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USGS1952

Carnotite resources of Club Mesa, Montrose County, Colorado

Club Mesa is 1 mile west of Uravan, Montrose County, Colo. About 200,000 short tons of carnotite ore containing an estimated 0.45 percent U 3 O 8 and 2.1 percent V 2 O 5 has been mined from the mesa. This production represents about one-fifth of the carnotite ore mined from the Colorado Plateau. All the principal deposits on the mesa are in the main ore-bearing sandstone which is in the top part of the Salt Wash sandstone member of the Jurassic Morrison formation. The deposits are in tabular masses of uneven thickness lying more or less parallel to the enclosing strata. The ore consists mainly of sandstone impregnated with carnotite and vanadiferous clay minerals. The sandstone near the deposits is generally over 30 feet in thickness, contains noticeable quantities of carbon, and vivid patches of limonite (?) stain. Also near ore deposits, the mudstone in contact with the sandstone is altered from red to gray or green through a thickness of 3 or 4 feet. Certain linear features of the ore bodies and of favorable parts of the main ore-bearing sandstone offer clues by their orientation to extensions of known ore bodies and of favorable ground. These features on Club Mesa trend mostly east to northeast. Between March 6, 1948, and January 22, 1952, the U.S. Geological Survey drilled 651 holes for a total of 167,495 feet. As a result of this drilling, 18 deposits were discovered and partly outlined. These range in size from 200 to 55,000 short tons of indicated ore reserves and are in layers 1 foot or more thick containing 0.10 percent or more U 3 O 8 or 1.0 percent or more V 2 O 5 . About 85 percent of this ore is in public land; the remainder is in claims owned by the United States Vanadium Co. Reserves in deposits known from drill holes or exposures are classed as indicated or inferred, and those in deposits that are predicted solely on geologic evidence are classed as potential. The tons of indicated and inferred reserves and the pounds of contained U 3 O 8 and V 2 O 5 are summarized in table 1. These reserves are subdivided also by thickness and grade cutoffs. At the higher grade cutoff, reserve figures express approximately the tonnage and grade of material that might actually be mined from these deposits under 1951 conditions. Indicated and inferred reserves of this type total 198,000 short tons, averaging 0.35 percent U 3 O 8 and 1.8 percent V 2 O 5, and contain 1,1,372,000 pounds of U 3 O 8 and 7,260,000 pounds of V 2 O 5. These reserves are based on Geological Survey drilling. Potential reserves are predicted to total about 40,000 short tons, averaging about 0.35 percent U 3 O 8 and 1.9 percent V 2 O 5 . No additional exploration on Club Mesa is planned by the Geological Survey, but exploration by private companies is recommended.

Colorado↗

USGS1978

Tin and related elements in sediments and beach sands from Afghanistan, Iran, and Turkey

Sixty samples of sediments from stream beds, outwash plains, and beaches were collected in Afghanistan, Iran, and Turkey by Fred L. Klinger, U.S. Bureau of Mines, as part of the field work undertaken by the National Geographic-Smithsonian Pyrotechnological Expedition of 1968. Facilities for the analysis of the samples for tin and other metals were not immediately available, but in 1973 arrangements were made for analyses to be made on a time-permitting basis in the U.S. Geological Survey. The original purpose in collecting the samples was to determine whether tin was present in amounts indicative of sources for tin ores used in antiquity for the manufacture of bronze. The results of the analyses not only permitted an evaluation of the potential for tin in the localities sampled, but also afforded chemical and mineralogical data that were interpretable in the context of regional potential for other elements of current industrial use. These include gold, base metals, ferro-alloy metals, beryllium, rare earths, and barium. The original 60 samples of sand were sieved to make three size fraction (>0.707 mm, <O.707->O.177 mm, and <0.177 mm) for spectrographic and chemical analysis. Splits of these fractions were used for replicate analyses to permit evaluation of the precision of the analytical procedures. Further splitting of the <0.707->0.177 mm sand gave fractions from each sample that were separated in bromoform. Concentrates from the heavy-liquid separations were divided magnetically into six parts from most magnetic to least magnetic. These concentrates were analyzed spectrographically. The precision of the spectrographic analyses is well within the limits of precision expected from semiquantitative procedures. Such precision allows semiquantitative spectrographic procedures to be used with confidence as a valuable tool for reconnaissance investigations in which multi-element analyses are necessary. The analyses of the various fractions of sediments and sediment concentrates indicate the sample media in which an element was most likely to occur. Tin exhibited no preferential concentration into any particular medium. However, many elements with which tin is associated, and other elements of industrial use, do concentrate into one or more of the sample media. This indication of a preferred medium permits interpretation of the analyses as to the best sample medium for a particular element in the environment of western Asia. Cassiterite and/or tin were detected in many samples from Afghanistan, Iran, and Turkey, but in most of the samples the tin was present in normal crustal abundance. Sixteen samples, including seven from Afghanistan, eight from Iran, and one from Turkey contain unusually large amounts of tin. The most notable areas of anomalous tin are near Mirzaka, Qala-i-Asad, and Shah Agha in Afghanistan; near Meshed, Shir Kuh, Natanz, Nodus, and Talmesi in Iran; and on the shore of the Balck Sea just west of Trabzon in Turkey. Even in these localities the tin appears to be a minor element associated with other ores. The most common association of tin is with copper at known mineralized areas. This relation may have historical significance in the context of the development of bronze. The results of the analyses provided geochemical data on the distribution of other elements of industrial use and clearly identified nine of the ten known mineral deposits represented by the samples. The known metallization at the reported deposits may be only a part of more complex groups of metals. In Afghanistan an array of anomalous elements at the known gold placers around Mirzaka and along the Anguri River signals the presence of complex ore deposits. These elements are silver, arsenic, gold, bismuth, cadmium, copper, mercury, indium, molybdenum, lead, antimony, tin, thallium, tungsten, and zinc. They may indicate a Carlin-type gold deposit in which the wall-rocks are enriched in micron-sized particles of gold. Other localities in Afghanistan signalled by the results of the analyses to be anomalous and to merit further geochemical exploration are: (1) a reach of the Panjshir River for beryllium, lead, zinc, chromium and nickel; (2) the area near Bamian for beryllium; (3) the Siakhak village area for gold and copper; (4) around Qala-i-Asad and Shah Agha for lead, zinc, gold, and tungsten. Some attention to the distribution of monazite around Siakhak, Shahjui, Qala-i-Asad, and Shah Agha is justified to determine if this ore mineral for the rare earths and thorium is enriched over its normally expectable trace as an accessory mineral in granitic rocks, pelitic schists, and gneisses. In Iran, the pluton of granodiorite porphyry near Sar Cheshmeh, an area where a huge porphyry copper deposit was being investigated by the Geological Survey of Iran when the present samples were collected in 1968, shows as a strong geochemical anomaly for copper and molybdenum. The granitic area near Meshed is geochemically enriched persistently in beryllium, tin, and barium, and locally in gold, lanthanum, niobium, yttrium, and other elements. This area deserves a thorough regional geochemical survey for beryl and nonberyl sources of beryllium, for fluorite, and for the ores of niobium, tin, barium, the rare earths, and thorium. Other localities in Iran that merit geochemical exploration on the basis of these data are: ;1) the areas between Tabas and Deyhuk, east of Naiband, and south of Naiband for barium and zinc; (2) a locality about midway between Kerman and Sirdjan for barium, lanthanum, strontium, and zinc; (4) the Meskani copper mine area for mercury, lead, and nickel as well as copper; (5) the Talmesi copper mine area for such other elements as barium, cobalt, mercury, strontium, and zinc; (6) a small pluton of granodiorite north of Natanz for tungsten and base metals; (7) the vicinity of Zendjan for auriferous polymetallic sufide deposits; (8) gold in the gorge 15 km east of Miyaneh; and (9) the area near Nodus for gold, base metals, molybdenum, and niobium, and possibly uranium. The Harsit River basin in Turkey appears to be a suitable target for geochemical exploration for gold and low-temperature hydrothermal deposits of base metals, barium, and mercury.

Open-File Report↗

USGS2008

Pathogen and chemical transport in the karst limestone of the Biscayne aquifer: 1. Revised conceptualization of groundwater flow

The Biscayne aquifer is a highly transmissive karst limestone that serves as the sole source of drinking water to over two million residents in south Florida. The aquifer is characterized by eogenetic karst, where the most transmissive void space can be an interconnected, touching‐vug, biogenically influenced porosity of biogenic origin. Public supply wells in the aquifer are in close proximity to lakes established by surface mining. The mining of the limestone has occurred to the same depths as the production wells, which has raised concerns about pathogen and chemical transport from these surface water bodies. Hydraulic and forced gradient tracer tests were conducted to augment geologic and geophysical studies and to develop a hydrogeologic conceptual model of groundwater flow and chemical transport in the Biscayne aquifer. Geologic and geophysical data indicate multiple, areally extensive subhorizontal preferential flow zones of vuggy limestone separated by rock with a matrix pore system. The hydraulic response from an aquifer test suggests that the Biscayne aquifer behaves as a dual‐porosity medium; however, the results of the tracer test showed rapid transport similar to other types of karst. The tracer test and concurrent temperature logging revealed that only one of the touching‐vug flow zones dominates transport near the production wells. On the basis of the rising limb of the breakthrough curve, the dispersivity is estimated to be less than 3% of the tracer travel distance, which suggests that the fastest flow paths in the formation are likely to yield limited dilution of chemical constituents.

Water Resources Research↗

USGS2018

Idaho water use, 2015

The ability to quantify water resources hinges on the understanding of water use by the population. The demand humans place on the water cycle varies across the United States, driven by both need and availability. The U.S. Geological Survey quantifies water use nationally, at the county scale, with estimates of water withdrawals and deliveries, by category of use (for example, irrigation, thermoelectric power, industrial, public supply, including domestic deliveries and self-supply domestic, livestock, mining, and aquaculture) and source (fresh and saline groundwater or surface water) every 5 years. Estimates of water use are an important component of the water budget to help manage water supplies and plan for the future. Understanding water use in Idaho is important not only at the local (county) and State scales, but also at the National level because Idaho ranked third in the Nation for total water use in 2015. This fact sheet describes calendar year 2015 freshwater withdrawals by source and by each Idaho county. An associated data release provides the data discussed herein. Freshwater withdrawals totaled 17,737 million gallons per day during 2015. Surface water accounted for 70 percent of total withdrawals for all categories of use, mostly for irrigation of crops and aquaculture production. Withdrawals for mining activities were mostly from surface water, whereas the remaining categories of use—public supply, domestic, industrial, livestock, irrigation of golf courses, and thermoelectric power—relied largely on groundwater withdrawals. Most withdrawals occurred in southern Idaho counties to support irrigated agriculture.

Idaho↗

USGS2022

Selenium in the Kootenai River Basin, Montana and Idaho, United States, and British Columbia, Canada

Selenium entering the 90-mile long transboundary Koocanusa Reservoir (also called Lake Koocanusa) in southeastern British Columbia, Canada, and northwestern Montana, United States, has been measured at concentrations above State and Federal water-quality and aquatic life standards. The reservoir is within the international Kootenai (or “Kootenay” in Canada) drainage basin, which contains critical habitat for native fish species and is impounded by Libby Dam 16 miles upstream from Libby, Montana. Since 1984, selenium concentrations have ranged from below detection to greater than 8 micrograms per liter in the Elk River, measured 2.2 miles above its discharge into Koocanusa Reservoir at a British Columbia environmental monitoring station (site 0200016). Selenium is a required micro-nutrient, but elevated concentrations in water bioaccumulate in egg-laying fish and birds, causing various sublethal effects and death. One possible source of selenium in the Kootenai River Basin is the excavation of bedrock in the Elk River Valley to access coal seams for metallurgical steelmaking and coal production. Five open-pit coal mines are operating in this region of southeastern British Columbia that produce about 21 million tons of metallurgical coal annually. Site-specific selenium standards were established for the reservoir in 2020 following collaborative work by the U.S. Geological Survey, Montana Department of Environmental Quality, the British Columbia Ministry of Environment and Climate Change Strategy, the Lake Koocanusa Monitoring and Research Working Group, and the Selenium Technical Subcommittee. The standards of 0.8 microgram per liter for dissolved selenium in the water column and 15.1 milligrams per kilogram dry weight for fish egg (ovary) tissue (in addition to the muscle and wholebody standards) were adopted into Montana State law in 2020 and approved by the U.S. Environmental Protection Agency in 2021.

British Columbia, Idaho, Montana↗

USGS2003

Geologic map of the Horse Mountain Quadrangle, Garfield County, Colorado

New 1:24,000-scale geologic map of the Horse Mountain 7.5' quadrangle, in support of the USGS Western Colorado I-70 Corridor Cooperative Geologic Mapping Project, summarizes available geologic information for the quadrangle. It provides new interpretations of the stratigraphy, structure, and geologic hazards in the area of the southwest flank of the White River uplift. Bedrock strata include the Paleocene and early Eocene Wasatch Formation down through Ordovician and Cambrian units into Precambrian hornblende tonalite. The Wasatch Formation includes the Shire, Molina and Atwell Gulch Members which are mapped separately. The underlying Upper Cretaceous Mesaverde Group is subdivided into the Willams Fork and Iles Formations. The Cameo-Fairfield clinker zone within the Williams Fork Formation is mapped separately. The Iles Formation includes the Rollins Sandstone Member at the top, mapped separately, and the Cozzette Sandstone and Corcoran Sandstone Members, which are undivided. The Mancos Shale consists of four members, an upper member, the Niobrara Member, the Juana Lopez Member, and a lower member, undivided. The Lower Cretaceous Dakota Sandstone, the Upper Jurassic Morrison Formation, and Jurassic Entrada Sandstone are mapped separately. The Lower Jurassic and Upper Triassic Glen Canyon Sandstone is mapped with the Entrada in the Horse Mountain Quadrangle. The upper Triassic Chinle Formation and the Lower Permian and Triassic(?) State Bridge Formation are present. The Pennsylvanian and Permian Maroon Formation is undivided. All the exposures of the Middle Pennsylvanian Eagle Valley Evaporite are diapiric, intruded into the Middle Pennsylvanian Eagle Valley Formation, which includes locally mappable limestone beds. The Lower and Middle Pennsylvanian Belden Formation and the Lower Mississippian Leadville Limestone are present. The Upper Devonian Chaffee Group consists of the Dyer Dolomite and the underlying Parting Quartzite, undivided. Locally, the Lower Ordovician Manitou Formation is mapped separately beneath the Chaffee. Elsewhere, Ordovician through Cambrian units, the Manitou and Dotsero Formations, underlain by the Sawatch Quartzite, are undivided. The southwest flank of the White River uplift is a late Laramide structure that is represented by the steeply southwest-dipping Grand Hogback, which is only present in the southwestern corner of the map area, and less steeply southwest-dipping older strata that flatten to nearly horizontal attitudes in the northern part of the map area. Between these two are a complex of normal faults, the largest of which dips southward placing Chafee dolostone and Leadville Limestone adjacent to Eagle Valley and Maroon Formations. Diapiric Eagle Valley Evaporite intruded close to the fault on the down-thrown side. Removal of evaporite by either flow or dissolution from under younger parts of the strata create structural benches, folds, and sink holes on either side of the normal fault. A prominent dipslope of the Morrison-Dakota-Mancos part of the section forms large slide blocks and mass movement deposits consisting of a chaos of admixed Morrison and Dakota lithologies. The major geologic hazard in the area consists of large landslides both associated with dip-slope slide blocks and the steep slopes of the Eagle Valley Formation and Belden Formation in the northern part of the map. Abandoned coal mines are present along the north face of the Grand Hogback in the lower part of the Mesaverde Group

Miscellaneous Field Studies Map↗

USGS2002

Selected trace-element and synthetic-organic compound data for streambed sediment from the Clark Fork-Pend Oreille and Spokane River basins, Montana, Idaho, and Washington, 1998

Streambed-sediment samples were collected at 22 sites during the summer of 1998 as part of the U.S. Geological Survey National Water-Quality Assessment Program. Sampling sites in the Clark Fork-Pend Oreille and Spokane River basins represented a wide range of environmental conditions including pristine mountain streams and large rivers affected by mining-related and urban activities. Samples were analyzed for 45 inorganic major and trace elements, 109 synthetic organic compounds, and carbon. This report presents the selected results of streambed-sediment sampling from the Clark Fork-Pend Oreille and Spokane River basins in Montana, Idaho, and Washington. Trace-element concentrations in streambed sediment determined from this study were compared to median trace-element concentrations for streambed- sediment data collected from streams across the Nation during 1992-96. Generally, concentrations of arsenic, cadmium, copper, lead, mercury, and zinc were higher or similar to the national median concentration of these same trace elements. Concentrations of chromium, nickel, and selenium in streambed sediment of the study area generally were lower than the national median concentration. Most of the analytical results for synthetic organic compounds were reported as either estimated or non-detected values. Phthalates and polycyclic aromatic hydrocarbons were the most frequently detected classes of synthetic organic compounds in streambed sediment. Organochlorine pesticide residues were detected at two sites. Polychlorinated biphenyls were detected at one site.

Idaho, Montana, Washington↗

USGS2014

Occurrence model for magmatic sulfide-rich nickel-copper-(platinum-group element) deposits related to mafic and ultramafic dike-sill complexes

Magmatic sulfide deposits containing nickel (Ni) and copper (Cu), with or without (±) platinum-group elements (PGE), account for approximately 60 percent of the world’s nickel production. Most of the remainder of the Ni production is derived from lateritic deposits, which form by weathering of ultramafic rocks in humid tropical conditions. Magmatic Ni-Cu±PGE sulfide deposits are spatially and genetically related to bodies of mafic and/or ultramafic rocks. The sulfide deposits form when the mantle-derived mafic and/or ultramafic magmas become sulfide-saturated and segregate immiscible sulfide liquid, commonly following interaction with continental crustal rocks. Deposits of magmatic Ni-Cu sulfides occur with mafic and/or ultramafic bodies emplaced in diverse geologic settings. They range in age from Archean to Tertiary, but the largest number of deposits are Archean and Paleoproterozoic. Although deposits occur on most continents, ore deposits (deposits of sufficient size and grade to be economic to mine) are relatively rare; major deposits are present in Russia, China, Australia, Canada, and southern Africa. Nickel-Cu sulfide ore deposits can occur as single or multiple sulfide lenses within mafic and/or ultramafic bodies with clusters of such deposits comprising a district or mining camp. Typically, deposits contain ore grades of between 0.5 and 3 percent Ni and between 0.2 and 2 percent Cu. Tonnages of individual deposits range from a few tens of thousands to tens of millions of metric tons (Mt) bulk ore. Two giant Ni-Cu districts, with ≥10 Mt Ni, dominate world Ni sulfide resources and production. These are the Sudbury district, Ontario, Canada, where sulfide ore deposits are at the lower margins of a meteorite impact-generated igneous complex and contain 19.8 Mt Ni; and the Noril’sk-Talnakh district, Siberia, Russia, where the ore deposits are in subvolcanic mafic intrusions related to flood basalts and contain 23.1 Mt Ni. In the United States, the Duluth Complex in Minnesota, comprised of a group of mafic intrusions related to the 1.1 Ga Midcontinent Rift system, represents a major Ni resource of 8 Mt Ni, but deposits generally exhibit low grades (0.2 percent Ni, 0.66 percent Cu) and remain in the process of being proven economic. The sulfides in magmatic Ni-Cu deposits generally constitute a small volume of the host rock(s) and tend to be concentrated in the lower parts of the mafic and/or ultramafic bodies, often in physical depressions or areas marking changes in the geometry of the footwall topography. In most deposits, the sulfide mineralization can be divided into disseminated, matrix or net, and massive sulfide, depending on a combination of the sulfide content of the rock and the silicate texture. The major Ni-Cu sulfide mineralogy typically consists of an intergrowth of pyrrhotite (Fe 7 S 8 ), pentlandite ([Fe, Ni] 9 S 8 ), and chalcopyrite (FeCuS 2 ). Cobalt, PGE, and gold (Au) are extracted from most magmatic Ni-Cu ores as byproducts, although such elements can have a significant impact on the economics in some deposits, such as the Noril’sk-Talnakh deposits, which produce much of the world’s palladium. In addition, deposits may contain between 1 and 15 percent magnetite associated with the sulfides.

Scientific Investigations Report↗

USGS1987

Overview of surface-water quality in Ohio's coal regions

This report is designed to provide the nontechnical audience with some of the results of an 'Assessment of Water Quality in Streams Draining Coal-Producing Areas in Ohio,' by Christine L. Pfaff and others (published by the U.S. Geological Survey in 1981). The purpose of the assessment was to document the occurrence of certain chemical constituents in streams in Ohio's coal region and determine to what extent the presence of these constituents was related to mining. Ohio's most productive coal seams are associated with the Allegheny and Monongahela Formation of Pennsylvanian age. These coals were mined by underground methods very early in Ohio's history. Underground mining continues in the state today; however, surface mining now produces significantly more coal. Acid mine drainage from unreclaimed surface and underground mines has affected surface-water quality in Ohio for many years, and recently has led to establishment of reclamation programs by State and Federal agencies. In their assessment of Ohio's coal region, Pfaff and others sampled 150 sites in small watersheds underlain by the Allegheny and the Monogahela Formations. Each site represented only one of four land-use types (active-mine, unmined, abandoned-mine, or reclaimed). Statistical analysis of data from the unmined, abandoned-mine, and reclaimed sites showed that there were significant differences in pH, specific conductance, alkalinity, and concentrations of sulfate and aluminum among abandoned-mine and unmined sites. Reclaimed sites had average pH values and aluminum concentrations similar to those unmined sites. Average specific conductance and sulfate concentrations were about the same for reclaimed abandoned-mine sites, but were significantly lower at unmined sites; specific conductance and sulfate concentration, in fact, proved to be reliable indicators of basins that had been disturbed by mining. Alkalinity was significantly different for all three land uses, the highest values being found at reclaimed sites. The relationship revealed by this study may be useful in designing future water-quality sampling programs in Ohio's coal region.

Water-Resources Investigations Report↗

USGS2002

Water Quality of Camp Creek, Costello Creek, and Other Selected Streams on the South Side of Denali National Park and Preserve, Alaska

The Camp and Costello Creek watersheds are located on the south side of Denali National Park and Preserve. The Dunkle Mine, an abandoned coal mine, is located near the mouth of Camp Creek. Due to concern about runoff from the mine and its possible effects on the water quality and aquatic habitat of Camp Creek and its receiving stream, Costello Creek, these two streams were studied during the summer runoff months (June to September) in 1999 and 2000 as part of a cooperative study with the National Park Service. Since the south side of Denali National Park and Preserve is part of the U.S. Geological Survey?s National Water-Quality Assessment Cook Inlet Basin study unit, an additional part of this study included analysis of existing water-quality data at 23 sites located throughout the south side of Denali National Park and Preserve to compare with the water quality of Camp and Costello Creeks and to obtain a broader understanding of the water quality in this area of the Cook Inlet Basin. Analysis of water column, bed sediment, fish, invertebrate, and algae data indicate no effects on the water quality of Camp Creek from the Dunkle Mine. Although several organic compounds were found in the streambed of Camp Creek, all concentrations were below recommended levels for aquatic life and most of the concentrations were below the minimum reporting level of 50 ?g/kg. Trace element concentrations of arsenic, chromium, and nickel in the bed sediments of Camp Creek exceeded threshold effect concentrations (TEC), but concentrations of these trace elements were also exceeded in streambed sediments of Costello Creek above Camp Creek. Since the percent organic carbon in Camp Creek is relatively high, the toxicity quotient of 0.55 is only slightly above the threshold value of 0.5. Costello Creek has a relatively low organic carbon content and has a higher toxicity quotient of 1.19. Analysis of the water-quality data for other streams located in the south side of Denali National Park and Preserve indicate similarities to Camp Creek and Costello Creek. Most of the streams are calcium bicarbonate/calcium bicarbonate-sulfate type water with the exception of two streams that are calcium sulfate and magnesium sulfate type water. Trace element concentrations of arsenic, chromium, and nickel in the bed sediments of 9 streams exceeded the TEC or the probable effect concentration (PEC). Seven streams exceeded the threshold value of the toxicity quotient. Analysis of trace element concentrations in bed sediment and basin characteristics for 16 watersheds by cluster and discriminant analysis techniques indicated that the watersheds could be separated into two groups based on their basin characteristics.

Water-Resources Investigations Report↗

USGS2017

Critical mineral resources of the United States—Economic and environmental geology and prospects for future supply

Summary Mineral commodities are vital for economic growth, improving the quality of life, providing for national defense, and the overall functioning of modern society. Minerals are being used in larger quantities than ever before and in an increasingly diverse range of applications. With the increasing demand for a considerably more diverse suite of mineral commodities has come renewed recognition that competition and conflict over mineral resources can pose significant risks to the manufacturing industries that depend on them. In addition, production of many mineral commodities has become concentrated in relatively few countries (for example, tungsten, rare-earth elements, and antimony in China; niobium in Brazil; and platinum-group elements in South Africa and Russia), thus increasing the risk for supply disruption owing to political, social, or other factors. At the same time, an increasing awareness of and sensitivity to potential environmental and health issues caused by the mining and processing of many mineral commodities may place additional restrictions on mineral supplies. These factors have led a number of Governments, including the Government of the United States, to attempt to identify those mineral commodities that are viewed as most “critical” to the national economy and (or) security if supplies should be curtailed. This book presents resource and geologic information on the following 23 mineral commodities currently among those viewed as important to the national economy and national security of the United States: antimony (Sb), barite (barium, Ba), beryllium (Be), cobalt (Co), fluorite or fluorspar (fluorine, F), gallium (Ga), germanium (Ge), graphite (carbon, C), hafnium (Hf), indium (In), lithium (Li), manganese (Mn), niobium (Nb), platinum-group elements (PGE), rare-earth elements (REE), rhenium (Re), selenium (Se), tantalum (Ta), tellurium (Te), tin (Sn), titanium (Ti), vanadium (V), and zirconium (Zr). For a number of these commodities—for example, graphite, manganese, niobium, and tantalum—the United States is currently wholly dependent on imports to meet its needs. The first two chapters (A and B) deal with general information pertinent to the study of mineral resources. Chapters C through V describe individual mineral commodities and include an overview of current uses of the commodity, identified resources and their distribution nationally and globally, the state of current geologic knowledge, the potential for finding additional deposits nationally and globally, and geoenvironmental issues that may be related to the production and uses of the commodity. These chapters are updates of the commodity chapters published in 1973 in U.S. Geological Survey Professional Paper 820, “United States Mineral Resources.”

Professional Paper↗

USGS2012

Minor element distribution in iron disulfides in coal: a geochemical review

Electron beam microanalysis of coal samples in U.S. Geological Survey (USGS) labs confirms that As is the most abundant minor constituent in Fe disulfides in coal and that Se, Ni, and other minor constituents are present less commonly and at lower concentrations than those for As. In nearly all cases, Hg occurs in Fe disulfides in coal at concentrations below detection by electron beam instruments. Its presence is shown by laser ablation ICP-MS, by selective leaching studies of bulk coal, and by correlation with Fe disulfide proxies such as total Fe and pyritic sulfur. Multiple generations of Fe disulfides are present in coal. These commonly show grain-to-grain and within-grain minor- or trace element compositional variation that is a function of the early diagenetic, coalification, and post-coalification history of the coal. Framboidal pyrite is almost always the earliest Fe disulfide generation, as shown by overgrowths of later Fe disulfides which may include pyrite or marcasite. Cleat- (or vein) pyrite (or marcasite) is typically the latest Fe disulfide generation, as shown by cross-cutting relations. Cleat pyrite forms by fluid migration within a coal basin and consequently may be enriched in elements such as As by deposition from compaction-driven fluids, metal enriched basinal brines or hydrothermal fluids. In some cases, framboidal pyrite shows preferential Ni enrichment with respect to co-occurring pyrite forms. This is consistent with bacterial complexing of metals in anoxic sediments and derivation of framboidal pyrite from greigite (Fe 3 S 4 ), an Fe monosulfide precursor to framboidal pyrite having the thio-spinel structure which accommodates transition metals. Elements such as As, Se, and Sb substitute for S in the pyrite structure whereas metals, including transition metals, Hg and Pb, are thought to substitute for Fe. Understanding the distribution of minor and trace elements in Fe disulfides in coal has important implications for their availability to the environment through coal mining and use, as well as for potential reduction by coal preparation, and for delineating diagenetic compositional changes throughout and after coal formation.

International Journal of Coal Geology↗

USGS2001

Geology and mineral deposits of the Minnie Moore and Bullion mineralized areas, Blaine County, Idaho

In the early 1880?s the discovery of rich ores in the Minnie Moore and Bullion mineralized areas sparked a rush to settle and develop the Wood River valley. Silver and lead discoveries in these areas spurred the boom in mining after completion of the Oregon Short Line Railroad to Hailey in 1883. In both areas the ore comprises galena, sphalerite, and tetrahedrite in a gangue of siderite, calcite, or quartz. Minor goldbearing quartz veins are also present. The ore is in fissure and replacement veins along fracture systems that formed in Late Cretaceous time, after intrusion of nearby granodiorite or quartz diorite stocks. The ore formed under mesothermal conditions and heat was supplied by the nearby plutons. In the Minnie Moore area, the mineralized veins are cut by low-angle normal faults that are of probable Eocene age. In the Minnie Moore mineralized area, the host rock is the middle part of the Devonian Milligen Formation, (the informal Lucky Coin limestone and Triumph argillite), which is the same stratigraphic level as the host ore in the rich Triumph mine northeast of Hailey. In the Bullion mineralized area, the ore is hosted by the lower member of the Middle Pennsylvanian to Lower Permian Dollarhide Formation. Rich ore was mined in several tunnels that reached the Mayflower vein, a northwest-striking mineralized shear zone. The deposits are thought to be mainly mesothermal veins that formed in association with Cretaceous magmatism. The syngenetic stratiform model of ore formation has often been applied to these deposits, however, no evidence of syngenetic mineralization was found in this study. Faulting has displaced most of the major orebodies and thus has made mining these deposits a challenge.

Bulletin↗

USGS1968

Geology, hydrology, and geochemistry of the Black Creek watershed near Mocanaqua, Luzerne County, Pennsylvania

The Black Creek watershed is in the southwestern end of the Northern Anthracite field in Luzerne County, northeastern Pennsylvania. The study of the watershed described in this report is designated as Project No. 2 in the Joint Federal-State Acid Mine Drainage Pollution Control Demonstration Program. The area studied encompasses the West End mine of the Blue Coal Company. Bedrock in the watershed, from oldest to youngest, consists of the Mauch Chunk Formation of Mississippian and, in part, of Pennsylvanian age; the Pottsville Formation of Pennsylvanian age; and the Llewellyn Formation of Pennsylvanian age. The anthracite beds are in the Llewellyn Formation.

Pennsylvania↗

USGS2002

Multielement geochemical dataset of surficial materials for the northern Great Basin

This report presents geochemical data generated during mineral and environmental assessments for the Bureau of Land Management in northern Nevada, northeastern California, southeastern Oregon, and southwestern Idaho, along with metadata and map representations of selected elements. The dataset presented here is a compilation of chemical analyses of over 10,200 stream-sediment and soil samples originally collected during the National Uranium Resource Evaluation's (NURE) Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) program of the Department of Energy and its predecessors and reanalyzed to support a series of mineral-resource assessments by the U.S. Geological Survey (USGS). The dataset also includes the analyses of additional samples collected by the USGS in 1992. The sample sites are in southeastern Oregon, southwestern Idaho, northeastern California, and, primarily, in northern Nevada. These samples were collected from 1977 to 1983, before the development of most of the present-day large-scale mining infrastructure in northern Nevada. As such, these data may serve as an important baseline for current and future geoenvironmental studies. Largely because of the very diverse analytical methods used by the NURE HSSR program, the original NURE analyses in this area yielded little useful geochemical information. The Humboldt, Malheur-Jordan-Andrews, and Winnemucca-Surprise studies were designed to provide useful geochemical data via improved analytical methods (lower detection levels and higher precision) and, in the Malheur-Jordan-Andrews and Winnemucca Surprise areas, to collect additional stream-sediment samples to increase sampling coverage. The data are provided in *.xls (Microsoft Excel) and *.csv (comma-separated-value) format. We also present graphically 35 elements, interpolated ("gridded") in a geographic information system (GIS) and overlain by major geologic trends, so that users may view the variation in elemental concentrations over the landscape and reach their own conclusions regarding correlation among geochemistry, geologic features, and known mineral deposits. Quality-control issues are discussed for the grids and data.

California; Nevada; Oregon↗

USGS2021

Correspondence analysis for mineral commodity research: An example workflow for mineralized calderas, southwest United States

Historical mine and mineral deposit datasets are routinely used to inform quantitative mineral assessment models, but they also can contain a wealth of supplementary qualitative information that is generally underutilized. We present a workflow that uses correspondence analysis, an exploratory tool commonly applied to multivariate abundance data, to better utilize qualitative data in these historical datasets. The workflow involves extraction of qualitative information on ore mineralogy from a mineral deposit database, attaches those data to a target geological feature, and analyzes the underlying data structure with correspondence analysis and hierarchical clustering. The output of correspondence analysis is inversely weighted to the relative frequency of ore minerals, and therefore rare mineral species (i.e., those with unusually low frequencies) can disproportionately contribute to the total variance of the dataset. We present a novel technique for aggregating frequencies of rare mineral species that minimizes this effect. We apply this workflow to evaluate how ore mineral assemblages in former and active mines vary in spatial relation to silicic calderas in the southwestern United States. The most common ore mineral associations observed spatially and genetically associated to calderas include those related to polymetallic, base metal-rich systems and epithermal Au–Ag systems. Three other groups of mineralized calderas were identified, including: (1) Hg–Sb mineralized calderas in the northern Great Basin and western Nevada volcanic field; (2) calderas associated with elevated abundances of Mn oxides/hydroxides, fluorite, and Be-minerals, mostly in eastern Utah and New Mexico; and (3) calderas with numerous U ± F deposits, which are located in central Colorado, the eastern Great Basin and in northern Nevada. The latter three groups are associated with economically significant critical mineral resources, including the Li resources of the McDermitt complex and Be associated with the Spor Mountain on the margin of the Thomas caldera complex. We conclude that correspondence analysis is a promising technique that can enhance data exploration of the qualitative information held within mineral deposit datasets. Consequently, it could have numerous applications for mineral potential mapping, resource assessment projects, and characterization of mineral systems.

Natural Resources Research↗

USGS1997

Epithermal mercury-antimony and gold-bearing vein lodes of southwestern Alaska

Epithermal mineral deposits and occurrences of southwestern Alaska consist of Hg-Sb and gold- and sulfide-bearing vein lodes. Numerous Hg-Sb lodes are located throughout a region measuring several tens of thousands of square kilometers in and surrounding the Kuskokwim River basin in southwestern Alaska. The Hg-Sb lodes are hosted in sedimentary rocks of the Cretaceous Kuskokwim Group, the Triassic to Cretaceous Gemuk Group, and the Paleozoic Holitna Group, as well as in Late Cretaceous and early Tertiary mafic to felsic intrusive rocks. Mineralized Hg-Sb vein and vein breccia lodes are found in the sedimentary or igneous rocks or at their contacts. The minerology of the Hg-Sb lodes is dominated by cinnabar and stibnite, with subordinate realgar, orpiment, and native mercury, pyrite, gold, and hematite, as well as solid and liquid hydrocarbons; quartz, carbonate, limonite, dickite, and sercite are alteration gangue minerals. The largest mercury mine in Alaska, Red Devil, produced about 36,000 flasks of mercury, but the Hg-Sb lodes of southwestern Alaska generally consist of small, discontinuous veins that rarely exceed a few meters in width and a few tens of meters in strike length. The Hg-Sb lodes generally contain about 1 to 5 percent Hg and less than 1 percent Sb and As but are generally poor in base emtals and precious metals. Anomalous concentrations of gold in some lodes, however, suggest that gold deposits may be present in higher temperature environments below some of the Hg-Sb lodes. The formation of the Hg-Sb lodes is closely correlated with igneous activity of a Late Cretaceous and early tertiary magmatic arc in southwestern Alaska. Geologic and geochemical characteristics of the Hg-Sb lodes suggest that ore fluids were generated in local sedimentary rocks as they were intruded by magmas. These intrusions provided the heat to initiate dehydration reactions and expel fluids from hydrous minerals and formational waters in the sedimentary rocks, causing thermal convection and hydrothermal fluid flow along fractures and faults. Isotopic data from sulfide and alteration minerals of the Hg-Sb lodes indicate multiple sources for the ore fluids; most fluids appear to have originated from local sedimentary rocks. Hydrothermal fluids with isotopically heavy oxygen but isotopically light hydrogen and sulfur compositions indicate derivation of these species from sedimentary rocks. Isotopically shifted, evolved meteoric water was a primary component in ore fluids from a few Hg-Sb lodes. Geochemical, isotopic, and fluid inclusion data also indicate that Hg, Co 2 , CH 4 , N2, and local hydrocarbons were derived from breakdown of organic matter in sedimentary rocks when they were heated by intrusions. Radiometric 40 Ar/ 39 Ar ages of 70 ± 3 Ma from hydrothermal sercites in the Hg-Sb lodes indicate a temporal association of igneous activity and mineralization, which is consistent with the geologic characteristics. Most epithermal gold-bearing vein lodes on the Alaska Peninsula and Aleutian Islands are located in Eocene to Pleistocene volcanic-arc rocks, commonly andesite and dacite. These vein and vein breccia lodes, such as the Alaska-Apollo and Shumagin deposits on Unga Island, tend to be aligned along regional, northeast-striking, steeply dipping faults and fractures. The Alaska-Apollo mine produced about 500,000 metric tons (t) of ore that yielded an estimated 3,500 kg (130,000 oz) of gold from veins that were as much as 12 m wide and extended for 1,500 m laterally and 420 m vertically. Ore minerals include gold, galena, sphalerite, chalcopyrite, pyrite, marcasite, arsenopyrite, and native copper; gangue minerals are quartz, sericite, calcite, and chlorite and locally, barsite, clay, rhodonite, and adularia. Ores generally have Au-Ag-Te-Pb-Zn-Mn-Cu geochemical signatures, with wide As-Hg aureoles around some veins. Geologic and mineralogical characteristics of these lodes are similar to adularia-sericite volcanic-hosted epithermal deposits. The gold-bearing vein lodes may be related to arc porphyry systems, but more data are required to verify this association.

Alaska↗

USGS1999

Examining risk in mineral exploration

Successful mineral exploration strategy requires identification of some of the risk sources and considering them in the decision-making process so that controllable risk can be reduced. Risk is defined as chance of failure or loss. Exploration is an economic activity involving risk and uncertainty, so risk also must be defined in an economic context. Risk reduction can be addressed in three fundamental ways: (1) increasing the number of examinations; (2) increasing success probabilities; and (3) changing success probabilities per test by learning. These provide the framework for examining exploration risk. First, the number of prospects examined is increased, such as by joint venturing, thereby reducing chance of gambler's ruin . Second, success probability is increased by exploring for deposit types more likely to be economic, such as those with a high proportion of world-class deposits. For example, in looking for 100+ ton (>3 million oz) Au deposits, porphyry Cu-Au, or epithermal quartz alunite Au types require examining fewer deposits than Comstock epithermal vein and most other deposit types. For porphyry copper exploration, a strong positive relationship between area of sulfide minerals and deposits' contained Cu can be used to reduce exploration risk by only examining large sulfide systems. In some situations, success probabilities can be increased by examining certain geologic environments. Only 8% of kuroko massive sulfide deposits are world class, but success chances can be increased to about 15% by looking in settings containing sediments and rhyolitic rocks. It is possible to reduce risk of loss during mining by sequentially developing and expanding a mine—thus reducing capital exposed at early stages and reducing present value of risked capital. Because this strategy is easier to apply in some deposit types than in others, the strategy can affect deposit types sought. Third, risk is reduced by using prior information and by changing the independence of trials assumption, that is, by learning. Bayes' formula is used to change the probability of existence of the deposit sought on the basis of successive exploration stages. Perhaps the most important way to reduce exploration risk is to employ personnel with the appropriate experience and yet who are learning.

Natural Resources Research↗