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Evidence for organic and igneous carbon sources in the Mesoproterozoic Adirondack Highlands graphite district, New York

This study examined the origin of graphite mineralization in the Mesoproterozoic Adirondack Highlands. Flake graphite was mined from the historic mining district around Ticonderoga, New York, USA, from the 1850s to the 1920s. Most of the production and reserves from the district are disseminated graphite from feldspathic quartz schists (e.g., Dixon-American Graphite Co. mine, Faxon property, Flake Graphite Company). Protolith sediments of the schists were deposited in the Trans-Adirondack backarc basin at ca. 1.25 Ga and were metamorphosed to high grade at 1.18–1.15 Ga during the accretionary Shawinigan orogeny and at 1.09–1.02 Ga during the Ottawan phase of the Grenvillian orogeny. Major elements and carbon isotopes of graphite from schists (δ 13 C = −28.1‰ to −5.4‰ relative to Vienna Peedee belemnite) are consistent with derivation from organic carbon in protolith sandstones that devolatilized during metamorphism. Some small mines and prospects in the district mined graphitic calcite marbles and clinopyroxene ± scapolite skarns associated with a pegmatite suite dated by U-Pb in zircon to 1.04–1.01 Ga (e.g., Lead Hill and Crown Point deposits), and rare graphite veins are observed at several deposits. Hydrothermal flake graphite from pegmatites, skarns, and veins are distinct from graphite in schist-hosted deposits and have δ 13 C values that cluster around −7‰ to −5‰, consistent with deposition from igneous CO 2 . Covariation of carbon and oxygen stable isotopes and U-Pb zircon geochronology are not compatible with precipitation from fluids derived from country rock metapelites or marbles. Some graphite districts elsewhere show compelling evidence for remobilization and redeposition of sedimentary-derived carbon as hydrothermal graphite, sometimes as thick veins producing world-class, high-grade deposits. In the Adirondacks, there is evidence for two generations of graphite mineralization with distinct carbon sources: syngenetic graphite with an organic origin in Shawinigan quartz schists and epigenetic graphite with an igneous origin in Ottawan skarns and pegmatites.

New York↗

Hydrogeologic structure of the Newark Basin, Pennsylvania, from borehole geophysical logs

The Brunswick and the underlying Lockatong Formations are comprised of littrifled Mesozoic sediments that constitute part of the Newark Basin in southeastern Pennsylvania (USA). These fractured rocks form an important regional aquifer that consists of gmdational sequences of shale, siltstone, and sandstone, with fluid transport occurring primarily in fractures. An extensive suite of geophysical logs was obtained in seven wells located at the borough of Iamsdale, PA in order to characterize the areal hydrogeologic system. Analyses of these data indicate that the aquifer can be separated into two distinct structural domains which may, in turn, reflect different mechanical responses to basin bxtension: (1) In the shallow zone above 125 m, the dominant fmcucre population consists of gertfly dipping bedding-plane partings that strike N46°E and dip to the NW at about 11°. Fluid flow is concentrated within the upper 80 m and transmissivities rapidly diminish in magnitude with depth. (2) The zone below 125 m marks the appearance of numerous steeply dipping fractures that are orthogonal to the bedding plane features, striking subparallel at N227°E but dipping sharply to the SE at 77°. This secondary set of fractures is associated with a reasonably thick (= 60 m) high-resistivity, low- transmissivity sandstoned siltstone unit that is abruptly terminated by a thin shale bed at a depth of 190 m. This lower contact effectively delineates the aquifer's vertical extent and the observed lack of hydraulic productivity with increasing depth may be associated with the gradational transition into the Lockatong Formation.

Pennsylvania↗

Rapid cooling rates at an active mid-ocean ridge from zircon thermochronology

Oceanic spreading ridges are Earth's most productive crust generating environment, but mechanisms and rates of crustal accretion and heat loss are debated. Existing observations on cooling rates are ambiguous regarding the prevalence of conductive vs. convective cooling of lower oceanic crust. Here, we report the discovery and dating of zircon in mid-ocean ridge dacite lavas that constrain magmatic differentiation and cooling rates at an active spreading center. Dacitic lavas erupted on the southern Cleft segment of the Juan de Fuca ridge, an intermediate-rate spreading center, near the intersection with the Blanco transform fault. Their U–Th zircon crystallization ages (29.3 − 4.6 + 4.8 ka; 1σ standard error s.e.) overlap with the (U–Th)/He zircon eruption age (32.7 ± 1.6 ka) within uncertainty. Based on similar 238 U− 230 Th disequilibria between southern Cleft dacite glass separates and young mid-ocean ridge basalt (MORB) erupted nearby, differentiation must have occurred rapidly, within ~ 10–20 ka at most. Ti-in-zircon thermometry indicates crystallization at 850–900 °C and pressures > 70–150 MPa are calculated from H 2 O solubility models. These time-temperature constraints translate into a magma cooling rate of ~ 2 × 10 − 2 °C/a. This rate is at least one order-of-magnitude faster than those calculated for zircon-bearing plutonic rocks from slow spreading ridges. Such short intervals for differentiation and cooling can only be resolved through uranium-series ( 238 U– 230 Th) decay in young lavas, and are best explained by dissipating heat convectively at high crustal permeability.

Juan de Fuca ridge and the Blanco transform fault ↗

Geology of the Quartz Creek Pegmatite District, Gunnison County Colorado

The Quartz Creek pegmatite district includes an area about 29 square miles in the vicinity of Quartz Creek in Gunnison County,. Colo. This area contains 1,803 pegmatites that are intruded into pre-Cambrian rocks. The rocks exposed in the district range in age from pre-Cambrian to Recent. The oldest pre-Cambrian rocks are chiefly quartzites interbedded with a few arkoses and conglomerates. These rocks are surrounded by more abundant hornblende gneiss and tonalite. A small body of biotite tonalite was intruded and two thin layers of dacitic pillow lava were extruded into this series. The hornblende gneiss and tonalite have the same composition and differ only in texture. The older material (hornblende gneiss) has a well-marked lineation, whereas the younger (tonalite) is equigranular. Subsequently, a large body of quartz monzonite was intruded along the northern boundary of the mapped area. Later, coarse-grained granite was intruded into the southern part of the area. Dikes of fine-grained granite cut the coarse-grained variety. The last period of intrusive activity in pre-Cambrian time is marked by a large number of pegmatites. The pre-Cambrian rocks were tilted and eroded, and the flatlying Jurassic Morrison formation was deposited on the irregular surface. This formation is conformably overlain by the Cretaceous Dakota sandstone. Faulting produced a vertical offset of 410 feet in the Mesozoic sediments along the only large fault in the area. At the end of Mesozoic time there was another period of erosion. Tertiary (?) tuff is exposed in small, scattered areas in the southern part of the district. It overlies both the Dakota sandstone and pre-Cambrian formations. Glacial till occurs along the edges of Quartz Creek and Wood Gulch. Quaternary alluvium fills the valley bottoms. Although the composition of the country rock has little effect on the shape of the pegmatites, the foliation imposed on this rock has a localizing effect and in part controls the ultimate shape of pegmatites. Zoned and related internal structures are not well developed in the pegmatites of this region. Many of the pegmatites are homogeneous and those that are zoned usually contain a large wall zone and small discontinuous cores. In addition to the more common homogeneous and zoned pegmatites, 7 percent of the pegmatites show a layered structure of textural and mineralogical units not repeated on the opposite side of the pegmatite. Other internal structural units include pegmatites which vary in composition along strike, multiple or “line-rock pegmatites” and fracture fillings. The mineralogy of the pegmatites is described in detail. Specific attention was given to most of the 27 observed minerals. A study of the index of refraction of 439 specimens of plagioclase showed that the variation from zone to zone and layer to layer is minor and that there is no systematic variation in respect to the entire district. No correlation could be found between the refractive index of plagioclase in the pegmatites and the type country rock, or the presence of various accessory minerals. Index of refraction determinations on 95 specimens of muscovite showed no constant variation from wall zone to core or from layer to layer. Curved muscovite has identical optical properties with the flat variety. The index of refraction was determined for 189 beryl specimens. The beryl in the pegmatites containing only a wall zone and a core showed no difference between zones, but in pegmatites that have intermediate zones, the indices of refraction of the beryl showed an inward increase in the alkali content from the contact. Beryl occurs with almost all of the pegmatite minerals and is not restricted in its mineral associations. Tourmaline, except the black variety, is associated with lepidolite. Dark green and blue tourmaline is found in the outer zones of pegmatites containing lepidolite, and the pink and light green varieties are found in direct contact with lepidolite. Lepidolite occurs in aggregates of fine grains, in flat plates, and in curved plates; the three varieties are optically identical. The lighter-colored varieties have higher indices of refraction and contain less lithia than the darker varieties. In addition, the occurrence of the following minerals is described in detail: perthite, quartz, martite, biotite, garnet, columbite-tantalite, monazite, microlite, topaz, gahnite, allanite, and an unidentified mineral. The lack of alteration in the wall rocks adjacent to the pegmatites is interpreted as indicating that the original pegmatite magma did not have an excess of materials such as B, OH-, and P that are needed to form alteration minerals. Because of their low concentration, the above materials were available only in the pegmatitic magma during its crystallization. Pegmatites that contain the rare minerals such as beryl, tourmaline, curved muscovite, biotite, magnetite, monazite, columbite-tantalite, cleavelandite, topaz, lepidolite, and microlite show a grouping in clusters within the district. Beryl-bearing pegmatites occur most abundantly in hornblende gneiss and are only rarely found in either granite or quartz monzonite. The types of minerals that form in a pegmatite appear to be determined by the character of the material segregated from the original magma and the period in which it segregated. The elements escape at one period and may be from only-a specific pocket in the magma. These liquids tend to form groups of pegmatites in which the later bodies contain a high proportion of volatiles. Inferred reserves of the district are estimated for beryl, scrap mica, both hand-cobbing and milling feldspar, lepidolite, columbite-tantalite, topaz, monazite, and microlite. No sheet mica was found. Reserves are small and transportation costs are high so substantial production of low-priced feldspar and scrap mica will depend on the adoption of economica milling techniques for recovering the large quantities of feldspar available. Beryl is irregularly distributed and its recovery as a byproduct will depend on the establishment of a stable market for feldspar and scrap mica. Lepidolite reserves are small low grade.

Colorado↗

Titanium mineral resources of the western U.S.: An update

Thirteen deposits or districts in the western U.S. have been examined in which titanium mineral resources have been reported or implied. These deposits are of the following general types (in probable order of importance): 1) Cretaceous shoreline placer deposits, 2) silica-sand deposits of California, 3) fluvial monazite placers of Idaho, 4) anorthosite related deposits, and 5) clay and bauxite deposits of the northwestern U.S. Relative to previous reports, this one shows some greater and some lesser resources (table 1). In any case, titanium-mineral resources of the western U.S. (west of 103° longitude) remain modest at world scale except as unconventional (especially perovskite) and by-product (especially porphyry) resources. Some deposits, however, have enhanced value to the titanium explorationist for the geologic relations they illustrate. Among the new conclusions are: a) Loci of Cretaceous shoreline placers form linear patterns, nested as a function of age, that can be traced for thousands of kilometers, permitting focused exploration in whole new mountain ranges. b) Medial hematite-ilmenite solid-solution, which is highly magnetic, is a major carrier of TiO 2 values in the Cretaceous deposits of Wyoming. This phase was previously thought to be relatively rare. c) Regressive shoreline placer deposits in indurated Cretaceous sequences expose intricate facies relations, such as the construction of shoreface sequences by long-shore drift over tidal-channel fill, without much loss of paleogeographic information. d) Due to deep weathering, virtually every Eocene sediment that accumulated in the Ione basin at the foot of the Sierra Nevada has economic value, permitting recovery of altered ilmenite and zircon along with silica, clay, coal, and gold. Ilmenite is most abundant in newly recognized shoreline sands. e) Upper Tertiary fluvial placers of Idaho formed in and filled fault-bounded basins and thus are far more voluminous than deposits in the modern valley system. Previously reported resources are thus far too low. f) Mafic igneous rocks of Proterozoic age near Bagdad, Arizona are of ophiolitic affinity, but contain nelsonitic ilmenite enrichments associated with anorthositic layers.

Open-File Report↗

Glaciers of Glacier National Park

Glacier National Park derives its name and much of its interest from the presence of many small glaciers. Very much of the grandeur of its wonderful Alpine scenery, the final sculpturing of the great mountain valleys and of the amphitheaters at their heads, and the production of the basins of its many beautiful lakes are due to the action of the more extended glaciers of the past. There are in the park about 90 small glaciers ranging in size from Blackfeet Glacier, with its 3 square miles of ice, down to masses but a few acres in extent yet exhibiting the characteristics of true glaciers. The most easily accessible of these from the beaten trails are the Blackfeet and Sperry Glaciers and the small glaciers at Iceberg Lake and at Ahern Pass. Some of the others can be reached by tourists who are willing to undergo the exertions of mountain climbing. Among these are Grinnell, Chaney, Shepard, Vulture, and Carter Glaciers, and one or two at Brown Pass. (See map facing page 17.) After examining these features one can easily picture to himself, as he looks down the valleys, the great rivers of ice which in ages past cascaded from the cliffs below the upper cirques, converged as tributaries from the many branch valleys, and united in great trunk glaciers. In imagination lie can see these great glaciers many hundreds of feet ill depth filling the great mountain volleys from side to side, and deploying thence upon the bordering plains. lie seems to see these mighty engines plucking away the rock ribs of the mountains, smoothing, grinding, and polishing the irregularities and sweeping away the debris to be spread on the plains below. These glaciers developed and extended three times and, after each development, the congealed masses melted away on the return of milder climatic conditions, until at length only the small cliff glaciers of the present day are left lurking in the protected recesses at the heads of the capacious valleys. Many of the rock-walled amphitheaters are no longer occupied by ice, but from all there issue streams fed by the melting snow or ice. These plunge over the cliffs in beautiful foaming cascades and rush on down the mountain gorges. The melting glaciers left many inclosed basins large and small, and in these the waters rest a while and mirror in their crystal depths the dark green of the surrounding forests, the rich colors of the rugged mountain walls, and the deep blue of the cloud-flecked sky. On again from lake to lake the waters flow and finally start down their long courses to the sea to merge at length with the chill waters of Hudson Bay, the balm t ides of the Gulf of Mexico, or the rolling billows of the Pacific. Compared in size with the great glaciers of Alaska the glaciers of Glacier National Park are insignificant. They are even surpassed in size by those of the Alps, of the Canadian Rockies, and of Mount Rainier, Washington. They are, however, thought small, among the best examples of this interesting type of phenomena now existing in the United States. They have also a splendid setting in magnificent Alpine scenery, unsurpassed in grandeur anywhere. Hidden away in the recesses of the mighty mountain ranges these rare and wonderful features form a climax to many of the interesting trips open to the tourist.

Montana↗

Late Cenozoic Climate History of the Ross Embayment from the AND-1B Drill Hole: Culmination of Three Decades of Antarctic Margin Drilling

Because of the paucity of exposed rock, the direct physical record of Antarctic Cenozoic glacial history has become known only recently and then largely from offshore shelf basins through seismic surveys and drilling. The number of holes on the continental shelf has been small and largely confined to three areas (McMurdo Sound, Prydz Bay, and Antarctic Peninsula), but even in McMurdo Sound, where Oligocene and early Miocene strata are well cored, the late Cenozoic is poorly known and dated. The latest Antarctic geological drilling program, ANDRILL, successfully cored a 1285-m-long record of climate history spanning the last 13 m.y. from subsea-floor sediment beneath the McMurdo Ice Shelf (MIS), using drilling systems specially developed for operating through ice shelves. The cores provide the most complete Antarctic record to date of ice-sheet and climate fluctuations for this period of Earth’s history. The >60 cycles of advance and retreat of the grounded ice margin preserved in the AND-1B record the evolution of the Antarctic ice sheet since a profound global cooling step in deep-sea oxygen isotope records ~14 m.y.a. A feature of particular interest is a ~90-m-thick interval of diatomite deposited during the warm Pliocene and representing an extended period (~200,000 years) of locally open water, high phytoplankton productivity, and retreat of the glaciers on land.

Open-File Report↗

Time-slice maps showing age, distribution, and style of deformation in Alaska north of 60° N.

The structural architecture of Alaska is the product of a complex history of tectonism that occurred along the Cordilleran and Arctic margins of North America through interactions with ancient and modern ocean plates and with continental elements derived from Laurentia, Siberia, and Baltica. To unravel the tectonic history of Alaska, we constructed maps showing the age, distribution, structural style, and kinematics of contractional and penetrative extensional deformation in Alaska north of latitude 60° N. at a scale of 1:5,000,000. These maps use the Geologic Map of the Arctic (Harrison and others, 2011) as a base map and follow the guidelines in the Tectonic Map of the Arctic project (Petrov and others, 2013) for construction, including use of the International Commission on Stratigraphy time scale (Cohen and others, 2013) divided into 20 time intervals. We find evidence for deformation in 14 of the 20 time intervals and present maps showing the known or probable extent of deformation for each time interval. Maps and descriptions of deformational style, age constraints, kinematics, and information sources for each deformational episode are discussed in the text and are reported in tabular form. This report also contains maps showing the lithologies and structural geology of Alaska, a terrane map, and the distribution of tectonically important units including post-tectonic sedimentary basins, accretionary complexes, ophiolites, metamorphic rocks. These new maps show that most deformational belts in Alaska are relatively young features, having developed during the late Mesozoic and Cenozoic. The oldest episode of deformation recognized anywhere in Alaska is found in the basement of the Farewell terrane (~1.75 Ga). Paleozoic and early Mesozoic deformational events, including Devonian deformation in the Arctic Alaska terrane, Pennsylvanian deformation in the Alexander terrane, Permian deformation in the Yukon Composite (Klondike orogeny) and Farewell terranes (Browns Fork orogeny), Early and Late Jurassic deformation in the Peninsular-Wrangellia terranes, and Early Cretaceous deformation in northern Alaska (early Brookian orogeny) show that within-terrane amalgamation events occurred prior to assembly of Alaska. Widespread episodes of deformation in the Late Cretaceous and early Cenozoic, in contrast, affected multiple terranes, indicating they occurred during or following the time of assembly of most of Alaska. The primary deformational event in northern Alaska was the Late Jurassic and Early Cretaceous (early) Brookian orogeny, which affected most terranes north and west of the early Cenozoic Tintina, Victoria Creek, Kaltag, and Poorman dextral-slip faults in central Alaska. In southern Alaska, formation of the southern Alaska accretionary complex (Chugach, Prince William, Yakutat terranes) and associated magmatism in the Peninsular-Wrangellia terrane began near the Triassic-Jurassic boundary and continued episodically throughout the remainder of the Mesozoic and the Cenozoic. The collision of these terranes with the Farewell and Yukon Composite terranes in central Alaska is recorded by contractional deformation that emanated from the intervening basins in the Late Cretaceous. The boundary between northern and central Alaska is constrained to late Early Cretaceous but is enigmatic and not obviously marked by contractional deformation. Early Cenozoic shortening and transpressional deformation is the most widespread event recorded in Alaska and produced the widespread late Brookian orogenic event in northern Alaska. Middle and late Cenozoic shortening and transpression is significant in southern Alaska inboard of the underthrusting Yakutat terrane at the Pacific margin subduction zone as well as in northeastern Alaska.

Alaska↗

Ground-Water Flow in the Vicinity of the Ho-Chunk Nation Communities of Indian Mission and Sand Pillow, Jackson County, Wisconsin

An analytic element ground-water-flow model was constructed to help understand the ground-water-flow system in the vicinity of the Ho-Chunk Nation communities of Indian Mission and Sand Pillow in Jackson County, Wisconsin. Data from interpretive reports, well-drillers' construction reports, and an exploratory augering program in 2003 indicate that sand and gravel of varying thickness (0-150 feet[ft]) and porous sandstone make up a composite aquifer that overlies Precambrian crystalline rock. The geometric mean values for horizontal hydraulic conductivity were estimated from specific-capacity data to be 61.3 feet per day (ft/d) for sand and gravel, 6.6 ft/d for sandstone, and 12.0 ft/d for the composite aquifer. A ground-water flow model was constructed, the near field of which encompassed the Levis and Morrison Creeks Watershed. The flow model was coupled to the parameter-estimation program UCODE to obtain a best fit between simulated and measured values of ground-water levels and estimated Q50 flow duration (base flow). Calibration of the model with UCODE provided a ground-water recharge rate of 9 inches per year and a horizontal hydraulic conductivity of 13 ft/d for the composite aquifer. Using these calibrated parameter values, simulated heads from the model were on average within 5 ft of the measured water levels. In addition, these parameter values provided an acceptable base-flow calibration for Hay, Dickey, and Levis Creeks; the calibration was particularly close for Levis Creek, which was the most frequently measured stream in the study area. The calibrated model was used to simulate ground-water levels and to determine the direction of ground-water flow in the vicinity of Indian Mission and Sand Pillow communities. Backward particle tracking was conducted for Sand Pillow production wells under two pumping simulations to determine their 20-year contributing areas. In the first simulation, new production wells 6, 7, and 8 were each pumped at 50 gallons per minute (gal/min). In the second simulation, new production wells 6, 7, and 8 and existing production well 5 were each pumped at 50 gal/min. The second simulation demonstrated interference between the existing production well 5 and the new production wells when all were pumping at 50 gal/min.

Scientific Investigations Report↗

The Geysers-Clear Lake geothermal area, California - An updated geophysical perspective of heat sources

The Geysers-Clear Lake geothermal area encompasses a large dry-steam production area in The Geysers field and a documented high-temperature, high-pressure, water-dominated system in the area largely south of Clear Lake, which has not been developed. Both systems have been extensively studied with geophysical techniques, drilling, and geological mapping during the past 20 years. An updated view is presented of the geological/geophysical complexities of the crust in The Geysers-Clear Lake region in order to address key unanswered questions about the heat source and tectonics. Early geophysical interpretations used a gravity low centered in the area between Clear Lake and The Geysers to suggest that a large magma chamber existed at depths starting at about 7 km. This first-order assumption of a large magma chamber expressed in the gravity data was used as a guide in subsequent geophysical and geological interpretations. Drill-hole temperature evidence is strongly suggestive of a shallow, hot-intrusive body, but in this paper the complexities are documented of the geological and geophysical data sets that make it difficult to pinpoint the location of “magma” or hot, solidified intrusive material. Forward modeling, multidimensional inversions, and ideal body analysis of the gravity data, new electromagnetic sounding models, and arguments made from other geophysical data sets suggest that many of the geophysical anomalies have significant contributions from rock property and physical state variations in the upper 7 km and not from ”magma“ at greater depths. Regional tectonic and magmatic processes are analyzed to develop an updated scenario for pluton emplacement that differs substantially from earlier interpretations. In addition, a rationale is outlined for future exploration for geothermal resources in The Geysers-Clear Lake area.

Geothermics↗

Geohydrology of Southeastern Pennsylvania

Rapid population growth in southeastern Pennsylvania has increased the demand for ground water. In an effort to address the increased ground-water needs, a ground-water investigation in a 5,200-square-mile area of southeastern Pennsylvania was initiated. Information on the geohydrologic system of the area and the water-bearing capabilities of 51 geohydrologic units in six physiographic provinces or sections (Coastal Plain, Piedmont Upland, Piedmont Lowland, Gettysburg-Newark Lowland, South Mountain, and Reading Prong) has been summarized. Also included are statistical summaries by geohydrologic unit for well construction and discharge data (according to water use), as well as inorganic and radiochemical ground-water-quality data. Characteristics of the ground-water-flow system in the study area, as well as aquifer hydrologic properties, are related to geology, but can be modified by human development. Ground-water flow in the Coastal Plain Physiographic Province, is through intergranular or primary openings under either unconfined or confined aquifer conditions. Historically, ground-water flowed toward the Delaware and Schuylkill Rivers, but the original flow paths and water quality have been altered significantly by urbanization. In igneous and metamorphic rocks (Piedmont Upland, South Mountain, and Reading Prong), ground-water flows through a network of interconnected secondary openings (fractures, joints, cleavage planes). Ground water in the carbonate rocks (Piedmont Lowland) also flows through a network of secondary openings, but these openings have been enlarged by solution. In the Triassic sedimentary rocks (Gettysburg-Newark Lowland), thin tabular aquifers are separated by much thicker, strata-bound aquitards. The fractured Triassic bedrock forms a very complex, anisotropic, and heterogeneous aquifer with horizontal permeability much greater than vertical permeability. In general, ground-water flow in southeastern Pennsylvania takes place within local flow systems that discharge within days or weeks to adjacent stream valleys or surface-water bodies. Intermediate (South Mountain) and regional (Gettysburg-Newark Lowland) scale systems, however, in which residence times have been measured in months or years discharge to major streams or rivers that are located in different physiographic provinces or sections or tens of miles distant. Well depths, casing lengths, reported yields, and specific capacities can vary significantly by geohydrologic unit, use of well, and topographic setting. Wells drilled in the Weverton and Loudon Formations, undivided, and the Montalto Quartzite Member (South Mountain) have median well and casing lengths of 374 and 130 feet, respectively, significantly greater than in almost every other geohydrologic unit in the study area. Wells drilled in the Peach Bottom Slate and Cardiff Conglomerate, undivided (Piedmont Upland) are typically shallow, with a median well depth of 90 feet. Wells in the Marburg Schist (Piedmont Upland) have the lowest median casing length—5.5 feet. Wells in the Stonehenge Formation (Piedmont Lowland), the most productive unit in the study area, have a median reported yield of 200 gallons per minute and a median specific capacity of 27 gallons per minute per foot. The Cocalico Formation (Piedmont Lowland) is the least productive unit with a median reported well yield of 2.5 gallons per minute and a median specific capacity of 0.01 gallons per minute per foot. In general, high-demand wells are significantly deeper, use significantly more casing, and have significantly greater yields than domestic wells drilled in the same unit. Commonly, wells drilled in valleys will have greater reported yields and specific capacities than wells drilled in the same unit on slopes or hilltops. Except where adversely affected by human activities, the quality of ground water in southeastern Pennsylvania is suitable for most purposes. Yet several water-quality criteria are exceeded in many wells throughout the area. Water from 51 percent of 2,075 wells sampled had a pH higher or lower than the range specified in the U.S. Environmental Protection Agency (USEPA) secondary maximum contaminant level (SMCL). Of water samples analyzed, about 1 percent of 1,623 wells contained concentrations of chloride and 27 percent of 1,624 wells sampled contained concentrations of iron that exceeded the USEPA SMCL. Twenty-seven percent of 1,397 wells sampled contained water with manganese concentrations greater than the USEPA SMCL. Sulfate concentrations in the water of 3 percent of 1,699 wells sampled and total dissolved solids in the water from 10 percent of 1,590 wells sampled exceeded the USEPA SMCL. Concentrations of cadmium, chromium, cyanide, mercury, nickel, radium-226, selenium, and zinc in the water exceeded the USEPA maximum contaminant level (MCL) in less than 5 percent of the 183 to 620 wells sampled. Nine percent of 625 wells sampled contained water with lead concentrations that exceeded the USEPA MCL. Radon concentrations in the water of 92 percent of the 285 wells sampled exceeded the proposed USEPA MCL. Radium-228 in the water of 10 percent of the 240 wells sampled and nitrate in the water of 13 percent of 1,413 wells sampled exceeded the USEPA MCL. Gross-alpha activity in the water was measured only in the Chickies and Harpers Formations of the Piedmont Upland, with 23 percent of the 168 wells sampled exceeding the USEPA MCL.

Water-Resources Investigations Report↗

Geochemistry and geodynamics of a Late Cretaceous bimodal volcanic association from the southern part of the Pannonian Basin in Slavonija (Northern Croatia)

In this paper we present petrological and geochemical information on a bimodal basalt-rhyolite suite associated with A-type granites of Late Cretaceous age from the South Pannonian Basin in Slavonija (Croatia). Basalts and alkali-feldspar rhyolites, associated in some places with ignimbrites, occur in volcanic bodies that are interlayered with pyroclastic and fossiliferous Upper Cretaceus sedimentary rocks. The petrology and geochemistry of the basalts and alkali-feldspar rhyolites are constrained by microprobe analyses, major and trace element analyses including REE, and radiogenic and stable isotope data. Basalts that are mostly transformed into metabasalts (mainly spilites), are alkalic to subalkalic and their geochemical signatures, particularly trace element and REE patterns, are similar to recent back-arc basalts. Alkali-feldspar rhyolites have similar geochemical features to the associated cogenetic A-type granites, as shown by their large variation of Na 2 O and K 2 O (total 8–9%), very low MgO and CaO, and very high Zr contents ranging between 710 and 149 ppm. Geochemical data indicate an amphibole lherzolite source within a metasomatized upper mantle wedge, with the influence of upper mantle diapir with MORB signatures and continental crust contamination. Sr incorporated in the primary basalt melt had an initial 87 Sr/ 86 Sr ratio of 0.7039 indicating an upper mantle origin, whereas the 87 Sr/ 86 Sr ratio for the alkali-feldspar rhyolites and associated A-type granites is 0.7073 indicating an apparent continental crust origin. However, some other geochemical data favour the idea that they might have mainly originated by fractionation of primary mafic melt coupled with contamination of continental crust. Only one rhyolite sample appears to be the product of melting of continental crust. Geological and geodynamic data indicate that the basalt-rhyolite association was probably related to Alpine subduction processes in the Dinaridic Tethys which can be correlated with recent back-arc basins. The difference in geological and isotope ages between the bimodal basalt-rhyolite volcanism with A-type granite plutonism (72 Ma) and the final synkinematic S-type granite plutonism (48 Ma) can be taken as a lifetime of the presumed BARB system of the Dinaridic Tethys. Remnants of this presumed subduction zone can be traced for 300 km along the surrounding northernmost Dinarides.

Pannonian Basin↗

The quartz crystal deposits of western Arkansas

Extensive geological investigations of domestic deposits of quartz crystals were undertaken by the Geological Survey of the United States Department of the Interior in the fall of 1942 in response to the urgent demand for crystals for war purposes. The work was continued throughout 1943 and took survey geologists into some 20 states in which over 1,400 deposits or reports of deposits were examined. Of the numerous highly varied occurrences of quartz examined, only the deposits in western Arkansas, in the Piedmont and Blue Ridge provinces of Virginia, North Carolina and Georgia and the placer quartz of Mokelumne Hill, California, were of sufficient promise to warrant detailed work. Production in 1943 from these areas totaled slightly less than 4 tons of oscillator quartz, over 85 per cent of which came from Arkansas.The Arkansas deposits occur throughout the thick, deformed Paleozoic shales, sandstones, and cherts exposed along the central belt of the Ouachita Mountains. Steeply dipping fractures closely related to the major folds control the deposition of most quartz.Clear quartz is confined largely to the terminal parts of primary crystals, which have developed without disturbance or interference, are commonly elongate parallel to their C axes and are bounded by relatively simple forms. Deposition of silica during and subsequent to the fracturing of crystals resulted in the formation of complex crystals which are characterized by extensive optical twinning and lineage structures, and commonly are bounded by aggregates of the simpler crystal forms. The principal defects in all types of crystals are twinning, smokiness, cavities, solid inclusions and fractures.The Arkansas quartz deposits include veins, sheeted zones and stock-works. They are largely cavity fillings, apparently deposited by rising, attenuated, hydrothermal solutions, at relatively low temperatures and pressures. Minerals associated with the quartz, which constitutes 90 per cent or more of the cavity fillings, include dickite and carbonaceous material, calcite, adularia, and chlorite. The constituents of the cavity fillings could have been derived principally from magmatic sources or more probably from underlying rocks, with small additions from the rocks enclosing the cavities. The complex vein fabrics apparently resulting from intermittent regional deformation during the deposition of the quartz, and certain structural relations of the deposits, indicate that they were formed in the final stages of the Ouachita orogeny, probably in mid-Pennsylvanian time.

Arkansas↗

Quaternary sediment thickness and bedrock topography of the glaciated United States east of the Rocky Mountains

Beginning roughly 2.6 million years ago, global climate entered a cooling phase known as the Pleistocene Epoch. As snow in northern latitudes compacted into ice several kilometers thick, it flowed as glaciers southward across the North American continent. These glaciers extended across the northern United States, dramatically altering the landscape they covered. East of the Rocky Mountains, the ice coalesced into continental glaciers (called the Laurentide Ice Sheet) that at times blanketed much of the north-central and northeastern United States. To the west of the Laurentide Ice Sheet, glaciers formed in the mountains of western Canada and the United States and coalesced into the Cordilleran ice sheet; this relatively smaller ice mass extended into the conterminous United States in the northernmost areas of western Montana, Idaho, and Washington. Throughout the Pleistocene, landscape alteration occurred by (1) glacial erosion of the rocks and sediments; (2) redeposition of the eroded earth materials in a form substantially different from their source rocks, in terms of texture and overall character; and (3) disruption of preexisting drainage patterns by the newly deposited sediments. In many cases, pre-glacial drainage systems (including, for example, the Mississippi River) were rerouted because their older drainage courses became blocked with glacial sediment. The continental glaciers advanced and retreated many times across those areas. During each ice advance, or glaciation, erosion and deposition occurred, and the landscape was again altered. Through successive glaciations, the landscape and the bedrock surface gradually came to resemble their present configurations. As continental ice sheets receded and the Pleistocene ended, erosion and deposition of sediment (for example in stream valleys) continued to shape the landscape up to the present day (albeit to a lesser extent than during glaciation). The interval of time since the last recession of the glaciers is called the Holocene and, together with the Pleistocene, constitutes the Quaternary Period of geologic time; this publication characterizes the three-dimensional geometry of the Quaternary sediments and the bedrock surface that lies beneath. The pre-glacial landscape was underlain mostly by weathered bedrock generally similar in nature to that found in many areas of the non-glaciated United States. Glacial erosion and redeposition of earth materials produced a young, mineral-rich soil that formed the basis for the highly productive agricultural economy in the U.S. midcontinent. Extensive buried sands and gravels within the glacial deposits also provided a stimulus to other economic sectors by serving as high-quality aquifers supplying groundwater to the region’s industry and cities. An understanding of the three-dimensional distribution of these glacial sediments has direct utility for addressing various societal issues including groundwater quality and supply, and landscape and soil response to earthquake-induced shaking. The Quaternary sediment thickness map and bedrock topographic map shown here provide a regional overview and are intended to supplement the more detailed work on which they are based. Detailed mapping is particularly useful in populated areas for site-specific planning. In contrast, regional maps such as these serve to place local, detailed mapping in context; to permit the extrapolation of data into unmapped areas; and to depict large-scale regional geologic features and patterns that are beyond the scope of local, detailed mapping. They also can enhance the reader’s general understanding of the region’s landscape and geologic history and provide a source of information for regional decision making that could benefit by improved predictability of bedrock depth beneath the unconsolidated Quaternary sediments. To enable these maps to be analyzed in conjunction with other types of information, this publication also includes the map data in GIS compatible format.

Scientific Investigations Map↗

Near-solidus melts of MORB + 4 wt% H2O at 0.8 – 2.8 GPa applied to issues of subduction magmatism and continent formation

Experiments on MORB + 4 wt% H 2 O at 0.8–2.8 GPa and 700–950 °C (Liu in High pressure phase equilibria involving the amphibolite–eclogite transformation. PhD dissertation, Stanford University, Stanford, California, 1997; Liu et al. in Earth Planet Sci Lett 143:161–171, 1996) were reexamined for their major and trace element melt compositions and melting relations. Degree of melting diminishes at greater pressures, with corresponding evolution of melt from andesitic at the lowest pressures and hottest temperatures to high-silica rhyolitic at the greatest pressure and coolest temperature. Quartz contributes greatly to the production of near-solidus melts of basaltic eclogite, with the result that melt productivity falls markedly following quartz exhaustion. This limits the extent of melting attainable in the basaltic eclogite portions of sub-arc subducting plates to no more than ~ 2 × the modal wt% quartz in the mafic eclogite protolith. Synthesized residual mineral assemblages lack an epidote-series mineral at temperatures > 750 °C, and as a result, melts from the rutile eclogite and rutile-amphibole eclogite facies have elevated concentrations of light rare earth elements, U, Th, have elevated Ba, K, and Sr, high Sr/Y, and are strongly depleted in Nb, Y, and the heavy rare earth elements. Models of eclogite partial melt reacting with peridotite of the mantle wedge reproduce major and trace element characteristics of parental arc magmas so long as the proportions of infiltrating melt to peridotite are relatively high, consistent with channelized ascent. Melt mass is estimated to increase roughly three- to ten-fold, consistent with H 2 O concentrations of 3–7 wt% in the magmas produced by reaction. Partial melts of subducting basaltic eclogite are predicted to have positive Sr concentration anomalies, relative to Ce and Nd, that persist through melt-peridotite reactions. Primitive arc magmas commonly have positive Sr anomalies, whereas such anomalies are smaller in estimates of the bulk continental crust. Overall, Sr anomalies diminish passing from primitive to more evolved arc volcanic rocks, consistent with extensive mineral-melt differentiation (crystallization, partial remelting) involving plagioclase. On the order of 50 wt% differentiation would be necessary to eliminate Sr positive anomalies, based on geochemical variations in the Cascade and western Aleutian magmatic arcs. Loss to the mantle of cumulates and restites with high Sr anomalies, in abundances broadly equal to the mass of the preserved crust, would be required to form the continents via processes similar to present-day subduction magmatism.

Contributions to Mineralogy and Petrology↗

Significance of a near-source tephra-stratigraphic sequence to the eruptive history of Hayes Volcano, south-central Alaska

Bluffs along the Hayes River valley, 31 km northeast and 40 km downstream from Hayes Volcano, reveal volcanic deposits that shed new light on its eruptive history. Three thick (>10 cm) and five thin (<10 cm) tephra-fall deposits are dacitic in whole rock composition and contain high proportions of amphibole to pyroxene and minor biotite and broadly correlate to Hayes tephra set H defined by earlier investigators. Two basal ages for the tephra-fall sequence of 3,690&plusmn;30 and 3,750&plusmn;30 14 C yr B.P. are also consistent with the Hayes tephra set H timeframe. Distinguishing among Hayes tephra set H units is critical because the set is an important time-stratigraphic marker in south-central Alaska and this section provides a new reference section for Hayes tephra set H. Analysis of Fe-Ti oxide grains in the tephras shows promise for identifying individual Hayes deposits. Beneath the dacitic tephra sequence lies an older, poorly sorted tephra (tephra A) that contains dacite and rhyolite lapilli and whose basal age is 4,450&plusmn;30 14 C yr B.P. Immediately below the tephra-fall sequence (Unit III) lies a series of mass-flow deposits that are rich in rhyodacitic clasts (Unit II). Below Unit II and possibly coeval with it, is a 20&ndash;30 m thick pumiceous pyroclastic-flow deposit (Unit I) that extends to the valley floor. Here informally named the Hayes River ignimbrite, this deposit contains pumice clasts of rhyolite with quartz, sanidine, plagioclase, and biotite phenocrysts, an assemblage that is unique among known Quaternary volcanic products of Hayes and other Alaskan volcanoes. Units I, II, and tephra A of Unit III represent at least two previously unrecognized eruptions of Hayes Volcano that occurred prior to ~3,700 yr B.P. No compositionally equivalent distal tephra deposits correlative with Hayes Volcano rhyodacites or rhyolites have yet been identified, perhaps indicating that some of these deposits are pre-Holocene, and were largely removed by glacial ice during the last ice age. More field and analytical work is needed to further refine the eruptive history of Hayes Volcano.

Alaska↗

Rare-earth element geochemistry of the island-arc volcanic rocks of Rabaul and Talasea, New Britain

The island-arc volcanic rocks of Rabaul and Talasea, New Britain, range in composition from basalt through rhyolite. Rare-earth elements have been determined by mass-spectrometric isotope dilution in 16 samples. Chondrite-normalized rare-earth element patterns are distinct for each volcanic center, but all are relatively flat (Ce/Yb E.F. = 1.1 to 3.0). Within each center, rare-earth element concentrations increase from basalt to dacite, and Eu anomalies become progressively more negative from basalt to dacite (Eu/Eu* = 1.0 to 0.8). Lavas inferred to contain cumulate phenocrysts show positive Eu anomalies (Eu/Eu* of up to 1.2). The observed variations are consistent with fractional crystallization of basalt or basaltic andesite by removal or accumulation of the observed phenocrysts, including olivine, plagioclase, pyroxene, and opaque minerals. Quantitative trace-element models for Talasea lavas indicate precipitation of 50 wt percent of phenocrysts from basalt to produce andesite and an additional 22 wt percent to produce dacite. A total-equilibrium model provides the best approximation to observed concentrations, implying that the process took place at a depth sufficient to allow slow cooling of the magma as precipitation proceeded. The “least fractionated” basalts and basaltic andesites are similar in rare-earth element pattern to those of corresponding type suites in other oceanic-island arcs, implying a widespread uniformity of source and process in the production of each magma type.

Geological Society of America Bulletin↗

Chesapeake Bay impact structure: A blast from the past

About 35 million years ago, a 2-mile-wide meteorite smashed into Earth in what is now the lower Chesapeake Bay in Virginia. The oceanic impact vaporized, melted, fractured, and displaced rocks and sediments and sent billions of tons of water, sediments, and rocks into the air. Glassy particles of solidified melt rock rained down as far away as Texas and the Caribbean. Large tsunamis affected most of the North Atlantic basin. The resulting impact structure is more than 53 miles wide and has a 23-mile-wide, filled central crater surrounded by collapsed sediments. Now buried by hundreds of feet of younger sediments, the Chesapeake Bay impact structure is among the 20 largest known impact structures on Earth. Since its discovery in the early 1990s, scientists have conducted deep drilling and geophysical surveys of the impact structure to find out more about its size, composition, structure, age, and biological effects and to understand its lingering influences on the regional groundwater system. These efforts culminated in the drilling of a 1-mile-deep, continuously sampled corehole in 2005 by an international group of scientists and agencies.

Chesapeake Bay↗