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System characterization report on the Environmental Mapping and Analysis Program (EnMAP)

This report addresses system characterization of the Environmental Mapping and Analysis Program hyperspectral sensor by the DLR (German Aerospace Center, ground segment project management), GFZ (Deutsches Geoforschungszentrum, science lead) and is part of a series of system characterization reports produced and delivered by the U.S. Geological Survey Earth Resources Observation and Science Cal/Val Center of Excellence. These reports present and detail the methodology and procedures for characterization; present technical and operational information about the EnMAP hyperspectral sensor; and provide a summary of test measurements, data retention practices, data analysis results, and conclusions. The Earth Resources Observation and Science Cal/Val Center of Excellence system characterization team completed data analyses to characterize the geometric (interior and exterior), and radiometric performances of the EnMAP hyperspectral sensor. Results of these analyses indicate that the Environmental Mapping and Analysis Program has a band-to-band geometric performance in the range of −0.135 to 0.15 pixel, geometric performance relative to the Operational Land Imager in the range of −27.716 meters (−0.92 pixel) to 32.892 meters (1.09 pixels) offset in comparison to Landsat 8 Operational Land Imager, offset of a radiometric comparison in the range of −0.012 to 0.020, slope of a radiometric comparison in the range of 0.947 to 1.031.

Open-File Report

Critical review of mercury methylation and methylmercury demethylation rate constants in aquatic sediments for biogeochemical modeling

Mercury is a toxin that causes neurological impairments in adults, is particularly harmful for fetuses and children, and is deadly in severe cases, making it a worldwide health concern. Methylmercury (MeHg) is the environmentally relevant form of mercury (Hg) because it biomagnifies along the food chain. Methylmercury is mainly produced in aquatic sediments via methylation of inorganic Hg (Hg(II)) and transformed back via demethylation. Because transformation rates determine MeHg concentrations, quantification of methylation and demethylation rates is needed to inform management of MeHg. Published rate constants for Hg(II) methylation ( 𝑘 𝑚 ) and MeHg demethylation ( 𝑘 𝑑 ) vary greatly, stemming partly from differences in experimental methods. We conducted a comprehensive review of rate laws, evaluated published rate constants, and performed biogeochemical simulations to assess variability in reported 𝑘 𝑚 and 𝑘 𝑑 . Based on selected studies employing the same pseudo-first-order rate law and similar experimental methods, we found that 𝑘 𝑚 = 0.04 ± 0.03 d −1 is a reasonable range for wetland sediments. Over a number of environments, maximum 𝑘 𝑑 was smaller at sites without Hg source ( 𝑘 𝑑 = 0.5 d −1 ) than at sites with identified Hg source ( 𝑘 𝑑 = 1.8 d −1 ). Larger variability and higher uncertainty in 𝑘 𝑑 compared to 𝑘 𝑚 highlight the need for more research on MeHg demethylation rates. This critical review: (a) aids the design of future experimental studies of 𝑘 𝑚 and 𝑘 𝑑 ; (b) provides guidance for comparing rate constants from different studies; (c) presents a biogeochemical reaction model to assess rate constants; and (d) informs selection of 𝑘 𝑚 and 𝑘 𝑑 values from the literature for use in model simulations.

Critical Reviews in Environmental Science and Tech

Fairweather transform boundary Oligocene to present orogenesis: Fairweather Range vertical extrusion and rotation of the Yakutat microplate at ca. 3 Ma

Oblique-slip along transform fault boundaries is often partitioned between a strike-slip system and thrust faults that accommodate contraction. However, topography along the Yakutat-North American transform (Fairweather fault), is asymmetric with low-terrain above active thrusts on the western, Yakutat side of the transform and high topography on the continental side with peaks >4500 m (Mount Fairweather: 4671 m) to the west of the Border Ranges fault, limited recorded earthquakes >M4, and no apparent reverse faults to generate the highest terrain. In this study we compile, for the first time, published U-Pb zircon, 40 Ar/ 39 Ar and K-Ar (hornblende, muscovite, and biotite) and U-Th/He and fission-track (zircon and apatite) bedrock ages (109) from 75 samples to investigate the exhumation history of the Fairweather Range region, complemented by a published detrital sample (ZFT and AFT) and 13 new 40 Ar/ 39 Ar (hornblende, biotite, and K-feldspar) ages on 9 bedrock samples from both sides of the Fairweather fault. Additionally, we examined published seismicity and geodetic data of the Fairweather region and assessed if plate paleo-vectors correlate with the cooling history of the Fairweather Range. Cooling age, seismic, and block-motion patterns indicate the Fairweather Range has been vertically extruded between the Fairweather and the Border Ranges faults as a coherent block since ca. 25 Ma. The pre-6 Ma Pacific plate motion (N30°W) aligns with the N33°W strike of the Fairweather Fault whereas a hypothetical pre-6 Ma Yakutat microplate paleo-vector of (N39°W) does not: indicating a post-6 Ma timing for Yakutat microplate counter-clockwise rotation (9°). We infer that rotation and impingement of the Yakutat microplate along the Fairweather fault at ca. 3 Ma led to the development of the Fairweather restraining bend and increased cooling rates. The resultant thickened Fairweather welt and the ∼30 km thick southeast end of the Yakutat microplate compounded double-indenter tectonics into Alaska's southeast convergent corner

Tectonophysics

Precariously balanced rocks in northern New York and Vermont, U.S.A.: Ground-motion constraints and implications for fault sources

Precariously balanced rocks (PBRs) and other fragile geologic features have the potential to constrain the maximum intensity of earthquake ground shaking over millennia. Such constraints may be particularly useful in the eastern United States (U.S.), where few earthquake‐source faults are reliably identified, and moderate earthquakes can be felt at great distances due to low seismic attenuation. We describe five PBRs in northern New York and Vermont—a region of elevated seismic hazard associated with historical seismicity. These boulders appear to be among the most fragile PBRs in the region, based on reports from hobbyists. The PBRs are glacial erratics, best evidenced by glacial striations on bedrock pedestals. The pedestals themselves are locally high knobs, often situated on regionally high topography; this setting limits soil development and indicates that any outwash deposits were likely ephemeral. As a result, PBR ages can be reliably established by the retreat of the last continental ice sheet, ∼15–13 ka. To quantify the fragility of the PBRs, we surveyed them with ground‐based light detection and ranging and calculated geometric parameters from the point clouds, field observations, and seismic responses. Preliminary validation of the 2023 time‐independent U.S. National Seismic Hazard Model (NSHM) shows that the existence of PBRs is generally consistent with the median site‐specific hazard curves. Only the Blue Ridge Road site suggests a modest reduction in hazard. To visualize the ensemble of data, we mapped the minimum permissible distance to potential source faults around each PBR site as a function of source magnitude by using the ground‐motion models from the 2023 NSHM. Viewed in this manner, our data are consistent with potential M ∼6.5 earthquake‐source faults in many parts of the Lake Champlain Valley and northern Adirondack Mountains. Our work illustrates a potential pathway for better constraining earthquake‐source faults in regions of cryptic faults.

Bulletin of the Seismological Society of America

Measurement of in situ-produced cosmogenic nuclides in fine-grained quartz from shale

In situ -produced 10 Be in quartz is widely used to constrain exposure ages and denudation rates, traditionally measured in sand-sized grains. Here we report a new method for isolating fine-grained quartz from shale and demonstrate its reliability for grain sizes down to single microns. Sequential dissolution tests and analyses of grain size separates show that meteoric 10 Be is eliminated and that recoil losses during cosmogenic nuclide production are balanced by implantation from other mineral grains. High-temperature combustion leads to diffusion of meteoric 10 Be into fine-grained quartz and must be used with caution.

Nuclear Instruments and Methods in Physics Researc

Using a temporary emigration model to estimate abundance of stream fishes from hybrid removal surveys with and without block nets

Monitoring programs are often faced with a decision to allocate resources into either robust spatiotemporal coverage to estimate a population index (e.g., not true abundance) or confirming closed sampling conditions (e.g., with block nets) for an unbiased population estimate at the cost of spatiotemporal coverage. However, making accurate and precise abundance estimates at robust spatiotemporal scales is possible when combining open and closed sampling designs with integrated modeling techniques. We used simulations and a case study of backpack electrofishing surveys in the Santa Ana River, California to test the efficacy of an integrated abundance model (temporary emigration model, TE) to estimate abundance of fishes using removal sampling methods with a hybrid sampling design (sampling with and without block nets during removal sampling). We found that the TE model performed well under most modeling scenarios (sample size, amount of closure violation, number of samples collected during closure), although at least a few samples with block nets were necessary for all parameters to be estimable. When applied to fish surveys in the Santa Ana River, we found that catch of the fishes fit to the TE model (Santa Ana Sucker, Arroyo Chub, Channel Catfish, Largemouth Bass, Yellow Bullhead) showed little evidence that the closure assumption was violated when block nets were not used. Additionally, we found that the abundance of non-native fishes negatively affected the abundance of the native Santa Ana Sucker, which was also found to adversely affect the native fish’s access to critical habitat consisting of gravel and cobble substrate. Our results indicate that the TE model presents a viable solution to common sampling problems that impact many monitoring programs, where precise and accurate population estimates can be made at large spatiotemporal scales even when most samples violate the closure assumption.

California

Bottom-up characterization of geologic methane emissions in the San Juan Basin in the southwestern USA

Methane is a potent greenhouse gas that plays an important role in atmospheric chemistry and global warming. The current global methane budget has large uncertainties, and a better understanding of the budget would help to guide strategies for reducing anthropogenic emissions to fight climate change. Natural geologic methane emissions are a particularly poorly constrained source, with top-down estimates from 14 C in ice cores suggesting much lower geologic emissions than bottom-up scaling of direct flux measurements. Our study aims to contribute to resolving this discrepancy through improved bottom-up characterization of geologic methane seepage in the San Juan Basin in southwestern Colorado and northwestern New Mexico, USA. We performed 983 new flux chamber measurements in this basin during summer 2022 and winter 2023 field campaigns. Our results, in combination with prior measurements, suggest that natural seepage in the San Juan Basin only occurs on or near the Fruitland coal outcrop. Specifically, our new measurements confirm previous measurements of seepage along the northwestern exposure of the Fruitland outcrop in Colorado (a known hydrodynamic overpressure region) and for the first time, identified seepage locations along the southernmost Fruitland outcrop exposure in New Mexico, in association with a coal cleat and a fault. Overall, seepage along the Fruitland coal outcrop is heterogeneously distributed, with both positive and negative (interpreted as microbial soil sink) methane fluxes. Features that are hypothesized to be predictive of seepage (e.g., faults) were not associated with positive methane fluxes in areas outside of the Fruitland outcrop. Our best estimate for total geologic methane seepage in the San Juan Basin from spatial interpolation and statistical upscaling is approximately 0.14 Tg CH 4 /yr, with a range from 0.029 to 0.48 Tg CH 4 /yr. This best-estimate value is lower than a previous bottom-up estimate from a gridded seepage inventory, but higher than a previous top-down estimate.

Colorado, New Mexico

Microclimate mediates the strength and direction of avian biotic interactions

Theory predicts that that the strength and direction of species interactions can shift from being competitive in benign environments toward being facilitative in stressful environments. However, the environmental context dependency of species interactions has rarely been tested in animal communities. We capitalized on a 15-year, landscape-scale dataset, collected annually in a relatively stable old-growth forest environment to test the long-held hypothesis that the strength and direction of species interactions might be mediated by climatic conditions. It is generally accepted that competitive and facilitative interactions drive the distributions of many species. Using multi-species dynamic occupancy models applied to long-term data, we tested whether annual settlement by bird species could affect either the persistence or settlement by other phylogenetically related species, and whether these interactions are mediated by microclimate. We found that species interactions were influenced by microclimate for some, but not all avian species pairs. Related species pairs more often showed settlement dynamics that were indicative of attraction rather than repulsion. In some cases, competitive interactions at warmer microclimates flipped to become facilitative in colder ones. However, the reverse was also true: facilitative interactions amplified for some species under warm conditions. Furthermore, species pairs that were closely related were more likely to exhibit competitive relationships along at least part of the microclimatic gradient. Our results highlight the importance of using long-term data to incorporate competitive and facilitative interactions into species distribution models and support the notion that the strength and direction of species interactions can be dependent on microclimatic environmental conditions.

Oregon

Repeated coseismic uplift of coastal lagoons above the Patton Bay Splay Fault System, Montague Island, Alaska, USA

Coseismic slip on the Patton Bay splay fault system during the 1964 M w 9.2 Great Alaska Earthquake contributed to local tsunami generation and vertically uplifted shorelines as much as 11 m on Montague Island in Prince William Sound (PWS). Sudden uplift of 3.7–4.3 m caused coastal lagoons along the island's northwestern coast to gradually drain. The resulting change in depositional environment from marine lagoon to freshwater muskeg created a sharp, laterally continuous stratigraphic contact between silt and overlying peat. Here, we characterize the geomorphology, sedimentology, and diatom ecology across the 1964 earthquake contact and three similar prehistoric contacts within the stratigraphy of the Hidden Lagoons locality. We find that the contacts signal instances of abrupt coastal uplift that, within error, overlap the timing of independently constrained megathrust earthquakes in PWS—1964 Common Era, 760–870 yr BP, 2500–2700 yr BP, and 4120–4500 yr BP. Changes in fossil diatom assemblages across the inferred prehistoric earthquake contacts reflect ecological shifts consistent with repeated draining of a lagoon system caused by >3 m of coseismic uplift. Our observations provide evidence for four instances of combined megathrust-splay fault ruptures that have occurred in the past ∼4,200 years in PWS. The possibility that 1964-style combined megathrust-splay fault ruptures may have repeated in the past warrants their consideration in future seismic and tsunami hazards assessments.

Alaska

Near-surface material and topography generate anomalous high-frequency ground motion amplification in Chugiak, Alaska

An ∼3 km long nodal array oriented approximately east–west was deployed in Chugiak, Alaska, by the U.S. Geological Survey during 2021. The array intersects with the permanent NetQuakes station NP.ARTY, where peak ground acceleration (PGA) value of 1.98 g was recorded during the 2018 M w 7.1 Anchorage, Alaska, earthquake, in sharp contrast to the PGA of ∼0.3 g at a site just 4 km to the west. Seismic data for M w 1.8–4.3 aftershocks from the M w 7.1 event recorded by the nodal array confirm the anomalously large ground motions obtained at NP.ARTY as well as similar amplifications at nodes within ∼1 km to the east. Here, we performed 0–10 Hz 3D finite‐difference simulations, including high‐resolution surface topography, to explore the cause of the unexpectedly large amplification. As expected, the simulations computed with a regional 3D tomography velocity model severely underpredict the 0–10 Hz acceleration records at almost all sites. Adding a near‐surface low‐velocity taper to 300 m depth amplifies the accelerations by up to a factor of 5 and enables a reasonable match between the nodal data and simulations at sites to the west of NP.ARTY. However, this model still underpredicts the spectral energy in the area covered by glacial sediments by up to an order of magnitude. The addition of a till layer using a depth‐dependent shear‐wave velocity ( ⁠⁠ V s ) profile along with a homogeneous, 8 m thick low‐velocity layer with V s = 250 m/s representing the kame terraces improves the fit to data to within a factor of 2 at nodes located on top of the glacial sediments. Our study shows that the anomalously large high‐frequency amplification recorded at and near NP.ARTY can be explained by a combination of topographic effects and near‐surface low‐velocity material with amplification effects on the high‐frequency ground motion by up to about 40% and an order of magnitude, respectively.

Alaska

Insights into Mountain Pass carbonatite formation from in-situ sulfur isotopes and geochemistry of sulfate and sulfide minerals

The Mountain Pass carbonatite stock hosts a world-class rare earth element deposit and may be classified as a carbonate-sulfate igneous rock, as it contains on average > 50 volume percent carbonate minerals and 20 to 30 volume percent sulfate minerals. The sulfates range in composition from barite to celestine and locally occur with sparse sulfide minerals. We investigate the origin of sulfur enrichment and the occurrence of sulfur-bearing minerals in the Mountain Pass carbonatite with in-situ sulfur isotope and mineral chemistry. Barite cores with δ 34 S of 1 to 3‰ do not coexist with sulfides, whereas celestine rims with δ 34 S of > 3‰ are associated with sulfides with δ 34 S < -10‰. We propose a model in which sulfur-bearing sediments were subducted during episodes of plate convergence in the Mojave Province that preceded Mountain Pass magmatism. Metasomatism of the overlying mantle by melts derived from the subducted sediments generated an unusually carbon- and sulfur-rich source to yield carbonatite magmas. Sulfur from primary carbonatite magmas and ~ 1 to 7% sulfur from subducted sediment melts yielded a slightly enriched δ 34 S composition (relative to depleted mantle δ 34 S of -1‰) for early crystallizing barite. Celestine rims on magmatic barite cores formed at low, hydrothermal temperatures (< 350 °C) based on S isotope thermometry for equilibrium celestine-galena and celestine-pyrite pairs. The sparse sulfides in the carbonatite stock are not in equilibrium with the primary barite cores and therefore do not permit S isotope thermometry estimates of magmatic temperatures. The S/Se ratios of sulfide minerals (> 3,400) typically exceed primitive mantle values (S/Se of 3,340), also consistent with their derivation from hydrothermal fluids. Trace occurrences of sulfide and sulfate minerals in alkaline silicate stocks related to the carbonatite stock have similar δ 34 S compositions and yield similarly low formation temperatures, suggesting regionally extensive and chemically similar sulfur-bearing hydrothermal fluids that imparted lithologically diverse rocks with a consistent sulfur isotope fingerprint.

California, Nevada

Constraining the earthquake recording threshold of intraslab earthquakes with turbidites in southcentral Alaska’s lakes and fjords

Strong ground motion from intraslab earthquakes, which do not produce primary paleoseismic evidence, may initiate gravity-driven turbidity flows in subaqueous basins. The resulting deposits (turbidites) can provide a paleoseismic proxy if the conditions that initiate these flows are known. To better constrain the initiating conditions, we use two recent intraslab earthquakes in southcentral Alaska, the M w 7.1 30 November 2018 Anchorage earthquake and the M w 7.1 24 January 2016 Iniskin earthquake, as calibration events. Through a multilake investigation, we document the occurrence, or the absence, of earthquake-generated turbidity flows from these two events. Both earthquakes are recorded by centimeter-scale turbidites that can be differentiated from climatically generated deposits, as well as other seismic sources based on deposit thickness, sedimentological properties, and deposit age. We show that a Modified Mercalli Intensity (MMI) of ∼V–V1/2 is the minimum shaking intensity required to generate localized sediment remobilization from deltaic slopes, and an MMI of ∼V1/2 is required to produce a deposit of sufficient thickness that a seismic origin can be confidently assigned. The documentation of seismically generated deposits in quick succession (∼2 years) with diagnostic features highlights the utility of using recent earthquakes as calibration events to investigate the subaqueous response to strong ground motion.

Alaska

In-situ geochronology using LA-ICP-MS/MS: Application of the Lu-Hf system in carbonate, apatite and fluorite

Geochronology is a fundamental tool for reconstructing earth history and constraining the timing of ore deposit formation. Traditionally, U-rich minerals like zircon, titanite, monazite and apatite have been analysed to determine the timing of mineralization and alteration events. However, not all deposits or alteration assemblages contain these minerals, and the U-Pb system can be disturbed due to open system behaviour. We present a methodology for obtaining in-situ Lu-Hf dates from various minerals to demonstrate the potential for dating ore deposits that lack U-rich minerals. Carbonate, apatite and fluorite minerals from different tectonic settings and geological environments were analysed. We acquired Lu-Hf and REE (rare earth element) data from carbonate minerals from a carbonatite orebody and dike samples from the Mountain Pass REE carbonatite deposit in California, USA. We also tested a ‘double-dating’ method, where U-Th-Pb dates and Lu-Hf dates were obtained from the same analysis of apatite from rocks in the Michigan’s Great Lakes Tectonic Zone. Preliminary results for Lu-Hf dating of fluorite from carbonatite rocks in the Lemitar Mountains of New Mexico are also included. The analytical methodology shows promising results in each of these cases where there is sufficient parent Lu and U and measurable daughter Hf and Pb respectively.

Conference Paper

Upper crustal seismic velocity structure of the Hayward fault zone, San Francisco Bay, California, USA: Results from the 2016 East Bay Seismic Experiment (EBSI-16)

We developed Vp, Vs, Vp / Vs ratio, and Poisson’s ratio models of the uppermost crust (<4 km depth) from the eastern San Francisco (SF) Bay (California, USA) to near the Calaveras fault along a 15-km-long, linear profile. Upper crustal velocities are highly variable beneath, west, and well east of the Hayward fault. We observe eight notable features, from west to east: (1) Near San Francisco Bay, there is an ~2-km-wide structure with high Vp / Vs ratios (up to 5) and Poisson’s ratios (up to 0.48) extending from the surface to the base of our model, which we suggest the structure is a near-vertical fault that lies along a straight-line projection between the Silver Creek fault to the south and the Point Richmond fault to the north. The structure may be part of an ~90-km-long fault along the eastern SF Bay. (2) The western East Bay Plain, the lower lying area between the bay and the hills, includes up to 800 m of low-velocity sediments ( Vp ~1600–3000 m/s, Vs ~500 m/s to ~1000 m/s), underlain by higher velocity basement rocks ( Vp ~3000–5800 m/s; Vs ~1000–1500 m/s). (3) Between ~1 km and 3 km east of the Bay shoreline, sediments thin in a series of steps (likely faults) toward the Hayward fault. (4) Between ~3 km west and ~1 km east of the Hayward fault (at the East Chabot fault) at depths greater than 1 km, basement Vp (up to 6000 m/s) and Vs (up to 2800 m/s) are high, and Vp / Vs ratios (<2) and Poisson’s ratios (<0.3) are low, suggesting crystalline rocks. Furthermore, a near-vertical zone of low Vp / Vs ratios and Poisson’s ratios is between near-surface traces of the Hayward and East Chabot faults, likely corresponding to the San Leandro Gabbro of Ponce et al. (2003) . (5) Eastward of the East Chabot fault in the upper 1.5 km, basement Vp (~3000 m/s to ~4200 m/s) and Vs (~1200–2000 m/s) are lower than those west of the fault. (6) In the eastern Hayward/Oakland Hills, there are zones of laterally varying, high- and low-velocity ( Vp ~2500–3000 m/s) Jurassic–Cretaceous and Tertiary sediments in the shallow subsurface that likely extend much deeper than imaged. (7) Seismic energy that propagates westward from sources east of the Hayward fault (HF) appear weaker than energy that propagates eastward from sources west of the HF, suggesting that the HF acts as a partial barrier to shallow seismic energy propagation into the more populated eastern SF Bay area. (8) Unlike many fault zones, it appears that the active trace of the Hayward fault (in our study area) is not cored by a prominent, low-velocity zone relative to rocks to the east and west of the active trace. However, the active trace does mark a prominent change from relatively higher velocities to the west and lower velocities to the east.

California

Quantitative mineral resource assessment of lithium pegmatite deposits in the Appalachian Orogen, USA

Lithium is classified as a U.S. critical mineral commodity, and its demand is projected to drastically increase through 2040, driven by electric vehicle production and energy storage applications (IEA 2021).Most global lithium production is not in the United States increasing vulnerability to a supply disruption. The U.S. Geological Survey is actively assessing domestic lithium deposits including lithium-bearing pegmatites in the Appalachian orogen. Permissive tracts for lithium pegmatite deposits were delineated by integrating lithological, tectonic, geochemical, geophysical, and mineral occurrence data. The geospatial data and permissive tracts were used to estimate the number of undiscovered lithium pegmatite deposits. Estimates were then integrated into probabilistic simulations along with a new global lithium pegmatite grade and tonnage dataset to quantify potential contained undiscovered lithium resources. An economic filter was used to estimate the amount of potentially recoverable undiscovered resources. Preliminary computations for the northern Appalachians, including application of the economic filter to the median recoverable contained resource, yields 900,000 metric tons of Li 2 O that correspond to enough Li 2 O to replace 127 years of import reliance at the current rate (7,100 t Li 2 O/yr; USGS, 2025). For the southern Appalachians, preliminary computations yielded 1,430,000 metric tons of Li 2 O, which corresponds to 201 years of import reliance.

Alabama, Connecticut, Delaware, Georgia, Maine, Ma

Rapid hydrothermal triggering of induced seismicity at the Coso Geothermal Field

The long-term producing Coso Geothermal Field (CGF) in California operates over 100 wells tapping into a reservoir characterized by an extensive fracture network, complex fluid pathways, and regular seismic activity. Understanding the interaction between seismicity and injection can shed important light on the hydrothermal characteristics of the field. Here, we analyze 15 years of local seismic and daily operational data from the CGF, identifying a strong correlation between short-term increase in seismicity rate and seasonal volumetric and temperature variations in the reinjected fluid. Furthermore, the seismic footprint during peak injection of colder fluids reveals a near-instantaneous response up to 2 km away from the injection well, too rapid for pore pressure diffusion alone. This short-term and distant response is observed to have directional preference, indicating structural or permeability anisotropy within the reservoir. Additionally, the seismic response correlates with the initial volumetric increase of colder fluids, but also with temperature decrease during stable injection periods, suggesting thermal effects alone can play an important role in triggering distant seismicity.

California

Geochemistry and radiogenic isotopes constrain the mantle source region of the Mountain Pass Intrusive Suite, California

The Mountain Pass carbonatite stock is the largest rare earth element (REE) deposit and only active REE mine in the United States. The carbonatite intrusion and spatially associated alkaline silicate intrusions constitute the Mountain Pass Intrusive Suite, which is located within the Mojave Province in California. Both the carbonatite and the alkaline silicate rocks are enriched in large ion lithophile elements and light REEs, and less enriched to depleted in high field strength elements, indicating the mantle source region was metasomatically enriched in incompatible trace elements. The cause of this metasomatic mantle enrichment and the genetic relationship between the carbonatite and the alkaline silicate stocks are poorly understood. In this study, major and trace element geochemical data and isotopic (Rb-Sr, Sm-Nd, and Lu-Hf) data are presented to constrain genesis of the Mountain Pass Intrusive Suite, from mantle source region to the intrusion of the stocks. Our geochemical data are consistent with derivation of the alkaline silicate and carbonatite melts through partial melting from a shared mantle source region rather than through liquid immiscibility or fractional crystallization and separation of a carbothermal fluid. Although the Rb-Sr isotopic system in the Mountain Pass Intrusive Suite is disturbed at the whole-rock scale, the isotopic systems for whole-rock Sm-Nd (εNd i = ‐2.2 ± 0.8) and zircon Lu-Hf (εHf i = 0.1 ± 1.1) are robust and support mantle derivation of the magmas. Geochemical modeling using experimentally derived partition coefficients was used to identify possible causes of enrichment in incompatible elements through metasomatism in the mantle source region. Modeling of metasomatism by melts derived by partial melting of deeply subducted carbonated sediments approximates observed Mountain Pass Intrusive Suite trace element chemistry. Scattered εHf i in inherited zircon (2.8 ± 2.6) is consistent with derivation from an arc-related environment with substantial crustal contamination. Paleotectonic studies in the Mojave Province indicate that regional subduction preceded emplacement of the Mountain Pass Intrusive Suite by ∼300 Ma. Melting of the Mountain Pass source region may have been caused by post-collisional thermal relaxation and extension.

California

New 10Be-26Al isochron burial dating informs the Pliocene and Pleistocene evolution of the lower Colorado River, southwestern United States

Four new 10 Be- 26 Al isochron burial ages ranging from 4.4 to 2 Ma on ancestral Colorado River deposits in the lower Colorado River corridor (LCRC) help constrain the river’s evolution during the Pliocene and early Pleistocene. They help fill a gap between previous work that focused on older and younger deposits: Older dated deposits include the 5 Ma Bouse Formation, which records the integration of the Colorado River through a series of preexisting basins to the Gulf of California and the ca. 4.5 - 3.5 Ma Bullhead Alluvium, a 200 to 300 m thick aggregational package that immediately followed integration. The much younger, 100 - 70 ka, Chemehuevi Formation is another major aggradation package mapped throughout the LCRC. The new burial ages on the facies of Santa Fe Railway (4.37 ± 0.71 Ma), boulder conglomerate of Bat Cave Wash (2.12 ± 0.26 and 2.05 ± 0.31 Ma), and the Palo Verde alluvium (3.03 ± 0.26 Ma) partially fill in a 3.5 M.y. gap between the deposition of the Bullhead Alluvium and the Chemeheuvi Formation and document the timescales over which the Colorado River was able to remove the Bullhead aggradational package and initiate newer and smaller aggradational pulses.

Arizona, California, Nevada