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At least 1,369 records · Page 76Linked to original sources

Flood profile study, Morgan Creek, Linn County, Iowa

The purpose of this report is to present the results of a study made for a 35,000-foot reach of Morgan Creek. The report shows profiles computed for a large flood under existing conditions and for a smaller flood for two assumed conditions of encroachment. Flood-plain management can benefit from this type of information during future expansion of the urban area. This report is a result of a cooperative agreement between the City of Cedar Rapids and the U.S. Geological Survey that provides for the collection and analysis of flood data in, and near, the City of Cedar Rapids.

Iowa↗

Geology and ground water for land-use planning in the Eagle River-Chugiak area, Alaska

The Eagle River — Chugiak area is a rapidly growing residential part of the Greater Anchorage Area Borough, south-central Alaska. High-density, urban development in some parts of the area may be restricted because of the nature of the surficial geologic materials and their hydrologic characteristics. This report assembles all information collected by the U.S. Geological Survey on the geology and ground-water resources of the Eagle River — Chugiak area. The study area lies mostly within the Cook Inlet — Susitna Lowland and consists of low hills and intervening channels, hummocky ridges, sloping alluvial fans, and low-lying tidal flats that border Knik Arm. The eastern part of the area lies on the steep slopes of the Chugach Mountains. Drainage is generally to the west and northwest, except that locally the slopes drain southwesterly to the Eagle River, the major stream of the area.

Alaska↗

Occurrence and distribution of volatile organic compounds and pesticides in ground water in relation to hydrogeologic characteristics and land use in the Santa Ana basin, southern California

This report presents an evaluation of the occurrence and distribution of VOCs and pesticides in the Santa Ana ground-water basins in relation to two types of explanatory factors: hydrogeologic characteristics and land use. The Santa Ana Basin is subdivided into the San Jacinto, the Inland, and the Coastal ground-water basins. Most wells sampled were deep and used for public supply. Data from regional studies were used to evaluate the occurrence and distribution of pesticides and volatile organic compounds (VOCs) in relation to hydrogeologic characteristics and land uses that could potentially explain variations between basins. Additional data from special studies (flow path and aquifer susceptibility) were used to evaluate potential factors affecting water quality for individual basins. The hydrogeologic characteristics evaluated in this report were hydrogeologic setting, ground-water age, depth to the top of the well screen (top of well perforations), and proximity to engineered recharge facilities. Urban land use, agricultural land use, and population density were characterized within a 500-meter radius of sampled wells and at the basin scale. Aquifers in the San Jacinto Basin are generally unconfined, and major land-use categories are urban (33 percent), agricultural (37 percent), and undeveloped (25 percent). Recharge is primarily from the overlying landscape, but engineered recharge is locally important in the Hemet area. VOCs and pesticides were detected more frequently in younger ground water (less than 50 years old) than in older ground water, and more frequently in shallower wells than deeper wells; the numbers of VOCs and pesticides detected also were significantly higher in the younger ground water and in the shallower wells. In the Hemet area of the San Jacinto Basin, VOCs and pesticides were detected more frequently in wells proximal to engineered recharge facilities than in distal wells. These patterns illustrate the importance of proximity to sources of recharge in relation to the occurrence and distribution of VOCs and pesticides in ground water. Aquifers in the Inland Basin also are generally unconfined, and the major land-use category is urban (58 percent), with lesser amounts of agricultural (13 percent) and undeveloped (28 percent) land. Recharge is from engineered facilities that utilize local runoff and imported water and from vertical infiltration. VOCs and pesticides were detected more frequently in younger ground water than in older ground water, and more frequently in shallower wells than deeper wells. The number of VOCs detected per well also was significantly higher in the younger ground water and in the shallower wells. Several solvent plumes extending between 5 and 10 kilometers illustrate the large distances that contaminants travel in basins with intensive use of ground water. Aquifers in the Coastal Basin, in contrast to the other basins, are generally confined. Land use in the basin is largely urban (80 percent), with lesser amounts of agricultural (7 percent) and undeveloped (12 percent) land. Recharge is primarily from engineered facilities that utilize water diverted from the Santa Ana River and imported water. Consequently, VOCs and pesticides were detected more frequently in wells proximal to engineered recharge facilities than in distal wells. These compounds were also detected more frequently in the unconfined area than in the confined area of the basin. In the confined area, the numbers of VOCs and pesticides detected per well were not significantly different in wells with shallower and deeper screens. This distribution reflects the dominance of lateral flow and insulation from overlying land use in the confined aquifers of the Coastal Basin. In the unconfined area of the Coastal Basin, the numbers of VOCs and pesticides detected per well were significantly higher in shallower wells than in deeper wells. VOC and pesticide detections were not statist

Scientific Investigations Report↗

Occurrence and distribution of pesticides and volatile organic compounds in ground water and surface water in Central Arizona Basins, 1996-98, and their relation to land use

Samples of ground water and surface water from the Sierra Vista subbasin, the Upper Santa Cruz Basin, and the West Salt River Valley were collected and analyzed to determine the occurrence and distribution of pesticides and volatile organic compounds in central Arizona. The study was done during 1996-98 within the Central Arizona Basins study unit of the National Water-Quality Assessment program. This study included 121 wells and 4 surface-water sites in the 3 basins and the analyses of samples from 4 sites along the Santa Cruz River that were part of a separate study. Samples were collected from 121 wells and 3 surface-water sites for pesticide analyses, and samples were collected from 109 wells and 3 surface-water sites for volatile organic compound analyses. Certain pesticides detected in ground water and surface water can be related specifically to agricultural or urban uses; others can be related to multiple land uses. Effects from historical agriculture are made evident by detections of DDE in ground-water and surface-water samples collected in the West Salt River Valley and detections of atrazine and deethylatrazine in the ground water in the Upper Santa Cruz Basin. Effects from present agriculture are evident in the seasonal variability in concentrations of pre-emergent pesticides in surface-water samples from the West Salt River Valley. Several detections of DDE and dieldrin in surface water were higher than established water-quality limits. Effects of urban land use are made evident by detections of volatile organic compounds in ground water and surface water from the West Salt River Valley. Detections of volatile organic compounds in surface water from the Santa Cruz River near Nogales, Arizona, also are indications of the effects of urban land use. One detection of tetrachloroethene in ground water was higher than established water-quality limits. Water reuse is an important conservation technique in the Southwest; however, the reuse of water provides a transport mechanism for pesticides and volatile organic compounds to reach areas that are not normally affected by manmade compounds from specific land-use activities. The most complex mixture of pesticides and volatile organic compounds is in the West Salt River Valley and is the result of water-management practices and the combination of land uses in this basin throughout history.

Arizona↗

Implementation and verification of a one-dimensional, unsteady-flow model for Spring Brook near Warrenville, Illinois

A model based on de Sant-Venant equations for dynamic flow in open channels was calibrated and verified for a 0.75-mile urbanized reach of Spring Brook, a tributary to the West Branch Du Page River. The model was used to simulate flow in the reach, which passes through two short culverts, one with overbank flow during periods of high flow. Stage and discharge data were collected at 10 sites with the study reach during three high-flow periods. Simulated stages and discharges were compared graphically to field-collected data. Errors in simulated stage and discharge were small except when debris, not represented in the model, clogged the culvert.

Water Supply Paper↗

HAZUS 99 estimated annualized earthquake losses for the United States

Recent earthquakes around the world show a pattern of steadily increasing damages and losses. The increases are due primarily to two factors: 1) significant growth in urban areas that are prone to earthquakes; and 2) the vulnerability of the older building stock, even buildings that were constructed within the past twenty years. In the United States, earthquake risk has grown substantially with development, while the earthquake hazard has remained relatively constant. To understand the hazard, we study earthquake characteristics and locales in which they occur. To understand risk, we must include characteristics of the built environment in the locales where earthquakes occur, and we must assess potential damages to the built environment and the people who use it. That is a complex undertaking and one this study intends to advance. It is important to estimate the varying degrees of seismic risk throughout the United States because we need that understanding in order to make informed decisions on mitigation policies, priorities, strategies and funding levels—in both the public and private sectors. We can reduce earthquake losses to older buildings by rehabilitating them, and we can reduce earthquake losses in new buildings by applying seismic codes to their design and construction. However, decisions to spend money on either of those solutions require evidence of risk. In the absence of a nationally accepted criterion and methodology for comparing seismic risk across regions, a consensus on optimal mitigation approaches has been difficult to reach. We are all aware of regions with high hazard and high risk, such as Los Angeles, but there is growing recognition that some regions with low seismic hazard actually have high seismic risk, as is the case in New York City and Boston. This risk results, in part, from concentrations of buildings and infrastructure built without use of seismic codes or provisions. Additionally, mitigation policies and practices in the public and private sectors may not have been adopted because a community’s earthquake risk was not clearly demonstrated, and neither was the value of mitigation measures in reducing that risk. The low hazard/high risk problem exists in a number of areas in the U.S., where the infrequency of damaging earthquakes has been interpreted, wrongly, as lack of risk. While earth scientists work to increase knowledge about the hazard throughout the United States, structural engineers and other professionals work to enumerate the many factors that comprise risk. This study is one result of that endeavor. It is based on loss estimates generated by Hazards U.S. (HAZUS), a Geographic Information System (GIS)- based earthquake loss estimation tool, developed by the Federal Emergency Management Agency (FEMA) in cooperation with the National Institute of Building Sciences (NIBS). The HAZUS tool provides an approach to quantifying future earthquake losses that is national in scope, uniform in application, and comprehensive in its coverage of the built environment.

Report↗

Investigating hydrologic alteration as a mechanism of fish assemblage shifts in urbanizing streams

Stream biota in urban and suburban settings are thought to be impaired by altered hydrology; however, it is unknown what aspects of the hydrograph alter fish assemblage structure and which fishes are most vulnerable to hydrologic alterations in small streams. We quantified hydrologic variables and fish assemblages in 30 small streams and their subcatchments (area 8–20 km 2 ) in the Etowah River Catchment (Georgia, USA). We stratified streams and their subcatchments into 3 landcover categories based on imperviousness (<10%, 10–20%, >20% of subcatchment), and then estimated the degree of hydrologic alteration based on synoptic measurements of baseflow yield. We derived hydrologic variables from stage gauges at each study site for 1 y (January 2003–2004). Increased imperviousness was positively correlated with the frequency of storm events and rates of the rising and falling limb of the hydrograph (i.e., storm “flashiness”) during most seasons. Increased duration of low flows associated with imperviousness only occurred during the autumn low-flow period, and this measure corresponded with increased richness of lentic tolerant species. Altered storm flows in summer and autumn were related to decreased richness of endemic, cosmopolitan, and sensitive fish species, and decreased abundance of lentic tolerant species. Species predicted to be sensitive to urbanization, based on specific life-history or habitat requirements, also were related to stormflow variables and % fine bed sediment in riffles. Overall, hydrologic variables explained 22 to 66% of the variation in fish assemblage richness and abundance. Linkages between hydrologic alteration and fish assemblages were potentially complicated by contrasting effects of elevated flows on sediment delivery and scour, and mediating effects of high stream gradient on sediment delivery from elevated flows. However, stormwater management practices promoting natural hydrologic regimes are likely to reduce the impacts of catchment imperviousness on stream fish assemblages.

Journal of the North American Benthological Societ↗

Complex mixtures of dissolved pesticides show potential aquatic toxicity in a synoptic study of Midwestern U.S. streams

Aquatic organisms in streams are exposed to pesticide mixtures that vary in composition over time in response to changes in flow conditions, pesticide inputs to the stream, and pesticide fate and degradation within the stream. To characterize mixtures of dissolved-phase pesticides and degradates in Midwestern streams, a synoptic study was conducted at 100 streams during May–August 2013. In weekly water samples, 94 pesticides and 89 degradates were detected, with a median of 25 compounds detected per sample and 54 detected per site. In a screening-level assessment using aquatic-life benchmarks and the Pesticide Toxicity Index (PTI), potential effects on fish were unlikely in most streams. For invertebrates, potential chronic toxicity was predicted in 53% of streams, punctuated in 12% of streams by acutely toxic exposures. For aquatic plants, acute but likely reversible effects on biomass were predicted in 75% of streams, with potential longer-term effects on plant communities in 9% of streams. Relatively few pesticides in water—atrazine, acetochlor, metolachlor, imidacloprid, fipronil, organophosphate insecticides, and carbendazim—were predicted to be major contributors to potential toxicity. Agricultural streams had the highest potential for effects on plants, especially in May–June, corresponding to high spring-flush herbicide concentrations. Urban streams had higher detection frequencies and concentrations of insecticides and most fungicides than in agricultural streams, and higher potential for invertebrate toxicity, which peaked during July–August. Toxicity-screening predictions for invertebrates were supported by quantile regressions showing significant associations for the Benthic Invertebrate-PTI and imidacloprid concentrations with invertebrate community metrics for MSQA streams, and by mesocosm toxicity testing with imidacloprid showing effects on invertebrate communities at environmentally relevant concentrations. This study documents the most complex pesticide mixtures yet reported in discrete water samples in the U.S. and, using multiple lines of evidence, predicts that pesticides were potentially toxic to nontarget aquatic life in about half of the sampled streams.

Illinois, Iowa, Kansas, Kentucky, Michigan, Minnes↗

Temporal and spatial variability of groundwater recharge on Jeju Island, Korea

Estimates of groundwater recharge spatial and temporal variability are essential inputs to groundwater flow models that are used to test groundwater availability under different management and climate conditions. In this study, a soil water balance analysis was conducted to estimate groundwater recharge on the island of Jeju, Korea, for baseline, drought, and climate-land use change scenarios. The Soil Water Balance (SWB) computer code was used to compute groundwater recharge and other water balance components at a daily time step using a 100 m grid cell size for an 18-year baseline scenario (1992–2009). A 10-year drought scenario was selected from historical precipitation trends (1961–2009), while the climate-land use change scenario was developed using late 21st century climate projections and a change in urban land use. Mean annual recharge under the baseline, drought, and climate-land use scenarios was estimated at 884, 591, and 788 mm, respectively. Under the baseline scenario, mean annual recharge was within the range of previous estimates (825–959 mm) and only slightly lower than the mean of 902 mm. As a fraction of mean annual rainfall, mean annual recharge was computed as only 42% and less than previous estimates of 44–48%. The maximum historical reported annual pumping rate of 241 × 10 6 m 3 equates to 15% of baseline recharge, which is within the range of 14–16% computed from earlier studies. The model does not include a mechanism to account for additional sources of groundwater recharge, such as fog drip, irrigation, and artificial recharge, and may also overestimate evapotranspiration losses. Consequently, the results presented in this study represent a conservative estimate of total recharge.

Jeju↗

Preliminary synthesis and assessment of environmental flows in the middle Verde River watershed, Arizona

A 3-year study was undertaken to evaluate the suitability of the available modeling tools for characterizing environmental flows in the middle Verde River watershed of central Arizona, describe riparian vegetation throughout the watershed, and estimate sediment mobilization in the river. Existing data on fish and macroinvertebrates were analyzed in relation to basin characteristics, flow regimes, and microhabitat, and a pilot study was conducted that sampled fish and macroinvertebrates and the microhabitats in which they were found. The sampling for the pilot study took place at five different locations in the middle Verde River watershed. This report presents the results of this 3-year study. The Northern Arizona Groundwater Flow Model (NARGFM) was found to be capable of predicting long-term changes caused by alteration of regional recharge (such as may result from climate variability) and groundwater pumping in gaining, losing, and dry reaches of the major streams in the middle Verde River watershed. Over the period 1910 to 2006, the model simulated an increase in dry reaches, a small increase in reaches losing discharge to the groundwater aquifer, and a concurrent decrease in reaches gaining discharge from groundwater. Although evaluations of the suitability of using the NARGFM and Basin Characteristic Model to characterize various streamflow intervals showed that smallerscale basin monthly runoff could be estimated adequately at locations of interest, monthly stream-flow estimates were found unsatisfactory for determining environmental flows. Orthoimagery and Moderate Resolution Imaging Spectroradiometer data were used to quantify stream and riparian vegetation properties related to biotic habitat. The relative abundance of riparian vegetation varied along the main channel of the Verde River. As would be expected, more upland plant species and fewer lowland species were found in the upper-middle section compared to the lower-middle section, and vice-versa. Vegetation changes within the upper-middle and lower-middle reaches are related to differences in climate and hydrology. In general, the riparian vegetation of the middle Verde River watershed is that of a healthy ecosystem’s mixed age, mixed patch structure, likely a result of the mostly unaltered disturbance regime. The frequency of in-river hydrogeomorphic features (pool, riffle, run) varied along the middle Verde River channel. There was a greater abundance of riffle habitat in the upper-middle reach; the lower-middle reach included more pool habitat. The Oak Creek tributary was more homogenous in geomorphic stream habitat composition than West Clear Creek, where runs dominated the upper reaches and pools dominated many of the lower reaches. On the basis of the period of record and discharges recorded at 15-minute intervals, five flows were found to reach the gravel-transport threshold. Sediment mobilization computed with flows averaged over daily time steps yielded just three flows that reached the gravel-transport threshold, and monthly averaged flows yielded none. In the middle Verde River watershed, 15-minute data should be used when possible to evaluate sediment transport in the river system. Data from more than 300 fish surveys conducted from 1992 to 2011 were analyzed using two schemes, one that divided the river into five reaches based on basin characteristics, and a second that divided the river into five reaches based on degree of flow alteration (specifically, diversions). Fish community metrics and assemblage data were used to analyze patterns of species composition and abundance in the two approaches. Overall, native and non-native species were regularly interacting and probably competing for similar resources. Fish abundances were also analyzed in response to floods and other flow metrics. Although the data are limited, native fish abundances increased more rapidly than non-native fish abundances in response to large floods. The basin-characteristic reach analysis showed native fish in greater abundance in the upper-middle reaches of the Verde River watershed and generally decreasing with downstream distance. The median relative abundance of native fish decreased by 50 percent from reach 1 to reach 5. Using the reach scheme based on degree of flow alteration, nondiverted reaches were found to have a greater abundance of native fish than diverted reaches. In heavily diverted reaches, non-native species outnumbered native species. Fish metrics and stream-flow metrics for the 30, 90, and 365-day periods before collection were computed and the results analyzed statistically. Only abundance of all fish species was associated with the 30-day flow metrics. The 90-day flow metrics were generally positively associated with fish metrics, whereas the 365-day flow metrics had more negative correlations. In particular, significant relations were found between fish metrics and the magnitude and frequency of high flows, including maximum monthly flow, median annual number of high-flow events, and median annual maximum streamflow. Native sucker (Catostomidae) populations tended to decrease in periods of extended base flow, and fish in the non-native sunfish family (Centrarchidae) decreased in periods of flashy, high magnitude flows. A pilot study surveyed fish at five locations in the upper part of the middle Verde River watershed as a means to measure microhabitat availability and quantify native and non-native fish use of that available microhabitat. Results indicated that native and non-native species exhibit some clear differences in microhabitat use. Although at least some native and non-native fish were found in each velocity, depth, and substrate category, preferential microhabitat use was common. On a percentage basis, non-native species had a strong preference for slow-moving and deeper water with silt and sand substrate, with a secondary preference for faster moving and very shallow water and a coarse gravel substrate. Native species showed a general preference for somewhat faster, moderate depth water over coarse gravel and had no clear secondary preference. Macroinvertebrate-variables index period, high-flow year, and collection location (upper-middle Verde River, lowermiddle Verde River, or Verde River tributaries) were found to be important explanatory variables in differentiating among community metrics. Overall richness (number of unique taxa), Shannon’s diversity index, and the percent of the most dominant taxa were all highly correlated, but their response to each macroinvertebrate variable was different. The percentage of mayfly (order Ephemeroptera) taxa was significantly higher in Oak Creek and the upper-middle and lower-middle Verde River reaches, locations which have higher flows and more urbanization than other reaches. When community metrics were related to hydrologic metrics, caddisfly (order Trichoptera) populations appeared to increase and mayfly populations to decrease in response to less flashy and more stable streamflows. Conversely, caddisfly populations appeared to decrease and mayfly populations to increase in response to greater flow variability. Six locations along the Verde River were sampled for macroinvertebrates as part of a pilot study associated with this report—(1) below Granite Creek, (2) near Campbell Ranch, (3) at the U.S. Geological Survey Paulden gage, (4) at the Perkinsville Bridge, (5) at the USGS Clarkdale gage, and (6) near the Reitz Ranch property. A nonmetric multidimensional scaling ordination of macroinvertebrate assemblages showed that the Verde River below Granite Creek site was different from the five other sites and that the Perkinsville Bridge and near Reitz Ranch samples had similar community structure. The near Campbell Ranch and Paulden gage locations had similar microhabitat characteristics, with the exception of riparian cover, yet the assemblage structure was very different. The different community composition at Verde River below Granite Creek was likely due to it having the smallest substrate sizes, lowest velocities, shallowest depths, and most riparian cover of the six sites.

Arizona↗

Pesticide Toxicity Index: a tool for assessing potential toxicity of pesticide mixtures to freshwater aquatic organisms

Pesticide mixtures are common in streams with agricultural or urban influence in the watershed. The Pesticide Toxicity Index (PTI) is a screening tool to assess potential aquatic toxicity of complex pesticide mixtures by combining measures of pesticide exposure and acute toxicity in an additive toxic-unit model. The PTI is determined separately for fish, cladocerans, and benthic invertebrates. This study expands the number of pesticides and degradates included in previous editions of the PTI from 124 to 492 pesticides and degradates, and includes two types of PTI for use in different applications, depending on study objectives. The Median-PTI was calculated from median toxicity values for individual pesticides, so is robust to outliers and is appropriate for comparing relative potential toxicity among samples, sites, or pesticides. The Sensitive-PTI uses the 5th percentile of available toxicity values, so is a more sensitive screening-level indicator of potential toxicity. PTI predictions of toxicity in environmental samples were tested using data aggregated from published field studies that measured pesticide concentrations and toxicity to Ceriodaphnia dubia in ambient stream water. C. dubia survival was reduced to &le; 50% of controls in 44% of samples with Median-PTI values of 0.1&ndash;1, and to 0% in 96% of samples with Median-PTI values > 1. The PTI is a relative, but quantitative, indicator of potential toxicity that can be used to evaluate relationships between pesticide exposure and biological condition.

Science of the Total Environment↗

Linking MODFLOW with an agent-based land-use model to support decision making

The U.S. Geological Survey numerical groundwater flow model, MODFLOW, was integrated with an agent-based land-use model to yield a simulator for environmental planning studies. Ultimately, this integrated simulator will be used as a means to organize information, illustrate potential system responses, and facilitate communication within a participatory modeling framework. Initial results show the potential system response to different zoning policy scenarios in terms of the spatial patterns of development, which is referred to as urban form, and consequent impacts on groundwater levels. These results illustrate how the integrated simulator is capable of representing the complexity of the system. From a groundwater modeling perspective, the most important aspect of the integration is that the simulator generates stresses on the groundwater system within the simulation in contrast to the traditional approach that requires the user to specify the stresses through time. Copyright ?? 2010 The Author(s). Journal compilation ?? 2010 National Ground Water Association.

Ground Water↗

Habitat fragmentation in coastal southern California disrupts genetic connectivity in the cactus wren ( Campylorhynchus brunneicapillus )

Achieving long-term persistence of species in urbanized landscapes requires characterizing population genetic structure to understand and manage the effects of anthropogenic disturbance on connectivity. Urbanization over the past century in coastal southern California has caused both precipitous loss of coastal sage scrub habitat and declines in populations of the cactus wren ( Campylorhynchus brunneicapillus ). Using 22 microsatellite loci, we found that remnant cactus wren aggregations in coastal southern California comprised 20 populations based on strict exact tests for population differentiation, and 12 genetic clusters with hierarchical Bayesian clustering analyses. Genetic structure patterns largely mirrored underlying habitat availability, with cluster and population boundaries coinciding with fragmentation caused primarily by urbanization. Using a habitat model we developed, we detected stronger associations between habitat-based distances and genetic distances than Euclidean geographic distance. Within populations, we detected a positive association between available local habitat and allelic richness and a negative association with relatedness. Isolation-by-distance patterns varied over the study area, which we attribute to temporal differences in anthropogenic landscape development. We also found that genetic bottleneck signals were associated with wildfire frequency. These results indicate that habitat fragmentation and alterations have reduced genetic connectivity and diversity of cactus wren populations in coastal southern California. Management efforts focused on improving connectivity among remaining populations may help to ensure population persistence.

California↗

Regression models for explaining and predicting concentrations of organochlorine pesticides in fish from streams in the United States

Empirical regression models were developed for estimating concentrations of dieldrin, total chlordane, and total DDT in whole fish from U.S. streams. Models were based on pesticide concentrations measured in whole fish at 648 stream sites nationwide (1992-2001) as part of the U.S. Geological Survey's National Water Quality Assessment Program. Explanatory variables included fish lipid content, estimates (or surrogates) representing historical agricultural and urban sources, watershed characteristics, and geographic location. Models were developed using Tobit regression methods appropriate for data with censoring. Typically, the models explain approximately 50 to 70% of the variability in pesticide concentrations measured in whole fish. The models were used to predict pesticide concentrations in whole fish for streams nationwide using the U.S. Environmental Protection Agency's River Reach File 1 and to estimate the probability that whole-fish concentrations exceed benchmarks for protection of fish-eating wildlife. Predicted concentrations were highest for dieldrin in the Corn Belt, Texas, and scattered urban areas; for total chlordane in the Corn Belt, Texas, the Southeast, and urbanized Northeast; and for total DDT in the Southeast, Texas, California, and urban areas nationwide. The probability of exceeding wildlife benchmarks for dieldrin and chlordane was predicted to be low for most U.S. streams. The probability of exceeding wildlife benchmarks for total DDT is higher but varies depending on the fish taxon and on the benchmark used. Because the models in the present study are based on fish data collected during the 1990s and organochlorine pesticide residues in the environment continue to decline decades after their uses were discontinued, these models may overestimate present-day pesticide concentrations in fish. ?? 2009 SETAC.

Environmental Toxicology and Chemistry↗

Hydrogeology, Chemical Characteristics, and Transport Processes in the Zone of Contribution of a Public-Supply Well in York, Nebraska

In 2001, the U.S. Geological Survey, as part of the National Water Quality Assessment (NAWQA) Program, initiated a topical study of Transport of Anthropogenic and Natural Contaminants (TANC) to PSW (public-supply wells). Local-scale and regional-scale TANC study areas were delineated within selected NAWQA study units for intensive study of processes effecting transport of contaminants to PSWs. This report describes results from a local-scale TANC study area at York, Nebraska, within the High Plains aquifer, including the hydrogeology and geochemistry of a 108-square-kilometer study area that contains the zone of contribution to a PSW selected for study (study PSW), and describes factors controlling the transport of selected anthropogenic and natural contaminants to PSWs. Within the local-scale TANC study area, the High Plains aquifer is approximately 75 m (meter) thick, and includes an unconfined aquifer, an upper confining unit, an upper confined aquifer, and a lower confining unit with lower confined sand lenses (units below the upper confining unit are referred to as confined aquifers) in unconsolidated alluvial and glacial deposits overlain by loess and underlain by Cretaceous shale. From northwest to southeast, land use in the local-scale TANC study area changes from predominantly irrigated agricultural land to residential and commercial land in the small community of York (population approximately 8,100). For the purposes of comparing water chemistry, wells were classified by degree of aquifer confinement (unconfined and confined), depth in the unconfined aquifer (shallow and deep), land use (urban and agricultural), and extent of mixing in wells in the confined aquifer with water from the unconfined aquifer (mixed and unmixed). Oxygen (delta 18O) and hydrogen (delta D) stable isotopic values indicated a clear isotopic contrast between shallow wells in the unconfined aquifer (hereinafter, unconfined shallow wells) and most monitoring wells in the confined aquifers (hereinafter, confined unmixed wells). Delta 18O and delta D values for a minority of wells in the confined aquifers were intermediate between those for the unconfined shallow wells and those for the confined unmixed wells. These intermediate values were consistent with mixing of water from unconfined and confined aquifers (hereinafter, confined mixed wells). Oxidation-reduction conditions were primarily oxic in the unconfined aquifer and variably reducing in the confined aquifers. Trace amounts of volatile organic compounds (VOC), particularly tetrachloroethylene (PCE) and trichloroethylene (TCE), were widely detected in unconfined shallow urban wells and indicated the presence of young urban recharge waters in most confined mixed wells. The presence of degradation products of agricultural pesticides (acetochlor and alachlor) in some confined mixed wells suggests that some fraction of the water in these wells also was the result of recharge in agricultural areas. In the unconfined aquifer, age-tracer data (chlorofluorocarbon and sulfur hexafluoride data, and tritium to helium-3 ratios) fit a piston-flow model, with apparent recharge ages ranging from 7 to 48 years and generally increasing with depth. Age-tracer data for the confined aquifers were consistent with mixing of 'old' water, not containing modern tracers recharged in the last 60 years, and exponentially-mixed 'young' water with modern tracers. Confined unmixed wells contained less than (<) 3 percent (%) young water mixed with a much larger fraction greater than or equal to (>=) 97% of old water. Confined mixed wells contained >30% young water and mean ages ranged from 12 to 14 years. Median concentrations of nitrate (as nitrogen, hereinafter, nitrate-N) were 17.3 and 16.0 mg/L (milligram per liter) in unconfined shallow urban and agricultural wells, respectively, indicating a range of likely nitrate sources. Septic systems are most numerous near the edge of the urban area and appear to be

Scientific Investigations Report↗

Potential for increased inundation in flood-prone regions of southeast Florida in response to climate and sea-level changes in Broward County, Florida, 2060–69

The U.S. Geological Survey, in cooperation with Broward County Environmental Planning and Resilience Division, has developed county-scale and local-scale groundwater/surface-water models to study the potential for increased inundation and flooding in eastern Broward County that are due to changes in future climate and sea-level rise. These models were constructed by using MODFLOW 2005, with the surface-water system represented by using the Surface-Water Routing process and a new Urban Runoff process. The local-scale model allowed the use of finer grid resolution in a selected area of the county, whereas the county-scale model provided boundary conditions for the local-scale model and insight into the hydrologic behavior of the larger system. The aquifer layering, properties, and boundaries relied heavily on a previous three-dimensional variable-density solute-transport model of the same area developed by the U.S. Geological Survey. The surface-water system within these new models actively simulates a part of the extensive canal network by using level-pool routing and active structure operations within the Surface-Water Routing process. These models were used to simulate a historical base-case period (1990–99) by using measured data and regional climate model rainfall and potential evapotranspiration output. The simulated flow and water-level results generally captured the behavior of the hydrologic system. A future period (2060–69) was simulated by using regional climate model rainfall and potential evapotranspiration output representing a wetter and drier future and low, intermediate, and high sea-level rise projections. The results were used to evaluate the potential effects on the surface-water drainage system, coastal-structure operation, and wet-season groundwater levels. Future period simulations using the county-scale model indicate that (1) the effects of the changing climate and sea level are much more evident in eastern and coastal areas of Broward County compared to western areas, with increases in groundwater level nearly equivalent to sea-level rise; (2) coastal groundwater-level increases are distributed farther inland in the wetter future scenarios than in the drier future scenarios; (3) water levels at the westernmost groundwater station locations exhibited little change caused by sea-level rise and showed more dependence on changes in precipitation; (4) there was a reduced west-to-east groundwater gradient with increasing sea-level rise; and (5) increased downstream tidal stage at the S–13 structure resulted in increased reliance on the pump to control upstream inland canal stages. Future simulations using the local-scale model indicate similar behavior as seen in the county-scale model: (1) the coastal areas exhibited the largest impacts in groundwater levels in the future scenarios; (2) the westernmost, interior areas exhibited little change during the future scenarios; and (3) there was an increased reliance on the pump at the S–13 coastal structure but to a lesser extent than indicated in the county-scale model because of the reduced temporal scale of the local-scale model. Possible adaptation and mitigation strategies were simulated to evaluate the county-scale and local-scale models’ ability to simulate hydrologic changes. Alterations to S–13 pump operations within the county-scale model were tested, and results indicate a reduced effect of sea-level rise inland of the control structure, but the affected area is spatially limited. The concept of using pumps to reduce the local groundwater levels in two neighborhood-sized areas was tested by using the local-scale model. The MODFLOW 2005 Drain package was used to remove groundwater by using drainage elevations set to zero, 1 foot, and 2 feet above average wet-season groundwater levels. Area 1 was well connected to coastal boundaries, and a high rate of groundwater removal was required, whereas the rate of groundwater removal required was greatly reduced in Area 2, which is less connected to tidal boundaries. Water for these scenarios was assumed to be pumped to tide with no downstream effects.

Florida↗

Assessment of per- and polyfluoroalkyl substances in water resources of New Mexico, 2020–21

Per- and polyfluoroalkyl substances (PFAS) have been detected in public and private drinking-water wells, springs, and surface waters in New Mexico; however, the presence and distribution of PFAS in water resources across the State are not well characterized. From August 2020 to October 2021, the U.S. Geological Survey, in cooperation with the New Mexico Environment Department, collected water-quality samples from groundwater and surface-water sites throughout New Mexico. One hundred and seventeen groundwater wells were sampled from unconfined water-table aquifers for PFAS and a geochemical suite including major ions, trace elements, nutrients, dissolved organic carbon (DOC), stable isotopes of oxygen and hydrogen, tritium, and carbon-14 to provide context for groundwater age and geochemical evolution. Eighteen surface-water samples were analyzed for PFAS, and select samples were analyzed for wastewater tracers, major ions, trace elements, and DOC. Blanks and replicates indicated low bias and variability for PFAS, wastewater tracers, and geochemical compounds. Twenty-seven of the 117 groundwater sites had PFAS concentrations reported above the detection level, and there were no exceedances of the 2016 U.S. Environmental Protection Agency health advisory of 70 nanograms per liter (ng/L) perfluorooctanoic acid plus perfluorooctane sulfonic acid. Twenty-two sites were resampled and showed similar signatures, excluding some springs. Total PFAS concentrations ranged from 0.91 to 80.3 ng/L. The most frequently detected PFAS at groundwater sites were perfluorobutanesulfonic acid (PFBS; 11 sites), perfluoropentanoic acid (10 sites), and perfluorohexanoic acid (9 sites). Correlations were found between certain PFAS compounds that suggest similar sources. PFAS were also correlated with tritium, DOC, and nitrate, which indicated that a presence of anthropogenic compounds could in turn indicate a likelihood of PFAS occurrence. In addition, a cluster analysis showed that varying geochemical processes and sources of anthropogenic compounds likely contribute to the PFAS signature of each groundwater sample. Surface-water samples showed variable total PFAS concentrations ranging from 1.0 to 155.4 ng/L. Sites downstream from urban areas showed numerous PFAS detections. Some undeveloped areas where minimal PFAS detections would be expected had PFAS detections. Correlations between PFAS were found that suggested similar sources. Perfluoropentanoic acid and PFBS were the most frequently detected PFAS, and PFBS had the highest single concentration of 93 ng/L. Results of the study provide an overview of PFAS occurrences in the water resources of New Mexico along with geochemical context and are used to identify areas for further scientific investigations that could further characterize PFAS occurrences in New Mexico.

New Mexico↗

Amphibian occurrence and aquatic invaders in a changing landscape: Implications for wetland mitigation in the Willamette Valley, Oregon

Despite concern about the conservation status of amphibians in western North America, few field studies have documented occurrence patterns of amphibians relative to potential stressors. We surveyed wetland fauna in Oregon's Willamette Valley and used an information theoretic approach (AIC) to rank the associations between native amphibian breeding occurrence and wetland characteristics, non-native aquatic predators, and landscape characteristics in a mixed urban-agricultural landscape. Best predictors varied among the five native amphibians and were generally consistent with life history differences. Pacific tree frog (Pseudacris regilla) and long-toed salamander (Ambystoma macrodactylum) occurrence was best predicted by the absence of non-native fish. Northern red-legged frog (Rana a. aurora) and northwestern salamander (Ambystoma gracile) were most strongly related to wetland vegetative characteristics. The occurrence of rough-skinned newts (Taricha granulosa), a migratory species that makes extensive use of terrestrial habitats, was best predicted by greater forest cover within 1 km. The absence of non-native fish was a strong predictor of occurrence for four of the five native species. In contrast, amphibians were not strongly related to native fish presence. We found little evidence supporting negative effects of the presence of breeding populations of bullfrog (Rana catesbeiana) on any native species. Only the two Ambystoma salamanders were associated with wetland permanence. Northwestern salamanders (which usually have a multi-year larval stage) were associated with permanent waters, while long-toed salamanders were associated with temporary wetlands. Although all the species make some use of upland habitats, only one (rough-skinned newt) was strongly associated with surrounding landscape conditions. Instead, our analysis suggests that within-wetland characteristics best predict amphibian occurrence in this region. We recommend that wetland preservation and mitigation efforts concentrate on sites lacking non-native fish for the conservation of native amphibians in the Willamette Valley and other western lowlands.

Wetlands↗