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Wangyanite, PdNi8S8, a new Pd end-member mineral of the pentlandite group from the J-M reef, Stillwater Complex, Montana, USA

Wangyanite (IMA2024-008a), ideally PdNi 8 S 8 , is a Pd end-member mineral of the pentlandite group that was discovered in the J-M reef of the Stillwater Complex, Montana, USA. Wangyanite occurs as anhedral-subhedral granular crystals 200–400 µm in size, associated with isoferroplatinum, braggite, pentlandite, and chalcopyrite interstitial to plagioclase grains within anorthosite. Wangyanite exhibits a yellowish brown color with a black streak and a metallic luster. It is brittle with uneven fractures, and has a calculated density of 5.14 g/cm 3 . The mineral does not show discernible pleochroism, bireflectance, or anisotropy. It has an average composition of 9.95 wt.% Pd, 31.95 wt.% Ni, 25.02 wt.% Fe, 0.57 wt.% Co, 31.74 wt.% S, totaling 99.23 wt.%. The empirical formula, based on eight sulfur atoms per formula unit, is (Pd 0.76 Co 0.08 ) Σ0.84 (Ni 4.39 Fe 3.60 ) Σ7.99 S 8 . Wangyanite has a cubic cell with a space group of Fm -3 m (#225), having lattice parameters of a = 10.1167(12) Å, V = 1035.4(4) Å 3 , and Z = 4. Its crystal structure has been solved by single-crystal three-dimensional electron diffraction study. The strongest X-ray diffraction lines of wangyanite are claculated at [ d in Å ( I %)( hkl )]: 5.841(14.03)(111), 3.050(100)(311), 1.947(29.16)(115,333), 1.264(11.66)(800), 3.577(8.79)(220), 2.920(20.82)(222), and 2.321(9.34)(331). Wangyanite shares the same crystal structure as pentlandite, but the octahedrally coordinated site is mainly occupied by Pd in wangyanite. Based on the textural features and previous experimental Pd-Fe-Ni-S phase system, wangyanite could form by peritectic reaction between braggite, pentlandite and sulfide liquid. These mineral associations are stable in a Ni-Pd-rich sulfide melt system at about 550 °C or even lower temperature. Therefore, wangyanite can potentially serve as an indicator of the presence of Pd-rich residual melts. The mineral is named in honor of Prof. Christina Yan Wang, a well-known researcher on platinum-group element (PGE) occurrences and enrichment mechanisms in mafic-ultramafic intrusions, notably those deposits related to the Emeishan large igneous province in China.

Montana

Advancing current understanding of Martian impact-generated hydrothermal systems through novel coupled modeling: Insights from Gale, Jezero, and other craters

Impact-generated hydrothermal systems are considered potentially habitable environments on Mars, Earth, and other planetary bodies for microbial life. However, there is an ongoing debate regarding what geological features on Mars provide definitive evidence for such systems. Although earlier studies have modeled hydrothermal processes in Martian craters, they often lacked integration with shock physics hydrocodes to constrain initial impact conditions. The importance of this two-code coupling was demonstrated by successfully replicating alteration signatures in the Earth's Haughton impact structure. In this study, we use a similar two-code approach, combining the iSALE hydrocode with the HYDROTHERM hydrothermal model to simulate the full evolution of impact-generated hydrothermal systems. We apply this method to craters the size of Jezero (∼50 km) and Gale (∼154 km) in diameter. Although Jezero's interior is largely buried, our results align with hypothesized hydrothermal vents and alteration minerals near central uplifts in similarly sized exposed craters, such as Toro and Auki. Furthermore, our models correspond to alteration patterns observed by the Curiosity in the lower layers of Mount Sharp, which may represent remnants of impact-driven hydrothermal activity. A key finding is that these systems may persist much longer than previously estimated. Our simulations suggest that a Jezero-sized system could remain habitable for thermophiles for approximately 720,000 years, whereas a Gale-sized system could persist for nearly 2 million years. Additionally, simulations under unsaturated crustal conditions reveal that air-dominated near-surface layers can suppress vertical fluid flow, enabling deep subsurface alteration without producing detectable mineral signatures at the surface.

Journal of Geophysical Research - Planets

USGS addresses needs for lithium calibration and quality control materials for pLIBS analysis

Lithium (Li) is a globally important commodity used for energy storage, national defense, human health, and advanced technologies. Lithium resource development requires identifying deposits with elevated concentrations and optimal mineralogy, typically associated with select clays and pegmatites. Lithium is a light, highly reactive alkali metal with low atomic mass that is difficult to detect and quantify using conventional portable geochemical techniques such as X-ray fluorescence (XRF). However, portable laser-induced breakdown spectroscopy (pLIBS) is a powerful analytical technique for lithium exploration due to its ability to analyze solids quickly with minimal preparation. The expanded utility of pLIBS is hampered by the lack of matrix-matched calibration and quality control (QC) materials. The United States Geological Survey (USGS) has developed in-house lithium calibration and QC materials for lithium in clay and pegmatite matrices to address this limitation. We present the workflow and implementation of a custom-built matrix specific calibration on a SciAps Z-300 pLIBS, using proprietary Profile Builder software. The implementation of the custom calibration and quality control standards enables us to collect semiquantitative results directly from the pLIBS while in the field. Ultimately, this calibration has improved confidence in sample selection and collection in the field, providing more efficient site characterization.

Conference Paper

A diatom-based quantitative sea-ice proxy for the Bering and Chukchi seas

Sea ice affects Earth's climate system on both regional and global scales. Its incorporation into climate can be used to achieve more accurate predictions of future climate. However, instrumental records of sea-ice concentration do not extend earlier than 1978. In an effort to extend this record, we constructed a proxy using the generalized additive model based on relative abundances of five easy-to-identify diatom species found in sediment samples across the Bering and Chukchi seas. Here we present the first quantitative diatom-based sea-ice proxy developed for Beringia. The developed proxy has been applied to two sediment cores in the Bering Sea ranging from 0 to 25.7 ka (HLY0204 51JPC) and 369 to 430 ka (IODP Exp 323 Site U1345) and one in the Chukchi Sea ranging from 2.7 to 10 ka (HLY0204 24JPC). The obtained reconstructions of sea-ice concentrations are similar, but not identical to previously published qualitative and nearby records based on other proxies. Because our results are quantitative, they can be incorporated into regional climate models. The proxy is publicly available as an R Shiny application (app) and can be applied to any diatom count from marine sediments in the region.

Bering Sea, Chukchi Sea

Earthquake recurrence estimates for northern Caribbean faults from combinatorial optimization

We use combinatorial optimization to find the optimal spatial distribution of random samples of earthquakes (≥6.5) that minimize the misfit in target slip rates for all faults in the northeast Caribbean, and we derive magnitude-frequency relationships with uncertainties for these faults. Slip rates for many faults are derived from GPS block models, not direct measurements, because of their underwater locations. Predicted recurrence rates for eastern Hispaniola and Puerto Rico Trench faults are 220-450 yr for M7 and 3-5 kyr for M8, with maximum feasible magnitude of M8.2. The most frequent earthquakes with magnitudes ≥7.0 are predicted on the large upper plate strike-slip faults, Enriquillo (EF) and Septentrional Fault, commensurate with the historical record. Calais et al. (2023) suggested that shortening in western Hispaniola is accommodated on the offshore Jérémie and onshore Malpasse faults north and south of EF, instead of on terrestrial faults in western Hispaniola and EF. Because of our system-modeling approach, such a configuration predicts less frequent earthquakes on EF and on western Hispaniola and Muertos convergent zones. Recurrence times of a few 100s yr for M6.7 earthquakes is predicted on the submerged faults in Mona Passage, and infrequent M>7 earthquakes are predicted on the Virgin Islands faults.

Lesser Antilles

Simulation of groundwater flow to evaluate hydrogeologic controls on a PFAS plume, Coakley Landfill Superfund Site, Rockingham County, New Hampshire

Per- and polyfluoroalkyl substances (PFAS), including perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS), have been detected at combined concentrations above 2,000 nanograms per liter (ng/L) at groundwater seep locations near the Coakley Landfill Superfund site, in North Hampton, New Hampshire. The landfill was active from 1972 to 1985. An impermeable cap was placed on the landfill in 1998. The adjacent area to the Coakley Landfill has many water supply wells, and transport of PFAS compounds to the wells is a concern. Fracture anisotropy in the underlying bedrock aquifer complicates the understanding of PFAS transport because groundwater preferentially travels along fractures that may not align with the prevailing groundwater flow direction. In 2018, the U.S Environmental Protection Agency and the U.S. Geological Survey began an investigation of the groundwater flow from the Coakley Landfill site. This report describes the modification of a numerical groundwater-flow model for the local area around the Coakley Landfill and summarizes findings of the investigation. In addition, this report includes a brief description of PFOA and PFOS occurrence, a discussion of model construction, evaluation of model performance through calibration, and discussion of simulation results for two periods (before and after capping). Limitations are also discussed. Results show that simulated groundwater flow moves from the Coakley Landfill to the west and north. Advective transport modeling using particle tracking shows that groundwater from the landfill discharges primarily to streams to the west and north, and a small amount is transported to distal wells. Dilution of contaminants through advection and dispersion likely plays a role in whether PFAS compounds from the landfill will be detected above laboratory reporting levels at distal wells.

EarthArXiv

Sackung at Bald Eagle ridge, central Colorado: An updated interpretation of ridge-spreading movement, structures, and mechanisms from 50 years (1975–2025) of U.S. Geological Survey research

Slow gravitational failures of mountain peaks and ridges are poorly understood. Herein, we report on 50 years of studies at a slowly spreading castellate ridge in the Sawatch Range in central Colorado. The orientations of geomorphic-structural features indicate that the fractured Precambrian granitic rock underlying the ridge has extended and spread northwestward toward the formerly glacier-covered Busk Creek valley. Results from surveying, field-based geomorphic-structural mapping using lidar, rock mass quality measurements, a passive seismic survey, and satellite radar provide a major update to research started by U.S. Geological Survey researchers in the 1970s and 1980s. New insights include a recognition that the entire ridge has slowly moved by concurrent sliding along an inferred northwest dipping, compound basal-slip surface (or zone), and through the formation of multiple grabens by normal faulting and flexural toppling along sets of pre-existing fractures that dip moderately (∼45°) to the southeast. We were unable to distinguish the presence of a sudden and strong contrast in seismic velocity across the inferred slip surface. Movement during the 50-year study period has been episodic and gradually decreasing, in correspondence with decreasing cumulative annual precipitation and increasing mean annual air temperatures. The fastest moving area, just upslope from the glacier trimline, had an average horizontal velocity of 3 – 4 mm/yr. Evidence suggests that movement started as a paraglacial response mechanism, but because of the site’s proximity to the Rio Grande Rift, we cannot exclude earthquake shaking as a mechanism for initiation or enhancement of slope movement. An estimate of longer-term horizontal movement from the exposed basal-slip surface at the uphill side of the ridgetop graben is ∼1.1 mm/yr for the 13 – 14 ky post-glacial period. Broad implications of our work are that: (1) long-term measurements (decades or longer) of slope movement can add insights into how sackungen form and evolve through time; (2) the identification of thrust faults and toes in zones of compression near valley bottoms can be crucial for interpreting sackung failure mechanisms, and (3) the use of passive-seismic techniques to identify the depth to a slip surface may not be successful in granitic terrain dominated by planar fractures and subtle changes in rock-mass characteristics.

Colorado

Satellite tracking of Galapagos Petrel Pterodroma phaeopygia reveals distribution and movements during chick rearing

We tracked 19 adult Galapagos Petrels Pterodroma phaeopygia during the chick-rearing seasons in 2009 and 2010 (Santa Cruz Island [ n = 16] and Floreana Island [ n = 3]) in the Galápagos Islands, Ecuador. Eight petrels performed 27 complete foraging trips lasting 0.6 to 18.8 days. Short trips (3.2 ± 2.1 days; 785 km; max displacement 671 km) and long trips (10.8 ± 3.9 days; 2,856 km; max displacement 1,034 km) resulted in concentrated use of waters off southern and western Isabela Island and within the Galápagos Marine Reserve (GMR). Less concentrated time extended farther southwest and eastward, in that case toward mainland Ecuador. Total distance covered among all completed trips, independent of duration, was strongly correlated with trip duration ( R ² = 0.92), indicating a strategy favoring active searching and foraging over commuting. Petrels ranged across Ecuador's exclusive economic zone (EEZ), as well as other countries' (Colombia, Costa Rica, Perú), and waters beyond; they spent 46%, 27%, and 34% of their time in the GMR during short, long, and apparent (incomplete) trips, respectively. However, overlap with EEZs or marine protected areas (MPAs) does not necessarily confer protection, because commercial tuna fishing, including legal fishing historically permitted inside the GMR, occurs within these waters. Including all complete and incomplete trips, petrels spent 37% of their time in high-seas waters without formal protection, outside both MPAs and EEZs. While some hot spots overlapped Galápagos MPAs, the far-ranging nature of chick-provisioning petrels underscores the importance for this species of also having coordinated, multinational protection of the high seas.

Floreana Island, Galápagos Islands, Santa Cruz Isl

Leveraging wildfire to augment forest management and amplify forest resilience

Successive catastrophic wildfire seasons in western North America have escalated the urgency around reducing fire risk to communities and ecosystems. In historically frequent-fire forests, fuel buildup as a result of fire exclusion is contributing to increased fire severity. The probability of high-severity fire can be reduced by active forest management that reduces fuels, prompting federal and state agencies to commit significant resources to increase the pace and scale of fuel reduction treatments. However, lower severity areas of wildfires also have the potential to act as “treatments,” and even catastrophic fires with large areas of high severity can still have substantial areas of lower severity fire that may be improving forest conditions locally. We quantified active management and wildfire severity across yellow pine and mixed conifer (YPMC) forests in the Sierra Nevada of California over a 22-year period (2001–2022). We did not detect increases in the area treated through time, but the area of beneficial wildfire (low to moderate severity) increased substantially, exceeding active treatment area in 8 of 22 years. Overall, beneficial wildfire treated ~17% more area than all treatments combined, and roughly four times more area than fire-related treatments alone. We then used disturbance history to evaluate resistance to high-severity wildfire and forest loss across the YPMC range. Of the 2.3 million ha YPMC of forests in 2001, 20% lost mature forests due to high-severity fire by 2022, which is nearly half of all YPMC area burned. Most of the landscape (47%) remains at risk of high-severity fire because it had no restorative disturbances, but 33% of the study area has some level of resistance to high-severity wildfire. In these areas, resistance will need to be enhanced and maintained over time via active management or managed wildfire, but these treatment needs will likely outpace capacity even under optimistic implementation scenarios. Given limited resources for implementing active management and the likelihood of a more fiery future, incorporating beneficial wildfire into landscape-level treatment planning has the potential to amplify the impact of active management treatments.

California, Nevada

A deep dive into subduction zones and the Japan Trench

Deep beneath the ocean, giant slabs of rock slide beneath one another in areas called subduction zones. These powerful movements shape the planet by building mountains, creating fiery volcanoes, and even causing huge earthquakes. Scientists study subduction zones to understand why these natural events happen and where and how they might occur so we can be better prepared. One important subduction zone is the Japan Trench, where a big earthquake happened in 2011. To learn more about subduction zones, scientists go on ocean drilling expeditions. They sail on research ships, drill into the seafloor, and collect rock samples. These samples help scientists understand what happened in the past and how subduction zones work. In turn, this information helps communities better understand and prepare for future earthquakes.

Frontiers for Young Minds

Simulation of groundwater flow to evaluate hydrogeologic controls on a PFAS plume, Coakley Landfill Superfund site, Rockingham County, New Hampshire

Per- and polyfluoroalkyl substances (PFAS), including perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS), have been detected at combined concentrations above 2,000 nanograms per liter (ng/L) at groundwater seep locations near the Coakley Landfill Superfund site, in North Hampton, New Hampshire. The landfill was active from 1972 to 1985. An impermeable cap was placed on the landfill in 1998. The adjacent area to the Coakley Landfill has many water supply wells, and transport of PFAS compounds to the wells is a concern. Fracture anisotropy in the underlying bedrock aquifer complicates the understanding of PFAS transport because groundwater preferentially travels along fractures that may not align with the prevailing groundwater flow direction. In 2018, the U.S. Environmental Protection Agency and the U.S. Geological Survey began an investigation of the groundwater flow from the Coakley Landfill site. This report describes the modification of a numerical groundwater-flow model for the local area around the Coakley Landfill and summarizes findings of the investigation. In addition, this report includes a brief description of PFOA and PFOS occurrence, a discussion of model construction, evaluation of model performance through calibration, and discussion of simulation results for two periods (before and after capping). Limitations are also discussed. Results show that simulated groundwater flow moves from the Coakley Landfill to the west and north. Advective transport modeling using particle tracking shows that groundwater from the landfill discharges primarily to streams to the west and north, and a small amount is transported to distal wells. Dilution of contaminants through advection and dispersion likely plays a role in whether PFAS compounds from the landfill will be detected above laboratory reporting levels at distal wells.

New Hampshire

Modeled groundwater and surface-water interactions surrounding Mobile Bay, Alabama, 2008–15

The U.S. Geological Survey, in cooperation with the Gulf Coast Ecosystem Restoration Council, has used MODFLOW 6 to develop a groundwater-flow model to simulate groundwater and surface-water interactions in the Mobile Bay, Alabama, area. The model results indicated that, on average, groundwater discharge near the coastline is equal to 2.5 percent of the surface water that flows into the bay. The model was also used to determine how changes in recharge, sea level, and groundwater pumping affect groundwater levels and discharge rates. The results indicate that more groundwater discharge occurred in the winter and spring when recharge was higher, sea level was lower, and groundwater pumping was lower than during the summer and fall. Additionally, the amount of emergent groundwater was closely related to sea level; when sea level was higher, there was more area with emergent groundwater. Furthermore, the depth of nonemergent groundwater was related to trends in recharge and pumping. During periods of increased recharge and reduced pumping, a significant portion of the model area exhibited a depth to the water table of less than 1 meter below the land surface. Conversely, during periods of decreased recharge and heightened pumping, much of the model area showed a depth to the water table ranging from 1 to 5 meters.

Alabama, Mississippi

3D viscoelastic models of slip-deficit rate along the Cascadia subduction zone

Interseismic deformation in the Pacific Northwest is constrained by the horizontal crustal velocity field derived from the Global Positioning System (GPS) in addition to vertical rates derived from GPS, leveling, and tide gauge measurements. Such measurements were folded in to deformation models of fault slip rates as part of the 2023 National Seismic Hazard Model (NSHM) update. Here I build upon one of the contributing models, the viscoelastic earthquake-cycle model of Pollitz [2022]. This model permits inclusion of effects of time-dependent viscoelastic relaxation within earthquake cycles (i.e., ‘ghost transients’) and laterally variable elastic and/or ductile material properties. I lever-age these capabilities to incorporate the Cascadia megathrust into Western U.S.-wide deformation models in which crustal fault slip rates are estimated simultaneously with slip deficit rates along the interplate boundary between the descending Juan de Fuca plate and North American plate. This effort includes construction of a margin-wide model of viscoelastic structure founded on the Slab 2.0 model and probes different models of the ductile properties of the surrounding oceanic asthenosphere, continental lower crust, and mantle asthenosphere. This results in new estimates of the distribution of slip deficit rate along the ∼ 1000 km long margin, highlights the importance of correcting for glacial-isostatic adjustment effects, and permits assessment of sensitivity of results to assumed ductile properties.

California, Oregon, Washington

Metallurgical coal—Deposits, production, resources, market dynamics, and supply chain risks

Plain Language Summary Metallurgical coal (met coal; consumed to produce coke for steelmaking) must meet specific chemical and physical specifications. In 2023, the conterminous United States produced 66 million short tons (mst) of met coal, consumed 15.85 mst domestically, exported 51.1 mst, and imported 0.7 mst. Most met coal was produced in the Appalachian Basin, but there are also resources that meet the specifications for met coal in the Western United States.

conterminous United States

Nitrogen deposition weakens soil carbon control of nitrogen dynamics across the contiguous United States

Anthropogenic nitrogen (N) deposition is unequally distributed across space and time, with inputs to terrestrial ecosystems impacted by industry regulations and variations in human activity. Soil carbon (C) content normally controls the fraction of mineralized N that is nitrified ( ƒ nitrified ), affecting N bioavailability for plants and microbes. However, it is unknown whether N deposition has modified the relationships among soil C, net N mineralization, and net nitrification. To test whether N deposition alters the relationship between soil C and net N transformations, we collected soils from coniferous and deciduous forests, grasslands, and residential yards in 14 regions across the contiguous United States that vary in N deposition rates. We quantified rates of net nitrification and N mineralization, soil chemistry (soil C, N, and pH), and microbial biomass and function (as beta-glucosidase (BG) and N -acetylglucosaminidase (NAG) activity) across these regions. Following expectations, soil C was a driver of ƒ nitrified across regions, whereby increasing soil C resulted in a decline in net nitrification and ƒ nitrified . The ƒ nitrified value increased with lower microbial enzymatic investment in N acquisition (increasing BG:NAG ratio) and lower active microbial biomass, providing some evidence that heterotrophic microbial N demand controls the ammonium pool for nitrifiers. However, higher total N deposition increased ƒ nitrified , including for high soil C sites predicted to have low ƒ nitrified , which decreased the role of soil C as a predictor of ƒ nitrified . Notably, the drop in contemporary atmospheric N deposition rates during the 2020 COVID-19 pandemic did not weaken the effect of N deposition on relationships between soil C and ƒ nitrified . Our results suggest that N deposition can disrupt the relationship between soil C and net N transformations, with this change potentially explained by weaker microbial competition for N. Therefore, past N inputs and soil C should be used together to predict N dynamics across terrestrial ecosystems.

contiguous United States

Characterization and validation of tidally calibrated strains from the Alto Tiberina Near Fault Observatory Strainmeter Array (TABOO-NFO-STAR)

Six horizontal borehole tensor strainmeters (TSM1-6) installed from Fall 2021 to Spring 2022 comprise the Alto Tiberina Near Fault Observatory Strainmeter Array (STAR), providing an unprecedented opportunity to investigate seismic and aseismic deformation from hazardous high- and low-angle normal faults in Italy. Prior to use in tectonic applications, they require in-situ calibration and correction for non-tectonic signals. We tidally calibrate the instruments, characterize the calibration uncertainty, and test the results against environmental and earthquake signals originating from local to teleseismic distances. The STAR sites demonstrably deviate from assumptions common to the standard manufacturer's calibrations, including negative areal coupling at TSM3-6. While the tidally calibrated strains have ~3-56% uncertainty, the calibrated dynamic strains show interstation precision and accuracy to nanostrain levels, and static coseismic offsets in the array footprint are within uncertainty. TSM3 records a complex series of strains that may arise from dynamically triggered near-borehole fracture slip and fluid flow that does not appear to affect its sensitivity to lower strain rate deformation. Future calibration improvement may be afforded with longer stable timeseries, particularly for TSM4. Overall, our analyses demonstrate expanded geodetic capability for detecting deformation in the Alto Tiberina Near Fault Observatory.

Alto Tiberina Near Fault Observatory

Depth of magma crystallization and fluid exsolution beneath the porphyry-skarn Cu deposits at Santa Rita and Hanover-Fierro, New Mexico, USA

The depth level at which porphyry Cu–forming magmas fractionated and exsolved mineralizing fluids is actively debated. In the classic model, extensive magma fractionation occurs in large, upper crustal magma chambers, and concomitant fluid exsolution leads to forceful expulsion of residual magmas in the form of porphyry dikes, stocks, and breccia pipes, which subsequently serve as pathways for the mineralizing fluids. In contrast, some recent studies highlighting the role of deep crustal magma fractionation in the production of fertile magmas essentially deny the existence of upper crustal magma chambers at the time of mineralization. To address this, we conducted a detailed thermobarometric investigation of 13 intermediate to felsic, porphyritic intrusive rocks related to porphyry-skarn Cu mineralization at Santa Rita and Hanover-Fierro, New Mexico, United States, representing two premineralization magmas (61–60 Ma), seven synmineralization magmas (60–58 Ma), and four late- to postmineralization magmas (58–57 Ma). For each sample, the pressure of last magma crystallization before final magma ascent to the current exposure level was reconstructed based on Al-in-hornblende barometry of small hornblende inclusions trapped within quartz phenocrysts and through titanium-in-quartz (TitaniQ) thermobarometry of the host quartz phenocrysts themselves. Since quartz is one of the last crystallizing magmatic minerals, and no significant phenocryst growth could have occurred in small dikes and stocks after final magma emplacement, quartz phenocrysts and their contained hornblende inclusions record the depth of last magma crystallization before final magma ascent. When present, hornblende phenocrysts and hornblende inclusions within other major phenocrysts were also analyzed. Both quartz and hornblende barometers return consistent average pressures of 3.2 ± 0.4 kbar for the entire suite of pre- to postmineralization magmas, corresponding to depths of 11 to 14 km. The synmineralization magmas return even more consistent average pressures of 3.1 ± 0.2 kbar, corresponding to a depth of 12 ± 1 km. The volume of the mineralizing porphyry dikes and stocks at the emplacement level is far too small to have provided all the fluids and metals required to form the observed ore deposits. Therefore, the majority of the ore-forming fluids must have originated from the magmas that crystallized at 12 ± 1 km depth. The ore deposits, conversely, formed at ~5-km paleodepth. This implies that most of the mineralizing fluids traveled an average vertical distance of ~7 km from their magmatic source to the eventual site of ore precipitation. The relatively unaltered nature and low veining degree of deeper parts of mineralized porphyry dikes and stocks suggest that the fluid transport through these intrusive bodies occurred mostly at near-solidus conditions by means of fluid percolation along grain boundaries. In summary, our results suggest that (1) a large, upper crustal pluton exists ~7 km beneath the Santa Rita and Hanover-Fierro deposits; (2) abundant phenocryst crystallization occurred at this depth level; and (3) this pluton was the main source for the exsolution of ore-forming fluids. However, the investigated rocks have elevated whole-rock Sr/Y ratios, indicating magma fractionation at deep crustal levels. As a result, our preferred model is a combination of the two end-member models introduced above, with most magma fractionation having occurred in the deep crust and with residual, intermediate to felsic melts having ascended and accumulated at 11 to 14 km paleodepth, where they continued to crystallize with comparatively little crystal-liquid separation, before some of these magmas ascended further to shallow levels and quenched to porphyries.

New Mexico

Morphodynamics of snow barchans at Concordia Station, Antarctica

Barchans are crescent-shaped dunes that form and migrate under unimodal wind regimes in areas of low sediment availability. While sand barchan morphodynamics has been extensively studied, snow barchans remain poorly documented. Here, using hourly time-series images taken near Concordia Station, Antarctica, we measure the sizes (lengths 0.3 m to 13 m, widths 0.4 m to 7.5 m) and migration rates (0.13 m h −1 to 3.5 m h −1 ) of 44 populations of snow barchans during 2017–2022. We compare this dataset with established height–velocity and length-width relationships for sand barchans in both air and water. Our results show that snow barchans follow the same scaling as sand barchans, allowing us to estimate a characteristic sintering (bonding of snow particles) time of about one day. This sintering process limits the size of snow barchans when active, reduces their aspect ratios, and, once wind falls below the transport threshold, explains their preservation over a few years. During wind events, migrating barchans are too small to maintain their shape and orientation, making them highly responsive to fluctuations in wind direction. Thus, studying snow barchans improves understanding of an elementary bedform encountered in multiple environments and also of the surface properties of snow on different timescales, offering insights into snow accumulation and wind-blown snow in ice cores.

Geomorphica