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Geologic studies in Alaska by the U.S. Geological Survey, 1992

This collection of 19 papers continues the annual series of U.S. Geological Survey reports on the geology of Alaska. The contributions, which include full-length Articles and shorter Geologic Notes, cover a broad range of topics including dune formation, stratigraphy, paleontology, isotopic dating, mineral resources, and tectonics. Articles, grouped under four regional headings, span nearly the entire State from the North Slope to southwestern, south-central, and southeastern Alaska (fig. 1). In the section on northern Alaska, Galloway and Carter use new data on dune morphology and radiocarbon ages from the western Arctic Coastal Plain to develop a late Holocene chronology of multiple episodes of dune stabilization and reactivation for the region. Their study has important implications for climatic changes in northern Alaska during the past 4,000 years. In two papers, Dumoulin and her coauthors describe lithofacies and conodont faunas of Carboniferous strata in the western Brooks Range, discuss depositional environments, and propose possible correlations and source areas for some of the strata. Schenk and Bird propose a preliminary division of the Lower Cretaceous stratigraphic section in the central part of the North Slope into depositional sequences. Aleinikoff and others present new U-Pb data for zircons from metaigneous rocks from the central Brooks Range. Karl and Mull, reacting to a proposal regarding terrane nomenclature for northern Alaska that was published in last year's Alaskan Studies Bulletin, provide a historical perspective of the evolution of terminology for tectonic units in the Brooks Range and present their own recommendations.

Alaska↗

Water-quality and algal conditions in the North Umpqua River Basin, Oregon, 1992-95, and implications for resource management

This report describes the results of a synoptic water-quality and algal investigation during July 1995 at 36 stream sites in a 1,350 square-mile area of the North Umpqua River Basin, Oregon. The study area includes a headwaters hydroelectric project area, a Wild and Scenic reach in the main stem immediately downstream, and the watersheds of several major tributaries. Additional data from previous investigations are reviewed, and impacts on water quality in the Wild and Scenic reach from resource management, including forestry and reservoir operations, are inferred where sufficient data exist. Water-quality standards were occasionally exceeded for dissolved oxygen and pH, and daily maximum stream temperatures in the Wild and Scenic reach were higher than both the 1996 standard for the State of Oregon and the optimal temperature ranges for many anadromous fish. Dissolved oxygen in the basin was controlled more by stream temperature and reaeration than by primary production. Arsenic concentrations in the river during low flow (1 µg/L [microgram per liter]) indicate a potential cancer risk of between 1:5,000 and 1:20,000 for people using the river as a source of drinking water and fish for consumption. Streambed-sediment concentrations of arsenic, chromium, copper, manganese, and nickel were approximately double the sediment-quality criteria values adopted by New York State and by the Ontario Ministry of the Environment. High concentrations of phosphorus in bed sediments indicated that much of the phosphorus observed in the water column throughout the basin (medians: 32, 9, and 50 µg/L in the main stem, tributaries, and hydroelectric project areas, respectively) could have been geologically derived. Inorganic and organic nitrogen concentrations in water were mostly below minimum reporting limits (5 and 200 µg/L, respectively), indicating severe nitrogen limitation at most locations. Benthic algal biomass, biovolume, and chlorophyll a concentrations were highest at the sites directly below impoundments and at one headwater tributary (medians: 46 grams per square meter, 821 million cubic micrometers per square centimeter, and 126 milligrams per square meter, respectively), and were also somewhat elevated downstream in the Wild and Scenic reach compared with those in similar streams in the Pacific Northwest. Classification of the algal taxa indicated that, among all sites sampled, alkaliphilic taxa, nitrogen fixing taxa, and eutrophic taxa were the most abundant on the basis of biovolume and density. Cold-water taxa, facultative nitrogen heterotrophs, and oligotrophic taxa constituted the remainder of the taxa. Multivariate analyses indicated that algal communities at the hydroelectric-project-affected sites were distinct from communities at sites on the main stem and Steamboat Creek. At many locations, the river’s algal community might be compensating for the low nitrogen concentrations by fixation of atmospheric nitrogen or through heterotrophic assimilation of organic nitrogen. Water quality in the Wild and Scenic reach is dominated by water released from the hydroelectric project area during summer. Effects of the hydroelectric project include seasonal control of streamflow, water temperature, and phosphorus concentrations, and the possible release of low but ecologically important concentrations of organic nitrogen. A review of available data and literature suggests that the reservoirs can increase the interception of sediments and large organic debris, and promote their conversion into fine-grained particulate and dissolved organic matter for downstream transport. These effects could be compounded by the effects of forestry in the basin, including alteration of hydrologic cycles, changes in sediment and nutrient runoff, reductions of the transport of large woody debris, and degradation of habitat quality. It is hypothesized that, in the North Umpqua River, these processes have induced a fundamental shift in the river’s food web, from a detritus-based system to a system with a 2 higher emphasis on algal production. Confirmation of these changes and their effects on higher trophic levels are needed to properly manage the aquatic resources for all designated beneficial uses in the basin.

Oregon↗

Scientific advances provide opportunities to improve pediatric environmental health

The health consequences of contaminants in the environment, with respect to the health of children and infants, recently have been dramatically brought to public attention by the motion pictures Erin Brockovich and A Civil Action . These productions focused public attention on the potential link between water contaminants and pediatric health, a continuing subject of public concern. As a consequence of the increasing production of new commercial chemicals, many chemicals have appeared in the scientific and public awareness as potential threats to health. These new or novel compounds eventually distribute in the environment and often are termed emerging contaminants . Gitterman and Bearer stated, "Children may serve as unwitting sentinels for society; they are often the youngest exposed to many environmental toxicants and may become the youngest in age to manifest adverse responses." The discipline of pediatric environmental health is still in its adolescence, but it will be increasingly important as new chemicals are generated and as more is learned about the health effects of chemicals already in commerce. Here, we provide an overview of recent advances in biomonitoring and environmental monitoring of environmental contaminants including emerging contaminants. Our purpose in writing this commentary is to make pediatricians aware of the current resources available for learning about pediatric environmental health and of ongoing research initiatives that provide opportunities to improve pediatric environmental health.

Journal of Pediatrics↗

Age, distribution, and stratigraphic relationship of rock units in the San Joaquin Basin Province, California: Chapter 5 in Petroleum systems and geologic assessment of oil and gas in the San Joaquin Basin Province, California

The San Joaquin Basin is a major petroleum province that forms the southern half of California’s Great Valley, a 700-km-long, asymmetrical basin that originated between a subduction zone to the west and the Sierra Nevada to the east. Sedimentary fill and tectonic structures of the San Joaquin Basin record the Mesozoic through Cenozoic geologic history of North America’s western margin. More than 25,000 feet (>7,500 meters) of sedimentary rocks overlie the basement surface and provide a nearly continuous record of sedimentation over the past ~100 m.y. Further, depositional geometries and fault structures document the tectonic evolution of the region from forearc setting to strike-slip basin to transpressional margin. Sedimentary architecture in the San Joaquin Basin is complicated because of these tectonic regimes and because of lateral changes in depositional environment and temporal changes in relative sea level. Few formations are widespread across the basin. Consequently, a careful analysis of sedimentary facies is required to unravel the basin’s depositional history on a regional scale. At least three high-quality organic source rocks formed in the San Joaquin Basin during periods of sea level transgression and anoxia. Generated on the basin’s west side, hydrocarbons migrated into nearly every facies type in the basin, from shelf and submarine fan sands to diatomite and shale to nonmarine coarse-grained rocks to schist. In 2003, the U.S. Geological Survey (USGS) completed a geologic assessment of undiscovered oil and gas resources and future additions to reserves in the San Joaquin Valley of California (USGS San Joaquin Basin Province Assessment Team, this volume, chapter 1). Several research aims supported this assessment: identifying and mapping the petroleum systems, modeling the generation, migration, and accumulation of hydrocarbons, and defining the volumes of rock to be analyzed for additional resources. To better understand the three dimensional relationships between hydrocarbon source and reservoir rocks, we compiled a database consisting of more than 13,000 well picks and of one-mile resolution seismic grids. Both the well picks and the seismic grids characterize the depths to the top of key stratigraphic units. This database formed the basis of subsequent numerical modeling efforts, including the construction of a three- dimensional geologic model (Hosford Scheirer, this volume, chapter 7) and simulation of the petroleum systems in space and time (Peters, Magoon, Lampe, and others, this volume, chapter 12). To accomplish this modeling, we synthesized the age, geographic distribution, lithology, and petroleum characteristics of hydrocarbon source and reservoir rocks in the basin. The results of that synthesis are presented in this paper in the form of new stratigraphic correlation columns for the northern, central, and southern San Joaquin Valley (fig. 5.1; note that all figures are at the back of this report, following the References Cited). The stratigraphic relationships and ages published here draw heavily on published and unpublished studies of the San Joaquin Basin. The stratigraphy presented in each of the columns necessarily idealizes the subsurface geology over a relatively large area, instead of representing the specific geology at an individual well, oil and gas field, or outcrop. In this paper we present the background rationale for defining the geographic divisions of the basin (inset map, fig. 5.1), the paleontological time scales used for assigning absolute ages to rock units (figs. 5.2 and 5.3), and the supporting maps illustrating the geographic distribution of each rock type included in the stratigraphic column (figs. 5.4 through 5.64).

California↗

Toward an efficient framework for remote sensing of river bathymetry: Comparing sensors and algorithms on an inaccessible proglacial river in Alaska

Remote sensing can provide reliable information on river depths and this approach might be particularly valuable in areas that are difficult to survey via conventional field methods. In this study, we assessed the potential to map the bathymetry of an inaccessible proglacial river in Alaska from both aerial orthophotos and a multispectral satellite image. In addition, we evaluated a variety of depth retrieval algorithms with different input data requirements, including some methods that require field measurements of water depth for calibration and other techniques that can be applied even when such field data are not available. These approaches might enable more efficient use of remote sensing methods by resource management agencies. Our results suggest that bathymetric mapping along the turquoise-colored river we examined was not only feasible but highly accurate ( R 2 up to 0.94) for both types of image data. Algorithms that use paired observations of depth and reflectance to train depth retrieval models were the most accurate, with errors on the order of 15%–20% and little or no bias. Alternative techniques based on hydraulic and statistical concepts also led to strong agreement between predicted and observed depths but were more susceptible to systematic biases toward under- or over-estimation of depth. In contrast to clear-flowing streams, bathymetric mapping in this environment was enabled by a direct relationship between the depth and brightness of the water due to scattering by suspended sediment. In selecting an appropriate depth retrieval method, a compromise might need to be reached between the level of field effort invested and the accuracy of the resulting image-derived bathymetry. Standalone software for implementing these techniques is freely available.

Alaska↗

Rapid inundation of the southern Florida coastline despite low relative sea-level rise rates during the late-Holocene

Sediment cores from Florida Bay, Everglades National Park were examined to determine ecosystem response to relative sea-level rise (RSLR) over the Holocene. High-resolution multiproxy analysis from four sites show freshwater wetlands transitioned to mangrove environments 4–3.6 ka, followed by estuarine environments 3.4–2.8 ka, during a period of enhanced climate variability. We calculate a RSLR rate of 0.67 ± 0.1 mm yr −1 between ~4.2–2.8 ka, 4–6 times lower than current rates. Despite low RSLR rates, the rapid mangrove to estuarine transgression was facilitated by a period of prolonged droughts and frequent storms. These findings suggest that with higher and accelerating RSLR today, enhanced climate variability could further hasten the loss of mangrove-lined coastlines, compounded by the reductions in natural flow to the coast caused by water management. Climate variability is nonlinear, and when superimposed on increases in RSLR, can complicate estimated trajectories of coastal inundation for resource management and urban planning.

Florida↗

Machine learning identifies a strong association between warming and reduced primary productivity in an oligotrophic ocean gyre

Phytoplankton play key roles in the oceans by regulating global biogeochemical cycles and production in marine food webs. Global warming is thought to affect phytoplankton production both directly, by impacting their photosynthetic metabolism, and indirectly by modifying the physical environment in which they grow. In this respect, the Bermuda Atlantic Time-series Study (BATS) in the Sargasso Sea (North Atlantic gyre) provides a unique opportunity to explore effects of warming on phytoplankton production across the vast oligotrophic ocean regions because it is one of the few multidecadal records of measured net primary productivity (NPP). We analysed the time series of phytoplankton primary productivity at BATS site using machine learning techniques (ML) to show that increased water temperature over a 27-year period (1990–2016), and the consequent weakening of vertical mixing in the upper ocean, induced a negative feedback on phytoplankton productivity by reducing the availability of essential resources, nitrogen and light. The unbalanced availability of these resources with warming, coupled with ecological changes at the community level, is expected to intensify the oligotrophic state of open-ocean regions that are far from land-based nutrient sources.

Scientific Reports↗

Human interactions with ground-water

Ground-Water could be considered as an immense reservoir, from which only a certain amount of water can be withdrawn without affecting the quantity and quality of water. This amount is determined by the characteristics of the environment in which ground-water occurs and by the interactions of ground-water with precipitation, surface water, and people. It should be recognized that quantity and quality of ground-water are intimately related and should be considered accordingly. Quantity refers to usable water and water is usable for any specific purpose only so long as its quality has not deteriorated beyond acceptable limits. Thus an overall quantitative and qualitative management of ground water is inevitable, and its should also involve the uses of ground-water reservoirs for purposes other than water supply. The main objective of ground-water management is to ensure that ground-water resources will be available in appropriate time and in appropriate quantity and quality to meet the most important demands of our society. Traditional, and obvious uses of ground-water are the extraction of water for water supplies (domestic, municipal, agricultural, and industrial) and the natural discharge feeding lakes and maintaining base flow of streams. Not so obvious are the uses of ground-water reservoirs, the very framework within which ground-water occurs and moves, and in which other fluids or materials can be stored. In the last two decades, ground-water reservoirs have been intensively considered for many other purposes than water supplies. Diversified and very often conflicting uses need to be evaluated and dealt with in the most efficient way in order to determine the importance of each possible use, and to assign priorities of these uses. With rising competition for the use of ground-water reservoirs, we will also need to increase the potential for effective planning of ground-water development and protection. Man's development and use of ground-water necessarily modifies the natural conditions and the total natural system must be successfully blended with the unnatural stresses placed upon it. This can be accomplished by introducing new methods (such as ground-water zoning) in and by developing alternative strategies for ground-water management and protection. ?? 1983 D. Reidel Publishing Company.

GeoJournal↗

Field methods for measurement of fluvial sediment

The complexity of hydrologic and physical environments and man's ever-increasing data needs make it essential for those who collect sediment data to be aware of basic concepts involved in the processes of erosion, transport, and deposition of sediment, and of the equipment and procedures necessary to representatively sample sediment and measure its concentration. This report describes equipment and procedures for the collection and measurement of fluvial sediment.

Techniques of Water-Resources Investigations↗

Hydrogeology of the area near the J4 test cell, Arnold Air Force Base, Tennessee

The U.S. Air Force operates a major aerospace systems testing facility at Arnold Engineering Development Center (AEDC) in Coffee County, Tennessee. Dewatering operations at one of the test facilities, the J4 test cell, has affected the local ground-water hydrology. The J4 test cell is approximately 100 feet in diameter, extends approximately 250 feet below land surface, and penetrates several aquifers. Ground water is pumped continuously from around the test cell to keep the cell structurally intact. Because of the test cell's depth, dewatering has depressed water levels in the aquifers surrounding the site. The depressions that have developed exhibit anisotropy that is controlled by zones of high permeability in the aquifers. Additionally, contaminants - predominately volatile organic compounds - are present in the ground-water discharge from the test cell and in ground water at several other Installation Restoration Program (IRP) sites within the AEDC facility. The dewatering activities at J4 are drawing these contaminants from the nearby sites. The effects of dewatering at the J4 test cell were investigated by studying the lithologic and hydraulic characteristics of the aquifers, investigating the anisotropy and zones of secondary permeability using geophysical techniques, mapping the potentiometric surfaces of the underlying aquifers, and developing a conceptual model of the ground-water-flow system local to the test cell. Contour maps of the potentiometric surfaces in the shallow, Manchester, and Fort Payne aquifers (collectively, part of the Highland Rim aquifer system) show anisotropic water-level depressions centered on the J4 test cell. This anisotropy is the result of features of high permeability such as chert-gravel zones in the regolith and fractures, joints, and bedding planes in the bedrock. The presence of these features of high permeability in the Manchester aquifer results in complex flow patterns in the Highland Rim aquifers near the J4 test cell. The occurrence, distribution, and orientation of these features has a great effect on ground-water flow to the J4 test cell. The depression caused by dewatering extends out horizontally through the aquifers along the most permeable pathways. Since the aquifers above the Chattanooga Shale are not separated by distinct confining units, areas in adjacent aquifers above and below these zones of high permeability in the Manchester aquifer are also dewatered. Conditions in all Highland Rim aquifers approximate steady-state equilibrium because ground-water withdrawal at the test cell has been continuous since the late 1960's. The average ground-water discharge from the dewatering system at the J4 test cell was 105 gallons per minute, for 1992-95. The ground-water capture areas in each aquifer extend into all or parts of landfill #2 and leaching pit #2 (IRP site 1), the main testing area (IRP site 7), and the old fire training area (IRP site 10). IRP sites 8 and 12 are outside the ground-water capture areas. Of the 35 sampled wells in the J4 area, 10 produced water samples containing chlorinated organic compounds such as 1,2-dichloroethane (1,2-DCA), 1,1-dichloroethylene (1,1-DCE), and trichloroethylene (TCE) in concentrations which exceeded the Tennessee Department of Environment and Conservation Maximum Contaminant Levels (MCL's) for public water-supply systems. The highest concentrations were detected in samples from well AEDC-274 with 45 micrograms per liter (mg/L) 1,2-DCA, 320 mg/L 1,1-DCE, and 1,200 mg/L TCE. These compounds are synthetic and do not occur naturally in the environment. A sample of the ground-water discharge from the J4 test cell also contained concentrations of these compounds that exceed MCL's. Chlorinated organic compounds, including 1,2-DCA; 1,1-DCE; and TCE also have been detected at IRP sites 1, 7, 8, nd 10. The six dewatering wells surrounding the J4 test cell penetrate the Chattanooga Shale and are open to the Highland Rim aquifer system, there

Water-Resources Investigations Report↗

Summary appraisals of the Nation's ground-water resources; Alaska

Alaska has enormous surface-water resources, but many of the streams are frozen for most of the year and most contain glacial silt that makes them unacceptable for human use. These factors lend special significance to ground water as a water-supply source, even though perennially frozen ground (permafrost) profoundly modifies ground-water flow systems in much of Alaska north of the maritime southern coast and southeastern panhandle areas. Frozen ground is a virtually impermeable layer that restricts recharge, discharge, and movement of ground water, acts as a confining layer and limits the volume of unconsolidated deposits and bedrock in which water may be stored. Ground water is an untested resource in most of Alaska, but in many areas potential development of ground water far exceeds current use. Alluvium of major river valleys, such as the Yukon, Tanana, Kuskokwim and Susitna Rivers, probably contains the most extensive aquifers in the State. Large amounts of ground water are also stored in glacial outwash aquifers that underlie coastal basins and valleys, such as those at Kenai and Anchorage in the Cook Inlet lowland. Individual wells yielding more than 1,000 gallons per minute have been developed in the Tanana River valley, Cook Inlet lowland, and the coastal valleys at Seward and Juneau. Comparable yields should be possible in other areas that have similar geohydrologic environments. No major aquifers have been identified in glacial and glaciolacustrine deposits of interior valleys or in deltaic deposits. Major bedrock aquifers have been identified only in carbonate rocks of the Brooks Range and on the north side of the Alaska Range. Springs issuing from the carbonate rocks of the Brooks Range have discharges as great as 16,000 gallons per minute. Most ground-water recharge occurs beneath reaches of stream channels that are losing flow to the ground-water system. Most ground-water discharge also takes place along reaches of stream channels. This discharge augments streamflows during summer and maintains low flows during winter when there is no surface-water runoff. On the basis of a streamflow hydrograph separation technique and using the 60 percent flow-duration value as an indicator of ground-water discharge, it is estimated that 25 percent of the total volume of streamflow in Alaska (exclusive of coastal, maritime environments) is contributed by ground-water discharge. The thawing of frozen ground in the permafrost regions of Alaska causes construction and engineering problems. Disturbance of the ground surface disrupts the natural thermal equilibrium and tends to thaw part of the permafrost. Thawing can cause loss of strength, a decrease in volume, and an increase in erosion potential, particularly if the frozen ground is fine grained and poorly drained. Present deficiencies in the ground-water information base are obvious limiting factors to ground-water development in Alaska. There is a need to extend the ground-water data-collection network and to pursue special research into the quantitative aspects of ground-water hydrology in cold regions, particularly the continuous permafrost zone.

Alaska↗

Landscape transcriptomics as a tool for addressing global change effects across diverse species

Landscape transcriptomics is an emerging field studying how genome-wide expression patterns reflect dynamic landscape-scale environmental drivers, including habitat, weather, climate, and contaminants, and the subsequent effects on organismal function. This field is benefitting from advancing and increasingly accessible molecular technologies, which in turn are allowing the necessary characterization of transcriptomes from wild individuals distributed across natural landscapes. This research is especially important given the rapid pace of anthropogenic environmental change and potential impacts that span levels of biological organization. We discuss three major themes in landscape transcriptomic research: connecting transcriptome variation across landscapes to environmental variation, generating and testing hypotheses about the mechanisms and evolution of transcriptomic responses to the environment, and applying this knowledge to species conservation and management. We discuss challenges associated with this approach and suggest potential solutions. We conclude that landscape transcriptomics has great promise for addressing fundamental questions in organismal biology, ecology, and evolution, while providing tools needed for conservation and management of species.

Molecular Ecology Resources↗

Current limitations and recommendations to improve testing for the environmental assessment of endocrine active substances

In the present study, existing regulatory frameworks and test systems for assessing potential endocrine active chemicals are described, and associated challenges are discussed, along with proposed approaches to address these challenges. Regulatory frameworks vary somewhat across geographies, but all basically evaluate whether a chemical possesses endocrine activity and whether this activity can result in adverse outcomes either to humans or to the environment. Current test systems include in silico, in vitro, and in vivo techniques focused on detecting potential endocrine activity, and in vivo tests that collect apical data to detect possible adverse effects. These test systems are currently designed to robustly assess endocrine activity and/or adverse effects in the estrogen, androgen, and thyroid hormone signaling pathways; however, there are some limitations of current test systems for evaluating endocrine hazard and risk. These limitations include a lack of certainty regarding: 1) adequately sensitive species and life stages; 2) mechanistic endpoints that are diagnostic for endocrine pathways of concern; and 3) the linkage between mechanistic responses and apical, adverse outcomes. Furthermore, some existing test methods are resource intensive with regard to time, cost, and use of animals. However, based on recent experiences, there are opportunities to improve approaches to and guidance for existing test methods and to reduce uncertainty. For example, in vitro high-throughput screening could be used to prioritize chemicals for testing and provide insights as to the most appropriate assays for characterizing hazard and risk. Other recommendations include adding endpoints for elucidating connections between mechanistic effects and adverse outcomes, identifying potentially sensitive taxa for which test methods currently do not exist, and addressing key endocrine pathways of possible concern in addition to those associated with estrogen, androgen, and thyroid signaling.

Integrated Environmental Assessment and Management↗

Fluorine, fluorite, and fluorspar in central Colorado

Fluorine (F) is a widespread element that was deposited in a variety of rocks, minerals, and geologic environments in central Colorado. It occurs as a trace element, as a major component of the mineral fluorite (CaFs), and as a major economic source of fluorine in fluorspar deposits, which are massive concentrations of fluorite. This study has compiled available geochemical analyses of rocks, both unmineralized and mineralized, to determine the distribution of fluorine in specific age-lithologic categories, ranging from 1.8-giga-annum (Ga) metamorphic rocks to modern soils, throughout central Colorado. It also draws upon field studies of fluorine-rich mineral deposits, including fluorspar deposits, to decipher the nearly two-billion-year-long geologic history of fluorine in the study area, with implications for mineral-resource evaluations and exploration. The resulting compilation provides an important inventory of the naturally occurring levels and sources of fluorine that ultimately weather, erode, and become part of surface waters that are used for domestic water supplies in densely populated areas along the Colorado Front Range. Most commonly, fluorine is a trace element in virtually all rocks in the region. In the 3,798 unmineralized rocks that were analyzed for fluorine in the study area, the average fluorine content was 1,550 parts per million (ppm). The median was 640 ppm, nearly identical to the average crustal abundance of 650 ppm, and some high-fluorine rocks in the Pikes Peak area skewed the average to a value much greater than the median. Most unmineralized age-lithologic rock suites, including Proterozoic metamorphic rocks, 1.7- and 1.4-Ga granitic batholiths, Cambrian igneous rocks, Phanerozoic sedimentary rocks, and Laramide and Tertiary igneous rocks, had median fluorine values of 400 to 740 ppm fluorine. In all suites, however, a small number of analyzed samples contained more than 1 percent (10,000 ppm) fluorine. The 1.1-Ga plutonic rocks related to the Pikes Peak batholith had a mean fluorine content of 1,700 ppm, and primary magmatic fluorite and fluorite-bearing pegmatites are common throughout that igneous mass. Fluorine was deposited in many types of economic mineral deposits in central Colorado, and it currently is a significant trace element in some thermal springs. In the fluorspar deposits, fluorine contents were as high as 37 percent. Some fluorine-rich porphyry systems, such as Jamestown, had fluorine values that ranged from 200 ppm to nearly 37 percent fluorine, and veins in other deposits contained hydrothermal fluorite, although it was not ubiquitous. For the 495 samples from non-fluorspar mining districts (and excluding Jamestown), however, the median fluorine content was 990 ppm. This is above the crustal average but still relatively modest compared to the fluorspar deposits, and it indicates that the majority of the mineralizing systems in central Colorado did not deposit large amounts of fluorine. Nevertheless, the fluorine- and fluorite-rich mineral deposits could be used as guides for the evaluation and discovery of related but concealed porphyry and epithermal base- and precious-metal deposits. The Cenozoic geologic history of central Colorado included multiple periods during which fluorine-bearing rocks and mineral deposits were exposed, weathered, and eroded. This protracted history has released fluorine into soils and regoliths, and modern rainfall and snowmelt interact with these substrates to add fluorine to the hydrosphere. This study did not evaluate the fluorine contents of water or make any predictions about what areas might be major sources for dissolved fluorine. However, the abundant data that are available on fluorine in surface water and ground water can be coupled with the results of this study to provide additional insight into natural sources of fluorine in domestic drinking water.

Scientific Investigations Report↗

A two-phase sampling design for increasing detections of rare species in occupancy surveys

1. Occupancy estimation is a commonly used tool in ecological studies owing to the ease at which data can be collected and the large spatial extent that can be covered. One major obstacle to using an occupancy-based approach is the complications associated with designing and implementing an efficient survey. These logistical challenges become magnified when working with rare species when effort can be wasted in areas with none or very few individuals. 2. Here, we develop a two-phase sampling approach that mitigates these problems by using a design that places more effort in areas with higher predicted probability of occurrence. We compare our new sampling design to traditional single-season occupancy estimation under a range of conditions and population characteristics. We develop an intuitive measure of predictive error to compare the two approaches and use simulations to assess the relative accuracy of each approach. 3. Our two-phase approach exhibited lower predictive error rates compared to the traditional single-season approach in highly spatially correlated environments. The difference was greatest when detection probability was high (0·75) regardless of the habitat or sample size. When the true occupancy rate was below 0·4 (0·05-0·4), we found that allocating 25% of the sample to the first phase resulted in the lowest error rates. 4. In the majority of scenarios, the two-phase approach showed lower error rates compared to the traditional single-season approach suggesting our new approach is fairly robust to a broad range of conditions and design factors and merits use under a wide variety of settings. 5. Synthesis and applications. Conservation and management of rare species are a challenging task facing natural resource managers. It is critical for studies involving rare species to efficiently allocate effort and resources as they are usually of a finite nature. We believe our approach provides a framework for optimal allocation of effort while maximizing the information content of the data in an attempt to provide the highest conservation value per unit of effort.

Methods in Ecology and Evolution↗

Biology and invasive species in the western U.S

The diversity of environments that characterizes the West is responsible for the region's rich biological heritage. This ecological diversity also means that opportunities for invasive species are many, varied, and complex. Island ecosystems are notoriously vulnerable to invaders as demonstrated in Hawaii and West Coast offshore islands. Aquatic invaders impose high economic and environmental costs in systems as varied as San Francisco Bay and desert springs in the Great Basin. Although the West's arid and montane ecosystems may seem resistant to plant and animal invaders, we now know that ex-otic species have altered physical processes related to fire and hydrology in a manner favoring further expansion and persis-tence of invaders. Natural resource managers value analytical, mapping, and genetics tools developed by USGS scientists to monitor invasive species and help conserve biological systems. USGS biologists conduct research to assist land and water managers' efforts to control invasive species and restore natural systems. Throughout the West, the USGS carries out studies for early detection and rapid assessment of invaders. The following are some examples of how the USGS is making a difference in the western United States.

Fact Sheet↗

Compilation of mercury data and associated risk to human and ecosystem health, Bad River Band of Lake Superior Chippewa, Wisconsin

Mercury is an environmentally ubiquitous neurotoxin, and its methylated form presents health risks to humans and other biota, primarily through dietary intake. Because methylmercury bioaccumulates and biomagnifies in living tissue, concentrations progressively increase at higher trophic positions in ecosystem food webs. Therefore, the greatest health risks are for organisms at the highest trophic positions and for humans who consume organisms such as fish from these high trophic positions. Data on environmental mercury concentrations in various media and biota provide a basis for comparison among sites and regions and for evaluating ecosystem health risks. The U.S. Geological Survey, in cooperation with the Natural Resources Department, Bad River Band of Lake Superior Chippewa, have compiled a dataset from analyses of mercury concentrations in surface water, bed sediment, fish tissue, Rana clamitans (green frog) tissue, Haliaeetus leucocephalus (bald eagle) feathers, Lontra canadensis (North American river otter) hair, Zizania palustris (northern wild rice), and litterfall from samples collected in the Bad River watershed, Wisconsin during 2004–18. These data originated from either the Natural Resources Department or another agency based on samples collected within or near to Bad River Tribal lands before transfer to the U.S. Geological Survey for compilation and analysis at the onset of the project. This report describes the compiled mercury dataset, provides comparisons to similar measurements in the region and elsewhere, and evaluates health risks to humans and to the sampled biota. Except for litterfall, data were not collected on a consistent, regular basis over a sufficient period to evaluate temporal patterns. The reported mercury concentrations are generally similar to those reported elsewhere in the upper Great Lakes region. Reported values are consistent with atmospheric deposition as the principal source and reflect a favorable environment for mercury methylation. Fish mercury concentrations increased at higher food web positions and generally increased with length in most species measured. Sander vitreus (walleye) present the greatest risk to humans among fishes considered here because of their high trophic position and associated elevated mercury concentrations in combination with relatively high walleye consumption rates by the Native American community. Methylmercury concentrations in wild rice are generally low and likely pose little health risk. Despite reports of declining atmospheric mercury deposition across eastern North America during the past decade, a downward trend in litterfall mercury deposition was not evident in samples collected during 2012–18. Limitations in this data compilation and analysis were noted due to missing information such as collection dates and site locations for some samples. Regular monitoring of mercury in litterfall and surface waters along with periodic collection of fish would enable evaluation of temporal change in the mercury cycle that might affect future risk to humans and aquatic ecosystem inhabitants.

Wisconsin↗

Application of surface geophysics to ground-water investigations

This manual reviews the standard methods of surface geophysics applicable to ground-water investigations. It covers electrical methods, seismic and gravity methods, and magnetic methods. The general physical principles underlying each method and its capabilities and limitations are described. Possibilities for non-uniqueness of interpretation of geophysical results are noted. Examples of actual use of the methods are given to illustrate applications and interpretation in selected geohydrologic environments. The objective of the manual is to provide the hydrogeologist with a sufficient understanding of the capabilities, imitations, and relative cost of geophysical methods to make sound decisions as to when to use of these methods is desirable. The manual also provides enough information for the hydrogeologist to work with a geophysicist in designing geophysical surveys that differentiate significant hydrogeologic changes.

Techniques of Water-Resources Investigations↗