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At least 1,369 records · Page 76Linked to original sources
USGS2020

Hydrogeology and groundwater geochemistry of till confining units and confined aquifers in glacial deposits near Litchfield, Cromwell, Akeley, and Olivia, Minnesota, 2014–18

Confined (or buried) aquifers of glacial origin overlain by till confining units provide drinking water to hundreds of thousands of Minnesota residents. The sustainability of these groundwater resources is not well understood because hydraulic properties of till that control vertical groundwater fluxes (leakage) to underlying aquifers are largely unknown. The U.S. Geological Survey, Iowa State University, Minnesota Geological Survey, and Minnesota Department of Health investigated hydraulic properties and groundwater flow through till confining units using field studies and heuristic MODFLOW simulations. Till confining units in the following late-Wisconsinan stratigraphic units (with locations in parentheses) were characterized: Des Moines lobe till of the New Ulm Formation (Litchfield, Minnesota), Superior lobe till of the Cromwell and Aitkin Formations (Cromwell, Minn.), and Wadena lobe till of the Hewitt Formation (hydrogeology field camp [HFC] near Akeley, Minn.). Pre-Illinoian till of the Good Thunder formation (Olivia, Minn.) was also characterized. Hydraulic and geochemical field data were collected from sediment cores and a series of five piezometer nests. Each nest consisted of five to eight piezometers screened at short vertical intervals in hydrostratigraphic units including (if present) surficial aquifers, till confining units, confined/buried aquifers, and underlying bedrock. Till hydraulic conductivity was estimated from slug tests (horizontal [ K h ]) and constant-rate aquifer tests in the confined aquifer (vertical [ K v ]). Travel times through the till were evaluated with Darcy’s law and stable isotope concentrations. A series of heuristic MODFLOW simulations were used to evaluate groundwater fluxes through till across the range of till hydraulic properties and pumping rates observed at the field sites. The field data demonstrated variability in hydraulic properties between and within till stratigraphic units horizontally and vertically. The variability in hydraulic properties within and between sites resulted in substantial differences in groundwater flux through till. A conceptual understanding that emerges from the vertical till profiles is that they are not homogeneous hydrostratigraphic units with uniform properties; rather, each vertical sequence is a heterogeneous mixture of glacial sediment with differing abilities to transmit water. Till thicknesses varied from 60 to 166 feet, and till textures ranged from a sandy loam (Hewitt Formation, HFC site) to a silt loam/clay loam (Good Thunder formation, Olivia site). Till Kh varied by one to three orders of magnitude within each piezometer nest. Four piezometer nests had downward hydraulic gradients ranging from 0.04 to 0.56, and one nest had a slight upward hydraulic gradient of 0.02. The Cromwell, HFC, and Litchfield 1 sites were examples of “leaky” tills with high Kv (0.001 to 1.1 feet per day [ft/d]) and geometric mean Kh (0.03 to 0.07 ft/d) and extensive vertical hydraulic connectivity between the confined aquifer and the overlying till. Estimated groundwater travel times through these sites ranged from 1 to 81 years, and two of these sites had tritium throughout their till profiles. The tills at the other two sites, Olivia and Litchfield 2, were effective confining units that had low Kv (0.001 to 0.0005 ft/d) and geometric mean Kh (0.0002 to 0.004 ft/d). The till piezometers at these sites had no drawdown response to short-term (up to 10 hours for Olivia and up to 5 days for Litchfield) high-capacity pumping from the confined aquifer. Estimated groundwater travel times through the tills at these sites ranged from 165 to nearly 1,800 years, and tritium was only detected in the upper one-third of these till profiles. Across all sites, the till vertical anisotropy (ratio of K h to K v ) ranged by four orders of magnitude from 0.05 at the Cromwell nest to 70 at the Litchfield 1 nest. Stable isotopes of oxygen and hydrogen indicate that groundwater throughout all five till profiles is younger than the last glacial advance into Minnesota at about 11,000 years ago. The heuristic modeling demonstrated that, for understanding sustainability of groundwater pumping from confined aquifers, knowledge of till hydraulic properties is just as important as knowledge of aquifer hydraulic properties. Substantial differences in groundwater fluxes into and through till were observed across hydrogeologic settings representative of the field sites. Over long periods of time (hundreds of years), pumping-induced hydraulic gradients are established in confined aquifer systems and, even in low hydraulic conductivity tills, these pumping-induced hydraulic gradients increase leakage into and through till compared to ambient conditions. In conclusion, groundwater flowing vertically downward through till confining units (leakage) replenishes water pumped from confined aquifers. Till hydraulic properties, such as those presented in this report, provide important information that can be used to quantify leakage rates through till. Till hydraulic properties are variable over short distances and profoundly affect leakage rates, demonstrating the importance of site-specific till hydraulic data for evaluating the sustainability of groundwater withdrawals from confined aquifers.

Minnesota↗
USGS1947

Major winter and nonwinter floods in selected basins in New York and Pennsylvania

The scientific design of flood-control works is based on an evaluation of the hydrologic factors basic to flood events, particularly how rainfall and snow runoff, soil conditions, and channel influences can combine to produce greater or lesser floods. For this purpose an analysis of the pertinent hydrologic data is needed. The methods of analysis adopted should conform as closely as possible to those already in use and must be adapted to the quality of the available information. Maximum floods in 8 basins in New York and Pennsylvania during the winter and nonwinter months were studied, a total of 21 floods. The most outstanding winter flood of record in the North Atlantic region was that of March 1936. Rainfall plus snow melt in the basins studied ranged between 3.04 and 6.87 inches, and associated volumes of direct runoff from 1.88 to 5.63 inches. Winter floods have a common characteristic in their relation to freezing temperature. The antecedent periods, representing a period of snow accumulation and frost penetration, are below freezing, and the flood itself is contemporaneous with a period of above-freezing temperatures, usually associated with rain, during which the previously accumulated snow is melted. A second common characteristic of major winter floods is their tendency to be associated with widespread causal meteorologic conditions. There was a more complete conversion of rainfall and snow melt into runoff during the winter storms studied than during the wettest nonwinter flood. Snow melt during winter floods ranged from 0.04 to 0.07 inch per degree-day above 32° F. The depth of mean areal rainfall produced by the nonwinter storms studied ranged from 3.05 to 4.96 inches. The maximum 24-hour quantity at single stations was 14 inches, which was measured during the storm of July 1935 in New York. The volume of direct runoff ranged between 1.39 and 3.41 inches. The portion of rainfall that was converted into runoff varied in accordance with the rate of antecedent base flow, expressed in second-feet per square mile, and emphasized the influence of antecedent conditions. The average volume of direct runoff during winter floods was 4.24 inches, and the average during nonwinter floods was 2.44 inches. The latter, however, were more concentrated as to time, tending to compensate for large volume of runoff in winter, so that the crest rates of direct runoff averaged 0.056 inches per hour during the winter and 0.051 inches during the nonwinter period.

New York, Pennsylvania↗
USGS2009

U.S. Geological Survey Science Strategy for the Wyoming Landscape Conservation Initiative

Southwest Wyoming's wildlife and habitat resources are increasingly affected by energy and urban/exurban development, climate change, and other key drivers of ecosystem change. To ensure that southwest Wyoming's wildlife populations and habitats persist in the face of development and other changes, a consortium of public resource-management agencies proposed the Wyoming Landscape Conservation Initiative (WLCI), the overall goal of which is to implement conservation actions. As the principal agency charged with conducting WLCI science, the U.S. Geological Survey (USGS) has developed a Science Strategy for the WLCI. Workshops were held for all interested parties to identify and refine the most pressing management needs for achieving WLCI goals. Research approaches for addressing those needs include developing conceptual models for understanding ecosystem function, identifying key drivers of change affecting WLCI ecosystems, and conducting scientific monitoring and experimental studies to better understand ecosystems processes, cumulative effects of change, and effectiveness of habitat treatments. The management needs drive an iterative, three-phase framework developed for structuring and growing WLCI science efforts: Phase I entails synthesizing existing information to assess current conditions, determining what is already known about WLCI ecosystems, and providing a foundation for future work; Phase II entails conducting targeted research and monitoring to address gaps in data and knowledge during Phase I; and Phase III entails integrating new knowledge into WLCI activities and coordinating WLCI partners and collaborators. Throughout all three phases, information is managed and made accessible to interested parties and used to guide and improve management and conservation actions, future habitat treatments, best management practices, and other conservation activities.

Scientific Investigations Report↗
USGS2017

A critical review of the postulated role of the non-essential amino acid, β-N-methylamino-L-alanine, in neurodegenerative disease in humans

The compound BMAA (β- N -methylamino-L-alanine) has been postulated to play a significant role in four serious neurological human diseases: Amyotrophic Lateral Sclerosis/Parkinsonism Dementia Complex (ALS/PDC) found on Guam, and ALS, Parkinsonism, and dementia that occur globally. ALS/PDC with symptoms of all three diseases first came to the attention of the scientific community during and after World War II. It was initially associated with cycad flour used for food because BMAA is a product of symbiotic cycad root-dwelling cyanobacteria. Human consumption of flying foxes that fed on cycad seeds was later suggested as a source of BMAA on Guam and a cause of ALS/PDC. Subsequently, the hypothesis was expanded to include a causative role for BMAA in other neurodegenerative diseases including Alzheimer’s disease (AD) through exposures attributed to proximity to freshwaters and/or consumption of seafood due to its purported production by most species of cyanobacteria. The hypothesis that BMAA is the critical factor in the genesis of these neurodegenerative diseases received considerable attention in the medical, scientific, and public arenas. This review examines the history of ALS/PDC and the BMAA-human disease hypotheses; similarities and differences between ALS/PDC and the other diseases with similar symptomologies; the relationship of ALS/PDC to other similar diseases, studies of BMAA-mediated effects in lab animals, inconsistencies and data gaps in the hypothesis; and other compounds and agents that were suggested as the cause of ALS/PDC on Guam. The review concludes that the hypothesis of a causal BMAA neurodegenerative disease relationship is not supported by existing data.

Journal of Toxicology and Environmental Health, Pa↗
USGS2006

Warming and earlier spring increase Western U.S. forest wildfire activity

Western United States forest wildfire activity is widely thought to have increased in recent decades, yet neither the extent of recent changes nor the degree to which climate may be driving regional changes in wildfire has been systematically documented. Much of the public and scientific discussion of changes in western United States wildfire has focused instead on the effects of 19th- and 20th-century land-use history. We compiled a comprehensive database of large wildfires in western United States forests since 1970 and compared it with hydroclimatic and land-surface data. Here, we show that large wildfire activity increased suddenly and markedly in the mid-1980s, with higher large-wildfire frequency, longer wildfire durations, and longer wildfire seasons. The greatest increases occurred in mid-elevation, Northern Rockies forests, where land-use histories have relatively little effect on fire risks and are strongly associated with increased spring and summer temperatures and an earlier spring snowmelt.

Science↗
USGS2022

Dipping reflectors in the Norwegian Sea—ODP Leg 104 drilling results: LEG 104 SCIENTIFIC PARTY

Ocean Drilling Program (ODP) Leg 104 successfully completed a number of deep drill holes on the Outer V0ring Plateau and the Vering Basin during July and August 1985 (Fig. 1; Eldholm, Thiede, Taylor et al. 1986). One of the principal objectives of the leg was to drill and sample a thick oceanward-dipping wedge of seismic reflectors, known to characterize much of the multichannel seismic (MCS) profile data recorded across ocean-continent transitions in the NE Atlantic north of 55°N. Elsewhere, these reflectors have previously been the target of deep drilling during Legs 48 and 81 of the International Phase of Ocean Drilling IPOD (Montadert, Roberts et al. 1979; Roberts, Schnitker et al. 1984). These efforts met with some success, sampling only the uppermost part of the sequence and identifying a series of tholeiitic lava flows. Over the Outer V~ring Plateau, a number of MCS profiles reveal a distinct change in seismic character at the base of the well-stratified dipping reflector sequence, where an irregular surface characterized by a band of low-frequency, high-amplitude reflectors occurs. This surface is referred to as K. Prior to Leg 104, therefore, relatively little was known regarding the variation in petrographic character of the flows at depth, their evolution and origin, and particularly the character of the material below the reflector sequence. A single deep drillhole (642E) successfully recovered a section through the

Journal of the Geological Society↗
USGS2007

The Distribution of Submersed Aquatic Vegetation in the Fresh and Oligohaline Tidal Potomac River, 2004

Introduction Submersed aquatic vegetation (SAV) is a critical component of the Potomac River ecosystem. Though SAV provides important habitat for fauna and stabilizes bottom sediment, very dense beds may restrict recreational and commercial navigation. Exotic species of SAV are managed by the Metropolitan Washington Council of Governments Potomac Aquatic Plant Management Program (PAPMP). Selected beds of exotic SAV species that limit navigation are harvested mechanically. The program began in 1986 when approximately 40 acres of plants were harvested from 18 sites (Metropolitan Washington Council of Governments 1987). Monitoring efforts are an effective means of quantifying the distribution and abundance of the exotic species, Hydrilla verticillata (hydrilla) and other SAV species. These annual surveys provide a basis for identifying large-scale changes throughout the ecosystem and allow managers to evaluate the effectiveness of resource management policies based on a reliable scientific foundation. The U.S. Geological Survey (USGS) has monitored the distribution and composition of SAV beds in the fresh and oligohaline (salinity 0.5 to 5) tidal Potomac River since 1978 using transect sampling (1978 to 1981, 1985 to 1987, and 2002) and shoreline surveys (1983 to 2004). Shoreline survey data from the tidal Potomac River are incorporated into the Virginia Institute of Marine Science (VIMS) annual report on SAV distribution in Chesapeake Bay. The VIMS report and methods are available at http://www.vims.edu/bio/sav. Additional publications concerning SAV distribution in the Potomac River can be found at http://water.usgs.gov/nrp/proj.bib/sav/wethome.htm.

Open-File Report↗
USGS1985

Water-resources activities of the U.S. Geological Survey in Nebraska, 1984

The State of Nebraska has a greater abundance of water than most of the surrounding States. The major water issues in the State concern the management of these water resources in regard to their availability areally across the State and temporally over the changing seasons and cycles of weather. Management also concerns the protection of the supply of water from deterioration through contamination. The U.S. Geological Survey (USGS) in Nebraska began providing data to allow for better management of the State 's water near the end of the 19th Century. Since then the USGS activities have continued and have included the monitoring of hydrologic conditions, detailed studies to describe the hydrology of specific areas, and studies to add to the basic scientific knowledge of hydrology. Projects in all these areas continue. The work has been supported through Federal funding, through support from other Federal agencies, and through cooperative programs with many State and local agencies. This report summarizes these activities which are ongoing in the State of Nebraska. (Lantz-PTT)

Open-File Report↗
USGS2011

Updated one-dimensional hydraulic model of the Kootenai River, Idaho: A supplement to Scientific Investigations Report 2005-5110

The Kootenai Tribe of Idaho, in cooperation with local, State, Federal, and Canadian agency co-managers and scientists, is assessing the feasibility of a Kootenai River habitat restoration project in Boundary County, Idaho. The restoration project is focused on recovery of the endangered Kootenai River white sturgeon (Acipenser transmontanus) population, and simultaneously targets habitat-based recovery of other native river biota. River restoration is a complex undertaking that requires a thorough understanding of the river and floodplain landscape prior to restoration efforts. To assist in evaluating the feasibility of this endeavor, the U.S. Geological Survey developed an updated one-dimensional hydraulic model of the Kootenai River in Idaho between river miles (RMs) 105.6 and 171.9 to characterize the current hydraulic conditions. A previously calibrated model of the study area, based on channel geometry data collected during 2002 and 2003, was the basis for this updated model. New high-resolution bathymetric surveys conducted in the study reach between RMs 138 and 161.4 provided additional detail of channel morphology. A light detection and ranging (LIDAR) survey was flown in the Kootenai River valley in 2005 between RMs 105.6 and 159.5 to characterize the floodplain topography. Six temporary gaging stations installed in 2006-08 between RMs 154.1 and 161.2, combined with five permanent gaging stations in the study reach, provided discharge and water-surface elevations for model calibration and verification. Measured discharges ranging from about 4,800 to 63,000 cubic feet per second (ft 3 /s) were simulated for calibration events, and calibrated water-surface elevations ranged from about 1,745 to 1,820 feet (ft) throughout the extent of the model. Calibration was considered acceptable when the simulated and measured water-surface elevations at gaging stations differed by less than (+/-)0.15 ft. Model verification consisted of simulating 10 additional events with measured discharges ranging from about 4,900 to 52,000 ft 3 /s, and comparing simulated and measured water-surface elevations at gaging stations. Average water-surface-elevation error in the verification simulations was 0.05 ft, with the error ranging from -1.17 to 0.94 ft over the range of events and gaging stations. Additional verification included a graphical comparison of measured average velocities that range from 1.0 to 6.2 feet per second to simulated velocities at four sites within the study reach for measured discharges ranging from about 7,400 to 46,600 ft 3 /s. The availability of high-resolution bathymetric and LIDAR data, along with the additional gaging stations in the study reach, allowed for more detail to be added to the model and a more thorough calibration, sensitivity, and verification analysis to be conducted. Model resolution and performance is most improved between RMs 140 and 160, which includes the 18.3-mile reach of the Kootenai River white sturgeon critical habitat.

Idaho↗
USGS2022

The abundance and persistence of Caprinae populations

Stable or growing populations may go extinct when their sizes cannot withstand large swings in temporal variation and stochastic forces. Hence, the minimum abundance threshold defining when populations can persist without human intervention forms a key conservation parameter. We identify this threshold for many populations of Caprinae , typically threatened species lacking demographic data. Doing so helps triage conservation and management actions for threatened or harvested populations. Methodologically, we used population projection matrices and simulations, with starting abundance, recruitment, and adult female survival predicting future abundance, growth rate (λ), and population trend. We incorporated mean demographic rates representative of Caprinae populations and corresponding variances from desert bighorn sheep ( Ovis canadensis nelsoni ), as a proxy for Caprinae sharing similar life histories. We found a population’s minimum abundance resulting in ≤ 0.01 chance of quasi-extinction ( QE ; population ≤ 5 adult females) in 10 years and ≤ 0.10 QE in 30 years as 50 adult females, or 70 were translocation (removals) pursued. Discovering the threshold required 3 demographic parameters. We show, however, that monitoring populations’ relationships to this threshold requires only abundance and recruitment data. This applied approach avoids the logistical and cost hurdles in measuring female survival, making assays of population persistence more practical.

Scientific Reports↗
USGS2026

Bayesian belief network model to predict human-wildlife conflict in protected areas

Human-wildlife conflict (HWC) poses a pervasive global challenge, affecting livelihoods and threatening biodiversity. To better anticipate and mitigate HWC risk, we developed a large-scale predictive model using a Bayesian Belief Network (BBN). We surveyed 1,011 park rangers across 135 terrestrial protected areas in three Andean countries, documenting recent HWC incidents involving wildlife persecution or killing, livestock depredation, crop damage, or threats to human safety and property. We identified key drivers of HWC risk, including governance, wildlife acceptance, participation, and habitat quality. A sensitivity analysis revealed that enhancing governance and improving wildlife acceptance could reduce HWC risk by > 85%. The BBN model demonstrated scalability, effectively identifying strategies to reduce HWC risk at multiple scales, from individual protected areas to national networks. Our findings highlight the importance of strengthening governance, increasing wildlife acceptance, and enhancing community participation in conservation efforts. BBNs provide a flexible, cost-effective, and data-driven tool to guide protected areas and wildlife managers in monitoring, anticipating, and making informed decisions to mitigate conflict and promote coexistence.

Scientific Reports↗
USGS2018

Isostatic gravity map of Mountain Pass and vicinity, California and Nevada

Gravity investigations of Mountain Pass and vicinity were begun as part of an effort to study regional crustal structures as an aid to understanding the geologic framework and mineral resources of the eastern Mojave Desert. The study area, which straddles the state boundary between southeastern California and southern Nevada, encompasses Mountain Pass, which is host to one of the world’s largest rare earth element carbonatite deposits. The deposit is found along a north-northwest-trending, fault-bounded block that extends along the eastern parts of the Clark Mountain Range, Mescal Range, and Ivanpah Mountains. This Paleoproterozoic block is composed of a 1.7-Ga metamorphic complex of gneiss and schist that underwent widespread metamorphism and associated plutonism during the Ivanpah orogeny. The Paleoproterozoic rocks were intruded by a Mesoproterozoic (1.4 Ga) ultrapotassic alkaline intrusive suite and carbonatite body. The intrusive rocks include, from oldest to youngest, shonkinite, mesosyenite, syenite, quartz syenite, potassic granite, carbonatite, carbonatite dikes, and late shonkinite dikes. Generally speaking, gravity anomalies can be used to infer subsurface geologic structure, revealing variations in lithology and delineating features such as faults, plutons, volcanic centers, calderas, and deep sedimentary basins. As part of this study, gravity data from more than 2,400 stations were collected and processed to identify lateral changes in subsurface density. Gravity stations were distributed across parts of Shadow Valley, Clark Mountain Range, Mescal Range, Ivanpah Mountains, and Ivanpah Valley. The new gravity data were combined with preexisting gravity data from the surrounding areas in California and Nevada. All gravity data were gridded using a minimum curvature algorithm at an interval of 200 m, and the result is displayed as a color-contour isostatic gravity map.

California, Nevada↗
USGS2021

Colored shaded-relief bathymetry, acoustic backscatter, and selected perspective views of the northern part of the California Continental Borderland, southern California

The California Continental Borderland is the complex continental margin in southern California that extends from Point Conception southward into northern Baja California (Fisher and others, 2009). This colored shaded-relief bathymetry map of the northern continental borderland in southern California was generated primarily from multibeam-echosounder data collected by the University of Washington in 2016, the Ocean Exploration Trust-Nautilus Exploration Program in 2015–17, and the National Oceanic and Atmospheric Administration in 2017. These datasets were processed in part by the U.S. Geological Survey. Additional smaller amounts of publicly available multibeam-bathymetry data collected by other federal and local agencies, academic institutions, and private firms were also incorporated into this map. Since the production of this map, other multibeam-bathymetry data have been collected in this region.

California↗
USGS2009

Estimation of Flood Discharges at Selected Recurrence Intervals for Streams in New Hampshire

This report provides estimates of flood discharges at selected recurrence intervals for streamgages in and adjacent to New Hampshire and equations for estimating flood discharges at recurrence intervals of 2-, 5-, 10-, 25-, 50-, 100-, and 500-years for ungaged, unregulated, rural streams in New Hampshire. The equations were developed using generalized least-squares regression. Flood-frequency and drainage-basin characteristics from 117 streamgages were used in developing the equations. The drainage-basin characteristics used as explanatory variables in the regression equations include drainage area, mean April precipitation, percentage of wetland area, and main channel slope. The average standard error of prediction for estimating the 2-, 5-, 10-, 25-, 50-, 100-, and 500-year recurrence interval flood discharges with these equations are 30.0, 30.8, 32.0, 34.2, 36.0, 38.1, and 43.4 percent, respectively. Flood discharges at selected recurrence intervals for selected streamgages were computed following the guidelines in Bulletin 17B of the U.S. Interagency Advisory Committee on Water Data. To determine the flood-discharge exceedence probabilities at streamgages in New Hampshire, a new generalized skew coefficient map covering the State was developed. The standard error of the data on new map is 0.298. To improve estimates of flood discharges at selected recurrence intervals for 20 streamgages with short-term records (10 to 15 years), record extension using the two-station comparison technique was applied. The two-station comparison method uses data from a streamgage with long-term record to adjust the frequency characteristics at a streamgage with a short-term record. A technique for adjusting a flood-discharge frequency curve computed from a streamgage record with results from the regression equations is described in this report. Also, a technique is described for estimating flood discharge at a selected recurrence interval for an ungaged site upstream or downstream from a streamgage using a drainage-area adjustment. The final regression equations and the flood-discharge frequency data used in this study will be available in StreamStats. StreamStats is a World Wide Web application providing automated regression-equation solutions for user-selected sites on streams.

Scientific Investigations Report↗
USGS2007

Evaluation of Streamflow Gain-Loss Characteristics of Hubbard Creek, in the Vicinity of a Mine-Permit Area, Delta County, Colorado, 2007

In 2007, the U.S. Geological Survey, in cooperation with Bowie Mining Company, initiated a study to characterize the streamflow and streamflow gain-loss in a reach of Hubbard Creek in Delta County, Colorado, in the vicinity of a mine-permit area planned for future coal mining. Premining streamflow characteristics and streamflow gain-loss variation were determined so that pre- and postmining gain-loss characteristics could be compared. This report describes the methods used in this study and the results of two streamflow-measurement sets collected during low-flow conditions. Streamflow gain-loss measurements were collected using rhodamine WT and sodium bromide tracers at four sites spanning the mine-permit area on June 26-28, 2007. Streamflows were estimated and compared between four measurement sites within three stream subreaches of the study reach. Data from two streamflow-gaging stations on Hubbard Creek upstream and downstream from the mine-permit area were evaluated. Streamflows at the stations were continuous, and flow at the upstream station nearly always exceeded the streamflow at the downstream station. Furthermore, streamflow at both stations showed similar diurnal patterns with traveltime offsets. On June 26, streamflow from the gain-loss measurements was greater at site 1 (most upstream site) than at site 4 (most downstream site); on June 27, streamflow was greater at site 4 than at site 2; and on June 27, there was no difference in streamflow between sites 2 and 3. Data from streamflow-gaging stations 09132940 and 09132960 showed diurnal variations and overall decreasing streamflow over time. The data indicate a dynamic system, and streamflow can increase or decrease depending on hydrologic conditions. The streamflow within the study reach was greater than the streamflows at either the upstream or downstream stations. A second set of gain-loss measurements was collected at sites 2 and 4 on November 8-9, 2007. On November 8, streamflow was greater at site 4 than at site 2, and on the following day, November 9, streamflow was greater at site 2 than at site 4. Data collection on November 8 occurred while the streamflow was increasing due to contributions from stream ice melting throughout different parts of the basin. Data collection on November 9 occurred earlier in the day with less stream ice melting and more steady-state conditions, so the indication that streamflow decreased between sites 2 and 4 may be more accurate. Diurnal variations in streamflow are common at both the upper and the lower streamflow-gaging stations. The upper streamflow-gaging station shows a melt-freeze influence from tributaries to Hubbard Creek during the winter season. Downstream from the study reach, observed diurnal variation is likely due to evapotranspiration associated with dense flood-plain vegetation, which consumes water from the creek during the middle of the day. Varying diurnal patterns in streamflow, combined with possible variations in tributary inflows to Hubbard Creek in the study reach, probably account for the observed variations in streamflow at the tracer measurement sites. During both sampling periods in June and November 2007, conditions were less than ideal and not steady state. The June 27 sampling indicates that the streamflow was increasing between measurement sites 2 and 4, and the November 9 sampling indicates that the streamflow was decreasing between measurement sites 2 and 4. The data collected during the diurnal and day-to-day variations in streamflow indicated that the streamflow reach is dynamic and can be gaining, losing, or constant.

Scientific Investigations Report↗
USGS2012

Distribution and variation of arsenic in Wisconsin surface soils, with data on other trace elements

A total of 664 soil samples distributed among different geographic regions and soil types were collected across Wisconsin to describe the distribution of arsenic relative to parent material, soil texture, and drainage class. Soils from 6 inches in depth were composited, digested in aqua regia, and analyzed for 17 trace elements. Observed soil arsenic concentrations range from a high of 39 milligrams per kilogram (mg/kg) to less than the laboratory detection limit of 1 mg/kg. Ten samples with soil arsenic concentrations greater than 8.5 mg/kg were determined to be significantly separate from the main cluster of the dataset. With these outliers removed, overall soil arsenic concentrations in Wisconsin have a median value of 1.8 mg/kg, and the 95-percent upper confidence limit of the mean is 2.4 mg/kg. Soils with sandy glacial outwash as a parent material have a lower median arsenic concentration (1.0 mg/kg) than soils forming in other parent materials (1.5 to 3.0 mg/kg). Soil texture and drainage category also influence median arsenic concentration. Finer grained soils have a higher observed range of concentrations. For loamy and loess-dominated soil groups, drainage category influences the median arsenic concentration and observed range of values, but a consistent relationship within the data is not apparent. Statistical analysis of the 16 other elements are presented in this report, but the relationships of concentrations to soil properties or geographic areas were not examined.

Wisconsin↗
USGS2012

Invertebrate response to changes in streamflow hydraulics in two urban areas in the United States

Stream hydrology is foundational to aquatic ecosystems and has been shown to be a structuring element for fish and invertebrates. The relations among urbanization, hydraulics, and invertebrate communities were investigated by the U.S. Geological Survey, National Water-Quality Assessment Program by using measures of stream hydraulics in two areas of the United States. Specifically, the hypothesis that the effects of urbanization on streamflow and aquatic biota are transferable across geographic regions was tested. Data from sites in Raleigh, North Carolina, and Milwaukee–Green Bay, Wisconsin, were compared and indicate that increasing urbanization has an effect on hydraulic characteristics (Reynolds number, shear stress, and stream power for example) in each metropolitan area, though limited commonality of significant correlations was noted between areas. Correspondence of significant correlations between invertebrate and hydraulic metrics between study areas also was limited. The links between urbanization, hydraulics, and invertebrates could be seen only in the Raleigh data. Connections among these three elements in the Milwaukee–Green Bay data were not clear and likely were obscured by antecedent land cover. Observed biotic differences due to hydrology and urbanization characteristics are not similar between geographic regions.

Scientific Investigations Report↗
USGS2013

Analytical properties of some commercially available nitrate reductase enzymes evaluated as replacements for cadmium in automated, semiautomated, and manual colorimetric methods for determination of nitrate plus nitrite in water

A multiyear research effort at the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL) evaluated several commercially available nitrate reductase (NaR) enzymes as replacements for toxic cadmium in longstanding automated colorimetric air-segmented continuous-flow analyzer (CFA) methods for determining nitrate plus nitrite (NO x ) in water. This research culminated in USGS approved standard- and low-level enzymatic reduction, colorimetric automated discrete analyzer NO x methods that have been in routine operation at the NWQL since October 2011. The enzyme used in these methods (AtNaR2) is a product of recombinant expression of NaR from Arabidopsis thaliana (L.) Heynh. (mouseear cress) in the yeast Pichia pastoris. Because the scope of the validation report for these new automated discrete analyzer methods, published as U.S. Geological Survey Techniques and Methods 5–B8, was limited to performance benchmarks and operational details, extensive foundational research with different enzymes—primarily YNaR1, a product of recombinant expression of NaR from Pichia angusta in the yeast Pichia pastoris—remained unpublished until now. This report documents research and development at the NWQL that was foundational to development and validation of the discrete analyzer methods. It includes: (1) details of instrumentation used to acquire kinetics data for several NaR enzymes in the presence and absence of known or suspected inhibitors in relation to reaction temperature and reaction pH; and (2) validation results—method detection limits, precision and bias estimates, spike recoveries, and interference studies—for standard- and low-level automated colorimetric CFA-YNaR1 reduction NO x methods in relation to corresponding USGS approved CFA cadmium-reduction (CdR) NO x methods. The cornerstone of this validation is paired sample statistical and graphical analysis of NOx concentrations from more than 3,800 geographically and seasonally diverse surface-water and groundwater samples that were analyzed in parallel by CFA-CdR and CFA enzyme-reduction methods. Finally, (3) demonstration of a semiautomated batch procedure in which 2-milliliter analyzer cups or disposable spectrophotometer cuvettes serve as reaction vessels for enzymatic reduction of nitrate to nitrite prior to analytical determinations. After the reduction step, analyzer cups are loaded onto CFA, flow injection, or discrete analyzers for simple, rapid, automatic nitrite determinations. In the case of manual determinations, analysts dispense colorimetric reagents into cuvettes containing post-reduction samples, allow time for color to develop, insert cuvettes individually into a spectrophotometer, and record percent transmittance or absorbance in relation to a reagent blank. Data presented here demonstrate equivalent analytical performance of enzymatic reduction NO x methods in these various formats to that of benchmark CFA-CdR NO x methods.

Scientific Investigations Report↗