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USGS1954

Airborne radioactivity survey of parts of Sand Creek SW and Sand Creek SE quadrangles, Sweetwater county, Wyoming

The accompanying map shows the results of an airborne radioactivity survey in 125 square miles of Sand Creek SW and Sand Creek SE quadrangles, Wyoming. This area is part of a larger survey made in southern Carbon and Sweetwater counties by the U.S. Geological Survey, November 9-24, 1953. The work was undertaken as part of a cooperative program with the U.S. Atomic Energy Commission. The survey was made with scintillation detection equipment mounted in a C-47 aircraft and consisted of parallel east-west flight lines spaced at quarter mile intervals, flown approximately 500 feet above the ground. Aerial photographs were used for pilot guidance, and the flight path of the aircraft was recorded by a gyrostabilized, continuous-strip-film camera. The distance of the aircraft from the ground was measured with a continuously recording radio altimeter. The width of the zone on the ground form which the anomalous radiation is measured at the nominal 500 foot flight altitude varied with the areal extent and the intensity of radioactivity of the source. For strong sources of radioactivity the width of the zone may be as much as 1,400 feet. Thus, quarter mile spacing of the flight lines would be adequate to detect anomalies from strong sources of radioactivity; however, small areas of considerable radioactivity midway between flight lines may not be noted. The approximate locations of nine radioactivity anomalies are shown on the accompanying map. The plotted position of the anomalies may be in error by as much as a quarter mile owing to the errors in available base maps or to the existence of areas on the base maps up to several square miles in which it is impossible to find and plot recognizable landmarks. The present technique of airborne radioactivity measurement does not permit distinguishing between activity due to thorium and that due to uranium. An anomaly, therefore, may represent radioactivity due entirely to one or to a combination of these elements. The radioactivity anomalies shown on the accompanying map cannot be interpreted in terms of either radioactive content or the extent of the source materials. Any particular anomaly may represent slightly greater-than-average radioactivity over an area of a few thousand square feet or high radioactivity over an area of a few hundred square feet. Thus radioactivity anomalies indicate localities of more-than-average radioactivity and, therefore, suggest areas in which uranium or thorium deposits are more likely to occur.

Wyoming↗

USGS2001

Water-quality characteristics in the Black Hills area, South Dakota

This report summarizes the water-quality characteristics of ground-water and surface-water in the Black Hills area. Differences in groundwater quality by aquifer and differences in surfacewater quality by water source are presented. Ground-water characteristics are discussed individually for each of the major aquifers in the Black Hills area, referred to herein as the Precambrian, Deadwood, Madison, Minnelusa, Minnekahta, and Inyan Kara aquifers. Characteristics for minor aquifers also are discussed briefly. Surface-water characteristics are discussed for hydrogeologic settings including headwater springs, crystalline core sites, artesian springs, and exterior sites. To characterize the water quality of aquifers and streams in the Black Hills area, data from the U.S. Geological Survey National Water Information System water-quality database were examined. This included samples collected as part of the Black Hills Hydrology Study as well as for other studies within the time frame of October 1, 1930, to September 30, 1998. Tables of individual results are not presented in this report, only summaries. Constituents summarized and discussed include physical properties, common ions, nutrients, trace elements, and radionuclides. Comparisons of concentration levels are made to drinking-water standards as well as beneficial-use and aquatic-life criteria. Ground water within the Black Hills and surrounding area generally is fresh and hard to very hard. Concentrations exceeding various Secondary and Maximum Contaminant Levels may affect the use of the water in some areas for many aquifers within the study area. Concentrations that exceed Secondary Maximum Contaminant Levels (SMCL's) generally affect the water only aesthetically. Radionuclide concentrations may be especially high in some of the major aquifers used within the study area and preclude the use of water in some areas. The sodiumadsorption ratio and specific conductance may affect irrigation use for some wells. High concentrations of iron and manganese are the only concentrations that may hamper the use of water from Precambrian aquifers. The principal deterrents to use of water from the Deadwood aquifer are the high concentrations of radionuclides as well as iron and manganese. Iron, manganese, and hardness may deter use of water from the Madison aquifer as well as dissolved solids and sulfate in downgradient wells (generally deeper than 2,000 feet). Iron, manganese, and hardness may also deter use of the Minnelusa aquifer. Water from the Minnekahta aquifer generally is suitable for all water uses although it is hard to very hard. High concentrations of dissolved solids, iron, sulfate, and manganese may hamper the use of water from the Inyan Kara aquifer. In the southern Black Hills, radium-226 and uranium concentrations also may preclude use of water from the Inyan Kara aquifer. Suitability for irrigation may be affected by high specific conductance and sodium-adsorption ratio for the Inyan Kara. Surface-water quality within the Black Hills and surrounding area generally is very good but the water is hard to very hard. Concentrations of some constituents in the study area tend to be higher exterior to the Black Hills, primarily due to influences from the Cretaceous-age marine shales, including dissolved solids, sodium, sulfate, selenium, and uranium. Headwater springs have relatively constant discharge, specific conductance, dissolved solids, and concentrations of most other constituents. Concentrations at crystalline core sites are very similar to those found in samples from Precambrian aquifers. Some high nitrate concentrations greater than the Maximum Contaminant Level (MCL) of 10 mg/L (milligrams per liter) have occurred at Annie Creek near Lead, which have been attributed to mining impacts. Trace elements generally are low with the exception of arsenic, for which 60 percent of samples exceed the proposed MCL of 10 ug/L (micrograms per liter) and one sample

Water-Resources Investigations Report↗

USGS1987

Ground-water flow and quality near Canon City, Colorado

Water in aquifers that underlie the Lincoln Park area near Canon City, Colorado, contains measurable concentrations of chemical constituents that are similar to those in raffinate (liquid waste) produced by a nearby uranium ore processing mill. The objective of this study was to expand the existing geohydrologic data base by collecting additional geohydrologic and water quality, in order to refine the description of the geohydrologic and geochemical systems in the study area. Geohydrologic data were collected from nine tests wells drilled in the area between the U.S. Soil Conservation Service dam and Lincoln Park. Lithologic and geophysical logs of these wells indicated that the section of Vermejo Formation penetrated consisted of interbedded sandstone and shale. The sandstone beds had a small porosity and small hydraulic conductivity. Groundwater flow from the U.S. Soil Conservation Service dam to Lincoln Park seemed to be along an alluvium-filled channel in the irregular and relatively undescribed topography of the Vermejo Formation subcrop. North of the De Weese Dye Ditch, the alluvium becomes saturated and groundwater generally flows to the northeast. Water samples from 28 sites were collected and analyzed for major ions and trace elements; selected water samples also were analyzed for stable isotopes; samples were collected from wells near the uranium ore processing mill, from privately owned wells in Lincoln Park, and from the test wells drilled in the intervening area. Results from the quality assurance samples indicate that cross-contamination between samples from different wells was avoided and that the data are reliable. Water in the alluvial aquifer underlying Lincoln Park is mainly a calcium bicarbonate type. Small variations in the composition of water in the alluvial aquifer appears to result from a reaction of water leaking from the De Weese Dye Ditch with alluvial material. Upward leakage from underlying aquifers does not seem to be significant in determining the chemical composition of water in the alluvial aquifer. (Author 's abstract)

Water-Resources Investigations Report↗

USGS1988

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in Bowdoin National Wildlife Refuge and adjacent areas of the Milk River basin, northeastern Montana, 1986-87

Concentrations of trace elements, radiochemicals, and pesticides in the Bowdoin National Wildlife Refuge lakes generally were not substantially larger than those in the water supplied from Dodson South Canal or in irrigation drainage. Concentrations of arsenic (47 micrograms/L), uranium (43 microg/L), and vanadium (51 microg/L) in Dry Lake Unit, and boron (1,000 microg/L) in Lake Bowdoin were notably larger than at other sites. Zinc concentrations in an irrigation drain (56 microg/L) and two shallow domestic wells (40 and 47 microg/L) were elevated relative to other sites. Concentrations of gross alpha radiation (64 picocuries/L) and gross beta radiation (71 picocuries/L) were elevated in Dry Lake Unit. Pesticides concentrations at all sites were 0.08 microg/L or less. Water use guidelines concentrations for boron, cadmium, uranium, zinc, and gross alpha radiation were slightly exceeded at several sites. In general, trace-constituent concentrations measured in the water do not indicate any potential toxicity problems in Bowdoin National Wildlife Refuge; however, highwater conditions in 1986 probably caused dilution of dissolved constituents compared to recent dry years. Trace element concentrations in bottom sediments of the refuge lakes were generally similar to background concentrations in the soils. The only exception was Dry Lake Unit, which had concentrations of chromium (99 micrograms/g), copper (37 microg/g), nickel (37 microg/g), vanadium (160 microg/g), and zinc (120 microg/g) that were about double the mean background concentrations. The maximum selenium concentration in bottom sediment was 0.6 microg/g. Pesticide concentrations in bottom sediments were less than analytical detection limits at all sites. With few exceptions, concentrations of trace elements and pesticides in biota generally were less than values known to produce harmful effects on growth or reproduction.

Montana↗

USGS1995

Radium and radon in ground water in the Chickies Quartzite, southeastern Pennsylvania

The Chickies Quartzite, a Lower Cambrian-age formation compromised of quartzite and slate overlying a basal conglomerate, forms a narrow ridges and crops out discontinuously over 112 square miles in the Piedmont physiographic province of southeastern Pennsylvania. The formation is a low-yielding, fractured- rock, water-table aquifer recharged primarily by local precipitation. It is the sole source of water supply for thousands of domestic users. Ground water in the Chickies Quartzite generally is soft and acidic. During 1986-88, the U.S. Geological Survey sampled water from 160 wells that penetrate the Chickies Quartzite to determine the magnitude and distribution of radium-226 (Ra-226), radium-228 (Ra-228), and radon-222 (Rn-222) activities in ground water in the formation and to characterize the geochemical environmental associated with elevated activities of radium (Ra). In addition, 28 wells penetrating adjacent geologic units and 1 well in the Hardyston Quartzite were sampled to determine relative background Ra and RN-222 activities in ground water. Analyses included determination of activities of dissolved Ra-226, Ra-228, and RN-222, and concentrations of dissolved uranium (U), dissolved organic carbon (DOC), and major and minor dissolved inorganic ions. Rock samples were analyzed for U and thorium (Th) and geophysical logs were run to determine sources of Ra and RN-222 in the Chickies Quartzite. Activities of up to 41 pCi/L (picocuries per liter) for Ra-226, 160 pCi/L for Ra-228, and 32,300 pCi/L for RN-222 were measured in ground water in the Chickies Quartzite. Forty-seven percent of the samples contained Ra-226 and Ra-228 activities greater than 5 pCi/L. Median activities measured were 1.2 pCi/L for Ra-226, 2.6 pCi/L for Ra-228, 4.2 pCi/L for combined Ra-226 and Ra-228, and 2,400 pCi/L for RN-222 Ra-228 activity exceeded Ra-226 activity in about 92 percent of 100 water samples; the median Ra-228/Ra226 activity ratio was 2.4. Ra-228/Ra-226 activity ratios commonly were greater in ground water than calculated Th/U ratios in rock samples, suggesting perferential leaching of Ra-228 from aquifer solids. Of ground water in the adjacent geologic units, the highest activities (up to 2.9 pCi/L for Ra-226, 12 pCi/L for Ra-228, and 25,300 pCi/L for RN-222) were measured in ground water in the Harpers Phyllite and Antietam Quartzite. Nonparametric (Spearman rho test) statistical correlations show that the activity of dissolved Ra is inversely related to pH and directly related to concentrations of total dissolved solids, DOC, barium, and sulfate. Low pH decreases absorption of Ra onto the aquifer matrix. The other factors may favor Ra mobility by enhancing complexation or increasing solubility. RN-222 activity does not correlate with and is not supported by the activity of its parent, Ra-226, in solution. Ra-226 activity correlates positively, but weakly, with U concentrations. Ra-226 does not appear to be supported by its parent, U-238, in solution. Observed distributions of Ra-228, Ra-226, and RN-222 activities in ground water in different lithologies of the Chickies Quartzite reflect different geochemical controls on absorption and distribution of parent thorium-232 (Th-232) and uranium-238 (U-238) in the formation. Radium activities were greatest in acidic ground water in the conglomerate and quartzite (median pH of 5.0 and 5.2, respectively) and least in the more neutral water in the slate (median pH of 6.4). For ground water in the conglomerate, quartzite, and slate, respectively, median activities measured were 1.3, 1.5, and .02 pCi/L for Ra-226; and 3.7, 2.5, and 1.0 pCi/L for Ra-228. Natural-gamma-ray geophysical logs and results of rock analyses indicate that the conglomerate may contain more Th and U than the quartzite and that the conglomerate may be more enriched in Th with respect to U than the quartzite; Th and U distribution in both lithogies is variable. Median RN-222 activities in gro

Water-Resources Investigations Report↗

USGS1994

Radioactivity in the environment; a case study of the Puerco and Little Colorado River basins, Arizona and New Mexico

This report, written for the nontechnical reader, summarizes the results of a study from 1988-91 of the occurrence and transport of selected radionuclides and other chemical constituents in the Puerco and Little Colorado River basins, Arizona and New Mexico. More than two decades of uranium mining and the 1979 failure of an earthen dam containing mine tailings released high levels of radionuclides and other chemical constituents to the Puerco River, a tributary of the Little Colorado River. Releases caused public concern that ground water and streamflow downstream from mining were contaminated. Study findings show which radioactive elements are present, how these elements are distributed between water and sediment in the environment, how concentrations of radioactive elements vary naturally within basins, and how levels of radioactivity have changed since the end of mining. Although levels of radioactive elements and other trace elements measured in streamflow commonly exceed drinking-water standards, no evidence was found to indicate that the high concentrations were still related to uraniurn mining. Sediment radioactivity was higher at sample sites on streams that drain the eastern part of the Little Colorado River basin than that of samples from the western part. Radioactivity of suspended sediment measured in this study, therefore, represents natural conditions for the streams sampled rather than an effect of mining. Because ground water beneath the Puerco River channel is shallow, the aquifer is vulnerable to contamination. A narrow zone of ground water beneath the Puerco River containing elevated uranium concentrations was identified during the study. The highest concentrations were nearest the mines and in samples collected in the first few feet beneath the streambed. Natuxal radiation levels in a few areas of the underlying sedimentary aquifer not connected to the Puerco River also exceeded water quality standards. Water testing would enable those residents not using public water supplies to determine if their water is safe to use.

Water-Resources Investigations Report↗

USGS1996

Summary of the San Juan structural basin regional aquifer-system analysis, New Mexico, Colorado, Arizona, and Utah

Ground-water resources are the only source of water in most of the San Juan structural basin and are mainly used for municipal, industrial, domestic, and stock purposes. Industrial use increased dramatically during the late 1970's and early 1980's because of increased exploration and development of uranium and coal resources. The San Juan structural basin is a northwest-trending, asymmetric structural depression at the eastern edge of the Colorado Plateau. The basin contains as much as 14,000 feet of sedimentary rocks overlying a Precambrian basement complex. The sedimentary rocks dip basinward from the basin margins toward the troughlike structural center, or deepest part of the basin. Rocks of Triassic age were selected as the lower boundary for the study. The basin is well defined by structural boundaries in many places with structural relief of as much as 20,000 feet reported. Faulting is prevalent in parts of the basin with displacement of several thousand feet along major faults. The regional aquifers in the basin generally are coincident with the geologic units that have been mapped. Data on the hydrologic properties of the regional aquifers are minimal. Most data were collected on those aquifers associated with uranium and coal resource production. These data are summarized in table format in the report. The regional flow system throughout most of the basin has been affected by the production of oil or gas and subsequent disposal of produced brine. To date more than 26,000 oil- or gas- test holes have been drilled in the basin, the majority penetrating no deeper than the bottom of the Cretaceous rocks. The general water chemistry of the regional aquifers is based on available data. The depositional environments are the major factor controlling the quality of water in the units. The dominant ions are generally sodium, bicarbonate, and sulfate. A detailed geochemical study of three sandstone aquifers--Morrison, Dakota, and Gallup--was undertaken in the northwestern part of the study area. Results of this study indicate that water chemistry changed in individual wells over short periods of time, not expected in a regional flow system. The chemistry of the water is affected by mixing of recharge, ion filtrate, or very dilute ancient water, and by leakage of saline water. The entire system of ground-water flow and its controlling factors has been defined as the conceptual model. A steady-state, three-dimensional ground-water flow model was constructed to simulate modern predevelopment flow in the post-Jurassic rocks of the regional flow system. In the ground-water flow model, 14 geologic units or combinations of geologic units were considered to be regional aquifers, and 5 geologic units or combinations of geologic units were considered to be regional confining units. The model simulated flow in 12 layers (hydrostratigraphic units) and used harmonic-mean vertical leakance to indirectly simulate aquifer connection across 3 other hydrostratigraphic confining units in addition to coupling the 12 units.

Water-Resources Investigations Report↗

USGS1996

Water-quality assessment of the Rio Grande Valley, Colorado, New Mexico, and Texas: Shallow ground-water quality of a land-use area in the San Luis Valley, south-central Colorado, 1993

This report describes the quality of shallow ground water in an agricultural area in the San Luis Valley, Colorado, and discusses how natural and human factors affect the quality of shallow ground water. Thirty-five wells were installed, and water samples were collected from these wells and analyzed for selected dissolved common constituents, nutrients, trace elements, radionuclides, and synthetic organic compounds. The San Luis Valley is a high intermontane valley that is partially drained by the Rio Grande. The San Luis Valley land-use study area was limited to a part of the valley where the depth to water is generally less than 25 feet. The area where the 35 monitor wells were installed was further limited to the part of the study area where center-pivot overhead sprinklers are used to irrigate crops. Precipitation, runoff from adjacent mountainous areas, and ground-water inflow from the adjacent mountainous areas are the main sources of water to the aquifers in the San Luis Valley. Discharge of water from the shallow, unconfined aquifer in the valley is mainly from evapotranspiration. The dominant land use in the San Luis Valley is agriculture, although nonirrigated land and residential land are interspersed with agricultural land. Alfalfa, native hay, barley, wheat, potatoes, and other vegetables are the main crops. Dissolved-solids concentrations in shallow ground water sampled ranged from 75 to 1,960 milligrams per liter. The largest median concentration of cations was for calcium, and the largest median concentration of anions was for bicarbonate in shallow ground water in the San Luis Valley. Calcium concentrations ranged from 7.5 to 300 milligrams per liter, and bicarbonate concentrations ranged from 28 to 451 milligrams per liter. Nitrite plus nitrate concentrations ranged from less than 0.1 to 58 milligrams per liter as N; water from 11 wells had nitrite plus nitrate concentrations greater than 10 milligrams per liter as N. With the exception of the following trace elements--aluminum, barium, iron, manganese, molybdenum, and uranium--the concentrations of trace elements were less than 10 micrograms per liter in 90 percent of the samples. All trace-element concentrations measured were below the maximum contaminant levels set by the U.S. Environmental Protection Agency. Five samples exceeded the proposed maximum contaminant level of 0.02 milligram per liter for uranium. All samples collected exceeded the proposed maximum contaminant level for radon-222. The volatile organic compound methyltertbutylether was detected in one sample at a concentration of 0.6 microgram per liter. Of the pesticides analyzed for, one or more were detected in water from 5 of the 35 wells sampled. Metribuzin was the most commonly detected pesticide and was detected in water from three wells at concentrations ranging from an estimated 0.005 to 0.017 microgram per liter. Metolachlor (detected in one sample at a concentration of 0.072 microgram per liter), prometon (detected in one sample at a concentration of 0.01 microgram per liter), and p,p'-DDE (detected in one sample at an estimated concentration of 0.002 microgram per liter) were the other pesticides detected. The U.S. Environmental Protection Agency lifetime health advisory for metolachlor, metribuzin, and prometon is 100 micrograms per liter, which is much larger than the concentrations measured in the shallow ground water sampled for this study. The elevated nitrite plus nitrate concentrations in shallow ground water are indicative of leaching of fertilizers from the land surface. This conclusion is consistent with conclusions made in other investigations of the San Luis Valley.

Colorado↗

USGS2022

MIS 5e sea-level history along the Pacific coast of North America

The primary last interglacial, marine isotope substage (MIS) 5e records on the Pacific coast of North America, from Washington (USA) to Baja California Sur (Mexico), are found in the deposits of erosional marine terraces. Warmer coasts along the southern Golfo de California host both erosional marine terraces and constructional coral reef terraces. Because the northern part of the region is tectonically active, MIS 5e terrace elevations vary considerably, from a few meters above sea level to as much as 70 m above sea level. The primary paleo-sea-level indicator is the shoreline angle, the junction of the wave-cut platform with the former sea cliff, which forms very close to mean sea level. Most areas on the Pacific coast of North America have experienced uplift since MIS 5e time, but the rate of uplift varies substantially as a function of tectonic setting. Chronology in most places is based on uranium-series ages of the solitary coral Balanophyllia elegans (erosional terraces) or the colonial corals Porites and Pocillopora (constructional reefs). In areas lacking corals, correlation to MIS 5e often can be accomplished using amino acid ratios of fossil mollusks, compared to similar ratios in mollusks that also host dated corals. Uranium-series (U-series) analyses of corals that have experienced largely closed-system histories range from ∼124 to ∼118 ka, in good agreement with ages from MIS 5e reef terraces elsewhere in the world. There is no geomorphic, stratigraphic, or geochronological evidence for more than one high-sea stand during MIS 5e on the Pacific coast of North America. However, in areas of low uplift rate, the outer parts of MIS 5e terraces apparently were re-occupied by the high-sea stand at ∼100 ka (MIS 5c), evident from mixes of coral ages and mixes of molluscan faunas with differing thermal aspects. This sequence of events took place because glacial isostatic adjustment processes acting on North America resulted in regional high-sea stands at ∼100 and ∼80 ka that were higher than is the case in far-field regions, distant from large continental ice sheets. During MIS 5e time, sea surface temperatures (SSTs) off the Pacific coast of North America were higher than is the case at present, evident from extralimital southern species of mollusks found in dated deposits. Apparently, no wholesale shifts in faunal provinces took place, but in MIS 5e time, some species of bivalves and gastropods lived hundreds of kilometers north of their present northern limits, in good agreement with SST estimates derived from foraminiferal records and alkenone-based reconstructions in deep-sea cores. Because many areas of the Pacific coast of North America have been active tectonically for much or all of the Quaternary, many earlier interglacial periods are recorded as uplifted, higher-elevation terraces. In addition, from southern Oregon to northern Baja California, there are U-series-dated corals from marine terraces that formed at ∼80 ka, during MIS 5a. In contrast to MIS 5e, these terrace deposits host molluscan faunas that contain extralimital northern species, indicating cooler SST at the end of MIS 5. Here I present a review and standardized database of MIS 5e sea-level indicators along the Pacific coast of North America and the corresponding dated samples. The database is available in Muhs et al. (2021b; https://doi.org/10.5281/zenodo.5903285 ).

Earth System Science Data↗

USGS1993

234U/238U as a ground-water tracer, SW Nevada-SE California

The 234U/238U ratio of uranium in oxidizing ground waters is potentially an excellent ground-water tracer because of its high solubility and insensitivity to chemical reactions. Moreover, recent advances in analytical capability have made possible very precise uranium-isotopic analyses on modest (approx.100 ml) amounts of normal ground water. Preliminary results on waters from SW Nevada/Se California indicate two main mixing trends, but in detail indicate significant complexity requiring three or more main components.

California, Nevada↗

USGS1992

Monitoring radionuclide and suspended-sediment transport in the Little Colorado River basin, Arizona and New Mexico, USA

From July 1988 through September 1991, radionuclide and suspended-sediment transport were monitored in ephemeral streams in the semiarid Little Colorado River basin of Arizona and New Mexico, USA, where in-stream gross-alpha plus gross-beta activities have exceeded Arizona's Maximum Allowable Limit through releases from natural weathering processes and from uranium-mining operations in the Church Rock Mining District, Grants Mineral Belt, New Mexico. Water samples were collected at a network of nine continuous-record streamgauges equipped with microprocessor-based satellite telemetry and automatic water-sampling systems, and six partial-record streamgauges equipped with passive water samplers. Analytical results from these samples were used to calculate transport of selected suspended and dissolved radionuclides in the uranium-238 and thorium-232 decay series.

Arizona;New Mexico↗

USGS2019

Multivariate analysis of hydrochemical data for Jewel Cave, Wind Cave, and surrounding areas

Jewel Cave National Monument and Wind Cave National Park in South Dakota contain two of the six longest caves worldwide. These caves contain subterranean lakes that are important points of intersection between the water table of the Madison aquifer and the caves. During 2015 to 2017, several subterranean lakes were discovered in Jewel Cave, which previously was thought to be above the regional water table. The objectives of this study were to better understand the hydrology of the recently discovered lakes in Jewel Cave and to evaluate their relation or possible connection to similar subterranean lakes in Wind Cave. Both objectives align with National Park Service resource management purposes. Multivariate analysis, consisting of principal component analysis (PCA), cluster analysis, and end member mixing, was applied to hydrochemical data for 70 sites within and surrounding Jewel Cave and Wind Cave. Hydrochemical data consisted of the contents of major ions (Ca, Mg, Na, HCO3, Cl, Si, SO4), arsenic (As), strontium (Sr), uranium (U), stable isotopes of oxygen and hydrogen (δ18O, δ2H), radiogenic isotope ratios of strontium and uranium (87Sr/86Sr and 234U/238U), pH, and electrical conductivity (EC) in water samples. Five hydrogeologic domains were identified on the basis of PCA and cluster analysis for the area encompassing Jewel Cave and Wind Cave in the southern Black Hills. The Artesian 1 and Artesian 2 domains represent primarily artesian springs and surrounding groundwater, the East and West domains represent areas where Madison and Minnelusa aquifer rocks are at or near the land surface, and the Precambrian domain represents the Precambrian aquifer. Multivariate analysis indicates that the Jewel Cave area is part of the West domain and that Wind Cave is part of the East domain. End member mixing was applied to estimate that groundwater in the Jewel Cave area primarily was derived from the West domain and secondarily from the Precambrian domain. Jewel Cave and Wind Cave contain lakes that are well connected to regional groundwater flow in the Madison aquifer.

South Dakota↗

USGS2022

Basis for technical guidance to evaluate evapotranspiration covers

This report provides technical guidance to evaluate evapotranspiration (ET) cover design criteria with emphasis on applications to long-term disposal sites such as Uranium Mill Tailings Radiation Control Act of 1978 (UMTRCA) sites. Water balance covers, also known as ET covers, reduce percolation by storing precipitation then allowing vegetation to cycle it back to the atmosphere. For long-term (over 200 years) waste isolation, ET covers may provide significant benefits over conventional, resistive covers that rely on engineered components, such as compacted clay barriers and geomembranes, to divert precipitation. UMTRCA covers were designed to impede and attenuate radioactive radon-222 gas flux from the underlying tailings, while minimizing percolation of any contaminants to groundwater. Such covers have implicit regulatory compliance post-construction. Alternative cover systems, such as ET covers, must explicitly meet some anticipated performance, and demonstrate beneficial use. While all engineered structures will change over time, an ET cover evolves with nature rather than resisting it, which may perpetuate a more reliable waste isolation system. For example, UMTRCA sites must provide safe and environmentally sound disposal, long-term stabilization, and control of uranium mill tailings and remain effective for up to 1,000 years, to the extent reasonably achievable, and, in any case, for at least 200 years. UMTRCA covers rely on the engineered properties to meet regulatory requirements during and immediately after construction. Subsequent compliance is implicit in the design. The design of an ET cover is far more dependent on mesoscale meteorology, native vegetation, and edaphic soil properties which are site-specific. Therefore, the design and anticipated performance of an ET cover must be demonstrated through a combination of modeling, natural analogues and pilot studies, and then verified with monitoring data. There is no single ET cover design that can likely meet performance standards across different climates, available soils, and vegetation. The technical information presented in this report reviews guidelines and performance criteria commonly used for ET covers at municipal waste facilities and the consideration factors of such covers to meet the regulatory requirements at long-term disposal sites.

Report↗

USGS2025

Airborne radiometric data map alteration of porphyry copper systems in the Elkhorn district, MT

The Elkhorn district in southwestern Montana is known for past production of high-grade base and precious metals from skarn and carbonate replacement deposits. The district also hosts a porphyry Cu-Mo deposit. A radiometric survey flown over the district and surrounds provides maps of surficial concentrations of potassium, thorium, and uranium. Handheld gamma ray spectrometer measurements on altered and unaltered rocks in the district and surrounding region provide a means to ground truth the airborne data. We demonstrate that the airborne and ground-based measurements show similar map patterns. We calculate ratios of the radioelement concentrations and present a potassium enhancement map that combines potassium and ratios of potassium to thorium and uranium. The results highlight the rocks previously mapped as having K-feldspar-biotite and quartz-sericite alteration assemblages in the Elkhorn district and map additional hydrothermal systems in the region, including known alteration in the Radersburg district. The data enhancement techniques can be used as a screening tool for mapping additional porphyry copper systems.

Montana↗

USGS2000

Chronic toxicity and hazard assessment of an inorganic mixture simulating irrigation drainwater to razorback sucker and bonytail

We conducted two 90 day chronic toxicity studies with two endangered fish, razorback sucker and bonytail. Swim-up larvae were exposed in a reconstituted water simulating the middle Green River. The toxicant mixture simulated the environmental ratio and concentrations of inorganics reported in a Department of the Interior study for the mouth of Ashley Creek on the Green River, and was composed of nine elements. The mixture was tested at 1X, 2X, 4X, 8X, and 16X where X was the measured environmental concentration (2 μg/L arsenic, 630 μg/L boron, 10 μg/L copper, 5 μg/L molybdenum, 51 μg/L selenate, 8 μg/L selenite, 33 μg/L uranium, 2 μg/L vanadium, and 20 μg/L zinc). Razorback sucker had reduced survival after 60 days exposure to the inorganic mixture at 8X, whereas growth was reduced after 30 and 60 days at 2X and after 90 days at 4X. Bonytail had reduced survival after 30 days exposure at 16X, whereas growth was reduced after 30, 60, and 90 days at 8X. Swimming performance of razorback sucker and bonytail were reduced after 60 and 90 days of exposure at 8X. Whole-body residues of copper, selenium, and zinc increased in a concentration-response manner and seemed to be regulated at 90 days of exposure at 4X and lower treatments for razorback sucker, and at 8X and lower for bonytail. Adverse effects occurred in fish with whole-body residues of copper, selenium, and zinc similar to those causing similar effects in other fish species. Comparison of adverse effect concentrations with measured environmental concentrations showed a high hazard to the two endangered fish. Irrigation activities may be a contributing factor to the decline of these endangered fishes in the middle Green River.

Environmental Toxicology↗

USGS2014

Assessment of parametric uncertainty for groundwater reactive transport modeling,

The validity of using Gaussian assumptions for model residuals in uncertainty quantification of a groundwater reactive transport model was evaluated in this study. Least squares regression methods explicitly assume Gaussian residuals, and the assumption leads to Gaussian likelihood functions, model parameters, and model predictions. While the Bayesian methods do not explicitly require the Gaussian assumption, Gaussian residuals are widely used. This paper shows that the residuals of the reactive transport model are non-Gaussian, heteroscedastic, and correlated in time; characterizing them requires using a generalized likelihood function such as the formal generalized likelihood function developed by Schoups and Vrugt (2010). For the surface complexation model considered in this study for simulating uranium reactive transport in groundwater, parametric uncertainty is quantified using the least squares regression methods and Bayesian methods with both Gaussian and formal generalized likelihood functions. While the least squares methods and Bayesian methods with Gaussian likelihood function produce similar Gaussian parameter distributions, the parameter distributions of Bayesian uncertainty quantification using the formal generalized likelihood function are non-Gaussian. In addition, predictive performance of formal generalized likelihood function is superior to that of least squares regression and Bayesian methods with Gaussian likelihood function. The Bayesian uncertainty quantification is conducted using the differential evolution adaptive metropolis (DREAM (zs) ) algorithm; as a Markov chain Monte Carlo (MCMC) method, it is a robust tool for quantifying uncertainty in groundwater reactive transport models. For the surface complexation model, the regression-based local sensitivity analysis and Morris- and DREAM (ZS) -based global sensitivity analysis yield almost identical ranking of parameter importance. The uncertainty analysis may help select appropriate likelihood functions, improve model calibration, and reduce predictive uncertainty in other groundwater reactive transport and environmental modeling.

Water Resources Research↗

USGS2005

Episodic incision of the Colorado River in Glen Canyon, Utah

Incision rates of the Colorado River are integral to understanding the development of the Colorado Plateau. Here we calculate episodic incision rates of the Colorado River based on absolute ages of two levels of Quaternary deposits adjacent to Glen Canyon, Utah, along the north flank of Navajo Mountain. Minimum surface ages are determined by a combination of cosmogenic radionuclide surface exposure ages, uranium series and soil-development formation times. Bedrock incision rates of the Colorado River between c. 500 ka and c. 250 ka, and c. 250 ka to present are c. 0??4 m ka-1 and c. 0??7 m ka-1, respectively. These rates are more than double the rates reported in the Grand Canyon, suggesting that the Colorado River above Lees Ferry is out of equilibrium with the lower section of the river. We also determine incision rates of two tributaries to the Colorado River. Oak Creek and Bridge Creek flow off Navajo Mountain into Glen Canyon from the southeast. Oak Creek and Bridge Creek both have incision rates of c. 0??6 m ka-1 over the past c. 100 ka at points about 9 km away from the main stem of the Colorado River. Copyright ?? 2005 John Wiley & Sons, Ltd.

Earth Surface Processes and Landforms↗

USGS2017

Optimization of on-line hydrogen stable isotope ratio measurements of halogen- and sulfur-bearing organic compounds using elemental analyzer–chromium/high-temperature conversion isotope ratio mass spectrometry (EA-Cr/HTC-IRMS)

Rationale: Accurate hydrogen isotopic analysis of halogen- and sulfur-bearing organics has not been possible with traditional high-temperature conversion (HTC) because the formation of hydrogen-bearing reaction products other than molecular hydrogen (H2) is responsible for non-quantitative H2 yields and possible hydrogen isotopic fractionation. Our previously introduced, new chromium-based EA-Cr/HTC-IRMS (Elemental Analyzer–Chromium/High-Temperature Conversion Isotope Ratio Mass Spectrometry) technique focused primarily on nitrogen-bearing compounds. Several technical and analytical issues concerning halogen- and sulfur-bearing samples, however, remained unresolved and required further refinement of the reactor systems. Methods: The EA-Cr/HTC reactor was substantially modified for the conversion of halogen- and sulfur-bearing samples. The performance of the novel conversion setup for solid and liquid samples was monitored and optimized using a simultaneously operating dual-detection system of IRMS and ion trap MS. The method with several variants in the reactor, including the addition of manganese metal chips, was evaluated in three laboratories using EA-Cr/HTC-IRMS (on-line method) and compared with traditional uranium-reduction-based conversion combined with manual dual-inlet IRMS analysis (off-line method) in one laboratory. Results: The modified EA-Cr/HTC reactor setup showed an overall H2-recovery of more than 96% for all halogen- and sulfur-bearing organic compounds. All results were successfully normalized via two-point calibration with VSMOW-SLAP reference waters. Precise and accurate hydrogen isotopic analysis was achieved for a variety of organics containing F-, Cl-, Br-, I-, and S-bearing heteroelements. The robust nature of the on-line EA-Cr/HTC technique was demonstrated by a series of 196 consecutive measurements with a single reactor filling. Conclusions: The optimized EA-Cr/HTC reactor design can be implemented in existing analytical equipment using commercially available material and is universally applicable for both heteroelement-bearing and heteroelement-free organic-compound classes. The sensitivity and simplicity of the on-line EA-Cr/HTC-IRMS technique provide a much needed tool for routine hydrogen-isotope source tracing of organic contaminants in the environment. Copyright © 2016 John Wiley & Sons, Ltd.

Rapid Communications in Mass Spectrometry↗