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Relation of periphyton and benthic invertebrate communities to environmental factors and land use at selected sites in part of the upper Mississippi River basin, 1996-98

The Upper Mississippi River Basin is one of the hydrologic systems selected for study by the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey. NAWQA utilizes a multi-disciplinary approach to explain factors that affect water quality. Part of the NAWQA design addresses the relation of land use and environmental factors to periphyton and benthic invertebrate communities in streams. This report focuses on a 122,000 square kilometer area of the Mississippi River Basin, including the Twin Cities metropolitan area (TCMA). The northeastern part of the study area is forested, the southwestern part is agricultural, and the central part is transitional between forest and agriculture. Sampling sites were selected based on a process that identified small streams in predominantly forested, agricultural, and urban settings, and large river sites on the Mississippi River and major tributaries. Periphyton and benthic invertebrate communities were evaluated at each site. Compared to the forested site, periphyton density and biovolume in small streams generally increased as nutrient concentrations associated with urban and agricultural land use increased. Periphyton communities varied within agricultural and urban streams, indicating that physical and chemical factors other than land use also affect periphyton communities. Benthic invertebrate communities also are affected by land use and associated stream habitat. There were few intolerant taxa (Ephemeroptera and Plecoptera) in urban streams, potentially due to high streamflow variability and contaminants from runoff. Ephemeroptera taxa richness was greatest in the agricultural streams. The most abundant Ephemeroptera taxa were those tolerant to high concentrations of suspended sediment. Richness of Plecoptera and Trichoptera taxa were greatest in the forested stream. Biological communities in the St. Croix and Minnesota River generally reflected relatively homogeneous land uses. Biological communities in the Mississippi River reflected changes in water quality and physical habitat as the Minnesota and St. Croix Rivers join the Mississippi River. Periphyton density and biovolume, and the relative abundance of blue-green algae density increased in the Mississippi River at the confluence compared to the Minnesota and St. Croix Rivers. Relative abundance of benthic invertebrate taxa richness and diversity generally decreased downstream in the large rivers as urban and agricultural land use become more prevalent. Impoundments and dredging of the Mississippi River in and downstream from the TCMA exacerbate effects of increasing river size to produce a more lake-like system.

Iowa, Minnesota, North Dakota, South Dakota, Wisco↗

Occurrence and distribution of nutrients, suspended sediment, and pesticides in the Mobile River Basin, Alabama, Georgia, Mississippi, and Tennessee, 1999-2001

The Mobile River Basin is one of more than 50 river basins and aquifer systems being investigated as part of the U.S. Geological Survey's National Water- Quality Assessment (NAWQA) Program. This basin is the sixth largest river basin in the United States and the fourth largest in terms of streamflow. The Mobile River Basin encompasses parts of Alabama, Georgia, Mississippi, and Tennessee, and almost two-thirds of the 44,0000-square-mile basin is located in Alabama. The extensive water resources of the Mobile River Basin are influenced by an array of natural and cultural factors, which impart unique and variable qualities to the streams, rivers, and aquifers and provide abundant habitat to sustain the diverse aquatic life in the basin. From January 1999 to December 2001, a study was conducted of the occurrence and distribution of nutrients, suspended sediment, and pesticides in surface water of the Mobile River Basin. Nine sampling sites were selected on the basis of land use. The nine sites included two streams draining agricultural areas, two urban streams, and five large rivers with mixed land use. Surface-water samples were collected from one to four times each month to characterize the spatial and temporal variation in nutrient and pesticide concentrations. Nutrient and suspended-sediment concentrations were highest in watersheds dominated by urban or agricultural land uses. Forty-two percent of the total phosphorus concentrations at all nine sites exceeded the U.S. Environmental Protection Agency's recommended maximum concentration of 0.1 milligram per liter. Flow-weighted mean concentrations at the Mobile River Basin sites generally were in the lower to middle percentile ranges compared with data from other NAWQA studies across the Nation. However, flow-weighted mean concentrations of ammonia, total nitrogen, orthophosphate, and total phosphorus at Bogue Chitto Creek, an agricultural watershed, ranked in the upper 20th percentile of agricultural sites sampled across the Nation as part of the NAWQA Program. Nutrient loads in the Tombigbee River were nearly twice as high compared with nutrient loads in the Alabama River. Nutrient yields were highest in Bogue Chitto Creek, Cahaba Valley Creek, and Threemile Branch because of agricultural and urban land uses in these watersheds. Of the 104 pesticides and degradation products analyzed in the stream samples, 69 were detected in one or more samples. Of the 69 detected pesticides, 51 were herbicides, 15 were insecticides, and 3 were fungicides. A relatively small number of heavily used herbicides accounted for most of the detections, including atrazine and its metabolites (deethylatrazine, 2-hydroxyatrazine, deisopropylatrazine, and deethyldeisopropylatrazine), simazine, metolachlor, tebuthiuron, prometon, diuron, and 2,4-D. Diazinon, chlorpyrifos, and carbaryl were the most frequently detected insecticides; metalaxyl was the most frequently detected fungicide in the Mobile River Basin. Concentrations of pesticides detected in surface water of the Mobile River Basin were among the highest concentrations recorded nationally by the NAWQA Program during 1991 to 2001. The three highest concentrations of atrazine detected at sites across the country were recorded at Bogue Chitto Creek; the highest concentrations of 2,4-D, imazaquin, and malathion recorded nationally were detected at Threemile Branch. Aquatic-life criteria were exceeded by concentrations of five herbicides (2,4-D, atrazine, cyanazine, diuron, and metolachlor), six insecticides (carbaryl, chlorpyrifos, diazinon, dieldrin, malathion, and p,p'-DDE), and one fungicide (chlorothalonil). Drinking-water standards were exceeded by concentrations of four herbicides (2,4-D, atrazine, cyanazine, and simazine), three insecticides (alpha- HCH, diazinon, and dieldrin), and one fungicide (chlorothalonil). The types and concentrations of pesticides found in surface water are linked to land use and to the types of pesti

Alabama, Georgia, Mississippi, Tennessee↗

Methods for estimating monthly mean concentrations of selected water-quality constituents for stream sites in the Red River of the North basin, North Dakota and Minnesota

Future development of the Garrison Diversion Unit may divert water from the Missouri River into the Sheyenne River and the Red River of the North for municipal and industrial use. The U.S. Bureau of Reclamation's Canals, Rivers, and Reservoirs Salinity Accounting Procedures model can be used to predict the effect various operating plans could have on water quality in the Sheyenne River and the Red River of the North. The model uses, as Input, monthly means of streamflow and selected water-quality constituents for a 54-year period at 28 nodes on the Sheyenne River and the Red River of the North. This report provides methods for estimating monthly mean concentrations of selected water-quality constituents that can be used for input to and calibration of the salinity model. Mater-quality data for 32 gaging stations can be used to define selected water-quality characteristics at the 28 model nodes. Materquality data were retrieved from the U.S. Geological Survey's National Mater Data Storage and Retrieval System data base and statistical summaries were prepared. The frequency of water-quality data collection at the gaging stations is inadequate to define monthly mean concentrations of the individual water-quality constituents for all months for the 54-year period; therefore, methods for estimating monthly mean concentrations were developed. Relations between selected water-quality constituents [dissolved solids, hardness (as CaCO 3 ), sodium, sulfate, and chloride] and streamflow were developed as the primary method to estimate monthly mean concentrations. Relations between specific conductance and streamflow and relations between selected water-quality constituents [dissolved solids, hardness (as CaCO 3 ), sodium, sulfate, and chloride] and specific conductance were developed so that a cascaded-regression relation could be developed as a second method of estimating monthly mean concentrations and, thus, utilize a large specific-conductance data base. Information about the quantity and the quality of ground water discharging to the Sheyenne River is needed for model input for reaches of the river where ground water accounts for a substantial part of streamflow during periods of low flow. Ground-water discharge was identified for two reaches of the Sheyenne River. Ground-water discharge to the Sheyenne River in the vicinity of Warwick, N.Dak., was about 14.8 cubic feet per second and the estimated dissolved-solids concentration was about 441 milligrams per liter during October 15 and 16, 1986. Ground-water discharge to the Sheyenne River in a reach between Lisbon and Kindred, N.Dak., ranged from an average of 25.3 cubic feet per second during September 13 to November 19, 1963, to about 45.0 cubic feet per second during October 21 and 22, 1986. Dissolved-solids concentration was estimated at about 442 milligrams per liter during October 21 and 22, 1986.

Water-Resources Investigations Report↗

Hydrologic and chemical interaction of the Arkansas River and the Equus Beds aquifer between Hutchinson and Wichita, south-central Kansas

Large chloride concentrations in Arkansas River water have the potential to degrade water quality in the adjacent Equus beds aquifer between Hutchinson and Wichita, Kansas. The aquifer is an important source of water for municipal, industrial, agricultural, and domestic uses. A three-dimensional, finite-difference, ground-water flow-model program (MODFLOW) was used with data from past studies and data collected during 1988-91 to simulate aquifer and stream conditions during the late 1930's, during 1940-89, and during 1990-2019. Results of ground-water flow-model simulations indicated that declining water levels in the Equus beds aquifer since the 1940's have caused base flow in the Arkansas and Little Arkansas Rivers to decrease. In 1940, the Arkansas and Little Arkansas Rivers had simulated net base-flow gains within the model area of about 21 and about 67 ft 3 /s (cubic feet per second), respectively. By the end of 1989, the Arkansas River had a simulated net base-flow loss of about 52 ft 3 /s, and the Little Arkansas River had a net base-flow gain of about 27 ft 3 /s. Simulations for 1990-2019 showed that the water-level changes in a selected model cell located in the central part of the Wichita well field could range from -0.2 to -78 feet. Waterlevel changes in a selected model cell located near the Arkansas River could range from +1.3 to -1.2 feet. In model simulations where only pumpage varied, net base-flow loss from the Arkansas River to the aquifer ranged from about 59 ft 3 /s (no increase in pumpage since 1989) to 117 ft 3 /s (a 3-percent per year increase in pumpage since 1989) by 2019. Assuming a chloride concentration of 630 milligrams per liter, the median concentration in Arkansas River water collected during 1988-91, the quantity of chloride discharged from the Arkansas River to the aquifer was estimated to have increased from about 21 tons per day in 1940 to about 100 tons per day in 1989. By 2019, chloride discharge was indicated to range from about 110 tons per day (associated with no increase in pumpage since 1989) to 200 tons per day (associated with a 3-percent per year increase in pumpage since 1989). A particle-tracking program (MODPATH), which used the results from the flow model, was used to simulate the distribution in the aquifer of chloride from the river during the same time periods. Particle-tracking simulations show that, during 1940-89, the simulated distribution of particles representing chloride from the Arkansas River expanded from relatively narrow bands near the river to a wider distribution within the aquifer and the Wichita well field. Particle-tracking simulations indicate that chloride discharge from the Arkansas River may have reached the edge of the Wichita well field as early as 1963.

Kansas↗

Determination of traveltimes in the lower San Joaquin River basin, California, from dye-tracer studies during 1994-1995

Dye-tracer studies were done in the lower San Joaquin River Basin in February 1994, June 1994, and February 1995. Dye releases were made in the Merced River (February 1994), Salt Slough (June 1994), Tuolumne River (February 1995), and Dry Creek (February 1995). The traveltimes determined in the studies aided the interpretation of pesticide data collected during storm sampling and guided sample collection during a Lagrangian pesticide study. All three studies used rhodamine WT 20-percent dye solution, which was released as a slug in midstream. The mean traveltime determined in the dye studies were compared to estimates based on regression equations of mean stream velocity as a function of streamflow. Dye recovery, the ratio of the calculated dye load at downstream sites to the initial amount of dye released, was determined for the 1994 studies and a dye-dosage formula was evaluated for all studies. In the February 1994 study, mean traveltime from the Merced River at River Road to the San Joaquin River near Vernalis (46.8 river miles) was 38.5 hours, and to the Delta-Mendota Canal at Tracy pumps (84.3 river miles) was 90.4 hours. In the June 1994 study, mean traveltime from Salt Slough at Highway 165 to Vernalis (64.0 river miles) was 80.1 hours. In the February 1995 study, the mean traveltime from the Tuolumne River at Roberts Ferry to Vernalis (51.5 river miles) was 35.8 hours. For the 1994 studies, the regression equations provided suitable estimates of travel-time, with ratios of estimated traveltime to mean dye traveltime of 0.94 to 1.08. However, for the 1995 dye studies, the equations considerably underestimated traveltime, with ratios of 0.49 to 0.73.In the February 1994 study, 70 percent of the dye released was recovered at Vernalis and 35percent was recovered at the Delta-Mendota Canal at Tracy pumps. In the June 1994 study, recovery was 61 percent at Patterson, 43 percent just upstream of the Tuolumne River confluence, and 37 percent at Vernalis. The dye-dosage formula overestimated the dye required for a given downstream concentration for the 1994 studies by ratios of 1.07 to 2.12. The ratios for the February 1995 studies were 0.67 to 0.95 for the Tuolumne River and 1.21 for Dry Creek. In all studies, the estimates improved with length of dye study.

Water-Resources Investigations Report↗

Water-quality conditions of the lower Boise River, Ada and Canyon Counties, Idaho, May 1994 through February 1997

Agricultural land and water use, wastewater treatment facility discharges, land development, road construction, urban runoff, confined-animal feeding operations, reservoir operations, and river channelization affect the water quality and biotic integrity of the lower Boise River between Lucky Peak Dam and the river's mouth at Parma, Idaho. During May 1994 through February 1997, 4 sites on the Boise River, 12 tributary/drain sites, and 3 wastewater treatment facilities were sampled at various intervals during the irrigation (high-flow) and post-irrigation (low-flow) seasons to determine sources, concentrations, and relative loads of nutrients and suspended sediment. Discharge entering the Boise River from the 12 tributary/drain sites and 3 wastewater treatment facilities was measured to determine the nutrient loads being contributed from each source. Total nitrogen, total phosphorus, and suspended sediment concentrations and loads tended to increase in a downstream direction along the Boise River. Among the 15 sources of discharge to the Boise River, 3 southside tributary/drains and the West Boise wastewater treatment facility contributed the largest loads of total nitrogen; the median daily load was more than 2,000 pounds per day. The West Boise wastewater treatment facility contributed the largest median daily load of total phosphorus (810 pounds per day); Dixie Drain contributed the largest median daily load of suspended sediment (26.4 tons per day). Nitrogen-to-phosphorus ratios at the four Boise River sites indicated that phosphorus could be limiting algal growth at the Diversion Dam site, whereas nitrogen could be limiting algal growth at the Glenwood and Middleton sites during some parts of the year. Algal growth in the Boise River near Parma did not appear to be nutrient limited. Because of the complexity of the plumbing system in the lower Boise River (numerous diversions and inflow points), accurate comparisons between discharge and nutrient loads entering the river at measured sites during high-flow sampling periods were difficult. During low-flow sampling periods, southside tributary/drains contributed most of the discharge and total nitrogen load, and wastewater treatment facilities contributed most of the total phosphorus load to the Boise River. During the 50-day period July 18 through September 5, 1996, the Idaho State standard for maximum daily average temperature for coldwater biota was exceeded by 34 percent at Middleton, 48 percent at Caldwell, and 80 percent near Parma. Violations of State standards for primary and secondary contact recreation were observed at all tributary/ drains and in the Boise River near Parma. Median instantaneous concentrations of fecal coliform bacteria exceeded State standards for primary contact recreation at five tributary/drains and exceeded standards for secondary contact recreation at one tributary/drain (Dixie Drain).

Idaho↗

Ground-water resources of the Middle Loup division of the lower Platte River basin, Nebraska, with a section on Chemical quality of the ground water

The Middle Loup division of the lower Platte River basin is an area of 650 square miles which includes the Middle Loup River valley from the confluence of the Middle and North Loup Rivers in Howard County, Nebr., to the site of the diversion dam that the U. S. Bureau of Reclamation proposes to construct in Blaine County near Milburn, Nebr. It also includes land in Howard and Sherman Counties designated by the Bureau of Reclamation as the Farwell unit. Irrigable land in this division is present on both sides of the Middle Loup River and along its tributaries. Most of the Middle Loup River valley is already irrigated by the Middle Loup Public Power and Irrigation District, which is strictly an irrigation enterprise. The uplands are not irrigated. Loess, dune sand, gravel, silt, and clay of Pleistocene or Recent age are exposed in the report area. These unconsolidated sediments rest on bedrock consisting of alternating layers of shale, mudstone, sandstone, and limestone, which are essentially fiat lying or slightly warped. The Ogallala formation, of Tertiary (Pliocene) age, immediately underlies the Pleistocene sediments and rests on the Pierre shale of Cretaceous age. Belts of alluvium occupy the Middle Loup River valley and the valleys of the principal streams in the area. The soils, dune sand, and terrace deposits are the most recent deposits. The Ogallala formation is water bearing and is the source of supply for some domestic and livestock wells. The saturated part of the sand and gravel formations of Pleistocene age, which yields water freely to wells, is the most important aquifer in the Middle Loup division. The water generally is under water-table conditions. The yields of properly constructed wells range from a few gallons per minute (gpm) to as much as 1,800 gpm. Some wells tap water in both the sand and gravel of Pleistocene age and in the underlying Ogallala formation. No wells are known to penetrate into formations older than the Ogallala. Fluctuations of the water table indicate changes in the amount of ground water stored in the water-bearing formations. The principal factors controlling the rise of the water table are the amount of precipitation within the area, the quantity of water coming into the area as underflow from the west and northwest, seepage from the Middle Loup River at times when the water surface in the river is higher than the adjoining water table, and the infiltration of irrigation water not utilized by vegetation or lost by runoff or evaporation. The principal factors controlling the decline of the water table are the discharge as effluent seepage into the Middle Loup River and its tributaries, the amount of water pumped from wells, evapotranspiration losses, and the amount of water leaving the area as underflow. Periodic water-level measurements were made in a total of 241 observation wells during the period 1948-50. Hydrographs of three observation wells having a longer period of record (1934-50) indicate that the water table rose slightly from 1934 until 1950 and that it remained nearly constant during the 1950 water year. The configuration of the water table in the Middle Loup division shows that, except north and northwest of Sargent, the Middle Loup River is an effluent, or gaining, stream throughout its entire length in this area. Thus any rise or fall in the ground-water level will increase or decrease the discharge of the river. The river recharges the ground- water reservoir only during periods when it is at flood stage. The depth to the water table from the land surface is governed largely by irregularities in topography. The depth to water is less than 10 feet near the river and increases to as much as 60 feet near the valley margins and the bordering intermediate slopes. In the Far- well unit the depth to water is more than 100 feet and in some parts more than 150 feet. Ground water pumped from wells is the source of supply for the principal municipalities in th

Water Supply Paper↗

Quality of surface waters in the lower Columbia River Basin

This report, made during 1959-60, provides reconnaissance data on the quality of waters in the lower Columbia River basin ; information on present and future water problems in the basin; and data that can be employed both in water-use studies and in planning future industrial, municipal, and agricultural expansion within this area. The lower Columbia River basin consists of approximately 46,000 square miles downstream from the confluence of the Snake and Columbia Rivers The region can be divided into three geographic areas. The first is the heavily forested, sparsely populated mountain regions in which quality of water in general is related to geologic and climatological factors. The second is a semiarid plateau east of the Cascade Mountains; there differences in geology and precipitation, together with more intensive use of available water for irrigation, bring about marked differences in water quality. The third is the Willamette-Puget trough area in which are concentrated most of the industry and population and in which water quality is influenced by sewage and industrial waste disposal. The majority of the streams in the lower Columbia River basin are calcium magnesium bicarbonate waters. In general, the rivers rising in the. Coast Range and on the west slope of the Cascade Range contain less than 100 parts per million of dissolved solids, and hardness of the water is less than 50 parts per million. Headwater reaches of the streams on the east slope of the Cascade Range are similar to those on the west slope; but, downstream, irrigation return flows cause the dissolved-solids content and hardness to increase. Most of the waters, however, remain calcium magnesium bicarbonate in type. The highest observed dissolved-solids concentrations and also some changes in chemical composition occur in the streams draining the more arid parts of the area. In these parts, irrigation is chiefly responsible for increasing the dissolved-solids concentration and altering the chemical composition of the streams. The maximum dissolved-solids concentration and hardness of water observed in major irrigation areas were 507 and 262 parts per million, respectively, for the. Walla Walla River near Touchet, Wash. In terms of the U.S. Salinity Laboratory Staff classification (1954, p. 80), water in most streams in the basin has low salinity and sodium hazards and is suitable for irrigation. A salt-balance problem does exist in the Hermiston-Stanfield, Oreg., area of the Umatilla River basin, and because of poor drainage, improper irrigation practices could cause salt-balance problems in the Willamette River Valley, Oreg., in which irrigation is rapidly increasing. Pollution by sewage disposal has reached undesirable levels in the Walla Walla River, in the Willamette River from Eugene to Portland, Oreg., and in the Columbia River from Portland to Puget Island. In the lower reaches of the Willamette River, the pollution load from sewage and industrial-waste disposal at times depletes the dissolved oxygen in the water to concentrations below what is considered necessary for aquatic life. Water in most of the tributaries to the lower Columbia River is of excellent quality and after some treatment could be used for industrial and municipal supplies. The principal treatment required would be disinfection and turbidity removal.

Water Supply Paper↗

Organic carbon and nitrogen concentrations and annual organic carbon load of six selected rivers of the United States

The organic carbon load during 1969-70 of each of the six rivers in this study is substantial. The 3.4-billion-kilogram (3.7-million-ton) and 47-million-kilogram (52-thousandton) annual organic carbon loads of the Mississippi River and the Brazos River (Tex.), respectively, were approximately equally distributed between dissolved and suspended phases, whereas the 725-million-kilogram (79.8-million-ton) organic load of the Missouri River was primarily in the suspended phase. The major portion of the 6.4-million-kilogram (7.3 thousand-ton) and the 19-million-kilogram (21-thousand-ton) organic carbon loads of the Sopchoppy River (Fla.) and the Neuse River (N.C.), respectively, was in the dissolved phase. DOC (dissolved organic carbon) concentrations in most rivers were usually less than 8 milligrams per litre. SOC (suspended organic carbon) concentrations fluctuated markedly with discharge, ranging between 1 and 14 percent, by weight, in sediment of most rivers. DOC concentrations were found to be independent of discharge, whereas SOC and SIC (suspended inorganic carbon) concentrations were positively correlated with discharge. Seasonal fluctuations in DOC and SOC were exhibited by the Missouri, Neuse, Ohio, and Brazos Rivers, but both SOC and DOC concentrations were relatively constant throughout the year in the Mississippi and Sopchoppy Rivers. The carbon-nitrogen ratio in the sediment phase of all river waters averaged less than 8 1 as compared with 12:1 or greater for most soils. This high nitrogen content shows a nitrogen enrichment of the stream sediment over that in adjacent soils, which suggests that different decomposition and humification processes are operating in streams than in the soils. The abundance of organic material in the dissolved and suspended phase of all river waters in this study indicate a large capacity factor for various types of organic reactivity within all streams and the quantitative importance of organic constituents in relation to the water quality of rivers and streams.

Water Supply Paper↗

Analysis of water quality of the Mahoning River in Ohio

The Mahoning River drains the densely populated and industrialized Warren-Youngstown area in northeastern Ohio. Significant chemical constituents and physical properties generally regarded as important in establishing water-quality standards for the Mahoning River are evaluated on the basis of hydrologic conditions and water use. Most of the interpretations and the appraisal of water-quality conditions are based on data collected from January 1963 to December 1965. Generally, streamflow during this period was lower than during a selected long-term reference period ; however, extremely low flows that occurred in the reference period did not occur in the 3-year study period. Water temperatures of the Mahoning River at Pricetown and Leavittsburg were not affected by thermal loading. Water temperatures at those stations ranged from the freezing point to 78?F during the 1963-65 period. Downstream from Leavittsburg, the use of large quantities of water for industrial cooling caused critical thermal loading during periods of low streamflow. Maximum water temperatures were 108?F and 104?F at Struthers and Lowellville, respectively. Water temperatures of the Mahoning River were lower during high water discharges and increased with higher steel-production indices. Flow augmentation and modifications in industrial processes have improved the water-temperature conditions in recent years. A combination of oxygen-consuming materials and warmed water from industrial and municipal wastes discharged into the lower reaches of the Mahoning River frequently depleted the dissolved-oxygen content. At Lowellville, the river water had a dissolved-oxygen content of 5 ppm (parts per million) or less for 67 percent of the time and 3 ppm or less for 16 percent of the time during the study period. The percentage of saturation of dissolved oxygen followed a similar trend. Both the dissolved-oxygen concentration and the percentage of saturation were noticeably lower downstream from Leavittsburg during the warm months when water temperatures were high and streamflow was low. The dissolved-oxygen content in the Mahoning River at Leavittsburg and Pricetown was almost always at acceptable levels. The calculated dissolved-solids concentration of the Mahoning River ranged from 150 to 450 ppm at Leavittsburg and from 200 ppm to 650 ppm at Lowellville. Industrial use of the water caused an increase in the dissolved-solids concentration at Lowellville. During one steel-mill shutdown the average dissolved-solids concentration decreased from about 360 to about 280 ppm. Chloride concentrations in the Mahoning River ranged from 42 ppm at Pricetown to 108 ppm at Struthers. The chloride load at 50-percent flow duration was 9 and 69 tons per day at Pricetown and Lowellville, respectively. The chloride content of the Mahoning River was well within acceptable levels. Sulfate from wastes disposal and acid mine drainage made up the largest quantity of dissolved-solids load in the Mahoning River. The sulfate load at 50-percent flow duration increased from 38 tons per day at Pricetown to 300 tons per day at Lowellville. At Pricetown the sulfate load ranged from about 2 to 588 tons per day, while at Lowellville, downstream from the industrialized area, the range was from 106 to 2,420 tons per day. Comparison of sulfate loads during periods of steel production with periods of steel-mill shutdown indicated that during low flow about half the sulfate load at Lowellville was derived from steel-mill wastes when the production index was 100. The alkalinity load of the Mahoning River at 50-percent flow duration increased from Pricetown (23 tons per day) to Lowellville (41 tons per day). During steel production the alkalinity of the water showed a marked decrease from Leavittsburg downstream to Lowellville. However, during steel-mill shutdowns the chemical composition of the river at Youngstown and Lowellville was similar to that at Leavittsburg. Acid mine drainag

Water Supply Paper↗

Magnitudes, nature, and effects of point and nonpoint discharges in the Chattahoochee River Basin, Atlanta to West Point Dam, Georgia

During the period April 1975 to June 1978, the U.S. Geological Survey conducted a river-quality assessment of the Upper Chattahoochee River basin in Georgia. One objective of the study was to assess the magnitudes, nature, and effects of point and non-point discharges in the Chattahoochee River basin from Atlanta to the West Point Dam. On an average annual basis and during the storm period of March 1215, 1976, non-point-source loads for most constituents analyzed were larger than point-source loads at the Whitesburg station, located on the Chattahoochee River about 40 river miles downstream of Atlanta. Most of the non-point-source constituent loads in the Atlanta-to-Whitesburg reach were from urban areas. Average annual point-source discharges accounted for about 50 percent of the dissolved nitrogen, total nitrogen, and total phosphorus loads, and about 70 percent of the dissolved phosphorus loads at Whitesburg. During weekends, power generation at the upstream Buford Dam hydroelectric facility is minimal. Streamflow at the Atlanta station during dry-weather weekends is estimated to be about 1,200 ft3/s (cubic feet per second). Average daily dissolved-oxygen concentrations of less than 5.0 mg/L (milligrams per liter) occurred often in the river, about 20 river miles downstream from Atlanta during these periods from May to November. During a low-flow period, June 1-2, 1977, five municipal point sources contributed 63 percent of the ultimate biochemical oxygen demand, 97 percent of the ammonium nitrogen, 78 percent of the total nitrogen, and 90 percent of the total phosphorus loads at the Franklin station, at the upstream end of West Point Lake. Average daily concentrations of 13 mg/L of ultimate biochemical oxygen demand and 1.8 mg/L of ammonium nitrogen were observed about 2 river miles downstream from two of the municipal point sources. Carbonaceous and nitrogenous oxygen demands caused dissolved-oxygen concentrations between 4.1 and 5.0 mg/L to occur in a 22-mile reach of the river downstream from Atlanta. Nitrogenous oxygen demands were greater than carbonaceous oxygen demands in the reach from river mile 303 to 271, and carbonaceous demands were greater from river mile 271 to 235. The heat load from the Atkinson-McDonough thermoelectric power-plants caused a decrease in the dissolved-oxygen concentrations of about 0.2 mg/L. During a critical low-flow period, a streamflow at Atlanta of about 1,800 ft3/s, with present (1977) point-source flows of 185 ft3/s containing concentrations of 45 mg/L of ultimate biochemical oxygen demand and 15 mg/L of ammonium nitrogen, results in a computed minimum dissolved-oxygen concentration of 4.7 mg/L in the river downstream from Atlanta. In the year 2000, a streamflow at Atlanta of about 1,800 ft3/s with point-source flows of 373 ft3/s containing concentrations of 45 mg/L of ultimate biochemical oxygen demand and 5.0 mg/L of ammonium nitrogen, will result in a computed minimum dissolved-oxygen concentration of 5.0 mg/L. A streamflow of about 1,050 ft3/s at Atlanta in the year 2000 will result in a dissolved-oxygen concentration of 5.0 mg/L if point-source flows contain concentrations of 15 mg/L of ultimate biochemical oxygen demand and 5.0 mg/L of ammonium nitrogen. Phytoplankton concentrations in West Point Lake, about 70 river miles downstream from Atlanta, could exceed 3 million cells per milliliter during extended low-flow periods in the summer with present point- and non-point-source nitrogen and phosphorus loads. In the year 2000, phytoplankton concentrations in West Point Lake are not likely to exceed 700,000 cells per milliliter during extended low-flow periods in the summer, if phosphorus concentrations do not exceed 1.0 mg/L in point-source discharges.

Georgia↗

Geohydrology and model analysis of stream-aquifer system along the Arkansas River in Kearny and Finney Counties, southwestern Kansas

A study was made, in cooperation with the Division of Water Resources, Kansas State Board of Agriculture, to determine geohydrologic conditions in an area comprising nearly 850,000 acres along the Arkansas River valley in Kearny and Finney Counties, southwestern Kansas. The Arkansas River meanders atop and interacts hydraulically with the area's multilayered, unconsolidated aquifer system. Declines in static water levels in wells in the heavily pumped lower aquifer ranged from 20 to 80 feet during 1974-80. The river is dry in much of the area. A digital computer model was calibrated to simulate the trends of historic water levels. Simulated 1974-80 conditions depicted an average annual recharge to the unconsolidated aquifer system of 66,900 acre-feet from precipitation and 36,200 acre-feet from river and canal seepage and boundary inflow. Simulated average annual discharge consisted of 634,800 acre-feet from pumpage and boundary outflow. Simulated average annual recharge to the unconsolidated aquifer system was 531,700 acre-feet less than average annual discharge, indicating the ground-water resource is currently (1982) being mined in the study area. Simulation also indicated that there would be sufficient saturated thickness in 2005 for irrigation if 1980 hydrologic conditions continued. Seepage losses from the Arkansas River and irrigation canals are a major source of recharge to the unconsolidated aquifer system. Therefore, the amount of flow in the Arkansas River would be important in determining the rate of future water-level declines in the study area. Streamflow seepage losses could be decreased by (1) decreasing the number of wells pumping in the study area in order to reduce downward leakage from the valley aquifer, or (2) increasing streamflow discharge in order to recharge the valley aquifer. The rate and direction of flow between the river and the valley aquifer depend on the hydraulic conductivity of the streambed and the hydraulic gradient between the river stage and the water table. As long as river stage remains high, the water table in the valley aquifer continues to rise. Seepage from the river to the valley aquifer decreases as the altitude difference between the river stage and the valley aquifer decreases, becoming insignificant when the water level in the valley aquifer nearly equals river stage. However, a rise in the water table in the valley aquifer because of recharge from the river will correspond to increased downward leakage to the lower aquifer, impeding recharge to the valley aquifer.

Kansas↗

Distribution and transport of trace substances in the Schuylkill River basin from Berne to Philadelphia, Pennsylvania

During the period from October 1978 to March 1981, the U.S. Geological Survey assessed the river quality of the Schuylkill River basin in Pennsylvania from the headwaters to the Fairmount Dam at Philadelphia (river mile 8.4). The assessment focused on the distribution and transport of trace metals and organic substances (trace substances). Trace metals included were arsenic, beryllium, cadmium, copper, lead, mercury, nickel, and zinc; trace organic substances included organochlorine insecticides and polychlorinated biphenyls. In general, concentrations of trace substances in the streambed sediments were greater in the main stem of the Schuylkill River than in its tributaries and exceeded the background concentrations in the study area. Concentrations of most trace metals in the sediments were lowest in the Berne area (river mile 95) and highest in the urban-industrial area of Reading (river mile 76). Concentrations generally decreased from Reading downstream to Philadelphia (river mile 10.2). Concentrations of the organochlorine insecticides chlordane, DDT and its metabolites, and dieldrin generally increased gradually from Berne to Philadelphia. Average concentrations of trace metals in the main stem of the Schuylkill River in the sediment-sized fraction, less than 0.063 millimeters, were: zinc, 603 ?g/g (micrograms per gram); lead, 284 ?g/g; copper, 252 ?g/g; nickel, 119 ?g/g; chromium, 96 ?g/g; beryllium, 8.2 ?g/g; arsenic, 0.64 ?g/g; and mercury, 0.002 ?g/g. Average concentrations of trace organic substances in sediments of the main stem of the river were: polychlorinated biphenyls, 152 ?g/kg (micrograms per kilogram); chlordane, 24 ?g/kg; DDT and its metabolites, 18 ?g/kg; and dieldrin, 1.8 ?g/kg. The average annual transport of trace substances by the river was computed for chromium, copper, lead, nickel, and zinc. Concentrations of other trace substances in the sediment-water mixtures were generally undetectable. Of the trace metals, average annual transport of zinc was the greatest, and that of nickel was the least. Transport of trace metals in the river is closely associated with and related to suspended-sediment transport. About 71 percent of the average annual total metal transport is particulate material. Yields, in tons per square mile per year, of copper, lead, zinc, and total organic carbon in the Schuylkill River basin were compared with yields in the Chattahoochee River basin (Georgia). The comparison indicates that yields, by constituent, were of the same order of magnitude. Both basins lie in the Piedmont province, and both have about the same percentage of urban land use. The frequency of occurrence of concentrations of copper, lead, and zinc in the sediment-water mixture at Manayunk in Philadelphia were compared with domestic water-supply criteria of the U.S. Environmental Protection Agency. The criteria are exceeded less than 1 percent of the time, or about 4 days per year.

Schuylkill River basin↗

The floods of March 1936, part 1, New England rivers

During the period March 9-22, 1936, there occurred in close succession over the northeastern United States, from the James and upper Ohio River Basins in Virginia and Pennsylvania to the river basins of Maine, two extraordinarily heavy storms, in which the precipitation was almost entirely in the form of rain. The depths of rainfall mark this period as one of the greatest concentrations of precipitation, in respect to time and magnitude of the area covered, of which there is record in this country. At the time of the rain there were also accumulations of snow on the ground over much of the storm-affected region that were large for the season. The comparatively warm temperatures associated with the storms thawed the snow and added materially to the quantities of water to be disposed of by drainage into the waterways, by surface storage in lakes, ponds, and reservoirs, by absorption in the ground, and, probably in comparatively negligible degree, by evaporation. The total quantity of water that had to be disposed of in these ways ranged between 10 and 30 inches in depth over much of the region. The water disposed of by natural storage, absorption, and evaporation amounted to average depths over the many river basins generally within the range of 1 to 3 inches, with a significant degree of uniformity and systematic areal distribution. The remainder of the rain and snow water, generally much larger or even several times larger in amount than surface storage, absorption, and evaporation, required accommodation by the channels of the brooks, creeks, and rivers. There were generally two distinct flood peaks, and in many of the basins the destruction was seriously aggravated, especially during the first flood, by the break-up of thick ice cover accumulated through a winter of exceptionally continuous and severe cold weather. The resulting floods were extraordinarily severe, and records of river stages, extending on some streams back to or nearly to the time of settlement by white men, were broken many of them by wide margins. The peak of the Connecticut River at Hartford, Conn., was 8.6 feet higher than had been experienced since the settlement by white men, 300 years ago. The Susquehanna River at Harrisburg, Pa., was 3.5 feet higher than had been known in a period of record covering about 200 years. The Ohio River at Pittsburgh, Pa., was 6.1 feet higher than had been known in the period beginning 1762. This volume presents many of the facts of these notable floods with respect to the New England rivers, for permanent record and for study and reference by engineers concerned with the building of highways, bridges, and industrial plants, planners of river development, and others. Similar volumes for the region from the Hudson River to the Susquehanna River and for the Potomac, James, and upper Ohio River Basins are presented in companion Water-Supply Papers 799 and 800 respectively. In this volume records of stage and discharge for the period Including the floods are presented for about 150 measurement stations; peak discharges with comparative data for other floods at more than 400 measurement points are summarized; crest stages along an aggregate length of stream channel of 2,820 miles are tabulated; and results of detailed studies of the rainfall and run-off and many other kinds of flood information are presented.

Water Supply Paper↗

The floods of March 1936, Part 3, Potomac, James, and upper Ohio Rivers

During the period March 9-22, 1936, there occurred in close succession over the northeastern United States, from the James and upper Ohio River Basins in Virginia and Pennsylvania to the river basins of Maine, two extraordinarily heavy storms, in which the precipitation was almost entirely in the form of rain. The depths of rainfall mark this period as one of the greatest concentrations of precipitation, in respect to time and magnitude of the area covered, of which there is record in this country. At the time of the rain there were also accumulations of snow on the ground over much of the storm-affected region that were large for the season. The comparatively warm temperatures associated with the storms thawed the snow and added materially to the quantities of water to be disposed of by drainage into the waterways, by surface storage in lakes, ponds, and reservoirs, by absorption in the ground, and, probably in comparatively negligible degree, by evaporation. The total quantity of water that had to be disposed of in these ways ranged between 10 and 30 inches in depth over much of the region. The water disposed of by natural storage, absorption, and evaporation amounted to average depths over the many river basins generally within the range of 1 to 3 inches, with a significant degree of uniformity and systematic areal distribution. The remainder of the rain and snow water, generally much larger or even several times larger in amount than surface storage, absorption, and evaporation, required accommodation by the channels of the brooks, creeks, and rivers. There were generally two distinct flood peaks, and in many of the basins the destruction was seriously aggravated, especially during the first flood, by the break-up of thick ice cover accumulated through a winter of exceptionally continuous and severe cold weather. The resulting floods were extraordinarily severe, and records of river stages, extending on some streams back to or nearly to the time of settlement by white men, were broken many of them by wide margins. The peak of the Connecticut River at Hartford, Conn., was 8.6 feet higher than had been experienced since the settlement by white men, 300 years ago. The Susquehanna River at Harrisburg, Pa., was 3.5 feet higher than had been known in a period of record covering about 200 years. The Ohio River at Pittsburgh, Pa., was 6.1 feet higher than had been known in the period beginning 1762. This volume presents many of the facts of these notable floods with respect to the New England rivers, for permanent record and for study and reference by engineers concerned with the building of highways, bridges, and industrial plants, planners of river development, and others. Similar volumes for the region from the Hudson River to the Susquehanna River and for the Potomac, James, and upper Ohio River Basins are presented in companion Water-Supply Papers 799 and 800 respectively. In this volume records of stage and discharge for the period Including the floods are presented for about 150 measurement stations; peak discharges with comparative data for other floods at more than 400 measurement points are summarized; crest stages along an aggregate length of stream channel of 2,820 miles are tabulated; and results of detailed studies of the rainfall and run-off and many other kinds of flood information are presented.

Water Supply Paper↗

Movements and habitat use of Silver Carp in the Arkansas and White rivers

Silver Carp Hypophthalmichthys molitrix is an invasive species found throughout the Mississippi River basin. Efforts have been made to control Silver Carp populations through removal programs and movement barrier implementation. Up to date information on diel, seasonal, and annual movements and habitat use by Silver Carp will benefit these efforts. Studies of Silver Carp movement are prevalent in the upper Mississippi River, Ohio River, and tributaries, but rare in tributaries of the lower Mississippi River. Between June 2021 and May 2022, we quantified average movement rates and residency periods of 48 Silver Carp in the free-flowing lower White River and lock-and-dam fragmented lower Arkansas River using passive acoustic telemetry arrays and internal implant acoustic transmitters. We also manually tracked Silver Carp in the two rivers during the four seasons to estimate diel movement rates and use of different habitats. On an annual scale, Silver Carp in the White River moved at faster rates than Silver Carp in the Arkansas River and were recorded more times by acoustic receivers. Diel movement rates varied by season in both rivers but were low overall. Silver Carp used lentic habitats more often than lotic habitats. Overall, results suggest the numerous locks and dams of the McClellan-Kerr Arkansas River Navigation System may limit large-scale, annual movement of Silver Carp in the Arkansas River compared to the White River. Low hourly diel movement rates and high occupancy of lentic habitats also should enable effective harvest of Silver Carp using active gears in those lentic habitats.

Arkansas↗

Modeling a three-dimensional river plume over continental shelf using a 3D unstructured grid model

River derived fresh water discharging into an adjacent continental shelf forms a trapped river plume that propagates in a narrow region along the coast. These river plumes are real and they have been observed in the field. Many previous investigations have reported some aspects of the river plume properties, which are sensitive to stratification, Coriolis acceleration, winds (upwelling or downwelling), coastal currents, and river discharge. Numerical modeling of the dynamics of river plumes is very challenging, because the complete problem involves a wide range of vertical and horizontal scales. Proper simulations of river plume dynamics cannot be achieved without a realistic representation of the flow and salinity structure near the river mouth that controls the initial formation and propagation of the plume in the coastal ocean. In this study, an unstructured grid model was used for simulations of river plume dynamics allowing fine grid resolution in the river and in regions near the coast with a coarse grid in the far field of the river plume in the coastal ocean, in the vertical, fine fixed levels were used near the free surface, and coarse vertical levels were used over the continental shelf. The simulations have demonstrated the uniquely important role played by Coriolis acceleration. Without Coriolis acceleration, no trapped river plume can be formed no matter how favorable the ambient conditions might be. The simulation results show properties of the river plume and the characteristics of flow and salinity within the estuary; they are completely consistent with the physics of estuaries and coastal oceans.

Conference Paper↗

Quantitative mineralogy of the Yukon River system: Changes with reach and season, and determining sediment provenance

The mineralogy of Yukon River basin sediment has been studied by quantitative X-ray diffraction. Bed, beach, bar, and suspended sediments were analyzed using the RockJock computer program. The bed sediments were collected from the main stem and from selected tributaries during a single trip down river, from Whitehorse to the Yukon River delta, during the summer of 2001. Beach and bar sediments were collected from the confluence region of the Tanana and Yukon Rivers during the summer of 2003. Suspended sediments were collected at three stations on the Yukon River and from a single station on the Tanana River at various times during the summers of 2001 through 2003, with the most complete set of samples collected during the summer of 2002. Changes in mineralogy of Yukon River bed sediments are related to sediment dilution or concentration effects from tributary sediment and to chemical weathering during transport. Carbonate minerals compose about 2 wt% of the bed sediments near Whitehorse, but increase to 14 wt% with the entry of the White River tributary above Dawson. Thereafter, the proportion of carbonate minerals decreases downstream to values of about 1 to 7 wt% near the mouth of the Yukon River. Quartz and feldspar contents of bed sediments vary greatly with the introduction of Pelly River and White River sediments, but thereafter either increase irregularly (quartz from 20 to about 50 wt%) or remain relatively constant (feldspar at about 35 wt%) with distance downstream. Clay mineral content increases irregularly downstream from about 15 to about 30 wt%. The chief clay mineral is chlorite, followed by illite + smectite; there is little to no kaolinite. The total organic carbon content of the bed sediments remains relatively constant with distance for the main stem (generally 1 to 2 wt%, with one exception), but fluctuates for the tributaries (1 to 6 wt%). The mineralogies of the suspended sediments and sediment flow data were used to calculate the amount of mineral dissolution during transport between Eagle and Pilot Station, a distance of over 2000 km. We estimate that approximately 3 wt% of the quartz, 15 wt% of the feldspar (1 wt% of the alkali and 25 wt% of the plagioclase), and 26 wt% of the carbonates (31 wt% of the calcite and 15 wt% of the dolomite) carried by the river dissolve in this reach. The mineralogies of the suspended sediments change with the season. For example, during the summer of 2002 the quartz content varied by 20 wt%, with a minimum in mid-summer. The calcite content varied by a similar amount, and had a maximum corresponding to the quartz minimum. These modes are related to the relative amount of sediment flowing from the White River system, which is relatively poor in quartz, but rich in carbonate minerals. Suspended total clay minerals varied by as much as 25 wt%, with maxima in mid July, and suspended feldspar varied up to 10 wt%. Suspended sediment data from the summers of 2001 and 2003 support the 2002 trends. A calculation technique was developed to determine theproportion of various sediment sources in a mixed sediment by unmixing its quantitative mineralogy. Results from this method indicate that at least three sediment sources can be identified quantitatively with good accuracy. With this technique, sediment mineralogies can be used to calculate the relative flux of sediment from different tributaries, thereby identifying sediment provenance.

American Mineralogist↗