of the deposits are ephemeral. The collected samples, although generally of small mass, are retained by the Hawaiian Volcano Observatory and are available for detailed study.

Hawaii

Modeling legacy nitrogen transport under instantaneous, steady-state, and transient groundwater flow conditions

In hydrologic settings where groundwater discharge contributes substantially to surface waters, legacy nitrogen in groundwater can confound surface water nitrogen loads estimated exclusively from current terrestrial sources. Additionally, legacy nitrogen in groundwater can contribute to lagged responses to nitrogen management efforts. Some methods of estimating groundwater contributions to surface water nitrogen loads account for legacy nitrogen, while others do not. The resulting differences are rarely quantified. We used a numerical modeling framework to compare three methods of estimating time-varying annual groundwater nitrogen loads to surface water receptors on eastern Long Island, New York. The instantaneous load method used steady-state contributing areas and includes no temporal groundwater lag. The second method used numerical simulations of nitrogen loads under steady-state flow, which captures groundwater transport lags but omits the annual variability in transient hydrologic stresses. The third method numerically simulated both transient groundwater flow and nitrogen transport to explicitly capture the effects of legacy nitrogen in groundwater. Depending on antecedent nitrogen and hydrologic conditions, historical nitrogen loads estimated from the numerical simulations were sometimes similar (<10% difference) and other times substantially different (±100%) from the instantaneous load estimates. Additionally, simulated future surface water nitrogen loads responded asymptotically over several decades following reductions in terrestrial nitrogen sources, further highlighting the effect of groundwater transport lag times. The comparison of the three methods, quantification of historical interannual variability, and prediction of lagged responses to nitrogen source reductions provide important context for decision makers using estimated groundwater nitrogen loads to help evaluate nitrogen management efficacy.

New York