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At least 1,369 records · Page 76Linked to original sources

Temperature data acquired from the DOI/GTN-P Deep Borehole Array on the Arctic Slope of Alaska, 1973-2013

A homogeneous set of temperature measurements obtained from the DOI/GTN-P Deep Borehole Array between 1973 and 2013 is presented; DOI/GTN-P is the US Department of the Interior contribution to the Global Terrestrial Network for Permafrost (GTN-P). The 23-element array is located on the Arctic Slope of Alaska, a region of cold continuous permafrost. Most of the monitoring wells are situated on the Arctic coastal plain between the Brooks Range and the Arctic Ocean, while others are in the foothills to the south. The data represent the true temperatures in the wellbores and surrounding rocks at the time of the measurements; they have not been corrected to remove the thermal disturbance caused by drilling the wells. With a few exceptions, the drilling disturbance is estimated to have been on the order of 0.1 K or less by 1989. Thus, most of the temperature measurements acquired during the last 25 yr are little affected by the drilling disturbance. The data contribute to ongoing efforts to monitor changes in the thermal state of permafrost in both hemispheres by the Global Terrestrial Network for Permafrost, one of the primary subnetworks of the Global Terrestrial Observing System (GTOS). The data will also be useful for refining our basic understanding of the physical conditions in permafrost in Arctic Alaska, as well as providing important information for validating predictive models used for climate impact assessments. The processed data are available from the Advanced Cooperative Arctic Data and Information Service (ACADIS) repository at doi:10.5065/D6N014HK.

Alaska↗

A Bayesian nonparametric approach to unmixing detrital geochronologic data

Sedimentary deposits constitute the primary record of changing environmental conditions that have acted on Earth’s surface over geologic time. Clastic material is eroded from source locations (parents) in sediment routing systems and deposited at sink locations (children). Both parents and children have characteristics that vary across many different dimensions, including grain size, chemical composition, and the geochronologic age of constituent detrital minerals. During transport, sediment from different parents is mixed together to form a child, which in turn may serve as the parent for other sediment farther down-system or later in time when buried sediment is exhumed. The distribution of detrital mineral ages observed in parent and child sediments allows for investigation of the proportion of each parent in the child sediment, which reflects the properties of the sediment routing system. To model the proportion of dates in a child sample that comes from each of the parent distributions, we use a Bayesian mixture of Dirichlet processes. This model enables us to estimate the mixing proportions with associated uncertainty while making minimal assumptions. We also present an extension to the model whereby we reconstruct unobserved parent distributions from multiple observed child distributions using mixtures of Dirichlet processes. The model accounts for uncertainty in both the number of mineral formation events that constitute each parent distribution and the mixing proportions of each parent distribution that constitutes a child distribution. To demonstrate the model, we perform analyses using simulated data where the true age distribution is known as well as using a real-world case study from the coast of central California, USA.

Mathematical Geosciences↗

GSLIB-style programs for discriminant analysis and regionalized classification

Discriminant analysis is a statistical technique used to predict the group membership of a set of multivariate observations, each of which is assumed to arise from one of a set of distinct classes or groups. Each group is characterized by a certain distribution in multivariate space, and group allocations are based on the similarity of each sample to each group. Assuming multivariate normality, generalized distance measures based on the squared Mahalanobis distance from each sample to each group centroid arise as the natural measure of similarity. One can allocate samples to groups either on the basis of minimum generalized distance or, equivalently, maximum posterior probability of group membership. In earth science applications samples are often associated with geographic locations. In this situation regionalized classification can be used to produce a map representing group membership throughout the sampled domain. This can be accomplished by interpolating either generalized distances or membership probabilities from sample locations to regularly spaced grid nodes and comparing resulting grids to produce a classification map. This paper presents a set of GSLIB-style FORTRAN programs for performing discriminant analysis and regionalized classification. The program disco performs discriminant analysis and the programs xmd2cls and prb2cls combine interpolated distances and probabilities, respectively, to create a grid of predicted classifications. In addition, the utility program colbind allows the user to combine selected columns from different GSLIB-style data files into one file. ?? 1997 Elsevier Science Ltd.

Computers & Geosciences↗

Oxygen, hydrogen, sulfur, and carbon isotopes in the Pea Ridge magnetite-apatite deposit, southeast Missouri, and sulfur isotope comparisons to other iron deposits in the region

Oxygen, hydrogen, sulfur, and carbon isotopes have been analyzed in the Pea Ridge magnetite-apatite deposit, the largest historic producer among the known iron deposits in the southeast Missouri portion of the 1.5 to 1.3 Ga eastern granite-rhyolite province. The data were collected to investigate the sources of ore fluids, conditions of ore formation, and provenance of sulfur, and to improve the general understanding of the copper, gold, and rare earth element potential of iron deposits regionally. The δ 18 O values of Pea Ridge magnetite are 1.9 to 4.0‰, consistent with a model in which some magnetite crystallized from a melt and other magnetite—perhaps the majority—precipitated from an aqueous fluid of magmatic origin. The δ 18 O values of quartz, apatite, actinolite, K-feldspar, sulfates, and calcite are significantly higher, enough so as to indicate growth or equilibration under cooler conditions than magnetite and/or in the presence of a fluid that was not entirely magmatic. A variety of observations, including stable isotope observations, implicate a second fluid that may ultimately have been meteoric in origin and may have been modified by isotopic exchange with rocks or by evaporation during storage in lakes. Sulfur isotope analyses of sulfides from Pea Ridge and seven other mineral deposits in the region reveal two distinct populations that average 3 and 13‰. Two sulfur sources are implied. One was probably igneous melts or rocks belonging to the mafic- to intermediate-composition volcanic suite that is present at or near most of the iron deposits; the other was either melts or volcanic rocks that had degassed very extensively, or else volcanic lakes that had trapped rising magmatic gases. The higher δ 34 S values correspond to deposits or prospects where copper is noteworthy—the Central Dome portion of the Boss deposit, the Bourbon deposit, and the Vilander prospective area. The correspondence suggests that (1) sulfur either limited the deposition of copper or was cotransported with copper, and (2) sulfur isotope analysis may be useful in evaluating southeast Missouri iron deposits for copper and possibly for gold.

Missouri↗

Mineral-deposit model for lithium-cesium-tantalum pegmatites

Lithium-cesium-tantalum (LCT) pegmatites comprise a compositionally defined subset of granitic pegmatites. The major minerals are quartz, potassium feldspar, albite, and muscovite; typical accessory minerals include biotite, garnet, tourmaline, and apatite. The principal lithium ore minerals are spodumene, petalite, and lepidolite; cesium mostly comes from pollucite; and tantalum mostly comes from columbite-tantalite. Tin ore as cassiterite and beryllium ore as beryl also occur in LCT pegmatites, as do a number of gemstones and high-value museum specimens of rare minerals. Individual crystals in LCT pegmatites can be enormous: the largest spodumene was 14 meters long, the largest beryl was 18 meters long, and the largest potassium feldspar was 49 meters long. Lithium-cesium-tantalum pegmatites account for about one-fourth of the world’s lithium production, most of the tantalum production, and all of the cesium production. Giant deposits include Tanco in Canada, Greenbushes in Australia, and Bikita in Zimbabwe. The largest lithium pegmatite in the United States, at King’s Mountain, North Carolina, is no longer being mined although large reserves of lithium remain. Depending on size and attitude of the pegmatite, a variety of mining techniques are used, including artisanal surface mining, open-pit surface mining, small underground workings, and large underground operations using room-and-pillar design. In favorable circumstances, what would otherwise be gangue minerals (quartz, potassium feldspar, albite, and muscovite) can be mined along with lithium and (or) tantalum as coproducts. Most LCT pegmatites are hosted in metamorphosed supracrustal rocks in the upper greenschist to lower amphibolite facies. Lithium-cesium-tantalum pegmatite intrusions generally are emplaced late during orogeny, with emplacement being controlled by pre-existing structures. Typically, they crop out near evolved, peraluminous granites and leucogranites from which they are inferred to be derived by fractional crystallization. In cases where a parental granite pluton is not exposed, one is inferred to lie at depth. Lithium-cesium-tantalum LCT pegmatite melts are enriched in fluxing components including H2O, F, P, and B, which depress the solidus temperature, lower the density, and increase rates of ionic diffusion. This, in turn, enables pegmatites to form thin dikes and massive crystals despite having a felsic composition and temperatures that are significantly lower than ordinary granitic melts. Lithium-cesium-tantalum pegmatites crystallized at remarkably low temperatures (about 350–550 °C) in a remarkably short time (days to years). Lithium-cesium-tantalum pegmatites form in orogenic hinterlands as products of plate convergence. Most formed during collisional orogeny (for example, Kings Mountain district, North Carolina). Specific causes of LCT pegmatite-related magmatism could include: ordinary arc processes; over thickening of continental crust during collision or subduction; slab breakoff during or after collision; slab delamination before, during, or after collision; and late collisional extensional collapse and consequent decompression melting. Lithium-cesium-tantalum pegmatite deposits are present in all continents including Antarctica and in rocks spanning 3 billion years of Earth history. The global age distribution of LCT pegmatites is similar to those of common pegmatites, orogenic granites, and detrital zircons. Peak times of LCT pegmatite genesis at about 2640, 1800, 960, 485, and 310 Ma (million years before present) correspond to times of collisional orogeny and supercontinent assembly. Between these pulses were long intervals when few or no LCT pegmatites formed. These minima overlap with supercontinent tenures at ca. 2450–2225, 1625–1000, 875–725, and 250–200 Ma. Exploration and assessment for LCT pegmatites are guided by a number of observations. In frontier areas where exploration has been minimal at best, the key first-order criteria are an orogenic hinterland setting, appropriate regional metamorphic grades, and the presence of evolved granites and common granitic pegmatites. New LCT pegmatites are most likely to be found near known deposits. Pegmatites tend to show a regional mineralogical and geochemical zoning pattern with respect to the inferred parental granite, with the greatest enrichment in the more distal pegmatites. Mineral-chemical trends in common pegmatites that can point toward an evolved LCT pegmatite include: increasing rubidium in potassium feldspar, increasing lithium in white mica, increasing manganese in garnet, and increasing tantalum and manganese in columbite-tantalite. Most LCT pegmatite bodies show a distinctive internal zonation featuring four zones: border, wall, intermediate (where lithium, cesium, and tantalum are generally concentrated), and core. This zonation is expressed both in cross section and map view; thus, what may appear to be a common pegmatite may instead be the edge of a mineralized body. Neither lithium-cesium-tantalum pegmatites nor their parental granites are likely to cause serious environmental concerns. Soils and country rock surrounding a LCT pegmatite, as well as waste from mining operations, may be enriched in characteristic elements relative to global average soil and bedrock values. These elements may include lithium, cesium, tantalum, beryllium, boron, fluorine, phosphorus, manganese, gallium, rubidium, niobium, tin, and hafnium. Among this suite of elements, however, the only ones that might present a concern for environmental health are beryllium and fluorine, which are included in the U.S. Environmental Protection Agency drinking-water regulations with maximum contaminant levels of 4 micrograms per liter and 4 milligrams per liter, respectively.

Scientific Investigations Report↗

Exploring the Earth's crust: History and results of controlled-source seismology

This volume contains a comprehensive, worldwide history of seismological studies of the Earth’s crust using controlled sources from 1850 to 2005. Essentially all major seismic projects on land and the most important oceanic projects are covered. The time period 1850 to 1939 is presented as a general synthesis, and from 1940 onward the history and results are presented in separate chapters for each decade, with the material organized by geographical region. Each chapter highlights the major advances achieved during that decade in terms of data acquisition, processing technology, and interpretation methods. For all major seismic projects, the authors provide specific details on field observations, interpreted crustal cross sections, and key references. They conclude with global and continental-scale maps of all field measurements and interpreted Moho contours. An accompanying DVD contains important out-of-print publications and an extensive collection of controlled-source data, location maps, and crustal cross sections.

GSA Memoir↗

Seismicity induced by wastewater injection in Washington County, Ohio: Influence of preexisting structure, regional stress regime, and well operations

Recent seismicity in Washington County, Ohio, has been suggested to be induced by wastewater disposal operations despite injection ~2 km above the Precambrian basement. We investigated the relationships between disposal well locations and operational histories, spatiotemporal patterns of seismicity enhanced by waveform correlation, and mapped subsurface structures. We also analyzed proxies for in situ stress conditions to evaluate existing principal stress orientations and magnitudes. Double‐difference relocations of small ( M L ≤ 2.1) seismicity revealed linear clusters defining a NE‐SW orientation that parallels the trend of small‐amplitude folds in Upper Paleozoic rocks within 1–2 km of the injection well. Hypocenter depths of ~3.1 to 4.3 km indicate seismicity occurred along faults below the Silurian injection interval in lower Paleozoic strata and Precambrian crystalline basement. Similar folds/faults imaged in nearby seismic reflection lines were associated with basement‐involved fault systems that cut the injection interval targeted by the injection well, providing permeability pathways for fluid pressure increases that initiated slip. Interpreted faults were also optimally oriented in the regional stress field for reactivation due to injection‐related decreases in effective stress. Well completion records suggest that during the recorded seismicity, the Long Run‐1 well was injecting disposal fluids close to or above the fracture pressure of the targeted Silurian injection interval. A comparison of observed seismicity rates and monthly injection records from the disposal well also indicate a close correspondence between earthquake frequency and injection rate. Taken together, these results provide a physical framework for understanding why wastewater disposal operations induced the Washington County seismic sequence.

Ohio↗

Vertical motions of the Puerto Rico Trench and Puerto Rico and their cause

The Puerto Rico trench exhibits great water depth, an extremely low gravity anomaly, and a tilted carbonate platform between (reconstructed) elevations of +1300 m and -4000 m. I argue that these features are manifestations of large vertical movements of a segment of the Puerto Rico trench, its forearc, and the island of Puerto Rico that took place 3.3 m.y. ago over a time period as short as 14-40 kyr. I explain these vertical movements by a sudden increase in the slab's descent angle that caused the trench to subside and the island to rise. The increased dip could have been caused by shearing or even by a complete tear of the descending North American slab, although the exact nature of this deformation is unknown. The rapid (14-40 kyr) and uniform tilt along a 250 km long section of the trench is compatible with scales of mantle flow and plate bending. The proposed shear zone or tear is inferred from seismic, morphological, and gravity observations to start at the trench at 64.5??W and trend southwestwardly toward eastern Puerto Rico. The tensile stresses necessary to deform or tear the slab could have been generated by increased curvature of the trench following a counterclockwise rotation of the upper plate and by the subduction of a large seamount.

Journal of Geophysical Research B: Solid Earth↗

B-positive: A robust estimator of aftershock magnitude distribution in transiently incomplete catalogs

The earthquake magnitude-frequency distribution is characterized by the b -value, which describes the relative frequency of large versus small earthquakes. It has been suggested that changes in b -value after an earthquake can be used to discriminate whether that earthquake is part of a foreshock sequence or a more typical mainshock-aftershock sequence, with a decrease in b -value heralding a larger earthquake to come. However, the measurement of b -value during an active aftershock sequence is strongly biased by short-term incompleteness of the earthquake catalog and by data-windowing, and these biases have the same direction as the proposed signal. Here I develop a new estimator of the b- value that is insensitive to transient changes in catalog completeness and that does not require data windowing. The new estimator “ b -positive” is based on the positive-only subset of the differences in magnitude between successive earthquakes, which are described by a double-exponential (Laplace) distribution with the same b -value as the magnitude distribution itself. The b -positive estimator greatly improves the robustness of continuous b -value measurements during active earthquake sequences, as well as in historical catalogs with unknown or variable completeness. The new estimator confirms some of the observations of Gulia and Wiemer (2019), although at a reduced level, showing a decrease and recovery of the b -value during several recent foreshock sequences that cannot be attributed simply to measurement bias. However, the unbiased b -value changes may be too subtle to use in a real-time earthquake alarm system.

Journal of Geophysical Research: Solid Earth↗

Modeled flooding by tsunamis and a storm versus observed extent of coral erratics on Anegada, British Virgin Islands— Further evidence for a great Caribbean earthquake six centuries ago

Models of near-field tsunamis and an extreme hurricane provide further evidence for a great precolonial earthquake along the Puerto Rico Trench. The models are benchmarked to brain-coral boulders and cobbles on Anegada, 125 km south of the trench. The models are screened by their success in flooding the mapped sites of these erratics, which were emplaced some six centuries ago. Among 25 tsunami scenarios, 19 have megathrust sources and the rest posit normal faulting on the outer rise. The modeled storm, the most extreme of 15 hurricanes of category 5, produces tsunami-like bores from surf beat. In the tsunami scenarios, simulated flow depth is 1 m or more at all the clast sites, and 2 m or more at nearly all, given either a megathrust rupture 255 km long with 7.5 m of dip slip and M8.45, or an outer-rise rupture 130 km long with 11.4 m of dip slip and M8.17. By contrast, many coral clasts lie beyond the reach of simulated flooding from the extreme hurricane. The tsunami screening may underestimate earthquake size by neglecting trees and shrubs that likely impeded both the simulated flows and the observed clasts; and it may overestimate earthquake size by leaving coastal sand barriers intact. The screening results broadly agree with those from previously published tsunami simulations. In either successful scenario, the average recurrence interval spans thousands of years, and flooding on the nearest Caribbean shores begins within a half-hour.

Anegada↗

Elastic stress coupling between supraglacial lakes

Supraglacial lakes have been observed to drain within hours of each other, leading to the hypothesis that stress transmission following one drainage may be sufficient to induce hydro-fracture-driven drainages of other nearby lakes. However, available observations characterizing drainage-induced stress perturbations have been insufficient to evaluate this hypothesis. Here, we use ice-sheet surface-displacement observations from a dense global positioning system array deployed in the Greenland Ice Sheet ablation zone to investigate elastic stress transmission between three neighboring supraglacial lake basins. We find that drainage of a central lake can place neighboring basins in either tensional or compressional stress relative to their hydro-fracture scarp orientations, either promoting or inhibiting hydro-fracture initiation beneath those lakes. For two lakes located within our array that drain close in time, we identify tensional surface stresses caused by ice-sheet uplift due to basal-cavity opening as the physical explanation for these lakes' temporally clustered hydro-fracture-driven drainages and frequent triggering behavior. However, lake-drainage-induced stresses in the up-flowline direction remain low beyond the margins of the drained lakes. This short stress-coupling length scale is consistent with idealized lake-drainage scenarios for a range of lake volumes and ice-sheet thicknesses. Thus, on elastic timescales, our observations and idealized-model results support a stress-transmission hypothesis for inducing hydro-fracture-driven drainage of lakes located within the region of basal cavity opening produced by the initial drainage, but refute this hypothesis for distal lakes.

JGR Earth Surface↗

Properties of new flows indicate that Martian gullies form via CO2 frost-fluidization processes

Martian gully landforms are widely seen as evidence of liquid water, often attributed to snowmelt during high-obliquity periods within the last few million years. However, widespread present-day flows within existing gullies are caused by CO 2 frost, presenting an alternative formation mechanism. Entrained frost vapourizes to fluidize flows, allowing them to behave similarly to wet debris flows on Earth. The slopes where present-day flows erode and deposit provide insights into the landforms that many such flows could create. The shallowest slopes eroded by the flows are similar to slopes at existing channel mouths, and the most mobile flows reach final slopes similar to the outer reaches of existing gully aprons. This is consistent with formation of gullies entirely by CO 2 frost-driven flows, assuming their intensity and frequency varies in space and time. Geologically recent snowmelt cannot be ruled out, but is not required to explain the observed gully morphology.

Geophysical Research Letters↗

Natural occurrence of silicon carbide in a diamondiferous kimberlite from Fuxian

Considerable debate surrounds the existence of silicon carbide in nature, mostly owing to the problem of possible contamination by man-made SiC. Recently, Gurney 1 reviewed reports of rare SiC inclusions in diamonds, and noted that SiC can only be regarded as a probable rather than proven cogenetic mineral. Here we report our observation of clusters of SiC coexisting with diamond in a kimberlite from Fuxian, China. Macrocrysts of α-SiC are overgrown epitaxially by β-SiC, and both polymorphs are structurally well ordered. We have also measured the carbon isotope compositions of SiC and diamonds from Fuxian. We find that SiC is more enriched in 12 C than diamond by 20‰, relative to the PDB standard. Isotope fractionation might have occurred through an isotope exchange reaction in a common carbon reservoir. Silicon carbide may thus ultimately provide information on carbon cycling in the Earth's mantle.

Nature↗

A seismic-reflection investigation of gas hydrates and sea-floor features of the upper continental slope of the Garden Banks and Green Canyon regions, northern Gulf of Mexico: report for cruise G1-99-GM (99002)

During April 1999, the U.S. Geological Survey (USGS) conducted a 13-day cruise in the Garden Banks and Green Canyon regions of the Gulf of Mexico. The R/V Gyre, owned by Texas A&M University, was chartered for the cruise. The general objectives were (1) to acquire very high resolution seismic-reflection data and side-scan sonar images of the upper and middle continental slope (200-1200-m water depths), (2) to study the acoustic character and features of the sea floor for evidence of sea-floor hazards, and (3) to look for evidence of subsurface gas hydrates and their effects. The Gulf of Mexico is well known for hydrocarbon resources, with emphasis now on frontier deep-water areas. For water depths greater than about 250 m, the pressure-termperature conditions are correct for the development of shallow-subsurface gas hydrate formation (Anderson et al., 1992). Gas hydrates are ice-like mixtures of gas and water (Kvenvolden, 1993). They are known to be present from extensive previous sampling in sea-floor cores and from mound-like features observed on the sea floor in many parts of the northern Gulf, including the Green Canyon and Garden Banks areas (e.g., Roberts, 1995). Seismic-reflection data are extensive in the Gulf of Mexico, but few very-high-resolution data like those needed for gas-hydrate studies exist in the public domain. The occurrence and mechanisms of gas hydrate formation and dissociation are important to understand, because of their perceived economic potential for methane gas, their potential controls on local and regional sea-floor stability, and their possible effects on earth climates due to massive release of methane greenhouse gas into the atmosphere. Three high-resolution seismic-reflection systems and one side-scan sonar system were used on the cruise to map the surface reflectance and features of the sea floor and the acoustic geometries and character of the shallow sub-surface. The cruise was designed to acquire regional and detailed local information. The regional survey covered an area about 3400 km2 in the Green Canyon and Garden Banks regions. Data recorded included 15 cu. in. water gun multichannel seismic-reflection and Huntec boomer information. Detailed surveys were planned in two parts of the study area, but due to a winch failure only one detailed survey was done in the Green Canyon area. The detailed survey included collection of 15 cu. in. water gun multichannel seismic-reflection, chirp seismic-reflection, and side-scan data.

Garden Banks Region, Green Canyon region, Gulf Of ↗

Linking soil moisture balance and source-responsive models to estimate diffuse and preferential components of groundwater recharge

Results are presented of a detailed study into the vadose zone and shallow water table hydrodynamics of a field site in Shropshire, UK. A conceptual model is developed and tested using a range of numerical models, including a modified soil moisture balance model (SMBM) for estimating groundwater recharge in the presence of both diffuse and preferential flow components. Tensiometry reveals that the loamy sand topsoil wets up via macropore flow and subsequent redistribution of moisture into the soil matrix. Recharge does not occur until near-positive pressures are achieved at the top of the sandy glaciofluvial outwash material that underlies the topsoil, about 1 m above the water table. Once this occurs, very rapid water table rises follow. This threshold behaviour is attributed to the vertical discontinuity in the macropore system due to seasonal ploughing of the topsoil, and a lower permeability plough/iron pan restricting matrix flow between the topsoil and the lower outwash deposits. Although the wetting process in the topsoil is complex, a SMBM is shown to be effective in predicting the initiation of preferential flow from the base of the topsoil into the lower outwash horizon. The rapidity of the response at the water table and a water table rise during the summer period while flow gradients in the unsaturated profile were upward suggest that preferential flow is also occurring within the outwash deposits below the topsoil. A variation of the source-responsive model proposed by Nimmo (2010) is shown to reproduce the observed water table dynamics well in the lower outwash horizon when linked to a SMBM that quantifies the potential recharge from the topsoil. The results reveal new insights into preferential flow processes in cultivated soils and provide a useful and practical approach to accounting for preferential flow in studies of groundwater recharge estimation.

Shropshire County↗

Chesapeake Bay impact structure: Morphology, crater fill, and relevance for impact structures on Mars

The late Eocene Chesapeake Bay impact structure (CBIS) on the Atlantic margin of Virginia is one of the largest and best-preserved "wet-target" craters on Earth. It provides an accessible analog for studying impact processes in layered and wet targets on volatile-rich planets. The CBIS formed in a layered target of water, weak clastic sediments, and hard crystalline rock. The buried structure consists of a deep, filled central crater, 38 km in width, surrounded by a shallower brim known as the annular trough. The annular trough formed partly by collapse of weak sediments, which expanded the structure to ???85 km in diameter. Such extensive collapse, in addition to excavation processes, can explain the "inverted sombrero" morphology observed at some craters in layered targets. The distribution of crater-fill materials i n the CBIS is related to the morphology. Suevitic breccia, including pre-resurge fallback deposits, is found in the central crater. Impact-modified sediments, formed by fluidization and collapse of water-saturated sand and silt-clay, occur in the annular trough. Allogenic sediment-clast breccia, interpreted as ocean-resurge deposits, overlies the other impactites and covers the entire crater beneath a blanket of postimpact sediments. The formation of chaotic terrains on Mars is attributed to collapse due to the release of volatiles from thick layered deposits. Some flat-floored rimless depressions with chaotic infill in these terrains are impact craters that expanded by collapse farther than expected for similar-sized complex craters in solid targets. Studies of crater materials in the CBIS provide insights into processes of crater expansion on Mars and their links to volatiles. ?? The Meteoritical Society, 2006.

Meteoritics and Planetary Science↗

Physicochemical properties and bioreactivity of sub-10 µm geogenic particles: Comparison of volcanic ash and desert dust

Exposure to ambient particulate matter (PM) with an aerodynamic diameter of <10 μm (PM 10 ) is a well-established health hazard. There is increasing evidence that geogenic (Earth-derived) particles can induce adverse biological effects upon inhalation, though there is high variability in particle bioreactivity that is associated with particle source and physicochemical properties. In this study, we investigated physicochemical properties and biological reactivity of volcanic ash from the April 2021 eruption of La Soufrière volcano, St. Vincent, and two desert dust samples: a standardized test dust from Arizona and an aeolian Gobi Desert dust sampled in China. We determined particle size, morphology, mineralogy, surface texture and chemistry in sub-10 μm material to investigate associations between particle physicochemical properties and observed bioreactivity. We assessed cellular responses (cytotoxic and pro-inflammatory effects) to acute particle exposures (24 hr) in monocultures at the air-liquid interface using two types of cells of the human airways: BEAS-2B bronchial epithelial cells and A549 alveolar type II epithelial cells. In acellular assays, we also assessed particle oxidative potential and the presence of microorganisms. The results showed that volcanic ash and desert dust exhibit intrinsically different particle morphology, surface textures and chemistry, and variable mineralogical content. We found that Gobi Desert dust is more bioreactive than freshly erupted volcanic ash and Arizona test dust, which is possibly linked to the presence of microorganisms (bacteria) and/or nanoscale elongated silicate minerals (potentially clay such as illite or vermiculite) on particle surfaces.

GeoHealth↗

Earth history and the passerine superradiation

Avian diversification has been influenced by global climate change, plate tectonic movements, and mass extinction events. However, the impact of these factors on the diversification of the hyperdiverse perching birds (passerines) is unclear because family level relationships are unresolved and the timing of splitting events among lineages is uncertain. We analyzed DNA data from 4060 nuclear loci and 137 passerine families using concatenation and coalescent approaches to infer a comprehensive phylogenetic hypothesis that clarifies relationships among all passerine families. Then, we calibrated this phylogeny using 13 fossils to examine the effects of different events in Earth history on the timing and rate of passerine diversification. Our analyses reconcile passerine diversification with the fossil and geological records, suggest that passerines originated on the Australian landmass ~47 Ma, and show that subsequent dispersal and diversification of passerines was affected by a number of climatological and geological events, such as Oligocene glaciation and inundation of the New Zealand landmass. Although passerine diversification rates fluctuated throughout the Cenozoic, we find no link between the rate of passerine diversification and Cenozoic global temperature, and our analyses show that the increases in passerine diversification we observe are disconnected from the colonization of new continents. Taken together, these results suggest more complex mechanisms than temperature change or ecological opportunity have controlled macroscale patterns of passerine speciation.

PNAS↗