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Controlled induced recharge tests at Kalamazoo, Mich

This article discusses the results of a controlled field testing program, which indicated that definite hydraulic and other advantages may be gained from induced recharging as practiced at Kalamazoo, Michigan. Results include the following: water levels and artesian pressures can be maintained at high stages, the results are lower pumping lifts and substantial reductions in the amount of power used for pumping; the high water levels permit increased rates of withdrawal during periods of peak demand; encroachment of poor quality water from other aquifers is minimized; the surface water induced into the aquifer is filtered naturally through great thicknesses of earth materials; natural underground storage is used to conserve and protect water, which otherwise would flow largely to waste; and, significant supplemental benefits, including flood control, have been derived. The tests demonstrated that it is possible to manipulate the regimen of a complex hydrologic system for definite hydraulic benefits with predictable results. Furthermore with current methods, quantitative evaluations may be made of the effects of induced recharge. The results of the tests, therefore, are applicable in other areas of similar hydrogeologic environments.

Michigan↗

Quantitative method development to determine feed consumption using a dye

Although there are many methods to determine ingestion and absorption of aquafeeds, none exist that are simple, cost-effective, and quantitative and that can mark fish with a long-lasting, visible indicator. In addition to aquafeed development, selective baits are needed that can be used for aquatic invasive species removal efforts, including for Grass Carp Ctenopharyngodon idella . Bait incorporated with a pesticide would allow for selective removal of targeted species. A method to quickly assess multiple bait formulations was developed to expediate development for invasive species management. Incorporation of Sudan Black B (SBB) in aquafeeds at concentrations greater than 75 and 120 mg SBB/kg fish resulted in pigmented external soft tissues of Largemouth Bass Micropterus salmoides and Rainbow Trout Oncorhynchus mykiss , respectively, 24 h after consumption. Visual confirmation of consumption was detectable in the gastrointestinal tract at all concentrations tested (≥10 mg SBB/kg) and quantifiable by absorbance measured at 601 nm from extracted SBB in tissues at concentrations less than those required for visual pigmentation. Although SBB was detectable in multiple tissues, fin and mandible tissues yielded the greatest accuracy in estimating consumption from extracted SBB. Compared with other tissues tested, liver tissue accumulated the highest level of SBB but had the greatest variability, while muscle tissue accumulated little detectable SBB. We used the SBB analytical method to compare consumption of six novel baits that were in the initial developmental stages to produce a palatable bait formulation designed to attract Grass Carp for management control. Overwhelming preference of a rapeseed bait formulation was confirmed using SBB as a tracer of consumption in the laboratory; however, use of SBB under natural conditions may be valuable for answering additional questions. Baits incorporated with SBB allowed for the rapid, simultaneous assessment of multiple formulations and could allow for future refinement of management baits, with results available as quickly as 24–72 h after application.

North American Journal of Aquaculture↗

Studies in the system MgO-SiO2-CO2-H2O(I): The activity-product constant of chrysotile

Chrysotile dissolves congruently in water according to the reaction: Mg 3 Si 2 O 6 ( OH ) 4 c + 5 H 2 O l = 3 Mg aq 2+ + 6 OH aq − + 2 H 4 SiO 4 aq . Experimental determination of the activity-product constant of chrysotile, K chr = [ Mg 2+ ] 3 [ OH − ] 6 [ H 4 SiO 4 aq ] 2 , at 90°C, yields the value of K chr = 10 −49.2 ± 10 0.5 . A synthetic sample and a natural sample from New Idria, California, were used in the determination. Values of K chr were calculated for temperatures ranging from 0°C to 200°C, using the thermochemical data of King et al . (1967) for chrysotile and antigorite, various solubility data for silica, and ionic partial molal heat capacities estimated by the method of criss and Cobble (1964a). K chr is 10 −54.1 at 0°C, rises to a maximum value of 10 −48.5 at approximately 135°C, and is 10 −49.1 at 200°C (all values for the three-phase system, chrysotile plus solution plus vapor). The calculated 90°C value is 10 −49.1 , in excellent agreement with the experimental value; for 25°C, the calculated value is 10 −50.8 .

Geochimica et Cosmochimica Acta↗

Geochemistry of speleothem records from southern Illinois: Development of (234U)/(238U) as a proxy for paleoprecipitation

Natural waters universally show fractionation of uranium series (U-series) parent-daughter pairs, with the disequilibrium between 234U and 238U (234U)/(238U) commonly used as a tracer of groundwater flow. Because speleothems provide a temporal record of geochemical variations in groundwater precipitating calcite, (234U)/(238U) variations in speleothems provide a unique method of investigating water-rock interaction processes over millennium time scales. We present high precision Thermal Ionization Mass Spectrometric (TIMS) U-series analyses of speleothems and drip waters from Fogelpole Cave in southern Illinois. Data from all speleothems from the cave show an inverse correlation between (234U)/(238U) and U concentration, following the pattern observed in groundwaters globally. Within a 65-cm-long stalagmite, concordant 234U-238 U-230Th and 235U-231Pa ages for 5 samples indicate accurate chronology from 78.5 ka to 30 ka. Notably, (234U)/(238U)o which differs from most speleothems by having (234U)/(238U)o <1, positively correlates with speleothem growth rate. We generalize this to the observation that speleothems globally show (234U)/ (238U)o deviating farther from secular equilibrium at lower growth rates and approaching secular equilibrium at higher grow rates. Based on the Fogelpole observations, we suggest that groundwater (234U)/(238U) is controlled by the U oxidation state, the U concentration of the water and the fluid velocity. A transport model whereby U-series nuclides react and exchange with mineral surfaces can reproduce the observed trend between growth rate and (234U)/(238U)o. Based on this result, we suggest that (234U)/(238U)o in speleothems may record changes in hydrologic flux with time and thus could provide a useful proxy for long term records of paleoprecipitation. ?? 2005 Elsevier B.V. All rights reserved.

Chemical Geology↗

Gas transport in unsaturated porous media: The adequacy of Fick's law

The increasing use of natural unsaturated zones as repositories for landfills and disposal sites for hazardous wastes (chemical and radioactive) requires a greater understanding of transport processes in the unsaturated zone. For volatile constituents an important potential transport mechanism is gaseous diffusion. Diffusion, however, cannot be treated as an independent isolated transport mechanism. A complete understanding of multicomponent gas transport in porous media (unsaturated zones) requires a knowledge of Knudsen transport, the molecular and nonequimolar components of diffusive flux, and viscous (pressure driven) flux. The constitutive equations relating these flux components are available from the “dusty gas” model of Mason et al. (1967). This review presents a brief discussion of the underlying principles and interrelationships among each of the above flux mechanisms. Some aspects of these transport mechanisms are, to our knowledge, generally unrecognized in the Earth science literature. The principles underlying the transport mechanisms are illustrated with binary systems; the constitutive equations are then cast in forms thought to be most useful for the study of natural unsaturated zones. The viscous and diffusive fluxes are coupled in the constitutive equations through the Knudsen diffusivities; a knowledge of Knudsen diffusivities is necessary to calculate the viscous component of flux and pressure gradients. The Knudsen diffusivities can be calculated from measurements of the Klinkenberg effect. Two examples are presented showing that in natural systems, very small pressure gradients (1 Pa/m or less) can produce viscous fluxes greater than or equal to diffusive fluxes and that, conversely, pressure gradients of this magnitude can be generated by diffusive processes. The example calculations show that major concentration gradients can be developed for stagnant (zero flux, nonreactive) gases. A method is presented for approximating the viscous and diffusive flux components of gases in a multicomponent system from a knowledge of the concentration profiles of stagnant gases. In subsoil environments, argon and nitrogen are considered to be stagnant gases. Fick's laws are essentially, by definition, inadequate to deal with stagnant gases. In the examples presented, the error associated with estimating the total fluxes of nonstagnant gases by Fick's law, relative to stationary coordinates, ranges from a few percent to orders of magnitude.

Reviews of Geophysics↗

Climate-smart invasive species management for 21st century global change challenges

Addressing the global challenges of climate change and biotic invasions requires understanding their interactions and implications for natural resource management. To facilitate and support invasive species management in a changing climate, we review how climate change and invasions interact to impact the planning, action, and outcomes of invasive species management. Climate change is affecting which species natural resource managers need to assess, monitor, and target by facilitating the introduction of new potential invasive species and altering pathways of introduction and spread. Climate-driven shifts in seasonal conditions and phenological events disrupt and require more flexible management timelines. Climate change may reduce the efficacy and feasibility of current treatment methods and create a need to shift management goals as native ecosystems become more vulnerable to disturbance. Additionally, extreme climate events can compound the spread and impacts of biological invasions, making invasive species management a necessary part of extreme event preparation and response planning. As a solution to these challenges, we propose climate-smart invasive species management, which we define as the approaches that managers and decision-makers can take to address the interactive effects of climate change and invasions. Climate-smart invasive species management includes considering shifts in species ranges, abundance, and impacts to inform monitoring, treatment, and regulation of potential and new invaders at multiple scales. Managers can also adjust the timing of and approach to treatment as efficacy and feasibility change, promote resilient ecosystems through climate-smart restoration, and consider the effects of climate change when setting management goals. Furthermore, climate adaptation funds could expand avenues of funding and support for invasive species management. Explicitly considering the interactions of climate change and biological invasions within organizational decision-making and policy will lead to more effective management and can promote more resilient landscapes.

Global Change Biology↗

Restoring Ecological Function to a Submerged Salt Marsh

Impacts of global climate change, such as sea level rise and severe drought, have altered the hydrology of coastal salt marshes resulting in submergence and subsequent degradation of ecosystem function. A potential method of rehabilitating these systems is the addition of sediment-slurries to increase marsh surface elevation, thus ameliorating effects of excessive inundation. Although this technique is growing in popularity, the restoration of ecological function after sediment addition has received little attention. To determine if sediment subsidized salt marshes are functionally equivalent to natural marshes, we examined above- and belowground primary production in replicated restored marshes receiving four levels of sediment addition (29-42 cm North American Vertical Datum of 1988 [NAVD 88]) and in degraded and natural ambient marshes (4-22 cm NAVD 88). Moderate intensities of sediment-slurry addition, resulting in elevations at the mid to high intertidal zone (29-36 cm NAVD 88), restored ecological function to degraded salt marshes. Sediment additions significantly decreased flood duration and frequency and increased bulk density, resulting in greater soil drainage and redox potential and significantly lower phytotoxic sulfide concentrations. However, ecological function in the restored salt marsh showed a sediment addition threshold that was characterized by a decline in primary productivity in areas of excessive sediment addition and high elevation (>36 cm NAVD 88). Hence, the addition of intermediate levels of sediment to submerging salt marshes increased marsh surface elevation, ameliorated impacts of prolonged inundation, and increased primary productivity. However, too much sediment resulted in diminished ecological function that was equivalent to the submerged or degraded system. ?? 2010 Society for Ecological Restoration International.

Restoration Ecology↗

Evidence for size‐based predation risk during Atlantic salmon (Salmo salar) smolt migration.

Hatchery supplementation is frequently employed during the conservation and recovery of imperilled salmon populations. At the smolt stage, hatchery rearing practices often produce individuals that are larger than wild conspecifics. Under this ‘bigger is better’ strategy, it is assumed that larger fish are less susceptible to predation during migration. We tested this hypothesis on hatchery-reared Atlantic salmon ( Salmo salar ) smolts with fork lengths representative of those of natural and hatchery origins, allowing us to isolate the influence of size from rearing history. From May to June 2023 we characterized predation risk for acoustic-tagged ( n = 50) and tethered ( n = 192) smolts of various sizes through a mostly free-flowing section of the Penobscot River, Maine, USA. Across both methods, more than 50% of smolts were predated, with the majority of predation events being attributed to smallmouth bass ( Micropterus dolomieu ). Tethered smolts of all sizes experienced similar predation risk. In the acoustic telemetry component of this study, smaller, wild-sized smolts incurred greater overall mortality relative to standard hatchery sizes (95% vs. 75%), the majority of which occurred within 3 km of the release site. Collectively, these results allude to a strong predation influence imposed by smallmouth bass on smolts in freshwater sections of the Penobscot River and small-bodied migrants may incur greater predation risk, particularly near stocking sites.

Journal of Fish Biology↗

Shear wave structure of Umbria and Marche, Italy, strong motion seismometer sites Affected by the 1997-98 Umbria-Marche, Italy, earthquake sequence

A long sequence of earthquakes, eight with magnitudes between 5 and 6, struck the Umbria and Marche regions of central Italy between September 26, 1997 and July 1998. The earthquake swarm caused severe structural damage, particularly to masonry buildings, and resulted in the loss of twelve lives and about 150 injuries. The source of the events was a single seismogenic structure that consists of several faults with a prevailing northwest-southeast strike and crosses the Umbria-Marche border. The focal mechanism of the largest shocks indicates that the events were the product of shallow extensional normal faulting along a NE-SW extension perpendicular to the trend of the Apennines. The network of analog seismometer stations in the Umbria and Marche regions recorded motions of the main September and October 1997 events and a dense array of mobile digital stations, installed since September 29, recorded most of the swarm. The permanent national network Rete Accelerometrica Nazionale (RAN) is administered and maintained by Dipartimento delle Protezione Civile (DPC: Civil Protection Department); the temporary array was managed by Servizio Sismico Nazionale (SSN) in cooperation with small agencies and Universities. ENEA, the operator of many seismometer stations in Umbria, is the public Italian National Agency for New Technologies, Energy and the Environment. Many of the temporary and permanent stations in the Italian seismic network have little or no characterization of seismic velocities. In this study, we investigated 17 Italian sites using an active-source approach that employs low frequency harmonic waves to measure the dispersive nature of surface waves in the ground. We used the Spectral Analysis of Surface Wave (SASW) approach, coupled with an array of harmonic-wave electro-mechanical sources that are driven in-phase to excite the ground. An inversion algorithm using a non-linear least-squares best-fit method is used to compute shear wave velocities for up to 100 meters of the soil column. A draft report was published in the summer of 2008, followed by a comment period, lengthy discussions with Italian colleagues, and improved knowledge of the subsurface at the sites from soil logs. Four of the sites were reprocessed in order to correct issues with phase unwrapping of the field dispersion curves that complicated the velocity profile calculations at the lowest velocity sites. This report presents the final results from the reprocessing effort.

Open-File Report↗

Chapter A6. Section 6.2. Dissolved oxygen

Accurate data for the concentration of dissolved oxygen in surface and ground waters are essential for documenting changes in environmental water resources that result from natural phenomena and human activities. Dissolved oxygen is necessary in aquatic systems for the survival and growth of many aquatic organisms and is used as an indicator of the health of surface-water bodies. This section of the National Field Manual (NFM) includes U.S. Geological Survey (USGS) guidance and protocols for four methods to determine dissolved-oxygen concentrations: the amperometric, luminescent-sensor, spectrophotometric, and iodometric (Winkler) methods. Each chapter of the National Field Manual is published separately and revised periodically. Newly published and revised chapters will be announced on the USGS Home Page on the World Wide Web under 'New Publications of the U.S. Geological Survey.'

Techniques of Water-Resources Investigations↗

Preliminary assessment of microbial communities and biodegradation of chlorinated volatile organic compounds in wetlands at Cluster 13, Lauderick Creek area, Aberdeen Proving Ground, Maryland

A preliminary assessment of the microbial communities and biodegradation processes for chlorinated volatile organic compounds was con-ducted by the U.S. Geological Survey in wetlands at the Cluster 13, Lauderick Creek area at Aberdeen Proving Ground, Maryland. The U.S. Geological Survey collected wetland sediment samples from 11 sites in the Lauderick Creek area for microbial analyses, and used existing data to evaluate biodegradation processes and rates. The bacterial and methanogen communities in the Lauderick Creek wetland sediments were similar to those observed in a previous U.S. Geological Survey study at the West Branch Canal Creek wet-land area, Aberdeen Proving Ground. Evaluation of the degradation rate of 1,1,2,2-tetrachloroethane and the daughter compounds produced also showed similar results for the two wetlands. How-ever, a vertical profile of contaminant concentra-tions in the wetlands was available at only one site in the Lauderick Creek area, and flow velocities in the wetland sediment are unknown. To better evaluate natural attenuation processes and rates in the wetland sediments at Lauderick Creek, chemi-cal and hydrologic measurements are needed along ground-water flowpaths in the wetland at additional sites and during different seasons. Nat-ural attenuation in the wetlands, enhanced biore-mediation, and constructed wetlands could be feasible remediation methods for the chlorinated volatile organic compounds discharging in the Lauderick Creek area. The similarities in the microbial communities and biodegradation pro-cesses at the Lauderick Creek and West Branch Canal Creek areas indicate that enhanced bioreme-diation techniques currently being developed for the West Branch Canal Creek wetland area would be transferable to this area.

Maryland↗

Length frequency, condition, growth, and catch per effort indices for common North American fishes

One of the greatest advantages to using standard sampling is the ability of compare sample data to those data collected from an array of other populations over a wide geographic area using similar techniques. A biologist can then ascertain if the sampling data are within an expected range or are higher or lower than expected when compared to other populations.. When biologists collect data using different biased, unvalidated methods, it is often impossible to compare data among populations and evaluate the results. Standard sampling allows comparisons of data among sampling periods and locations. Until now, summaries of freshwater fisheries data collected in a standard manner across North America have not been available. Length at age, length-weight relationships, and other types of detailed summary data are available in Carlander (1696-1977). However, a variety of sampling methods were used to collect these data, allowing successful comparisons among length at age and length-weight data but making it difficult or impossible to compare size distribution and catch per unit effort (CPUE) data among populations. This chapter provides North American and ecoregion (area that contains a geographically distinct assemblage of natural communities and share similar environmental conditions) averages and distributions of several commonly used sampling techniques described in this book. Biologists using the standardized sampling techniques described in this book will be able to compare their data sets to the summaries provided in the tables that follow to determine if the data from their sampled populations of fish are average, below average, or above average for a given index in their ecoregion or across North America.

Book chapter↗

Satellite-derived barrier response and recovery following natural and anthropogenic perturbations, northern Chandeleur Islands, Louisiana

The magnitude and frequency of storm events, relative sea-level rise (RSLR), sediment supply, and anthropogenic alterations drive the morphologic evolution of barrier island systems, although the relative importance of any one driver will vary with the spatial and temporal scales considered. To explore the relative contributions of storms and human alterations to sediment supply on de-cadal changes in barrier landscapes, we applied Otsu’s thresholding method to multiple satel-lite-derived spectral indices for coastal land-cover classification and analyzed Landsat satellite imagery to quantify changes to the northern Chandeleur Islands barrier system since 1984. This high temporal-resolution dataset shows decadal-scale land-cover oscillations related to storm–recovery cycles, suggesting that shorter and (or) less resolved time series are biased toward storm impacts and may significantly overpredict land-loss rates and the timing of barrier mor-phologic state changes. We demonstrate that, historically, vegetation extent and persistence were the dominant controls on alongshore-variable landscape response and recovery following storms, and are even more important than human-mediated sediment input. As a result of exten-sive vegetation losses over the past few decades, however, the northern Chandeleur Islands are transitioning to a new morphologic state in which the landscape is dominated by intertidal envi-ronments, indicating reduced resilience to future storms and possibly rapid transitions in mor-phologic state with increasing rates of RSLR.

Louisiana↗

Science support for evaluating natural recovery of polychlorinated biphenyl concentrations in fish from Crab Orchard Lake, Crab Orchard National Wildlife Refuge, Illinois

Introduction Crab Orchard Lake in southern Illinois is one of the largest and most popular recreational lakes in the state. Construction of the nearly 7,000-acre reservoir in the late 1930s created employment opportunities through the Works Progress Administration, and the lake itself was intended to supply water, control flooding, and provide recreational opportunities for local communities (Stall, 1954). In 1942, the Department of War appropriated or purchased more than 20,000 acres of land around Crab Orchard Lake and constructed the Illinois Ordnance Plant, which manufactured bombs and anti-tank mines during World War II. After the war, an Act of Congress transferred the property to the U.S. Department of the Interior. Crab Orchard National Wildlife Refuge was established on August 5, 1947, for the joint purposes of wildlife conservation, agriculture, recreation, and industry. Production of explosives continued, but new industries also moved onsite. More than 200 tenants have held leases with Crab Orchard National Wildlife Refuge and have operated a variety of manufacturing plants (electrical components, plated metal parts, ink, machined parts, painted products, and boats) on-site. Soils, water, and sediments in several areas of the refuge were contaminated with hazardous substances from handling and disposal methods that are no longer acceptable environmental practice (for example, direct discharge to surface water, use of unlined landfills). Polychlorinated biphenyl (PCB) contamination at the refuge was identified in the 1970s, and a PCB-based fish-consumption advisory has been in effect since 1988 for Crab Orchard Lake. The present advisory covers common carp ( Cyprinus carpio ) and channel catfish ( Ictalurus punctatus ); see Illinois Department of Public Health (2017). Some of the most contaminated areas of the refuge were actively remediated, and natural ecosystem recovery processes are expected to further reduce residual PCB concentrations in the lake. The U.S. Fish and Wildlife Service sought technical support to understand environmental drivers of current (2017) PCB residues in fish tissue and patterns in PCB residues through time to inform the fish-consumption advisory for Crab Orchard Lake. This project is planned in two phases (Tasks 1 and 2); the first phase is included in this report. Task 1, reported here, includes a review of existing literature and a brief overview focused on environmental and biochemical/physiological processes that drive PCB residues in fish tissue. This review specifically targets processes that are relevant for freshwater lacustrine environments such as those at Crab Orchard Lake. In addition to discussions of environmental fate, metabolism, and accumulation of PCBs, this review includes a brief scientifically based explanation of approaches used to establish fish-consumption advisories. A planned second task (Task 2) will include a compilation and summary of existing data on PCB residues in fish tissue samples from Crab Orchard Lake. This summary will also place Crab Orchard Lake data in a broader geographic context through a comparison with fish data from other Midwestern lakes. When Task 1 and Task 2 are complete, resource managers will have (a) a synthesis of existing literature that characterizes the processes influencing the fate of residual PCBs remaining in systems such as Crab Orchard Lake, (b) a summary of natural PCB attenuation processes for use in risk communication with the public, and (c) a summary of existing data on PCBs in fish tissues from Crab Orchard Lake, including exploratory plots of tissue residues through time. Overall, this project will provide data to help resource managers better understand the ecological and public health consequences of residual PCBs in Crab Orchard Lake.

Illinois↗

Vegetation index-based crop coefficients to estimate evapotranspiration by remote sensing in agricultural and natural ecosystems

Crop coefficients were developed to determine crop water needs based on the evapotranspiration (ET) of a reference crop under a given set of meteorological conditions. Starting in the 1980s, crop coefficients developed through lysimeter studies or set by expert opinion began to be supplemented by remotely sensed vegetation indices (VI) that measured the actual status of the crop on a field-by-field basis. VIs measure the density of green foliage based on the reflectance of visible and near infrared (NIR) light from the canopy, and are highly correlated with plant physiological processes that depend on light absorption by a canopy such as ET and photosynthesis. Reflectance-based crop coefficients have now been developed for numerous individual crops, including corn, wheat, alfalfa, cotton, potato, sugar beet, vegetables, grapes and orchard crops. Other research has shown that VIs can be used to predict ET over fields of mixed crops, allowing them to be used to monitor ET over entire irrigation districts. VI-based crop coefficients can help reduce agricultural water use by matching irrigation rates to the actual water needs of a crop as it grows instead of to a modeled crop growing under optimal conditions. Recently, the concept has been applied to natural ecosystems at the local, regional and continental scales of measurement, using time-series satellite data from the MODIS sensors on the Terra satellite. VIs or other visible-NIR band algorithms are combined with meteorological data to predict ET in numerous biome types, from deserts, to arctic tundra, to tropical rainforests. These methods often closely match ET measured on the ground at the global FluxNet array of eddy covariance moisture and carbon flux towers. The primary advantage of VI methods for estimating ET is that transpiration is closely related to radiation absorbed by the plant canopy, which is closely related to VIs. The primary disadvantage is that they cannot capture stress effects or soil evaporation. Copyright ?? 2011 John Wiley & Sons, Ltd.

Hydrological Processes↗

Toppling analysis of the Echo Cliffs precariously balanced rock

Toppling analysis of a precariously balanced rock (PBR) can provide insight into the nature of ground motion that has not occurred at that location in the past and, by extension, can constrain peak ground motions for use in engineering design. Earlier approaches have targeted 2D models of the rock or modeled the rock–pedestal contact using spring‐damper assemblies that require recalibration for each rock. Here, a method to model PBRs in 3D is presented through a case study of the Echo Cliffs PBR. The 3D model is created from a point cloud of the rock, the pedestal, and their interface, obtained using terrestrial laser scanning. The dynamic response of the model under earthquake excitation is simulated using a rigid‐body dynamics algorithm. The veracity of this approach is demonstrated through comparisons against data from shake‐table experiments. Fragility maps for toppling probability of the Echo Cliffs PBR as a function of various ground‐motion parameters, rock–pedestal interface friction coefficient, and excitation direction are presented. These fragility maps indicate that the toppling probability of this rock is low (less than 0.2) for peak ground acceleration (PGA) and peak ground velocity (PGV) lower than 3 m/s 2 and 0.75 m/s, respectively, suggesting that the ground‐motion intensities at this location from earthquakes on nearby faults have most probably not exceeded the above‐mentioned PGA and PGV during the age of the PBR. Additionally, the fragility maps generated from this methodology can also be directly coupled with existing probabilistic frameworks to obtain direct constraints on unexceeded ground motion at a PBR’s location.

California↗

Design-based and model-based inference in surveys of freshwater mollusks

Well-known concepts in statistical inference and sampling theory are used to develop recommendations for planning and analyzing the results of quantitative surveys of freshwater mollusks. Two methods of inference commonly used in survey sampling (design-based and model-based) are described and illustrated using examples relevant in surveys of freshwater mollusks. The particular objectives of a survey and the type of information observed in each unit of sampling can be used to help select the sampling design and the method of inference. For example, the mean density of a sparsely distributed population of mollusks can be estimated with higher precision by using model-based inference or by using design-based inference with adaptive cluster sampling than by using design-based inference with conventional sampling. More experience with quantitative surveys of natural assemblages of freshwater mollusks is needed to determine the actual benefits of different sampling designs and inferential procedures.

Journal of the North American Benthological Societ↗

Groundwater-quality data in the northern Coast Ranges study unit, 2009: Results from the California GAMA Program

Groundwater quality in the 633-square-mile Northern Coast Ranges (NOCO) study unit was investigated by the U.S. Geological Survey (USGS) from June to November 2009, as part of the California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment (GAMA) Program's Priority Basin Project (PBP) and the U.S. Geological Survey National Water-Quality Assessment Program (NAWQA). The GAMA-PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001 and is being conducted in collaboration with the SWRCB and Lawrence Livermore National Laboratory (LLNL). The NOCO study unit was the thirtieth study unit to be sampled as part of the GAMA-PBP. The GAMA Northern Coast Ranges study was designed to provide a spatially unbiased assessment of untreated-groundwater quality in the primary aquifer systems, and to facilitate statistically consistent comparisons of untreated groundwater quality throughout California. The primary aquifer systems (hereinafter referred to as primary aquifers) are defined as that part of the aquifer corresponding to the perforation intervals of wells listed in the California Department of Public Health (CDPH) database for the NOCO study unit. The quality of groundwater in shallow or deep water-bearing zones may differ from the quality of groundwater in the primary aquifers; shallow groundwater may be more vulnerable to surficial contamination. In the NOCO study unit, groundwater samples were collected from 58 wells in 2 study areas (Interior Basins and Coastal Basins) in Napa, Lake, Mendocino, Glenn, Humboldt, and Del Norte Counties. The 58 wells were selected by using a spatially distributed, randomized grid-based method to provide statistical representation of the study areas. GAMA-PBP wells sampled as part of the spatially-distributed, randomized grid-cell network are referred to as "grid wells."The groundwater samples were analyzed for organic and special-interest constituents (volatile organic compounds [VOC], pesticides and pesticide degradates, and perchlorate), naturally occurring inorganic constituents (trace elements, nutrients, dissolved organic carbon [DOC], major and minor ions, silica, total dissolved solids [TDS], and alkalinity), radioactive constituents (radon-222, radium isotopes, gross alpha and gross beta radioactivity, lead-210, and polonium-210), and microbial indicators (F-specific and somatic coliphage, Escherichia coli [E. coli] and total coliform). Naturally occurring isotopes (stable isotopes of hydrogen and oxygen in water, stable isotopes of carbon in dissolved inorganic carbon, activities of tritium, and carbon-14 abundance), and dissolved noble gases also were measured to identify the sources and ages of the sampled groundwater. In total, 239 constituents and 12 field water-quality indicators were measured. Three types of quality-control samples (blanks, replicates, and matrix-spikes) were collected at up to 12 percent of the wells in the NOCO study unit, and the results for these samples were used to evaluate the quality of the data for the groundwater samples. Blanks rarely contained detectable concentrations of any constituent, suggesting that contamination from sample collection procedures was not a significant source of bias in the data for the groundwater samples. Replicate samples generally were within the limits of acceptable analytical reproducibility. Matrix-spike recoveries were within the acceptable range (70 to 130 percent) for approximately 89 percent of the compounds. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, untreated groundwater typically is treated, disinfected, and (or) blended with other waters to maintain water quality. Regulatory benchmarks apply to water that is served to the consumer, not to untreated groundwater. However, to provide some context for the results, concentrations of constituents measured in the untreated groundwa

Data Series↗