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Mineral resource of the month: sulfur

The article presents information on sulfur. Sulfur is said to be among the few solid elements found in elemental form in nature and has industrial uses. Changes in the sulfur production process over the years are discussed as well as the mining process developed by German engineer Herman Frasch that involves melting the sulfur underground and pumping it to the surface.

Earth↗

Oxygen isotopes of dissolved sulfate as a tool to distinguish natural and mining-related dissolved constituents

Natural and mining-related dissolved-constituent concentrations need to be distinguished in a watershed affected by abandoned mines to prioritize subbasins for remediation and to assist with the establishment of water-quality standards. The oxygen isotopes of dissolved sulfate can be used to distinguish between natural and mining-related sources of dissolved constituents. Several methods employing the oxygen isotopes of dissolved sulfate can be used to determine the relative amounts of natural and mining related dissolved constituents in water: (1) the isotope-dilution equation for simple mixing zones (two sources and one receiving stream); (2) the isotope mass-balance equation for streams receiving dissolved sulfate from multiple geologic sources; and (3) graphical relations and the mathematical solution of simultaneous equations in a watershed approach. Using the different methods for data collected during low flow, about 71 to 75 percent of the dissolved-constituent concentrations are from natural sources in selected subbasins of the upper Animas watershed.

Open File Report↗

U.S. Geological Survey Programs in Minnesota

The U.S. Geological Survey (USGS) maps, describes, and seeks to understand Minnesota's mineral, water, and biological resources. The USGS is known for impartial data collection and data interpretation that enable resource planners and others to make informed decisions. Today's issues are more pressing than ever - understanding natural hazards to minimize their effects on life and property, the continuing need for mineral- and water-resource development, and understanding the effects of human activities on water resources. As the Nation's leading natural-science agency, the USGS works with other Federal agencies and State and local agencies in addressing these issues. Watershed districts; soil- and water-conservation districts; Tribal governments; mining industries; educators; city, county, regional, State, and Federal planning agencies; consulting firms; crop consultants; farmers; and other private citizens use USGS maps, interpretive reports, and data to manage Minnesota's resources.

Fact Sheet↗

A geostatistical approach to predicting sulfur content in the Pittsburgh coal bed

The US Geological Survey (USGS) is completing a national assessment of coal resources in the five top coal-producing regions in the US. Point-located data provide measurements on coal thickness and sulfur content. The sample data and their geologic interpretation represent the most regionally complete and up-to-date assessment of what is known about top-producing US coal beds. The sample data are analyzed using a combination of geologic and Geographic Information System (GIS) models to estimate tonnages and qualities of the coal beds. Traditionally, GIS practitioners use contouring to represent geographical patterns of "similar" data values. The tonnage and grade of coal resources are then assessed by using the contour lines as references for interpolation. An assessment taken to this point is only indicative of resource quantity and quality. Data users may benefit from a statistical approach that would allow them to better understand the uncertainty and limitations of the sample data. To develop a quantitative approach, geostatistics were applied to the data on coal sulfur content from samples taken in the Pittsburgh coal bed (located in the eastern US, in the southwestern part of the state of Pennsylvania, and in adjoining areas in the states of Ohio and West Virginia). Geostatistical methods that account for regional and local trends were applied to blocks 2.7 mi (4.3 km) on a side. The data and geostatistics support conclusions concerning the average sulfur content and its degree of reliability at regional- and economic-block scale over the large, contiguous part of the Pittsburgh outcrop, but not to a mine scale. To validate the method, a comparison was made with the sulfur contents in sample data taken from 53 coal mines located in the study area. The comparison showed a high degree of similarity between the sulfur content in the mine samples and the sulfur content represented by the geostatistically derived contours. Published by Elsevier Science B.V.

International Journal of Coal Geology↗

Reported Historic Asbestos Mines, Historic Asbestos Prospects, and Natural Asbestos Occurrences in the Rocky Mountain States of the United States (Colorado, Idaho, Montana, New Mexico, and Wyoming)

This map and its accompanying dataset provide information for 48 natural asbestos occurrences in the Rocky Mountain States of the United States (U.S.), using descriptions found in the geologic literature. Data on location, mineralogy, geology, and relevant literature for each asbestos site are provided. Using the map and digital data in this report, the user can examine the distribution of previously reported asbestos occurrences and their geological characteristics in the Rocky Mountain States. This report is part of an ongoing study by the U.S. Geological Survey to identify and map reported natural asbestos occurrences in the U.S., which thus far includes similar maps and datasets of natural asbestos occurrences within the Eastern U.S. (http://pubs.usgs.gov/of/2005/1189/) and the Central U.S. (http://pubs.usgs.gov/of/2006/1211/). These reports are intended to provide State and local government agencies and other stakeholders with geologic information on natural occurrences of asbestos in the U.S.

Open-File Report↗

Metals transport in the Sacramento River, California, 1996-1997; volume 1: Methods and data

Metals transport in the Sacramento River, northern California, was evaluated on the basis of samples of water, suspended colloids, streambed sediment, and caddisfly larvae that were collected on one to six occasions at 19 sites in the Sacramento River Basin from July 1996 to June 1997. Four of the sampling periods (July, September, and November 1996; and May-June 1997) took place during relatively low-flow conditions and two sampling periods (December 1996 and January 1997) took place during high-flow and flooding conditions; respectively. Tangential-flow ultrafiltration with 10,000 nominal molecular weight limit, or daltons (0.005 micrometer equivalent), pore-size membranes was used to separate metals in streamwater into ultrafiltrate (operationally defined dissolved fraction) and retentate (colloidal fraction) components, respectively. Conventional filtration with capsule filters (0.45 micrometer pore-size) and membrane filters (0.40 micrometer pore-size) and total-recoverable analysis of unfiltered (whole-body) samples were done for comparison at all sites. Because the total-recoverable analysis involves an incomplete digestion of particulate matter, a more reliable measurement of whole-water concentrations is derived from the sum of the dissolved component that is based on the ultrafiltrate plus the suspended component that is based on a total digestion of colloid concentrates from the ultra-filtration retentate. Metals in caddisfly larvae were determined for whole-body samples and cytosol extracts, which are intercellular solutions that provide a more sensitive indication of the metals that have been bioaccumulated. Trace metals in acidic, metal-rich drainage from abandoned and inactive sulfide mines were observed to enter the Sacramento River system (specifically, into both Shasta Lake and Keswick Reservoir) in predominantly dissolved form, as operationally defined using ultrafiltrates. The predominant source of acid mine drainage to Keswick Reservoir is Spring Creek, which drains the Iron Mountain mine area. Copper concentrations in filtered samples from Spring Creek taken during December 1996, January 1997, and May 1997 ranged from 420 to 560 micrograms per liter. Below Keswick Dam, copper concentrations in conventionally filtered samples ranged from 0.5 micrograms per liter during September 1996 to 9.4 micrograms per liter during January 1997; the latter concentration exceeded the applicable water-quality standard. The proportion of trace metals that was dissolved (versus colloidal) in samples collected at Shasta and Keswick dams decreased in the order cadmium zinc > copper > aluminum iron lead mercury. At four sampling sites on the Sacramento River at various distances downstream of Keswick Dam (Bend Bridge, 71 kilometers; Colusa, 256 kilometers; Verona, 360 kilometers; and Freeport, 412 kilometers) concentrations of these seven metals were predominantly colloidal during both high- and low-flow conditions. Because copper compounds are used extensively as algaecides in rice farming, agricultural drainage at the Colusa Basin Drain was sampled in June 1997 during a period shortly after copper applications to newly planted rice fields. Copper concentrations ranged from 1.3 to 3.0 micrograms per liter in filtered samples and from 12 to 13 micrograms per liter in whole-water samples (total recoverable analysis). These results are consistent with earlier work by the U.S. Geological Survey indicating that copper in rice-field drainage likely represents a detectable, but relatively minor source of copper to the Sacramento River. Lead isotope data from suspended colloids and streambed sediments collected during October and November 1996 indicate that lead from acid mine drainage sources became a relatively minor component of the total lead at the site located 71 kilometers downstream of Keswick Dam and beyond. Cadmium, copper, and zinc concentrations in caddisfly larvae were elevated at several sites downstream of Keswick Dam, but concentrations of aluminum, iron, lead, and mercury were relatively low, especially in the cytosol extracts. Cadmium showed the highest degree of bioaccumulation in whole-body and cytosol analyses, relative to an unmineralized control site (Cottonwood Creek). Cadmium bioaccumulation persisted in samples collected as far as 118 kilometers downstream of Keswick Dam, consistent with transport in a form more bioavailable than lead.

California↗

Significant deposits of gold, silver, copper, lead, and zinc in the United States

Approximately 99 percent of past production and remaining identified resources of gold, silver, copper, lead, and zinc in the United States are accounted for by deposits that originally contained at least 2 metric tonnes (t) gold, 85 t silver, 50,000 t copper, 30,000 t lead, or 50,000 t zinc. The U.S. Geological Survey, beginning with the 1996 National Mineral Resource Assessment, is systematically compiling data on these deposits, collectively known as "significant" deposits. As of December 31, 1996, the significant deposits database contained 1,118 entries corresponding to individual deposits or mining districts. Maintaining, updating, and analyzing a database of this size is much easier than managing the more than 100,000 records in the Mineral Resource Data System and Minerals Availability System/Minerals Industry Location System, yet the significant deposits database accounts for almost all past production and remaining identified resources of these metals in the United States. About 33 percent of gold, 22 percent of silver, 42 percent of copper, 39 percent of lead, and 46 percent of zinc are contained in or were produced from deposits discovered after World War II. Even within a database of significant deposits, a disproportionate share of past production and remaining resources is accounted for by a very small number of deposits. The largest 10 producers for each metal account for one third of the gold, 60 percent of the silver, 68 percent of the copper, 85 percent of the lead, and 75 percent of the zinc produced in the United States. The 10 largest deposits in terms of identified remaining resources of each of the five metals contain 43 percent of the gold, 56 percent of the silver, 48 percent of the copper, 94 percent of the lead, and 72 percent of the zinc. Identified resources in significant deposits for each metal are less than the mean estimates of resources in undiscovered deposits from the 1996 U.S. National Mineral Resource Assessment. Identified resources are roughly the same magnitude as cumulative past production. Assuming that roughly the same proportion of resources in undiscovered deposits will occur in significant deposits, a substantial number of significant deposits remain to be discovered.

Economic Geology↗

MiniSipper: A new in situ water sampler for high-resolution, long-duration acid mine drainage monitoring

Abandoned hard-rock mines can be a significant source of acid mine drainage (AMD) and toxic metal pollution to watersheds. In Colorado, USA, abandoned mines are often located in remote, high elevation areas that are snowbound for 7–8 months of the year. The difficulty in accessing these remote sites, especially during winter, creates challenging water sampling problems and major hydrologic and toxic metal loading events are often under sampled. Currently available automated water samplers are not well suited for sampling remote snowbound areas so the U.S. Geological Survey (USGS) has developed a new water sampler, the MiniSipper, to provide long-duration, high-resolution water sampling in remote areas. The MiniSipper is a small, portable sampler that uses gas bubbles to separate up to 250 five milliliter acidified samples in a long tubing coil. The MiniSipper operates for over 8 months unattended in water under snow/ice, reduces field work costs, and greatly increases sampling resolution, especially during inaccessible times. MiniSippers were deployed in support of an U.S. Environmental Protection Agency (EPA) project evaluating acid mine drainage inputs from the Pennsylvania Mine to the Snake River watershed in Summit County, CO, USA. MiniSipper metal results agree within 10% of EPA-USGS hand collected grab sample results. Our high-resolution results reveal very strong correlations (R 2 > 0.9) between potentially toxic metals (Cd, Cu, and Zn) and specific conductivity at the Pennsylvania Mine site. The large number of samples collected by the MiniSipper over the entire water year provides a detailed look at the effects of major hydrologic events such as snowmelt runoff and rainstorms on metal loading from the Pennsylvania Mine. MiniSipper results will help guide EPA sampling strategy and remediation efforts in the Snake River watershed.

Colorado↗

Ground-water flow to Death Valley, as inferred from the chemistry and geohydrology of selected springs in Death Valley National Park, California and Nevada

Death Valley lies downgradient from adjacent valleys to the north, south, east, and west in California and Nevada, and is the site of substantial ground-water discharge. The sources of the discharging waters have been discussed by several investigators in the past and are of heightened concern because of the potential disposal of high-level radioactive waste at Yucca Mountain, Nevada, and because of ground-water withdrawals attendant to commercial mining in the northwestern Amargosa Valley region. This report describes high- and low-discharge springs in and along the Amargosa Range that were sampled to augment the level of understanding of the extent and distribution of westward ground-water flow through the range. The Black Mountains do not seem to be part of a significant path of ground-water flow from the Amargosa region. This is attributed to the complex lithology and geologic history of the Black Mountains structural block and to the presence of the intervening Furnace Creek fault zone. The only ground-water discharge associated with the Black Mountains where water chemistry reflects an external source or sources is Saratoga Spring, for which δ 2 H and δ 18 O data indicate recharge in the Spring Mountains to the east. The southern part of the Funeral Mountains transmits a large volume of water through faulted and fractured rocks of Cambrian age that lie at or along the distal part of the northeast -oriented Spotted Range-Mine Mountain structural zone. Waters discharging from springs in the Furnace Creek Ranch vicinity (Travertine and Nevares) both compositionally and isotopically resemble waters from the Ash Meadows spring group in the Amargosa Desert. The Ash Meadows springs and water in the Amargosa Valley alluvium likely are chemically representative of ground water entering the southern Funeral Mountains. Much less ground water flows through the central and northern Funeral Mountains than flows through the southern part, as indicated by the geologic setting and chemistry of Keane Wonder Spring. The northern one-half of the mountains comprises early-to-middle Proterozoic metamorphic rocks that are the core of the Funeral Mountains anticlinorium. The core is largely unfaulted, plunges to the northeast and southwest, and is truncated to some extent on the east by the shallow-dipping Boundary Canyon fault. This structural setting and the paucity of springs in the northern one-half of the Funeral Mountains indicate a long traveltime from the Amargosa region to the western margin of the northern and central parts of the mountains. The Grapevine Mountains include the highest elevations in the Amargosa Range. Substantial precipitation and recharge above about 2,000 meters are evinced by numerous small springs and seeps along the east and west margins. The local nature of the recharge is reflected in δ 2 H and δ 18 O values and in the spring chemistries that indicate control by Tertiary volcanic rocks. The highest spring discharges associated with the Grapevine Mountains are near the north end of the mountains in the Grapevine Ranch area. The springs in this area are similar chemically and isotopically, except for one or two order-of-magnitude differences in calcium, magnesium, and strontium concentrations and a 1.2 per mil difference in δ 13 C values. These differences can be attributed to differences in the distal parts of the respective flow paths. The springs also lie at the end of a northeast -oriented structural zone in the Walker Lane Belt, and their δ 2 H, δ 13 C, and δ 18 O values indicate a recharge area likely to the northeast, outside of the Grapevine Mountains.

California;Nevada↗

Forty-first annual report of the Director of the United States Geological Survey

The appropriations for the public work under the United States Geological Survey for the fiscal year 1919-20 comprised items amounting to $1,586,353.50. In general the results of the varied activities of the Geological Survey may be regarded as meeting with a constantly increasing measure of public approval, as shown by the larger use that is being made of this branch of the public service. Correspondence with all classes of citizens—ranchers and corporation officials, school children and university professors, prospectors and mining engineers—has continued to increase, and this gain has been evident in the requests both for specific information and for publications. Ten years ago a telegraphic request for a map or report was a notable incident; now telegrams of this kind are of daily occurrence. Especially gratifying has been the popular demand for topographic maps, the increase in sales this year being 70 per cent. The number of all publications—books and maps—distributed during the year exceeded the number printed this year, this disproving the common assertion that Government publications simply accumulate until they become only waste paper. Indeed, an embarrassing feature of much of the correspondence during the year has been the thousands of requests for reports that were out of print, and more reprints than usual of exhausted editions have been authorized to meet an insistent demand. The public is making use of the publications of the Geological Survey as never before.

Annual Report↗

Invertebrate trophic structure on marine ferromanganese and phosphorite hardgrounds

The Southern California Borderland hosts a variety of geologic and oceanographic features that allow for diverse habitats to occur in a restricted region with a strong oxygen minimum zone (OMZ) and hard substrates. These include ferromanganese (FeMn) crusts and phosphorites targeted for deep-seabed mining in other regions. Baseline studies regarding hardground macro- (> 0.3 mm) and megafaunal (> 2 cm) invertebrates are lacking, although they contribute to understanding nutrient cycling and resilience of deep-sea communities to ocean deoxygenation, fishing, or mineral extraction. With the goal of understanding how substrate type, depth, and dissolved oxygen concentration influence invertebrate trophic structure, we surveyed δ 13 C and δ 15 N values of invertebrates on hard substrates on the Southern California Borderland margin along a depth gradient (120–2400 m) through the OMZ at inshore (< 100 km from shore) and offshore (100–250 km from shore) sites, using generalized additive models and community-level metrics. Macrofaunal isotopic values correlate with substrate type, exhibiting higher trophic diversity on FeMn crusts and specialized communities on phosphorites. Megafaunal isotopic values correlate with proximity to shore; animals offshore seem to depend more on phytoplanktonic production than animals inshore. In general, δ 15 N increased with decreasing dissolved oxygen and increasing depth, possibly due to remineralization processes within the OMZ and with depth. We discuss how feeding modes and community composition might influence the observed patterns. This study elucidates the importance of the environmental context in shaping invertebrate trophic structure on continental margins and provides baseline knowledge that may be useful in regions where these minerals are targeted for extraction.

Limnology and Oceanography↗

Ore microscopy of the Paoli silver-copper deposit, Oklahoma

The Paoli silver-copper deposit is located in south-central Oklahoma, 56 km south-southeast from Norman, Oklahoma. It was mined for high-grade silver-copper near the beginning of this century, and intensive exploratory drilling during the early 1970's delineated unmined portions of the deposit. A collaborative study between the U.S.G.S., the Kansas Geological Survey, and the University of Missouri-Rolla was undertaken to provide new information on the character of red bed copper deposits of the Midcontinent region. The Paoli deposit has been interpreted to occur as a roll-front type of deposit. The silver and copper mineralization occurs within paleochannels in the Permian Wellington Formation. The silver-copper interfaces appear to be controlled by oxidation-reduction interfaces that are marked by grey to red color changes in the host sandstone. Ore microscopic examinations of polished thin sections show that unoxidized ore consists of chalcocite, digenite, chalcopyrite, covellite and pyrite; and oxidized ores are characterized by covellite, bornite, hematite and goethite. In sandstone-hosted ores, chalcocite and digenite replace dolomite and border clastic quartz grains. In siltstone-hosted ores, the copper sulfide grains have varied shapes; most are irregular in shape and 5–25 μm across, others have euhedral shapes suggestive of pyrite crystal replacements, and some are crudely spherical and are 120–200 μm across. Chalcopyrite is the predominant copper sulfide at depth. Covellite and malachite replace chalcocite and digenite near the surface. Silver only occurs as native silver; most as irregularly shaped grains 40–80 μm across, but some as cruciform crystals that are up to 3.5 mm across. The native silver has been deposited after copper sulfides, and locally replaces chalcocite. Surficial nodules of pyrite, malachite and hematite locally are present in outcrops at the oxidation-reduction fronts. Polished sections of the nodules show that malachite forms a cement around quartz sand grains, and brecciated pyrite grains are surrounded by rims of hematite and goethite. Dolomite is the principal sandstone cement. Cathodoluminescence microscopic study of the mineral has shown that it was deposited during seven periods before the copper sulfide mineralization.

Oklahoma↗

Methods for synthesis of some jarosites

Experimental procedures in this report summarize attempts to synthesize potassium-, hydronium-, sodium-, and mixed-composition (hydronium-bearing) jarosites. After experimentation, some acceptable combinations of chemical and physical factors were found to routinely synthesize chemically different jarosites, which were used as part of a characterization study of some natural and synthetic jarosites. Jarosite is a sulfate mineral that is common in geologic settings where iron sulfide minerals such as pyrite or marcasite are subject to oxidative weathering. The presence of jarosite is a hallmark of acidic conditions. Jarosite forms as a secondary mineral in weathered sulfidic ores, coal mine wastes, on oxidizing mine wastes, and in streams affected by acid mine drainage. Jarosite also forms in acid-sulfate soils, as an alteration product of sulfidic shales, and in hydrothermal environments. Because of its important role in earth surface processes, the USGS is conducting mineralogical, geochemical, and remote sensing studies to characterize natural jarosites and to elucidate its stability range and conditions of formation. The presence of jarosite is not limited to the Earth. The recent identification of jarosite in the rocks at the Meridiani Planum on Mars has given planetary geologists reason to think that jarosite may be evidence of relict lacustrine (lake systems) or hydrothermal (water enriched magma emanations) systems on the Martian surface. USGS scientists are currently developing jarosite detection systems that can be placed on orbiting spectrometers. One day these systems may guide Mars landers to sites abundant in jarosite, sites most likely to have sheltered ancient Martian life.

Techniques and Methods↗

U. S. GEOLOGICAL SURVEY'S RESEARCH PROGRAM IN THE NEWLY PROCLAIMED EXCLUSIVE ECONOMIC ZONE.

The U. S. Geological Survey (USGS) has been developing a program which would emphasize broad-scale surveys of the continental margin and intensive studies of 'baseline corridors' in various areas of the U. S. EEZ to gather energy and mining information in this new frontier as quickly as possible. Of twelve baseline corridors identified to date along the east and west coasts and the Gulf of Mexico, the highest priority would be placed on areas off the west coast, including Juan De Fuca and Gorda Ridges and off Hawaii. Each corridor assessment will involve collection of multi-channel and high resolution geophysical data, bottom relief and sampling, and production of reports and cartographic products displaying the scientific findings of the assessments.

Conference Paper↗

Geologic studies in Alaska by the U.S. Geological Survey, 1997

The eight papers that follow continue the series of U.S. Geological Survey (USGS) reports on investigations in the geologic sciences in Alaska. The series presents new and sometimes preliminary findings that are of interest to earth scientists in academia, government, and industry; to land and resource managers; and to the general public. Reports presented in Geologic Studies in Alaska cover a broad spectrum of topics from all parts of the State (fig. 1), which serves to emphasize the diversity of USGS efforts to meet the Nation's needs for earth-science information in Alaska. The papers in this volume are organized under the topics Resources, Geologic Framework, and Environment and Climate. Such an organization is intended to reflect the scope and objectives of USGS programs currently active in Alaska. Resource papers include one that presents detailed observations from a Mississippian Zn-Pb-Cu-Ag occurrence in the Brooks Range (Werdon). Mineralogic, chemical, and isotopic data provide the basis for a proposed relationship between this vein-breccia deposit and the shale-hosted massive sulfide deposit type, which includes the active Red Dog mine in the western Brooks Range. Also included under the topic of Resources is a paper that presents geochemical and isotopic data from the Greens Creek and Woewodski Island volcanogenic massive sulfide deposits in southeastern Alaska (Newberry and Brew). The depositional environment and sedimentological setting of Tertiary coal beds in the Matanuska and Susitna Valleys is the focus of a third paper under the topic of Resources (Flores and others). Geologic Framework studies provide background information that is the scientific basis for present and future studies of the environment, mineral and energy resources, paleoclimate, and hazards in Alaska. One paper presents the results of sedimentologic and paleontologic comparisons of lower Paleozoic, deep-water-facies rock units in central Alaska (Dumoulin and others). The authors show which of these units are likely to correlate with one another, suggest likely source regions, and provide a structural restoration of units that have been fragmented by large fault motions. A second framework paper provides a map, rock descriptions, and chemical compositions of volcanic rocks in a newly recognized, geologically young volcanic center in the Aleutian volcanic arc (Hildreth and others). A third paper presents an interesting summary of gravity changes that occurred in south-central Alaska during the great earthquake of 1964 and for the following 25 years (Barnes). Gravity changes correlate with land-elevation changes in some cases, but not in others, which means that different processes are responsible for the gravity changes.

Alaska↗

Rare earth element mineral deposits in the United States

Because of their unique special chemical properties, many of the metals in the group of rare earth elements (REEs) have essential applications in 21st century technologies. Examples of products that use REEs are cell phones, computers, fluorescent and light-emitting-diode lights, flat-screen television and computer monitors, and in high-strength magnets used by clean energy technologies such as the generators of wind turbines and batteries of hybrid and electric vehicles. REEs are used in many defense applications, such as in components of jet engines, missile guidance systems, antimissile defense systems, satellites, and communication systems. The rare earth elements have become vital to manufacturing numerous high-tech products, which has been accompanied by a large increase in their demand. At the same time, there has been concern by the United States and many other Nations about the near-monopoly of mining, processing, and supply of REEs from one Nation, China. Between 2011 and 2017, China produced approximately 84 percent of the world’s REEs, and during this time the United States only produced REEs between 2012 and 2015. The U.S. production came entirely from the Mountain Pass mine in California, providing only about 4 percent of the world REE supply. Because REEs are essential for technological applications and are primarily supplied by one Nation, there has been an increased concern in identifying new sources of REEs, including economic REE deposits. In response to these concerns, since 2009, the U.S. Geological Survey (USGS) has conducted numerous studies focused on the distribution, geology, and potential resources for the REE-bearing mineral deposits in the United States. The basic characteristics of mineral deposit types that host REE enrichments in the United Sates are summarized in this report, with selected examples. Several types of REE-enriched mineral deposits are reviewed, including deposits in carbonatites, alkaline igneous rocks, sedimentary phosphate-rich rocks (phosphorite), regions containing REE-rich veins, iron oxide deposits containing REE-bearing apatite, monazite-xenotime-bearing placer deposits (heavy-mineral sands), and ion-adsorption clay deposits (REE in granite-derived regolith). A better understanding of these mineral deposits will assist in identifying domestic resources to help alleviate the dependence on imported REEs. The economic development of REE mineral deposits is affected by many factors beyond mining, such as commodity prices and mineral processing costs. Most of the REEs are hosted by minerals that have complex chemical formulas; this presents more challenges to process and extract the REEs. Continued advancements and refinements in mineral processing techniques may allow REE deposits with complex mineralogy to be economically developed in the future.

Circular↗

Preliminary assessment of channel stability and bed-material transport in the Tillamook Bay tributaries and Nehalem River basin, northwestern Oregon

This report summarizes a preliminary study of bed-material transport, vertical and lateral channel changes, and existing datasets for the Tillamook (drainage area 156 square kilometers [km 2 ]), Trask (451 km 2 ), Wilson (500 km 2 ), Kilchis (169 km 2 ), Miami (94 km 2 ), and Nehalem (2,207 km 2 ) Rivers along the northwestern Oregon coast. This study, conducted in coopera-tion with the U.S. Army Corps of Engineers and Oregon Department of State Lands to inform permitting decisions regarding instream gravel mining, revealed that: Study areas along the six rivers can be divided into reaches based on tidal influence and topography. The fluvial (nontidal or dominated by riverine processes) reaches vary in length (2.4-9.3 kilometer [km]), gradient (0.0011-0.0075 meter of elevation change per meter of channel length [m/m]), and bed-material composition (a mixture of alluvium and intermittent bedrock outcrops to predominately alluvium). In fluvial reaches, unit bar area (square meter of bar area per meter of channel length [m 2 /m]) as mapped from 2009 photographs ranged from 7.1 m 2 /m on the Tillamook River to 27.9 m 2 /m on the Miami River. In tidal reaches, all six rivers flow over alluvial deposits, but have varying gradients (0.0001-0.0013 m/m) and lengths affected by tide (1.3-24.6 km). The Miami River has the steepest and shortest tidal reach and the Nehalem River has the flattest and longest tidal reach. Bars in the tidal reaches are generally composed of sand and mud. Unit bar area was greatest in the Tidal Nehalem Reach, where extensive mud flats flank the lower channel. Background factors such as valley and channel confinement, basin geology, channel slope, and tidal extent control the spatial variation in the accumulation and texture of bed material. Presently, the Upper Fluvial Wilson and Miami Reaches and Fluvial Nehalem Reach have the greatest abundance of gravel bars, likely owing to local bed-material sources in combination with decreasing channel gradient and valley confinement. Natural and human-caused disturbances such as mass movements, logging, fire, channel modifications for navigation and flood control, and gravel mining also have varying effects on channel condition, bed-material transport, and distribution and area of bars throughout the study areas and over time. Existing datasets include at least 16 and 18 sets of aerial and orthophotographs that were taken of the study areas in the Tillamook Bay tributary basins and Nehalem River basin, respectively, from 1939 to 2011. These photographs are available for future assessments of long-term changes in channel condition, bar area, and vegetation establishment patterns. High resolution Light Detection And Ranging (LiDAR) surveys acquired in 2007-2009 could support future quantitative analyses of channel morphology and bed-material transport in all study areas. A review of deposited and mined gravel volumes reported for instream gravel mining sites shows that bed-material deposition tends to rebuild mined bar surfaces in most years. Mean annual deposition volumes on individual bars exceeded 3,000 cubic meters (m 3 ) on Donaldson Bar on the Wilson River, Dill Bar on the Kilchis River, and Plant and Winslow Bars on the Nehalem River. Cumulative reported volumes of bed-material deposition were greatest at Donaldson and Dill Bars, totaling over 25,000 m 3 per site from 2004 to 2011. Within this period, reported cumulative mined volumes were greatest for the Donaldson, Plant, and Winslow Bars, ranging from 24,470 to 33,940 m 3 . Analysis of historical stage-streamflow data collected by the U.S. Geological Survey on the Wilson River near Tillamook (14301500) and Nehalem River near Foss (14301000) shows that these rivers have episodically aggraded and incised, mostly following high flow events, but they do not exhibit systematic, long-term trends in bed elevation. Multiple cross sections show that channels near bridge crossings in all six study areas are dynamic with many subject to incision and aggradation as well as lateral shifts in thalweg position and bank deposition and erosion. In fluvial reaches, unit bar area declined a net 5.3-83.6 percent from 1939 to 2009. The documented reduction in bar area may be attributable to several factors, including vegetation establishment and stabilization of formerly active bar surfaces, lateral channel changes and resulting alterations in sediment deposition and erosion patterns, and streamflow and/or tide differences between photographs. Other factors that may be associated with the observed reduction in bar area but not assessed in this reconnaissance level study include changes in the sediment and hydrology regimes of these rivers over the analysis period. In tidal reaches, unit bar area increased on the Tillamook and Nehalem Rivers (98.0 and 14.7 percent, respectively), but declined a net 24.2 to 83.1 percent in the other four tidal reaches. Net increases in bar area in the Tidal Tillamook and Nehalem Reaches were possibly attributable to tidal differences between the photographs as well as sediment deposition behind log booms and pile structures on the Tillamook River between 1939 and 1967. The armoring ratio (ratio of the median grain sizes of a bar's surface and subsurface layers) was 1.6 at Lower Waldron Bar on the Miami River, tentatively indicating a relative balance between transport capacity and sediment supply at this location. Armoring ratios, however, ranged from 2.4 to 5.5 at sites on the Trask, Wilson, Kilchis, and Nehalem Rivers; these coarse armor layers probably reflect limited bed-material supply at these sites. On the basis of mapping results, measured armoring ratios, and channel cross section surveys, preliminary conclusions are that the fluvial reaches on the Tillamook, Trask, Kilchis, and Nehalem Rivers are currently sediment supply-limited in terms of bed material - that is, the transport capacity of the channel generally exceeds the supply of bed material. The relation between transport capacity and sediment is more ambiguous for the fluvial reaches on the Wilson and Miami Rivers, but transport-limited conditions are likely for at least parts of these reaches. Some of these reaches have possibly evolved from sediment supply-limited to transport-limited over the last several decades in response to changing basin and climate conditions. Because of exceedingly low gradients, all the tidal reaches are transport-limited. Bed material in these reaches, however, is primarily sand and finer grain-size material and probably transported as suspended load from upstream reaches. These reaches will be most susceptible to watershed conditions affecting the supply and transport of fine sediment. Compared to basins on the southwestern Oregon coast, such as the Chetco and Rogue River basins, these six basins likely transport overall less gravel bed material. Although tentative in the absence of actual transport measurements, this conclusion is supported by the much lower area and frequency of bars and longer tidal reaches along all the northcoast rivers examined in this study. Previous studies suggest that the expansive and largely unvegetated bars visible in the 1939 photographs are primarily associated with voluminous sedimentation starting soon after the first Tillamook Burn fire in 1933. However, USGS studies of temporal bar trends in other Oregon coastal rivers unaffected by the Tillamook Burn show similar declines in bar area over approximately the same analysis period. In the Umpqua and Chetco River basins, historical declines in bar area are associated with long-term decreases in flood magnitude. Other factors may include changes in the type and volume of large wood and riparian vegetation. Further characterization of hydrology patterns in these basins and possible linkages with climate factors related to flood peaks, such as the Pacific Decadal Oscillation, could support inferences of expected future changes in vegetation establishment and channel planform and profile. More detailed investigations of bed-material transport rates and channel morphology would support assessments of lateral and vertical channel condition and longitudinal trends in bed material. Such assessments would be most practical for the fluvial study areas on the Wilson, Kilchis, Miami, and Nehalem Rivers and relevant to several ongoing management and ecological issues pertaining to sand and gravel transport. Tidal reaches may also be logical subjects for indepth analysis where studies would be more relevant to the deposition and transport of fine sediment (and associated channel and riparian conditions and processes) rather than coarse bed material.

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Hydrologic studies of the U.S. Geological Survey related to coal development on Colorado

This report summarizes the hydrologic studies related to coal development being conducted by the U.S. Geological Survey in the State of Colorado. The objective of the hydrologic data-acquisition program is to collect surface-water quality and quantity data and ground-water level records. These data are needed to define predevelopment conditions and to monitor the effects of construction and operation of coal mines and waste-disposal areas. Data-acquisition activities related to coal development in Colorado have concentrated on the Yampa River basin. A description of the hydrologic data-acquisition activities, including parameters collected and frequency of collection, precedes the summaries of the three interpretive studies currently in progress. Each study summary consists of the project title, definition of the problem being studied, objective of the study, approach of the study, and when known, the schedule for completion of the study and proposed report products resulting from the study. (Woodard-USGS)

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