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Geology of the area adjacent to the Free Enterprise uranium-silver Mine, Boulder District, Jefferson County, Montana

Uranium minerals.occur in pods associated with cryptocrystalline silica, silver minerals, and scattered sulfide mineral grains in a hydrothermal vein that cuts quartz monzonite and alaskite at the Free Enterprise mine, 2 miles west of Boulder, Mont. The Free Enterprise vein is one of many silicified reef-like structures in this area, most of which trend about N. 60° E. The cryptocrystalline silica zones of the area are lenticular and are bordered by an altered zone where quartz monzonite is the wall rock. No alteration was noticed where alaskite is adjacent to silica zones. No uranium minerals were observed at the surface, but radioactivity anomalies were noted at 57 outcrops. Underground mining has shown that leaching by downward percolating waters has removed most of the uranium from the near-surface part of the Free Enterprise vein and probably has enriched slightly, parts of the vein and the adjacent wall rock from the bottom of the leached zone to the ground-water level. It is possible that other veins that show low to moderate radioactivity at the surface may contain significant concentrations of uranium minerals at relatively shallow depth. The quartz monzonite appears to be a more favorable host rock for the cryptocrystalline silica and associated uranium minerals than the alaskite. The alaskite occurs as vertical_dikes plug-like masses, and as irregularly shaped, gently dipping masses that are believed to have been intruded into open fractures formed during the cooling of the quartz monzonite.

Montana↗

A 15 000-year record of climate change in northern New Mexico, USA, inferred from isotopic and elemental contents of bog sediments

Elemental (C, N, Pb) and isotopic ( δ 13 C, δ 15 N) measurements of cored sediment from a small bog in northern New Mexico reveal changes in climate during the Late Pleistocene and Holocene. Abrupt increases in Pb concentration and δ 13 C values ca. 14 420 cal. YBP indicate significant runoff to the shallow lake that existed at that time. Weathering and transport of local volcanic rocks resulted in the delivery of Pb-bearing minerals to the basin, while a 13 C-enriched terrestrial vegetation source increased the δ 13 C values of the sedimentary material. Wet conditions developed over a 300 a period and lasted for a few hundred years. The Younger Dryas period (ca. 12 700–11 500 cal. YBP) caused a reduction in terrestrial productivity reflected in decreasing C/N values, δ 15 N values consistently greater than 0‰ and low organic content. By contrast, aquatic productivity increased during the second half of this period, evidenced by increasing δ 13 C values at the time of highest abundance of algae. Dry conditions ca. 8 000–6 000 cal. YBP were characterised by low organic carbon content and high Pb concentrations, the latter suggesting enhanced erosion and aeolian transport of volcanic rock. The range in δ 13 C, δ 15 N and C/N values in the sedimentary record fall within the range of modern plants, except during the periods of runoff and drought. The sedimentary record provides evidence of natural climate variability in northern New Mexico, including short- (multi-centennial) and long-(millennial) term episodes during the Late Pleistocene and Holocene.

Journal of Quaternary Science↗

Magmatic-hydrothermal gold mineralization at the Lone Tree Mine, Battle Mountain district, Nevada

The Lone Tree deposit is located in the northern Battle Mountain mining district, Nevada. Prior to mine closure in 2006, Santa Fe Pacific Gold and Newmont produced 4.2 Moz of gold at an average grade of 2.06 g/t at Lone Tree, primarily from the N-S– to NNW-SSE–striking Wayne zone. The ore is located between the Roberts Mountain and Golconda thrusts in siliciclastic rocks of the Ordovician Valmy Formation and in the Pennsylvanian-Permian Battle Mountain and Edna Mountain Formations, and above the Golconda thrust in siliciclastic and carbonate rocks of the Mississippian to Permian Havallah sequence. Ore is also hosted by rhyolitic dikes that were emplaced at 40.95 ± 0.06 Ma based on zircon U-Pb chemical abrasion-thermal ionization mass spectrometry. The gold is associated with sericitic and argillic alteration of the siliciclastic rocks and dikes and with decarbonatization and Fe carbonate alteration of the carbonate-bearing units, as well as in Fe-As sulfide and finegrained quartz alteration of all rock types. Oxidation affects 30 to 45% of the deposit, penetrating into the stratigraphy along numerous steeply dipping north-south, east-west, and north-northeast–south-southwest structures. Gold is positively correlated with Ag, As, Hg, and Sb. The highest Au grades occur in quartz-sulfide ore hosted in siliciclastic and carbonate sedimentary rocks and rhyolitic intrusions. In this ore style, fine-grained quartz and sericite are intergrown with disseminated sulfide minerals (quartz-sericite-pyrite alteration), constituting cores of weakly mineralized pyrite or marcasite, which are surrounded by fuzzy arsenopyrite rims that contain up to ~2,000 ppm Au. Low gold grades occur in late-stage banded pyrite breccias consisting of a finely zoned Au-poor pyrite matrix surrounding jigsaw-fit clasts of quartz-, illite-, barite-, and adularia-altered siliciclastic rock. The timing of main-stage mineralization is bracketed between the emplacement of the dikes and an adularia 40 Ar/ 39 Ar age of 40.14 ± 0.74 Ma. Sericite intergrown with arsenopyrite-rimmed pyrite in phenocrysts of the rhyolite dikes gave δ 18 O values of 1.6 to 9.5‰ and δ D values of –105 to –145‰. For temperatures of 300 ± 100°C, the calculated fluid isotopic compositions are consistent with felsic magmatic water and minor modifications by mixing with meteoric water and exchange with wall rocks. In the silica-sulfide ore, in situ isotopic laser ablation-multicollector-inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS) analyses of pyrite cores yielded δ 34 S values ranging from 3.4 to 7.7‰, with average values of 5.6‰ in the felsic dikes, 4.5‰ in the siliciclastic rocks, and 5.3‰ in the carbonate rocks. These values match conventional pyrite δ 34 S data reported for Eocene porphyry systems elsewhere in the district. Nanoscale secondary ion mass spectrometry analyses show that gold and associated trace elements occur in submicron-scale zones within arsenopyrite rims on pyrite. The average δ 34 S values of the arsenopyrite rims are 5.3 to 6.5‰ heavier than the pyrite cores, indicating cooling and an increasing H 2 S/SO 2 ratio. The highest grades resulted from episodic pulses of a gold-rich fluid that was partly derived from, or exchanged with, the sedimentary host rocks. In situ LA-MC-ICP-MS δ 34 S values for the late-stage banded pyrite breccia become progressively lighter from veinlet margin to center, reaching a low of –32‰. These veinlets indicate a shift from main-stage quartz-sericite-pyrite and intermediate argillic alteration to more neutral pH and oxidizing conditions during late-stage mineralization, indicating either increasing interaction between the fluid and sedimentary sulfur sources in the host-rock package or bacterial sulfate reduction and supergene sulfide precipitation.

Nevada↗

Maps showing mines, prospects, and mineral sites in the Tray Mountain Roadless Area and vicinity, Northern Georgia

The Tray Mountain Roadless Area, a 36,300-acre tract in the Chattahoochee National Forest, northeastern Georgia, lies within the Blue Redge physiographic province. The roadless area is composed of Precambrian(?)-age metamorphic rocks from two tectonic units, the Hayesville thrust sheet and the "Helen belt" (Nelson, 1982) (fig. 1). The Hayesville thrust sheet consists mostly of biotite gneiss and schist, fine-grained biotite-feldspar gneiss, metasandstone, quartzite, and amphibolite; ultramafic bodies, some granitic gneiss, and small pegmatites are also present. The Helen belt contains mostly metagraywacke, metasandstone, quartzite, graphite schist, amphibolite, some ultramafic bodies, and granitic gneiss. Two "gold belts" and an area of mineralization associated with ultramafic rocks are on lands adjacent to the roadless area. Mining within the roadless area has not been extensive, and there is no current mineral activity in the surrounding region.

Georgia↗

A comprehensive survey of faults, breccias, and fractures in and flanking the eastern Española Basin, Rio Grande rift, New Mexico

A comprehensive survey of geologic structures formed in the Earth’s brittle regime in the eastern Española Basin and flank of the Rio Grande rift, New Mexico, reveals a complex and protracted record of multiple tectonic events. Data and analyses from this representative rift flank-basin pair include measurements from 53 individual fault zones and 22 other brittle structures, such as breccia zones, joints, and veins, investigated at a total of just over 100 sites. Structures were examined and compared in poorly lithified Tertiary sediments, as well as in Paleozoic sedimentary and Proterozoic crystalline rocks. Data and analyses include geologic maps; field observations and measurements; orientation, kinematic, and paleostress analyses; statistical examination of fault trace lengths derived from aeromagnetic data; mineralogy and chemistry of host and fault rocks; and investigation of fault versus bolide-impact hypotheses for the origin of enigmatic breccias found in the Proterozoic basement rocks. Fault kinematic and paleostress analyses suggest a record of transitional, and perhaps partitioned, strains from the Laramide orogeny through Rio Grande rifting. Normal faults within Tertiary basin-fill sediments are consistent with more typical WNW-ESE Rio Grande rift extension, perhaps decoupled from bedrock structures due to strength contrasts favoring the formation of new faults in the relatively weak sediments. Analyses of the fault-length data indicate power-law length distributions similar to those reported from many geologic settings globally. Mineralogy and chemistry in Proterozoic fault-related rocks reveal geochemical changes tied to hydrothermal alteration and nearly isochemical transformation of feldspars to clay minerals. In sediments, faulted minerals are characterized by mechanical entrainment with minor secondary chemical changes. Enigmatic breccias in rift-flanking Proterozoic rocks are autoclastic and isochemical with respect to their protoliths and exist near shatter cones believed to be related to a previously reported pre-Pennsylvanian impact event. A weak iridium anomaly is associated with the breccias as well as adjacent protoliths, thus an impact shock wave cannot be ruled out for their origin. Major fault zones along the eastern rift-flank mountain front are discontinuous and unlikely to impede regional groundwater flow into Española Basin aquifers. The breccia bodies are not large enough to constitute aquifers, and no fault- or breccia-related geochemical anomalies were identified as potential contamination sources for ground or surface waters. The results of this work provide a broad picture of structural diversity and tectonic evolution along the eastern flank of the central Rio Grande rift and the adjacent Española Basin representative of the rift as a whole and many rifts worldwide.

New Mexico↗

Wisconsin Glaciation of the Sierra Nevada (79,000-15,000 yr B.P.) as recorded by rock flour in sediments of Owens Lake, California

Chemical analyses of the clay-sized fractions of 564 continuous sediment samples (200-yr resolution) from composite core OL90/92 allow quantification of an abundance of glacial rock flour. Rock flour produced during glacier advances is represented by clay-sized plagioclase, K-feldspar, and biotite in homogeneous internal composition. The abundance of rock flour is deemed proportional to the intensity of glacies advances. Age control for the composite section is provided by combining previously published radiocarbon dates on organics, U/Th dates on ostracode shells, and U/Th dates on saline minerals from nearby Searles Lake correlated to OL92 by pollen. The rock flour record displays three levels of variability: (1) a dominant one of about 20,000 yr related to summer insolation and precipitation; (2) an intermediate one of 3000-5000 yr, perhaps related to North Atlantic Heinrich events; and (3) a minor one of 1000-2000 yr, perhaps related to North Atlantic thermohaline-driven air-temperature variation. ?? 2001 University of Washington.

Quaternary Research↗

Hydrology of the Helena area bedrock, west-central Montana, 1993-98

The Generalized Bedrock Geologic Map of the Helena Area, West-Central Montana (plate 1 in the report) provides an intermediate-scale overview of bedrock in the Helena area. The geologic map has been compiled at a scale of 1:100,000 from the most widely available sources of geologic map information (see index to geologic mapping on pl. 1). That information has been updated by M.W. Reynolds for this report with more recent geologic mapping and field revision of published maps. All well locations and all bedrock units penetrated during drilling have been confirmed on geologic maps at the largest scale available. Source geologic maps are all at scales larger than 1:100,000 scale. Care has been taken to ensure accurate representation of the original geology at the compilation scale. However, positional accuracy of some features might be somewhat diminished at the smaller scale of the base map when compared with the original data source. Also, line thicknesses for contacts and faults necessarily assume a greater width, relative to the real geologic feature, at the scale of the generalized map than on any original map. The map is not intended for large-scale, site-specific detailed planning. Bedrock units throughout the Helena area are generally covered by young surficial deposits such as alluvium, colluvium, glacial debris, or windblown sediment. Thickness of such deposits varies from veneers through which the underlying bedrock is clearly discernible to major thicknesses that conceal all underlying bedrock and structure. Boundaries of major accumulations of surficial deposits are attributed separately from bedrock contacts. These boundaries should not be considered precise at the map scale or at larger scales. Boundaries shown may be less accurate positionally than bedrock contacts and faults because (1) surficial deposits commonly thin to a knife edge; (2) different mappers will interpret the edge differently when drawing a boundary; or (3) the original geologic map maker was concerned principally with bedrock units and structure and thus overlooked, or did not originally map as consistently, some surficial deposits. Veneers of surficial sediment, when saturated, can be local sources of recharge to underlying bedrock. Use of the generalized map to define their distribution does not substitute for site specific mapping of such deposits. Specific knowledge is needed to determine the water-bearing properties of the geologic units at and surrounding a site because the units, including the igneous and metamorphic rocks, have internal differences in stratigraphy, composition, mineralogy and grain size or crystallinity. These differences, together with structural imprints such as faults, folds, and the spacing, orientation, degree of openness of fractures, and extent and type of mineral filling in fractures and faults, all affect the ability of rocks to store and transmit water.

Montana↗

Ground water in the Eola-Amity Hills area, northern Willamette Valley, Oregon

The Eola-Amity Hills area ,comprises about 230 square miles on the west side of the Willamette Valley between Salem and McMinnville, Oreg. The area is largely rural, and agriculture is the principal occupation. Rocks ranging in age from Eocene to Recent underlie the area. The oldest rocks are a sequence more than 5,000 feet thick of marine-deposited shale and siltstone strata, with thin interbeds of sandstone that range in age from Eocene to middle Oligocene. They are widely exposed in and west of the Eola-Amity Hills and underlie younger sedimentary and volcanic rocks throughout the study area. In the Eola-Amity Hills and Red Hills of Dundee, the Columbia River Group, a series of eastward-dipping basaltic lava flows locally of Miocene age, and conformably overlies the marine sedimentary rocks. The Columbia River Group ranges in thickness from less than 1 foot to about 900 feet and has an average thickness of about 200 feet. The formation is exposed in the Eola-Amity Hills and Red Hills of Dundee and, at places, extends to the east beneath younger rocks. Overlying the Columbia River Group and marine sedimentary rocks are nonmarine sedimentary deposits that range in thickness from less than 1 foot, where they lap up (to an altitude of about 200 ft) on the flanks of the higher hills, to several hundred feet along the east margin of the study area. These deposits include the Troutdale Formation of Pliocene age, the Willamette Silt of late Pleistocene age, and alluvium of the Willamette River and its tributaries. The Troutdale Formation and the alluvium of the Willamette River contain the most productive aquifers in the Eola-Amity Hills area. These aquifers, which consist mainly of sand and gravel, generally yield moderate to large quantities of water to properly constructed wells. Basalt of the Columbia River Group yields small to moderate quantities of water to wells, and the marine sedimentary rocks and Willamette Silt generally yield small but adequate quantities of water for domestic and stock supplies. Ground water from the Columbia River Group and nonmarine sedimentary rocks is chemically suitable for irrigation and other uses, as is the water from shallow depths in the marine sedimentary rocks. However, water from depths of more than several hundred feet in the marine sedimentary rocks contains large amounts of chloride and other dissolved mineral constitutents that make it unsuitable for most uses. Samples from three fairly closely spaced wells obtaining water from depth zones of 50 to 77, 191 to 201, and about 2,000 feet contained 172, 1,160, and 26,000 ppm (parts per million) of chloride, respectively. About 6,100 acre-feet of ground water was pumped from wells and withdrawn from springs for various uses during 1964; of this amount about 4,800 acre-feet was used for irrigation. The total volume of ground water withdrawn and put to beneficial use each year is small compared with the amount that discharges naturally by evapotranspiration and through undeveloped seeps and springs. Much of the natural discharge could be intercepted and put to beneficial use by pumping from wells. Major problems affecting the development of ground water in the area include a) uneven areal distribution of permeable rocks, (b) undesirable chemical quality of the ground water locally in the marine sedimentary rocks, and (c) fine sand entering wells that tap the Troutdale Formation and thereby causing loss of well efficiency and costly wear on pumps and water-supply systems.

Water Supply Paper↗

Baked shale and slag formed by the burning of coal beds

The baking and reddening of large masses of strata caused by the burning of coal beds is a striking feature of the landscape in most of the great western coal-bearing areas. The general character and broader effects of the burning have been described by many writers, but the fact that in places enough heat is generated to fuse and thoroughly recrystallize the overlying shale and sandstone has received less attention. Some of the natural slags thus formed simulate somewhat abnormal igneous rocks, but others consist largely of rare and little known minerals. A wide range in the mineral composition of such slags is to be expected, depending on the composition of the original sediment and the conditions of fusion and cooling. These products of purely thermal metamorphism offer a fertile field for petrologic investigation. The writer has observed the effects produced by the burning of coal beds in several localities in Montana, particularly along upper Tongue River in the southern part of the State, in the district lying southeast of the mouth of Bighorn River, and in the Little Sheep Mountain coal field north of Miles City. A number of specimens of the rock formed have been examined under the microscope, though time has not been available for a systematic examination. The writer is greatly indebted to Mr. E. S. Larsen for assistance in the study of some of the minerals.

Montana↗

Lead isotope compositions as guides to early gold mineralization: The North Amethyst vein system, Creede district, Colorado

The North Amethyst vein system, which is hosted by approximately 27 Ma Carpenter Ridge Tuff and approximately 26 Ma Nelson Mountain Tuff, has two mineral associations separated by brecciation and sedimentation in the veins. The early association consists of quartz, rhodonite, hematite, magnetite, electrum (Au (sub 0.3-0.5) Ag (sub 0.7-0.5)) , and Mn carbonate, Au-Ag sulfide, Ag sulfosalt, and base metal sulfide minerals. The later mineral association cuts the Mn- and Au-bearing assemblages and consists of quartz, calcite, sericite, chlorite, hematite, adularia, fluorite, base metal sulfides, and Ag-bearing tetrahedrite.Our detailed studies show that the Pb isotope compositions of paragenetically early galenas associated with Au-rich mineralization in the North Amethyst vein system are relatively unradiogenic ( 206 Pb/ 204 Pb: 18.826-18.881, 207 Pb/ 204 Pb: 15.588-15.602, and 208 Pb/ 204 Pb: 37.790-37.926) compared to Pb isotope compositions of galenas formed later at about 25 Ma during Ag and base metal mineralization ( 206 Pb/ 204 Pb: 19.041-19.115, 207 Pb/ 204 Pb: 15.627- 15.672, and 208 Pb/ 204 Pb: 37.829-38.057). New Pb isotope data for the central and southern parts of the Creede district, which are located 5 to 7 km south of the North Amethyst area, agree with the results of a regional study by Doe et al. (1979) that included five samples from the main part of the Creede district. Galenas and adularia from the central and southern Creede district and galenas from the Bondholder district, 7 km north of the North Amethyst area, are similar to the Pb isotope compositions of galenas formed later in the North Amethyst area during Ag and base metal mineralization. Galenas from the Alpha-Corsair vein, which was mined for Ag prior to 1910, are isotopically similar to galenas associated with North Amethyst Au-stage mineralization. This isotopic similarity suggests that unexplored segments of the Alpha-Corsair structure may have the same mineralogy as the North Amethyst Au stage; thus, the Alpha-Corsair structure has the potential for high gold contents.Pb isotope compositions from the late stage of the North Amethyst vein system and from the Bondholder and central and southern Creede mining districts are more radiogenic than the host volcanic rocks of the central cluster of the San Juan volcanic field. Our Pb isotope results indicate that early Au mineralization of the North Amethyst area may represent the product of an older and relatively local hydrothermal system distinct from that of the younger base metal and Ag mineralization found throughout the region. Fluids that deposited Au minerals may have derived their Pb isotope composition by a greater degree of interaction with shallow, relatively less radiogenic volcanic wall rocks. The younger, base metal and Ag-rich mineralization that overprints the Au mineralization in the North Amethyst area clearly has a more radiogenic isotopic signature, which implies that the later mineralization derived a greater component of its Pb from Proterozoic source rocks, or sediments derived from them.Paragenetically early sulfide-rich vein assemblages have the least radiogenic galenas and generally also have the highest Au contents. Thus, identification of paragenetically early vein assemblages with relatively unradiogenic Pb isotope compositions similar to those of the North Amethyst area provides an additional exploration tool for Au in the central San Juan Mountains area.

Colorado↗

Thorium and rare earth minerals in the Powderhorn district, Gunnison County, Colorado

Thorium has been found since 1949 in at least 33 deposits in an area 6 miles wide and 20 miles long in the Powderhorn district, Gunnison County, Colo. The district is composed largely of pre-Jurassic metamorphic and igneous rocks, which are chiefly if not entirely pre-Cambrian in age. The metamorphic and igneous rocks are overlain by sandstone of the Morrison formation of Jurassic age, and by volcanic rocks of the Alboroto group and Hinsdale formation of Miocene and Pliocene (?) age, respectively. The thorium deposits occur in or near alkalic igneous rocks in which such elements as titanium, rare earths, barium, strontium, and niobium occur in greater-than-average amounts. The greatest mass of the alkalic igneous rocks the Iron Hill composite stoc,- occupies an area of 12 square miles in the southeastern part of the district. The age of the thorium deposits, like that of the alkalic igneous rocks, is not known other than pre-Jurassic. The thorium veins and mineralized shear zones range from a few inches to 18 feet in thickness and from a few feet to 3,500 feet in length. The veins are composed of calcite,.dolomite, siderite, ankerite, quartz, barite, pyrite, sphalerite, galena, goethite,. apatite, alkali feldspar, and many other minerals. The thorium occurs at least partly in thorite or hydrothorite. Sparse xenotime has been tentatively identified in one deposit. Several minerals containing rare earths of the cerium group as major constituents are found in carbonate veins near Iron Hill. Bastnaesite has been identified by X-ray methods, and cerite and synchisite are probably present also.The fluorapatite in some veins and in parts of the carbonate rock mass that occupies 2 square miles in the central part of the Iron Hill complex contains rare earths of the cerium group, generally in amounts of a fraction of a percent of the rock. The radioactivity of the deposits appears to be due almost entirely to thorium and its daughter products The ThO 2 content of selected highgrade samples from the Little Johnnie vein is as much as 4 percent. The ThO 2 content of the veins is generally less than 1 percent, however, and is only 0.05 to 0.1 percent in many of the veins studied. The little Johnnie vein, which was mapped in detail, can be traced discontinuously for a distance of more than 3,500 feet. The thoriumbearing material occurs as irregular veinlets and thin films introduced into the fault zone. The mineralized shear zone ranges from less than 6 inches to 5 feet in thickness. Near its west end the vein is broken by many faults in a zone that marks the edge of a roughly circular fault block, 1 1/2. miles in diameter, that has dropped 1,000 feet or more since the deposition of Miocene volcanic-rocks that now floor the Milkranch basin.

Colorado↗

The Rôle of volatiles in the formation of Virginia titanium deposits

The feldspathic rock with which the titanium deposits of Virginia are associated appears to be an anorthosite, although the plagioclase is somewhat more sodic than in normal anorthosites. That is, this rock shows evidence of having been introduced as a mush‐like mass of crystals and intersititial magma, and of undergoing very thorough crushing during introduction. This rook was later very thoroughly altered by hydrothermal solutions which migrated through the fractures in the feldspar rook and new minerals including the titanium minerals—rutile and ilmenite—were introduced. The elements introduced into the feldspathic rock ware TiO 2 FeO, MgO, P 2 O 5 , and F. The other elements that went into the formation of new minerals were derived from the feldspar originally present. There was a distinct order in the abstraction of the introduced elements from the carrying solutions, as shown by the zonal relatione of the secondary minerals. Ferrous iron was abstracted first in the formation of the ferromagnesian silicates and ilmenite. Magnesium and titanium, in the absence of iron, traveled farther from the source of the solutions and deposited rutile and magnesian silicates. At greater distances most of the introduced elements had been abstracted from the solutions but notwithstanding this the feldspar was extensively altered, but without any marked changes between the chemical composition of the original feldspar rook and the resulting altered rook. ©1934. American Geophysical Union. All Rights Reserved.

Virginia↗

Reconnaissance examination of the uranium deposits northeast of Winston, Broadwater County, Montana

Anomalous radioactivity and a yellow secondary uranium mineral tentatively identified as carnotite have been found in Tertiary sedimentary rocks about 3 miles northeast of Winston, Mont. The uranium is in tuffs and tuffaceous shales and particularly in beds rich in organic matter. Carnotite(?) was identified from three localities, principally coating fractures but in places part replacing organic material, and anomalous radioactivity without recognizable uranium minerals has been detected at four localities. Six of the seven localities are at approximately the same stratigraphic horizon. The deposits are virtually unexplored and consequently their size and grade are not known. Selected specimens assay as high as 0.36 percent eU. Exploitable deposits of uranium may be found in this area, as well as in similar areas of western Montana that are underlain by Tertiary tuffaceous rocks.

Trace Elements Memorandum↗

Carbon, hydrogen, and oxygen isotope studies of the regional metamorphic complex at Naxos, Greece

At Naxos, Greece, a migmatite dome is surrounded by schists and marbles of decreasing metamorphic grade. Sillimanite, kyanite, biotite, chlorite, and glaucophane zones are recognized at successively greater distances from the migmatite dome. Quartz-muscovite and quartz-biotite oxygen isotope and mineralogie temperatures range from 350 to 700°C. The metamorphic complex can be divided into multiple schist-rich (including migmatites) and marblerich zones. The δ 18 O values of silicate minerals in migmatite and schist units and quartz segregations in the schist-rich zones decrease with increase in metamorphic grades. The calculated δ 18 O H2O values of the metamorphic fluids in the schist-rich zones decrease from about 15‰ in the lower grades to an average of about 8.5‰ in the migmatite. The δD values of OH-minerals (muscovite, biotite, chlorite, and glaucophane) in the schist-rich zones also decrease with increase in grade. The calculated δD H2O values for the metamorphic fluid decrease from −5‰ in the glaucophane zone to an average of about −70‰ in the migmatite. The δD values of water in fluid inclusions in quartz segregations in the higher grade rocks are consistent with this trend. Theδ 18 O values of silicate minerals and quartz segregations in marble-rich zones are usually very large and were controlled by exchange with the adjacent marbles. The δD values of the OH minerals in some marble-rich zones may reflect the value of water contained in the rocks prior to metamorphism. Detailed data on 20 marble units show systematic variations of δ 18 O values which depend upon metamorphic grade. Below the 540°C isograd very steep δ 18 O gradients at the margins and large δ 18 O values in the interior of the marbles indicate that oxygen isotope exchange with the adjacent schist units was usually limited to the margins of the marbles with more exchange occurring in the stratigraphic bottom than in the top margins. Above the 540°C isograd lower δ 18 O values occur in the interior of the marble units reflecting a greater degree of recrystallization and the occurrence of Ca-Mg-silicates. Almost all the δ 13 C values of the marbles are in the range of unaltered marine limestones. Nevertheless, the δ 13 C values of most marble units show a general correlation with δ 18 O values. The CO 2 H 2 O "> CO 2 H 2 O mole ratio of fluid inclusions in quartz segregations range from 0.01 to 2. Theδ 13 C values of the CO 2 range from −8.0 to 3.6‰ and indicate that at some localities CO 2 in the metamorphic fluid was not in carbon isotopic equilibrium with the marbles.

Geochimica et Cosmochimica Acta↗

"Ribbon rock", an unusual beryllium-bearing tactite

The beryllium deposits at Iron Mountain, near the northern end of the Sierra Cuchillo in Sierra and Socorro Counties, New Mexico, are unusual products of contact metamorphism. They occur in irregular bodies of tactile formed by replacement of Paleozoic limestone, generally at or near contacts with small intrusive masses of rhyolite, aplite, and fine-grained granite. The metamorphism took place in mid-Tertiary time. Beryllium is present chiefly in the complex silicate minerals helvite and danalite, and is a minor constituent of the garnet grossularite, a boron-bearing idocrase, and chlorite. These minerals are known to occur in noteworthy concentrations in only one type of rock, a peculiar rhythmically layered variety of tactile to which the name "ribbon rock" is given. The structure of such tactite is very conspicuous, and appears in section as thin, finely crenulated bands of magnetite alternating with similar bands of silicate minerals and finely crystalline fluorite. Concentric banding about fluorite-rich pod-like masses is common. Bodies of "ribbon rock" range in size from inch-thick lenses to large masses amounting to thousands of tons; most appear to have been formed along contacts between re-crystallized limestone and massive magnetite-andradite tactite, chiefly by replacing fluids penetrating the limestone from fractures. The layered structure is interpreted as a diffusion effect.The formation of massive and "ribbon rock" tactites can be traced through a range of falling temperature from a stage characterized by deposition from iron-rich vapors to a stage in which hydrothermal solutions were dominant. Both vapors and liquids appear to have been acid. Reducing conditions undoubtedly existed during the latter part of the hydrothermal stage. The occurrence of beryllium in "ribbon rock," but not in typical massive tactite, may signify that its compounds in deposits at or near intrusive contacts are confined to rocks of hydrothermal origin. The occurrence of "ribbon rock" is suggested as a potentially useful clue for recognition of beryllium-bearing contact deposits elsewhere; at least two other occurrences of what apparently is "ribbon rock" have been described in the literature.

New Mexico↗

Evolution of thought on ore controls in east Tennessee

All early students of the zinc and barite deposits of East Tennessee, noting the geographic coincidence of the principal mining area with complex late Paleozoic geologic structure, concluded that (1) the ore-bearing breccias were produced by Appalachian tectonic forces and that (2) mineralizing solutions gained access through fault-produced channelways. In 1931, Ulrich suggested that the breccias were produced by collapse and fragmentation resulting from solution of the carbonate rocks. This idea was promptly rejected by most geologists, and for the next 15 years nearly all papers on these deposits contained refutations of Ulrich's hypothesis and "proof" of the late Paleozoic tectonic origin of the breccias. Recognition by Odell in 1950 of a spatial association between thinning of the lime-stone zone of the Kingsport Formation and the presence of ore bodies, plus the observation that all identifiable blocks in the breccias were displaced downward as much as 30 to 50 feet, led him to suggest that foundering of the rocks over solution-thinned zones produced the breccias. Hydrothermal fluids, rather than ordinary ground water, were thought to be the dissolving agent.Kendall, in 1960, described a stratified "varved" matrix with detrital sphalerite grains in many breccias at Jefferson City, in which lamination is parallel to bedding of the host Kingsport Formation, indicating that both brecciation and mineralization occurred while the rocks were horizontal. Ruskell about 1960 pointed out the similarity between cross sections of southwest Wisconsin ore bodies and those of East Tennessee when the latter were rotated to a horizontal position. Detailed studies of the post-Knox unconformity led to recognition of a paleokarst topography of considerable relief developed on this surface. Regional stratigraphic studies of the Knox Group by Harris demonstrated the probability of pre-Middle Ordovician exposure of the Kingsport somewhere to the north or northwest, providing a recharge area for ground waters at that time. Detailed mapping of ore bodies, barren areas, and related structures by the mining-company geologists, plus application of the principles of ground-water hydrology and rock mechanics, has led to the theory, generally accepted in the district, of solution-collapse origin of the breccias, probably during Ordovician time.

Tennessee↗

"Sour gas" hydrothermal jarosite: Ancient to modern acid-sulfate mineralization in the southern Rio Grande Rift

As many as 29 mining districts along the Rio Grande Rift in southern New Mexico contain Rio Grande Rift-type (RGR) deposits consisting of fluorite-barite??sulfide-jarosite, and additional RGR deposits occur to the south in the Basin and Range province near Chihuahua, Mexico. Jarosite occurs in many of these deposits as a late-stage hydrothermal mineral coprecipitated with fluorite, or in veinlets that crosscut barite. In these deposits, many of which are limestone-hosted, jarosite is followed by natrojarosite and is nested within silicified or argillized wallrock and a sequence of fluorite-barite??sulfide and late hematite-gypsum. These deposits range in age from ???10 to 0.4 Ma on the basis of 40Ar/39Ar dating of jarosite. There is a crude north-south distribution of ages, with older deposits concentrated toward the south. Recent deposits also occur in the south, but are confined to the central axis of the rift and are associated with modern geothermal systems. The duration of hydrothermal jarosite mineralization in one of the deposits was approximately 1.0 my. Most ??18OSO4-OH values indicate that jarosite precipitated between 80 and 240 ??C, which is consistent with the range of filling temperatures of fluid inclusions in late fluorite throughout the rift, and in jarosite (180 ??C) from Pen??a Blanca, Chihuahua, Mexico. These temperatures, along with mineral occurrence, require that the jarosite have had a hydrothermal origin in a shallow steam-heated environment wherein the low pH necessary for the precipitation of jarosite was achieved by the oxidation of H2S derived from deeper hydrothermal fluids. The jarosite also has high trace-element contents (notably As and F), and the jarosite parental fluids have calculated isotopic signatures similar to those of modern geothermal waters along the southern rift; isotopic values range from those typical of meteoric water to those of deep brine that has been shown to form from the dissolution of Permian evaporite by deeply circulating meteoric water. Jarosite ??34S values range from -24??? to 5???, overlapping the values for barite and gypsum at the high end of the range and for sulfides at the low end. Most ??34S values for barite are 10.6??? to 13.1???, and many ??34S values for gypsum range from 13.1??? to 13.9??? indicating that a component of aqueous sulfate was derived from Permian evaporites (??34 S=12??2???). The requisite H2SO4 for jarosite formation was derived from oxidation of H2S which was likely largely sour gas derived from the thermochemical reduction of Permian sulfate. The low ??34S values for the precursor H2S probably resulted from exchange deeper in the basin with the more abundant Permian SO42- at ???150 to 200 ??C. Jarosite formed at shallow levels after the pH buffering capacity of the host rock (typically limestone) was neutralized by precipitation of earlier minerals. Some limestone-hosted deposits contain caves that may have been caused by the low pH of the deep basin fluids due to the addition of deep-seated HF and other magmatic gases during periods of renewed rifting. Caves in other deposits may be due to sulfuric acid speleogenesis as a result of H2S incursion into oxygenated groundwaters. The isotopic data in these "sour gas" jarosite occurrences encode a record of episodic tectonic or hydrologic processes that have operated in the rift over the last 10 my. ?? 2004 Elsevier B.V. All rights reserved.

Chemical Geology↗

Using mineral geochemistry to decipher slab, mantle, and crustal input in the generation of high-Mg andesites and basaltic andesites from the northern Cascade Arc

To better understand the role of slab melt in the petrogenesis of North Cascades magmas, this study focuses on petrogenesis of high-Mg lavas from the two northernmost active volcanoes in Washington. High-Mg andesites (HMA) and basaltic andesites (HMBA) in the Cascade Arc have high Mg# [molar Mg/(Mg+Fe 2+ )] relative to their SiO 2 contents, elevated Nd/Yb, and are Ni- and Cr-enriched. The rock units examined here include the Tarn Plateau HMBA (51.8–54.0 wt% SiO 2 , Mg# 68–70) and Glacier Creek HMA (58.3–58.7 wt% SiO 2 , Mg# 63–64) from the Mount Baker Volcanic Field, and the Lightning Creek HMBA (54.8–54.6 SiO 2 , Mg# 69–73) from Glacier Peak. This study combines major and trace element compositions of minerals and whole rocks to test several petrogenetic hypotheses and to determine which, if any, are applicable to North Cascades HMA and HMBA. In the Tarn Plateau HMBA, rare earth element (REE) equilibrium liquids calculated from clinopyroxene compositions have high Nd/Yb that positively correlates with Mg#. This correlation suggests an origin similar to that proposed for Aleutian adakites, where intermediate, high Nd/Yb slab-derived melts interact with the overlying mantle to become Mg-rich, and subsequently mix with low Nd/Yb, mantle-derived mafic magmas with lower Mg#. In the Glacier Creek HMA, elevated whole-rock MgO and SiO 2 contents resulted from accumulation of xenocrystic olivine and differentiation processes, respectively, but the cause of high Nd/Yb is less clear. However, high whole-rock Sr/P (fluid mobile/fluid immobile) values indicate a mantle source that was fluxed by an enriched, hydrous slab component, likely producing the observed high Nd/Yb REE signature. The Lightning Creek HMBA is a hybridized rock unit with at least three identifiable magmatic components, but only one of which has HMA characteristics. Cr and Mg contents in Cr-spinel and olivine pairs in this HMA component suggest that its source is a strongly depleted mantle, and high whole-rock Sr/P values indicate mantle melting that was induced through hydration, likely adding the component responsible for the observed high Nd/Yb REE pattern. The elevated SiO 2 contents (54.6 wt%) of the HMA component resulted from differentiation or high degrees of partial melting of ultramafic material through the addition of H 2 O. Therefore the Lightning Creek HMBA is interpreted to have originated from a refractory mantle source that underwent melting through interaction with an enriched slab component. Our results indicate that in addition to slab-derived fluids, slab-derived melts also have an important role in the production of HMA and HMBA in the north Cascade Arc.

American Mineralogist↗