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Trace elements in streambed sediment and fish liver at selected sites in the Upper Colorado River Basin, Colorado 1995-96

Trace elements were analyzed in streambed-sediment samples collected from 16 sites and in fish-liver samples collected from 14 sites in the Upper Colorado River Basin in Colorado as part of the National Water-Quality Assessment program. Sites sampled represented agricultural, mining, mixed, and urban/recreation land uses and background conditions. The results for 15 trace elements in streambed-sediment and in fish-liver samples are presented in this report. Fourteen of the selected trace elements were detected in streambed-sediment samples collected at all sites. Twelve of the selected trace elements were detected in fish liver at more than 50 percent of the sites. Cadmium, copper, selenium, and zinc were selected for a more detailed analysis. Cadmium, copper, and zinc concentrations in streambed sediment were highest at mining land-use sites in the Southern Rocky Mountains physiographic province. Selenium concentrations in streambed sediment were highest at an agricultural land-use site in the Colorado Plateau physiographic province. The concentration of trace elements in streambed sediment generally increased as particle size decreased. Concentrations of trace elements in fish liver generally did not follow the same relation to land use as concentrations in streambed sediment; however, cadmium concentrations in fish liver were highest at a mining land-use site in the Southern Rocky Mountains physiographic province, and selenium concentrations in fish liver were highest at an agricultural land-use site in the Colorado Plateau physiographic province. Copper and zinc concentrations in fish liver were highest at mixed land-use sites. Comparison of streambed-sediment and fish-liver concentrations to two other similar NAWQA studies in the Rocky Mountain region generally indicated similar patterns in relation to land use for streambed sediment, but not for fish liver. Cadmium, copper, and zinc concentrations in streambed sediment were highest at sites affected by mining in all three study units. Selenium concentrations in streambed sediment did not indicate relations among the three study units when compared to land use. Cadmium in fish liver was highest at sites affected by mining in all three study units. Copper, selenium, and zinc in fish liver did not indicate relations among the three study units when compared to land use.

Colorado↗

Relations among rainstorm runoff, streamflow, pH, and metal concentrations, Summitville Mine area, upper Alamosa River basin, southwest Colorado, 1995-97

The upper Alamosa River Basin contains areas that are geochemically altered and have associated secondary sulfide mineralization. Occurring with this sulfide mineralization are copper, gold, and silver deposits that have been mined since the 1870's. Weathering of areas with sulfide mineralization produces runoff with anomalously low pH and high metal concentrations; mining activities exacerbate the condition. Summer rainstorms in the upper Alamosa River Basin produce a characteristic relation between streamflow and pH; streamflow suddenly increases and pH suddenly decreases (commonly by more than 1 pH unit). This report evaluates changes in pH in the upper Alamosa River Basin during July, August, and September 1995, 1996, and 1997 to examine possible adverse environmental effects due to rainstorm runoff. Ninety-three percent of the rainstorms occurring during 1995?97 produced runoff throughout the entire basin. Out of 54 storms, only 3 storms were isolated to the river reach upstream from the streamflow-gaging station Alamosa River above Wightman Fork, and only 1 storm was isolated to the river reach between the streamflow-gaging stations Alamosa River below Jasper and Alamosa River above Terrace Reservoir. Although most rainstorm runoff events occurred throughout the entire basin, pH changes were highest in parts of the basin that receive runoff from hydrothermally altered areas. The three principal altered areas within the basin are the Jasper, Stunner, and Summitville areas. Only limited mining occurred in the Stunner altered area, and yet significant decreases in pH values occur due to runoff from this area. Even after environmental restoration activities are completed at the Summitville Mine, the main stem of the Alamosa River may continue to be adversely affected by runoff from the Stunner and Jasper altered areas. A comparison of measured pH with Federal and State of Colorado water-quality standards and Toxicological Reference Values indicates pH was too low to support aquatic life in many parts of the basin for extended periods of time. Added stresses from sudden decreases in pH due to rainstorm runoff compound the adverse effects. Discharge of effluent from the Summitville Mine impoundment can significantly decrease pH in the Alamosa River downstream to Terrace Reservoir. A release of only 3 cubic feet per second from the impoundment decreased pH by at least 1 standard unit at all downstream sites. Low-flow years may pose a substantial risk to aquatic organisms within and downstream from Terrace Reservoir. During 1996, the basin had a low-flow year, and water storage and pool size of Terrace Reservoir were significantly reduced. The pH of water discharging from Terrace Reservoir was anomalously low during late August and September 1996, possibly due to geochemical interactions between sediment and the water column within the reservoir. In general, an inverse log-log relation exists between pH and the logarithm of dissolved metal concentrations, but the relations generally are not significant enough to confidently predict metal concentrations based upon measured pH values.

Water-Resources Investigations Report↗

Assessment of water quality, nutrients, algal productivity, and management alternatives for low-flow conditions, South Umpqua River basin, Oregon, 1990-92

This report is an evaluation of the effects of nutrient loading on water quality in the South Umpqua River Basin. The study was done by the U.S. Geological Survey in cooperation with Douglas County, Oregon. Five wastewater-treatment plants were shown to contribute less than 15 percent of the flow, but more than 90 percent of the nitrogen and phosphorus, in the South Umpqua River during low streamflows in summer. These nutrient inputs were associated with, and largely responsible for, the dense growth of periphytic algae that covered the rocky channel and produced biomass values as large as 340 grams of ash-free dry weight per square meter. The nighttime respiration of periphytic algae caused violations of the Oregon water-quality standard, which requires a dissolved oxygen concentration of at least 90 percent of saturation, at most sites along the South Umpqua River. Photosynthesis by algae during daylight resulted in many exceedances of the Oregon pH standard of 8.5. Net productivity, calculated from hourly measurements of dissolved oxygen concentrations, was as much as 3.8 grams of oxygen per square meter per day. The magnitude of productivity increased with increases in dissolved inorganic nitrogen concentration and load. The large amount of nutrient uptake by algae resulted in lowered nutrient concentrations downstream from nutrient point sources. Management alternatives for the South Umpqua River Basin include several methods to reduce nutrient concentrations and loads. The reduction of dissolved-inorganic-nitrogen and soluble- reactive-phosphorus loads from wastewater- treatment-plant effluent would reduce the frequency of violations of water-quality standards. Flow augmentation probably would decrease water-quality problems in the river, but it is difficult to predict the magnitude of the effects of increased velocity and decreased temperature on algal growth. Land application and storage of wastewater-treatment-plant effluent during the summer months would reduce the input of nutrients from point sources. Three exceedances of the Oregon standard for fecal coliform of 200 colonies per 100 milliliters were associated with large streamflows, suggesting that nonpoint sources affect the river during periods of high runoff. Fecal-streptococcus counts were larger than historical values and require confirmation. Ammonia from wastewater-treatment-plant effluent, high pH values, and high temperatures present a potential for chronic ammonia toxicity in the lower reaches of the South Umpqua River; however, actual violations of standards for chronic concentrations were not detected because of diel fluctuations in pH and water temperature.

Oregon↗

Mountain-front recharge along the eastern side of the Middle Rio Grande Basin, central New Mexico

Mountain-front recharge, which generally occurs along the margins of alluvial basins, can be a large part of total recharge to the aquifer system in such basins. Mountain-front recharge occurs as the result of infiltration of flow from streams that have headwaters in the mountainous areas adjacent to alluvial basins and ground- water flow from the aquifers in the mountainous areas to the aquifer in the alluvial basin. This report presents estimates of mountain-front recharge to the basin-fill aquifer along the eastern side of the Middle Rio Grande Basin in central New Mexico. The basin is a structural feature that contains a large thickness of basin-fill deposits, which compose the main aquifer in the basin. The basin is bounded along the eastern side by mountains composed of crystalline rocks of Precambrian age and sedimentary rocks of Paleozoic age. Precipitation is much larger in the mountains than in the basin; many stream channels debouch from the mountainous area to the basin. Chloride-balance and water-yield regression methods were used to estimate mountain-front recharge. The chloride-balance method was used to calculate a chloride balance in watersheds in the mountainous areas along the eastern side of the basin (subareas). The source of chloride to these watersheds is bulk precipitation (wet and dry deposition). Chloride leaves these watersheds as mountain-front recharge. The water-yield regression method was used to determine the streamflow from the mountainous watersheds at the mountain front. This streamflow was assumed to be equal to mountain-front recharge because most of this streamflow infiltrates and recharges the basin-fill aquifer. Total mountain-front recharge along the eastern side of the Middle Rio Grande Basin was estimated to be about 11,000 acre- feet per year using the chloride-balance method and about 36,000 and 38,000 acre-feet per year using two water-yield regression equations. There was a large range in the recharge estimates in a particular subarea using the different methods. Mountain-front recharge ranged from 0.7 to 15 percent of total annual precipitation in the subareas (percent recharge). Some of the smallest values of percent recharge were in the subareas in the southern part of the basin, which generally have low altitudes. The larger percent-recharge values were from subareas with higher altitudes. With existing information, determining which of the mountain- front recharge estimates is most accurate and the reasons for discrepancies among the different estimates is not possible. The chloride-balance method underestimates recharge if the chloride concentration used in the calculations for precipitation is too small or the chloride concentration in recharge is too large. Water-yield regression methods overestimate recharge if the amount of evapotranspiration of water that infiltrates into the channel bed of arroyos during runoff from summer thunderstorms is large.

Water-Resources Investigations Report↗

Ground-water development and the effects on ground-water levels and water quality in the town of Atherton, San Mateo County, California

The installation of at least 100 residential wells in the town of Atherton, California, during the 198792 drought has raised concerns about the increased potential for land subsidence and salt water intrusion. Data were collected and monitor ing networks were established to assess current processes and to monitor future conditions affect ing these processes. Data include recorded pump age, recorded operation time, and measured pumpage rates from 38 wells; water levels from 49 wells; water chemistry samples from 20 wells, and land-surface elevation data from 22 survey sites, including one National Geodetic Survey estab lished bench mark. Geologic, lithologic, climato logic, well construction, well location, and historical information obtained from available reports and local, state, and Federal agencies were used in this assessment. Estimates of annual residential pumpage from 269 assumed active residential wells in the study area indicate that the average annual total pumping rate is between 395 and 570 acre-feet per year. The nine assumed active institutional wells are estimated to pump a total of about 200 acre- feet per year, or 35 to 50 percent of the total resi dential pumpage. Assuming that 510 acre-feet per year is the best estimate of annual residential pumpage, total pumpage of 710 acre-feet per year would represent about 19 percent of the study area's total water supply, as estimated. Depth-to-water-level measurements in wells during April 1993 through September 1995 typically ranged from less than 20 feet below land surface nearest to San Francisco Bay to more than 70 feet below land surface in upslope areas near exposed bedrock, depending on the season. This range, which is relatively high historically, is attributed to above normal rainfall between 1993 and 1995. Water levels expressed as hydraulic heads indicate the presence of three different hydrologic subareas on the basis of hydraulic-head contour configurations and flow direction. That all measured hydraulic heads in the study area from April 1993 through September 1995 were above sea level indicates that saltwater intrusion was unlikely during this period. The chemistry of 20 well-water samples is characterized as a calcium magnesium carbonate bicarbonate type water. There is no evidence of saltwater intrusion from San Francisco Bay; how ever, water samples from wells nearest the bay and bedrock assemblages indicate a greater concentra tion of dissolved constituents and salinity. Dissolved-solids concentrations of water samples from wells in these areas exceeded 1,000 milli grams per liter, and several samples contained a substantial fraction of sodium and chloride. Water hardness for the 20 wells sampled averaged 471 milligrams per liter as calcium carbonate, which is classified as very hard. One well sample exceeded the primary maximum contaminant level for drinking water in nitrate, several wells exceeded the secondary maximum contaminant level for chloride and sulfate, and all wells sampled exceeded the secondary maximum contaminant level for total dissolved solids. Land-subsidence and the resultant damage because of excessive ground-water pumping, in combination with periodic drought, have a well- documented history in the south San Francisco Bay area. Land-elevation surveying data from 1934 to 1967 indicate that subsidence ranged from 0.1 to approximately 0.5 foot in the vicinity of the study area. It could not be determined from land- surface elevation surveying data from 1993 whether subsidence is currently occurring in the study area.

Water-Resources Investigations Report↗

Trends in concentrations of polychlorinated biphenyls in fish tissue from selected sites in the Delaware River basin in New Jersey, New York, and Pennsylvania, 1969-98

Polychlorinated biphenyl (PCB) concentrations in fish tissue collected during the 1990's from selected sites in the Delaware River Basin were compared with concentrations in fish tissue collected during 1969-88. Data collected by State and Federal agencies on concentrations in whole-body common carp ( Cyprinus carpio ) and white sucker ( Catostomus commersoni ), and edible portions of American eel ( Anguilla rostrata ), smallmouth bass ( Micropterus dolomieu ), and channel catfish ( Ictalurus punctatus ) during 1969-98 were compiled to define temporal trends in concentrations of PCBs in fish tissue from selected segments of the Delaware River, Lehigh River, Schuylkill River, and Brandywine Creek. The Delaware River in the vicinity of Trenton, New Jersey and Yardley, Pennsylvania (above the tidal influence) had the largest long-term data set among the sites considered for this study and was the only site with sufficient data for statistical analysis. A general pattern of decline in PCB concentrations during 1969-98 was apparent for this river segment. PCB concentrations in whole-body white sucker from this lower Delaware River segment declined during 1969-98 from a highest concentration of 7 micrograms per gram ( μ g/g, wet weight) in a sample collected during 1972 to 0.26 μ g/g (wet weight) in a sample collected during 1998. PCB concentration was negatively correlated with year (Spearman rank correlation -0.46, p < 0.08, n = 15); especially after removal of a sample from 1977 with an unusually low concentration (Spearman rank correlation -0.53, p = 0.05, n = 14). PCB concentrations in edible flesh of American eel declined during 1975-95, from a highest concentration of 3.8 μ g/g (wet weight) in a sample collected during 1976 to less than the reporting limit of 0.26 μ g/g (wet weight) in samples collected during 1993 and 1995. PCB concentrations in most samples (for species considered in this study) collected from the lower Delaware River exceeded the National Academy of Sciences and National Academy of Engineering (NAS/NAE) wildlife guideline level of 0.5 μ g/g during the 1970's and 1980's, and decreased to below this level during the 1990's. No samples of edible portions of game fish exceeded the U.S. Food and Drug Administration (FDA) tolerance level by the mid 1980's. However, the PCB concentration in a smallmouth bass fillet sample that was collected during 1998 (0.37 μ g/g) exceeded the Pennsylvania fish-consumption advisory level of 0.06 μ g/g, and the concentrations in whole-body common carp and white sucker collected during 1998 (1.10 μ g/g and 0.26 μ g/g, respectively) exceeded the New York State Department of Environmental Conservation wildlife criterion concentration of 0.11 μ g/g. (The concentration in carp also exceeded the 1973 NAS/NAE wildlife guideline concentration of 0.5 μ g/g.) Graphical analysis of PCB concentrations in whole white sucker and (or) edible portions of American eel from the upper Delaware River, lower Delaware River, middle Schuylkill River, and Brandywine Creek indicate a decline from the 1970's and (or) 1980's to the middle to late 1990's. Temporal trends in PCB concentrations in white sucker samples from the lower Lehigh and Schuylkill Rivers during 1979-98 are less clear; the PCB concentration (wet-weight basis) from a sample collected in 1998 from the lower Lehigh River was similar to that from a sample collected in 1979, and concentrations actually increased during 1982-98. Similarly, PCB concentrations in samples of white sucker and American eel from the lower Schuylkill River were highly variable over time.

New Jersey, New York, Pennsylvania↗

Trends in nutrients and suspended solids at the Fall Line of five tributaries to the Chesapeake Bay in Virginia, July 1988 through June 1995

Water-quality samples were collected at the Fall Line of five tributaries to the Chesapeake Bay in Virginia during a 6- to 7-year period. The water-quality data were used to estimate loads of nutrients and suspended solids from these tributaries to the non-tidal part of Chesapeake Bay Basin and to identify trends in water quality. Knowledge of trends in water quality is required to assess the effectiveness of nutrient manage- ment strategies in the five basins. Multivariate log-linear regression and the seasonal Kendall test were used to estimate flow-adjusted trends in constituent concentration and load. Results of multivariate log-linear regression indicated a greater number of statistically significant trends than the seasonal Kendall test; how-ever, when both methods indicated a significant trend, both agreed on the direction of the trend. Interpre- tation of the trend estimates for this report was based on results of the parametric regression method. No significant trends in total nitrogen concentration were detected at the James River monitoring station from July 1988 through June 1995, though total Kjeldahl nitrogen concen- tration decreased slightly in base-flow samples. Total phosphorus concentration decreased about 29 percent at this station during the sampling period. Most of the decrease can be attributed to reductions in point-source phosphorus loads in 1988 and 1989, especially the phosphate detergent ban of 1988. No significant trends in total suspended solids were observed at the James River monitoring station, and no trends in runoff- derived constituents were interpreted for this river. Significant decreases were detected in concentrations of total nitrogen, total Kjeldahl nitrogen, dissolved nitrite-plus-nitrate nitrogen, and total suspended solids at the Rappahannock River monitoring station between July 1988 and June 1995. A similar downward trend in total phosphorus concentration was significant at the 90-percent confidence level, but not the 95-percent confidence level. These decreases can be attributed primarily to reductions in nonpoint nutrient and sediment loads, and may have been partially caused by implementation of best management practices on agricultural and silvicultural land. Flow-adjusted trends observed at the Appomattox, Pamunkey, and Mattaponi monitoring stations were more difficult to explain than those at the James and Rappahannock stations. Total Kjeldahl nitrogen and total phosphorus increased 16 and 23 percent, respectively, at the Appomattox River monitoring station from July 1989 through June 1995. Total phosphorus concentration increased about 46 percent at the Pamunkey River monitoring station between July 1989 and June 1995. At the Mattaponi River monitoring station, decreases in dissolved nitrite-plus-nitrate nitrogen were offset by increases in total Kjeldahl nitrogen, resulting in no net change in total nitrogen concentration from October 1989 through June 1995.

Water-Resources Investigations Report↗

Hydrogeology of the interstream area between Ty Ty Creek and Ty Ty Creek tributary near Plains, Georgia

This report is part of an interdisciplinary effort to identify and describe processes that control movement and fate of selected fertilizers and pesticides in the surface and subsurface environments in the Fall Line Hills district of the Georgia Coastal Plain physiographic province. This report describes the hydrogeology of the interstream area between Ty Ty Creek and it's tributary near Plains, Sumter County, Georgia. Geologic units of interest to this study are, in ascending order, (1) the Tuscahoma Formation, a bluish gray, silty clay; (2) the Tallahatta Formation, a fine-to-coarse, poorly sorted quartz sand that is divided into an upper and lower unit; and (3) the undifferentiated overburden, which consists of fine to medium poorly sorted sand, silt and clay. Continuous-core samples indicate that the unsaturated zone includes the undifferentiated overburden and the upper unit of the Tallahatta Formation, and attains a maximum thickness of about 52 feet (ft) in the southern part of the study area. The Claiborne aquifer in the study area consists of the lower unit of the Tallahatta Formation and ranges in thickness from 3 ft near Ty Ty Creek tributary to about 20 ft in the upland divide area. It is confined below by the clayey sediments of the Tuscahoma Formation. The Claiborne aquifer in the study area generally is confined above by an extensive clay layer that is the base if the upper unit of the Tallahatta Formation. Fluctuations in the amount of vertical recharge to the aquifer result in areal and temporal changes in aquifer conditions from confined to unconfined in parts of the study area. Hydraulic conductivity of the aquifer ranges from 3.5 to 7 feet per day. The transmissivity of the aquifer is approximately 50 feet squared per day. Water-level data indicate the potentiometric surface slopes to the south, southeast, and southwest with a gradient of about 87 to 167 feet per mile. The shape of the potentiometric surface and the direction of groundwater flow remains relatively unchanged during high and low water-level periods. Water levels in the Claiborne aquifer fluctuated by a maximum of 6 ft during the period from January to December 1991. Recharge to the Claiborne aquifer consists of a local and regional flow component. Lateral ground-water flow (regional flow) into the study area is dependent on regional hydraulic controls (pumpage, stream discharge, and rainfall). The rate of lateral movement of ground water is dependent on the hydraulic conductivity of the saturated zone, the hydraulic gradient, and other hydraulic factors, and is considered to be relatively constant. Local recharge enters the ground-water system as rainfall that percolates down to the water table. Annual water-level fluctuations in the Claiborne aquifer indicate that the majority of regional and local recharge occurs in the interstream area with recharge decreasing downslope to the streams. Ground water discharges to Ty Ty Creek and it's tributary throughout the year during low and high water-level periods.

Georgia↗

Sediment transport, particle sizes, and loads in lower reaches of the Chippewa, Black, and Wisconsin Rivers in Western Wisconsin

Hydraulic and sediment data were collected at three sites on the Chippewa River (near Caryville, at Durand, and near Pepin); at one site near Galesville on the Black River; and at one site at Muscoda on the Wisconsin River during water years 1976-83. This report summarizes an interpretation of those data by providing (1) a description of the relation of suspended sediment, bedload, and total-sediment discharge to water discharge; (2) a description of particle-size characteristics of bed material, bedload, and suspended sediment; and (3) estimates of annual and average annual suspended load, bedload, and total-sediment load for water years 1974-83. Direct measurement with a Helley-Smith bedload sampler and calculations by the modified-Einstein procedure were used to estimate bedload. Single equations describe the suspended- and totalsediment transport-rate relations for Chippewa River at Durand and main channel at Pepin, and the Black River near Galesville. Two equations were needed to define the transport- rate relations for the Chippewa River near Caryville and Wisconsin River at Muscoda. Bed material at all sites except Chippewa River near Caryville were of similar particle size and exhibited little variation with time or location in the river cross sections. Median diameter at these sites ranged from 0.35 to 0.84 mm (millimeter). At Chippewa River near Caryville, median diameter ranged from 0.42 to 15 mm. Helley-Smith bedload at Chippewa River at Durand and near Pepin, Black River near Galesville, and Wisconsin River at Muscoda were of similar particle size. About 57 to 65 percent of bedload at all sites except Chippewa River near Caryville was in the 0.4- to 0.6- mm size range. About 50 percent of bedload at Chippewa River near Caryville was in the 0.5- to 1.0-mm size range. Suspended sediment at all sites except Chippewa River near Caryville was in the sand-size range; the average median diameters were between 0.17 and 0.22 mm. At Chippewa River near Caryville, 60 percent (on the average) of suspended sediment was finer than 0.062 mm. Average annual total-sediment load and the percentage transported as bedload were determined for a 10-year period (water years 1974-83)(October 1,1973-September 30, 1982). These loads and percentages were, respectively, 123,000 tons and 35 percent at Chippewa River near Caryville; 1,073,000 tons and 61 percent at Chippewa River at Durand; 940,000 tons and 44 percent at Chippewa River near Pepin; 277,000 tons and 43 percent at Black River near Galesville; and 558,000 tons and 49 percent at Wisconsin River at Muscoda.

Wisconsin↗

Hydrology and water quality of Powers Lake, southeastern Wisconsin

This report describes the hydrology and water quality of Powers Lake, a recreational lake in a densely populated area of southeastern Wisconsin, from October 16, 1986 - October 15, 1987. The hydrologic budget for the study period showed that direct precipitation on the lake and ground water were dominant sources of water entering the lake (37 and 36 percent, respectively) and that streamflow dominated the outflow. Surface runoff contributed 27 percent of the inflow-23 percent from Powers Lake inlet and 4 percent from shoreline drainage. Streamflow through Powers Lake outlet accounted for 62 percent of the outflow and evaporation accounted for 38 percent. Based on the streamflow from Powers Lake outlet, the lake's hydraulic residence time was 3.8 years. During the study period, precipitation was 27.16 inches or 4.08 inches below long-term (1951-80) average. The data were adjusted or normalized to represent an average year of precipitation and runoff to help evaluate the water quality of the lake for an average year. For an average year, precipitation dominated inflow (42 percent), followed by ground water (32 percent), Powers Lake inlet (21 percent), and shoreline drainage (5 percent). Streamflow through Powers Lake outlet accounted for 61 percent of an average year's outflow budget and the remaining 39 percent was evaporation. Based on an average year's streamflow from Powers Lake outlet, the lake's hydraulic residence time was 4.2 years. Phosphorus budgets were prepared for the study period and for an estimated normal year. The phosphorus budget for the study period showed that, of the total inputs (516 pounds), surface runoff contributed the largest amount; shoreline drainage contributed 44 percent, and Powers Lake inlet contributed 36 percent. Direct precipitation contributed 11 percent; ground water, 2 percent; and septic systems, 7 percent. Of the total outputs, 83 pounds (16 percent) was lost from the lake via the outlet; 433 pounds (84 percent) was lost to the sediments as the phosphorus that was attached to particles settled to the lake bottom. An estimated phosphorus budget for a normal year showed that of the total inputs (744 pounds), surface runoff contributed the largest amount; Powers Lake inlet contributed 45 percent and shoreline drainage contributed 35 percent. Precipitation contributed 9 percent; ground water, 1 percent; and septic systems, 10 percent. The health of the lake was evaluated using Carlson's Trophic State Index and Vollenweider's model. Carlson's Trophic State Index showed that Powers Lake was moderately enriched and in the mesotrophic range. Comparison of guidelines from Vollenweider's model showed that the total phosphorus input for the study period and for an estimated average year would not cause eutrophic conditions.

Wisconsin↗

Occurrence of organochlorine compounds in whole fish tissue from streams of the lower Susquehanna River Basin, Pennsylvania and Maryland, 1992

Tissue samples of whole body white sucker ( Catostomus commersoni ) were collected at 15 sites and smallmouth bass ( Micropterus dolomieu ) were collected at 5 sites during 1992 in the Lower Susquehanna River Basin to determine the occurrence and distribution of 28 selected organochlorine compounds as part of the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Program. Only 12 of the 28 compounds occurred at concentrations greater than the 5 µg/kg reporting limit (total PCB’s reporting limit is ‹50 µg/kg and toxaphene is ‹200 µg/kg). The most frequently reported compounds were p,p ’-DDE (reported in all tissue samples), total polychlorinated biphenyls (PCB’s), and trans-nonachlor. High concentrations of p,p’ -DDE and low concentrations of the other DDT metabolites for the Lower Susquehanna River sites indicate no recent influx of DDT. Comparison with historical data from the Lower Susquehanna River Basin shows a decline of organochlorine concentrations within the basin. In 1987, Quittapahilla Creek had the highest concentrations of p,p’ -DDE in a national survey of contaminant occurrence in fish tissue conducted by the U.S. Environmental Protection Agency. This stream ranked the highest for total DDT of the 20 NAWQA studies started nationally in 1991. Total DDT concentrations were higher in agriculture-dominated (>50 percent) sites than in forest-dominated (>50 percent) sites with the exception of Deer Creek and Big Beaver Creek. These two sites are located more in grazing areas that lack a substantial crop-land use. Concentrations of total PCB’s were highest in basins with greater than 10 percent urban land use excluding the larger river sites. Concentrations of total chlordane were highest at sites with greater than 70 percent agricultural and 10 percent urban land use. Regional comparisons of total DDT, total PCB’s, and total chlordane in white sucker tissue from the Lower Susquehanna, Hudson (in New York), and Connecticut River Basins showed that median concentrations of total DDT were different (p=0.05), with the Lower Susquehanna Basin being the lowest. Total PCB’s and total chlordane medians were similar. Comparison of the data from national and regional studies with data from this local study showed concentrations of p,p’ -DDE in the Lower Susquehanna River Basin are similar to those nationwide and lower than the concentrations measured in the Northeast. PCB concentrations in the Lower Susquehanna River Basin and the Northeast were higher than those nationwide.

Water-Resources Investigations Report↗

SUTRA: A model for 2D or 3D saturated-unsaturated, variable-density ground-water flow with solute or energy transport

SUTRA (Saturated-Unsaturated Transport) is a computer program that simulates fluid movement and the transport of either energy or dissolved substances in a subsurface environment. This upgraded version of SUTRA adds the capability for three-dimensional simulation to the former code (Voss, 1984), which allowed only two-dimensional simulation. The code employs a two- or three-dimensional finite-element and finite-difference method to approximate the governing equations that describe the two interdependent processes that are simulated: 1) fluid density-dependent saturated or unsaturated ground-water flow; and 2) either (a) transport of a solute in the ground water, in which the solute may be subject to: equilibrium adsorption on the porous matrix, and both first-order and zero-order production or decay; or (b) transport of thermal energy in the ground water and solid matrix of the aquifer. SUTRA may also be used to simulate simpler subsets of the above processes. A flow-direction-dependent dispersion process for anisotropic media is also provided by the code and is introduced in this report. As the primary calculated result, SUTRA provides fluid pressures and either solute concentrations or temperatures, as they vary with time, everywhere in the simulated subsurface system. SUTRA flow simulation may be employed for two-dimensional (2D) areal, cross sectional and three-dimensional (3D) modeling of saturated ground-water flow systems, and for cross sectional and 3D modeling of unsaturated zone flow. Solute-transport simulation using SUTRA may be employed to model natural or man-induced chemical-species transport including processes of solute sorption, production, and decay. For example, it may be applied to analyze ground-water contaminant transport problems and aquifer restoration designs. In addition, solute-transport simulation with SUTRA may be used for modeling of variable-density leachate movement, and for cross sectional modeling of saltwater intrusion in aquifers at near-well or regional scales, with either dispersed or relatively sharp transition zones between freshwater and saltwater. SUTRA energy-transport simulation may be employed to model thermal regimes in aquifers, subsurface heat conduction, aquifer thermal-energy storage systems, geothermal reservoirs, thermal pollution of aquifers, and natural hydrogeologic convection systems. Mesh construction, which is quite flexible for arbitrary geometries, employs quadrilateral finite elements in 2D Cartesian or radial-cylindrical coordinate systems, and hexahedral finite elements in 3D systems. 3D meshes are currently restricted to be logically rectangular; in other words, they are similar to deformable finite-difference-style grids. Permeabilities may be anisotropic and may vary in both direction and magnitude throughout the system, as may most other aquifer and fluid properties. Boundary conditions, sources and sinks may be time dependent. A number of input data checks are made to verify the input data set. An option is available for storing intermediate results and restarting a simulation at the intermediate time. Output options include fluid velocities, fluid mass and solute mass or energy budgets, and time-varying observations at points in the system. Both the mathematical basis for SUTRA and the program structure are highly general, and are modularized to allow for straightforward addition of new methods or processes to the simulation. The FORTRAN-90 coding stresses clarity and modularity rather than efficiency, providing easy access for later modifications.

Water-Resources Investigations Report↗

Arsenic and selenium in soils and shallow ground water in the Turtle Lake, New Rockford, Harvey Pumping, Lincoln Valley, and LaMoure irrigation areas of the Garrison Diversion Unit, North Dakota

The Garrison Diversion Unit project was authorized as part of the Pick-Sloan Missouri River Basin program to divert water from Lake Sakakawea to irrigation areas in North Dakota. A special Garrison Commission was created to evaluate an environmental concern that return flow from the irrigation areas might contain metals in toxic concentrations. This report summarizes the results of detailed investigations of the Turtle Lake, New Rockford, Harvey Pumping, Lincoln Valley, and LaMoure irrigation areas. A total of 223 soil samples were collected from the irrigation areas and analyzed for elemental composition. Water extractions were done on 40 of the 223 soil samples using a 1:5 soil-to-water extraction method, and the solution from the extraction was analyzed for elemental composition. A total of 52 ground-water samples were collected and analyzed for inorganic constituents and organic carbon. Average arsenic concentrations in the entire soil column ranged from 1.0 milligram per kilogram in the Harvey Pumping irrigation area to 70 milligrams per kilogram in the New Rockford irrigation area. Average selenium concentrations ranged from less than 0.1 milligram per kilogram in the Turtle Lake, New Rockford, Harvey Pumping, and Lincoln Valley irrigation areas to 6.0 milligrams per kilogram in the Turtle Lake irrigation area. In the Turtle Lake irrigation area, average arsenic and selenium concentrations generally increased with depth through the topsoil, oxidized soil, and transition soil but decreased in the reduced soil at the bottom of the sampled horizons. Average arsenic concentrations in the New Rockford irrigation area follow the same pattern as in the Turtle Lake irrigation area, but selenium concentrations do not show a clear pattern of variation with depth. In the Harvey Pumping and Lincoln Valley irrigation areas, arsenic and selenium concentrations do not appear to vary systematically with depth. No correlation is shown between the concentrations in soils and soil extracts, indicating that, based on conditions of laboratory soil-water extraction experiments, trace-element concentrations in soils are not good predictors of trace-element concentrations in irrigation return flow. Arsenic concentrations in the aquifers ranged from less than 1 microgram per liter to 27 micrograms per liter. Arsenic concentrations generally were larger in the deep part of the aquifers underlying the Turtle Lake and New Rockford irrigation areas than in the shallow part of the aquifers. In the shallow part of the aquifers, where oxidizing conditions prevail, arsenic is strongly adsorbed to soil particles. In the deep part of the aquifers, where reducing conditions prevail, arsenic is more mobile. Selenium concentrations in the aquifers ranged from less than 1 microgram per liter to 4 micrograms per liter. Little difference existed between the selenium concentrations in the shallow part of the aquifers underlying the irrigation areas and the concentrations in the deep part of the aquifers.

Water-Resources Investigations Report↗

Availability and Quality of Water from Underground Coal Mines in Johnson and Martin Counties, Kentucky

This report provides water users with detailed information on the location, quantity, and quality of water available from underground coal mines in the Breathitt Formation of Pennsylvanian age in part of eastern Kentucky. The principal coal seams mined are the Van Lear in Johnson County and the Alma in Martin County. Coal mines that contained water were located by field inventory and coal-mine maps. The principal factors that affect the occurrence of water in coal mines are the size of the recharge area overlying the mine, the intensity and duration of precipitation, and the altitude of the mine relative to that of the nearest perennial stream. Ten above-drainage mines (that is, mines at higher elevations than that of the nearest perennial stream) are considered potential sources of water. Discharge from these mines ranged from 12 to 1,700 gallons per minute. The highest sustained discharge from a mine ranged from 750 to 1,200 gallons per minute. The water in coal mines is part of the hydrologic system and varies seasonally with precipitation. Annual discharge from most above-drainage mines ranged from 3 to 10 percent of annual precipitation on the 1and-surface area above the mine. Eight below-drainage mines are considered potential sources of water. Two were test-pumped at rates of 560 to 620 gallons per minute for as long as 6 hours. After test pumping the Warfield Mining No. 1 mine during September 1977 and March 1978, the recovery (or recharge) rates were significantly different. In September, the recharge rate was about 1,150 gallons per minute, but in March the recharge rate was 103,500 gallons per minute. This difference reflects the seasonal variations in the amount of water available to the ground-water system. Estimates of water stored in below-drainage mines ranged from 22 to 1,462 million gallons. This storage represents a safety factor sufficient to provide water through periods of limited recharge to the mine. Most mine water is of the calcium magnesium sulfate type. In general, water from below-drainage mines had lower concentrations of dissolved constituents and higher pH than water from mines above drainage. The hardness of water ranged from soft to very hard and pH ranged -from 3.1 to 8.0 units. Dissolved iron ranged from 0.01 to 64 milligrams per liter. Phenol concentrations in water from eight coal mines ranged from 0 to 5 micrograms per liter. There seems to be a significant difference in the chemical quality of water from above- and below-drainage mines. The concentration of most constituents was lower in water from below-drainage mines than it was from above-drainage mines. The better quality water from below-drainage mines may reflect (1) lower mineralization resulting from less atmospheric oxygen available to react with pyrite or, (2) the result of sampling only the upper zones of water in below-drainage mines where the water has been diluted by less mineralized surface water or inflow or recharge.

Water-Resources Investigations Report↗

Simulation of regional ground-water flow in the Upper Deschutes Basin, Oregon

This report describes a numerical model that simulates regional ground-water flow in the upper Deschutes Basin of central Oregon. Ground water and surface water are intimately connected in the upper Deschutes Basin and most of the flow of the Deschutes River is supplied by ground water. Because of this connection, ground-water pumping and reduction of artificial recharge by lining leaking irrigation canals can reduce the amount of ground water discharging to streams and, consequently, streamflow. The model described in this report is intended to help water-management agencies and the public evaluate how the regional ground-water system and streamflow will respond to ground-water pumping, canal lining, drought, and other stresses. Ground-water flow is simulated in the model by the finite-difference method using MODFLOW and MODFLOWP. The finite-difference grid consists of 8 layers, 127 rows, and 87 columns. All major streams and most principal tributaries in the upper Deschutes Basin are included. Ground-water recharge from precipitation was estimated using a daily water-balance approach. Artificial recharge from leaking irrigation canals and on-farm losses was estimated from diversion and delivery records, seepage studies, and crop data. Ground-water pumpage for irrigation and public water supplies, and evapotranspiration are also included in the model. The model was calibrated to mean annual (1993-95) steady-state conditions using parameter-estimation techniques employing nonlinear regression. Fourteen hydraulic-conductivity parameters and two vertical conductance parameters were determined using nonlinear regression. Final parameter values are all within expected ranges. The general shape and slope of the simulated water-table surface and overall hydraulic-head distribution match the geometry determined from field measurements. The fitted standard deviation for hydraulic head is about 76 feet. The general magnitude and distribution of ground-water discharge to streams is also well simulated throughout the model. Ground-water discharge to streams in the area of the confluence of the Deschutes, Crooked, and Metolius Rivers is closely matched. The model was also calibrated to transient conditions from 1978 to 1997 using traditional trial-and-error methods. Climatic cycles during this period provided an excellent regional hydrologic signal for calibration. Climate-driven water-level fluctuations are simulated with reasonable accuracy over most of the model area. The timing and magnitude of simulated water-level fluctuations caused by annual pulses of recharge from precipitation match those observed reasonably well, given the limitations of the time discretization in the model. Water-level fluctuations caused by annual canal leakage are simulated very well over most of the area where such fluctuations occur. The transient model also simulates the volumetric distribution and temporal variations in ground-water discharge reasonably well. The match between simulated and measured volume of and variations in ground-water discharge is, however, somewhat dependent on geographic scale. The rates of and variations in ground-water discharge are matched best at regional scales. Example simulations were made to demonstrate the utility of the model for evaluating the effects of ground-water pumping or canal lining. Pumping simulations show that pumped water comes largely from aquifer storage when pumping begins, but as the water table stabilizes, the pumping increasingly diminishes the discharge to streams and, hence, streamflow. The time it takes for pumping to affect streamflow varies spatially depending, in general, on the location of pumping relative to the discharge areas. Canal-lining simulations show similar effects.

Water-Resources Investigations Report↗

Ground-water quality in Bannock, Bear Lake, Caribou, and part of Power counties, southeastern Idaho

This report provides information about the current quality of ground waters in southeastern Idaho and discusses the natural and manmade environmental controls on that quality. This information will be useful in planning and monitoring the development and use of the ground-water resources of southeastern Idaho. The southeastern corner of Idaho, as described in this report, encompasses an area of about 4,000 mil in Bannock, Bear Lake, Caribou, and part of Power Counties. The popu- lation of the area in 1975, based on best estimates by the Idaho Division of Budget, Policy Planning, and Coordination (1976) was 75,200. About 80 percent of the population is in and near the city of Pocatello, which is the second largest population center in the State. Pocatello's economy depends largely on manufacturing and industrial processing, which includes chemicalfertilizer plants. The econ- omy in the rural areas depends largely on agriculture--both dry and irrigated farming are practiced. Mining is important and expected to dominate the economy in the eastcentral part of the area in the future. Natural resources include phosphate ore, which makes up about 35 percent of the U.S. reserves (U.S. Department of Interior and U.S. Department of Agriculture, 1977); ground water, which mostly underlies the several intermontane valleys that dissect the area; and hot springs, which indicate that geothermal energy sources may underlie part of the area. Also, current (1978) speculation is that petroleum reserves may be present in the vicinity of Bear Lake. Development of more sprink- ler-irrigated lands, increases in population, and growth of phosphate mining are expected to place stress on the ground-water resources, both in quality and quantity. The purpose of this report is to present the results of a study whose primary objectives were (1) to provide current waterquality data representative of the water in several different aquifers (water- bearing formations) in the study area, and (2) to relate these data to natural and manmade environmental controls. The wells sampled during this study establish a quasi-network, which could be resampled in the future to document and analyze changes (if any) in ground-water quality. Based on this information, planners and water managers could better understand the causeand-effect relations controlling water quality and could better manage land and water-resource development. The report is designed for ease of reading and presentation. It uses maps, tables, and abbreviated text to describe geology, hydrology, and ground-water quality and how they are interrelated. Some practical ways for improving water quality are discussed for the benefit of individual water users. The field data collected in making the study are contained in the Data Section of this report. The authors gratefully acknowledge the many individual well owners, municipal officials, and private industries that provided well information and allowed access to their properties and collection of water samples. Without their help, this work could not have been done. Water samples were collected at 103 well sites. Waterlevel measurements were made at 98 of these sites during July, August, and September of 1976. This study was made by the U.S. Geological Survey in cooperation with the Idaho Department of Water Resources. A similar study is being made (1978) in north Idaho. Other studies are planned, specifically to obtain ground-water-quality data in areas where land and water-resource development is expected or accelerating.

Idaho↗

Trichloroethylene and 1,1-dichloroethylene concentrations in ground water after temporary shutdown of the reclamation well field at Air Force Plant 44, Tucson, Arizona, 1999

Industrial activities beginning in the early 1940s resulted in extensive contamination of ground water near the Tucson International Airport, Tucson, Arizona, including an area around Air Force Plant 44, an industrial facility located on land owned by the U.S. Air Force and operated by a defense contractor. Principal ground-water contaminants are volatile organic compounds, primarily trichloroethylene (also called trichloroethene) and 1,1-dichloroethylene (also called 1,1-dichloroethene). A ground- water reclamation system was put into operation in 1987 to extract and treat contaminated ground water at Air Force Plant 44 and the downgradient area that is south of Los Reales Road. The ground- water reclamation system consists of 25 extraction wells, 22 recharge wells, and a water-treatment facility. Soil-vapor extraction techniques are being used to remove volatile organic compounds from the unsaturated zone. More than 120,000 pounds of volatile organic compounds have been removed from the regional aquifer and overlying unsaturated zone at Air Force Plant 44 and adjacent downgradient areas south of Los Reales Road. Air Force Plant 44 and adjacent areas being remediated by the ground-water reclamation system are about 7 square miles. To assess ground-water cleanup progress at Air Force Plant 44 and surrounding areas south of Los Reales Road, and possibly to identify areas that are resistant to cleanup attempts, ground-water samples were collected and analyzed after water levels had returned to near-equilibrium conditions following a 3-week shutdown of extraction and recharge wells. Modifications of the standard ground-water sampling procedures used at the site also were tested. The modifications included tests of a reduced-flow purging and sampling method in six monitoring wells and vertical- profile sampling in five extraction wells at the reclamation well field. The water treatment facility and all extraction and recharge wells at the reclamation well field were shut down on April 15, 1999, and water levels were allowed to recover for about 3 weeks before samples of ground water were obtained from 102 wells at Air Force Plant 44 and surrounding areas. Concentrations of trichloroethylene and 1,1-dichloroethylene were determined for samples obtained during the sitewide sampling effort. Data for 101 wells sampled in February 1999 before shutdown were compared with data obtained for wells sampled in May 1999 after shutdown. Concentrations of trichloroethylene increased in 36 wells, remained the same in 32 wells, and decreased in 33 wells. Increases in concentrations of trichloroethylene of as much as 1,476 micrograms per liter and decreases of as much as 2,292 micrograms per liter were reported after shutdown. Concentrations of trichloroethylene remained the same for the two sampling periods in wells that had concentrations that were at, or close to, the lower reporting limit (0.5 micrograms per liter) before shutdown. Net change in concentrations of trichloroethylene after shutdown on a percentage basis ranged from an increase of 1,300 percent to a decrease of 100 percent. Increases in concentrations of 1,1-dichloroethylene after shutdown of the reclamation well field of as much as 66 micrograms per liter and decreases of as much as 411.6 micro- grams per liter were reported. Concentrations of 1,1-dichloroethylene remained the same for the two sampling periods in wells that had concentrations that were at, or close to, the lower reporting limit (0.5 micrograms per liter) before shutdown. Net change in concentrations of 1,1-dichloroethylene after shutdown on a percentage basis ranged from an increase of 660 percent to a decrease of 100 percent. Data obtained from the water samples indicate that the largest changes in concentrations of trichloroethylene and 1,1-dichloroethylene occurred in samples collected from wells completed in the upper zone of the regional aquifer, along the axis of the contaminant plume, in close proximity to previously identified historical disposal areas. Changes in contaminant concentrations observed after shutdown of the well field probably were the result of changes in ground-water flow directions under nonpumping conditions compared with those present when the extraction and recharge wells were operating. Minimal changes occurred at the perimeter of the plume, which suggests that operation of the reclamation well field has been successful at containing the spread of the plume. New contaminant-source areas were not identified within the perimeter of the plume. A modification of the standard sampling technique used at Air Force Plant 44 was tested in six wells. In these wells, greatly reduced flow rates were used for well purging and sampling. Results indicate no distinct pattern of change of contaminant concentrations compared with concentrations in samples subsequently obtained using the standard technique, and no advantage was evident for using this method in routine sampling of the monitoring wells at Air Force Plant 44. Temperature profiles obtained before vertical-profile sampling of selected wells indicate little temperature variation with depth. The temperature-profile information suggests that under nonpumping conditions, most of the water enters these wells near the top of the screened interval and moves downward in response to a hydraulic gradient in the regional aquifer. Samples at depths below the top of the screened interval probably do not accurately represent water from the adjacent sediments. Vertical-profile samples were obtained in five wells and analyzed for concentrations of trichloroethylene. None of the wells showed large enough variation of contaminant concentrations with depth to indicate that a major improvement in extraction efficiency could be obtained by pumping selectively from a restricted interval. The largest variation in concentrations of trichloroethylene with depth that was observed ranged from 62 micrograms per liter near the top of the screened interval to 42 micrograms per liter near the bottom of the screened interval of one of the wells. The lack of large variation is probably the result of downward water flow in the casing of these wells.

Arizona↗

Numerical simulation of ground-water flow in La Crosse County, Wisconsin, and into nearby pools of the Mississippi River

This report describes a two-dimensional regional screening model and two associated three-dimensional ground-water flow models that were developed to simulate the ground-water flow systems in La Crosse County, Wisconsin, and Pool 8 of the Mississippi River. Although the geographic extents of the three-dimensional models were slightly different, both were derived from the same geologic interpretation and regional screening model, and their calibrations were performed concurrently. The objectives of the La Crosse County (LCC) model were to assess the effects of recent (1990s) and potential future ground-water withdrawals and to provide a tool suitable to evaluate the effects of proposed water-management programs. The Pool 8 model objectives were to quantify the magnitude and distribution of ground-water flow into the Pool. The Wisconsin Geological and Natural History Survey and the U.S. Geological Survey developed the models cooperatively. The report describes: 1) the conceptual hydrogeologic model; 2) the methods used in simulating flow; 3) model calibration and sensitivity analysis; and 4) model results, such as simulation of predevelopment conditions and location and magnitude of ground-water discharge into Pool 8 of the Mississippi. Three aquifer units underlie the model area: 1) a shallow unconsolidated sand and gravel aquifer; 2) an upper bedrock aquifer, composed of Cambrian and Ordovician sandstone and dolomite; and 3) a lower bedrock aquifer composed of Cambrian sandstone of the Eau Claire Formation and the Mount Simon Formation. A shale layer that is part of the Eau Claire Formation forms a confining unit separating the upper and lower bedrock aquifers. This confining unit is absent in the Black River and parts of the La Crosse and Mississippi River valleys. Precambrian crystalline basement rock forms the lower base of the ground-water flow system. The U.S. Geological Survey ground-water flow model code, MODFLOW, was used to develop the La Crosse County (LCC) and Pool 8 ground-water flow models. Boundary conditions for the MODFLOW model were extracted from an analytic element screening model of the regional flow system surrounding La Crosse County. Model input was obtained from previously published and unpublished geologic and hydrologic data. Pumpages from municipal and high-capacity wells were also simulated. Model calibration included a comparison of modeled and field-measured water levels and field-measured base flows to simulated stream flows. At calibration, most measured water levels compared favorably to model-calculated water levels. Simulated streamflows at two targets were within 3 percent of estimated measured base flows. Mass balance results from the LCC and Pool 8 models indicated that 63 to 74 percent of ground water was from recharge and 19 to 26 percent was from surface-water sources. Ground-water flow out of the model was to rivers and streams (85 to 87 percent) and pumping wells (11 and 13 percent). The model demonstrates the effects of development on ground water in the study area. The maximum simulated water-level decline in the city of La Crosse metropolitan area is 9.3 feet. Simulated stream losses are similar to the amount of ground water pumped by wells. This indicates that ground water withdrawn by La Crosse County wells is water that under predevelopment conditions discharged to streams and lakes. The models provide estimates of the locations and amount of ground-water flow into Pool 8 and the southern portion of Pool 7 of the Mississippi River. Ground-water discharges into all areas of the pools, except along the eastern shore in the vicinity of the city of La Crosse and immediately downgradient from lock and dam 7 and 8. Ground-water flow into the pools is generally greatest around the perimeter with decreasing amounts away from the perimeter. An area of relatively high ground-water discharge extends out towards the center of Pool 7 from the upper reaches of the pool and may

Wisconsin↗